JPH0872097A - In-mold coating molding method for rim molding - Google Patents
In-mold coating molding method for rim moldingInfo
- Publication number
- JPH0872097A JPH0872097A JP23405194A JP23405194A JPH0872097A JP H0872097 A JPH0872097 A JP H0872097A JP 23405194 A JP23405194 A JP 23405194A JP 23405194 A JP23405194 A JP 23405194A JP H0872097 A JPH0872097 A JP H0872097A
- Authority
- JP
- Japan
- Prior art keywords
- mold
- rim
- molded product
- molding
- paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
- B29C37/0028—In-mould coating, e.g. by introducing the coating material into the mould after forming the article
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/005—Compensating volume or shape change during moulding, in general
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
- B29C67/246—Moulding high reactive monomers or prepolymers, e.g. by reaction injection moulding [RIM], liquid injection moulding [LIM]
Landscapes
- Moulds For Moulding Plastics Or The Like (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】この発明は、RIM成形品のイン
モールドコート成形法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an in-mold coat molding method for RIM molded products.
【0002】[0002]
【従来の技術】RIM成形品は、リアクションインジェ
クションモールディング(RIM)成形機を用いて、ポ
リオール成分とイソシアネート成分の2系統に分かれた
RIM原料を高圧で衝突させ、その衝突後のRIM原料
を金型内に吐出させて成形されるもので、プラスチック
成形品の一つとして種々の分野で用いられている。2. Description of the Related Art RIM molded articles are produced by using a reaction injection molding (RIM) molding machine to collide RIM raw materials separated into two systems, a polyol component and an isocyanate component, at high pressure, and mold the RIM raw materials after the collision. It is discharged and molded inside, and is used in various fields as one of plastic molded products.
【0003】このRIM成形品においては、その成形時
に成形品表面にピンホール(微細な孔)を生じ易いた
め、金型から取り出した後に成形品表面を塗装して塗膜
を形成することがなされる。しかし、その塗装により形
成された塗膜にもピンホールが発生し易く平滑な表面を
得難い問題がある。In this RIM molded product, since pin holes (fine holes) are easily formed on the surface of the molded product during molding, it is necessary to coat the surface of the molded product after taking it out of the mold to form a coating film. It However, there is a problem that pinholes are easily generated in the coating film formed by the coating and it is difficult to obtain a smooth surface.
【0004】近年、前記ピンホールをなくすため、RI
M成形品表面にインモールドコート成形法により塗膜を
形成することが提案されている。このRIM成形品のイ
ンモールドコート成形法は、通常上型と下型で構成され
る金型のキャビティにRIM原料を充填してRIM成形
品を成形した後、前記金型内でのRIM成形品の収縮に
より生じるRIM成形品表面と上型キャビティ面間の隙
間に、上型の塗料注入孔から塗料を注入して、前記RI
M成形品表面に塗膜を形成する方法である。In recent years, in order to eliminate the pinhole, RI
It has been proposed to form a coating film on the surface of an M molded product by an in-mold coat molding method. The in-mold coat molding method for this RIM molded product is performed by filling a cavity of a mold, which is usually composed of an upper mold and a lower mold, with a RIM raw material to mold the RIM molded product, and then forming the RIM molded product in the mold. The paint is injected from the paint injection hole of the upper mold into the gap between the surface of the RIM molded product and the cavity surface of the upper mold caused by the contraction of
This is a method of forming a coating film on the surface of an M molded product.
【0005】このRIM成形品のインモールドコート成
形法によれば、RIM成形品の成形時にその成形品表面
に発生したピンホール(微細な孔)に、前記塗料が圧入
されてピンホールが塞がれるとともに、RIM成形品表
面を覆う塗膜自体にもピンホールが発生し難いため、平
滑な塗膜で覆われた成形品が得られる。According to this in-mold coat molding method for RIM molded products, the paint is press-fitted into the pinholes (fine holes) generated on the surface of the RIM molded product at the time of molding to close the pinholes. In addition, pinholes are unlikely to occur in the coating film itself that covers the surface of the RIM molded product, so that a molded product covered with a smooth coating film can be obtained.
【0006】しかし、前記RIM成形品のインモールド
コート成形法によって形成される塗膜は、RIM成形品
の収縮率やRIM成形品の厚み等によって異なるもの
の、通常50〜100μm程度の厚みであり、RIM成
形品の用途によっては感触が硬く、不向きな場合があ
る。また、前記塗膜の厚みを大にしても、塗膜のソフト
感はそれ程向上せず、ソフト感の更なる向上が求められ
ている。However, the coating film formed by the in-mold coat molding method of the RIM molded product is usually about 50 to 100 μm in thickness, although it varies depending on the shrinkage ratio of the RIM molded product and the thickness of the RIM molded product. Depending on the application of the RIM molded product, the feel may be hard and unsuitable. Further, even if the thickness of the coating film is increased, the soft feeling of the coating film is not improved so much, and further improvement of the soft feeling is demanded.
【0007】[0007]
【発明が解決しようとする課題】そこで本発明は、RI
M成形品の表面に、ソフトかつ平滑な塗膜を形成できる
インモールドコート成形法の提供を目的とする。Therefore, the present invention is based on the RI
An object of the present invention is to provide an in-mold coat molding method capable of forming a soft and smooth coating film on the surface of an M molded product.
【0008】[0008]
【課題を解決するための手段】この発明は、金型内のキ
ャビティにRIM原料を充填してRIM成形品を成形し
た後、前記金型内でRIM成形品を収縮させてRIM成
形品表面と金型の下型キャビティ面間に隙間を形成し、
該隙間に前記下型に形成した塗料注入孔から気泡混入塗
料を注入して、前記RIM成形品表面にソフトな塗膜を
形成することを特徴とするRIM成形品のインモールド
コート成形法に係る。According to the present invention, a cavity in a mold is filled with a RIM raw material to mold an RIM molded product, and then the RIM molded product is contracted in the mold to form a surface of the RIM molded product. Form a gap between the lower mold cavities of the mold,
According to the in-mold coat molding method for an RIM molded product, characterized in that an air-blended paint is injected into the gap from a paint injection hole formed in the lower mold to form a soft coating film on the surface of the RIM molded product. .
【0009】[0009]
【実施例】以下添付の図面に従ってこの発明を詳細に説
明する。図1はこの発明の成形法の一例におけるRIM
原料充填時を示す金型の断面図、図2はRIM成形品の
収縮時を示す金型の断面図、図3は気泡混入塗料注入時
を示す金型の断面図、図4はそれにより得られた成形品
の部分拡大断面図、図5は他の実施例の金型の断面図で
ある。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described in detail below with reference to the accompanying drawings. FIG. 1 shows the RIM in one example of the molding method of the present invention.
2 is a sectional view of the mold showing the time of filling the raw material, FIG. 2 is a sectional view of the mold showing the contraction of the RIM molded product, FIG. 3 is a sectional view of the mold showing the time of injecting paint containing air bubbles, and FIG. FIG. 5 is a partially enlarged sectional view of the obtained molded product, and FIG. 5 is a sectional view of a mold of another embodiment.
【0010】図1に示す金型10は、上型21と下型3
1とからなり、成形品形状のキャビティ11を内部に有
し、またそのキャビティ11に通じる原料注入孔12を
有している。この原料注入孔12には、公知のRIM成
形機の原料注入ヘッド41が接続される。The mold 10 shown in FIG. 1 includes an upper mold 21 and a lower mold 3.
1 has a cavity 11 in the shape of a molded product inside, and also has a raw material injection hole 12 communicating with the cavity 11. A raw material injection head 41 of a known RIM molding machine is connected to the raw material injection hole 12.
【0011】上型21は、成形品の裏側面を成形するキ
ャビティ面22を有する。一方、下型31は、成形品の
表側面を形成するキャビティ面32を有し、そのキャビ
ティ面32の所定位置に塗料注入孔33が形成されてい
る。この塗料注入孔33には、塗料注入機のヘッド42
が接続されている。塗料注入機は、この実施例ではポリ
オール側とイソシアネート側とに分かれた2液ウレタン
系塗料用の公知の塗料注入機を用い、そのポリオール側
に気泡混入のためのエアーローディング装置50が接続
されている。The upper mold 21 has a cavity surface 22 for molding the back side surface of the molded product. On the other hand, the lower mold 31 has a cavity surface 32 forming the front surface of the molded product, and a paint injection hole 33 is formed at a predetermined position on the cavity surface 32. A head 42 of the paint pouring machine is provided in the paint pouring hole 33.
Is connected. The paint injecting machine used in this embodiment is a known paint injecting machine for two-component urethane-based paint which is divided into a polyol side and an isocyanate side, and an air loading device 50 for mixing air bubbles is connected to the polyol side. There is.
【0012】前記エアーローディング装置50は、塗料
注入機のポリオール側タンクと接続されて、そのタンク
内のポリオール側塗料に空気を圧入することにより気泡
を混入する装置で、従来よりRIM原料の粘度低下用と
してRIM成形機に用いられているものが使用できる。
前記エアーローディング装置50によってポリオール側
塗料に圧入された空気は、タンク内のポリオール側塗料
の攪拌により微細な気泡としてポリオール側塗料内に分
散する。前記空気の混入量は体積%で10〜40%が好
ましい。前記ポリオール側塗料内に気泡を混入すること
によって、塗料の密度が下がり、RIM成形品表面に形
成される塗膜にソフト感を付与することができる。前記
エアーローディング装置50によって生成される気泡の
大きさは、約8〜23μmが好ましく、塗料の密度は約
0.8〜0.9g/cm3 となる。なお、気泡を混入さ
せない場合の塗料の密度は、約1.1g/cm3 であっ
た。The air loading device 50 is a device which is connected to a polyol side tank of a paint injecting machine and mixes air bubbles by injecting air into the polyol side paint in the tank. For the purpose, those used in the RIM molding machine can be used.
The air pressed into the polyol-side paint by the air loading device 50 is dispersed in the polyol-side paint as fine bubbles by stirring the polyol-side paint in the tank. The amount of the air mixed is preferably 10 to 40% by volume. By mixing air bubbles in the polyol-side paint, the density of the paint is reduced, and a soft feeling can be imparted to the coating film formed on the surface of the RIM molded product. The size of the bubbles generated by the air loading device 50 is preferably about 8 to 23 μm, and the density of the paint is about 0.8 to 0.9 g / cm 3 . The density of the coating material when air bubbles were not mixed was about 1.1 g / cm 3 .
【0013】次に、前記金型10を用いて行なうRIM
成形品のインモールドコート成形法について説明する。
まず、図1に示すように、原料注入ヘッド41からRI
M原料51aをキャビティ11内に充填する。充填され
たRIM原料51aは、キャビティ11内を満たし、直
ちに硬化してRIM成形品51を形成する。Next, RIM performed using the mold 10.
The in-mold coat molding method of the molded product will be described.
First, as shown in FIG.
The cavity 11 is filled with M raw material 51a. The filled RIM raw material 51a fills the inside of the cavity 11 and is immediately cured to form the RIM molded product 51.
【0014】前記金型10内で成形されたRIM成形品
51は、硬化反応の進行により図2に示すように成形品
全体が収縮し、下型キャビティ面32とRIM成形品5
1表面間に隙間Sを形成する。前記隙間Sは、用いるイ
ンモールドコート用塗料にもよるが、通常20〜60μ
m程度となるようにRIM原料の充填量等を設定するの
が好ましい。The RIM molded product 51 molded in the mold 10 shrinks as a whole as shown in FIG. 2 due to the progress of the curing reaction, and the lower mold cavity surface 32 and the RIM molded product 5 are formed.
A gap S is formed between the surfaces. The gap S is usually 20 to 60 μ, though it depends on the in-mold coating material used.
It is preferable to set the filling amount of the RIM raw material and the like so as to be about m.
【0015】ところで、前記RIM成形品51は、その
形状や上型21と下型31の温度差等によって、下型キ
ャビティ面32にRIM成形品51が密着したまま下型
31側へ収縮し、その下型キャビティ面32とRIM成
形品51間に全く隙間を生じず、塗料注入口33を塞ぐ
こともあり得る。By the way, the RIM molded product 51 shrinks to the lower mold 31 side while the RIM molded product 51 is in close contact with the lower mold cavity surface 32 due to the shape thereof, the temperature difference between the upper mold 21 and the lower mold 31, and the like. The paint injection port 33 may be closed without forming a gap between the lower mold cavity surface 32 and the RIM molded product 51.
【0016】しかし、図5に示すように、上型のキャビ
ティ面22に、RIM成形品の係止部23を形成してお
けば、当該係止部23に係止したRIM成形品を成形で
き、図中の鎖線で示したように、前記RIM成形品が前
記上型キャビティ面22に係止した状態で確実に上型側
へ収縮するので、常に下型キャビティ面32との間に隙
間を形成することができる。前記係止部23は、少なく
とも塗料注入口33と対向する位置の上型キャビティ面
22に設け、前記収縮時に塗料注入口33付近のRIM
成形品が下型31側へ収縮したり、または屈曲して塗料
注入口33を塞がないようにすることが好ましい。ま
た、この実施例の係止部23は内部が拡大した凹形状よ
りなり、キャビティ内のRIM成形品を確実に係止する
ことができるようになっている。However, as shown in FIG. 5, if the locking portion 23 of the RIM molded product is formed on the cavity surface 22 of the upper mold, the RIM molded product locked by the locking portion 23 can be molded. As shown by the chain line in the figure, the RIM molded product surely contracts to the upper mold side in a state of being locked to the upper mold cavity surface 22, so that there is always a gap between the RIM molded product and the lower mold cavity surface 32. Can be formed. The locking portion 23 is provided at least on the upper mold cavity surface 22 at a position facing the paint injection port 33, and the RIM near the paint injection port 33 at the time of the contraction.
It is preferable that the molded product does not contract toward the lower mold 31 or bend to prevent the paint injection port 33 from being blocked. Further, the locking portion 23 of this embodiment has a concave shape in which the inside is enlarged so that the RIM molded product in the cavity can be locked securely.
【0017】次いで、図3に示すように、前記下型31
の塗料注入孔33に挿入された塗料注入ヘッド42か
ら、前記RIM成形品51表面と下型キャビティ面32
間の隙間Sに気泡混入塗料15が注入される。気泡混入
塗料15は、インモールドコート用2液ウレタン系塗料
に、前記のようにエアーローディング装置50を用いて
気泡を混入したものが好適である。また、この気泡混入
塗料15は、前記隙間S内で気泡が流動可能なように、
注入時の粘度を1000cps以下に調整するのが好ま
しい。その粘度調整は、塗料温度および金型温度等を調
節することにより行なうことができる。なお、塗料に
は、必要に応じて整泡剤等の助剤が適宜添加される。Next, as shown in FIG. 3, the lower mold 31
From the paint injection head 42 inserted into the paint injection hole 33, the surface of the RIM molded product 51 and the lower mold cavity surface 32
The bubble-containing paint 15 is injected into the gap S between them. The bubble-containing paint 15 is preferably a two-component urethane-based paint for in-mold coating, in which bubbles are mixed by using the air loading device 50 as described above. Further, the bubble-mixed coating material 15 allows the bubbles to flow in the gap S.
The viscosity at the time of injection is preferably adjusted to 1000 cps or less. The viscosity can be adjusted by adjusting the paint temperature and the mold temperature. In addition, an auxiliary agent such as a foam stabilizer is appropriately added to the paint, if necessary.
【0018】前記隙間Sに注入された気泡混入塗料15
は、気泡が塗料内を上昇して上型キャビティ面21側へ
移動し、下型キャビティ面31付近では気泡が少ないス
キン層を形成する。その結果、前記気泡混入塗料15が
硬化することによってRIM成形品51表面に形成され
る塗膜は、表面に気泡によるピンホールがない平滑面と
なり、しかも前記気泡が塗膜内に分散しているため、ソ
フトなものとなる。図4は、その成形品の一部を示すも
ので、51はRIM成形品、16は気泡、17は塗膜で
ある。その後、金型を開いてRIM成形品を脱型する。
得られた成形品の表面は、ソフト感に優れ、しかも表面
にピンホールがない美麗な塗膜によって覆われている。Bubble-containing paint 15 injected into the gap S
Causes bubbles to rise in the paint and move toward the upper mold cavity surface 21 side, and forms a skin layer with few bubbles near the lower mold cavity surface 31. As a result, the coating film formed on the surface of the RIM molded product 51 by curing the bubble-containing paint 15 becomes a smooth surface without pinholes due to bubbles, and the bubbles are dispersed in the coating film. Therefore, it becomes soft. FIG. 4 shows a part of the molded product, 51 is a RIM molded product, 16 is a bubble, and 17 is a coating film. Then, the mold is opened and the RIM molded product is demolded.
The surface of the obtained molded product is covered with a beautiful coating film which is excellent in softness and has no pinholes on the surface.
【0019】[0019]
【発明の効果】以上図示し説明したように、この発明の
成形法によれば、RIM成形後の収縮により生じるRI
M成形品表面と金型キャビティ面間の隙間に、気泡を混
入した塗料を注入してRIM成形品表面に塗膜を形成す
るため、その気泡の存在によりソフトな塗膜を容易に形
成できる。さらに、前記気泡混入塗料を下型側から注入
するため、前記混入した気泡によるピンホールが塗膜表
面に生じるのを確実に防止することができ、良好な外観
からなる成形品を得ることができる。As shown and described above, according to the molding method of the present invention, RI generated by contraction after RIM molding is performed.
Since a paint mixed with bubbles is injected into the gap between the surface of the M molded product and the surface of the mold cavity to form a coating film on the surface of the RIM molded product, a soft coating film can be easily formed due to the presence of the bubbles. Furthermore, since the bubble-containing paint is injected from the lower mold side, it is possible to reliably prevent pinholes due to the mixed bubbles from being generated on the coating film surface, and it is possible to obtain a molded product having a good appearance. .
【図1】この発明の成形法の一例におけるRIM原料充
填時を示す金型の断面図である。FIG. 1 is a cross-sectional view of a mold showing RIM raw material filling in an example of the molding method of the present invention.
【図2】RIM成形品の収縮時を示す金型の断面図であ
る。FIG. 2 is a cross-sectional view of a mold showing a RIM molded product during contraction.
【図3】気泡混入塗料注入時を示す金型の断面図であ
る。FIG. 3 is a cross-sectional view of a mold showing the time of injecting paint containing air bubbles.
【図4】それにより得られた成形品の部分拡大断面図で
ある。FIG. 4 is a partially enlarged cross-sectional view of a molded product obtained thereby.
【図5】他の実施例の金型の断面図である。FIG. 5 is a sectional view of a mold of another embodiment.
10 金型 11 キャビティ 12 原料吐出口 15 気泡混入塗料 16 気泡 21 上型 31 下型 33 塗料注入口 50 エアーローディング装置 51 RIM成形品 10 Mold 11 Cavity 12 Raw Material Discharge Port 15 Air-Blended Paint 16 Bubble 21 Upper Mold 31 Lower Mold 33 Paint Inlet 50 Air Loading Device 51 RIM Molded Product
Claims (2)
してRIM成形品を成形した後、前記金型内でRIM成
形品を収縮させてRIM成形品表面と金型の下型キャビ
ティ面間に隙間を形成し、該隙間に前記下型に形成した
塗料注入孔から気泡混入塗料を注入して、前記RIM成
形品表面にソフトな塗膜を形成することを特徴とするR
IM成形品のインモールドコート成形法。1. A cavity in a mold is filled with an RIM raw material to mold an RIM molded product, and then the RIM molded product is contracted in the mold so that the surface between the RIM molded product surface and the lower mold cavity surface of the mold. R is characterized in that a gap is formed in the gap and a paint containing air bubbles is injected into the gap from the paint injection hole formed in the lower mold to form a soft coating film on the surface of the RIM molded product.
In-mold coat molding method for IM molded products.
にRIM成形品の係止部を設けたことを特徴とするRI
M成形品のインモールドコート成形法。2. The RI according to claim 1, wherein a locking portion for the RIM molded product is provided on the cavity surface of the upper mold.
In-mold coat molding method for M molded products.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23405194A JPH0872097A (en) | 1994-09-02 | 1994-09-02 | In-mold coating molding method for rim molding |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23405194A JPH0872097A (en) | 1994-09-02 | 1994-09-02 | In-mold coating molding method for rim molding |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0872097A true JPH0872097A (en) | 1996-03-19 |
Family
ID=16964808
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP23405194A Pending JPH0872097A (en) | 1994-09-02 | 1994-09-02 | In-mold coating molding method for rim molding |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0872097A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2781715A1 (en) * | 1998-07-30 | 2000-02-04 | Allibert Ind | Mold producing and coating plastic objects with paint, includes secondary cavity forming peripheral bead joined by thin web to main molding, to resist paint leakage in parting plane |
JP2008525212A (en) * | 2004-12-24 | 2008-07-17 | バイエル・マテリアルサイエンス・アクチェンゲゼルシャフト | Method for molding and coating a substrate |
US20220297345A1 (en) * | 2020-08-14 | 2022-09-22 | Raytheon Technologies Corporation | Method and system for molded coating on cmc |
-
1994
- 1994-09-02 JP JP23405194A patent/JPH0872097A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2781715A1 (en) * | 1998-07-30 | 2000-02-04 | Allibert Ind | Mold producing and coating plastic objects with paint, includes secondary cavity forming peripheral bead joined by thin web to main molding, to resist paint leakage in parting plane |
JP2008525212A (en) * | 2004-12-24 | 2008-07-17 | バイエル・マテリアルサイエンス・アクチェンゲゼルシャフト | Method for molding and coating a substrate |
US20220297345A1 (en) * | 2020-08-14 | 2022-09-22 | Raytheon Technologies Corporation | Method and system for molded coating on cmc |
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