JPH0837340A - Surface emission semiconductor element - Google Patents

Surface emission semiconductor element

Info

Publication number
JPH0837340A
JPH0837340A JP11768294A JP11768294A JPH0837340A JP H0837340 A JPH0837340 A JP H0837340A JP 11768294 A JP11768294 A JP 11768294A JP 11768294 A JP11768294 A JP 11768294A JP H0837340 A JPH0837340 A JP H0837340A
Authority
JP
Japan
Prior art keywords
layer
gaas
band gap
multilayer reflective
reflective film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11768294A
Other languages
Japanese (ja)
Inventor
Seiji Uchiyama
誠治 内山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GIJUTSU KENKYU KUMIAI SHINJOHO
GIJUTSU KENKYU KUMIAI SHINJOHO SHIYORI KAIHATSU KIKO
Furukawa Electric Co Ltd
Original Assignee
GIJUTSU KENKYU KUMIAI SHINJOHO
GIJUTSU KENKYU KUMIAI SHINJOHO SHIYORI KAIHATSU KIKO
Furukawa Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GIJUTSU KENKYU KUMIAI SHINJOHO, GIJUTSU KENKYU KUMIAI SHINJOHO SHIYORI KAIHATSU KIKO, Furukawa Electric Co Ltd filed Critical GIJUTSU KENKYU KUMIAI SHINJOHO
Priority to JP11768294A priority Critical patent/JPH0837340A/en
Publication of JPH0837340A publication Critical patent/JPH0837340A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To provide a surface emission semiconductor element, which can lower applied voltage for emission. CONSTITUTION:In a 0.9-1.1mum band surface emission semiconductor element with GaAs/In0.48Ga0.52P semiconductor multilayer reflection films 2a and 2b, which reflects light from an active layer 3, the GaAs/In0.48Ga0.52P semiconductor multi-layer reflection films 2a and 2b perform lattice matching with GaAs between a GaAs layer and an In0.48Ga0.52P layer, and is formed via a GaInAsP layer having a band gap which is intermediate between a band gap of GaAs and a band gap of In0.48Ga0.52P.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、面発光半導体素子に関
し、特に面発光半導体素子を構成する半導体多層反射膜
に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a surface emitting semiconductor device, and more particularly to a semiconductor multi-layer reflective film constituting the surface emitting semiconductor device.

【0002】[0002]

【従来の技術】面発光半導体レーザ素子あるいは面発光
型半導体ダイオードでは、低しきい値化および発光効率
の向上のために、半導体多層反射膜を用いて高反射率化
が進められている。従来、0.9〜1.1μm帯面発光
半導体レーザ素子あるいは面発光型半導体ダイオードを
構成する半導体多層反射膜の材料としては、例えば文献
1に示されているように、屈折率が高いGaAs(また
はGaAsに近いバンドギャップを有する組成のGa
1-X AlX As、X<0.1)と屈折率の低い材料であ
るAlAs(またはAlAsに近いバンドギャップを有
する組成のGa1-X AlX As、X>0.9)の組み合
わせが広く用いられている。この半導体多層反射膜の構
成は、発光波長をλ0 、GaAsおよびAlAsの屈折
率をそれぞれn1 、n2とすると、それぞれの層の厚さ
はλ0 /4n1 およびλ0 /4n2 であり、これらの層
を交互に組み合わせたものである。このような構成にす
ることにより、波長λ0 において吸収率を小さくし反射
率を大きくすることができる。
2. Description of the Related Art In a surface emitting semiconductor laser device or a surface emitting type semiconductor diode, a semiconductor multilayer reflective film is used to increase the reflectance in order to reduce the threshold value and improve the luminous efficiency. Conventionally, as a material of a semiconductor multi-layer reflective film that constitutes a 0.9 to 1.1 μm band surface emitting semiconductor laser device or a surface emitting semiconductor diode, for example, as shown in Document 1, GaAs (having a high refractive index) ( Or Ga having a composition having a band gap close to that of GaAs
A combination of 1-X Al X As, X <0.1) and AlAs (or a Ga 1-X Al X As with a composition having a band gap close to AlAs, X> 0.9) having a low refractive index Widely used. This semiconductor multilayer reflective film has a thickness of λ 0 / 4n 1 and λ 0 / 4n 2 when the emission wavelength is λ 0 and the refractive indices of GaAs and AlAs are n 1 and n 2 , respectively. Yes, these are alternating combinations of these layers. With such a configuration, the absorptance can be reduced and the reflectance can be increased at the wavelength λ 0 .

【0003】ところで、上述の半導体多層反射膜では、
GaAs(格子定数a1 =0.56533nm)とAl
As(格子定数a2 =0.56605nm)の間に0.
13%の格子不整合が存在する。また、この多層反射膜
を円形あるいは矩形のメサに形成する工程で、空気中に
露出したAlAs中のAlが酸化しやすく、信頼性に問
題を生ずるとともに、埋め込みヘテロ構造を形成する際
に、AlAs層側面に結晶再成長をおこなうことが困難
であるという問題があった。そこで、Alを含まない半
導体多層反射膜として、GaAs/InGaP半導体多
層反射膜が検討されている。 文献1:Electron. Lett., 1989, 25, pp.1123-1124
By the way, in the above-mentioned semiconductor multilayer reflective film,
GaAs (lattice constant a 1 = 0.56533 nm) and Al
During As (lattice constant a 2 = 0.56605 nm), a value of 0.
There is a 13% lattice mismatch. Also, in the process of forming this multilayer reflective film into a circular or rectangular mesa, Al in AlAs exposed in the air is easily oxidized, which causes a problem in reliability, and when forming a buried hetero structure, AlAs is formed. There is a problem that it is difficult to re-grow the crystal on the side surface of the layer. Therefore, a GaAs / InGaP semiconductor multilayer reflective film has been studied as a semiconductor multilayer reflective film containing no Al. Reference 1: Electron. Lett., 1989, 25, pp.1123-1124

【0004】[0004]

【発明が解決しようとする課題】しかしながら、上述の
GaAs/InGaP半導体多層反射膜では、GaAs
/InGaP界面にスパイク状の大きなバンドギャップ
が存在し、その値は0.35eVにもなる。そのため、
p型でホールがこのバンドギャップを乗り越えるために
は、高い電圧を印加することが必要になるという問題が
あった。
However, in the above-mentioned GaAs / InGaP semiconductor multilayer reflective film, GaAs is used.
A large spike-like band gap exists at the / InGaP interface, and the value is as high as 0.35 eV. for that reason,
There is a problem that a high voltage needs to be applied in order for p-type holes to overcome this band gap.

【0005】[0005]

【課題を解決するための手段】本発明は上記問題点を解
決した面発光半導体素子を提供するもので、活性層から
の光を反射するGaAs/In0.48Ga0.52P半導体多
層反射膜を有する0.9〜1.1μm帯面発光半導体素
子において、前記半導体多層反射膜はGaAs層とIn
0.48Ga0.52P層の間に、GaAsと格子整合し、Ga
AsのバンドギャップとIn0.48Ga0.52Pのバンドギ
ャップの中間のバンドギャップを有するGaInAsP
層を介在させたことを特徴とするものである。
SUMMARY OF THE INVENTION The present invention provides a surface emitting semiconductor device that solves the above problems, and has a GaAs / In 0.48 Ga 0.52 P semiconductor multilayer reflective film that reflects light from an active layer. .9 to 1.1 μm surface emitting semiconductor device, the semiconductor multilayer reflective film comprises a GaAs layer and an In layer.
Ga between the 0.48 Ga 0.52 P layer is lattice-matched with GaAs,
GaInAsP having a band gap intermediate between the band gap of As and the band gap of In 0.48 Ga 0.52 P
It is characterized by interposing layers.

【0006】[0006]

【作用】上述のように、半導体多層反射膜を構成するG
aAs層とIn0.48Ga0.52P層の間に、GaAsと格
子整合し、GaAsのバンドギャップとIn0.48Ga
0.52Pのバンドギャップの中間のバンドギャップを有す
るGaInAsP層を介在させると、GaAs層とIn
0.48Ga0.52P層の間のバンドギャップがなだらかに変
化し、スパイク状のバンドギャップがなくなるので、発
光させるための印加電圧を低下させることができる。
As described above, the G which constitutes the semiconductor multilayer reflective film
Between the aAs layer and the In 0.48 Ga 0.52 P layer, lattice matching is performed with GaAs, and the band gap of GaAs and In 0.48 Ga
When a GaInAsP layer having a bandgap in the middle of the bandgap of 0.52 P is interposed, a GaAs layer and an In layer are formed.
Since the band gap between the 0.48 Ga 0.52 P layers changes gently and the spike-shaped band gap disappears, the applied voltage for light emission can be lowered.

【0007】[0007]

【実施例】以下、図面に示した実施例に基づいて本発明
を詳細に説明する。図1は、本発明にかかる面発光半導
体レーザ素子の一実施例の断面図である。図中、1はn
−GaAs基板、2a、2bはそれぞれn型およびp型
の半導体多層反射膜、3は多重量子井戸活性層(バンド
ギャップ波長0.9〜1.1μm)、4は電流ブロック
層、5はn電極、6はp電極である。レーザ共振器は、
活性層3を挟む半導体多層反射膜2a、2bにより構成
されており、基板1と垂直方向に発振する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described in detail below with reference to the embodiments shown in the drawings. FIG. 1 is a sectional view of an embodiment of a surface emitting semiconductor laser device according to the present invention. In the figure, 1 is n
-GaAs substrate, 2a and 2b are n-type and p-type semiconductor multilayer reflective films, 3 is a multiple quantum well active layer (bandgap wavelength 0.9 to 1.1 [mu] m), 4 is a current blocking layer, and 5 is an n electrode. , 6 are p electrodes. Laser cavity
The semiconductor multilayer reflection films 2a and 2b sandwich the active layer 3 and oscillate in a direction perpendicular to the substrate 1.

【0008】図2は、半導体多層反射膜2a、2bのバ
ンドダイヤグラムを示す図である。半導体多層反射膜2
a、2bは、屈折率n1 のGaAs層8と、GaAsと
格子整合がとれ、GaAsよりも高い屈折率n2 を有す
るIn0.48Ga0.52P層7を交互に重ねて構成されてい
る。また、In0.48Ga0.52P層7とGaAs層8との
間に、GaAsに格子整合し、GaAsのバンドギャッ
プ(Eg :1.42eV)とIn0.48Ga0.52Pのバン
ドギャップ(Eg :1.91eV)の中間のバンドギャ
ップを有するGaInAsP層9を介在させる。GaI
nAsP層9の組成は厚さ方向にステップ状に変化し、
GaAs層8側から、Ga0.62In0.38As0.270.73
(Eg :1.55eV)、Ga0.72In0.28As0.47
0.53(Eg :1.65eV)、Ga0.85In0.15As
0.710.29(Eg :1.77eV)とする。その結果、
In0.48Ga0.52P層7とGaAs層8のバンドギャッ
プはステップ状になだらかにつながり、スパイク状のバ
ンドギャップがなくなる。
FIG. 2 is a diagram showing a band diagram of the semiconductor multilayer reflective films 2a and 2b. Semiconductor multilayer reflective film 2
a, 2b includes a GaAs layer 8 having a refractive index n 1, take a GaAs lattice matching, is configured by alternately stacking the In 0.48 Ga 0.52 P layer 7 having a high refractive index n 2 than GaAs. Further, the In 0.48 Ga 0.52 P layer 7 and the GaAs layer 8 are lattice-matched to GaAs, and the band gap of GaAs (E g : 1.42 eV) and the band gap of In 0.48 Ga 0.52 P (E g : 1 A GaInAsP layer 9 having an intermediate bandgap of .91 eV) is interposed. GaI
The composition of the nAsP layer 9 changes stepwise in the thickness direction,
From the GaAs layer 8 side, Ga 0.62 In 0.38 As 0.27 P 0.73
(E g : 1.55 eV), Ga 0.72 In 0.28 As 0.47 P
0.53 (E g : 1.65 eV), Ga 0.85 In 0.15 As
0.71 P 0.29 (E g : 1.77 eV). as a result,
The band gaps of the In 0.48 Ga 0.52 P layer 7 and the GaAs layer 8 are smoothly connected in a step shape, and the spike-shaped band gap disappears.

【0009】各層の厚さは、例えば以下のように設定す
る。即ち、 1)GaAs層8の層厚d1 がλ0 /4n1 (λ0 :発
振波長)、In0.48Ga0.52P層7厚d2 +GaInA
sP層9厚d3 がλ0 /4na (na :n2 とGaIn
AsPの屈折率の平均)とする。 2)あるいは、d2 =λ0 /4n2 、d1 +d3 =λ0
/4nb (nb :n1 とGaInAsPの屈折率の平
均)とする。 3)さらには、d2 +d3 /2=λ0 /4na 、d1
3 /2=λ0 /4nbとする。 このような半導体多層反射膜2a、2bでは、In0.48
Ga0.52P層7とGaAs層8との間のバンドギャップ
はなだらかに変化し、スパイク状に変化する部分がない
ため、半導体多層反射膜2a、2bにnまたはp型不純
物をドーピングして電流を流す際に、GaInAsP層
9を介在させない場合に比較して、印圧電圧を小さくす
ることができる。
The thickness of each layer is set as follows, for example. 1) The layer thickness d 1 of the GaAs layer 8 is λ 0 / 4n 10 : oscillation wavelength), In 0.48 Ga 0.52 P layer 7 thickness d 2 + GaInA
sP layer 9 thickness d 3 is λ 0 / 4n a (n a : n 2 and GaIn
The average of the refractive index of AsP). 2) Alternatively, d 2 = λ 0 / 4n 2 , d 1 + d 3 = λ 0
/ 4n b (n b : the average of the refractive indices of n 1 and GaInAsP). 3) Furthermore, d 2 + d 3/2 = λ 0 / 4n a, d 1 +
and d 3/2 = λ 0 / 4n b. In such a semiconductor multilayer reflective film 2a, 2b, In 0.48
Since the band gap between the Ga 0.52 P layer 7 and the GaAs layer 8 changes gently and there is no portion that changes in a spike shape, the semiconductor multilayer reflective films 2a and 2b are doped with an n or p-type impurity to increase the current. When flowing, the printing pressure voltage can be reduced as compared with the case where the GaInAsP layer 9 is not interposed.

【0010】本実施例の素子は以下のようにして製作す
る。即ち、先ず、有機金属気相成長(MOCVD)法あ
るいは分子エピタキシー(MBE)法で、基板1上に上
述のGaInAsP層9を介在させたn型In0.48Ga
0.52P/GaAs半導体多層反射膜2a、活性層3、上
述のGaInAsP層9を介在させたp型In0.48Ga
0.52P/GaAs半導体多層反射膜2bを順次成長させ
る。次いで、活性層3を含む円形または矩形メサを形成
し、このメサを電流ブロック層4で埋め込み、n電極
5、p電極6を形成する。この場合、半導体多層反射膜
2a、2bにAlAsまたはGaAlAsが含まれてい
ないため、メサが酸化することはない。なお、上記実施
例では、GaInAsP層9のバンドギャップはステッ
プ状に変化したが、連続的に変化してもよい。
The element of this embodiment is manufactured as follows. That is, first, n-type In 0.48 Ga in which the above-mentioned GaInAsP layer 9 is interposed on the substrate 1 by the metal organic chemical vapor deposition (MOCVD) method or the molecular epitaxy (MBE) method.
0.52 P / GaAs semiconductor multilayer reflective film 2a, active layer 3, and p-type In 0.48 Ga with the GaInAsP layer 9 interposed therebetween.
A 0.52 P / GaAs semiconductor multilayer reflective film 2b is sequentially grown. Next, a circular or rectangular mesa including the active layer 3 is formed, and this mesa is embedded with the current block layer 4 to form the n electrode 5 and the p electrode 6. In this case, since the semiconductor multilayer reflective films 2a and 2b do not contain AlAs or GaAlAs, the mesas are not oxidized. Although the band gap of the GaInAsP layer 9 was changed stepwise in the above-mentioned embodiment, it may be changed continuously.

【0011】[0011]

【発明の効果】以上説明したように本発明によれば、活
性層からの光を反射するGaAs/In0.48Ga0.52
半導体多層反射膜を有する0.9〜1.1μm帯面発光
半導体素子において、前記半導体多層反射膜はGaAs
層とIn0.48Ga0.52P層の間に、GaAsと格子整合
し、GaAsのバンドギャップとIn0.48Ga0.52Pの
バンドギャップの中間のバンドギャップを有するGaI
nAsP層を介在させるため、発光させるための印加電
圧を低下させることができるという優れた効果がある。
As described above, according to the present invention, GaAs / In 0.48 Ga 0.52 P that reflects light from the active layer is obtained.
In a 0.9 to 1.1 μm band surface emitting semiconductor device having a semiconductor multilayer reflective film, the semiconductor multilayer reflective film is GaAs.
GaI lattice-matched to GaAs and having a bandgap intermediate between the bandgap of GaAs and the bandgap of In 0.48 Ga 0.52 P between the In layer and the In 0.48 Ga 0.52 P layer.
Since the nAsP layer is interposed, there is an excellent effect that the applied voltage for emitting light can be lowered.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明に係る面発光半導体素子の一実施例の断
面図である。
FIG. 1 is a sectional view of an embodiment of a surface emitting semiconductor device according to the present invention.

【図2】上記実施例に用いた半導体多層反射膜のバンド
ダイヤグラムを示す図である。
FIG. 2 is a diagram showing a band diagram of a semiconductor multilayer reflective film used in the above-mentioned examples.

【符号の説明】[Explanation of symbols]

1 基板 2a、2b 半導体多層反射膜 3 活性層 4 電流ブロック層 5 n電極 6 p電極 7 In0.48Ga0.52P層 8 GaAs層 9 GaInAsP層1 Substrate 2a, 2b Semiconductor Multilayer Reflective Film 3 Active Layer 4 Current Blocking Layer 5 n Electrode 6 p Electrode 7 In 0.48 Ga 0.52 P Layer 8 GaAs Layer 9 GaInAsP Layer

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 活性層からの光を反射するGaAs/I
0.48Ga0.52P半導体多層反射膜を有する0.9〜
1.1μm帯面発光半導体素子において、前記半導体多
層反射膜はGaAs層とIn0.48Ga0.52P層の間に、
GaAsと格子整合し、GaAsのバンドギャップとI
0.48Ga0.52Pのバンドギャップの中間のバンドギャ
ップを有するGaInAsP層を介在させたことを特徴
とする面発光半導体素子。
1. A GaAs / I that reflects light from an active layer.
n 0.48 Ga 0.52 P having a semiconductor multilayer reflective film 0.9 to
In the 1.1 μm band surface emitting semiconductor device, the semiconductor multilayer reflective film is formed between the GaAs layer and the In 0.48 Ga 0.52 P layer.
It is lattice-matched with GaAs and has a band gap I
A surface emitting semiconductor device characterized in that a GaInAsP layer having a bandgap in the middle of the bandgap of n 0.48 Ga 0.52 P is interposed.
JP11768294A 1994-05-06 1994-05-06 Surface emission semiconductor element Pending JPH0837340A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11768294A JPH0837340A (en) 1994-05-06 1994-05-06 Surface emission semiconductor element

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11768294A JPH0837340A (en) 1994-05-06 1994-05-06 Surface emission semiconductor element

Publications (1)

Publication Number Publication Date
JPH0837340A true JPH0837340A (en) 1996-02-06

Family

ID=14717686

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11768294A Pending JPH0837340A (en) 1994-05-06 1994-05-06 Surface emission semiconductor element

Country Status (1)

Country Link
JP (1) JPH0837340A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001022545A1 (en) * 1999-09-22 2001-03-29 Mitsubishi Chemical Corporation Luminous element and luminous element module
JP2011135104A (en) * 2011-04-01 2011-07-07 Ricoh Co Ltd Surface emitting laser element, surface emitting laser array equipped with the same, image forming apparatus equipped with surface emitting laser element or surface emitting laser array, optical pickup device equipped with surface emitting laser element or surface emitting laser array, optical transmission module equipped with surface emitting laser element or surface emitting laser array, optical transmission reception module equipped with surface emitting laser element or surface emitting laser array, and optical communication system equipped with surface emitting lase element or surface emitting laser array

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001022545A1 (en) * 1999-09-22 2001-03-29 Mitsubishi Chemical Corporation Luminous element and luminous element module
US7102174B2 (en) 1999-09-22 2006-09-05 Mitsubishi Chemical Corporation Light emitting device and light emitting device module
US7164157B2 (en) 1999-09-22 2007-01-16 Mitsubishi Chemical Corporation Light emitting device and light emitting device module
JP2011135104A (en) * 2011-04-01 2011-07-07 Ricoh Co Ltd Surface emitting laser element, surface emitting laser array equipped with the same, image forming apparatus equipped with surface emitting laser element or surface emitting laser array, optical pickup device equipped with surface emitting laser element or surface emitting laser array, optical transmission module equipped with surface emitting laser element or surface emitting laser array, optical transmission reception module equipped with surface emitting laser element or surface emitting laser array, and optical communication system equipped with surface emitting lase element or surface emitting laser array

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