JPH08277210A - Deodorant composition for perming - Google Patents

Abstract

PURPOSE: To remove an unpleasant smell from an agent for perming by using a specific natural essential oil. CONSTITUTION: This composition contains at least one of natural essential oil obtained from Foeniculum vulgare Mill., Citrus sinensis Osbeck or Citrus aurantium subsp. amara, Caryophyllata Thunb., Pinus spp., Mentha arvensis L., Eucalyptus globulus Labill, Rosmarinus officinalis L. and Antheis nobilis L. The essential oil obtained from the Citrus sinensis Osbeck or Citrus aurantium subsp. amara in the natural essential oil has especially high effects and a citrus refreshing aroma and is extremely readily usable. Among them, the essential oil obtained from Citrus sinensis f. valencia has the highest effects. The content of the natural essential oil in the composition is 0.01-1.00wt.% based on the total amount.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a deodorizing composition for permanent wave for removing unpleasant odor of hair generated by using a permanent wave agent containing a mercapto compound.

[0002]

2. Description of the Related Art Conventionally, a treatment with a permanent wave agent is performed by a first agent containing a reducing agent and a second agent containing an oxidizing agent.
It is carried out with the agent. As the reducing agent of the first agent, thioglycolic acid or a salt thereof, or a mercapto compound such as cysteine is used. When treated with a permanent waving agent using this mercapto compound, it is accompanied by an unpleasant odor, and the unpleasant odor remains on the hair,
It cannot be removed by washing with shampoo several times.

When the hair is damp or sweats,
The unpleasant odor was particularly remarkable when blown, and the subject was not satisfied with the odor. The cause of the unpleasant odor due to the permanent wave treatment is that free SH groups in the hair generated during the permanent wave treatment are decomposed into mercapto compounds such as hydrogen sulfide and methyl mercaptan. It is also due to the fact that the mercapto compound in the agent is fairly strongly adsorbed on the hair keratin and cannot be completely removed by rinsing with water.

As a method of eliminating the unpleasant odor of such permanent wave treatment, there is a masking method.
This is a method of perfuming a strong fragrance to a permanent waving agent or a hair treatment agent, and sensuously reduces unpleasant odor. However, this method cannot completely remove the unpleasant odor. Further, even if the unpleasant odor derived from the mercapto compound is reduced, the fragrance of the fragrance itself remains persistent on the hair, and it is often disliked in terms of palatability.

Therefore, it is necessary to add a deodorant component to the permanent waving agent (Japanese Patent Laid-Open No. 63-13051).
6) and the development of a deodorizing composition for permanent wave (Japanese Patent Laid-Open No. 4-247013) have been tried, but they are not always satisfactory although they can alleviate the unpleasant odor to some extent.

[0006]

In view of the above circumstances, the present invention provides a deodorant composition for permanent wave, which completely removes the unpleasant odor of hair caused by the use of a permanent wave agent containing a mercapto compound. The purpose is to do.

[0007]

Means for Solving the Problems As a result of intensive studies to achieve the above object, the present inventors have found that fennel,
In order to complete the present invention, it was found that natural essential oils obtained from orange, clove, pine, mint, eucalyptus, mannen wax, and Roman chamomile almost completely remove the unpleasant odor of hair caused by the use of a permanent waving agent. I arrived. That is, the present invention is a deodorant composition for permanent wave, containing at least one natural essential oil obtained from fennel, orange, clove, pine, peppermint, eucalyptus, mannen wax, and Roman chamomile.

In the present invention, natural essential oils obtained from the above plants are used. Generally, fennel is fruit, clove is bud or leaf, pine is wood or balsam,
Essential oils are obtained by steam-distilling the above-ground parts of mint, leaves of eucalyptus, fresh leaves of mannen wax, apexes and flowers, and dried flower heads of Roman chamomile, and squeezing the peel of orange.

The content of the natural essential oil in the composition of the present invention is 0.01 to 1.00% by weight based on the total amount,
It is preferably 0.05 to 0.25% by weight. 0.01
If it is less than 10% by weight, the effect cannot be expected so much, and 1.0
If it exceeds 0% by weight, the scent is too strong and it is not preferred in terms of taste.

Among the above-mentioned natural essential oils of the present invention, the essential oil obtained from orange is particularly effective. The essential oil obtained from orange is a citrus fruit, has a refreshing fragrance, and is an extremely easy-to-use essential oil. Essential oils obtained from orange oil are roughly classified into sweet orange oil (sweet).
orange oil; an essential oil obtained from sweet orange) and bitter orange oil (bitter)
orange oil; bitter orange
essential oil obtained from oil), but sweet orange oil is more effective. Among them, the essential oil obtained from Valencia orange is the most effective.

The deodorant composition for permanent wave of the present invention contains, in addition to the above-mentioned essential essential oil, essential essential oils, optional components that are usually used, if necessary, within a range that does not impair the effects of the present invention. Can be used, aqueous type,
It can be adjusted to an appropriate form such as an emulsion type, a cream type and a foam type. Specific examples include any form used for hair such as permanent wave 1 agent, permanent wave 2 agent, hair rinse, hair treatment, hair cream and the like.

The unpleasant odor caused by the permanent waving agent includes unpleasant odor during the treatment of the permanent waving agent and unpleasant odor after the treatment. The unpleasant odor after the treatment remains on the hair and cannot be removed by washing with shampoo several times. . The embodiment is roughly divided into two types according to the removal stage. One is to remove the unpleasant odor associated with the permanent wave treatment. Either the permanent wave 1 agent or the permanent wave 2 agent uses the deodorant composition for permanent wave containing the natural essential oil used in the present invention. To do. In this case, of course, no unpleasant odor remains on the hair, so that there is no unpleasant feeling during shampooing.

The other is to remove the unpleasant odor after the permanent wave treatment. Permanent wave treatment is usually performed in a beauty salon or the like, but for the convenience of the menu, it may be treated with a normal permanent wave agent. At that time, an unpleasant odor remains on the hair. As its removal, a deodorant for permanent wave in which a natural essential oil used in the present invention is added to a hair rinse, a hair treatment or the like used immediately after the permanent treatment or after several days have passed, or a hair cream or the like used as a finishing agent. Use the composition. In other words, the deodorant composition for permanent wave of the present invention can remove unpleasant odor after use without or without rinsing.

[0014]

The present invention will be described in more detail below with reference to examples, but the present invention is not limited thereto. In addition, in the formulations shown in Tables 1 to 20, the numerical value of each component represents% by weight. Also, 50% ammonium thioglycolate is 50% as thioglycolic acid.
% Aqueous solution.

The unpleasant odor was sensory evaluated based on the following criteria. I feel an unpleasant odor ・ × × I feel a little unpleasant odor ・ ・ ・ ・ △ I hardly notice an unpleasant odor ・ ・ ・ ・ 〇 I do not feel any unpleasant odor ・ ・ ・ ・ ◎

(Examples 1 to 64, Comparative Examples 1 to 16) Table 1
According to the formulations shown in to 8, the permanent waving agent using the deodorant composition of the present invention was prepared, the permanent waving treatment was performed, and the unpleasant odor during and after the treatment was sensory evaluated. The evaluation results are shown in Tables 1-8. In the prescription, fennel oil is fennel, orange oil is orange, clove oil is clove, turpentine oil is pine, mint oil is mint, eucalyptus oil is eucalyptus, rosemary oil is mannen wax, and Roman chamomile oil is obtained from Roman chamomile. It is a natural essential oil.

[0017]

[Table 1]

[0018]

[Table 2]

[0019]

[Table 3]

[0020]

[Table 4]

[0021]

[Table 5]

[0022]

[Table 6]

[0023]

[Table 7]

[0024]

[Table 8]

(Comparative Examples 17 to 26) Permanent wave agents were prepared according to the formulations shown in Table 9, and were subjected to permanent wave treatment, and the unpleasant odor during and after the treatment was sensorially evaluated. The evaluation results are shown in Table 9. The fragrance in the formulation has been used as a masking fragrance, which is said to have a great effect.

[0026]

[Table 9]

Comparative Example 27 A permanent waving agent was prepared according to the formulation shown in Table 10 and subjected to a permanent waving treatment, and the unpleasant odor during and after the treatment was sensorially evaluated. The evaluation results are shown in Table 10.

[Table 10]

(Examples 65 to 96, Comparative Examples 28 to 35)
Hair treatments using the deodorant composition of the present invention were prepared according to the formulations shown in Tables 11 to 14 and used after the permanent wave treatment, and the unpleasant odor was sensory evaluated.
The evaluation results are shown in Tables 11-14. In the prescription, fennel oil is fennel, orange oil is orange, clove oil is clove, turpentine oil is pine, mint oil is mint, eucalyptus oil is eucalyptus, rosemary oil is mannen wax, and Roman chamomile oil is obtained from Roman chamomile. It is a natural essential oil.

[0029]

[Table 11]

[0030]

[Table 12]

[0031]

[Table 13]

[0032]

[Table 14]

(Comparative Examples 36 to 40) Hair treatments were prepared according to the formulations shown in Table 15 and used after the permanent wave treatment, and the unpleasant odor was sensory evaluated. The evaluation results are shown in Table 15. The fragrance in the formulation has been used as a masking fragrance, which is said to have a great effect. (Comparative Example 41) According to the formulation shown in Table 15, Examples 65-
A hair treatment was prepared in the same manner as in 96 and Comparative Examples 28 to 35 and used after the permanent wave treatment, and the unpleasant odor was sensory evaluated. The evaluation results are shown in Table 15.

[0034]

[Table 15]

(Examples 97 to 128, Comparative Examples 42 to 4)
9) A hair cream using the deodorant component of the present invention was prepared according to the formulations shown in Tables 16 to 19 and used after the permanent wave treatment, and the unpleasant odor was sensory evaluated. The evaluation results are shown in Tables 16 to 19. In the prescription, fennel oil is fennel, orange oil is orange, clove oil is clove, turpentine oil is pine, peppermint oil is mint,
Eucalyptus oil is a eucalyptus oil, rosemary oil is a mannose wax, and Roman chamomile oil is a natural oil obtained from Roman chamomile.

[0036]

[Table 16]

[0037]

[Table 17]

[0038]

[Table 18]

[0039]

[Table 19]

Comparative Examples 50 to 54 Hair creams were prepared according to the formulations shown in Table 20, used after the permanent wave treatment, and unpleasant odor was evaluated organoleptically. The evaluation results are shown in Table 20. The fragrance in the formulation has been used as a masking fragrance, which is said to have a great effect. (Comparative Example 55) A hair cream was prepared according to the formulation shown in Table 20, used after permanent wave treatment, and the unpleasant odor was sensory evaluated. The evaluation results are shown in Table 20.

[0041]

[Table 20]

As is clear from Tables 1 to 10, the deodorant composition for permanent wave of the present invention can remove the unpleasant odor peculiar to the mercapto compound during and after the perm treatment. Further, as is clear from Tables 11 to 20, the deodorant composition for permanent wave of the present invention can remove the unpleasant odor peculiar to the mercapto compound after the perm treatment.

[0043]

As is apparent from the examples, the deodorant composition for permanent wave of the present invention can sufficiently remove the unpleasant odor of hair generated by the use of the permanent wave agent, and has a commercial value. It is extremely expensive.

Claims (2)

[Claims] 1. A deodorant composition for permanent wave, which comprises at least one natural essential oil obtained from fennel, orange, clove, pine, peppermint, eucalyptus, mannen wax, and chamomile. 2. The deodorant composition for permanent wave according to claim 1, wherein the natural essential oil obtained from orange is sweet orange oil.