JPH0851011A - Magnetic oxide material - Google Patents
Magnetic oxide materialInfo
- Publication number
- JPH0851011A JPH0851011A JP6204525A JP20452594A JPH0851011A JP H0851011 A JPH0851011 A JP H0851011A JP 6204525 A JP6204525 A JP 6204525A JP 20452594 A JP20452594 A JP 20452594A JP H0851011 A JPH0851011 A JP H0851011A
- Authority
- JP
- Japan
- Prior art keywords
- inductance
- mol
- oxide material
- magnetic oxide
- magnetic field
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、PHS等の通信機器、
携帯型VTR等の回路に使用されるエポキシ樹脂等で外
装した構造を有するインダクター用の磁心材料となる酸
化物磁性材料に関するものである。BACKGROUND OF THE INVENTION The present invention relates to communication equipment such as PHS,
The present invention relates to an oxide magnetic material serving as a magnetic core material for an inductor having a structure coated with an epoxy resin or the like used in a circuit of a portable VTR or the like.
【0002】[0002]
【従来技術】このインダクターとしては、磁心に巻線を
施した後、樹脂等でモールドされる場合があり、このよ
うな場合、コアに加わる応力によってインダクタンスが
低下するという問題点、また外部から一時的に加わる磁
界によってインダクタンスが低下するという問題点があ
った。例えば、特開平3―93667号公報に示されて
いるように、25〜45mol%のFe2O3、0〜20
mol%のZnO、残りがNiOとCuOであり、Ni
Oのモル比がCuOのモル比よりも多いスピネル型組成
物であって、少量成分として0.1〜12wt%のBi
2O3及び0.05〜4.0wt%のSiO2を含む材料
が1MHz以上の高周波においても損失が少なく、かつ
外部からの加圧及び磁場印加に対するインダクタンスの
低下が少ない材料であることが提案されている。2. Description of the Related Art As an inductor, there is a case where a magnetic core is wound and then molded with resin or the like. In such a case, the stress applied to the core causes a decrease in inductance, and it is possible to temporarily reduce the inductance from the outside. There is a problem in that the inductance is reduced by the magnetic field that is applied. For example, as disclosed in JP-A-3-93667, 25-45 mol% Fe 2 O 3 , 0-20
mol% ZnO, the rest NiO and CuO,
A spinel-type composition in which the molar ratio of O is higher than that of CuO, and 0.1 to 12 wt% of Bi as a minor component is used.
It is proposed that the material containing 2 O 3 and 0.05 to 4.0 wt% of SiO 2 has little loss even at a high frequency of 1 MHz or more, and has little decrease in inductance due to external pressure and magnetic field application. Has been done.
【0003】[0003]
【発明が解決しようとする課題】この外部応力に対する
インダクタンスの変化、及び外部磁場印加後のインダク
タンスの低下に対して、更なる改良の要求があり、大き
な外部応力に対してもインダクタンスの変化が小さく、
外部磁場印加後のインダクタンスの低下の少ない酸化物
磁性材料を提供することを目的とする。There is a demand for further improvement with respect to the change of the inductance due to the external stress and the decrease of the inductance after the application of the external magnetic field, and the change of the inductance is small even under the large external stress. ,
It is an object of the present invention to provide an oxide magnetic material whose inductance is less likely to decrease after application of an external magnetic field.
【0004】[0004]
【課題を解決するための手段】本発明は、Fe2O3 5
〜24.5mol%、CuO 0〜30mol%(但
し、0mol%を含まない)、残部NiOからなる主成
分に対し、SiO2 0〜10wt%(但し、0wt%
を含まない)、Bi2O3 0〜10wt%(但し、0w
t%を含まない)を含有する酸化物磁性材料である。ま
た本発明は、上記材料に、Co3O4を0〜0.5wt%
(但し、0wt%を含まない)含有するものである。SUMMARY OF THE INVENTION The present invention relates to Fe 2 O 3 5
To 24.5 mol%, CuO 0 to 30 mol% (excluding 0 mol%) and the balance NiO to the main component consisting of SiO 2 0 to 10 wt% (however, 0 wt%
Not included), Bi 2 O 3 0-10 wt% (however, 0w
(not including t%). The present invention also provides that the above material contains Co 3 O 4 in an amount of 0 to 0.5 wt%.
(However, 0 wt% is not included).
【0005】[0005]
【作用】本発明は、Fe2O3の含有量が24.5mol
%以下であることが、外部磁場印加後のインダクタンス
の低下が少ないことを見出したものである。本発明にお
いて、各成分を限定した理由は以下の通りである。Fe
2O3の含有量は、24.5mol%を越えると、磁場印
加後のインダクタンスの低下が大きくなり、5mol%
より少ないと、透磁率が1.5以下となり、磁性体とし
て役立たない。CuOが30mol%を越えると、透磁
率が焼成条件で敏感に変動し、特性の再現性が悪い。S
iO2は、10wt%を越えると焼結性が悪くなり、製
品の強度が低下する。Bi2O3は、10wt%を越える
と透磁率が大幅に低下する。Co3O4が0.5wt%を
越えると、磁場劣化が大きくなる。The present invention has a Fe 2 O 3 content of 24.5 mol.
It has been found that the decrease of the inductance after application of the external magnetic field is small when it is less than or equal to%. The reason why each component is limited in the present invention is as follows. Fe
If the content of 2 O 3 exceeds 24.5 mol%, the decrease in inductance after applying a magnetic field becomes large, and
If it is less, the magnetic permeability will be 1.5 or less, and it will not be useful as a magnetic material. When CuO exceeds 30 mol%, the magnetic permeability changes sensitively under the firing conditions and the reproducibility of the characteristics is poor. S
When iO 2 exceeds 10 wt%, the sinterability deteriorates and the product strength decreases. When Bi 2 O 3 exceeds 10 wt%, the magnetic permeability is significantly reduced. When Co 3 O 4 exceeds 0.5 wt%, the magnetic field deterioration becomes large.
【0006】[0006]
【実施例】Fe2O3 20.0mol%、CuO 2.
5mol%、NiO 77.5mol%の主成分に、S
iO2 0.6wt%、Bi2O3 4.0wt%、Co3
O4 0.1wt%を含有させた原料を混合し、900
℃で2時間仮焼した後、振動ミル、アトライタで粉砕
し、1.0〜1.5μmのフェライト粉末を作成した。
これを造粒し、30φのトロイダル形状の成形体と、角
棒(5×5×15mm)の成形体を得た。これを大気中
1050℃で2時間焼成し試料を作成した。これを実姉
例1とする。EXAMPLES Fe 2 O 3 20.0 mol%, CuO 2.
5 mol%, NiO 77.5 mol% as the main component, S
iO 2 0.6 wt%, Bi 2 O 3 4.0 wt%, Co 3
The raw materials containing 0.1 wt% of O 4 are mixed to obtain 900
After calcination for 2 hours at ℃, it was pulverized by a vibration mill and an attritor to prepare a ferrite powder of 1.0 to 1.5 μm.
This was granulated to obtain a 30φ toroidal shaped body and a square bar (5 × 5 × 15 mm) shaped body. A sample was prepared by firing this in air at 1050 ° C. for 2 hours. This is referred to as actual sister example 1.
【0007】焼成した30φのトロイダルコアは、透磁
率、Q、相対温度係数(αμr)、焼結密度の測定に用
いた。角棒は、2×2×10mmに加工し、消磁した
後、直径0.1mmの被膜導線を40ターン密巻に巻線
を施し、応力特性の測定を行った。この応力特性は、5
kg/mm2、10kg/mm2の圧力をかけて、圧力を
かける前のインダクタンスをL1とし、軸方向に上記の
荷重を加えた状態でインダクタンスを測定し、L2と
し、(L2―L1)/L1*100により変化率(%)
とした。また、磁場特性については、10kg/mm2
の荷重を加えた状態で100mTの磁界を瞬間的に加
え、外部磁界を取り去った後インダクタンスを測定し、
L3とし、(L3−L2)/L1*100により変化率
(%)とした。The fired 30φ toroidal core was used to measure magnetic permeability, Q, relative temperature coefficient (αμr), and sintered density. The square bar was processed into 2 × 2 × 10 mm and demagnetized, and then a coated conductive wire with a diameter of 0.1 mm was wound in a tight winding of 40 turns, and the stress characteristics were measured. This stress characteristic is 5
by applying a pressure of kg / mm 2, 10kg / mm 2, the inductance before applying pressure and L1, the inductance is measured while applying the above load in the axial direction, and L2, (L2-L1) / Change rate (%) by L1 * 100
And Regarding the magnetic field characteristics, 10 kg / mm 2
The magnetic field of 100 mT is momentarily applied under the condition that the load is applied, and after removing the external magnetic field, the inductance is measured,
L3, and the rate of change (%) was calculated from (L3-L2) / L1 * 100.
【0008】また、表1に示す組成比にて、上記実施例
1と同様にして各試料を作成し、特性を評価した。各試
料の特性を表2に示す。Further, each sample was prepared with the composition ratio shown in Table 1 in the same manner as in Example 1 above, and the characteristics were evaluated. The characteristics of each sample are shown in Table 2.
【0009】[0009]
【表1】 [Table 1]
【0010】[0010]
【表2】 [Table 2]
【0011】この表1、2からわかるとおり、本発明の
実姉例は、加圧特性では従来例と大差ないが、磁場特性
において、従来例に比較し、大幅に改善されている。ま
た本発明では、添加物としてPbOを添加しても良い、
この場合、PbOは焼結促進に有効であるが、10wt
%を越えると透磁率が大幅に低下するため、10wt%
以下が望ましい。As can be seen from Tables 1 and 2, the actual sisters of the present invention are not much different from the conventional examples in the pressurizing characteristics, but are significantly improved in the magnetic field characteristics as compared with the conventional examples. Further, in the present invention, PbO may be added as an additive,
In this case, PbO is effective in promoting sintering, but 10 wt.
%, The magnetic permeability will drop significantly, so 10 wt%
The following is desirable.
【0012】[0012]
【発明の効果】本発明によれば、外部応力を受けたとき
にインダクタンスの変化が少なく、しかも外部磁界の影
響によるインダクタンスの低下が極めて少ない磁性材料
を得ることが出来る。これにより、チップインダクター
として用いられた場合、巻線後の樹脂モールドによる応
力に対してインダクタンスの変化が少なく、しかも自動
装着機などを使用した場合の磁石による吸着を受けた場
合のインダクタンスの低下の少ないチップインダクター
を得ることが出来、産業上有益である。According to the present invention, it is possible to obtain a magnetic material in which the change in inductance is small when an external stress is applied and the decrease in inductance due to the influence of an external magnetic field is extremely small. As a result, when used as a chip inductor, there is little change in the inductance due to the stress caused by the resin mold after winding, and the inductance decreases when attracted by the magnet when using an automatic mounting machine. It is possible to obtain a chip inductor with less power consumption, which is industrially beneficial.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C04B 35/28 B ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display location C04B 35/28 B
Claims (2)
O 0〜30mol%(但し、0mol%を含まな
い)、残部NiOからなる主成分に対し、SiO2 0
〜10wt%(但し、0wt%を含まない)、Bi2O3
0〜10wt%(但し、0wt%を含まない)を含有
することを特徴とする酸化物磁性材料。1. Fe 2 O 3 5 to 24.5 mol%, Cu
O 0~30mol% (however, not including 0 mol%), relative to the main component of the balance of NiO, SiO 2 0
-10 wt% (excluding 0 wt%), Bi 2 O 3
An oxide magnetic material comprising 0 to 10 wt% (excluding 0 wt%).
5wt%(但し、0wt%を含まない)含有することを
特徴とする酸化物磁性材料。2. The method according to claim 1, wherein Co 3 O 4 is added to 0 to 0.
An oxide magnetic material containing 5 wt% (excluding 0 wt%).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6204525A JPH0851011A (en) | 1994-08-05 | 1994-08-05 | Magnetic oxide material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6204525A JPH0851011A (en) | 1994-08-05 | 1994-08-05 | Magnetic oxide material |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0851011A true JPH0851011A (en) | 1996-02-20 |
Family
ID=16491984
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6204525A Pending JPH0851011A (en) | 1994-08-05 | 1994-08-05 | Magnetic oxide material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0851011A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6183659B1 (en) | 1998-10-23 | 2001-02-06 | Tdk Corporation | Ferrite oxide magnetic material |
EP1201621A1 (en) * | 2000-10-31 | 2002-05-02 | TDK Corporation | Magnetic ferrite material and inductor |
CN102122557A (en) * | 2010-12-14 | 2011-07-13 | 深圳顺络电子股份有限公司 | Low magnetic ferrite material and manufacturing method thereof |
JP6142950B1 (en) * | 2016-09-30 | 2017-06-07 | Tdk株式会社 | Ferrite composition and electronic component |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54163911A (en) * | 1978-06-15 | 1979-12-27 | Hitachi Metals Ltd | High frequency magnetic material |
JPH0391209A (en) * | 1989-09-01 | 1991-04-16 | Hitachi Ferrite Ltd | Chip inductor |
-
1994
- 1994-08-05 JP JP6204525A patent/JPH0851011A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54163911A (en) * | 1978-06-15 | 1979-12-27 | Hitachi Metals Ltd | High frequency magnetic material |
JPH0391209A (en) * | 1989-09-01 | 1991-04-16 | Hitachi Ferrite Ltd | Chip inductor |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6183659B1 (en) | 1998-10-23 | 2001-02-06 | Tdk Corporation | Ferrite oxide magnetic material |
EP1201621A1 (en) * | 2000-10-31 | 2002-05-02 | TDK Corporation | Magnetic ferrite material and inductor |
US6583699B2 (en) | 2000-10-31 | 2003-06-24 | Tdk Corporation | Magnetic material and inductor |
CN102122557A (en) * | 2010-12-14 | 2011-07-13 | 深圳顺络电子股份有限公司 | Low magnetic ferrite material and manufacturing method thereof |
JP6142950B1 (en) * | 2016-09-30 | 2017-06-07 | Tdk株式会社 | Ferrite composition and electronic component |
JP2018052793A (en) * | 2016-09-30 | 2018-04-05 | Tdk株式会社 | Ferrite composition and electronic component |
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