JPH0860102A - Composition for polishing floor - Google Patents
Composition for polishing floorInfo
- Publication number
- JPH0860102A JPH0860102A JP6233965A JP23396594A JPH0860102A JP H0860102 A JPH0860102 A JP H0860102A JP 6233965 A JP6233965 A JP 6233965A JP 23396594 A JP23396594 A JP 23396594A JP H0860102 A JPH0860102 A JP H0860102A
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- parts
- composition
- floor
- floor polish
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は速硬性に優れたフロアー
ポリッシュ用組成物に関する。詳しくは、木質系床材、
合成樹脂からなる化学床材、コンクリートや大理石等の
石床などの床面に好適であり、速硬性に優れたフロアー
ポリッシュ用組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a composition for floor polish excellent in rapid hardening property. For more details, wooden floor materials,
The present invention relates to a composition for a floor polish, which is suitable for a floor surface such as a chemical flooring material made of a synthetic resin, a stone flooring such as concrete or marble, and has an excellent rapid hardening property.
【０００２】[0002]
【従来の技術】木質系床材、合成樹脂からなる化学床
材、コンクリートや大理石等の石床などの床面には、床
材の美観を保つともに、床面を保護することを目的とし
てフロアーポリッシュ剤が用いられている。フロアポリ
ッシュ剤には、溶剤を使用する油性タイプのものから、
水性または乳化状態のものが一般的である。例えば、特
公昭４７−１４０１９号公報、特公昭４７−１５５９７
号公報には、水性分散状態にあるエチレン性不飽和化合
物の重合体に、多価金属化合物を使用したフロアーポリ
ッシュ用組成物が開示されている。このものは、床に塗
布、乾燥して得られた皮膜は、耐久性、走行性などに優
れた特性を示しているが、塗布後、走行可能な状態にな
る迄には、一般に数時間以上を要し、この間、床の使用
が制限される等の問題があった。このため塗布後の速硬
性を改良する目的で、各種の検討がなされてきた。例え
ば、重合体のガラス転移温度を高くすることにより、速
硬性を向上する試みがあるが、ガラス転移温度の上昇と
ともに造膜性が悪くなる。また、皮膜形成剤の使用量を
減少させ、それにより相対的に乾燥性を向上させる試み
もあるが、この方法も造膜性、リコート性（塗り重ね
性）等を悪くする。さらに多価金属化合物の使用量を増
加させる試みも、乾燥性には殆ど効果がないことが判明
している。以上のように、フロアーポリッシュ剤とし
て、速硬性に優れたフロアーポリッシュ用組成物は皆無
の状態である。2. Description of the Related Art Floors such as wooden floors, chemical floors made of synthetic resin, and stone floors such as concrete and marble are intended to protect the floor while maintaining the aesthetics of the flooring. A polishing agent is used. Floor polishes include oil-based types that use solvents,
It is generally in an aqueous or emulsified state. For example, JP-B-47-14019 and JP-B-47-15597.
The publication discloses a composition for floor polish using a polyvalent metal compound in a polymer of an ethylenically unsaturated compound in an aqueous dispersion state. The coating obtained by coating and drying on the floor has excellent durability and running properties, but it generally takes several hours or more before it can be run after coating. However, there was a problem that the use of the floor was restricted during this period. Therefore, various studies have been made for the purpose of improving the quick-hardening property after coating. For example, there has been an attempt to improve the rapid hardening property by increasing the glass transition temperature of the polymer, but the film forming property deteriorates as the glass transition temperature rises. There are also attempts to reduce the amount of the film forming agent used, thereby relatively improving the drying property, but this method also deteriorates the film forming property, recoating property (coating property) and the like. Further, it has been found that an attempt to increase the amount of the polyvalent metal compound used has almost no effect on the drying property. As described above, as a floor polishing agent, there is no floor polishing composition excellent in quick-hardening property.
【０００３】[0003]
【発明が解決しようとする課題】本発明は、上記課題を
解決するものであり、フロアポリッシュ剤として、塗布
性、光沢、耐久性などの諸性能に優れ、塗布、乾燥後、
短時間で十分な皮膜硬度が得られる速硬性に優れたフロ
アポリッシュ用組成物を提供することを目的とする。DISCLOSURE OF THE INVENTION The present invention is to solve the above-mentioned problems, and as a floor polish agent, it is excellent in various properties such as coatability, gloss and durability, and after coating and drying,
It is an object of the present invention to provide a composition for floor polish, which is capable of obtaining sufficient film hardness in a short time and is excellent in rapid hardening.
【０００４】[0004]
【課題を解決するための手段】上記背景のもと、本発明
者らは鋭意研究を重ねた結果、予想外のことに、ガラス
転移温度を低く、酸価を特定した、エチレン性不飽和化
合物の重合体に、特定量の多価金属化合物を用いること
により、速硬性に優れたフロアーポリッシュ用組成物が
得られることを見いだし、本発明を完成した。すなわ
ち、本発明は、水性分散状態にあるエチレン性不飽和化
合物の重合体であって、該重合体のガラス転移温度が１
０℃〜４０℃であり、且つ酸価が１００〜１７０である
重合体に、多価金属化合物を該重合体の−ＣＯＯＨ１当
量あたり０．３〜０．５当量を含有させることを特徴と
するフロアーポリッシュ用組成物である。Based on the above background, the present inventors have made earnest studies, and as a result, unexpectedly, an ethylenically unsaturated compound having a low glass transition temperature and a specified acid value was identified. It was found that by using a specific amount of a polyvalent metal compound in the polymer, a composition for floor polish excellent in rapid hardening can be obtained, and the present invention was completed. That is, the present invention is a polymer of an ethylenically unsaturated compound in an aqueous dispersion state, wherein the glass transition temperature of the polymer is 1 or less.
A polymer having a temperature of 0 ° C. to 40 ° C. and an acid value of 100 to 170 contains a polyvalent metal compound in an amount of 0.3 to 0.5 equivalent per 1-COOH equivalent of the polymer. It is a composition for floor polish.
【０００５】本発明において使用される、エチレン性不
飽和化合物の重合体のガラス転移温度は１℃〜４０℃で
ある必要があり、ガラス転移点が１０℃未満では、ベタ
付きが生じ、耐久性と速硬性の良い皮膜を得ることがで
きず、また、４０℃を超えると造膜性と速硬性の良い皮
膜が得ることができず、本発明の効果を得ることができ
ない。尚、本発明にて用いるガラス転移温度（Ｔｇ）
は、Ｆｏｘの式（１）で求めたものである。 １／Ｔｇ＝Ｗ１／Ｔｇ１＋Ｗ２／Ｔｇ２＋Ｗ３／Ｔｇ３＋・・・ −（１） ここで、Ｗ１、Ｗ２、Ｗ３、・・・は重合体中の単量体
１、２、３、・・・の重量分率を示し、Ｔｇ１、Ｔ
ｇ２、Ｔｇ３、・・・は同じく単量体１、２、３、・・
・のホモポリマー（単独重合体）のガラス転移温度を示
したものである。ホモポリマー（単独重合体）のＴｇと
しては、ポリマーハンドブックに記載されている文献
値、例えば、ポリメタクリル酸メチル１０５℃、ポリア
クリル酸ブチル−５４℃、ポリアクリル酸２−エチルヘ
キシル−５０℃、ポリメタクリル酸２２８℃、ポリスチ
レン１００℃等が用いられる。また、重合体の酸価（重
合体１ｇ中のカルボン酸を中和するのに必要なＫＯＨの
ｍｇ数）は、１００〜１７０である必要があり、１００
未満では速硬性、耐久性の良い皮膜を得ることができ
ず、１７０を超えると、重合体の粘度が上昇し作業性が
悪くなる。The glass transition temperature of the polymer of the ethylenically unsaturated compound used in the present invention must be 1 to 40 ° C. If the glass transition point is less than 10 ° C., stickiness occurs and durability is high. When the temperature exceeds 40 ° C., a film having good film-forming property and quick hardening cannot be obtained, and the effect of the present invention cannot be obtained. The glass transition temperature (Tg) used in the present invention
Is obtained by the Fox equation (1). 1 / Tg = W 1 / Tg 1 + W 2 / Tg 2 + W 3 / Tg 3 + ··· - (1) wherein, W 1, W 2, W 3, ··· of the monomer in the polymer 1,2,3, represents the weight fraction of · · ·, Tg 1, T
g 2 , Tg 3 , ... Are the same as monomers 1, 2, 3, ...
It shows the glass transition temperature of the homopolymer (homopolymer) of. As Tg of a homopolymer (homopolymer), literature values described in a polymer handbook, for example, polymethyl methacrylate 105 ° C., polybutyl acrylate-54 ° C., polyethyl acrylate 2-ethylhexyl-50 ° C., poly Methacrylic acid 228 ° C., polystyrene 100 ° C., etc. are used. Further, the acid value of the polymer (the number of mg of KOH necessary to neutralize the carboxylic acid in 1 g of the polymer) needs to be 100 to 170, and 100
When it is less than 170%, a film having fast curing property and good durability cannot be obtained, and when it exceeds 170, the viscosity of the polymer increases and the workability deteriorates.
【０００６】本発明に用いられるエチレン性不飽和化合
物の重合体を製造するには、エチレン性不飽和単量体と
して、（メタ）アクリル酸メチル、（メタ）アクリル酸
エチル、（メタ）アクリル酸プロピル、（メタ）アクリ
ル酸ブチル、（メタ）アクリル酸２−エチルヘキシル、
（メタ）アクリル酸ラウリルなどの（メタ）アクリル酸
エステル類、スチレン、α−メチルスチレン、（メタ）
アクリロニトリル、及び、（メタ）アクリル酸、イタコ
ン酸等のエチレン性不飽和カルボン酸等が使用できる。
この中より任意の不飽和化合物を選択することにより、
一般に公知の乳化重合法、懸濁重合法等により、ガラス
転移温度１０〜４０℃、酸価１００〜１７０を有する重
合体を得ることができる。To produce a polymer of an ethylenically unsaturated compound used in the present invention, methyl (meth) acrylate, ethyl (meth) acrylate, (meth) acrylic acid are used as ethylenically unsaturated monomers. Propyl, butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate,
(Meth) acrylic acid esters such as lauryl (meth) acrylate, styrene, α-methylstyrene, (meth)
Acrylonitrile and ethylenically unsaturated carboxylic acids such as (meth) acrylic acid and itaconic acid can be used.
By selecting any unsaturated compound from among these,
A polymer having a glass transition temperature of 10 to 40 ° C. and an acid value of 100 to 170 can be obtained by a generally known emulsion polymerization method, suspension polymerization method, or the like.
【０００７】本発明に含有される多価金属化合物として
は、マグネシウム、アルミニウム、カルシウム、亜鉛、
ジルコニウムなどの多価金属の、酸化物、水酸化物、塩
基性塩、酸性塩、中性塩またはそれらの錯体、キレート
物のいずれかを用いることができる。多価金属化合物の
含有量は、重合体中の−ＣＯＯＨ１当量に対して０．３
〜０．５当量である。０．３未満では得られるフロアー
ポリッシュ用組成物は、耐久性が得られず、０．５を超
えると造膜性が悪くなる。以上、本発明のエチレン性不
飽和化合物の重合体に特定量の多価金属化合物を用いた
フロアーポリッシュ用組成物に、公知の添加物、例え
ば、可塑剤としてジブチルフタレート等のフタル酸エス
テル類、トリブトキシエチルホスフェート等のリン酸エ
ステル類、ジメチルアジピン酸エステル等のアジピン酸
エステル類等を、皮膜形成剤として、アルコール類、グ
リコールエーテル類等を、レベリング剤としてアルカリ
可溶性樹脂、滑り調整剤として、植物系、動物系、鉱物
系、石油系ワックス等の天然ワックスまたは、合成炭化
水素、ポリエチレンワックス、ポリプロピレンワック
ス、変性ワックス等の合成ワックスを、濡れ性向上剤と
してフッ素系界面活性剤等を、その他乳化剤、防腐剤、
消泡剤等を用いてフロアーポリッシュ剤として使用する
ことができる。尚、本発明の、モノエチレン性不飽和化
合物の重合体は、フロアーポリッシュ剤中に、６〜２５
重量％の範囲で用いると良い。添加物を含めた不揮発分
は、１０〜３５重量％が好ましい。またフロアーポリッ
シュ剤を製造する好ましい方法は、水に可塑剤、皮膜形
成剤、アルカリ可溶性樹脂、フッ素系界面活性剤を添加
した後、本発明のフロアーポリッシュ用組成物を加え、
さらにワックス類などを、混合することにより製造する
ことができるが、この限りではない。The polyvalent metal compound contained in the present invention includes magnesium, aluminum, calcium, zinc,
Any of oxides, hydroxides, basic salts, acidic salts, neutral salts or their complexes and chelate compounds of polyvalent metals such as zirconium can be used. The content of the polyvalent metal compound is 0.3 with respect to 1 equivalent of -COOH in the polymer.
~ 0.5 equivalent. If it is less than 0.3, the resulting composition for floor polish cannot obtain durability, and if it exceeds 0.5, the film-forming property is deteriorated. As described above, in the composition for floor polish using a specific amount of polyvalent metal compound in the polymer of the ethylenically unsaturated compound of the present invention, known additives, for example, phthalates such as dibutyl phthalate as a plasticizer, Phosphates such as tributoxyethyl phosphate, adipates such as dimethyl adipate, etc. as film forming agents, alcohols, glycol ethers, etc., alkali-soluble resin as a leveling agent, as a slip adjusting agent, Natural wax such as plant-based, animal-based, mineral-based, petroleum-based wax or the like, or synthetic wax such as synthetic hydrocarbon, polyethylene wax, polypropylene wax or modified wax, fluorine-based surfactant or the like as a wettability improver, etc. Emulsifier, preservative,
It can be used as a floor polish agent by using an antifoaming agent or the like. In addition, the polymer of the monoethylenically unsaturated compound of the present invention contains 6 to 25 parts by weight of the floor polish agent.
It is preferable to use it in the range of% by weight. The nonvolatile content including the additives is preferably 10 to 35% by weight. A preferred method for producing a floor polish agent is to add a plasticizer, a film-forming agent, an alkali-soluble resin, and a fluorosurfactant to water, and then add the floor polish composition of the present invention,
Furthermore, it can be produced by mixing waxes and the like, but is not limited thereto.
【０００８】[0008]
【実施例】以下、本発明の実施例及び比較例を挙げて本
発明組成物の効果について例証する。常用の乳化重合法
を用いて、以下に示す組成のエチレン性不飽和化合物の
重合体を重合し、多価金属化合物を添加した後、その固
形分を４０％に調整し、実施例１〜７および、比較例１
〜６のフロアーポリッシュ用組成物を得た。EXAMPLES The effects of the composition of the present invention will be illustrated below with reference to Examples of the present invention and Comparative Examples. Using a conventional emulsion polymerization method, a polymer of an ethylenically unsaturated compound having the composition shown below was polymerized, a polyvalent metal compound was added, and then its solid content was adjusted to 40%. And Comparative Example 1
~ 6 floor polish compositions were obtained.
【０００９】実施例１ アクリル酸ブチル５０部、メタクリル酸メチル１０部、
スチレン２０部、メタクリル酸２０部からなる、Ｔｇ１
４℃、酸価１３０の重合体に、酸化亜鉛を、重合体１０
０部に対して、３．７７部（重合体の−ＣＯＯＨ１当量
あたり０．４当量）を添加してフロアーポリッシュ用組
成物１を得た。Example 1 50 parts of butyl acrylate, 10 parts of methyl methacrylate,
Tg1 consisting of 20 parts of styrene and 20 parts of methacrylic acid
Zinc oxide was added to a polymer having an acid value of 130 at 4 ° C.
3.77 parts (0.4 equivalent per 1-COOH of polymer) was added to 0 part to obtain a composition 1 for floor polish.
【００１０】実施例２、３、４ アクリル酸ブチル４４部、メタクリル酸メチル１６部、
スチレン２０部、メタクリル酸２０部からなる、Ｔｇ２
４℃、酸価１３０の重合体に、酸化亜鉛を、重合体１０
０部に対して、実施例２においては、３．３０部（重合
体の−ＣＯＯＨ１当量あたり０．３５当量）を、実施例
３においては、３．７７部（重合体の−ＣＯＯＨ１当量
あたり０．４当量）を、実施例４においては、４．２４
部（重合体の−ＣＯＯＨ１当量あたり０．４５当量）を
それぞれ添加して、各フロアーポリッシュ用組成物２、
３、４を得た。Examples 2, 3, 4 44 parts of butyl acrylate, 16 parts of methyl methacrylate,
Tg2 consisting of 20 parts of styrene and 20 parts of methacrylic acid
Zinc oxide was added to a polymer having an acid value of 130 at 4 ° C.
In contrast to 0 parts, in Example 2, 3.30 parts (0.35 equivalents per equivalent of -COOH of the polymer) and in Example 3 3.77 parts (0 per equivalent of -COOH of the polymer). .4 equivalent), in Example 4, 4.24
Parts (0.45 equivalents per 1-COOH equivalent of the polymer), respectively, to prepare each composition 2 for floor polishing,
3 and 4 were obtained.
【００１１】実施例５ アクリル酸ブチル３８部、メタクリル酸メチル２２部、
スチレン２０部、メタクリル酸２０部からなる、Ｔｇ３
４℃、酸価１３０の重合体に、酸化亜鉛を、重合体１０
０部に対して、３．７７部（重合体の−ＣＯＯＨ１当量
あたり０．４当量）を添加してフロアーポリッシュ用組
成物５を得た。Example 5 38 parts of butyl acrylate, 22 parts of methyl methacrylate,
Tg3 consisting of 20 parts of styrene and 20 parts of methacrylic acid
Zinc oxide was added to a polymer having an acid value of 130 at 4 ° C.
3.77 parts (0.4 equivalents per equivalent of -COOH of the polymer) was added to 0 parts to obtain a composition 5 for floor polish.
【００１２】実施例６ アクリル酸ブチル４３部、メタクリル酸メチル２０部、
スチレン２０部、メタクリル酸１７部からなる、Ｔｇ２
４℃、酸価１１１の重合体に、酸化亜鉛を、重合体１０
０部に対して、３．２２部（重合体の−ＣＯＯＨ１当量
あたり０．４当量）を添加してフロアーポリッシュ用組
成物６を得た。Example 6 43 parts of butyl acrylate, 20 parts of methyl methacrylate,
Tg2 consisting of 20 parts of styrene and 17 parts of methacrylic acid
Zinc oxide was added to a polymer having an acid value of 111 at 4 ° C.
3.22 parts (0.4 equivalent per 1-COOH of a polymer) was added with respect to 0 part, and the composition 6 for floor polishes was obtained.
【００１３】実施例７ アクリル酸２−エチルヘキシル４７部、メタクリル酸メ
チル８部、スチレン２０部、メタクリル酸２５部からな
る、Ｔｇ２５℃、酸価１６３の重合体に、酸化亜鉛を、
重合体１００部に対して、４．７３部（重合体の−ＣＯ
ＯＨ１当量あたり０．４当量）を添加してフロアーポリ
ッシュ用組成物７を得た。Example 7 Zinc oxide was added to a polymer composed of 47 parts of 2-ethylhexyl acrylate, 8 parts of methyl methacrylate, 20 parts of styrene and 25 parts of methacrylic acid and having a Tg of 25 ° C. and an acid value of 163.
4.73 parts per 100 parts of polymer (-CO of the polymer
0.4 equivalents per 1 equivalent of OH) was added to obtain a composition 7 for floor polish.
【００１４】比較例１ アクリル酸ブチル５６部、メタクリル酸メチル４部、ス
チレン２０部、メタクリル酸２０部からなる、Ｔｇ５
℃、酸価１３０の重合体に、酸化亜鉛を、重合体１００
部に対して、３．７７部（重合体の−ＣＯＯＨ１当量あ
たり０．４当量）を添加してたフロアーポリッシュ用組
成物（１）を得た。Comparative Example 1 Tg5 consisting of 56 parts of butyl acrylate, 4 parts of methyl methacrylate, 20 parts of styrene and 20 parts of methacrylic acid.
Zinc oxide is added to a polymer having an acid value of 130 at a temperature of 100.
3.77 parts (0.4 equivalents per 1 equivalent of -COOH of the polymer) was added to 3 parts to obtain a composition (1) for floor polish.
【００１５】比較例２ アクリル酸ブチル３２部、メタクリル酸メチル２８部、
スチレン２０部、メタクリル酸２０部からなる、Ｔｇ４
６℃、酸価１３０の重合体に、酸化亜鉛を、重合体１０
０部に対して、３．７７部（重合体の−ＣＯＯＨ１当量
あたり０．４当量）を添加してフロアーポリッシュ用組
成物（２）を得た。Comparative Example 2 32 parts of butyl acrylate, 28 parts of methyl methacrylate,
Tg4 consisting of 20 parts of styrene and 20 parts of methacrylic acid
Zinc oxide was added to a polymer having an acid value of 130 at 6 ° C.
3.77 parts (0.4 equivalent per 1-COOH of polymer) was added to 0 part to obtain a composition (2) for floor polish.
【００１６】比較例３、４ アクリル酸ブチル４４部、メタクリル酸メチル１６部、
スチレン２０部、メタクリル酸２０部からなる、Ｔｇ２
４℃、酸価１３０の重合体に、酸化亜鉛を、重合体１０
０部に対して、比較例３においては、１．８９部（重合
体の−ＣＯＯＨ１当量あたり０．２当量）を、比較例４
においては、５．６６部（重合体の−ＣＯＯＨ１当量あ
たり０．６当量）をそれぞれ添加して、各フロアーポリ
ッシュ用組成物（３）、（４）を得た。Comparative Examples 3 and 4 44 parts of butyl acrylate, 16 parts of methyl methacrylate,
Tg2 consisting of 20 parts of styrene and 20 parts of methacrylic acid
Zinc oxide was added to a polymer having an acid value of 130 at 4 ° C.
In Comparative Example 3, 1.89 parts (0.2 equivalents per 1 equivalent of —COOH of the polymer) was used in Comparative Example 4 with respect to 0 parts.
In the above, 5.66 parts (0.6 equivalents per equivalent of -COOH of the polymer) were added, to obtain compositions (3) and (4) for floor polishing.
【００１７】比較例５ アクリル酸ブチル４２部、メタクリル酸メチル２４部、
スチレン２０部、メタクリル酸１４部からなる、Ｔｇ２
４℃、酸価９１の重合体に、酸化亜鉛を、重合体１００
部に対して、２．６４部（重合体の−ＣＯＯＨ１当量あ
たり０．４当量）を添加してフロアーポリッシュ用組成
物（５）を得た。Comparative Example 5 42 parts of butyl acrylate, 24 parts of methyl methacrylate,
Tg2 consisting of 20 parts of styrene and 14 parts of methacrylic acid
Zinc oxide was added to a polymer having an acid value of 91 at 4 ° C.
2.64 parts (0.4 equivalents per equivalent of -COOH of the polymer) was added to the parts to obtain a composition (5) for floor polish.
【００１８】比較例６ アクリル酸ブチル４６部、メタクリル酸メチル６部、ス
チレン２０部、メタクリル酸２８部からなる、Ｔｇ２５
℃、酸価１８３の重合体に、酸化亜鉛を、重合体１００
部に対して、５．３１部（重合体の−ＣＯＯＨ１当量あ
たり０．４当量）を添加してフロアーポリッシュ用組成
物（６）を得た。Comparative Example 6 Tg25 consisting of 46 parts of butyl acrylate, 6 parts of methyl methacrylate, 20 parts of styrene and 28 parts of methacrylic acid.
Zinc oxide was added to a polymer having an acid value of 183 and a polymer 100
5.31 parts (0.4 equivalents per equivalent of -COOH of the polymer) was added to parts to obtain a composition (6) for floor polish.
【００１９】実施例１〜７、及び比較例１〜６で得られ
た各フロアーポリッシュ用組成物を使用し、下記の処方
によりフロアーポリッシュ剤を製造し性能に供した。 Using the floor polish compositions obtained in Examples 1 to 7 and Comparative Examples 1 to 6, a floor polish agent was produced according to the following formulation and used for performance.
【００２０】得られた各フロアーポリッシュ剤につい
て、粘度、光沢度、耐ヒールマーク性、造膜性、硬化ま
での時間（乾燥時間）を測定し、結果を表１に示す。各
測定方法は、以下の通りである。 １．粘度 ＪＩＳ Ｋ−３９２０（フロアーポリッシュ
試験方法）に準拠、単一円筒粘度計を用いて測定した。 ２．光沢度 ＪＩＳ Ｋ−３９２０に準拠、コンポジシ
ョンビニルタイル（東リ製、ニューマチコＶ Ｎｏ．３
３）を用いて試料を３回塗布後測定した。 ３．耐ヒールマーク性 ＪＩＳ Ｋ−３９２０に準拠、
ホモジニアスビニルタイル（東リ製、マチコＳプレーン
Ｎｏ．５６２６）を用い測定した。（１０段階評価） ４．造膜性 ５℃の雰囲気下にて、ホモジニアスビニル
タイル（東リ製、マチコＳプレーンＮｏ．５６０８）に
試料を塗布し、皮膜のクラックの有無を観察した。 ５．硬化までの時間 ２０℃、６０％の雰囲気下にて、
ホモジニアスビニルタイル（東リ製、マチコＳプレーン
Ｎｏ．５６２６）に試料を１５ｇ／ｍ２で塗布、乾燥
し、カーボンブラックを押しつけた。塗布後カーボンブ
ラックが皮膜に付着しなくなるまでの時間を測定した。With respect to each of the obtained floor polish agents, the viscosity, glossiness, heel mark resistance, film-forming property, and time until curing (drying time) were measured, and the results are shown in Table 1. Each measuring method is as follows. 1. Viscosity Based on JIS K-3920 (Floor Polish Test Method), viscosity was measured using a single cylinder viscometer. 2. Glossiness Compliant with JIS K-3920, Composition vinyl tile (Tori, New Machico V No. 3
The sample was applied 3 times using 3) and then measured. 3. Heel mark resistance conforming to JIS K-3920,
It measured using the homogeneous vinyl tile (Tori make, Machiko S plane No. 5626). (10-step evaluation) 4. Film Formability In a 5 ° C. atmosphere, a sample was applied to a homogeneous vinyl tile (manufactured by Tori, Machico S Plane No. 5608), and the presence or absence of cracks in the film was observed. 5. Time to cure 20 ° C, 60% atmosphere,
A sample was applied at 15 g / m 2 to a homogeneous vinyl tile (Machico S Plane No. 5626, manufactured by Tori), dried and pressed against carbon black. After the application, the time until the carbon black stopped adhering to the film was measured.
【００２１】[0021]
【表１】 [Table 1]
【００２２】[0022]
【表２】 [Table 2]
【００２３】[0023]
【発明の効果】表１の試験結果より、比較例（６）は皮
膜が硬化するまでの時間は短いが、粘度が高くフロアー
ポリッシュ剤としては不適当である。しかし、本発明の
フロアーポリッシュ用組成物は、塗布性、光沢、耐久性
などの諸性能に優れ、且つ、塗布、乾燥後、短時間で十
分な皮膜硬度が得られる速硬性に優れたフロアーポリッ
シュ剤を得ることができ、フロアーポリッシュ剤塗布後
の、床の使用制限を大幅に削減することができる。EFFECTS OF THE INVENTION From the test results in Table 1, Comparative Example (6) has a short time until the film is cured, but has a high viscosity and is not suitable as a floor polish agent. However, the floor polish composition of the present invention is excellent in various properties such as coatability, gloss, and durability, and is a floor polish excellent in quick-hardening property in which sufficient film hardness can be obtained in a short time after coating and drying. The agent can be obtained, and the limitation on the use of the floor after applying the floor polishing agent can be greatly reduced.
Claims (1)
合物の重合体であって、該重合体のガラス転移温度が１
０℃〜４０℃であり、且つ酸価が１００〜１７０である
重合体に、多価金属化合物を該重合体中の−ＣＯＯＨ１
当量あたり０．３〜０．５当量を含有させることを特徴
とするフロアーポリッシュ用組成物。1. A polymer of an ethylenically unsaturated compound in an aqueous dispersion state, wherein the polymer has a glass transition temperature of 1.
A polyvalent metal compound is added to a polymer having a temperature of 0 ° C to 40 ° C and an acid value of 100 to 170 in a -COOH1 content of the polymer.
A composition for floor polish, which comprises 0.3 to 0.5 equivalent per equivalent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23396594A JP3942044B2 (en) | 1994-08-23 | 1994-08-23 | Floor polish composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23396594A JP3942044B2 (en) | 1994-08-23 | 1994-08-23 | Floor polish composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0860102A true JPH0860102A (en) | 1996-03-05 |
| JP3942044B2 JP3942044B2 (en) | 2007-07-11 |
Family
ID=16963416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23396594A Expired - Fee Related JP3942044B2 (en) | 1994-08-23 | 1994-08-23 | Floor polish composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3942044B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001002980A (en) * | 1999-04-22 | 2001-01-09 | Jsr Corp | Aqueous coating composition |
| WO2003002678A1 (en) * | 2001-06-29 | 2003-01-09 | Johnsondiversey, Inc. | Floor polish composition |
| JP2003327774A (en) * | 2002-05-10 | 2003-11-19 | Toagosei Co Ltd | Aqueous polymer composition |
| JP2005023149A (en) * | 2003-06-30 | 2005-01-27 | Johnson Professional Co Ltd | Gloss restoration agent composition for floor, floor structure using the same, and floor surface maintenance and administration method |
| JP2009287037A (en) * | 1997-09-08 | 2009-12-10 | Rohm & Haas Co | Floor polish vehicle composition |
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|---|---|---|---|---|
| JPS52124487A (en) * | 1976-04-13 | 1977-10-19 | Rohm & Haas | Oligomer aqueous finishing agents |
| JPS5454148A (en) * | 1977-10-07 | 1979-04-28 | Morizou Nakamura | Aqueous coating composition |
| JPS57117552A (en) * | 1981-01-13 | 1982-07-22 | Nippon Shokubai Kagaku Kogyo Co Ltd | Floor gloss composition |
| JPS62112673A (en) * | 1985-11-11 | 1987-05-23 | Japan Synthetic Rubber Co Ltd | Aqueous lustrous composition |
| JPS63286471A (en) * | 1987-05-19 | 1988-11-24 | Japan Synthetic Rubber Co Ltd | Luster composition for floor |
| JPH02219863A (en) * | 1988-12-16 | 1990-09-03 | Rohm & Haas Co | Crosslinking of acid-containing polymer with transition metal |
| JPH04224810A (en) * | 1990-12-26 | 1992-08-14 | Kao Corp | Emulsion copolymer for floor polishing composition |
| JPH055083A (en) * | 1991-02-06 | 1993-01-14 | Yuho Chem Kk | Coating material composition |
| JPH06145588A (en) * | 1992-11-13 | 1994-05-24 | Japan Synthetic Rubber Co Ltd | Water-base coating composition |
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1994
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Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52124487A (en) * | 1976-04-13 | 1977-10-19 | Rohm & Haas | Oligomer aqueous finishing agents |
| JPS5454148A (en) * | 1977-10-07 | 1979-04-28 | Morizou Nakamura | Aqueous coating composition |
| JPS57117552A (en) * | 1981-01-13 | 1982-07-22 | Nippon Shokubai Kagaku Kogyo Co Ltd | Floor gloss composition |
| JPS62112673A (en) * | 1985-11-11 | 1987-05-23 | Japan Synthetic Rubber Co Ltd | Aqueous lustrous composition |
| JPS63286471A (en) * | 1987-05-19 | 1988-11-24 | Japan Synthetic Rubber Co Ltd | Luster composition for floor |
| JPH02219863A (en) * | 1988-12-16 | 1990-09-03 | Rohm & Haas Co | Crosslinking of acid-containing polymer with transition metal |
| JPH04224810A (en) * | 1990-12-26 | 1992-08-14 | Kao Corp | Emulsion copolymer for floor polishing composition |
| JPH055083A (en) * | 1991-02-06 | 1993-01-14 | Yuho Chem Kk | Coating material composition |
| JPH06145588A (en) * | 1992-11-13 | 1994-05-24 | Japan Synthetic Rubber Co Ltd | Water-base coating composition |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009287037A (en) * | 1997-09-08 | 2009-12-10 | Rohm & Haas Co | Floor polish vehicle composition |
| JP2001002980A (en) * | 1999-04-22 | 2001-01-09 | Jsr Corp | Aqueous coating composition |
| JP4644905B2 (en) * | 1999-04-22 | 2011-03-09 | Ｊｓｒ株式会社 | Aqueous coating composition |
| WO2003002678A1 (en) * | 2001-06-29 | 2003-01-09 | Johnsondiversey, Inc. | Floor polish composition |
| JP2003327774A (en) * | 2002-05-10 | 2003-11-19 | Toagosei Co Ltd | Aqueous polymer composition |
| JP2005023149A (en) * | 2003-06-30 | 2005-01-27 | Johnson Professional Co Ltd | Gloss restoration agent composition for floor, floor structure using the same, and floor surface maintenance and administration method |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3942044B2 (en) | 2007-07-11 |
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