JP3515791B2 - Floor polish composition - Google Patents

Description

Detailed Description of the Invention

[0001]

FIELD OF THE INVENTION This invention relates to floor polish compositions. Specifically, it is applied to the floor surface of wooden floor materials, chemical floor materials made of synthetic resin, stone floors such as concrete and marble, and dried to form a film to maintain the aesthetics of the floor material and protect the floor surface. The present invention relates to a floor polish composition (a floor polish composition).

[0002]

2. Description of the Related Art There are three types of floor polish compositions: aqueous, emulsifying and oily. In recent years, with the development of various new types of flooring materials, a solvent is used in the oil type. It cannot be used depending on the type of floor material. Therefore, the mainstream of floor polish is water-based or emulsifiable, and as a non-volatile component, it imparts flexibility to a polymer such as a synthetic resin or a polymer and wax, or a coating film made of the polymer, and well adheres to a floor material. Including a plasticizer for Furthermore, a leveling agent is added to help the hydrophobic floor surface to wet well and form a uniform film. Tributoxyethyl phosphate is exclusively used as the plasticizer and the leveling agent.

[0003]

However, since this tributoxyethyl phosphate contains a phosphorus component,
If this is blended with the floor polish, the phosphorus component is mixed into the waste water, which is not preferable. It is an object of the present invention to solve this problem and to provide a floor polish composition containing a plasticizer and a leveling agent comparable to tributoxyethyl phosphate.

[0004]

Under the above background, the inventors of the present invention have made various studies for the purpose of obtaining an excellent plasticizer and leveling agent for floor polish, which is an alternative to tributoxyethyl phosphate. As a result, it was found that the above object was achieved by the specific compound.

Namely, the present invention comprises a glazing component comprising a specific polymer or specific polymers and waxes, and adipic acid esters, Porietoshiki of
Provided is a floor polish composition that does not contain an aliphatic secondary alcohol . Hereinafter, the present invention will be described in detail, as the polymer, especially a styrene - acrylic copolymer resin, acrylic resin, urethane resin and urethane - acrylic resin is used, they are usually used as a polymer emulsion.

As the waxes, natural waxes such as plant-based, animal-based, mineral-based, petroleum-based waxes, etc., which have been conventionally used as film forming and polishing components for floor polish, synthetic waxes, polyethylene waxes, etc.
Synthetic waxes such as modified waxes are used, and these are also usually emulsion-dispersed.

The proportion of the polymer and waxes used in the floor polish cannot be generally stated because it varies depending on the gloss and durability of the floor polish or the type of floor material, but the polymer is usually 1 to 50% by weight as a solid content. %, And waxes have a solid content of about 0 to 15% by weight.

The floor polish composition of the present invention is characterized by containing adipic acid esters as a plasticizer and a leveling agent. Examples of the adipic acid esters include dimethyl adipate, di-2-ethylhexyl adipate, diisodecyl adipate, diisobutyl adipate, dibutoxyethyl adipate, dibutyl adipate, dibutyl diglycol adipate. Esters and the like can be mentioned, which are usually added in an amount of 0.1 to 10% by weight, preferably 0.5 to 5% by weight.

Further, the floor polish composition of the present invention contains colloidal silica together with adipic acid esters to improve durability and antistatic effect.
Colloidal silica is a colloidal solution in which ultrafine particles of silicic acid anhydride are dispersed in water with water as a dispersion medium, and the size of the silicic acid particles forming the dispersoid is about 1 to 100 mμ. Known commercially available products include Snowtex (Nissan Chemical Co., Ltd.) and Cataloid-S (Catalyst Chemical Co., Ltd.). This is typically 0.1 to 1 as solids.
0% by weight, preferably 0.4-6% by weight is used.

The floor polish composition of the present invention further comprises, if necessary, an alkali-soluble resin, a polymer and a coating film used as an auxiliary agent for assisting the leveling of polymers and waxes and improving the peelability. Fluorine-based interface that facilitates film formation even at room temperature, a film-forming aid consisting of a high-boiling solvent that volatilizes and does not remain after the film is formed, and lowers the surface tension of the emulsion to improve wettability to the floor surface. An appropriate amount of an activator, a polyvalent metal compound for improving detergent resistance and releasability, other emulsifiers, preservatives, antifoaming agents and the like may be contained.

The floor polish composition of the present invention is produced by blending the above-mentioned components and water so that the solid content is about 10 to 45% by weight, and uniformly mixing with a usual mixer. Next, the present invention will be described more specifically according to examples, but the present invention is not limited to the following examples.

[0012]

Example 1 The floor polish composition of the present invention was obtained by uniformly agitating and mixing the components shown in Table 1 with an ordinary mixer.

[0013]

[Table 1]

Regarding each composition obtained, JIS K3
PH value according to 920 (Floor polish test method),
Viscosity (using a single-cylinder rotary viscometer), gloss, leveling (5 grade visual evaluation), and heel mark resistance (visual 10
(Graded evaluation) was measured. The glossiness and leveling were measured after applying three times using a vinyl non-asbestos tile (manufactured by Toyo Linoleum, New Machico V No. 33) and a homogeneous vinyl tile (manufactured by Toyo Linoleum, Machico S plane No. 5626). . Regarding heel mark resistance, a homogeneous vinyl tile (Machico S Plane No. manufactured by Toyo Linoleum Co., Ltd.) was used.
5626). Table 2 shows these measurement results.
Shown in. For reference, the measurement results of conventionally known plasticizers and tributoxyethyl phosphate as leveling agents are also shown.

[0015]

[Table 2] Note) The first row in the table is DIBA (diisobutyl adipate), DBA (dibutyl adipate), BXA (dibutyl diglycol adipate), DMA (dimethyl adipate), K
The abbreviation for P-140 (tributoxyethyl phosphate) is shown.

[0016]

Example 2 The floor polish composition of the present invention was obtained in the same manner as in Example 1 by uniformly stirring and mixing the components shown in Table 3 using a conventional mixer.

[0017]

[Table 3]

About the obtained composition [A], Example 1
In order to carry out the same measurement and chargeability measurement as JIS
Conducted according to K-6911, using Yokogawa Hewlett-Packard Co.'s super insulation resistance meters 4329A and 16008A, and applied voltage 100 under conditions of temperature 20 ° C. and humidity 60%.
The surface resistivity value was measured at 0V. The surface specific resistance was measured after applying three times using a homogeneous vinyl tile (Machico S plane No. 5626, manufactured by Toyo Linoleum Co., Ltd.). The results are shown in Table 4. For reference, the measurement results of the composition [B] using conventionally known tributoxyethyl phosphate are also shown.

[0019]

[Table 4]

[0020]

Example 3 The same floor polish composition of the present invention as in Example 1 was obtained by uniformly stirring and mixing the components shown in Table 5 with a conventional mixer.

[0021]

[Table 5]

The compositions [C] and [D] thus obtained were measured in the same manner as in Example 1, and the results are shown in Table 6. As a reference, the measurement results of the composition [E] using tributoxyethyl phosphate are also shown.

[0023]

[Table 6]

[0024]

The floor polish composition of the present invention comprises:
Among the conventionally used plasticizers and leveling agents, it has a performance comparable to that of the most excellent floor polish composition containing tributoxyethyl phosphate, and, like tributoxyethyl phosphate, has a phosphorus component. Since it does not contain water, it is preferable in treating wastewater. Further, by using colloidal silica in combination, the heel mark resistance is significantly improved, and a floor polish having even more excellent durability can be obtained. Moreover, since the surface specific resistance value of the film can be reduced, it is possible to prevent the adhesion of dust and the like due to static electricity during the dry season such as winter, and maintain the aesthetic appearance.

Front page continuation (72) Inventor Tetsuro Kondo 699 Hongo, Koufu, Oiso-machi, Naka-gun, Kanagawa (56) References JP-A-63-304073 (JP, A) JP-A-63-130684 (JP, JP, A) JP-A-4-25084 (JP, A) JP-A-3-66771 (JP, A) JP-A-59-206476 (JP, A) JP-A-49-126614 (JP, A) JP-A-59 -109653 (JP, A) JP-A 1-204937 (JP, A) JP-A 2-225348 (JP, A) JP-A 6-33016 (JP, A) (58) Fields investigated (Int.Cl) . ⁷ , DB name) C09G 1/00-1/18

Claims (2)

(57) [Claims] And 1. A following polymers (a) or poly <br/> mer (a) and glazing component comprising a wax below, contain adipic acid esters, Porietoshiki of aliphatic
A floor polish composition containing no secondary alcohol . (A) Styrene-acrylic copolymer resin, acrylic resin
Select from grease, urethane resin and urethane-acrylic resin
Polymer. 2. A following polymers (a) or poly <br/> mer (a) and glazing component comprising a wax below, adipic acid esters, containing colloidal silica, Po
A floor polish composition that does not contain a riethosylated aliphatic secondary alcohol . (A) Styrene-acrylic copolymer resin, acrylic resin
Select from oil, urethane resin and urethane, acrylic resin
Polymer.