JPH08259344A - Porous adsorbing material - Google Patents
Porous adsorbing materialInfo
- Publication number
- JPH08259344A JPH08259344A JP7070127A JP7012795A JPH08259344A JP H08259344 A JPH08259344 A JP H08259344A JP 7070127 A JP7070127 A JP 7070127A JP 7012795 A JP7012795 A JP 7012795A JP H08259344 A JPH08259344 A JP H08259344A
- Authority
- JP
- Japan
- Prior art keywords
- oxide
- inorganic
- adsorbent
- silica
- porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000463 material Substances 0.000 title claims abstract description 28
- 239000003463 adsorbent Substances 0.000 claims abstract description 56
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 45
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 37
- 150000001875 compounds Chemical class 0.000 claims abstract description 25
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000011148 porous material Substances 0.000 claims abstract description 23
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 18
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 13
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000011941 photocatalyst Substances 0.000 claims abstract description 10
- 239000011787 zinc oxide Substances 0.000 claims abstract description 9
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 5
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005751 Copper oxide Substances 0.000 claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 5
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003610 charcoal Substances 0.000 claims abstract description 5
- 229910000428 cobalt oxide Inorganic materials 0.000 claims abstract description 5
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910000480 nickel oxide Inorganic materials 0.000 claims abstract description 5
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000741 silica gel Substances 0.000 claims abstract description 5
- 229910002027 silica gel Inorganic materials 0.000 claims abstract description 5
- 229910001935 vanadium oxide Inorganic materials 0.000 claims abstract description 5
- 239000010457 zeolite Substances 0.000 claims abstract description 5
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims abstract description 5
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims abstract description 5
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims abstract description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001887 tin oxide Inorganic materials 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 8
- 230000008961 swelling Effects 0.000 abstract description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 4
- 229910052717 sulfur Inorganic materials 0.000 abstract description 4
- 239000011593 sulfur Substances 0.000 abstract description 4
- 235000019645 odor Nutrition 0.000 description 21
- 238000001179 sorption measurement Methods 0.000 description 21
- 229910052901 montmorillonite Inorganic materials 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000006713 insertion reaction Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000009830 intercalation Methods 0.000 description 3
- 230000002687 intercalation Effects 0.000 description 3
- 230000001678 irradiating effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000001699 photocatalysis Effects 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910000271 hectorite Inorganic materials 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- -1 phenol resin Chemical compound 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- OGHBATFHNDZKSO-UHFFFAOYSA-N propan-2-olate Chemical compound CC(C)[O-] OGHBATFHNDZKSO-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- DKAGJZJALZXOOV-UHFFFAOYSA-N hydrate;hydrochloride Chemical compound O.Cl DKAGJZJALZXOOV-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 238000001935 peptisation Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Landscapes
- Treating Waste Gases (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Catalysts (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は高性能な多孔性吸着体に
関する。FIELD OF THE INVENTION The present invention relates to a high performance porous adsorbent.
【０００２】[0002]
【従来の技術】従来、生活回りの各種悪臭に対しては、
活性炭を利用するものが一般的であった。この活性炭
は、やし殻、石炭、砂糖、木材、リグナイト、ピート、
フェノール樹脂等の、炭素を大量に含む材料を出発物質
として、数百度の熱処理で炭化させたもので、取り扱い
易くするために粉末状、粒状、ハニカム状の形態に成形
し、さらに水蒸気、二酸化炭素、酸素によるガス賦活処
理、あるいは、塩化亜鉛、リン酸、塩化カルシウム、硫
化カリウム、その他脱水、酸化、浸食性薬品による薬品
賦活処理を施すことで、微細孔を発達させたものであ
る。2. Description of the Related Art Conventionally, for various offensive odors in daily life,
It was common to use activated carbon. This activated carbon is made from palm shell, coal, sugar, wood, lignite, peat,
A material containing a large amount of carbon, such as phenol resin, is carbonized by heat treatment at several hundred degrees, and is formed into powder, granules, or honeycomb for easy handling, and steam, carbon dioxide The micropores are developed by performing a gas activation treatment with oxygen, or a chemical activation treatment with zinc chloride, phosphoric acid, calcium chloride, potassium sulfide, other dehydration, oxidation, or an erosive chemical.
【０００３】前記の方法で得られた活性炭は、微細孔へ
の分子の物理吸着を主に利用するため、アンモニア等の
低沸点分子を吸着させるのが困難であった。そこで、活
性炭成形物にクエン酸等の酸を添着させる等の化学処理
で、吸着しにくい特定物質の吸着性能を向上させる方法
が採られていた。しかし、このような処理を施すと、活
性炭が本来有している物理吸着性能を損なうという欠点
があった。このように、従来の活性炭成形物では、多種
多様な分子が複合されている悪臭に対して、十分な脱臭
性能を発揮できず、イオウ（Ｓ）系の臭気成分の吸着性
能に優れているが、窒素（Ｎ）系の臭気成分の吸着性能
については、満足できるレベルには至っていなかった。
そこで、イオウ（Ｓ）系の臭気成分及び窒素（Ｎ）系の
臭気成分のいずれの臭気成分に対しても吸着性能に優れ
た高性能な吸着剤が求められていた。The activated carbon obtained by the above method mainly utilizes physical adsorption of molecules into fine pores, and thus it is difficult to adsorb low boiling point molecules such as ammonia. Therefore, a method of improving the adsorption performance of a specific substance that is difficult to be adsorbed by a chemical treatment such as impregnating an activated carbon molded product with an acid such as citric acid has been adopted. However, such treatment has a drawback in that the physical adsorption performance originally possessed by activated carbon is impaired. As described above, the conventional activated carbon molded product cannot exhibit sufficient deodorizing performance against a malodor composed of various kinds of molecules and is excellent in the adsorption performance of the sulfur (S) odor component. However, the adsorption performance of nitrogen (N) odorous components has not reached a satisfactory level.
Therefore, there has been a demand for a high-performance adsorbent having excellent adsorption performance for both the sulfur (S) odor component and the nitrogen (N) odor component.
【０００４】[0004]
【発明が解決しようとする課題】本発明は前述の事実に
鑑みてなされたもので、その目的とするところは、イオ
ウ（Ｓ）系の臭気成分及び窒素（Ｎ）系の臭気成分とも
に高性能に吸着できる多孔性吸着体を提供することにあ
る。SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned facts, and an object of the present invention is to achieve high performance in both sulfur (S) odor components and nitrogen (N) odor components. The object is to provide a porous adsorbent capable of adsorbing to.
【０００５】[0005]
【課題を解決するための手段】本発明の請求項１に係る
多孔性吸着体は、膨潤性層状化合物の層間に無機ピラー
材が配置されてなる無機多孔体と吸着剤とを含むことを
特徴とする。A porous adsorbent according to claim 1 of the present invention comprises an adsorbent and an inorganic porous material in which an inorganic pillar material is arranged between layers of a swellable layered compound. And
【０００６】本発明の請求項２に係る多孔性吸着体は、
前記無機ピラー材が、アルミナ、シリカ−アルミナ複合
酸化物、シリカ−チタニア複合酸化物、シリカ−ジルコ
ニア、酸化鉄、酸化ニッケル、酸化コバルト、酸化マン
ガン、酸化バナジウム及び酸化銅からなる群から選択さ
れる少なくとも１種であることを特徴とする。The porous adsorbent according to claim 2 of the present invention is
The inorganic pillar material is selected from the group consisting of alumina, silica-alumina composite oxide, silica-titania composite oxide, silica-zirconia, iron oxide, nickel oxide, cobalt oxide, manganese oxide, vanadium oxide and copper oxide. It is characterized by being at least one kind.
【０００７】本発明の請求項３に係る多孔性吸着体は、
前記無機ピラー材が、光触媒であることを特徴とする。The porous adsorbent according to claim 3 of the present invention is
The inorganic pillar material is a photocatalyst.
【０００８】本発明の請求項４に係る多孔性吸着体は、
前記光触媒が、チタニア、チタン酸ストロンチウム、ジ
ルコニア、酸化亜鉛及び酸化スズからなる群から選択さ
れる少なくとも１種であることを特徴とする。The porous adsorbent according to claim 4 of the present invention is
The photocatalyst is at least one selected from the group consisting of titania, strontium titanate, zirconia, zinc oxide and tin oxide.
【０００９】本発明の請求項５に係る多孔性吸着体は、
前記吸着剤が活性炭、活性炭素繊維、木炭、シリカゲ
ル、活性アルミナ、ゼオライト、リン酸ジルコニウム及
び酸化亜鉛からなる群から選択される少なくとも１種で
あることを特徴とする。The porous adsorbent according to claim 5 of the present invention comprises:
It is characterized in that the adsorbent is at least one selected from the group consisting of activated carbon, activated carbon fiber, charcoal, silica gel, activated alumina, zeolite, zirconium phosphate and zinc oxide.
【００１０】以下、本発明を詳細に説明する。本発明に
係る多孔性吸着体は、膨潤性層状化合物の層間に無機ピ
ラー材が配置されてなる無機多孔体と吸着剤とを含んで
いる。前記無機多孔体は、膨潤性層状化合物の層間に無
機ピラー材が担持されている。Hereinafter, the present invention will be described in detail. The porous adsorbent according to the present invention contains an inorganic porous material having an inorganic pillar material arranged between layers of a swellable layered compound and an adsorbent. In the inorganic porous material, an inorganic pillar material is supported between layers of a swellable layered compound.
【００１１】前記膨潤性層状化合物は、特定の無機化合
物に限定されないが、例えば、Ｎａ−モンモリロナイ
ト、Ｃａ−モンモリロナイト、合成スメクタイト、Ｎａ
−テニオライト、Ｌｉ−テニオライト、Ｎａ−ヘクトラ
イト、Ｌｉ−ヘクトライト、酸性白土、合成雲母等のフ
ィロケイ酸鉱物等が挙げられ、それぞれ、単独、または
２種以上の混合物でもよい。なお、膨潤に際して、Ｃａ
−モンモリロナイト、酸性白土等の難膨潤性のものは、
混練等により強い剪断力を与えるとよい。The swellable layered compound is not limited to a specific inorganic compound, and examples thereof include Na-montmorillonite, Ca-montmorillonite, synthetic smectite, and Na.
-Teniolite, Li-teniolite, Na-hectorite, Li-hectorite, phyllosilicate minerals such as acid clay, synthetic mica, etc. may be mentioned, and each may be a single type or a mixture of two or more types. When swelling, Ca
-For swelling materials such as montmorillonite and acid clay,
A strong shearing force may be applied by kneading or the like.
【００１２】前記無機ピラー材は、例えば、アルミナ、
シリカ−アルミナ複合酸化物、シリカ−チタニア複合酸
化物、シリカ−ジルコニア、酸化鉄、酸化ニッケル、酸
化コバルト、酸化マンガン、酸化バナジウム及び酸化銅
からなる群から選択される少なくとも１種であるのが好
ましく、光触媒であることが、さらに好ましい。この光
触媒は、例えば、チタニア、チタン酸ストロンチウム、
ジルコニア、酸化亜鉛及び酸化スズからなる群から選択
される少なくとも１種が挙げられる。The inorganic pillar material is, for example, alumina,
It is preferably at least one selected from the group consisting of silica-alumina composite oxide, silica-titania composite oxide, silica-zirconia, iron oxide, nickel oxide, cobalt oxide, manganese oxide, vanadium oxide and copper oxide. More preferably, it is a photocatalyst. This photocatalyst is, for example, titania, strontium titanate,
At least one selected from the group consisting of zirconia, zinc oxide and tin oxide can be mentioned.
【００１３】本発明に係る多孔性吸着体は、膨潤性層状
化合物の層間に無機ピラーが挿入されている多孔体であ
って、高比表面積であるため、吸着性能に優れている。
また、固体酸性を有しているため、特にＮ系臭気成分の
吸着性能に優れている。そのうえ、無機ピラーを光触媒
で構成すると、光を照射することで、光触媒性能を発揮
し、臭気成分の除去性能が向上する。さらに、すでに吸
着していた成分を分解することもできるため、吸着剤の
再生が可能になる。The porous adsorbent according to the present invention is a porous body in which the inorganic pillars are inserted between the layers of the swellable layered compound, and has a high specific surface area, and therefore has excellent adsorption performance.
Further, since it has a solid acidity, it is particularly excellent in the adsorption performance of N-type odor components. Moreover, when the inorganic pillar is composed of a photocatalyst, the photocatalytic performance is exhibited by irradiating light, and the performance of removing odorous components is improved. Furthermore, since the components that have already been adsorbed can be decomposed, the adsorbent can be regenerated.
【００１４】本発明に用いる前記吸着剤として、例え
ば、活性炭、活性炭素繊維、木炭、シリカゲル、活性ア
ルミナ、ゼオライト、リン酸ジルコニウム及び酸化亜鉛
からなる群から選択される少なくとも１種が挙げられ
る。これの吸着剤は、特にＳ系臭気成分の吸着性能に優
れている。すなわち、本発明に係る多孔性吸着体は、膨
潤性層状化合物の層間に無機ピラー材が配置されてなる
無機多孔体が主に、Ｎ系臭気成分を吸着して除去し、吸
着剤が主に、Ｓ系臭気成分を吸着して除去するので、Ｎ
系臭気成分及びＳ系臭気成分のいずれも高性能に吸着し
て除去することができる。Examples of the adsorbent used in the present invention include at least one selected from the group consisting of activated carbon, activated carbon fiber, charcoal, silica gel, activated alumina, zeolite, zirconium phosphate and zinc oxide. This adsorbent is particularly excellent in the adsorption performance of S-based odor components. That is, in the porous adsorbent according to the present invention, the inorganic porous body in which the inorganic pillar material is arranged between the layers of the swellable layered compound is mainly used to adsorb and remove the N-based odor component, and the adsorbent is mainly used. , S-type odor components are adsorbed and removed, so N
Both the system odor component and the S system odor component can be adsorbed and removed with high performance.
【００１５】本発明に係る多孔性吸着体は次のようにし
て得られる。まず、膨潤性層状化合物を溶媒と混合し、
さらに必要に応じて混練し、層間に溶媒を十分含ませて
膨潤状態に保持する。この膨潤状態の膨潤性層状化合物
の層間の間隔は、例えば、水等の溶媒に０．８重量％で
分散したＮａ−モンモリロナイトの場合で１５０Å以上
である。The porous adsorbent according to the present invention is obtained as follows. First, a swellable layered compound is mixed with a solvent,
Further, if necessary, kneading is performed, and a solvent is sufficiently included between the layers to maintain a swollen state. The distance between the layers of the swellable layered compound in the swollen state is, for example, 150 Å or more in the case of Na-montmorillonite dispersed in a solvent such as water at 0.8% by weight.
【００１６】前記膨潤に用いる溶媒としては、例えば、
水、エタノール、メタノール、ジメチルホルムアミド
（ＤＭＦ）、ジメチルスルホキシド（ＤＭＳＯ）、アセ
トン等の極性溶媒が単独又は併用して用いられる。なか
でも、水が汎用される。The solvent used for the swelling is, for example,
Polar solvents such as water, ethanol, methanol, dimethylformamide (DMF), dimethylsulfoxide (DMSO), and acetone are used alone or in combination. Among them, water is commonly used.
【００１７】次に、無機ピラー材の調整方法について説
明する。無機ピラー材、例えば、チタニア及びこのチタ
ニアと酸化物の複合酸化物は次のようにして準備する。
チタンのアルコキシド、硝酸塩、塩化物等を出発原料と
し、この原料を加水分解し、重合反応した後に、解膠反
応し、ポリカチオン状態のチタニアゾルを得る。これら
反応の際に、必要に応じて、塩酸、硝酸、アンモニア、
ピペリジン、水酸化ナトリウム等の触媒を用いる。ま
た、チタニアと複合する前記酸化物は、この金属酸化物
を含む金属アルコキシド、硝酸塩、塩化物等を加水分解
し、重合反応して、酸化物を含有したゾルを得る。Next, a method for adjusting the inorganic pillar material will be described. An inorganic pillar material such as titania and a composite oxide of the titania and an oxide is prepared as follows.
A titanium alkoxide, nitrate, chloride or the like is used as a starting material, and this material is hydrolyzed, polymerized, and then peptized to obtain a titania sol in a polycation state. During these reactions, if necessary, hydrochloric acid, nitric acid, ammonia,
A catalyst such as piperidine or sodium hydroxide is used. Further, the oxide complexed with titania hydrolyzes a metal alkoxide, a nitrate, a chloride and the like containing the metal oxide, and polymerizes to obtain a sol containing the oxide.
【００１８】次に、前記酸化物ゾルの溶液を、前記膨潤
性層状化合物を分散させた溶媒に添加し、層間に酸化物
を挿入し担持する、いわゆる、インターカレーション反
応を行う。反応温度、反応時間は限定しないが、一例と
して、６０℃、１．５時間という条件が挙げられる。こ
のようにして、前記チタニア酸化物が、膨潤した膨潤性
層状化合物の層間に挿入されて無機ピラー材となり、無
機多孔体が得られる。Next, the solution of the oxide sol is added to the solvent in which the swellable layered compound is dispersed, and the so-called intercalation reaction is carried out in which the oxide is inserted and supported between the layers. Although the reaction temperature and the reaction time are not limited, conditions such as 60 ° C. and 1.5 hours are mentioned as an example. In this way, the titania oxide is inserted between layers of the swollen swellable layered compound to form an inorganic pillar material, and an inorganic porous body is obtained.
【００１９】さらに、この無機多孔体に例えば、活性炭
等の吸着剤を添加して、多孔性吸着体が得られる。この
とき、無機多孔体と活性炭等の吸着剤とを混合せずに、
独立に分離した状態で一体になっていてもよいが、無機
多孔体と活性炭等の吸着剤とを混合して均一に分散され
た多孔性吸着体のほうが好ましい。Further, for example, an adsorbent such as activated carbon is added to this inorganic porous material to obtain a porous adsorbent. At this time, without mixing the inorganic porous material and the adsorbent such as activated carbon,
Although it may be integrated independently in a separated state, a porous adsorbent in which an inorganic porous material and an adsorbent such as activated carbon are mixed and uniformly dispersed is preferable.
【００２０】本発明の無機多孔体の作製における、膨潤
性層状化合物、チタニアを用いる割合は、特に限定され
ないが、一例を示すと、膨潤性層状化合物１００重量部
（以下部と記す）に対して、チタニアは１０〜１５０部
の範囲が適量である。さらに、例えば、無機多孔体１部
に対して、吸着剤１〜１０部を添加して混合する。The proportion of the swellable layered compound and titania used in the preparation of the inorganic porous material of the present invention is not particularly limited, but, for example, with respect to 100 parts by weight of the swellable layered compound (hereinafter referred to as "part"). The proper amount of titania is 10 to 150 parts. Further, for example, 1 to 10 parts of the adsorbent is added to and mixed with 1 part of the inorganic porous body.
【００２１】前記酸化物を挿入する反応を行った後に、
この反応の終了した液を遠心分離で洗浄を繰り返してゲ
ル状化した後に、ヘラ等で板状に配向成形する。この配
向成形した後に、乾燥を行う。前記液の状態から配向成
形を行わずに乾燥を行ってもよい。After carrying out the reaction of inserting the oxide,
The liquid after the reaction is repeatedly washed by centrifugation to form a gel, and then oriented and shaped into a plate with a spatula or the like. After this orientation molding, drying is performed. Drying may be performed from the liquid state without performing orientation molding.
【００２２】このようにして得られる無機多孔体は、膨
潤性層状化合物の層間に、無機ピラー材としてチタニア
が担持され、吸着性能に優れている。The inorganic porous material thus obtained has excellent adsorption performance because titania is supported as an inorganic pillar material between the layers of the swellable layered compound.
【００２３】[0023]
【作用】本発明の請求項１に係る多孔性吸着体は、膨潤
性層状化合物の層間に無機ピラー材が配置されてなる無
機多孔体と吸着剤とを含むので、膨潤性層状化合物の層
間に無機ピラー材が配置されてなる無機多孔体が主に、
Ｎ系臭気成分を吸着して除去し、吸着剤が主に、Ｓ系臭
気成分を吸着して除去するため、Ｎ系臭気成分及びＳ系
臭気成分のいずれも高性能に吸着して除去することがで
きる。本発明の請求項２に係る多孔性吸着体は、前記無
機ピラー材が、アルミナ、シリカ−アルミナ酸化物、シ
リカ−チタニア酸化物、シリカ−ジルコニア、酸化鉄、
酸化ニッケル、酸化コバルト、酸化マンガン、酸化バナ
ジウム及び酸化銅からなる群から選択される少なくとも
１種であるので、固体酸性を有しているため、特にＮ系
臭気成分の吸着性能に優れる。The porous adsorbent according to claim 1 of the present invention contains an inorganic porous material in which an inorganic pillar material is arranged between layers of a swellable layered compound and an adsorbent, so that the porous adsorbent is provided between layers of a swellable layered compound. Mainly inorganic porous material in which the inorganic pillar material is arranged,
Adsorbs and removes N-type odor components, and the adsorbent mainly absorbs and removes S-type odor components. Therefore, both N-type odor components and S-type odor components are adsorbed and removed with high performance. You can In the porous adsorbent according to claim 2 of the present invention, the inorganic pillar material is alumina, silica-alumina oxide, silica-titania oxide, silica-zirconia, iron oxide,
Since it is at least one selected from the group consisting of nickel oxide, cobalt oxide, manganese oxide, vanadium oxide, and copper oxide, it has solid acidity, and therefore is particularly excellent in the adsorption performance of N-based odorous components.
【００２４】本発明の請求項３及び請求項４に係る多孔
性吸着体は、前記無機ピラー材が、光触媒であるので、
光を照射することで、光触媒性能を発揮し、臭気成分の
除去性能が向上する。さらに、すでに吸着していた成分
を分解することもできるため、吸着剤の再生が可能にな
る。In the porous adsorbent according to claim 3 and claim 4 of the present invention, since the inorganic pillar material is a photocatalyst,
By irradiating with light, the photocatalytic performance is exhibited and the performance of removing odorous components is improved. Furthermore, since the components that have already been adsorbed can be decomposed, the adsorbent can be regenerated.
【００２５】本発明の請求項５に係る多孔性吸着体は、
前記吸着剤が活性炭、活性炭素繊維、木炭、シリカゲ
ル、活性アルミナ、ゼオライト、リン酸ジルコニウム及
び酸化亜鉛からなる群から選択される少なくとも１種で
あるので、特にＳ系臭気成分の吸着性能に優れている。The porous adsorbent according to claim 5 of the present invention is
Since the adsorbent is at least one selected from the group consisting of activated carbon, activated carbon fiber, charcoal, silica gel, activated alumina, zeolite, zirconium phosphate and zinc oxide, it is particularly excellent in adsorption performance of S-based odor components. There is.
【００２６】[0026]
【実施例】以下本発明を実施例によって具体的に説明す
る。EXAMPLES The present invention will be specifically described below with reference to examples.
【００２７】（実施例１）アルミナは次のように作製し
た。塩化アルミニウムを２Ｎ水酸化ナトリウム水溶液に
加え、加水分解、重合反応を行うことにより、透明なア
ルミナゾルを得た。Example 1 Alumina was produced as follows. Aluminum chloride was added to a 2N aqueous sodium hydroxide solution, and hydrolysis and polymerization were performed to obtain a transparent alumina sol.
【００２８】膨潤性層状化合物として、Ｎａ−モンモリ
ロナイト（クニミネ工業株式会社製：商品名クニピア
Ｆ）を用いた。上記Ｎａ−モンモリロナイトを水に分散
し、０．８ｗｔ％の水溶液を作製した。このＮａ−モン
モリロナイトが分散した水溶液に、上記アルミナゾルを
添加し、アルミナの挿入反応（インターカレーション反
応）を行い、Ｎａ−モンモリロナイトの層間にアルミナ
を担持した。この条件は、反応温度は６０℃、反応時間
は１．５時間であった。As the swellable layered compound, Na-montmorillonite (Kunimine Industries Co., Ltd .: trade name Kunipia F) was used. The Na-montmorillonite was dispersed in water to prepare a 0.8 wt% aqueous solution. The alumina sol was added to the aqueous solution in which the Na-montmorillonite was dispersed, and an insertion reaction (intercalation reaction) of alumina was performed to support the alumina between the Na-montmorillonite layers. Under these conditions, the reaction temperature was 60 ° C. and the reaction time was 1.5 hours.
【００２９】次に、この挿入反応が終了した液を遠心分
離、水洗を繰り返し、溶液のｐＨが略中性となったこと
を確認した後に、６０℃で乾燥し、空気中で４００℃で
焼成を行い、無機多孔体を得た。Next, the liquid in which this insertion reaction has been completed is repeatedly centrifuged and washed with water, and after confirming that the pH of the solution has become substantially neutral, it is dried at 60 ° C. and calcined at 400 ° C. in air. Then, an inorganic porous material was obtained.
【００３０】無機多孔体を得るための各成分の配合は、
Ｎａ−モンモリロナイト：アルミナ＝１００重量部：６
０重量部の割合となるよう行った。すなわち、膨潤性層
状化合物としてＮａ−モンモリロナイト( クニミネ工業
株式会社製、商品名クニピアＦ）１００重量部、無機ピ
ラーとしてアルミナ（塩化アルミニウムを水酸化ナトリ
ウムで加水分解、重合したもの）６０重量部の割合で用
い、アルミナを層状化合物層間に挿入した無機多孔体を
合成し、この無機多孔体１５重量部に対して、活性炭
（クラレケミカル株式会社製：商品名ＰＵ２００ＵＨ）
を８５重量部の割合で添加、混合して、多孔性吸着体を
得た。この多孔性吸着体を３００ccの容器に０．０１g
充填し、約１００ppm のトリメチルアミンを容器に導入
して、半減期を調べることにより、で多孔性吸着体の吸
着性能を評価した。その結果を表１に示した。The composition of each component for obtaining the inorganic porous material is as follows.
Na-montmorillonite: alumina = 100 parts by weight: 6
The proportion was 0 part by weight. That is, 100 parts by weight of Na-montmorillonite (Kunimine Industries Co., Ltd., trade name Kunipia F) as the swelling layered compound, and 60 parts by weight of alumina (aluminum chloride hydrolyzed and polymerized with sodium hydroxide) as the inorganic pillar. Used to synthesize an inorganic porous material in which alumina was inserted between the layered compound layers, and activated carbon (manufactured by Kuraray Chemical Co .: trade name PU200UH) was added to 15 parts by weight of the inorganic porous material.
Was added and mixed at a ratio of 85 parts by weight to obtain a porous adsorbent. 0.01g of this porous adsorbent in a 300cc container
The adsorption performance of the porous adsorbent was evaluated by filling the container, introducing about 100 ppm of trimethylamine into the container, and examining the half-life. The results are shown in Table 1.
【００３１】（実施例２）チタニアは次のように作製し
た。チタン酸イソプロポキシド〔Ｔｉ（ＯＣ
3 Ｈ 7 ）4 、半井テスク株式会社製試薬〕を２Ｎ塩酸水
溶液に加え、加水分解、重合反応、さらに解膠反応し、
透明なチタニアゾルを得た。(Example 2) Titania was manufactured as follows.
Was. Titanic acid isopropoxide [Ti (OC
3H 7)Four, Hanui Tesque Co., Ltd.] 2N hydrochloric acid water
In addition to the solution, hydrolysis, polymerization reaction, peptization reaction,
A transparent titania sol was obtained.
【００３２】膨潤性層状化合物として、Ｎａ−モンモリ
ロナイト（クニミネ工業株式会社製：商品名クニピア
Ｆ）を用いた。上記Ｎａ−モンモリロナイトを水に分散
し、０．８ｗｔ％の水溶液を作製した。このＮａ−モン
モリロナイトが分散した水溶液に、上記チタニアゾルを
添加し、チタニアの挿入反応（インターカレーション反
応）を行い、Ｎａ−モンモリロナイトの層間にチタニア
を担持した。この条件は、反応温度は６０℃、反応時間
は１．５時間であった。As the swellable layered compound, Na-montmorillonite (Kunimine Industries Co., Ltd .: trade name Kunipia F) was used. The Na-montmorillonite was dispersed in water to prepare a 0.8 wt% aqueous solution. The titania sol was added to the aqueous solution in which the Na-montmorillonite was dispersed, and the titania insertion reaction (intercalation reaction) was performed to support the titania between the Na-montmorillonite layers. Under these conditions, the reaction temperature was 60 ° C. and the reaction time was 1.5 hours.
【００３３】次に、この挿入反応が終了した液を遠心分
離、水洗を繰り返し、溶液のｐＨが略中性となったこと
を確認した後に、６０℃で乾燥を行った。乾燥した後
に、空気中で４００℃で焼成を行い、無機多孔体を得
た。Next, the liquid in which this insertion reaction was completed was repeatedly centrifuged and washed with water, and after confirming that the pH of the solution became substantially neutral, it was dried at 60 ° C. After drying, it was baked in air at 400 ° C. to obtain an inorganic porous body.
【００３４】無機多孔体を得るための各成分の配合は、
Ｎａ−モンモリロナイト：チタニア＝１００重量部：６
０重量部の割合となるよう行った。すなわち、膨潤性層
状化合物としてＮａ−モンモリロナイト（クニミネ工業
株式会社製：商品名クニピアＦ）１００重量部、無機ピ
ラーとしてチタニア（チタン酸イソプロポキシドを塩酸
で加水分解、重合、解こうしたもの）６０重量部の割合
で用い、チタニアを層状化合物層間に挿入した無機多孔
体を合成し、この無機多孔体３０重量部に対して、繊維
状活性炭（大阪ガス株式会社製：商品名リノベス）を７
０重量部の割合で添加、混合して、多孔性吸着体を得
た。この多孔性吸着体の吸着性能を実施例１と同様にし
て評価し、その結果を表１に示した。The composition of each component for obtaining the inorganic porous material is as follows.
Na-montmorillonite: titania = 100 parts by weight: 6
The proportion was 0 part by weight. That is, 100 parts by weight of Na-montmorillonite (Kunimine Industries Co., Ltd .: trade name Kunipia F) as a swellable layered compound, and 60 parts by weight of titania (hydrolyzing and polymerizing isopropoxide titanate with hydrochloric acid as an inorganic pillar). The inorganic porous material in which titania was inserted between the layered compound layers was synthesized in an amount of 10 parts by weight, and fibrous activated carbon (trade name: Linoves, manufactured by Osaka Gas Co., Ltd.) was added to 30 parts by weight of the inorganic porous material.
A porous adsorbent was obtained by adding and mixing at a ratio of 0 part by weight. The adsorption performance of this porous adsorbent was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
【００３５】（実施例３）実施例１と同様にして得た無
機多孔体３０重量部に対して、活性アルミナ（住友化学
株式会社製、商品名ＡＬ−４３）を７０重量部の割合で
添加、混合して、多孔性吸着体を得た。この多孔性吸着
体の吸着性能を実施例１と同様にして評価し、その結果
を表１に示した。(Example 3) 70 parts by weight of activated alumina (trade name AL-43, manufactured by Sumitomo Chemical Co., Ltd.) was added to 30 parts by weight of the inorganic porous material obtained in the same manner as in Example 1. , And mixed to obtain a porous adsorbent. The adsorption performance of this porous adsorbent was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
【００３６】（比較例１）活性炭（クラレケミカル株式
会社製、商品名ＰＵ２００ＵＨ）を単独で用いた。この
活性炭の吸着性能を実施例１と同様にして評価し、その
結果を表１に示した。Comparative Example 1 Activated carbon (produced by Kuraray Chemical Co., Ltd., trade name PU200UH) was used alone. The adsorption performance of this activated carbon was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
【００３７】（比較例２）実施例１で得られた無機多孔
体を単独で用いた。この無機多孔体の吸着性能を実施例
１と同様にして評価し、その結果を表１に示した。(Comparative Example 2) The inorganic porous material obtained in Example 1 was used alone. The adsorption performance of this inorganic porous material was evaluated in the same manner as in Example 1, and the results are shown in Table 1.
【００３８】[0038]
【表１】 [Table 1]
【００３９】表１の結果、実施例は比較例に比べて、半
減期が短く、すなわち、吸着性能に優れていることが分
かった。From the results shown in Table 1, it was found that the examples had a shorter half-life than the comparative examples, that is, the adsorption performance was excellent.
【００４０】[0040]
【発明の効果】本発明の請求項１に係る多孔性吸着体に
よると、膨潤性層状化合物の層間に無機ピラー材が配置
されてなる無機多孔体が主に、Ｎ系臭気成分を吸着して
除去し、吸着剤が主に、Ｓ系臭気成分を吸着して除去す
るため、Ｎ系臭気成分及びＳ系臭気成分のいずれも高性
能に吸着して除去することができ、吸着性能に優れる。According to the porous adsorbent according to the first aspect of the present invention, the inorganic porous body in which the inorganic pillar material is arranged between the layers of the swelling layered compound mainly adsorbs the N-type odor component. Since the adsorbent mainly removes and removes the S-based odor component, both the N-based odor component and the S-based odor component can be adsorbed and removed with high performance, and the adsorption performance is excellent.
【００４１】本発明の請求項２に係る多孔性吸着体によ
ると、固体酸性を有しているため、特にＮ系臭気成分の
吸着性能に優れる。According to the porous adsorbent of the second aspect of the present invention, since it has a solid acidity, it is particularly excellent in the adsorption performance of N-based odorous components.
【００４２】本発明の請求項３及び請求項４に係る多孔
性吸着体によると、光を照射することで、光触媒性能を
発揮し、臭気成分の除去性能が向上し、すでに吸着して
いた成分を分解することもできるため、吸着剤の再生が
可能になる。According to the porous adsorbents according to the third and fourth aspects of the present invention, by irradiating light, the photocatalytic performance is exhibited, the removal performance of the odorous components is improved, and the components already adsorbed. Since it can be decomposed, the adsorbent can be regenerated.
【００４３】本発明の請求項５に係る多孔性吸着体によ
ると、特にＳ系臭気成分の吸着性能に優れている。According to the porous adsorbent according to claim 5 of the present invention, the adsorption performance of the S-based odorous component is particularly excellent.
Claims (5)
が配置されてなる無機多孔体と吸着剤とを含むことを特
徴とする多孔性吸着体。1. A porous adsorbent comprising an inorganic porous material having an inorganic pillar material arranged between layers of a swellable layered compound and an adsorbent.
−アルミナ複合酸化物、シリカ−チタニア複合酸化物、
シリカ−ジルコニア、酸化鉄、酸化ニッケル、酸化コバ
ルト、酸化マンガン、酸化バナジウム及び酸化銅からな
る群から選択される少なくとも１種であることを特徴と
する請求項１記載の多孔性吸着体。2. The inorganic pillar material is alumina, silica-alumina composite oxide, silica-titania composite oxide,
The porous adsorbent according to claim 1, which is at least one selected from the group consisting of silica-zirconia, iron oxide, nickel oxide, cobalt oxide, manganese oxide, vanadium oxide, and copper oxide.
を特徴とする請求項１記載の多孔性吸着体。3. The porous adsorbent according to claim 1, wherein the inorganic pillar material is a photocatalyst.
ロンチウム、ジルコニア、酸化亜鉛及び酸化スズからな
る群から選択される少なくとも１種であることを特徴と
する請求項３記載の多孔性吸着体。4. The porous adsorbent according to claim 3, wherein the photocatalyst is at least one selected from the group consisting of titania, strontium titanate, zirconia, zinc oxide and tin oxide.
炭、シリカゲル、活性アルミナ、ゼオライト、リン酸ジ
ルコニウム及び酸化亜鉛からなる群から選択される少な
くとも１種であることを特徴とする請求項１乃至請求項
４いずれか記載の多孔性吸着体。5. The adsorbent is at least one selected from the group consisting of activated carbon, activated carbon fiber, charcoal, silica gel, activated alumina, zeolite, zirconium phosphate and zinc oxide. 5. The porous adsorbent according to claim 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7070127A JPH08259344A (en) | 1995-03-28 | 1995-03-28 | Porous adsorbing material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7070127A JPH08259344A (en) | 1995-03-28 | 1995-03-28 | Porous adsorbing material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08259344A true JPH08259344A (en) | 1996-10-08 |
Family
ID=13422586
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7070127A Withdrawn JPH08259344A (en) | 1995-03-28 | 1995-03-28 | Porous adsorbing material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH08259344A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0892159A2 (en) * | 1997-07-17 | 1999-01-20 | Hitachi, Ltd. | Exhaust gas cleaning apparatus and method for internal combustion engine |
| JPH11323188A (en) * | 1998-05-14 | 1999-11-26 | Mitsubishi Materials Corp | Photocatalytic film, method for forming it and photocatalytic coating |
| WO2005102963A1 (en) * | 2004-04-22 | 2005-11-03 | Ngk Insulators, Ltd. | Method for producing porous honeycomb structure and porous honeycomb structure |
| JP2006175430A (en) * | 2004-11-24 | 2006-07-06 | Yoshihiro Taki | Method for producing photocatalyst and method for decomposing contaminant |
| JP2009056391A (en) * | 2007-08-31 | 2009-03-19 | National Institute For Materials Science | Photocatalytic material of octahedron seat structure |
| JP2011224533A (en) * | 2010-03-31 | 2011-11-10 | National Institute Of Advanced Industrial Science & Technology | Photocatalyst-carrying porous clay material |
| KR101389378B1 (en) * | 2012-07-10 | 2014-04-29 | 한국화학연구원 | Metal oxide-carbon complex containing photoactive metal oxides, and its manufacturing method, and the photocatalyst thereof |
| JP2016050122A (en) * | 2014-08-28 | 2016-04-11 | 株式会社丸長 | Clay for ceramic product |
| CN113321466A (en) * | 2021-06-01 | 2021-08-31 | 武汉理工大学 | Facing mortar capable of removing adsorbed gas pollutants and preparation method thereof |
| JP2022162500A (en) * | 2021-04-12 | 2022-10-24 | 垰田 宏子 | Photocatalyst powder, photocatalyst molding, environment purifying agent and method for producing photocatalyst powder |
| KR102501315B1 (en) | 2022-09-20 | 2023-02-22 | 한국건설기술연구원 | Method for manufacturing highly porous silica photo catalyst including iron oxide and manganese oxide, and method for removing synthetic organic chemicals in aqua using the same |
-
1995
- 1995-03-28 JP JP7070127A patent/JPH08259344A/en not_active Withdrawn
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0892159A3 (en) * | 1997-07-17 | 2000-04-26 | Hitachi, Ltd. | Exhaust gas cleaning apparatus and method for internal combustion engine |
| EP0892159A2 (en) * | 1997-07-17 | 1999-01-20 | Hitachi, Ltd. | Exhaust gas cleaning apparatus and method for internal combustion engine |
| JPH11323188A (en) * | 1998-05-14 | 1999-11-26 | Mitsubishi Materials Corp | Photocatalytic film, method for forming it and photocatalytic coating |
| US8366989B2 (en) | 2004-04-22 | 2013-02-05 | Ngk Insulators, Ltd. | Method for producing porous honeycomb structure and porous honeycomb structure |
| WO2005102963A1 (en) * | 2004-04-22 | 2005-11-03 | Ngk Insulators, Ltd. | Method for producing porous honeycomb structure and porous honeycomb structure |
| JP2006175430A (en) * | 2004-11-24 | 2006-07-06 | Yoshihiro Taki | Method for producing photocatalyst and method for decomposing contaminant |
| JP2009056391A (en) * | 2007-08-31 | 2009-03-19 | National Institute For Materials Science | Photocatalytic material of octahedron seat structure |
| JP2011224533A (en) * | 2010-03-31 | 2011-11-10 | National Institute Of Advanced Industrial Science & Technology | Photocatalyst-carrying porous clay material |
| KR101389378B1 (en) * | 2012-07-10 | 2014-04-29 | 한국화학연구원 | Metal oxide-carbon complex containing photoactive metal oxides, and its manufacturing method, and the photocatalyst thereof |
| JP2016050122A (en) * | 2014-08-28 | 2016-04-11 | 株式会社丸長 | Clay for ceramic product |
| JP2022162500A (en) * | 2021-04-12 | 2022-10-24 | 垰田 宏子 | Photocatalyst powder, photocatalyst molding, environment purifying agent and method for producing photocatalyst powder |
| CN113321466A (en) * | 2021-06-01 | 2021-08-31 | 武汉理工大学 | Facing mortar capable of removing adsorbed gas pollutants and preparation method thereof |
| KR102501315B1 (en) | 2022-09-20 | 2023-02-22 | 한국건설기술연구원 | Method for manufacturing highly porous silica photo catalyst including iron oxide and manganese oxide, and method for removing synthetic organic chemicals in aqua using the same |
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