JP3515791B2 - Floor polish composition - Google Patents
Floor polish compositionInfo
- Publication number
- JP3515791B2 JP3515791B2 JP27335292A JP27335292A JP3515791B2 JP 3515791 B2 JP3515791 B2 JP 3515791B2 JP 27335292 A JP27335292 A JP 27335292A JP 27335292 A JP27335292 A JP 27335292A JP 3515791 B2 JP3515791 B2 JP 3515791B2
- Authority
- JP
- Japan
- Prior art keywords
- floor polish
- polish composition
- floor
- resin
- urethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明はフロアーポリッシュ組成
物に関する。詳しくは、木質系床材、合成樹脂からなる
化学床材、コンクリートや大理石等の石床などの床面に
塗布、乾燥して皮膜を形成し、床材の美観を保つととも
に、床面を保護するフロアーポリッシュ組成物(床用艶
出し組成物)に関する。FIELD OF THE INVENTION This invention relates to floor polish compositions. Specifically, it is applied to the floor surface of wooden floor materials, chemical floor materials made of synthetic resin, stone floors such as concrete and marble, and dried to form a film to maintain the aesthetics of the floor material and protect the floor surface. The present invention relates to a floor polish composition (a floor polish composition).
【0002】[0002]
【従来の技術】フロアーポリッシュ組成物としては、水
性、乳化性及び油性の3種があるが、近年、種々の新し
いタイプの床材が開発されるにともない、油タイプでは
溶剤を使用するので、床材の種類によっては使用できな
い場合が多い。従って、フロアーポリッシュの主流は水
性または乳化性のものであり、不揮発性成分として、合
成樹脂などのポリマーもしくはポリマー及びワックス
類、またはポリマーによる塗膜に柔軟性を与え、床材と
の密着をよくするための可塑剤を含む。更に疎水性の床
面にもよく濡れ、均一な皮膜をつくることを助けるレベ
リング剤が配合される。この可塑剤及びレベリング剤と
しては、もっぱらトリブトキシエチルホスフェートが用
いられている。2. Description of the Related Art There are three types of floor polish compositions: aqueous, emulsifying and oily. In recent years, with the development of various new types of flooring materials, a solvent is used in the oil type. It cannot be used depending on the type of floor material. Therefore, the mainstream of floor polish is water-based or emulsifiable, and as a non-volatile component, it imparts flexibility to a polymer such as a synthetic resin or a polymer and wax, or a coating film made of the polymer, and well adheres to a floor material. Including a plasticizer for Furthermore, a leveling agent is added to help the hydrophobic floor surface to wet well and form a uniform film. Tributoxyethyl phosphate is exclusively used as the plasticizer and the leveling agent.
【0003】[0003]
【発明が解決しようとする課題】しかしながら、このト
リブトキシエチルホスフェートはリン成分を含むため、
これをフロアーポリッシュに配合すれば、廃水中へリン
成分が混入するので好ましくない。本発明は、この問題
点を解決するものであり、しかもトリブトキシエチルホ
スフェートに匹敵する可塑剤及びレベリング剤を配合し
たフロアーポリッシュ組成物を提供することを目的とす
る。However, since this tributoxyethyl phosphate contains a phosphorus component,
If this is blended with the floor polish, the phosphorus component is mixed into the waste water, which is not preferable. It is an object of the present invention to solve this problem and to provide a floor polish composition containing a plasticizer and a leveling agent comparable to tributoxyethyl phosphate.
【0004】[0004]
【課題を解決するための手段】本発明者らは、上記の背
景のもと、トリブトキシエチルホスフェートに代る優れ
たフロアーポリッシュ用の可塑剤及びレベリング剤を得
ることを目的として種々検討を重ねた結果、特定の化合
物により上述の目的が達成されることを知見した。Under the above background, the inventors of the present invention have made various studies for the purpose of obtaining an excellent plasticizer and leveling agent for floor polish, which is an alternative to tributoxyethyl phosphate. As a result, it was found that the above object was achieved by the specific compound.
【0005】すなわち、本発明は、特定のポリマーまた
は特定のポリマー及びワックス類からなる艶出し成分
と、アジピン酸エステル類とを含有し、ポリエトシキ化
脂肪族第2級アルコールを含有しないフロアーポリッシ
ュ組成物を提供する。以下、本発明を詳細に説明する
に、ポリマーとしては、特に、スチレン−アクリル共重
合樹脂、アクリル樹脂、ウレタン樹脂及びウレタン−ア
クリル樹脂が用いられ、これらは通常、ポリマーエマル
ジョンとして用いられる。Namely, the present invention comprises a glazing component comprising a specific polymer or specific polymers and waxes, and adipic acid esters, Porietoshiki of
Provided is a floor polish composition that does not contain an aliphatic secondary alcohol . Hereinafter, the present invention will be described in detail, as the polymer, especially a styrene - acrylic copolymer resin, acrylic resin, urethane resin and urethane - acrylic resin is used, they are usually used as a polymer emulsion.
【0006】ワックス類としては、これも従来、フロア
ーポリッシュの皮膜形成、艶出し成分として常用されて
いる植物系、動物系、鉱物系、石油系ワックス等の天然
ワックスまたは合成炭化水素、ポリエチレンワックス、
変性ワックス等の合成ワックスが用いられ、これらも通
常乳化分散したものが用いられる。As the waxes, natural waxes such as plant-based, animal-based, mineral-based, petroleum-based waxes, etc., which have been conventionally used as film forming and polishing components for floor polish, synthetic waxes, polyethylene waxes, etc.
Synthetic waxes such as modified waxes are used, and these are also usually emulsion-dispersed.
【0007】フロアーポリッシュ中のポリマー及びワッ
クス類の使用割合は、フロアーポリッシュの光沢、耐久
性或いは床材の種類等により相違するので一概には言え
ないが、通常ポリマーは固形分として1〜50重量%程
度、またワックス類は固形分として0〜15重量%程度
である。The proportion of the polymer and waxes used in the floor polish cannot be generally stated because it varies depending on the gloss and durability of the floor polish or the type of floor material, but the polymer is usually 1 to 50% by weight as a solid content. %, And waxes have a solid content of about 0 to 15% by weight.
【0008】本発明のフロアーポリッシュ組成物は、可
塑剤及びレベリング剤として、アジピン酸エステル類を
含むことを特徴とする。アジピン酸エステル類として
は、例えば、ジメチルアジピン酸エステル、ジ−2−エ
チルヘキシルアジピン酸エステル、ジイソデシルアジピ
ン酸エステル、ジイソブチルアジピン酸エステル、ジブ
トキシエチルアジピン酸エステル、ジブチルアジピン酸
エステル、ジブチルジグリコールアジピン酸エステル等
が挙げられ、これは通常、0.1〜10重量%、好まし
くは0.5〜5重量%添加される。The floor polish composition of the present invention is characterized by containing adipic acid esters as a plasticizer and a leveling agent. Examples of the adipic acid esters include dimethyl adipate, di-2-ethylhexyl adipate, diisodecyl adipate, diisobutyl adipate, dibutoxyethyl adipate, dibutyl adipate, dibutyl diglycol adipate. Esters and the like can be mentioned, which are usually added in an amount of 0.1 to 10% by weight, preferably 0.5 to 5% by weight.
【0009】また、本発明のフロアーポリッシュ組成物
は、アジピン酸エステル類とともにコロイダルシリカを
含むことにより、耐久性、帯電防止効果が改善される。
コロイダルシリカとしては、水を分散媒とし、無水珪酸
の超微粒子を水中に分散せしめた膠質溶液であり、分散
質をなす珪酸粒子の大きさは1〜100mμ程度であ
る。市販品としては、スノーテックス(日産化学工業株
式会社)、カタロイド−S(触媒化成工業株式会社)等
が知られている。これは通常、固形分として0.1〜1
0重量%、好ましくは0.4〜6重量%が用いられる。Further, the floor polish composition of the present invention contains colloidal silica together with adipic acid esters to improve durability and antistatic effect.
Colloidal silica is a colloidal solution in which ultrafine particles of silicic acid anhydride are dispersed in water with water as a dispersion medium, and the size of the silicic acid particles forming the dispersoid is about 1 to 100 mμ. Known commercially available products include Snowtex (Nissan Chemical Co., Ltd.) and Cataloid-S (Catalyst Chemical Co., Ltd.). This is typically 0.1 to 1 as solids.
0% by weight, preferably 0.4-6% by weight is used.
【0010】本発明のフロアーポリッシュ組成物は、更
に必要に応じ、ポリマー、ワックス類のレベリングを助
けたり、はく離性を向上させるなどの補助剤的に使用さ
れるアルカリ可溶性樹脂、ポリマー及び塗膜の皮膜形成
を常温でも容易に行なわせ、皮膜形成後は揮散して皮膜
に残らない高沸点溶剤からなる皮膜形成助剤、エマルジ
ョンの表面張力を下げて床面への濡れ性をよくするフッ
素系界面活性剤、耐洗剤性及び剥離性を向上させるため
の多価金属化合物、その他乳化剤、防腐剤、消泡剤等を
適量含有することもできる。The floor polish composition of the present invention further comprises, if necessary, an alkali-soluble resin, a polymer and a coating film used as an auxiliary agent for assisting the leveling of polymers and waxes and improving the peelability. Fluorine-based interface that facilitates film formation even at room temperature, a film-forming aid consisting of a high-boiling solvent that volatilizes and does not remain after the film is formed, and lowers the surface tension of the emulsion to improve wettability to the floor surface. An appropriate amount of an activator, a polyvalent metal compound for improving detergent resistance and releasability, other emulsifiers, preservatives, antifoaming agents and the like may be contained.
【0011】本発明のフロアーポリッシュ組成物は、上
述の成分と水とを固形分が10〜45重量%程度となる
ように配合し、通常のミキサーで均一に混合することに
より製造される。次に実施例に従って、本発明を更に具
体的に説明するが、本発明は以下の実施例に限定される
ものではない。The floor polish composition of the present invention is produced by blending the above-mentioned components and water so that the solid content is about 10 to 45% by weight, and uniformly mixing with a usual mixer. Next, the present invention will be described more specifically according to examples, but the present invention is not limited to the following examples.
【0012】[0012]
【実施例1】表1に示す成分を通常のミキサーを用いて
均一に撹伴混合することにより、本発明のフロアーポリ
ッシュ組成物を得た。Example 1 The floor polish composition of the present invention was obtained by uniformly agitating and mixing the components shown in Table 1 with an ordinary mixer.
【0013】[0013]
【表1】 [Table 1]
【0014】得られた各組成物について、JIS K3
920(フロアーポリッシュ試験方法)によりPH値、
粘度(単一円筒回転粘度計使用)、光沢度、レベリング
(目視5段階評価)、及び耐ヒールマーク性(目視10
段階評価)について測定した。光沢度、レベリングにつ
いては、ビニルノンアスベストタイル(東洋リノリュー
ム社製、ニューマチコV No.33)及びホモジニア
スビニルタイル(東洋リノリューム社製、マチコSプレ
ーンNo.5626)を用いて3回塗布後測定した。ま
た、耐ヒールマーク性については、ホモジニアスビニル
タイル(東洋リノリューム社製マチコSプレーンNo.
5626)を用いて測定した。これらの測定結果を表2
に示す。なお参考として、従来公知の可塑剤及びレベリ
ング剤としてのトリブトキシエチルホスフェートについ
ての測定結果も示す。Regarding each composition obtained, JIS K3
PH value according to 920 (Floor polish test method),
Viscosity (using a single-cylinder rotary viscometer), gloss, leveling (5 grade visual evaluation), and heel mark resistance (visual 10
(Graded evaluation) was measured. The glossiness and leveling were measured after applying three times using a vinyl non-asbestos tile (manufactured by Toyo Linoleum, New Machico V No. 33) and a homogeneous vinyl tile (manufactured by Toyo Linoleum, Machico S plane No. 5626). . Regarding heel mark resistance, a homogeneous vinyl tile (Machico S Plane No. manufactured by Toyo Linoleum Co., Ltd.) was used.
5626). Table 2 shows these measurement results.
Shown in. For reference, the measurement results of conventionally known plasticizers and tributoxyethyl phosphate as leveling agents are also shown.
【0015】[0015]
【表2】
注)表中第1行目は、それぞれDIBA(ジイソブチル
アジピン酸エステル)、DBA(ジブチルアジピン酸エ
ステル)、BXA(ジブチルジグリコールアジピン酸エ
ステル)、DMA(ジメチルアジピン酸エステル)、K
P−140(トリブトキシエチルホスフェート)の略名
を示す。[Table 2] Note) The first row in the table is DIBA (diisobutyl adipate), DBA (dibutyl adipate), BXA (dibutyl diglycol adipate), DMA (dimethyl adipate), K
The abbreviation for P-140 (tributoxyethyl phosphate) is shown.
【0016】[0016]
【実施例2】表3に示す成分を通常のミキサーを用いて
均一に撹伴混合することにより、実施例1と同様に本発
明のフロアーポリッシュ組成物を得た。Example 2 The floor polish composition of the present invention was obtained in the same manner as in Example 1 by uniformly stirring and mixing the components shown in Table 3 using a conventional mixer.
【0017】[0017]
【表3】 [Table 3]
【0018】得られた組成物〔A〕について、実施例1
と同様の測定及び帯電性の測定を行なうために、JIS
K−6911に準じて行ない、横河ヒューレットパッ
カード社製超絶縁抵抗計4329Aと16008Aを用
い、温度20℃、湿度60%の条件下で印加電圧100
0Vで表面固有抵抗値を測定した。表面固有抵抗の測定
には、ホモジニアスビニルタイル(東洋リノリューム社
製、マチコSプレーンNo.5626)を用い3回塗布
後測定した。その結果を表4に示す。参考として、従来
公知のトリブトキシエチルホスフェートを用いた組成物
〔B〕の測定結果も示す。About the obtained composition [A], Example 1
In order to carry out the same measurement and chargeability measurement as JIS
Conducted according to K-6911, using Yokogawa Hewlett-Packard Co.'s super insulation resistance meters 4329A and 16008A, and applied voltage 100 under conditions of temperature 20 ° C. and humidity 60%.
The surface resistivity value was measured at 0V. The surface specific resistance was measured after applying three times using a homogeneous vinyl tile (Machico S plane No. 5626, manufactured by Toyo Linoleum Co., Ltd.). The results are shown in Table 4. For reference, the measurement results of the composition [B] using conventionally known tributoxyethyl phosphate are also shown.
【0019】[0019]
【表4】 [Table 4]
【0020】[0020]
【実施例3】表5に示す成分を通常のミキサーを用い
て、均一に撹伴混合することにより、実施例1と同様の
本発明のフロアーポリッシュ組成物を得た。Example 3 The same floor polish composition of the present invention as in Example 1 was obtained by uniformly stirring and mixing the components shown in Table 5 with a conventional mixer.
【0021】[0021]
【表5】 [Table 5]
【0022】得られた組成物〔C〕及び〔D〕につい
て、実施例1と同様の測定を行ない、その結果を表6に
示す。また、参考として、トリブトキシエチルホスフェ
ートを用いた組成物〔E〕の測定結果も示す。The compositions [C] and [D] thus obtained were measured in the same manner as in Example 1, and the results are shown in Table 6. As a reference, the measurement results of the composition [E] using tributoxyethyl phosphate are also shown.
【0023】[0023]
【表6】 [Table 6]
【0024】[0024]
【発明の効果】本発明のフロアーポリッシュ組成物は、
従来用いられている可塑剤及びレベリング剤の中で、最
も優れているトリブトキシエチルホスフェートを含むフ
ロアーポリッシュ組成物に匹敵する性能を有するもので
あり、また、トリブトキシエチルホスフェートのよう
に、リン成分を含まないので廃水処理上も好ましい。ま
た、コロイダルシリカを併用することにより、耐ヒール
マーク性が大幅に向上し、より一層耐久性の優れたフロ
アーポリッシュが得られる。また、皮膜の表面固有抵抗
値を低下させることができるので、冬季等の乾燥時期に
おける静電気によるホコリ等の付着を防止でき、美観が
維持できる。The floor polish composition of the present invention comprises:
Among the conventionally used plasticizers and leveling agents, it has a performance comparable to that of the most excellent floor polish composition containing tributoxyethyl phosphate, and, like tributoxyethyl phosphate, has a phosphorus component. Since it does not contain water, it is preferable in treating wastewater. Further, by using colloidal silica in combination, the heel mark resistance is significantly improved, and a floor polish having even more excellent durability can be obtained. Moreover, since the surface specific resistance value of the film can be reduced, it is possible to prevent the adhesion of dust and the like due to static electricity during the dry season such as winter, and maintain the aesthetic appearance.
フロントページの続き (72)発明者 近藤 哲郎 神奈川県中郡大磯町国府本郷699 ジョ ンソン株式会社内 (56)参考文献 特開 昭63−304073(JP,A) 特開 昭63−130684(JP,A) 特開 平4−225084(JP,A) 特開 平3−66771(JP,A) 特開 昭59−206476(JP,A) 特開 昭49−126614(JP,A) 特開 昭59−109653(JP,A) 特開 平1−204937(JP,A) 特開 平2−225348(JP,A) 特開 平6−33016(JP,A) (58)調査した分野(Int.Cl.7,DB名) C09G 1/00 - 1/18 Front page continuation (72) Inventor Tetsuro Kondo 699 Hongo, Koufu, Oiso-machi, Naka-gun, Kanagawa (56) References JP-A-63-304073 (JP, A) JP-A-63-130684 (JP, JP, A) JP-A-4-25084 (JP, A) JP-A-3-66771 (JP, A) JP-A-59-206476 (JP, A) JP-A-49-126614 (JP, A) JP-A-59 -109653 (JP, A) JP-A 1-204937 (JP, A) JP-A 2-225348 (JP, A) JP-A 6-33016 (JP, A) (58) Fields investigated (Int.Cl) . 7 , DB name) C09G 1/00-1/18
Claims (2)
マー(a)及びワックス類からなる艶出し成分と、アジ
ピン酸エステル類とを含有し、ポリエトシキ化脂肪族第
2級アルコールを含有しないフロアーポリッシュ組成
物。(a)スチレン−アクリル共重合樹脂、アクリル系樹
脂、ウレタン樹脂及びウレタン−アクリル樹脂から選ば
れるポリマー。 And 1. A following polymers (a) or poly <br/> mer (a) and glazing component comprising a wax below, contain adipic acid esters, Porietoshiki of aliphatic
A floor polish composition containing no secondary alcohol . (A) Styrene-acrylic copolymer resin, acrylic resin
Select from grease, urethane resin and urethane-acrylic resin
Polymer.
マー(a)及びワックス類からなる艶出し成分と、アジ
ピン酸エステル類と、コロイダルシリカとを含有し、ポ
リエトシキ化脂肪族第2級アルコールを含有しないフロ
アーポリッシュ組成物。(a)スチレン−アクリル共重合樹脂、アクリル系樹
脂、ウレタン樹脂及びウレタン、アクリル樹脂から選ば
れるポリマー。 2. A following polymers (a) or poly <br/> mer (a) and glazing component comprising a wax below, adipic acid esters, containing colloidal silica, Po
A floor polish composition that does not contain a riethosylated aliphatic secondary alcohol . (A) Styrene-acrylic copolymer resin, acrylic resin
Select from oil, urethane resin and urethane, acrylic resin
Polymer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27335292A JP3515791B2 (en) | 1992-08-31 | 1992-08-31 | Floor polish composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27335292A JP3515791B2 (en) | 1992-08-31 | 1992-08-31 | Floor polish composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0680933A JPH0680933A (en) | 1994-03-22 |
JP3515791B2 true JP3515791B2 (en) | 2004-04-05 |
Family
ID=17526705
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP27335292A Expired - Lifetime JP3515791B2 (en) | 1992-08-31 | 1992-08-31 | Floor polish composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3515791B2 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1184435A1 (en) * | 2000-08-28 | 2002-03-06 | Asahi Glass Company Ltd. | Floor polishing compound |
US6727309B1 (en) | 2002-10-08 | 2004-04-27 | 3M Innovative Properties Company | Floor finish composition |
BRPI0601352A (en) | 2005-04-25 | 2006-12-26 | Rohm & Haas | composition and method of preparing a composition |
JP4030553B2 (en) | 2005-04-25 | 2008-01-09 | ローム アンド ハース カンパニー | Floor coating composition and additive for floor coating composition |
JP2008208272A (en) * | 2007-02-27 | 2008-09-11 | Johnson Diversey Co Ltd | Floor polish composition for flooring floor |
JP5653196B2 (en) | 2010-12-03 | 2015-01-14 | 株式会社Adeka | Aqueous polishing composition for floors |
WO2015116459A1 (en) | 2014-01-29 | 2015-08-06 | 3M Innovative Properties Company | Aqueous surface coating composition and modified particles |
-
1992
- 1992-08-31 JP JP27335292A patent/JP3515791B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPH0680933A (en) | 1994-03-22 |
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