JPH08298889A - Animal excretion treating agent having insecticidal function - Google Patents

Abstract

PURPOSE: To obtain an animal excretion treating agent with insecticidal action in the form of granules which comprises each prescribed amounts of organic waste, high water absorbing resin and a fumigatory pyrethroid insecticide, can be easily used for disposal of waste and can control the infestation of mites and fleas on the animal skins. CONSTITUTION: This treating agent comprises (A) an organic waste such as the coffee residue after extraction, used tea leaves, paper powder, wood powder and the like, (B) a less amount than (A) of a high water absorbing resin such as a cross-liked polyacrylic resin and (C) a less amount than (B) of a fumigatory pyrethroid insecticide such as empenthrin and is formed in granules.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION The present invention utilizes organic waste materials,
TECHNICAL FIELD The present invention relates to an animal excrement disposal material having an insect repellent function, and particularly when used at the time of excretion, to prevent pests adhering to the body of animals, especially pet animals for pets, from the body of animals or to prevent them from adhering to body of animals The present invention relates to an animal excrement disposal material having an insect repellent function.

[0002]

2. Description of the Related Art Tick and flea tend to attach to the body of animals, which may cause illness and the like, which is unhygienic when kept indoors. Therefore, in order to exterminate ticks and flea from the body of the animal, an earring or a collar containing an insect repellent material for exterminating the mites and flea is always attached to the ear or neck of the animal, and the tick is removed from the body of the animal. Exterminating flea.

[0003]

However, earrings and collars containing insect repellent materials are always used by attaching them to ears or necks, and earrings and collars containing such insect repellent materials are always used. If you put it on your ears or neck, it causes skin disorders such as redness and eczema, which is a problem.

On the other hand, with the increase in demand for coffee beverages such as canned coffee and instant coffee and beverages such as canned tea and instant tea, the extraction residue obtained by extracting these beverages, such as coffee grounds and tea leaves, is enormous. It is a huge problem in the beverage industry, such as coffee beverages, because the amount thereof is large and the treatment thereof is very expensive. In particular, since the coffee extract extract residue contains a large amount of fat, it is incinerated exclusively and is a problem. In the lumber and cypress lumber production process, a large amount of wood waste is produced in the hiba and cypress, but the hiba and cypress include hiba oil and hinokitiol. Since it has insect repellent and antiseptic functions and is hard to rot, it is difficult to dispose of, and it is hardly used, and it is incinerated at high expense, which is a problem.

Further, the used office paper is broken by a shredder or the like to generate a large amount of paper scraps, and a large amount of punch scraps generated when punching the office paper is incinerated at high cost. ing. In addition, the paper, foil, and paper tube that winds the fabric are made of paperboard and strong size paper,
It is discarded in large quantities after use and is incinerated at high cost because it has no use. Furthermore, in the disposable diaper and feminine sanitary products industries, with the increase in demand for disposable diapers and sanitary products, the amount of defective products produced during the production process of disposable diapers and sanitary products and waste paper powder produced during the production process is enormous. It is difficult to handle because it contains a highly water-absorbent resin, and it is hardly used, and it is discarded by incineration at high cost, which is a problem. The present invention solves the problems of waste disposal of wood chips such as hiba wood and cypress wood containing coffee extract extraction residue, tea leaves and / or paper powder, and hiba oil, and problems with conventional livestock insect repellent materials. The purpose is to do.

[0006]

The present invention uses an organic waste material such as paper powder, coffee extract extraction residue and / or tea husk, and wood chips such as hiba wood and / or cypress wood as a base material and has an insect repellent function. It is intended to provide a granular animal excrement disposal material.

[0007] That is, the present invention is characterized in that it is formed in a granular form by containing an organic waste material, a superabsorbent resin in a smaller amount than the organic waste material, and a transpirationable pyrethroid insect repellent. The animal excrement disposal material has
Further, the present invention, the organic waste material is mainly contained in the granulation portion, the superabsorbent resin and transpirationable pyrethroid insect repellent,
Insect repellent function, characterized in that it is contained in the granulation part and / or the coating layer part formed on the surface of the granulation part, and is formed in a granular form by the granulation part and the coating layer part. It is an animal excrement disposal material having.

Furthermore, in the present invention, the organic waste material is mainly contained in the granulation part, and the super absorbent polymer, the paper powder and the transpirationable pyrethroid insect repellent are present on the granulation part and / or on the surface of the granulation part. Contained in the coating layer part formed in
An animal excrement disposal material having an insect-repellent function, characterized in that it is formed in a granular form by the granulation part and the coating layer part. Contained in the super absorbent polymer, paper powder, transpirationable pyrethroid insect repellent and fungicide are contained in the granulation part and / or the coating layer part formed on the surface of the granulation part. The animal excrement disposal material having an insect repellent function is characterized in that the granulated portion and the coating layer portion are formed in a granular shape.

In the present invention, the animal excrement-treating material having an insect repellent function is formed into a granular material consisting of only the granulation portion or the granulation portion and the coating layer portion, and is made of organic waste material, and a small amount of high water absorption than the organic waste material. It can be formed by blending a small amount of a transpirationable pyrethroid insect repellent than the organic resin and the super absorbent polymer and granulating the mixture. In the animal excrement disposal material having the insect repellent function, as the organic waste material, coffee extract extraction residue, tea leaves, wood chips and / or paper powder are used. In the present invention, as the wood chips, the wood chips of the hiba wood and the Japanese cypress are used. Hiba or cypress wood scraps have an insect repellent function because they contain hiba oil and / or hinokitiol.
As the transpirationable pyrethroid insect repellent having an insect repellent function, for example, empensulin is used.

The transpirationable pyrethroid insect repellent empensulin used in the present invention has a contact poisoning action and is an insecticidal component, but it is relatively harmless to warm-blooded animals, so it is used as an insect repellent. It is used.
Empensulin acts on the body of an animal to drive out harmful insects such as mites and flea from the body of the animal, and its structural formula is represented by the following formula.

In the present invention, the granular animal excrement treating material having an insect repellent function is a granular part formed by granular granulation, that is, a granulation part and a coating covering the periphery of the granulation part. It can have a layer part and can be formed in a granular shape. The transpirationable pyrethroid insect repellent can be contained in the granulation part and / or the coating layer part. The content of empensulin in the transpirationable pyrethroid insect repellent is 0.05% by weight or more, preferably 0.4% by weight or more. However, transpirationable pyrethroid insect repellents are relatively expensive, and the content thereof is preferably 1% by weight or less. Empensulin is an insecticide that has an excellent insecticidal effect against harmful insects such as squid, hemlock beetle, white-flies, mites, mosquitoes, house flies and cockroaches. Can last.

In the present invention, the volatile pyrethroid, empensulin, is used as an insect repellent component in the animal excrement disposal material having an insect repellent function. In the present invention, in order to retain the insect repellent function, the animal excrement disposal material, a transpirationable pyrethroid, for example, empensulin,
It can be blended by dispersing or dissolving it in a non-alcoholic organic solvent such as an isoparaffin solvent, a hydrocarbon solvent, a halogenated hydrocarbon solvent or a solvent for esters.
By blending empensulin in this way, during excretion, the empensulin in the animal excrement disposal material having an insect repellent function evaporates and comes into contact with the animal's body during excretion, and drives off the harmful insects adhering to the animal's body. be able to. In this case, the empensulin may be blended in either the granulation part or the coating layer part covering the surface of the granulation part.

In the present invention, the animal excrement disposal material having an insect repellent function is one or more kinds of organic waste materials, a super absorbent resin and a transpirationable pyrethroid insect repellent in a much smaller amount than these, alone or in combination with other materials. It is produced by blending with insect repellent components, but when blending the transpirationable pyrethroid insect repellent alone, in a mixture of organic waste material and super absorbent resin, the transpiration pyrethroid insect repellent empensulin as a solvent. The dissolved solution is added and mixed by stirring, or in the granulating process of the mixture of the organic waste material and the superabsorbent resin, the empensulin solution in which empensulin is dissolved in a solvent is sprayed on the mixture. Alternatively, by impregnating or mixing the solvent solution of the empensulin with, for example, paper powder of an organic waste material, or by spraying or spraying the solvent solution of the empensulin on the paper powder of the organic waste material, or by adding the paper powder of the organic waste material to the solution. It is preferable that the solution is impregnated with a paper powder of an organic waste material and the paper powder impregnated with the empensulin is mixed with another organic waste material.

In the present invention, it is preferable to use paper powder in the organic waste materials together with other organic waste materials because the water retention and water absorption can be increased. In the present invention, among the organic waste materials, among the wood chips discharged from the sawmill, for example, the wood chips of the hiba wood and the wood chips of the cypress wood contain hinokitiol and hiba oil having insect repellent action,
In addition to the transpirationable pyrethroid insect repellent empensurin for animal excrement disposal materials, the repellent of the transpirationable pyrethroid insect repellent by adding waste materials of lumber such as Hiba wood waste and cypress wood waste. In addition to the action, insect repellent action of Hiba oil and / or hinokitiol is added,
It will increase the insect repellent effect.

Thus, when using, for example, Hiba wood scraps and cypress wood scraps containing hinokitiol and hiba oil as an insect repellent component with empensulin, the Hiba wood scraps and cypress wood scraps are used. In the case of a granulation portion by extrusion granulation, the powder is crushed to a particle size of 0.5 mm or less, preferably 0.3 mm or less in the case of a coating layer, or a uniform particle size, for example, in the case of a coating layer, and is mixed into an excretion-treating material. In this case, since the particles are crushed during the extrusion process, the particle size can be 5 mm to 3 mm. Further, in the present invention, the amount of the wood waste of the hiba wood and / or the wood waste of the cypress wood is 10% by weight or more of the granulation part, and in order to enhance the action as a repellent material for insects, 20
It is preferably at least wt%.

In the present invention, wood chips containing hinokitiol and / or hiba oil, such as Japanese cypress and hiba wood, have deodorant, insect repellent and peculiar fragrances, and therefore, not only the granulated part of the granulated product Occasionally, the animal excrement disposal material having an insect repellent function can also be provided with a deodorant function, an insect repellent function, and a fragrance function by also using the covering layer portion. In this way, by mixing the wood waste of the hiba or cypress into the excrement disposal material, the excrement prevention function of the animal excrement disposal material having the insect repellent function is enhanced,
It is preferable because the manufacturing cost can be reduced.

In the present invention, a substance having a bactericidal action can be added to the coating layer portion of the animal excrement disposal material having an insect repellent function in order to avoid the generation of mold during storage. Examples of such a substance having a bactericidal action include salt, sorbic acid or a salt thereof, calcium propionate,
There are fungicides, preservatives and antifungal agents such as sodium hypochlorite and / or benzoic acid or salts thereof. In the present invention, bentonite, zeolite or the like can be added as an auxiliary deodorant in an amount of 10% by weight or less. Further, in the present invention, in order to enhance the water retention function, it is preferable to add a highly water-absorbent resin as a water absorbing agent.

In the present invention, the animal excrement disposal material having an insect repellent function can prevent the development of mold during storage by drying so as to have a water content of 15% by weight or less. In the present invention, the superabsorbent resin enhances the water-retaining function of the mixture to be molded during molding of the animal excrement disposal material, and serves as a lubricant during granulation of the mixture to be molded. Added. In this case, the super absorbent polymer is 10% or less of the granulated product,
It is preferably 0.5 to 5% by weight. In the present invention, the granulation part of the animal excrement disposal material having an insect repellent function,
When a super absorbent polymer is used as a compounding substance, the super absorbent polymer absorbs water from the periphery of the granulation part during excretion, swells, and retains water, so that the humidity of the coated part can be adjusted. preferable.

In the present invention, a highly water-absorbent resin may be added to the animal excrement disposal material having an insect repellent function in order to maintain the water absorption. In this case, the super absorbent resin is a resin that can retain its shape even if it absorbs about tens to two hundred times its own weight of water, for example, a vinyl ester and an ethylenically unsaturated carboxylic acid or a derivative thereof. Copolymer saponification product, starch-acrylic acid graft polymer, polyacrylic acid cross-linked product, vinyl alcohol-acrylic acid copolymer, polyacrylonitrile partial hydrolyzate, carboxymethyl cellulose cross-linked product, polyethylene glycol There are cross-linked products, chitosan salts, pullulan gels and the like, and these are used alone or as a compounding substance by mixing two or more of them with an organic waste material.

In the present invention, the super absorbent resin is added in an amount that functions as a lubricant when a mixture of organic waste materials is granulated by a granulator. In the present invention, a defective resin can be used as a highly water-absorbent resin having a water absorption capacity of less than 200 g / g and poor water absorption performance. Such defective polyacrylic acid resin products having low water absorption performance include those having a particle size of 600 μm or more and fine particles having a particle size of 10 μm or less. These defective products are obtained, for example, by classifying waste diaper materials. Available as a non-standard product of polyacrylic acid resin. Defective products having a particle size of 600 μm or more are preferably used in the granulation part, and fine defective products having a particle size of 10 μm or less are preferably used in the coating part. As described above, since the waste material of the diaper contains the super absorbent resin, when the waste material of the diaper is used as the paper powder, the amount of the super absorbent resin added can be reduced accordingly. In the present invention, in order to impart an adsorption function to the animal excrement disposal material having the insect repellent function, the organic waste material may be granulated by selecting, for example, paper powder, coffee extract extraction residue and / or tea leaves. preferable.

Coffee Extract The extraction residue has a coffee odor and contains significant fat content. Since animals such as cats are relatively sensitive to these odors and the like, when using the coffee extract extraction residue, when using the excrement disposal material, the coffee odor is softened and the animal is given a dry and dry feel. Further, in order to prevent mold from occurring during long-term storage of the excrement treating material, in the present invention, the granules of the coffee extract extraction residue preferably have a water content of 15% by weight or less. More preferably, it is dried to 10% by weight or less and used as an animal excrement disposal material. In the present invention, bentonite, zeolite or the like can be added as an auxiliary deodorant in an amount of 10% by weight or less.

In the present invention, in order to avoid pulverization of the excrement disposal material at the time of use, it is preferable to mix the organic waste material with a compounding substance having an adhesive function. Such compounded substances include, as water-soluble or water-dispersible compounded substances, paper powder, papermaking pulp, papermaking sludge, pulp sludge, polyvinyl alcohol (PVA), wheat flour, starch, corn starch, carboxymethylcellulose (CMC), pullulan. Alternatively, there are gelatin and the like, and these can be used alone, or two or more kinds of them can be mixed and used as a compounding substance. Further, as the alcohol-soluble compounding substance, there are hydroxyethyl cellulose (HEC), hydroxypropyl cellulose (HPC), polyvinylpyrrolidone or (PVP), etc., and in this case as well, they are used alone or in combination with these 2 A mixture of two or more species can be used as a compounding substance.

In the present invention, the animal excrement treating material having an insect repellent function is, for example, 3 mm or more in order to avoid the presence of fine dust of organic waste materials such as coffee extract extraction residue, tea leaves, wood chips, and paper powder. Although it is preferable to granulate into granules having a particle size of, if granulating into particles having a particle size of 7 mm or more, for example, it becomes difficult to disperse from a toilet box into the room It is easy to collect and is preferable for keeping indoor hygiene. But in these cases,
It does not completely exclude the presence of particles of 3 mm or less and the presence of particles of 7 mm or less. In the present invention, the granulated product can be formed into various shapes such as spherical shape, columnar shape, granular shape and granular shape.

The animal excrement disposal material of the present invention, when the coffee extract extraction residue is contained as an organic waste material,
Since the appearance of the granulated product is brown, it looks unpleasant to use, and therefore the white powdery compounding substance is used in the granulation in an amount of 40% by weight or less, preferably 10% by weight or less. Prior to mixing with the coffee extract extraction residue, or by sprinkling on the surface of the granules of the coffee extract extraction residue, the color of the coffee grounds of the granulation, for example, the surface is almost white or close to white. It is preferable to alleviate it, for example.

In the present invention, for example, paper powder can be used as the white or substantially white compounded substance. As a white compound used with paper dust,
For example, a white substance such as corn starch, starch, bentonite, or zeolite can be mixed with the paper powder. Bentonite and zeolite are white and have adsorptive properties, and therefore, they are blended with an animal excrement treating material having an insect repellent function consisting of a granulated product of coffee extract extract residue, or an animal excrement having an insect repellent function. It is a preferable compounding substance in terms of dusting the surface of the treated material. Further, in the present invention, as a compounding substance for softening the brown color on the surface of the granulated product of the coffee extract extraction residue, there are dyes or pigments having an appropriate color such as titanium white.

Further, paper powder of a compounding substance to be attached to the surface of the animal excrement disposal material having an insect repellent function, which is composed of granules of coffee extract extraction residue, is attached together with a water-soluble or alcohol-soluble adhesive. In the case of allowing it to excrete, urine or the like adheres to the granulated product when excreted by the animal, but the parts to which the urine or the like adheres easily stick to each other to form a mass, which is preferable. In the present invention, the compounded substance to be compounded prior to granulation and the compounded substance to be attached to the surface of the granulated product can be the same or different.

In the present invention, the organic waste materials and the empensulin are mixed in the mixing device and granulated by the granulating device. As the granulating apparatus, a conventionally well-known extrusion granulating apparatus can be used. When granulating with an extrusion granulator, the organic waste material is crushed and granulated, so for example, in the case of paper powder that is relatively soft and difficult to absorb water, such as water-resistant punch scraps. For example, 4m
It is necessary to make the particle size smaller than m and smaller than the extrusion diameter, but paper powder having flexibility such as diaper waste material, or paper powder exhibiting flexibility by absorbing water such as paper tube. In this case, it is possible to extrude and granulate with a particle diameter of 10 mm or less, which is larger than the extrusion diameter.

However, in the present invention, the granulation can be carried out using various granulating apparatuses such as a pan type, a drum type and a fluidized bed type in addition to the extrusion granulating apparatus. In these granulators, the adhesion of the white powder to the surface of the formed granulated product is such that, when the granulated product is formed, for example, the white powder is directly adhered to the surface of the granulated product, or the white powder is attached. Can be changed to a solution or suspension and attached by spraying or the like. After granulation, the granulated product such as the organic waste material is blended on the surface of the granulated product by, for example, sprinkling a compounded substance having an adhesive ability, a super absorbent resin, a compounded substance having a bactericidal action or another compounded substance. It is preferred that the substance is attached and then dried so that it does not easily come off.

[0029]

In the present invention, the animal excrement treating material having an insect repellent function mainly contains organic waste materials such as coffee extract extraction residue having excellent deodorizing property and having a size of 3 mm or more, preferably 7 or more.
Since it is formed into a granulated product having a particle size of mm or more with a compound substance such as water-absorbent paper powder, superabsorbent resin, and transpirational empensulin of insect repellent, the absorption of urine excreted by animals is good, Further, it has a good water retention property, and is also excellent in that it can remarkably exhibit insect repellent properties against the animals used.

In addition, the animal excrement treating material having the insect repellent function of the present invention has paper powder and superabsorbent resin, and in addition, wheat flour, poval, starch or other adhesive ability especially in the coating portion. Since the compounded substance, or a substance having a bactericidal action or two or more of these compounded substances can be mixed and blended, the substance adheres to the animal excrement and wraps the excrement in a lump form, and the disposition is easy and easy. It's easy.
Further, when a deodorant and / or a water absorbing agent is mixed, the deodorizing property and the water absorbing property more excellent as an animal excrement disposal material having an insect repellent function are exhibited. Furthermore, when a substance having a bactericidal action is mixed, the animal excrement disposal material having an insect repellent function can be stored for a long period of time without generation of mold or the like.

[0031]

EXAMPLES Examples of embodiments of the present invention will be described below, but the present invention is not limited to the following description and examples. FIG. 1 is a schematic process drawing showing a process for producing an animal excrement disposal material having an insect repellent function according to one embodiment of the present invention.

In FIG. 1, a weighing hopper 1 for coffee extract and extraction residue is a conveyor belt 2 of a conveyor device.
Is provided on the conveyer belt 2 so as to be able to supply the coffee extraction liquid extraction residue. Further, the weighing hopper 3 for super absorbent resin is located on the conveyor path of the conveyor belt 4 of the conveyor device, and
It is provided so that the super absorbent resin can be supplied. Exit side 5 of conveyor belt 2 and exit side 6 of conveyor belt 4
Are provided opposite to each other on the conveyor belt 7 of the conveyor device for conveying the mixture of the coffee extract extraction residue and the super absorbent resin. The exit side 8 of the conveyor belt 7 for conveying the mixture of the coffee extract and the superabsorbent resin is located on the mixing device 9.

In this example, a weighing hopper 10 for paper dust
Is provided on the conveyor path of the conveyor belt 11 of the conveyor device so that paper powder can be supplied to the conveyor belt 11 of the conveyor device. The outlet side 12 of the conveyor belt 11 for supplying paper dust is located on the mixing device 9. In order to convey the mixture mixed in the mixing device 9, a conveyor belt 14 for conveying the mixture is provided at the mixture outlet 13 of the mixing device 9, and the coffee extract extraction residue,
The super absorbent resin and the paper powder are mixed in the mixing device 9, and the mixture is supplied from the outlet 13 of the mixing device 9 to the conveyor belt 14 of the conveyor device for conveying the mixture and extruded from the conveyor belt 14 for conveying the mixture. It is supplied to the premixing device 16 of the granulating device 15.

In the pre-mixing device 16, a non-alcoholic organic solvent solution of empensulin is supplied from the supply pipe 17 to the pre-mixing device 16 in addition to the coffee extract extraction residue and the superabsorbent resin. The liquid extraction residue, the high-grade aqueous resin, the paper powder and the empensulin are mixed uniformly. The mixture of the coffee extract liquid, the highly water-absorbent resin, and the paper powder supplied with the empensulin is introduced into the extrusion granulator 15 and extruded from the die 18 side as a columnar granule. Below the die 18 of the granulating device 15, a conveyor belt 20 of a conveyor device for conveying the granulated product for sending the extruded granulated product to the circular sieve 19 is provided.

In this example, the opening of the circular sieve 20 is 4
mm, the sieving particles exit the sieving outlet 21 and are supplied to a conveyor belt 22 of a conveyor device for conveying sieving particles connected to the sieving outlet 21. The conveyor belt 22 for transporting the particles on the sieve is connected to the vibration type particle sizer 23.
The vibration type particle sizer 23 is for loosening granulated materials that adhere to each other by vibrating them, and is provided to minimize powdering during use. The on-screen particles are supplied to the vibration type particle sizer 23 by the conveyor belt 22 for transportation. On the other hand, the sieved particles of the circular sieve 19 are returned to the granulator 15 by the conveyor belt 25 for conveying sieved particles provided at the outlet 24 for sieves, through the conveyor belt 14 for conveying the mixture, and again. Granulated.

The granulated product sent to the vibration type particle sizer 23 is loosened to one particle by the vibration of the vibration type particle sizer 23 and sent out. In this example, on the outlet side of the vibration sizing machine 23,
A sieve 26 having an opening of 4 mm is provided. This sieve 2
Below the sieving outlet of 6, a below-sieving conveyor belt 27 that is connected to the conveyor belt 14 for conveying a mixture is provided. Conveyor belt for conveying mixture 14
After that, it is returned to the extrusion granulator 15 and granulated again.

In the vibration type particle sizer 23, particles having a particle size of 4 mm or more are carried out from a conveyor belt 29 of a conveyor device for carrying over a sieve connected to a sieve outlet 28. The exit of the conveyor belt 29 for conveying on the sieve is connected to the first granule coating device 30. In the vibration sieving machine 23, particles having a particle size of 4 mm or more are carried out from a conveyor belt 29 for carrying over the sieve connected to the sieve outlet 28 in order to coat the surface with the super absorbent resin and the paper powder. It It is supplied to the sieve 31 of the first granule coating device 30 connected to the conveyor belt 29 for conveying on the sieve.

In this example, the first and second granule coating devices 30 and 32 are both vibration type coating devices and are provided in series. The sieving device 33 at the outlet of the first granule coating device 30 has its outlet connected to the second granule coating device 32. A first spraying sieve 34 having an outlet is provided on the vibrating coating transport path of the first granule coating device 30, and a spray nozzle is provided on the vibrating coating transport path of the second granule coating device 32. A second spraying device 35 for spraying is provided at the opening. From the first spraying screen 34, a mixture of highly water-absorbent resin and paper powder is sprayed, and a second spraying device 35 for spraying.
A polyvinyl alcohol diluting solution is sprayed from.

In each of the granule coating devices, the coating material is sprayed on the vibrating granules to coat the granules.
The first spraying sieve 34 is connected to a hopper 36 for spraying a first coating material in which a mixture of a highly water-absorbent resin and paper powder is put, and a spraying device 35 for a second spraying is a coating containing a polyvinyl alcohol diluent. It is connected to the liquid tank 37. The spray screen and spray device for spraying, a coating material for spraying,
It is formed so that it can be always sprayed at a constant ratio to the granulated product.

A conveyor belt 38 of a conveyor device for conveying coated granules is connected to the second granulated substance coating device 32, and the granules coated by the second granulated substance coating device 32 are provided. The granules are sent by the coated granule transport conveyor belt 38 to the drying device 39 connected to the coated granule transport conveyor belt 38. The coated granules are introduced into a drying device 39, for example, a hot air dryer, and dried,
The product is sent to the product tank 42 by a conveyor belt 41 for carrying the dried granulated product, which is connected to the dried product outlet 40. The product of the dry granulated product is taken out to the bagging area 44 by the conveyor belt 43 of the conveyor device for carrying out the product, which is provided below the outlet below the product tank 42, and is packed and shipped.

Since the apparatus of this example is constructed as described above, a predetermined amount of coffee extraction liquid extraction residue is put in the weighing hopper 1, and a predetermined amount of super absorbent resin is weighed in the hopper 3.
Then, a predetermined amount of paper powder is put into the weighing hopper 11. Therefore, the conveyor belt 2 for supplying the coffee extract and the extraction residue, the conveyor belt 4 for supplying the super absorbent resin,
Conveyor belt 7 and conveyor belt 11 for supplying paper dust
Are operated to supply a predetermined amount of coffee extract extraction residue, superabsorbent resin and paper powder to the mixing device 9, respectively, and mix them.

The mixture of the coffee extraction liquid extraction residue, the super absorbent resin and the paper powder thus mixed is sent out to the operating conveyor belt 9 for carrying the mixture, and sent to the premixing device 16. To the premixing device 16, a non-alcoholic organic solvent solution of empensulin is supplied from the supply pipe 12 in addition to the coffee extract extraction residue, the superabsorbent resin and the paper powder. In the pre-mixing device 16, the coffee extract extraction residue, the high-grade aqueous resin, the paper powder and the empensulin are uniformly mixed, and the uniformly mixed mixture is
It is sent to the extrusion granulator 15.

In this example, the extrusion granulator 15 pushes the mixture to be granulated by rotating the screw,
Particles having a cross section corresponding to the holes of the die 18 and a length corresponding to the thickness of the die 18 are obtained. In this example,
A cylindrical granulate with a diameter of 6 mm and a length of 10 mm is obtained. The granules particles extruded from the die 18 of the extrusion granulator 15 are sent from the conveyor belt 20 for conveying granules to, for example, a circular sieve 19 having a mesh opening of 4 mm and sieved. The granulated product having a particle size of 4 mm or less under the sieve is returned to the conveyor belt 14 for carrying the mixture by the conveyor belt 25 for carrying the undersize particle, and the granulator 1
It is sent to No. 5 and granulated again.

The sieve particles having a particle size of 4 mm or more are oscillated by the conveyor belt 22 for conveying the sieve particles.
The particles having a particle diameter of 4 mm or more, which have been sent to No. 3 and have been loosened, are sent to the first granule coating device 30 by the conveyor belt 29 for conveying on the sieve of the sieve 26, and the superabsorbent resin there. And, a coating material in which paper powder is mixed in a predetermined amount is sprinkled and coated. On the other hand, the particles having a particle size of less than 4 mm loosened by the vibration sieving machine 28 are sent from the sieving outlet of the sieve 31 by the sieving conveying conveyor belt 27 to the conveyor belt 14 for conveying the mixture, and granulated. It is returned to the apparatus 15 and granulated again.

The granule particles coated with the first coating material in the first granule coating apparatus 30 are the same as the first granule coating apparatus 3.
0 outlet sieving device 33 to second granule coating device 32
And is sprayed with the coating diluent of the second coating material. The granule particles sprayed with the coating diluent are discharged from the sieving device 38 at the outlet of the second granule coating device 32 to the dryer 3
9 and dried. The temperature of the dryer 39 is 100 ° C
It is kept at the above temperature. The dried granulated product is transferred to the product tank 42 by the conveyor belt 41 for conveying the dried granulated product.
Will be sent to and shipped as a product.

In this example, the product is obtained after drying. However, a non-alcoholic organic solvent solution of volatile empensulin and a dilute solution of polyvinyl alcohol can be sprayed after drying. In this case, a diluting solution of polyvinyl alcohol and a non-alcoholic organic solvent solution of volatile empenseline may be separately formed and sprayed.

In the present example, the granulation part is blended with an insect repellent. For example, a non-alcohol organic solvent of empensulin is blended with superabsorbent resin or paper powder and mixed with hiba wood. be able to. In this case, it is preferable to increase the amount of the super absorbent polymer and to dry it under weak drying conditions. In this example, tea leaves and wood flour are not used, but tea leaves and / or wood flour may be used in place of part or all of the paper dust or coffee extract extraction residue.

Example 1. 28.3% by weight of the extraction residue, ie, coffee grounds (water content 65% by weight) on a dry basis, and a superabsorbent resin on a dry basis, were added to the roasted coffee beans ground product by adding water to extract the coffee extract. .9% by weight, paper powder on a dry basis 31.5% by weight, benzoic acid 0.4% by weight
And 31.5% by weight of water and 0.4% by weight of empensulin were placed in a mixer and mixed. The mixture was put into the extrusion part of an extrusion granulator, extruded through a rotary die having a plurality of openings with a diameter of 6 mm, and appropriately cut with a chopper to granulate. The granulated product was dried with a hot air dryer until the water content became 15% or less, to obtain a granular product having an average diameter of 5 mm and a length of 6 to 15 mm. This granular material was collected and used as sand for cat litter. In the room, the sand for cat litter was used. It was possible to control the mites and fleas parasitic on cats during repeated use. In the room, 50 ml of ammonia water diluted to 20 times the temperature of 35 ° C. was added to the cat litter sand, but the water absorption and deodorizing property were very good, and no ammonia odor was felt in the room. In addition, I used this cat litter for the cat litter with a thickness of 3 cm, but I used the cat litter as usual,
There was no problem in use. After the cat has used it for excretion, the part of this cat litter sand that the cat excreted is:
I was able to take it out easily. Moreover, the cat litter for cats of this example had water absorbency and deodorant property, and it was possible to avoid generating an unpleasant odor indoors.

Example 2. Based on the dry base obtained in Example 1, 25.2% by weight of coffee grounds, 0.4% by weight of benzoic acid, 4.4% by weight of super absorbent resin Hymosab 500 (registered trademark) manufactured by Hymo Co., and 32 of paper powder. 0.6% by weight, 0.4% by weight of empensulin and 37% by weight of water were placed in a mixer and mixed. The mixture was put into an extruding section of an extrusion granulator, extruded through a screen having a plurality of openings having a diameter of 6 mm, and appropriately cut by a chopper to granulate. A mixture of 87% by weight of paper powder and 13% by weight of a super absorbent polymer is sprinkled on the granulated product so as to be 15% by weight based on the granulated product, and a 10-fold diluted polyethylene glycol diluted solution is sprayed thereon. did. The granulated product is dried with a hot air dryer until the water content becomes 13%, and the average diameter is 6 mm and the length is 6 to 15 mm.
To obtain granules of. This granular material was collected and used as sand for cat litter. In the room, the sand for cat litter was used. It was possible to control the mites and fleas parasitic on cats during repeated use. In the room, 50 ml of ammonia water diluted to 20 times the temperature of 35 ° C. was added to this cat litter sand, but it had strong water absorption and deodorant properties, and no ammonia odor was felt in the room. Further, the sand for cat's toilet was laid on the cat's toilet to a thickness of 3 cm and used, but the cat used it as a toilet as usual, and there was no problem in using it. After the cat used it for excretion, the part of the cat litter sand that the cat excreted could be easily removed. Moreover, the sand for the cat's toilet in this example is
It was excellent in water absorption and deodorization, and it was possible to avoid generating an unpleasant odor indoors.

Example 3. 5. Tea cups (water content: 75% by weight) on a dry basis of 22.75% by weight, and on a dry basis, a super absorbent polymer Hymo Sub 500 (registered trademark) manufactured by Hymo Co., Ltd.
0 wt%, 29.6 wt% paper powder on a dry basis, 0.2 wt% empensulin, 0.2 wt% sodium benzoate and 42.25 wt% water were placed in a mixer and mixed.
The mixture is extruded and put into the extruding part of the granulator, and the diameter is 6 m.
It was extruded through a screen having a plurality of openings of m, and appropriately cut with a chopper to granulate. Add 0.3 to this granule.
60% by weight of paper powder crushed to mm or less and particle size of 30μ
m A mixture of 40% by weight of super absorbent polymer was sprinkled so as to be 12% by weight with respect to the granulated product, and a 10-fold diluted polyethylene glycol diluted solution was sprayed thereon. The sprayed granules were dried with a hot air dryer until the water content became 15%, to obtain granules having an average diameter of 6 mm and a length of 6 to 15 mm. This granular material was collected and used as sand for cat litter. In the room, the sand for cat litter was used. It was possible to control the mites and fleas parasitic on cats during repeated use. Inside the room, sand 3 for this cat's toilet
Although 50 ml of ammonia water diluted to 20 times the temperature of 5 ° C. was added, it had strong water absorption and deodorizing properties, and no ammonia odor was felt in the room. Further, the sand for cat's toilet was laid on the cat's toilet to a thickness of 3 cm and used, but the cat used it as a toilet as usual, and there was no problem in using it. After the cat had used it for excretion, the toilet sand of the cat could be easily taken out because the part excreted by the cat was lumpy. Moreover, it has excellent water absorption and deodorant properties,
It is possible to avoid generating an unpleasant odor indoors.

Example 4 44.6% by weight of wood powder crushed to a particle size of 4.1 mm on a dry basis, 8% by weight of a super absorbent polymer Hymosab 500 (registered trademark) manufactured by Hymo Co., Ltd. on a dry basis, and a dry basis. Then, 10% by weight of paper powder, 0.4% by weight of empensulin and 37% by weight of water were put into a mixer and mixed. The mixture is put into the extruding section of an extrusion granulator and extruded through a screen having a plurality of openings with a diameter of 6 mm,
Granulated by cutting appropriately with a chopper. In this granulated product,
A mixture of 60% by weight of paper powder pulverized to 0.3 mm or less and 40% by weight of a super absorbent polymer having a particle size of 30 μm so as to be 12% by weight with respect to the granulated product, and 10 times diluted polyethylene glycol The diluted solution was sprayed. The granulated product was dried with a hot air dryer until the water content became 15% to obtain a granular product having an average diameter of 6 mm and a length of 6 to 15 mm. This granular material was collected and used as sand for cat litter. In the room, the sand for cat litter was used. It was possible to control the mites and fleas parasitic on cats during repeated use. Inside the room, sand 3 for this cat's toilet
Although 50 ml of ammonia water diluted to 20 times the temperature of 5 ° C. was added, it had strong water absorption and deodorizing properties, and no ammonia odor was felt in the room. Further, the sand for cat's toilet was laid on the cat's toilet to a thickness of 3 cm and used, but the cat used it as a toilet as usual, and there was no problem in using it. After the cat had used it for excretion, the toilet sand of the cat could be easily taken out because the part excreted by the cat was lumpy. Moreover, it has excellent water absorption and deodorant properties,
It is possible to avoid generating an unpleasant odor indoors.

Example 5. Tea leaf with a moisture content of 75% by weight on a dry basis is 17.5% by weight, and a coffee extract extraction residue with a moisture content of 65% by weight is on a dry basis of 17.2% by weight. Trademark) 7.
2% by weight, 45.2% by weight of paper powder on a dry basis, 0.2% by weight of sodium benzoate, 0.2% by weight of empensulin
And 36% by weight of water were placed in a mixer and mixed. The mixture was put into an extruding section of an extrusion granulator, extruded through a screen having a plurality of openings having a diameter of 6 mm, and appropriately cut by a chopper to granulate. A mixture of 60% by weight of paper powder crushed to 0.3 mm or less and 40% by weight of a super absorbent polymer having a particle size of 30 μm is sprinkled on the granulated product so that the mixture becomes 12% by weight based on the granulated product. A 2-fold diluted polyethylene glycol diluted solution was sprayed. The granulated product is dried with a hot air dryer until the water content becomes 15%, and the average diameter is 6 m.
Granules having a length of m and a length of 6 to 15 mm were obtained. This granular material was collected and used as sand for cat litter. In the room, the sand for cat litter was used. It was possible to control the mites and fleas parasitic on cats during repeated use. In the room, 50 ml of ammonia water diluted to 20 times the temperature of 35 ° C. was added to this cat litter sand, but it had strong water absorption and deodorant properties, and no ammonia odor was felt in the room. Also, this cat litter for cat litter has a thickness of 3
The cat was used as a toilet as usual, and there was no problem in using it. After the cat had used it for excretion, the toilet sand of the cat could be easily taken out because the part excreted by the cat was lumpy. Moreover, it is excellent in water absorption and deodorizing property, and it is possible to avoid generation of an unpleasant odor indoors.

In these examples, organic waste materials such as coffee extract extraction residue, tea leaves, wood powder, and paper powder are used, but some of these organic waste materials can be replaced with other organic waste materials. When a wet organic waste material is used as a raw material, it is not necessary to supply water from the outside as long as it can be granulated by the contained water. However, when the water content is higher than necessary, it is preferable to add the same or another organic waste material that has been dehydrated or dried to adjust the water content.

[0054]

EFFECTS OF THE INVENTION The present invention relates to an animal excrement treating material having an insect repellent function, which is mainly made of organic coffee waste such as roasted coffee bean extract residue, tea leaves, various paper powders and wood powders.
It contains super absorbent resin and insect repellent empensulin and is molded into particles with a particle size of 3 mm or more. Therefore, it is treated as a waste material compared to conventional animal excrement disposal materials. In addition, the waste material of organic matter can be effectively used, and at the time of excretion, the insect repellent empenthrin vapor comes into contact with the body of the animal, and it is possible to destroy mites and flea that are parasitic on the skin of the animal. In addition, compared to animal insect control collars, etc., they only contact the animal's body during excretion,
It does not cause skin disorders such as redness and eczema. further,
Since all of the organic waste materials used as raw materials are combustible materials, the waste treatment materials after use can be easily incinerated as flammable wastes, which is a waste compared to conventional waste treatment materials. Easy to process.

As described above, according to the present invention, as compared with the conventional animal waste treatment materials, the problems relating to the disposal of organic waste materials such as the coffee extract extraction residue of roasted coffee beans and the conventional use. It solves all the problems of waste treatment related to the non-flammability of used animal excrement disposal materials, and it also eliminates harmful insects that parasitize the skin of animals. It is significant in terms of cost reduction and environmental waste treatment.

[Brief description of drawings]

FIG. 1 is a schematic flow process chart showing a process for producing an insect repellent material according to an embodiment of the present invention.

[Explanation of symbols]

1 Coffee extract liquid Measuring hopper for extraction residue 2 Conveyor belt of conveyor device for supplying coffee extract liquid extraction residue 3 Measuring hopper of super absorbent resin 4 Conveyor belt of conveyor device for supplying super absorbent resin 5 Coffee extract liquid extraction Conveyor belt outlet for residue supply 6 Conveyor belt outlet for super absorbent resin supply 7 Conveyor belt for transporting a mixture of coffee extract residue and super absorbent resin 8 Exit side of conveyor belt 7 Mixing device 10 Paper hopper for paper powder 11 Conveyor belt of conveyor device for paper powder supply 12 Exit side of conveyor belt 11 Mixer outlet of mixing device 14 Conveyor belt for conveying mixture 15 Extrusion granulator 16 Premixing device 17 Empensulin Of non-alcoholic organic solvent solution supply 18 dies 19 circular sieve 20 Conveyor Belt of Conveyor Device for Conveying Granules 21 Sieve Outlet of Circular Sieve 14 22 Conveyor Belt of Conveyor Device for Conveying Sieve Particles of Circular Sieve 14 23 Vibratory Sizing Machine 24 Circumferential Exit of Circular Sieve 14 25 Conveyor Belt of Conveyor Device for Conveying Particles Under Circular Sieve 14 26 Sieve 27 Conveyor Belt of Conveyor Device for Conveying Sieve 26 28 Upper Exit of Sieve 26 29 Conveyor Device for Conveying Sieve 26 Conveyor belt 30 First granule coating device 31 First granule coating device 30 inlet sieve 32 Second granule coating device 33 First granule coating device 30 outlet sieve Device 34 Spraying screen of first granule coating device 30 35 Spraying device for second spraying 36 Hopper for spraying first coating material 37 Coating liquid tank 38 Conveyor of conveyor device for transporting coating granules Belt 39 drying device 40 dry product outlet 41 dry granulation conveyor belt 44 bags stuffed area of the conveyor device of the conveyor belt 42 the product tank 43 for products unloading conveyor device for conveying

Claims (6)

[Claims] 1. A granular material containing an organic waste material, a superabsorbent resin in an amount smaller than that of the organic waste material, and a transpirationable pyrethroid insect repellent in an amount less than that of the superabsorbent resin. An animal excrement disposal material having a characteristic insect repellent function. 2. The organic waste material is mainly contained in the granulation part, and the super absorbent polymer and the transpirationable pyrethroid insect repellent are
Insect repellent function, characterized in that it is contained in the granulation part and / or the coating layer part formed on the surface of the granulation part, and is formed in a granular form by the granulation part and the coating layer part. Animal excrement disposal material having. 3. The organic waste material is mainly contained in the granulation part, and the superabsorbent resin, paper powder and transpirationable pyrethroid insecticide are formed on the granulation part and / or on the surface of the granulation part. An animal excrement disposal material having an insect repellent function, which is contained in the coating layer portion and is formed in a granular shape by the granulation portion and the coating layer portion. 4. The waste organic material is contained mainly in the granulation part, and the superabsorbent resin, paper powder, transpirationable pyrethroid insect repellent and antifungal agent are contained in the granulation part and / or on the surface of the granulation part. An animal excrement disposal material having an insect repellent function, which is contained in the formed coating layer portion and is formed in a granular shape by the granulation portion and the coating layer portion. 5. The animal excrement having an insect repellent function according to any one of claims 1 to 4, wherein the organic waste material is coffee liquid extraction residue, tea leaves, paper powder, or wood powder. Processing material. 6. The organic waste material used is at least two of coffee liquid extraction residue, tea leaves, paper powder, and wood powder, and any one of claims 1 to 4 is characterized. Animal excrement disposal material with insect repellent function.