JPH08257107A - Deodorizing composition - Google Patents

Deodorizing composition

Info

Publication number
JPH08257107A
JPH08257107A JP7070129A JP7012995A JPH08257107A JP H08257107 A JPH08257107 A JP H08257107A JP 7070129 A JP7070129 A JP 7070129A JP 7012995 A JP7012995 A JP 7012995A JP H08257107 A JPH08257107 A JP H08257107A
Authority
JP
Japan
Prior art keywords
zinc oxide
clay
deodorizing
composition
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP7070129A
Other languages
Japanese (ja)
Other versions
JP3052231B2 (en
Inventor
Manabu Mizobuchi
学 溝渕
Tadao Kawamura
忠勇 河村
Kazuhiro Matsuura
一弘 松浦
Naoharu Nakagawa
尚治 中川
Toshiyuki Yamauchi
俊幸 山内
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Electric Works Co Ltd
Original Assignee
Matsushita Electric Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Works Ltd filed Critical Matsushita Electric Works Ltd
Priority to JP7070129A priority Critical patent/JP3052231B2/en
Publication of JPH08257107A publication Critical patent/JPH08257107A/en
Application granted granted Critical
Publication of JP3052231B2 publication Critical patent/JP3052231B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

PURPOSE: To provide a deodorizing composition which enables deodorizing of malodors involved in the human lives such as odors of tobacco, garbage and toilets having various molecules compounded and odors of exhaust gases from buses, trucks, automobiles and the like effectively and simplifying of a production process of forming in a particle or a honeycomb shape. CONSTITUTION: In a deodorizing composition containing an activated carbon powder, a binder, a plasticizer containing a clay-like substance and zinc oxide, the content of the zinc oxide is 1-40wt.% of the total of the deoxidizing composition. Aluminum silicate is also contained and the content of the zinc oxide and the aluminum silicate is 1-30 wt.% of the total of the deodorizing composition at a rate of 2.5-20 pts. zinc oxide per 1 pt. the aluminum silicate.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、例えば、たばこ臭、生
ゴミ臭及びトイレ臭等の生活回りの悪臭並びにバス、ト
ラック及び自動車等からの排気ガス臭等に対して、優れ
た浄化性能を有する脱臭性組成物に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention has excellent purification performance against, for example, bad odors in daily life such as tobacco odor, garbage odor and toilet odor, and exhaust gas odor from buses, trucks and automobiles. Having a deodorant composition.

【0002】[0002]

【従来の技術】従来、生活回りの各種悪臭等に対して
は、活性炭を利用するものが一般的であった。この活性
炭は、やし殻、石炭、砂糖、木材、リグナイト、ピー
ト、フェノール樹脂等の、炭素を大量に含む材料を出発
物質として、数百度の熱処理で炭化させたもので、取り
扱い易くするために粉末状、粒状、ハニカム状の形態に
成形し、さらに水蒸気、二酸化炭素、酸素によるガス賦
活処理、あるいは、塩化亜鉛、リン酸、塩化カルシウ
ム、硫化カリウム、その他脱水、酸化、浸食性薬品によ
る薬品賦活処理を施すことで、微細孔を発達させたもの
である。
2. Description of the Related Art Conventionally, activated carbon has been generally used for various offensive odors in daily life. This activated carbon is a material containing a large amount of carbon, such as coconut shell, coal, sugar, wood, lignite, peat, and phenol resin, which is carbonized by heat treatment at several hundred degrees, for easy handling. Molded into powder, granular or honeycomb form, and further gas activation treatment with steam, carbon dioxide, oxygen, or chemical activation with zinc chloride, phosphoric acid, calcium chloride, potassium sulfide, other dehydration, oxidation, erodible chemicals The micropores are developed by the treatment.

【0003】前記の方法で得られた活性炭は、微細孔へ
の分子の物理吸着を主に利用するため、アンモニア等の
低沸点分子を吸着させるのが困難であった。そこで、活
性炭成形物に酸を添着させる等の化学処理で、吸着しに
くい特定物質の吸着性能を向上させる方法が採られてい
る。しかし、このような処理を施すと、活性炭が本来有
している物理吸着性能を損なうという欠点があった。こ
のように、従来の活性炭成形物では、多種多様な分子が
複合されている悪臭に対して、十分な脱臭性能を発揮で
きず、粒状活性炭、ハニカム状活性炭を調整するには、
前記のように数工程を必要とし、さらに、大掛かりな賦
活処理装置が必要であるという問題があった。
The activated carbon obtained by the above method mainly utilizes physical adsorption of molecules into fine pores, and thus it is difficult to adsorb low boiling point molecules such as ammonia. Therefore, a method of improving the adsorption performance of a specific substance which is difficult to be adsorbed by a chemical treatment such as impregnating an activated carbon molded product with an acid is adopted. However, such treatment has a drawback in that the physical adsorption performance originally possessed by activated carbon is impaired. In this way, in the conventional activated carbon molded product, against the malodor of which a wide variety of molecules are compounded, sufficient deodorizing performance cannot be exhibited, and in order to adjust the granular activated carbon and the honeycomb-shaped activated carbon,
As described above, there is a problem that several steps are required and a large-scale activation processing device is required.

【0004】[0004]

【発明が解決しようとする課題】本発明は前述の事実に
鑑みてなされたもので、その目的とするところは、多種
多様な分子が複合されているたばこ臭、生ゴミ臭及びト
イレ臭等の生活回りの悪臭並びにバス、トラック及び自
動車等からの排気ガス臭等に対して効果的に脱臭するこ
とができ、また、粒状、ハニカム状に成形する製造工程
を簡略化することができる脱臭性組成物を提供すること
にある。
SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned facts, and an object of the present invention is to provide a tobacco odor, a garbage odor, a toilet odor, etc. in which various molecules are combined. A deodorant composition that can effectively deodorize offensive odors in daily life and exhaust gas odors from buses, trucks, automobiles, etc., and also can simplify the manufacturing process for molding into granular or honeycomb shapes. To provide things.

【0005】[0005]

【課題を解決するための手段】本発明の請求項1に係る
脱臭性組成物は、活性炭粉末と、バインダーと、粘土状
物質を含む可塑剤と、酸化亜鉛とを含有する脱臭性組成
物であって、酸化亜鉛の含有量が、脱臭性組成物の全量
に対して、1〜40重量%であることを特徴とする。
The deodorizing composition according to claim 1 of the present invention is a deodorizing composition containing activated carbon powder, a binder, a plasticizer containing a clay-like substance, and zinc oxide. It is characterized in that the content of zinc oxide is 1 to 40% by weight based on the total amount of the deodorant composition.

【0006】本発明の請求項2に係る脱臭性組成物は、
ケイ酸アルミニウムをも含有し、酸化亜鉛及びケイ酸ア
ルミニウムの含有量が、脱臭性組成物の全量に対して、
1〜30重量%であり、ケイ酸アルミニウム1重量部に
対して、酸化亜鉛2.5〜20重量部の割合で含有する
ことを特徴とする。
The deodorizing composition according to claim 2 of the present invention is
Also containing aluminum silicate, the content of zinc oxide and aluminum silicate, relative to the total amount of the deodorant composition,
The content is 1 to 30% by weight, and 2.5 to 20 parts by weight of zinc oxide is contained with respect to 1 part by weight of aluminum silicate.

【0007】本発明の請求項3に係る脱臭性組成物は、
前記バインダ−が、メチルセルロース、カルボキシメチ
ルセルロース、ポリビニルアルコール及び澱粉のりから
なる群から選択される少なくとも1種の水溶性有機バイ
ンダーであり、この水溶性有機バインダーを脱臭性組成
物の全量に対して、1〜25重量%含有することを特徴
とする。
The deodorizing composition according to claim 3 of the present invention is
The binder is at least one water-soluble organic binder selected from the group consisting of methyl cellulose, carboxymethyl cellulose, polyvinyl alcohol and starch paste, and the water-soluble organic binder is used in an amount of 1 relative to the total amount of the deodorant composition. It is characterized by containing ~ 25 wt%.

【0008】本発明の請求項4に係る脱臭性組成物は、
前記粘土状物質が木節粘土、蛙目粘土及びベントナイト
からなる群から選択される少なくとも1種を含み、か
つ、前記粘土状物質の含有量が脱臭性組成物の全量に対
して、3〜30重量%であることを特徴とする。
The deodorizing composition according to claim 4 of the present invention is
The clay-like substance contains at least one selected from the group consisting of Kikibushi clay, frog clay and bentonite, and the content of the clay-like substance is 3 to 30 with respect to the total amount of the deodorant composition. It is characterized in that it is wt%.

【0009】以下、本発明を詳細に説明する。本発明で
は、既に賦活処理を施した活性炭粉末を用い、これを粒
状、ハニカム状に成形する際に、バインダー、粘土状物
質等の可塑剤及び酸化亜鉛を配合する。活性炭粉末の出
発物質としては、やし殻、石炭、砂糖、木材、リグナイ
ト、ピート、フェノール樹脂等の、炭素を大量に含む材
料を利用することができ、特に石炭を数百度の熱処理で
炭化させたものが好ましい。
The present invention will be described in detail below. In the present invention, activated carbon powder that has already been subjected to activation treatment is used, and a binder, a plasticizer such as a clay-like substance, and zinc oxide are compounded when the activated carbon powder is formed into a granular or honeycomb shape. As a starting material for the activated carbon powder, materials containing a large amount of carbon such as coconut shell, coal, sugar, wood, lignite, peat, and phenol resin can be used. In particular, coal is carbonized by heat treatment at several hundred degrees. Those that are preferred are.

【0010】活性炭粉末に酸化亜鉛を配合することによ
り、多種多様な分子が複合されている悪臭、例えば、た
ばこ臭、生ゴミ臭及びトイレ臭等の生活回りの悪臭並び
にバス、トラック及び自動車等からの排気ガス臭等を吸
着除去する効果が発現するものである。この酸化亜鉛の
含有量は、脱臭性組成物の全量に対して、1〜40重量
%であることが必要であり、より好ましくは、1〜30
重量%、さらに好ましくは、1〜20重量%である。す
なわち、酸化亜鉛の含有量が脱臭性組成物の全量に対し
て、1重量%未満の場合には、多種多様な分子が複合さ
れている悪臭に対する吸着脱臭性能を十分に得ることが
できなくなり、40重量%を越える場合には、粒状、ハ
ニカム等への成形性を損なう恐れがある。
By blending zinc oxide with activated carbon powder, a variety of molecules are combined in a bad odor, for example, bad odors in daily life such as tobacco odor, kitchen odor and toilet odor, and from buses, trucks and automobiles. The effect of adsorbing and removing the exhaust gas odor and the like is exhibited. The content of this zinc oxide needs to be 1 to 40% by weight with respect to the total amount of the deodorant composition, and more preferably 1 to 30%.
%, And more preferably 1 to 20% by weight. That is, when the content of zinc oxide is less than 1% by weight with respect to the total amount of the deodorant composition, it becomes impossible to sufficiently obtain the adsorptive deodorizing performance for a bad odor in which various molecules are combined, If it exceeds 40% by weight, there is a risk of impairing the formability of granules, honeycombs and the like.

【0011】ケイ酸アルミニウムをも含有し、酸化亜鉛
及びケイ酸アルミニウムの含有量は、脱臭性組成物の全
量に対して、1〜30重量%で、この混合比として、ケ
イ酸アルミニウム1重量部に対して、酸化亜鉛2.5〜
20重量部の割合で含有することが好ましい。すなわ
ち、脱臭性組成物にケイ酸アルミニウムをも含有するこ
とにより吸着脱臭性能が、さらに向上する。酸化亜鉛及
びケイ酸アルミニウムの含有量が脱臭性組成物の全量に
対して、1重量%未満、あるいは、酸化亜鉛及びケイ酸
アルミニウムの混合比が前記の範囲外の場合には、多種
多様な分子が複合されている悪臭に対する吸着脱臭性能
を十分に得ることができ難くなり、30重量%を越える
場合には、粒状、ハニカム等への成形性を損なう恐れが
ある。
It also contains aluminum silicate, and the content of zinc oxide and aluminum silicate is 1 to 30% by weight based on the total amount of the deodorant composition, and the mixing ratio is 1 part by weight of aluminum silicate. In contrast, zinc oxide 2.5-
It is preferably contained in a proportion of 20 parts by weight. That is, when the deodorizing composition also contains aluminum silicate, the adsorptive deodorizing performance is further improved. When the content of zinc oxide and aluminum silicate is less than 1% by weight based on the total amount of the deodorant composition, or when the mixing ratio of zinc oxide and aluminum silicate is out of the above range, a wide variety of molecules can be prepared. It becomes difficult to sufficiently obtain the adsorption and deodorization performance against the malodor which is compounded with, and when it exceeds 30% by weight, the formability into granules, honeycombs and the like may be impaired.

【0012】またバインダーとしては、メチルセルロー
ス、カルボキシメチルセルロース、ポリビニルアルコー
ル、澱粉のり等の水溶性有機バインダーを用いることが
でき、この水溶性有機バインダーを脱臭性組成物の全量
に対して、1〜25重量%含有することが望ましい。特
にメチルセルロースを用いることが好ましい。
As the binder, a water-soluble organic binder such as methyl cellulose, carboxymethyl cellulose, polyvinyl alcohol, or starch paste can be used, and the water-soluble organic binder is used in an amount of 1 to 25% by weight based on the total amount of the deodorant composition. % Content is desirable. It is particularly preferable to use methyl cellulose.

【0013】粘土状物質は成形時の可塑剤として配合さ
れるものである。粘土状物質としては木節粘土、蛙目粘
土、ベントナイト等を用いることができる。粘土状物質
の含有量は、脱臭性組成物の全量に対して、3〜30重
量%であることが望ましい。すなわち、この粘土状物質
の含有量が、脱臭性組成物の全量に対して、3重量%未
満の場合には、粒状、ハニカム等への成形性、保形性を
高める効果を十分に得ることができず、30重量%を越
える場合には、活性炭の相対的な割合が小さくなり、十
分な脱臭性能を得ることができなくなる恐れがある。
The clay-like substance is added as a plasticizer during molding. As the clay-like substance, kibushi clay, frog eye clay, bentonite and the like can be used. The content of the clay-like substance is preferably 3 to 30% by weight based on the total amount of the deodorant composition. That is, when the content of the clay-like substance is less than 3% by weight with respect to the total amount of the deodorant composition, it is possible to sufficiently obtain the effect of enhancing the formability into granular particles, honeycombs, etc., and the shape retention. When it exceeds 30% by weight, the relative proportion of activated carbon becomes small, and there is a possibility that sufficient deodorizing performance cannot be obtained.

【0014】前記の含有量に配合したものを混合・混練
することで脱臭性組成物を得ることができるものであ
り、これを押し出し成形等で成形を行い、さらに乾燥す
ることで、粒状の脱臭性組成物、ハニカム状の脱臭性組
成物等を調整することができる。水溶性バインダーや粘
土状物質の配合によって、粒状、ハニカム状への成形
性、保形性を得ることができるため、原料の混合・混
練、成形、乾燥という簡単な製造方法で粒状の脱臭性組
成物、ハニカム状の脱臭性組成物等を製造することが可
能になるものである。
A deodorizing composition can be obtained by mixing and kneading the components blended in the above-mentioned contents, and the deodorizing composition is molded by extrusion molding or the like and further dried to obtain a granular deodorizing composition. Composition, a honeycomb-shaped deodorizing composition, and the like can be prepared. By mixing water-soluble binders and clay-like substances, it is possible to obtain granular and honeycomb formability and shape retention. It is possible to produce a deodorant composition in the form of a product, a honeycomb or the like.

【0015】[0015]

【作用】本発明の請求項1に係る脱臭性組成物は、活性
炭粉末と、バインダーと、粘土状物質を含む可塑剤と、
酸化亜鉛とを含有する脱臭性組成物であって、酸化亜鉛
の含有量が、脱臭性組成物の全量に対して、1〜40重
量%であるので、悪臭に対する吸着脱臭性能及び成形性
に優れる。
The deodorizing composition according to claim 1 of the present invention comprises activated carbon powder, a binder, and a plasticizer containing a clay-like substance,
A deodorant composition containing zinc oxide, wherein the content of zinc oxide is 1 to 40% by weight with respect to the total amount of the deodorant composition, and thus the composition has excellent adsorption and deodorizing performance against malodor and moldability. .

【0016】本発明の請求項2に係る脱臭性組成物は、
ケイ酸アルミニウムをも含有し、酸化亜鉛及びケイ酸ア
ルミニウムの含有量が、脱臭性組成物の全量に対して、
1〜30重量%であり、ケイ酸アルミニウム1重量部に
対して、酸化亜鉛2.5〜20重量部の割合で含有する
ので、悪臭に対する吸着脱臭性能が向上する。
The deodorizing composition according to claim 2 of the present invention is
Also containing aluminum silicate, the content of zinc oxide and aluminum silicate, relative to the total amount of the deodorant composition,
The amount is 1 to 30% by weight, and the content of zinc oxide is 2.5 to 20 parts by weight with respect to 1 part by weight of aluminum silicate, so that the adsorption and deodorization performance against bad odor is improved.

【0017】本発明の請求項3に係る脱臭性組成物は、
前記バインダ−が、メチルセルロース、カルボキシメチ
ルセルロース、ポリビニルアルコール及び澱粉のりから
なる群から選択される少なくとも1種の水溶性有機バイ
ンダーであり、この水溶性有機バインダーを脱臭性組成
物の全量に対して、1〜25重量%含有するので、成形
性に優れる。
The deodorizing composition according to claim 3 of the present invention is
The binder is at least one water-soluble organic binder selected from the group consisting of methyl cellulose, carboxymethyl cellulose, polyvinyl alcohol and starch paste, and the water-soluble organic binder is used in an amount of 1 relative to the total amount of the deodorant composition. Since it is contained in an amount of up to 25% by weight, it has excellent moldability.

【0018】本発明の請求項4に係る脱臭性組成物は、
前記粘土状物質が木節粘土、蛙目粘土及びベントナイト
からなる群から選択される少なくとも1種を含み、か
つ、前記粘土状物質の含有量が脱臭性組成物の全量に対
して、3〜30重量%であるので、成形性に優れる。
The deodorizing composition according to claim 4 of the present invention is
The clay-like substance contains at least one selected from the group consisting of Kikibushi clay, frog clay and bentonite, and the content of the clay-like substance is 3 to 30 with respect to the total amount of the deodorant composition. Since it is wt%, it has excellent moldability.

【0019】[0019]

【実施例】以下本発明を実施例によって具体的に説明す
る。
EXAMPLES The present invention will be specifically described below with reference to examples.

【0020】(実施例1〜実施例12)脱臭性組成物の
全量に対する重量%で示した表1及び表2の配合量に従
って、石炭を出発物質とし、水蒸気賦活処理した200
メッシュアンダーの微粉末活性炭に、酸化亜鉛、ケイ酸
アルミニウム、メチルセルロース、粘土状物質として蛙
目粘土を配合し、混合・混練して脱臭性組成物を得た。
さらに得られた脱臭性組成物を押し出し成形して乾燥す
ることで、200セル/インチ2 のハニカムを成形し
た。
(Examples 1 to 12) Steam activation treatment was performed using coal as a starting material according to the blending amounts shown in Tables 1 and 2 in% by weight based on the total amount of the deodorant composition.
Zinc oxide, aluminum silicate, methyl cellulose, and frog-eyed clay as a clay-like substance were mixed with fine powdered activated carbon of mesh under, mixed and kneaded to obtain a deodorant composition.
The resulting deodorant composition was extruded and dried to form a honeycomb having 200 cells / inch 2 .

【0021】[0021]

【表1】 [Table 1]

【0022】[0022]

【表2】 [Table 2]

【0023】(比較例1〜比較例6)脱臭性組成物の全
量に対する重量%で示した表3の配合量に従って、実施
例1と同様にして、脱臭性組成物を得て、ハニカムを成
形した。
(Comparative Examples 1 to 6) Deodorizing compositions were obtained in the same manner as in Example 1 according to the compounding amounts shown in Table 3 in% by weight relative to the total amount of the deodorizing compositions to form honeycombs. did.

【0024】なお、比較例1は酸化亜鉛を配合しなかっ
たもの、比較例2は過剰に酸化亜鉛を配合したものであ
る。また、比較例3及び比較例5は粘土状物質を配合し
なかったもの、比較例4及び比較例6はメチルセルロー
スを配合しなかったものである。
In Comparative Example 1, zinc oxide was not mixed, and in Comparative Example 2, zinc oxide was excessively mixed. Further, Comparative Examples 3 and 5 are those in which the clay-like substance is not blended, and Comparative Examples 4 and 6 are those in which methyl cellulose is not blended.

【0025】[0025]

【表3】 [Table 3]

【0026】前記のようにして作製したハニカム活性炭
について、排気ガス臭に対する脱臭性能を評価した。脱
臭性能評価試験は、このハニカム活性炭に、SV(空間
速度:風量/ハニカム体積)=170000[1/h]
でディーゼル発電機から排出される排気ガスを通過させ
て行った。この排気ガス臭は採取後、表4に示す6段階
臭気強度表示法で5(強烈なにおい)に調整したもので
ある。脱臭性能はハニカム通過後の排気ガス臭のにおい
の強さを、6人のパネルに表4に示す6段階臭気強度表
示法に従って官能評価させ、各パネルの評価値を上下カ
ット、残り4名の平均値により比較した。結果を表5に
示した。
The honeycomb activated carbon produced as described above was evaluated for deodorizing performance against exhaust gas odor. In the deodorization performance evaluation test, SV (space velocity: air volume / honeycomb volume) = 17,000 [1 / h] was applied to this honeycomb activated carbon.
The exhaust gas emitted from the diesel generator was passed through. This exhaust gas odor was adjusted to 5 (strong odor) by the 6-step odor intensity display method shown in Table 4 after collection. For the deodorizing performance, the odor intensity of the exhaust gas odor after passing through the honeycomb was sensory-evaluated on the panel of 6 persons according to the 6-level odor intensity display method shown in Table 4, and the evaluation value of each panel was cut up and down. The average value was compared. The results are shown in Table 5.

【0027】[0027]

【表4】 [Table 4]

【0028】[0028]

【表5】 [Table 5]

【0029】また、ハニカムへの押し出し成形時に、成
形性、保形性について目視にて判定し、成形性良好を
「○」、成形性やや良好を「△」、成形性不良を「×」
の3段階で評価して表5に示した。
Further, at the time of extrusion molding into a honeycomb, the moldability and the shape-retaining property were visually judged, and the moldability was “good”, the moldability was slightly good, and the poor moldability was “x”.
The results are shown in Table 5.

【0030】表5から明らかなように、実施例は比較例
に比べて、多種多様な分子が複合されているたばこ臭、
生ゴミ臭及びトイレ臭等の生活回りの悪臭並びにバス、
トラック及び自動車等からの排気ガス臭等に対して、高
い脱臭性能を発現していることが確認された。また、実
施例は比較例に比べて、成形性が良好であった。
As is clear from Table 5, the examples have a tobacco odor in which various kinds of molecules are combined, as compared with the comparative examples.
Offensive odors such as kitchen garbage and toilet odors and buses,
It was confirmed that high deodorizing performance was exhibited against exhaust gas odor from trucks and automobiles. The moldability of the example was better than that of the comparative example.

【0031】なお、粘土状物質として蛙目粘土のみでな
く、木節粘土、蛙目粘土及びベントナイトからなる群か
ら選択される少なくとも1種を使用することにより、ほ
ぼ同様の結果が得られた。
It should be noted that substantially the same result was obtained by using not only the frog-eyed clay but also at least one selected from the group consisting of Kikibushi clay, frog-eyed clay and bentonite as the clay-like substance.

【0032】[0032]

【発明の効果】本発明の請求項1に係る脱臭性組成物に
よると、活性炭が本来有している吸着性能に加え、酸化
亜鉛の配合により、多種多様な分子が複合されているた
ばこ臭、生ゴミ臭及びトイレ臭等の生活回りの悪臭並び
にバス、トラック及び自動車等からの排気ガス臭等に対
して効果的に脱臭することができる。
According to the deodorizing composition according to the first aspect of the present invention, in addition to the adsorption performance originally possessed by activated carbon, a tobacco odor in which a wide variety of molecules are compounded by blending zinc oxide, It is possible to effectively deodorize offensive odors such as kitchen garbage and toilet odors and exhaust gas odors from buses, trucks, automobiles and the like.

【0033】本発明の請求項2に係る脱臭性組成物によ
ると、ケイ酸アルミニウムをも含有するので、悪臭に対
する吸着脱臭性能が、さらに向上する。
Since the deodorizing composition according to the second aspect of the present invention also contains aluminum silicate, the adsorptive deodorizing performance against a bad odor is further improved.

【0034】本発明の請求項3及び請求項4に係る脱臭
性組成物によると、成形性に優れ、混合・混練、成形、
乾燥という簡便な方法で粒状の脱臭性組成物、ハニカム
状の脱臭性組成物等の成形体を得ることができる。
According to the deodorizing composition according to claims 3 and 4 of the present invention, the moldability is excellent, and mixing / kneading, molding,
A molded body such as a granular deodorant composition or a honeycomb deodorant composition can be obtained by a simple method of drying.

フロントページの続き (72)発明者 中川 尚治 大阪府門真市大字門真1048番地松下電工株 式会社内 (72)発明者 山内 俊幸 大阪府門真市大字門真1048番地松下電工株 式会社内(72) Inventor Shoji Nakagawa 1048, Kadoma, Kadoma City, Osaka Prefecture Matsushita Electric Works Co., Ltd. (72) Toshiyuki Yamauchi, 1048, Kadoma, Kadoma City, Osaka Matsushita Electric Works Co., Ltd.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 活性炭粉末と、バインダーと、粘土状物
質を含む可塑剤と、酸化亜鉛とを含有する脱臭性組成物
であって、酸化亜鉛の含有量が、脱臭性組成物の全量に
対して、1〜40重量%であることを特徴とする脱臭性
組成物。
1. A deodorizing composition containing activated carbon powder, a binder, a plasticizer containing a clay-like substance, and zinc oxide, wherein the content of zinc oxide is relative to the total amount of the deodorizing composition. And 1 to 40% by weight, a deodorant composition.
【請求項2】 ケイ酸アルミニウムをも含有し、酸化亜
鉛及びケイ酸アルミニウムの含有量が、脱臭性組成物の
全量に対して、1〜30重量%であり、ケイ酸アルミニ
ウム1重量部に対して、酸化亜鉛2.5〜20重量部の
割合で含有することを特徴とする請求項1記載の脱臭性
組成物。
2. The composition also contains aluminum silicate, and the content of zinc oxide and aluminum silicate is 1 to 30% by weight based on the total amount of the deodorant composition, and relative to 1 part by weight of aluminum silicate. The deodorizing composition according to claim 1, wherein the zinc oxide is contained in a proportion of 2.5 to 20 parts by weight.
【請求項3】 前記バインダ−が、メチルセルロース、
カルボキシメチルセルロース、ポリビニルアルコール及
び澱粉のりからなる群から選択される少なくとも1種の
水溶性有機バインダーであり、この水溶性有機バインダ
ーを脱臭性組成物の全量に対して、1〜25重量%含有
することを特徴とする請求項1又は請求項2記載の脱臭
性組成物。
3. The binder is methyl cellulose,
At least one water-soluble organic binder selected from the group consisting of carboxymethyl cellulose, polyvinyl alcohol, and starch paste, and containing 1 to 25% by weight of the water-soluble organic binder with respect to the total amount of the deodorant composition. The deodorant composition according to claim 1 or 2, characterized in that.
【請求項4】 前記粘土状物質が木節粘土、蛙目粘土及
びベントナイトからなる群から選択される少なくとも1
種を含み、かつ、前記粘土状物質の含有量が脱臭性組成
物の全量に対して、3〜30重量%であることを特徴と
する請求項1乃至請求項3いずれか記載の脱臭性組成
物。
4. The clay-like material is at least one selected from the group consisting of kibushi clay, frog eye clay and bentonite.
The deodorant composition according to any one of claims 1 to 3, further comprising a seed, and the content of the clay-like substance is 3 to 30% by weight based on the total amount of the deodorant composition. Stuff.
JP7070129A 1995-03-28 1995-03-28 Deodorizing composition Expired - Fee Related JP3052231B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7070129A JP3052231B2 (en) 1995-03-28 1995-03-28 Deodorizing composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7070129A JP3052231B2 (en) 1995-03-28 1995-03-28 Deodorizing composition

Publications (2)

Publication Number Publication Date
JPH08257107A true JPH08257107A (en) 1996-10-08
JP3052231B2 JP3052231B2 (en) 2000-06-12

Family

ID=13422647

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7070129A Expired - Fee Related JP3052231B2 (en) 1995-03-28 1995-03-28 Deodorizing composition

Country Status (1)

Country Link
JP (1) JP3052231B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20190065986A (en) * 2019-05-23 2019-06-12 최승국 air purifying agent with excellent antibacterial and deodorizing activity
CN112484037A (en) * 2020-11-03 2021-03-12 李洪 Deodorant for compatibility of RDF and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20190065986A (en) * 2019-05-23 2019-06-12 최승국 air purifying agent with excellent antibacterial and deodorizing activity
CN112484037A (en) * 2020-11-03 2021-03-12 李洪 Deodorant for compatibility of RDF and application thereof

Also Published As

Publication number Publication date
JP3052231B2 (en) 2000-06-12

Similar Documents

Publication Publication Date Title
JP4102364B2 (en) Deodorant carbon nanoball with multi-layer structure
CN100491242C (en) Activated carbon metal oxide matrix and method for making same
JP2939049B2 (en) Deodorant and method for producing the same
EP1578457B1 (en) Carbon nanoball for deodorization
JP3026339B2 (en) Deodorizing composition
KR20190138024A (en) Deodorant and Method for Producing the Same
JPH08259344A (en) Porous adsorbing material
JPH08257107A (en) Deodorizing composition
JPH07313867A (en) Deodorant composition
JP3745857B2 (en) Deodorizing agent, deodorizing filter and deodorizing device using the same
JPH11553A (en) Deodorizing material and its production
JP2701062B2 (en) Composite adsorbent
JP2950683B2 (en) Air purifier and air purifier
JP2017064048A (en) Deodorant and deodorant filter with the deodorant
JP3060801B2 (en) Deodorizing composition
JP3029764B2 (en) Deodorant
JP4562838B2 (en) Gel deodorant
JPH08266599A (en) Deodorant composition
JP2002191966A (en) Deodorizing composition
JPH09154927A (en) Deodorizing material
JP3945369B2 (en) Deodorant
JPH06121823A (en) Deodorant
JP2831180B2 (en) Deodorant
JPH0716422A (en) Deodorizing material
JP2001321426A (en) Deodorant and method for deodorizing

Legal Events

Date Code Title Description
FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080407

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090407

Year of fee payment: 9

LAPS Cancellation because of no payment of annual fees