JPH08239305A - Repelling tool for bird and animal - Google Patents

Abstract

PURPOSE: To provide a bird and animal repelling tool composed of a foamed material consisting of a sulfide compound or a material containing sulfide compound, a repelling perfume and a synthetic polymer, having high repelling effect per unit area, producible at a low cost and exhibiting excellent repelling effect on birds and animals. CONSTITUTION: This bird and animal repelling tool is composed of a foamed material consisting of a sulfide compound or a material containing a sulfide compound, a repelling perfume and a synthetic polymer. It has high disposition flexibility and shape flexibility and is effective for restricting the movement of birds and animals such as cat, dog, rat and bird scattering feces in the living space of human and having daily actions harmful for human. The sulfide- containing material is preferably onion oil, leek oil and garlic oil. The repelling perfume is cinnamic oil, cinnamaldehyde, cinnamic alcohol, etc. The foamed state and foaming ratio of the repelling tool can be adjusted by the use of the synthetic polymer. The amounts of the sulfide compound and the repelling perfume are 0.5-30wt.% and 5-300wt.% based on 100wt.% of the synthetic polymer, respectively.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention has installation adaptability and shape adaptability, and scatters manure in a human living space,
The present invention relates to a repellent device for restricting the behavior of wildlife such as cats, dogs, mice, and birds whose life activities harm humans.

[0002]

2. Description of the Related Art In recent years, urbanization has progressed and various animals and birds have settled in the city. Under such circumstances, cats, dogs, etc. scatter manure in the living space of humans and Doing harm. As a place where this excrement and harm are caused, especially in sandboxes such as parks, kindergartens and nursery schools, the rate of excrement of feces there is extremely high, causing a bad odor, parasites, protozoa and pathogenic substances contained in the excrement. Bacteria make it unsanitary, especially when kindergarten and nursery school children play sand in this sandbox, the problem of hygiene such as putting things directly into the mouth with their hands becomes a problem, and moreover, the manure The excretion action to do so also causes many damages such as digging the flowerbeds by digging up the flower beds. In addition, especially in the living space of human beings, the ecology of the rats has been confirmed indoors, for example, by invading a house through a drainage outlet to scavenge leftover food and drip sewage, which is a sanitary problem, to cause damage. It causes problems and, in severe cases, bites parts of the human body, which is a problem. Furthermore, especially in birds such as pigeons, sparrows and crows, they settle down in the fields and under the eaves of houses, feed crops, drop manure on balustrades and under the eaves, and give offensive odor to humans. It has problems such as fear of transmitting diseases such as Aum disease.

As a repellent for cats, dogs, mice, birds and other birds and animals that cause various kinds of damage to humans, it is generally practiced to keep them away from the place of damage. However, those containing many forms of repellent have been commercialized. Among them, as a repellent for cats, dogs and birds, fragrance-derived ingredients such as cinnamon oil, cinnamic aldehyde, and d-limonene are used to impregnate or add to a suitable base material, As is, or in the form of granules, the method of spraying in the garden or sandbox where cats, dogs and birds are likely to approach. Further, in mice, such repellents are not effective, and cycloheximide or capsaicin is mixed with a synthetic resin such as vinyl chloride, which is likely to cause a rat, and molding is performed so that the mice are not bitten. Further, in those used in general households, etc., they are killed by incineration by using sticky so-called "rats" that are provided with an inducer and are destroyed by incineration.

Further, JP-A-1-139515 discloses a repellent composition for dogs, cats and birds containing as an active ingredient a powder of a plant containing a spicy spice or a powder of a plant containing an aromatic spice. Japanese Unexamined Patent Publication No. 3-74306 discloses a bird and beast containing an odorant having an odor-changing effect of deodorizing and modifying the body odor, excrement odor, feed odor, living odor and environmental odor of birds and animals as an active ingredient. Repellents and birds and animals repellents each containing one or more of the above-mentioned deodorants and sensory stimulants that stimulate the skin, mucous membranes, etc. that sense taste, odor, pain, etc. as active ingredients are disclosed, respectively. There is. Further, the present inventors have proposed a repellent device for cats or dogs in which the above-mentioned repellent agent is contained in a polyurethane foam in Japanese Patent Application No. 6-126284.

[0005]

Therefore, the conventional method has various problems. That is, as a repellent used in birds and animals, cinnamon oil, cinnamic aldehyde, cinnamic alcohol, d-limonene, terpineol, lemongrass oil, methylnonylketone, methylphenylketone, green leaf alcohol, green leaf aldehyde, menthol, In the conventional fragrance ingredients such as citral and pine oil, the repellent ability per unit was weak and the repellent effect was weak. Further, the method of kneading and mixing a synthetic resin such as vinyl chloride with cycloheximide, capsacin, etc. is effective in preventing the bite, but it is impossible to prevent them from coming close to each other. Furthermore, in the conventional "mouse harvesting" that is commercially available, if an oily substance adheres to the limbs of the mouse, the adhesive effect is weakened and the mouse cannot be caught.

Further, in the technique disclosed in Japanese Patent Laid-Open No. 1-139515, granules and repellent compositions prepared from powders of hot spicy spices such as onions or aromatic spices and raw materials such as starch are disclosed. The pores of porous materials such as cristobalite are impregnated.For example, granules collapse during rainfall, so there are problems with persistence such as unusable during the rainy season. If the pores are impregnated, the repellent will volatilize quickly in the summer when the temperature is high, and the repellent effect will decline in a short period of time. As a result, the earliest is 3 days, and the slower is about 10 days. There were various problems such as the disappearance of the repellent effect and the problem of sustainability, and the volatility of the effect could not be adjusted. Furthermore, JP-A-3
According to Japanese Patent Laid-Open No. 74306, even granules, powders, emulsions, and simple aerosols have the same problems as described above, such as disintegration during rainfall and volatilization in summer. In Japanese Patent Application No. 6-126284 proposed by the present inventors, the above-mentioned conventional repellent is used, and there is no problem in installation adaptability, shape adaptability, sustainability, etc., and depending on the type of repellent, In some cases, the repellent effect diminished, and as a result, cats had problems such as dropping feces in the area where the repellent device was installed. In addition, the effect was not found on all dogs, cats, mice, or birds, and a repellent suitable for the repellent target had to be used. In this way, with the granules, powders, emulsions, and simple aerosols of the above-mentioned technology, it is not possible to consider the installation location on the bottom surface of the top plate, vertical wall surface, etc. The installation adaptability and shape adaptability have been improved accordingly.

[0007]

Therefore, the present invention solves these problems and has a stronger repellent effect per unit area than conventional repellents, and further, it is possible to adjust sustainability and adaptability to installation. Another object of the present invention is to provide a repellent device for animals and animals which can obtain shape adaptability and has repellent effect on birds and animals such as dogs, cats, mice and birds, which does not require replacement and the like.

The above problems can be solved by a bird and animal repellent which is a foam made of a sulfide compound or a substance containing a sulfide compound, a repellent fragrance and a synthetic polymer. Such a sulfide compound contains an SH group, and in particular, an organic sulfide compound can be used. Specific examples of the sulfide compound include dimethyl sulfide, allyl methyl sulfide, methyl propenyl sulfide, dimethyl disulfide, allyl propyl sulfide, propyl propenyl sulfide, methyl propyl disulfide, methyl-
(Z) -propenyl disulfide, methyl- (E) -propenyl disulfide, dimethyl trisulfide, propyl isopropyl disulfide, dipropyl disulfide, propyl allyl, propyl- (Z) -propenyl disulfide, diallyl disulfide, propyl- (E)
-Propenyl disulfide, allyl propenyl disulfide, dipropenyl disulfide, methylpropyl trisulfide, methylallyl trisulfide, methyl-
(Z) -propenyl trisulfide, methyl- (E)-
Propenyl trisulfide, diisopropyl trisulfide, propyl isopropyl trisulfide, etc. can be illustrated, and the 1 type (s) or 2 or more types selected from the illustrated can also be used.

Further, as the sulfide compound-containing substance, an extract obtained from the genus Allium can be used. From the bulbs, flower stems, rhizomes, bulbs, leaves, stems, etc. of the genus Allium, steam distillation method, compression method, solvent extraction method with organic solvent such as petroleum ether or alcohol, oil adsorption method by adsorption of oils, propane, butane, etc. Unfoamed synthetic polymer using one or more selected from onion oil, garlic oil and leak oil obtained by liquefied gas extraction method using liquefied gas, supercritical extraction method, etc. It is particularly preferable because it has excellent mixing properties with and is easily available. Further, as the sulfide compound-containing material, it is possible to use dried or fresh products such as bulbs, flower stems, rhizomes, bulbs, leaves and stems of Allium, and further, powdery or granular products of the present invention. It can be used as a bird and animal repellent.
A specific example of the genus Allium belongs to the genus Allium in taxonomic terms.
ium fistulosum L. ), Onion (A
Illium cepa L. ), Chinese chive (Allium)
tuberosum L. ), Leek (Allium)
porrum L. ), Garlic (Allium s)
ativum L. ), Rakkyo (Allium c)
hinense L. ), Asatsuki (Allium l)
edebourianum L. ), Wakegi (Alli
um wakegi Araki) and the like.

As the repellent fragrance, those having a repellent effect can be used, but preferably cinnamon oil, cinnamic aldehyde, cinnamic alcohol, d-limonene, terpineol, lemongrass oil, which has little effect on the human body. , One or more selected from methyl nonyl ketone, methyl phenyl ketone, green leaf alcohol, green leaf aldehyde, menthol, citral, pine oil, etc. are appropriately used.

The synthetic polymer used in the bird and animal repellent of the present invention preferably forms a foam, for example, a synthetic resin. As the synthetic resin, a porous material having a particularly large surface area can be used, and examples thereof include foams such as polyurethane, polystyrene, polyacrylate, polyester, polylactic acid, polycaprolactone, and polyglycolic acid. Further, cellulose, a derivative of cellulose, starch or the like can be mixed with this synthetic polymer.

The bird and animal repellent of the present invention can be prepared by the following method in order to add the sulfide compound or the sulfide compound-containing substance and the repellent fragrance to the above-mentioned synthetic polymer. First, in the case of obtaining a bird and animal repellent of polyurethane foam using a urethane resin which is one of synthetic resins, a compound having an isocyanate group, a foaming agent, a sulfide compound or a compound containing a sulfide compound and a repellent fragrance are mixed. Can be foamed.
As the compound having an isocyanate group, a prepolymer having an active isocyanate group obtained by reacting a polyisocyanate compound and a polyether polyol is used, and this prepolymer, a polyisocyanate compound, a polyol, a sulfide compound or a sulfide compound is used. The bird and animal repellent of the present invention can be obtained by obtaining a foam using the content, the repellent fragrance, the catalyst, and the foaming agent. Here, as a method for producing the polyurethane foam, it is possible to carry out by a prepolymer method or a one-shot method according to a conventional method, but in order to obtain a long-lasting repellent effect or to obtain a repellent effect over a wide range. Also, in the present invention, as described above, first, a prepolymer is prepared, and in the process of further reacting this with a polyisocyanate compound and a polyol, the sulfide compound or the sulfide compound-containing material and the repellent perfume are retained, thereby It can be contained in a large amount as compared with the shot method.

Specific examples of the compound having an isocyanate group or the polyisocyanate compound used in such a repellent for birds and animals include toluene diisocyanate (TDI), diphenylmethane diisocyanate and 1,6-hexamethylene diisocyanate. (HD
It is possible to use I), 2,2,4-trimethyl-hexamethylene diisocyanate (TMDI), p-phenylene diisocyanate (PPDI), and modified types thereof. Furthermore, one or a combination of two or more selected from the polyisocyanate compounds listed here may be used.

Further, examples of the polyol include low molecular weight polyol and high molecular weight polyol. Specific examples of the high molecular weight polyol include polyether polyol, polyester polyol, polyether ester polyol, hydrocarbon backbone polyol, graft polyol, polyuric acid-dispersed polyol and the like. As a starting material for producing such a polyol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerin, trimethylolpropane, etc. are used, and one or more kinds selected from those listed here are used. You may use what combined.

Further, as the catalyst, N, N-dimethylcyclohexylamine, N, N-dicyclohexylmethylamine, N, N-dimethylcetylamine, 2-methyl-
Triethylenediamine, triethanolamine, methyldiethanolamine, N, N-dimethylaminoether, ethoxylate hydroxyamine, N, N, N'-
Trimethylaminoethylethanolamine, N, N,
There are amines such as N′-trimethylaminopropylethanolamine, and other organic carboxylic acid salts such as zinc, lead, tin, copper, etc., and one or more selected from those listed here. You may use what combined the thing. Moreover, the thing similar to this is also used.

Water is used as a foaming agent for foaming such polyurethane. Further, as a foaming agent and a propellant, liquefied petroleum gas (LPG), dimethyl ether (DME), alternative CFCs (HCFC123, HFC)
-134a etc.) and the like are used.

Further, a foam stabilizer may be used if necessary. As the foam stabilizer, a surfactant containing silicone or the like is used. Specifically, there are silicone-based surfactants such as polyether-modified, alkylaralkylpolyether-modified, epoxypolyether-modified, alcohol-modified, fluorine-modified, amino-modified, mercapto-modified, epoxy-modified, and allyl-modified. It is preferable to use one kind or two or more kinds selected from the above.

As the synthetic resin to be foamed, a one-component curing type synthetic resin may be used, and the synthetic resin in an unfoamed state is filled in a spray container and foamed at the same time as pouring or coating. It is also possible to start. Furthermore, when a two-component curable foamable synthetic resin is used as the synthetic resin, the unfoamed synthetic resin and the curing agent are respectively filled in a spray container and mixed at the same time as pouring or coating to foam. It can also be cured to obtain a bird and animal repellent. Alternatively, a synthetic resin and a curing agent may be mixed before installation and installed while foaming. Further, it is possible to give an adhesive force to the synthetic resin.

When a bird repellent of an acrylic resin foam is obtained by using an acrylic resin in addition to the above polyurethane foam, the acrylic resin, the foaming agent, the sulfide compound or the sulfide compound-containing material, and the repellent property are used. A fragrance can be mixed and foamed. That is, as the acrylic resin, a homopolymer or copolymer containing acrylic acid, methyl acrylate, ethyl acrylate, methacrylic acid, methyl methacrylate, ethyl methacrylate, styrene or the like is used, and the blowing agent is also a propellant. LP
G, DME, CFC substitute, etc. can be used. The acrylic resin foam may be used in combination with the above homopolymer and copolymer. Silicon, a surfactant, and an emulsifier can be used if necessary. Then, a mixed solution obtained by mixing the acrylic resin, the foaming agent, the sulfide compound or the sulfide compound-containing material, and the repellent fragrance is enclosed in a spray container, and at the same time as pouring from the container, LPG, DME which is also a propellant. The CFC substitute plays the role of a foaming agent, and foams to obtain a foam. At this time, the sulfide compound or the sulfide compound-containing substance and the repellent fragrance become the constituent components of the partition walls of the cell which is made of the acrylic resin and constitutes the porous structure, and enables the sustained release.

By using such a synthetic resin as described above, it is possible to install it in a place where it will drop unless it is adhered to, such as a vertical wall surface or the bottom surface of the top plate, so that the installation place can be selected anywhere. The adaptability can be obtained, and further the shape adaptability can be obtained by foaming according to the shape of the place where it is installed.

The avian and animal repellent of the present invention can be adjusted in foaming state and foaming ratio by a synthetic polymer, and in the foaming state, closed cells or open cells can be appropriately selected. That is, the foaming state can be selected depending on the difference in vapor pressure at the volatile compound or the sulfide compound-containing material and the repellent fragrance and the vapor pressure at room temperature, and the use environment. For example, when the sulfide compound or the sulfide compound-containing substance and the repellent fragrance are easily volatilized, when the use environment is relatively high temperature such as summer, and when delayed action is required, the closed-cell type and the above-mentioned less volatile type are used. When the immediate effect is required when the temperature is low, such as in winter, the open cell type can be appropriately selected. Here, the open cells mean a structure in which cells, which are foaming cells, are continuously connected, and closed cells mean a structure in which individual cells are independently surrounded by partition walls without continuous connection. The sulfide compound or the sulfide compound-containing substance and the repellent fragrance are retained in the bubbles or in the partition walls, and in the case of the continuous cells, the volatile compound is easily volatilized through the bubbles, and in the case of the closed cells, the sulfide is contained. The compound or the sulfide compound-containing substance, the repellent fragrance, and the like pass through the partition walls and volatilize while controlling the sustained release. In addition, when it comes into contact with water such as rainwater, the foam such as polyurethane has a hydrophobic property, so it is difficult for it to enter, and when it is closed cells, it has a hydrophobic property and only on the surface part. Since the air bubbles are in contact with the outside air, the sulfide compound or the sulfide compound-containing substance and the repellent fragrance are prevented from flowing out. Further, when a biodegradable material such as cellulose is mixed and the foam is repelled, it is possible to save the trouble of discarding.

As described above, in the bird and animal repellent, since the sulfide compound or the substance containing the sulfide compound and the repellent fragrance are contained in the synthetic polymer, the repellent is not supported in the pores of the foam, and It will be a constituent of the partition walls of the cell.

The mixture of the sulfide compound or the sulfide compound-containing substance, the repellent fragrance, and the synthetic polymer in the bird and animal repellent is 10% by weight.
0, the sulfide compound or the sulfide compound-containing substance is 0.5 to 30, and the repellent fragrance is 5 to 300.
It is desirable that the sulfide compound or the sulfide compound-containing material is 1 to 20 and the repellent fragrance is 10 to 200. That is, when the content of the sulfide compound or the content of the sulfide compound is less than 0.5 and the content of the repellent fragrance is less than 5, the repellent effect is reduced, and the amount of the sulfide compound or the content of the sulfide compound is 3 or less.
If it is more than 0 and the amount of the repellent fragrance is more than 300, the smell of the sulfide compound is strongly irritating to humans, and the installation location must be taken into consideration. Therefore, the synthetic polymer and the sulfide compound in the bird and animal repellent device should be considered. Alternatively, the mixing ratio of the sulfide compound-containing material and the repellent flavor is preferably within the above range.

[0024]

The bird / animal repellent of the present invention contains a sulfide compound or a sulfide compound by a bird / animal repellent having an unfoamed synthetic polymer containing a sulfide compound or a sulfide compound-containing substance and a repellent fragrance. The substance and the repellent fragrance act efficiently on the odor of birds and animals to improve the repellent effect, and further, the repellent fragrance and the sulfide compound or the sulfide compound-containing substance are It becomes a constituent. When the sulfide compound-containing material is one or more kinds selected from onion oil, leak oil, and garlic oil, it is more liquid, so that the action having a better repellent effect can be obtained. The repellent fragrance is cinnamon oil,
Cinnamic aldehyde, cinnamic alcohol, d
-When one or more kinds selected from limonene, terpineol, lemongrass oil, methylnonylketone, methylphenylketone, green leaf alcohol, green leaf aldehyde, menthol, citral, and pine oil are used, the sulfide compound or By using the sulfide compound-containing material, it is possible to more efficiently evade. In addition, the sulfide compound or the sulfide compound-containing substance is 0.5 in a weight ratio with respect to the synthetic polymer 100.
Even if a bird and animal repellent having a repellent fragrance of 5 to 300 is mixed, the repellent can be efficiently repelled.

Further, the present invention is a method for causing a non-foamed bird and animal repellent containing a sulfide compound or a sulfide compound-containing substance and a repellent fragrance to be repelled by adhering to the repellent target region while foaming. Then, when repelling in this way, the bird and animal repellent is stored in a container such as a spray container or a bottle and is injected by an appropriate method such as gas ejection or pump ejection, and is directly attached to the repulsion target area. Then, it is foam-cured to form a repellent bird and animal repellent to repel it. This direct adhesion to a place for birds and animals means, for example, in a place where it is desired to regulate the invasion of birds and animals, an unfoamed state containing a sulfide compound or a sulfide compound-containing substance and a repellent fragrance at appropriate places in the invasion route. It is installed by pouring out and adhering the bird and animal repellents from the above, and allowing them to foam and harden.

Further, in the middle of the path of movement of birds and animals, for example, by applying to a gap such as a figurine or the back surface of an installation or by directly adhering it by another appropriate method and foam-curing, the foamed state can be obtained. A bird and animal repellent can be attached and formed. Further, as another method, the unfoamed synthetic polymer may be injected into a container having an appropriate shape and foam-molded at a place other than the place of installation, and the molded product may be placed at an appropriate place. That is why.

In the case where the sulfide compound or the sulfide compound-containing substance and the repellent fragrance contained in the repellent device for avian animals in a foamed state are present by using these substances directly or indirectly for birds and birds. Can vaporize and, in some cases, leak out of water and act to prevent access.

That is, in the bird and animal repellent of the present invention, the sulfide compound or the sulfide compound-containing substance and the repellent fragrance for the bird and animal are held in the unfoamed synthetic polymer, and this is applied to the target site. The sulfide compound or the sulfide compound-containing substance and the repellent fragrance are intended to act on birds and animals by adhering and foam-curing or by setting the cured foam in an appropriate shape.

Since the foamed bird and animal repellent which has released the sulfide compound or the sulfide compound-containing substance and the repellent fragrance contained therein is unnecessary, the bird and animal repellent is to be repelled. It can be easily removed by peeling it from the bonded portion of the area by hand or by a suitable means. Then, the bird and animal repellent of the present invention is newly attached and foamed and cured, so that the repellent effect can be continued again.

In order to install a foamed bird and animal repellent that has been foam-cured at a place other than the installation site, cut the foam into a piece suitable for the shape of the installation site, and place it in the area to be repelled. It is installed in the invasion route, etc., or in the middle of the movement route of birds and animals, for example, in a gap such as a figurine or the back of the installed item. In such a foamed bird and animal repellent device, the sulfide compound or the sulfide compound-containing material and the repellent fragrance are vaporized in the repellent target area, or the sulfide compound leaks due to the moisture of rainwater to act on birds and animals. , Prevent birds and animals from approaching the repellent area.

Those which have released the repellent fragrance are
From the area to be repelled, remove from the installation site by an appropriate means such as hand and dispose. And, by installing new birds and animals repellent, we will continue to prevent the invasion of birds and animals. In addition, even if the repellent fragrance and the sulfide compound or the sulfide compound-containing substance are not injected and re-injected into the bird and animal repellent, and sealed with an appropriate container or sealing material to facilitate the sustained release, the bird and animal repellent is repelled. Make it possible to reuse the equipment.

[0032]

EXAMPLES The present invention will be described based on examples. (Example 1) In Example 1, 10 parts by weight of garlic oil as a sulfide compound-containing material and 100 parts by weight of lemon grass oil as a repellent fragrance were used.
A porous polyurethane foam was prepared by the prepolymer method. The method is as follows: 70 parts by weight of PPG triol (trade name: EXCENOL 850 manufactured by Asahi Glass Co., Ltd.),
A prepolymer was prepared by reacting 10 parts by weight of diphenyl methane isocyanate (trade name: Cosmonate pH Mitsui Toatsu Co., Ltd.). And this prepolymer 8
Mixture of 0 parts by weight, 10 parts by weight of C-diphenyl methane isocyanate (trade name: Sumijour 44V20 manufactured by Sumitomo Bayer Urethane Co., Ltd.), 10 parts by weight of garlic oil, and 100 parts by weight of lemongrass oil. 1 part by weight of silicon (trade name: NUC Silicon L-3600 manufactured by Nippon Unica Co., Ltd.) and 2-
Methyl-triethylenediamine (trade name: METHYL
-DABCO Sankyo Aero Products Co., Ltd.) 1 part by weight and 2 parts by weight of water were added to a premixed mixture,
A total amount of 20 g was used for reaction and foaming to obtain a foam having a foaming ratio of 5 times in a pudding cup (100 ml capacity).

Example 2 In Example 2, 1 g of onion oil as a sulfide compound-containing material and 5 g of cinnamon oil as a repellent fragrance were used, and 60 g of an acrylic resin (trade name: MM-2002, Fujikura Kasei Co., Ltd.) 1 g of silicone (trade name: KF-96-500)
CS, manufactured by Shin-Etsu Chemical Co., Ltd.), 10 g of a surfactant (trade name: Rheodor SP-030, manufactured by Kao Corporation), 3
After dissolving 5 g of LPG and 35 g of DME in a spray container, the whole amount was sprayed (jetted) to obtain a bird and animal repellent device.

Comparative Example 1 As Comparative Example 1, Example 1 was used.
Except that the garlic oil in Example 1 was replaced with lemongrass oil, the same operation and the same bird and animal repellent device as in Example 1 were obtained.

Comparative Example 2 As Comparative Example 2, Example 2 was used.
Except for replacing the onion oil in Example 1 with cinnamon oil, the same operation as in Example 2 and the same bird and animal repellent device were obtained.

(Test for Cats) First, for cats, 5
g of each Example or Comparative Example, 50 g of cat food (trade name: manufactured by Monpetit Gold Frisky Co., Ltd.)
To prepare a bait. And to check the repellent effect against cats, put a container containing 55 g of food in one space and put 20 hungry cats (hybrid) in the other space, It was observed whether the hybrids ingested food. The results are shown in Table 1.

[0037]

[Table 1]

From Table 1, 90% or more of the cats did not ingest food in the examples, but 90% or more of the cats in the comparative examples did. As a result, the effect was recognized in cats.

(Test for dogs) First, for dogs, 5
Each 50 g of each Example or Comparative Example was mixed with 50 g of dog food (trade name: Pedigly Cham Master Foods Limited) to prepare 55 g of food. And how to check the repellent effect for dogs is to put a container containing 55 g of food in one space and put 20 hungry Shiba Inu in the other space, how many Shiba Inu ingest the food. I observed what to do. The results are shown in Table 2.

[0040]

[Table 2]

From Table 2, 90% or more of the dogs in the Examples did not ingest, whereas 90% or more of the dogs in the Comparative Example ingested the food. As a result, the effect was recognized also in dogs.

(Test for Mouse) First, for mouse, 5
g of each Example or Comparative Example was mixed with 50 g of grated cheese (palmesan cheese) to prepare 55 g of grated cheese. To confirm the repellent effect against mice, place a container containing 55 g of grated cheese in one space and put 20 hungry rat rats in the other space, how many dog rats will eat the grated cheese. I observed what to do. Table 3 shows the results.

[0043]

[Table 3]

From Table 3, in the examples, the number of mice that did not eat food was 90% or more, while in the comparative example, 90.
% Or more were eating food. As a result, the effect was recognized also on the mouse.

(Test for Birds) Thickness of 5 for birds
A transparent acrylic resin plate having a diameter of 25 mm and a partition plate having a hole with a diameter of 25 cm at the center is installed to divide a volume into two to make a 1 m × 1 m × 1 m container. Each Example or Comparative Example and 20 budgerigars were put and the behavior was observed. Then, the observation confirmed how many animals moved to the other room due to the influence of the repellent fragrance. The results are shown in Table 4.

[0046]

[Table 4]

From Table 4, 90% or more of the budgerigars migrated in the examples. However, in the comparative example, 90% or more did not move. As a result, it was confirmed that it was effective against birds.

[0048]

INDUSTRIAL APPLICABILITY According to the bird and animal repellent of the present invention, the use of the sulfide compound or the sulfide compound-containing substance and the repellent fragrance enhances the repellent effect per unit amount, and repels the conventional repellent object. The fragrance is effective for all birds and animals, it is cheap in cost, and it becomes a constituent component of the cell partition wall of a porous material such as polyurethane foam. In areas where the damage has occurred, the damage can be stopped more effectively, and it can be avoided for a long time. Also, if you use onion oil, leak oil, garlic oil, etc., the repellent effect will work more efficiently, so you can repel it in a small amount, so you can keep the sandbox such as parks and kindergartens clean from birds and animals. it can. Further, the repellent fragrance is in cinnamon oil, cinnamic aldehyde, cinnamic alcohol, d-limonene, terpineol, lemongrass oil, methyl nonyl ketone, methyl phenyl ketone, green leaf alcohol, green leaf aldehyde, menthol, citral, pine oil. It can be efficiently repelled even if one or two or more selected from the above are used, and further, it is harmless to the human body and can be repelled for a long period of time, so it does not take time and cost. Is also cheap. By using a bird and animal repellent having a sulfide compound content of 0.5 to 30% by weight with respect to 100 of the synthetic polymer and a repellent fragrance of 5 to 300, the repellent can be repelled more efficiently.

Further, since it has been foamed, it is enclosed in a spray container or the like to repel it by foaming during or before installation in the area to be repelled. Is obtained. Then, it appears as an action that balances the excellent repellent effect and its sustainability in any place, and prevents the outflow of the sulfide compound or the sulfide compound-containing substance and the repellent fragrance for a long period of time even against rainfall or snowfall. It becomes possible to evade birds and animals.

The installation adaptability and the shape adaptability can be obtained and the foaming can be achieved by selecting either the pouring method or the application method as the installation method, which can be easily avoided. Further, even if the repellent device foamed by such a method is foam-molded into any of a granular shape, a pellet shape, and a block shape, the repellent effect can be obtained according to various handling.

The difference between open cells and closed cells in the foam is selected according to various physical properties such as volatility of the sulfide compound or the sulfide compound-containing material used and the repellent fragrance. That is, since the open cells are connected by cells that are bubbles and the contact area with the outside air is increased, the sulfide compound or the sulfide compound-containing substance and the repellent fragrance are easily moved in the foamed repellent device, and have low volatility. Even a sulfide compound or a substance containing a sulfide compound and a repellent fragrance can provide a moderate sustained action. In addition, closed cells exist independently with one cell surrounded by partition walls, and since only the cells are the contact surface with the outside air on the surface of the foamed repellent device, the volatile compound with high volatility and low volatility is used. Alternatively, the sulfide compound-containing substance and the repellent fragrance permeate through the cell partition walls, and a sustained release action is obtained. Further, the open cells act so as to enable selection of the delayed effect or the immediate effect of the repellent action when the same sulfide compound or the sulfide compound-containing substance and the repellent fragrance are used. In this way, the closed cells and open cells can be used properly even if the physical properties of the sulfide compound or the sulfide compound-containing material and the repellent fragrance used are changed.
It has an excellent action in terms of obtaining a more stable effect, and has a sustained release action in repelling birds and animals, and also prevents rainwater from entering, providing a long-lasting repellent effect, and is suitable for installation. The effect of flexibility and shape adaptability works, producing excellent effects such as easy installation.

By storing the foamed repellent containing a sulfide compound or a sulfide compound-containing substance and a repellent fragrance in a container having an opening or air permeability, it is possible to permeate through the container for sustained release. As a result, it is easy to store or install, it is easy to handle, and it is not necessary to directly touch the bird and animal repellent, so it is convenient and clean.

Further, the bird and animal repellent device of the present invention can be set at any place, and at the same time, if it is provided with an adhesive force, it can be set in a state where it is adhered and the position is fixed. In addition, if the bird and beast repellent device has independent bubbles, the repellent fragrance is retained in each bubble to allow sustained release.The sustained release level can be adjusted by the degree of foaming, and is affected by rainwater and the atmosphere from the outside. In the case of continuous cells, the rapid release of the repellent fragrance is accelerated. In particular, if you use such adhesiveness, foamability, etc., you can set it by adhering to the gaps where birds and animals enter, the bottom surface of the floor, the vertical wall surface, etc.
In addition to being adaptable to installation and shape, it is also peelable after use. Further, since it is in a foamed state, it has a buffer property even when it comes into contact with or collides with it, and the partition wall of the cell of the bird-repellent repellent that is a foam becomes a surface layer for reinforcing the bird-repellent repellent. It also serves as a control film when releasing internal components.

 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Mitsunobu Kobayashi 3-1, Asahi-cho, Takatsuki-shi Sunstar Stock Association In-house

Claims (4)

[Claims] 1. A bird and animal repellent which is a foam comprising a sulfide compound or a substance containing a sulfide compound, a repellent fragrance and a synthetic polymer. 2. The bird and animal repellent according to claim 1, wherein the sulfide compound-containing material is one or more selected from onion oil, leak oil and garlic oil. 3. The repellent fragrance is cinnamon oil, cinnamic aldehyde, cinnamic alcohol, d-limonene, terpineol, lemongrass oil, methylnonylketone, methylphenylketone, green leaf alcohol, green leaf aldehyde, menthol, citral, The bird and animal repellent according to claim 1 or 2, which is one or more selected from pine oil. 4. A weight ratio to the synthetic polymer 100,
The bird and animal repellent device according to claim 1, 2 or 3, wherein the sulfide compound or the sulfide compound-containing substance is mixed in an amount of 0.5 to 30, and the repellent fragrance is mixed in an amount of 5 to 300.