JPH0864213A - Layer-built battery and manufacture thereof - Google Patents

Abstract

PURPOSE: To manufacture a small and thin layer-built battery excellent in the heat radiating property and volume energy density. CONSTITUTION: A positive electrode current collector 5 and a negative electrode current collector 6 concurrently serving as exterior bodies are arranged face to face. A positive electrode active material 7, a solid electrolyte 9, and a negative electrode active material 8 are arranged between them. The peripheral areas of the current collectors 5, 6 are stuck together with a thermo-adhesive resin frame 10, the frame 10 is protruded to the outside of the peripheral areas to form a thin type cell, multiple thin type cells are stacked, and the protruded portions 10a of the frames 10 are integrally stuck together. The frame 10 having the same size as the outer sizes of the current collectors 5, 6 is stuck to the current collectors 5, 6 by pressure, the frame 10 is protruded to the outside of the current collectors 5, 6 to form the thin type cell, then multiple thin type cells are stacked, and the protruded portions 10a of the frames 10 are integrated through mutual heat fusion.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a thin battery used in the fields of electronic devices, electric vehicles, toys, accessories, display devices, emergency power supplies, portable devices and the like.

[0002]

2. Description of the Related Art As shown in FIGS. 9 and 10, in a conventional battery, a positive electrode current collector 1 is provided with a projecting terminal portion 1a, and a negative electrode current collector 2 also has a similar projecting shape. Is provided with the terminal portion 2a. A window frame-shaped adhesive material 3 is arranged as a sealing material that also serves as an electrical insulator in the inner peripheral areas of the current collectors 1 and 2. Then, a positive electrode active material, a solid electrolyte, a negative electrode active material, and the like are arranged between the current collectors 1 and 2 and sealed with an adhesive material 3. When a plurality of such thin batteries 4 are stacked to increase the battery voltage, the lower battery 4 ′ and the upper battery 4 ″ of the same polarity terminal portion 2a do not overlap as shown in FIG. As described above, the batteries 4'and 4 "were stacked while being staggered. In the case of stacking without shifting, the terminal portions 1b and 2a of the overlapping current collectors are cut or subjected to an insulation treatment so that the terminal portions do not short-circuit. Further, in order to integrate the batteries 4 ′ and 4 ″, the surface of the stacked batteries was covered with a film or the like.

[0003]

DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention
The method of stacking the batteries 4'and 4 "by shifting them has a problem that the batteries become long in the lateral direction and the overall size becomes large. Further, the terminals 1a and 2a may be cut off or insulated. However, when the surface is covered with a film or the like, the heat radiation from the current collectors 5 and 6 deteriorates and the volume energy density also deteriorates. The present invention has been made in view of the above problems, and an object of the present invention is to provide a small and thin laminated battery excellent in heat dissipation and a volume energy density and a laminated battery thereof. It is to provide a manufacturing method.

[0004]

In order to achieve the above object, the laminated battery of the present invention comprises a positive electrode current collector 5 also serving as an outer package.
Between the negative electrode current collector 6 and the positive electrode active material 7, the solid electrolyte 9 and the negative electrode active material 8 are arranged, and the peripheral regions of the current collectors 5 and 6 are adhered to each other with a thermoadhesive resin frame 10, and It is characterized in that a plurality of thin batteries having the frame body 10 protruding outward from the peripheral region are laminated, and the protruding portions 10a of the frame body 10 are bonded and integrated. The size of the portion 10a of the frame body 10 protruding from the current collectors 5 and 6 is 0.2 mm.
The above is desirable. Further, in the method of the present invention, a thermo-adhesive resin frame 10 having the same outer dimensions as the current collectors 5 and 6 is pressure-bonded to the current collectors 5 and 6, and the frame 10 is collected. A thin battery protruding from the peripheral regions of the electric bodies 5 and 6 is produced, and then a plurality of the thin batteries are stacked, and the protruding portions 10a of the frame body 10 are adhered to each other to be integrated. Characterize.

[0005]

According to the present invention, since the thin battery is not provided with the terminal portion, there is no risk of short circuit and the battery can be made compact. Further, since the frame bodies 10 are bonded and integrated, the width dimension is substantially the same as the width dimension of the thin battery, and the thickness is the same as the laminated thickness of the thin batteries. Furthermore, the upper and lower collectors 5,
Since 6 is exposed, heat dissipation is easy. According to the second aspect, when the frame bodies 10 are adhered to each other, heat transfer to the current collectors 5 and 6 is reduced, and the negative electrode active material 8 can be prevented from melting. Further, the protruding portions 10a can be easily bonded to each other. According to the third aspect, since the current collectors 5 and 6 and the frame body 10 are pressure-bonded to each other with the same size, the alignment can be facilitated, and there is no displacement and a short circuit in the battery can be prevented. Further, since the frame bodies 10 are heat-welded to each other, they can be firmly bonded.

[0006]

【Example】

(Embodiment 1) The present invention will be described below with reference to the drawings. FIG. 1 is a perspective view of a main part of a strip-shaped positive electrode current collector 5 or negative electrode current collector 6 constituting a battery element according to the present invention, which is cut into a predetermined size from a continuously processed series. . That is, a large number of pieces are formed in a fixed pattern, cut at predetermined locations, and used as current collectors of individual thin batteries. 5a and 6a are alignment holes, 5b and 6b.
Is a partition hole of the pattern. This current collector 5 or 6 is
In order to provide non-porosity in terms of battery life, for example, stainless foil has a thickness of about 0.010 mm or more, and copper foil has a thickness of about 0.02.
0 mm or more is required. In each pattern area of the positive electrode current collector 5, a surface treatment for applying and curing a carbon-based resin is performed in order to enhance the adhesion with the positive electrode active material 7 and improve the bending characteristics. Thereafter, the positive electrode active material 7 is prepared by kneading manganese dioxide, nickel oxide, cobalt oxide, FeOCl, lithium vanadate, disulfide and the like with carbon, graphite, acetylene black, Ketjen black and other conductive materials, electrolytes and monomers. About 0.1
It is printed with a thickness of 5 mm to 0.20 mm and cured by electron beam irradiation (or heat, UV, etc.).

On the other hand, a negative electrode active material 8 such as metallic lithium, lithium-aluminum alloy or carbon is pressure-bonded or printed in each pattern area of the negative electrode current collector 6. Furthermore, the solid electrolyte 9 (electrolyte, so as to cover the entire surface of the negative electrode active material 8)
Monomer, filler, etc.) about 0.020 mm to 0.0
Printed on 55mm thick, electron beam irradiation (or heat V etc.)
To cure. Next, the inner size is about 0.2 to 0.5 mm larger than the outer size of each active material 7 and 8 and the outer size of the current collector (corresponding to the length between the insides of the patterned holes). A series of larger patterned thermo-adhesive resin frame bodies 10 shown in FIG. 2 are manufactured by press punching or engraving blade rolls, Thomson blades or the like to provide holes 10a at regular intervals. The frame 10 is made of, for example, polypropylene or modified polypropylene and has a thickness of about 0.20 mm to 0.30.
mm.

Next, the heat-adhesive resin frame 10 is placed on the negative electrode current collector 6, the holes 6a and 10a are aligned with each other, and the current collector 6
And the pattern of the frame body 10 are matched. Then, the positive electrode current collector 5 is placed on this, and the holes 5a and 10a are aligned with each other,
The patterns of the current collector 5 and the frame 10 are matched. next,
A heat plate is pressed from the outside of the current collectors 5 and 6 where the frame body 10 is arranged, the frame body 10 and the current collectors 5 and 6 are heat-welded, and arranged in a strip shape as shown in FIG. A large number of thin batteries are manufactured. Next, the connecting portions (5c, 6c in FIG. 1) of the partition holes 5b, 6b of the current collectors 5, 6 are trimmed with a laser or the like,
Electrically separate adjacent thin cells. After that, the frame body 10 was cut along the partition holes 5b and 6b to fabricate a thin battery in which a large number of strips were arranged as shown in FIG. The frame 1
The width dimension of the partition holes 5a, 6a is 0.4 mm or more so that 0 protrudes from the periphery of the current collectors 5, 6 by 0.2 mm or more. I cut it.

Next, two thin batteries 11 shown in FIG. 4 are laminated as shown in FIG. 5, and the portion 1 of the frame body 10 protruding by the die 12 is stacked.
0a was heat-pressed under pressure to produce a laminated battery as shown in FIG. The mold 12 has a recessed central portion, and a member 12a, such as a silicon-based sponge, having elasticity and little heat conduction is disposed in the recessed portion so as to press the central portion of the thin battery. It has become.

(Embodiment 2) FIG. 6 is a cross-sectional view of a thin battery which is in the process of assembly showing another embodiment, and the same reference numerals as those in Embodiment 1 indicate the same names. In FIG. 6, the positive electrode active material 7 has a thickness of about 0.135 mm, a shape of about 19.2 mm square, and is arranged on the positive electrode current collector 5 of about 22 mm square (lower side in the figure). It should be noted that the positive electrode current collector 5 is subjected to a chrome treatment to increase the degree of adhesion to the peripheral region width of about 1 mm, and the outer surface is nickel-plated to reduce the contact resistance when thin batteries are stacked. . Negative electrode active material 8
(Lithium foil) has a thickness of about 0.028 mm and a thickness of about 19.2.
It has a square shape of mm mm and is arranged on the negative electrode current collector 6 whose inner and outer surfaces are plated with nickel. The thickness of the anode active material 8 is about 0.040 mm and about 19.6.
A solid electrolyte 9 of mm mm is printed and cured by electron beam irradiation. The heat-adhesive resin frame 10 has a thickness of about 0.30 mm, an outer dimension of about 22 mm, and an inner dimension of about 20 mm, and has a square shape between the positive electrode current collector 5 and the negative electrode current collector 6. It is arranged. Then, the positive electrode active material 7, the negative electrode active material 8, and the electrolyte 9 are arranged inside the frame 10.
Next, the thin battery shown in FIG. 6 is placed under vacuum, and the frame body 10 is heated and pressed from above and below to set the frame body 10 to a width of the positive electrode current collector 5 and the negative electrode current collector 6 of about 1
In addition to adhering to the peripheral area of mm, the frame body 10 was further extended outward so that the outer dimension was about 23 mm, and the frame body 10 was protruded from the end of the current collector by about 0.5 mm. At this time, the thickness of the thin battery was about 0.24 mm including the thickness of each current collector of 0.02 mm.

Two thin batteries are laminated, a conductive material (for example, silver paste, solder paste, carbon resin, graphite resin, etc.) is interposed between the facing current collector surfaces, and heat pressing is performed. By doing so, the protruding frame body 10 was heat-welded, and two thin batteries were integrated into one as shown in FIG. 8 to produce a laminated battery having a thickness of about 0.5 mm. Next, this laminated battery was externally short-circuited for initial discharge and the battery voltage was measured without load, and it was about 6.0 V to about 5.9 V. This voltage value matches the upper limit of the IC element operating voltage, and I
It can be easily applied to equipment using C elements.

[0012]

As described above, the laminated battery of the present invention has the following effects. (1) According to claim 1, since it has substantially the same width dimension as the thin battery and the thickness can be made the same as the stacked thickness of the thin batteries, it can be sufficiently mounted on an IC card or an ID card. A laminated battery can be provided. (2) According to claim 1, since there is no protruding terminal portion,
An internal short circuit can be prevented, and a laminated battery having an excellent appearance can be provided. (3) According to the first aspect, since the current collector is exposed without the covering portion, the heat dissipation performance is excellent, the deterioration of the battery material due to the heat effect when laminated together with the device is small, and the volume energy is high. A laminated battery with improved density can be provided. (4) According to the second aspect, it is possible to prevent heat damage to the battery element at the time of manufacturing, which facilitates the manufacturing work. (5) According to claim 3, the current collector and the frame can be easily aligned with each other, and a short circuit can be prevented. Further, the thin batteries can be firmly integrated with each other.

[Brief description of drawings]

FIG. 1 is a perspective view of an essential part showing a strip-shaped positive electrode current collector or negative electrode current collector according to the present invention.

FIG. 2 is a perspective view of essential parts showing a band-shaped heat-adhesive resin frame body according to the present invention.

FIG. 3 is a cross-sectional view of an essential part showing a thin battery arranged in a strip according to the present invention.

FIG. 4 is a perspective view showing a thin battery according to the first embodiment of the present invention.

FIG. 5 is an explanatory view showing the manufacturing method according to the first embodiment of the present invention.

FIG. 6 is a cross-sectional view showing a thin battery being assembled according to a second embodiment of the present invention.

7 is a cross-sectional view showing the thin battery after assembly in FIG.

FIG. 8 is a cross-sectional view showing a laminated battery of the present invention.

FIG. 9 is a perspective view showing a conventional thin battery.

10 is a cross-sectional view taken along the line A-A ′ of FIG.

11 is a perspective view showing a conventional laminated battery in which the batteries of FIG. 9 are laminated.

[Explanation of symbols]

 5 Positive Electrode Current Collector 6 Negative Current Collector 7 Positive Electrode Active Material 8 Negative Electrode Active Material 9 Solid Electrolyte 10 Thermal Adhesive Resin Frame 10a Overhanging Part of Frame

Claims (3)

[Claims] 1. A positive electrode current collector (5) also serving as an outer package and a negative electrode current collector (6) are opposed to each other, and a positive electrode active material (7), a solid electrolyte (9) and a negative electrode active material (8) are placed therebetween. As well as
The peripheral region of the current collectors (5, 6) is connected to the heat-adhesive resin frame (1
0) are adhered to each other, and the frame (10) is provided outside the peripheral area.
A plurality of thin type batteries protruding from the above are stacked and the frame body (1
A laminated battery characterized in that the protruding portions (10a) of (0) are bonded and integrated with each other. 2. The laminated battery according to claim 1, wherein the size of the portion (10a) protruding from the current collectors (5, 6) is 0.2 mm or more. 3. A heat-adhesive resin frame (10) having the same outer dimensions as the current collectors (5, 6) is pressure-bonded to the current collectors (5, 6), and the frame ( 10) is made to protrude to the outside of the current collectors (5, 6) to produce a thin battery, and then a plurality of the thin batteries are stacked to form the frame (1
The method for manufacturing a laminated battery according to claim 1, wherein the protruding portions (10a) of (0) are heat-welded and integrated with each other.