JPH0716044A - Method for exerting inhibitive action on animal, microorganism, etc., and inhibiting material - Google Patents

Abstract

PURPOSE:To effectively exert an inhibiting action having prolonged repelling effect on animal, microorganism, etc., by applying an inhibiting component from a specific foamed inhibiting material to an animal, microorganism, etc. CONSTITUTION:Inhibitive action on animal, microorganism, etc., is exerted by using an unexpanded foamable adhesive material containing an inhibiting component (e.g. fungicide) against animal, microorganism, etc., such as cockroach and mold, directly attaching the material to a place possible to contact with the animal, microorganism, etc., and expanding and curing the material or placing the material formed to a proper form, thereby forming an expanded material for exerting inhibitive action on animal, microorganism, etc., and applying the inhibiting component from the foamed inhibiting material to the animal, microorganism, etc. This inhibiting material 1 is obtained by including an inhibitive component against animal, microorganism, etc., into an unexpanded foamable adhesive material and putting the product into a container.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION The present invention relates to animals, microorganisms such as dogs, cats, rats, snakes, centipedes, cockroaches, mites, flies, mosquitoes, molds, etc., which are problematic at home and in various places for commercial use.
A state in which an inhibitory component against yeasts and other bacteria is applicable for installation and shape, has adhesiveness, and has a function of controlling the release of components and further promoting the release of components from the outside. The present invention relates to a method for inhibiting life activity or behavior of animals, microorganisms, etc.

[0002]

2. Description of the Related Art Conventionally, there are products for the purpose of repellency and sterilization of relatively large animals such as dogs, cats and rats, small animals such as ants, earthworms and cockroaches, and microorganisms such as molds, yeasts and bacteria. is there. One is a repellent and the other is a fungicide, an insecticide and even a pesticide. However, many of these product forms are in the form of granules or liquids, and the liquid form is a form in which they are directly applied or sprayed with a spray or the like. In many cases, the granular material is installed in a place where it is repelled during use.

In addition, many products containing insecticidal / bactericidal components, such as insecticides and other germicides,
It takes the form of liquid or powder. And this product is also generally used by being sprayed and attached to the air or a target area.

In addition to these granular, powdery, liquid and other forms of use, there is also one as disclosed in Japanese Patent Laid-Open No. 4-96968. This is the title of the invention: mite-repellent polyurethane foam, mite-repellent polyurethane elastomer and mite-repellent polyurethane coating composition. That is, the present invention contains a mite repellent component in a polyurethane foam, a polyurethane elastomer and a polyurethane coating composition, some of which are in a foamed product state,
It is intended to be used in a liquid state.

[0005]

The methods and products for repelling, insecticidal, sterilizing, etc. have the following problems. That is, the repellents, insecticides, bactericides in a granular form, and when installed in a hot and humid place, the granular material containing the repellent component and the container that contains them are those Then, it collapses due to rainwater or the like to shorten the service life, and the collapsed thing pollutes the installation place. Furthermore, there is a risk that various problems will occur when the granular material adheres to children's hands or eats it. In addition, since it is a granular material,
There is a problem that the installation place is an inclined surface, or it cannot be installed on an antigravity place, that is, on the side surface or the back side of the plate. Even if the target is soiled with a liquid or powder, it may not be possible to remove it when it is not needed, and due to rainfall, etc., repellent components, bactericidal components, or insecticidal components flow out, Problems may occur in the persistence of the repellent effect against each animal or microorganism and the inhibitory effect such as insecticidal and sterilization.

In addition, in the above-mentioned mite-repellent polyurethane foam and other inventions, although the mite-repellent agent is carried in polyurethane or is contained in polyurethane elastomer or polyurethane paint, it is suitable place. Adaptability to installation, for example, polyurethane foam must be cut into an appropriate shape before installation, and if polyurethane elastomer can be filled in a specific space, it does not have adhesiveness or adhesiveness. Even if there is a property, it is too strong and peeling is difficult. With paint, when peeling is required after application, a situation arises in which this is difficult or impossible. Therefore, in view of such a situation, the present invention provides a repellent component, an insecticidal component, a bactericidal component, and other components that inhibit life activity and behavior against animals and microorganisms, installation adaptability, shape adaptability, adhesiveness, and after use. It is used in a state where it has peeling properties, etc., and in the course of use, it has the ability to control the release of inhibitory ingredients and the ability to prevent the release of ingredients from the outside, and
A skin layer on the surface provides a method for inhibiting the release of an inhibitor, a method for imparting physical strength and prevention of invasion of rainwater to animals and microorganisms, and an inhibitor.

[0007]

[Means for Solving the Problems] In order to achieve the above-mentioned object, the present invention provides an unfoamed and adherent foamable material containing an inhibitory component against animals, microorganisms, etc.
By directly adhering to a place against microorganisms, etc., and foaming and hardening, or by forming it into an appropriate shape and installing it, a foaming inhibitory substance for animals, microorganisms, etc. is formed. Etc., and a method for imparting inhibition to animals, microorganisms, etc., which is obtained by acting on such substances to inhibit them. Further, the inhibitor-imparting substance used for this is a non-foaming and adhesive foaming material containing an inhibitory component against animals, microorganisms, etc.,
It is housed in a container.

First, in the method of imparting inhibition to animals and microorganisms, the animals and microorganisms are relatively large animals such as dogs, cats and rats, and small animals such as ants, centipedes, pit bugs, mites, cockroaches and mosquitoes. Including mold, yeast,
It is one or more kinds of microorganisms such as bacteria, and targets animals, microorganisms and the like, which have an unpleasant or specifically adverse effect on the environment in which humans live. The above-mentioned specific posted animals and microorganisms are examples of these, and there are also unpleasant or inhibitory substances that are given to human life or its living environment against other organisms given to human life. It is included. For example, slugs and the like that give rise to traces of movement by moving the tree and moving on the fruit surface when growing fruit trees such as oranges and apples are included in these.

The inhibitory components for acting on these animals, microorganisms, etc. are classified into behavior inhibitory components and life activity inhibitory components. When these animals, microorganisms, etc. adversely affect humans and other living environments,
Various components can be used as long as they are components that inhibit life activity and behavior. Inhibition in this inhibitory component means the human living environment or non-human beings by blocking or damaging the activities of animals, microorganisms, etc. or by blocking their life activities or harming their life activities. Means a component that can prevent or stop the influence of other substances on the biological environment.

The behavior-inhibiting component is one that can prevent or limit the behavior of these animals, microorganisms and the like in the living space of human beings that cause discomfort or adverse effects. Generally, they are repellents and fragrances. Furthermore, magnetic properties for birds are studied, and one or more of these are used. The following repellents, fragrances, magnetism and the like are used.

As repellents, acetoxyphenyl butane, vanillin, hexanal, geranyl formate, α, β-
Pinene, limonene, safrole, anethole, anisaldehyde, γ-lactone, 1,8-cineole, naphthalene, angelica, cyclic terpene alcohol, menthol, N, N-diethyl-m-toluamide, ethyl thiomethone, isothionate, cresol, limonene, spices (Pepper, capsicum, peppermint, perilla, clove, etc.), vanilla, nonyl lactone, citryl, linalool, 2-butoxyethanol, bisether, cyclohexanone, isophorone, spearmint oil, green leaf alcohol, cinnamon alcohol, methylnonylketone, methylphenylketone. , Camphor, lemongrass oil, citral, eucalyptol, allyl isotianate, cycloheximide, capsaicin, cycloheximide and the like are used.

As the fragrance, spearmint oil, peppermint oil, citronella oil, eucalyptus oil, cascarilla oil, birch oil, cinnamon oil, clove oil, garlic oil, peppermint oil, marjoram oil, nutmeg oil, palmarosa oil, and the like as natural fragrances. Perilla oil, rose oil, savory oil, rosemary oil, lavender oil, etc. are used. In addition, amyl acetate, α-amylcinnamic aldehyde, isoamyl salicylate, anisaldehyde,
Benzyl acetate, benzyl alcohol, borneol, l
-Carvone, menthol, citral, citronellal, citronellol, coumarin, eugenol, methyl salicylate, vanillin, terpineol and the like are used.

For magnetism, permanent magnets such as ferrite magnets and rare earth magnets are generally used.

As these behavior-inhibiting ingredients, one or more kinds of these repellents, fragrances, pesticides, magnetism and the like may be combined and supported on the inhibition-imparting substance, and the content thereof is 0.1% by weight. Content of less than 0.1% by weight, the repellent effect is short-lasting, and if more than 50% by weight, foam formation is inhibited. Is preferably contained in an amount of 2 to 20% by weight.

Next, the component for inhibiting life activity is a component that literally inhibits the life activity of these animals, microorganisms and the like. In some cases, the life is interrupted, and in some cases it is harmful. In other words, it can be used for all pesticides, antibacterial agents, antifungal agents, etc. The following pesticides, antibacterial agents, and antifungal agents and the like are used, and these are also applied to pesticides as behavior-inhibiting ingredients.

Examples of the component for inhibiting life activity include pesticides, insecticides, bactericides, nematicides, miticides and the like.
The bactericides include dithiocarbamate agents (Manzeb, Manneb, polycarbamate, etc.), organic sulfur agents (Captan,
Captafol, folvet, etc.), organic phosphorus agents (O, O-
Diisopropyl-S-benzylthiophosphate, O-
Ethyl-S, S-diphenyldithiophosphate, etc.),
Organic chlorine agents (pentachlorophenol, chlorothronyl, etc.), organic arsenic agents (methylarsenic dimethylcarbamate, dodecylsulfate), aliphatic halogen agents (methyl bromide, chloropicrin, etc.), benomyl, oxycarboxyne, phenazine oxide , Anilazine, oxyquinoline sulfate, triphenyltin hydroxide, hydroxyisoxazole, pinapacryl, butiobate, inorganic sulfur agents (sulfur, lime polysulfide, etc.), copper agents (Bordeaux solution), antibiotics (streptomycin, novobiocin, chlorampheni) Cole, blasticidin S, kasugamycin,
Validamycin A, polyoxin, cycloheximide, etc., and other plant-based bactericidal components (humron (hum
ulon), lupulon, allicin,
Allyl isothiocyanate
anate)), chlorogenic acid, solanine, tangeritin, berberine, hinokitiol, iodine and the like.

As the insecticide, organophosphorus insecticides (dichlorvos, sinophos, O-ethyl-O-phenylphosphothionate, marathon, parathion, etc.) and carbamate insecticides (1-naphthyl-N-methylcarbamate, Isoprocarb, etc.), organohalogen pesticides (Detiti, benzahexachloride, erdrin, aldrin, dieldrin, etc.), nicotine (nicotine, nornicotine, etc.), fluoroacetamide, pyrethroids (pyrethrin, allethrin, etc.), plants Derived essential oils (cineole, dill oil, Japanese peppermint oil, eucalyptus oil, turpentine oil, etc.), boric acid and the like are used.

Examples of the acaricides include quelsen, prochronol, chlorvedilate, chloropropylate, phenisobromolate, and chlorfenson.
son), tetradiphone, propargite (propar)
Gito), pinapacryl, tricyclohexyltin hydroxide, fenbutatin oxide, quinothiomate, amitraz, benzomate, polynactiones (polynac)
ions), lavender oil, melissa oil, peppermint oil, salvia oil, rosemary oil and the like.

As nematicides, chlorpicrin, 2,
There are a mixture of 3-dichloropropane and 1,3-dichloropropene, 1,2-dibromomethane, and methyl isocyanate, and preferably chloropicrin, a mixture of 2,3-dichloropropane and 1,3-dichloropropene, and the like are used.

As the antibacterial agent, methylparaben, ethylparaben, propylparaben, vanillin, cinnamic aldehyde, p-hydroxybenzoic acid ester, d-limonene, ethyl alcohol, camphor, phenyl oxide, p-dichlorobenzene, dimethyl fumarate. , Hiba oil, asunaro oil, taiwan cypress oil, cassia oil, dill oil, lemon oil, citronella oil, clove oil, thyme oil, linalool,
Trans-pinocarbeol, p-isopropylcyclohexanol, camferenic aldehyde, γ-decalactone, γ-undecalactone, silver and the like are used.

As the antifungal agent, sodium hypochlorite, moldicidin, cycloheximide, iodine, silver, chloramphenicol and the like are used.

As the components for inhibiting life activity, one or more kinds of these pesticides, antibacterial agents and antifungal agents are combined and supported on the inhibitor, and the content is 0.1% by weight. ˜50% by weight,
If the content is less than 0.1% by weight, the persistence of repellent effect is short, and if the content is more than 50% by weight, foam formation is inhibited. It is desirable to do.

Therefore, these inhibitory components are
It inhibits behavior or life activity against microorganisms and the like, and this component is contained in the foamable material. As the foamable material, various materials can be used as long as they have foaming performance. A material having foamability means that the material itself can be foamed under certain specific conditions or by another foaming agent, in many cases, the material and another foaming agent. This foaming property is given by the coexistence of the above and by a certain bonding state. That is, this foamable material is in an unfoamed state during use because of its foaming ability. In addition, this material is selected to be adhesive to the object. This material may be one or a combination of two or more selected from expandable synthetic resins, expandable natural polymers and expandable inorganic materials. Naturally, synthetic resin,
Originally, natural polymers and inorganic materials have extremely few foaming properties, but in many cases, a foaming agent is coexistent or contained in order to impart foaming properties to various materials. Examples of the foaming synthetic resin that can be used here include polyvinyl alcohol, polystyrene, polyethylene, polyurethane, polyvinyl chloride, polyvinylidene chloride, polyethylene terephthalate, polyamide, polymethylpentene, polyacrylamide, polypropylene having a foaming agent. , Polyethylene vinyl acetate, polyvinyl acetate, silicone resin, epoxy resin,
Alkyd resin, melamine resin, furan resin, silicon resin,
Acrylic resins, urea resins, phenol resins, polyacetal resins and the like, and copolymers and derivatives thereof are available.

The use of self-decomposing materials as these materials brings about a good condition for the treatment after use. For example,
A synthetic resin that decomposes by absorbing ultraviolet rays may be used, or a biodegradable resin may be selected. Usually, examples of biodegradable materials include the following natural polymer materials. Natural polymer materials include plant polysaccharides (amylopectin, amylose, pectin, starch, starch derivatives, cellulose, cellulose derivatives, etc.), seaweed-derived polysaccharides (agar, carrageenan, alginic acid, agarose, etc.), plant seed-derived polysaccharides (arabis). Nogalactan, gum arabic, sesame seed gum, tanmarid seed gum, etc.), polysaccharides derived from microorganisms (xanthan gum, gellan gum, dextran, pullulan, curdlan, etc.), polysaccharides derived from animals (chitin, chitosan, chondroitin sulfate, heparin, etc.), proteins (Soy protein, gliadin, glutenin, gluten, collagen, actin, myosin, sodium caseinate, γ-globulin, gelatin, etc.) and lignin.

Further, the expandable inorganic material is cement or the like having a foaming agent. It should be noted that the above-mentioned behavior-inhibiting components, life-activity-inhibiting components and effervescent materials are examples of these, and the present invention is not limited to those exemplified, and those similar to them are adopted. What is done is not restricted.

The foaming material containing the inhibitory component, like the inhibitory substance of the present invention, is contained in a container such as a can or a bottle for spraying, and is appropriately blown out with a gas or pumped out. It is poured out by a method, directly adhered to a portion against animals, microorganisms, etc., and then foamed and cured to form a foam-like inhibitory substance for animals, microorganisms, etc. The direct attachment to the place against the animals and microorganisms, for example, in places where it is desired to regulate the invasion of dogs, cats, mice, centipedes, etc., use repellent components having repellent components in place of these invasion routes. The foamable material contained as an inhibiting component is set by pouring out and adhering and foaming and curing.

Furthermore, in the middle of the moving route of the animal, for example,
In the house, apply it to an appropriate place such as a gap between furniture and figurines or the back of the installation, or in the case of fungus in the bathroom, apply it to the breeding site of the fungus, or by other appropriate method. By directly attaching and foaming and curing,
That is, it is possible to adhere and form the inhibition imparting substance in a foamed state. As another method, it is also possible to foam-mold the foamable material into a suitable shape at a place other than the installation place and install it in an appropriate place.

By directly or indirectly applying these substances to the animal, microorganism, etc., the inhibitory component contained in the effervescent inhibitory product is vaporized in some cases, and moisture in other cases. By infiltrating it, and ingesting the inhibitory substance in some cases, the inhibitory component is allowed to act on these animals and microorganisms to prevent the animals and microorganisms from approaching, or to invade. By killing things, these animals and microorganisms are prevented from approaching and their existence is eliminated.

In other words, in the present inhibition imparting method, the inhibitory component against animals, microorganisms, etc. is retained in the unfoamed foaming material, and this is adhered to the target site to foam and harden, or as appropriate. It is intended to allow the inhibitory components to act on these animals, microorganisms, etc. by placing a substance that is hardened into such a shape and placed there.

This foamy inhibition-providing substance has various advantages because it has an inhibitory component inside and is in a foamy state. In other words, since it is in a foamed state, the inhibitory component inside it is retained in the bubbles or in the partition walls forming the bubbles in the case of using independent bubbles.
This makes the partition difficult to release to the outside, and enables sustained release. In particular, expandable synthetic resins, for example,
When using this inhibitor-inhibiting substance made of foamed synthetic resin, which uses materials such as urethane foam, polyethylene foam, and polypropylene foam, and when using those with closed cells, the inhibitor component is effectively retained inside. And, it allows for sustained release.

That is, the partition wall of each closed cell constitutes a cell for holding these components, and at the same time, when the inhibitory component is a vaporized component, it restricts the release of the vaporized substance, and further assists the release from the outside. When a material, for example rainwater, adheres to the foaming inhibitor, in the case of a conventional granular material or solid material having a repellent, a bactericide, an insecticide, etc., the components inside thereof are dissolved and flowed out. However, in the present invention, external rainwater can be shut off by the partition walls of the closed cells. In particular, for foamed synthetic resin,
This property is strong, and the release of the vaporized component from the inside has a controlled release ability.

Since the foam-like inhibitory substance which has released the components contained therein becomes unnecessary, it can be peeled from the adhesion site by hand or by an appropriate means. Easy to remove, and then
In addition to being able to adhere and use the foamable material in the new invention, the inhibitor for foaming after releasing the inhibitory component is re-injected with the inhibitory component by a nozzle or the like, and a suitable sealant for the filling port trace or By sealing with tape etc.,
It is possible to use this foam-like inhibition-providing substance as an effective one.

Next, if the foaming state is open-celled, the components contained in the tissue of the inhibitor-imparting substance are likely to be released to the outside through the open-cells, and means for promoting the release of components such as rainwater from the outside. Since it has the property of being susceptible to the action of, it is preferably used when it is necessary to rapidly release the component.

The state of the method for imparting inhibition to animals, microorganisms and the like and the substance imparting inhibition according to the present invention will be further understood in detail with reference to FIGS. 1 to 6. Figure 1
When a foamable material that has been foamed in a block shape, for example, a foamable urethane, is poured out of a container, surface tension acts to form a blocky material as shown in the figure. Closed cells are created inside the surface, and a skin layer is formed on the surface.

That is, the blocky foam-like inhibition-imparting substance 1 for animals, microorganisms, etc. in FIG. 1 has the inhibitory component inside, and if the inhibitory component is, for example, a vaporizable repellent, it is repelled. The agent vaporizes, passes through the partition of each closed cell, and is released to the surface. Furthermore, it is a pesticide, an antibacterial agent, or a fragrance that is a life activity inhibiting component, and those components are vaporizable. If present, by vaporizing it acts like the repellent,
In addition, in those that are not vaporizable, those components are
What has leaked to the surface by the osmotic force acts on the partition walls of closed cells. It can be said that it is preferable to use the non-vaporizable one, especially the one in the foamed state of the open cells, in order to elute the components from the external rainwater or the like. This block inhibition imparting material has closed cells or open cells inside, has a skin layer on the surface, and
Since the bottom surface is adhered to the target location, it can be adapted to various locations.

As shown in FIG. 2, the container shown in FIG. 1 is obtained by filling the foamable material in a suitable container 2 and foam-molding it, for example, or by installing it as it is or at the bottom of the container. Adhesion with the provided adhesive layer and the like are appropriately adopted. In particular, as shown in FIG. 3, the thing of FIG. 1, for example, fills the gap 4 of the furniture 3 with a foaming material, and foams at this portion to give a foam-like inhibitory substance to animals, microorganisms and the like. Can be formed. For example, in the case of containing a repellent or insecticide against cockroaches, by filling and sealing the gaps 4 at such various places with the inhibition-imparting substance, it is possible to prevent migration and also to inhibit these inhibitions. Physiological and pharmacological actions by the components enable more complete sealing. When the foam inhibiting agent is a foamable synthetic resin and is colored so as to be compatible with various interiors, by filling the gap 4, the inhibitory action against animals and the like and the gap filler are used together. sell. Further, in using these, not only the gap 4 but also the furniture side surface as shown by 5 in the drawing can be used, and various other measures can be taken. In particular, since this foaming material has adhesiveness, it can be formed by appropriately pouring out and adhering it to an antigravity position, especially to the back side of the shelf, the vertical side surface and the like.

FIG. 4 shows still another example. In the figure, 6 is a sandbox, and 7 is a concrete wall that constitutes the outer frame of the sandbox. Dogs, cats, and especially cats, come to the sandbox for defecation at night when there are no people. However, since children play in this sandbox and their hands and feet directly contact with this sandbox, allowing excretion of animals to this sandbox creates a disease infection or unsanitary condition for children. Therefore, by providing the blocky foam-like blocker as shown in FIG. 1 containing the repellent component for dogs or cats according to the present invention at a proper place on the surface of the concrete outer frame 7 as shown in the figure. , Dogs, cats, etc. were prevented from entering this sandbox, or as shown in the figure, several were buried in the ground at appropriate places outside this concrete outer frame 7 or part of them was exposed. It is also possible to bury it in the state.
Alternatively, as shown by 8 in the figure, by enclosing this sandbox 6 and burying the rod-shaped present foamy inhibition-imparting substance in the ground as shown in the sectional view of FIG. 5, it is possible to prevent the invasion of these animals. it can. In addition, these ideas are based on the invading animals that enter the area such as the market, dining room or home,
It is also possible to prevent dogs, cats, mice, etc. by surrounding the whole house with such an inhibitor.

As shown in FIG. 6, since pigeons and other birds fly to the verandas and the like of each household and pollute with feces and the like, it is conceivable to install the present foamy inhibition-imparting substance 1 in this place. In this case, a component having a repellent action against these birds is contained, and the release of the component due to its vaporization prevents the invasion of these birds or the stoppage at their place. Magnetism generating material, for example, the surface 10 and the lower surface 1 of the handrail 9 which are mixed and shown in the figure.
1 or attached to the side surface 12 or the like.
In particular, when it is installed on the lower surface 11 of the handrail, the appearance is not uncomfortable, and when it is attached to the surface of the handrail 9, it is foam-molded as a plate-like one instead of a lump-like one as shown in the figure. In terms of appearance, it can be said that things are in a preferable usage state.

[0039]

【Example】

(Examples 1 to 3) Spearmint oil having a repellent effect on the American cockroach was used as a repellent, and the contents of Spearmint were changed, and Examples 1, 2 and 3 were blended according to the formulations shown in Table 1, respectively, and 10 parts in a two-component system. Chemical expansion was performed at a double expansion ratio, and about 10 cc was injected into a container with a diameter of 3 cm and a depth of 5 cm as shown in FIG. As Comparative Example 1, spearmint oil was used as a repellent and blended in a urethane elastomer resin-based paint, and a transparent acrylic resin plate was brushed with a length of 5 cm and a width of 3
The size of cm was compared with the coated one. Then, the persistence of the repellent effect was measured every week for 8 weeks, and the results in Table 2 were obtained. Each test was conducted outdoors, of which 30 days were fine weather and 26 days rain. To confirm the persistence of the repellent effect, the size is 100 cm × 50 cm × 50 in Example 1, Example 2 and Comparative Example 1.
cm, in the center of a transparent container made of acrylic resin, a partition with a circular hole having a diameter of 30 cm is opened so as to make the volume even, and the hindered substance after each hour is installed in one room. , 50 American cockroaches were released, and the number of American cockroaches moving to the other room was measured.

As a result, as shown in Table 2, in Examples 1, 2 and 3 of the present invention, the persistence of the repellent effect continued for 8 weeks. On the other hand, in Comparative Example 1, the repellent flowed out due to rainfall, and the effect was less than 2 weeks.

[0041]

[Table 1]

[0042]

[Table 2]

(Examples 4 to 6) Cinnamon oil was blended as a repellent for dogs and cats, and the content of the repellent shown in Table 3 was changed. Examples 4, 5 and 6 are shown in FIG. , A rod-shaped dog with a foaming ratio of 5 times, a diameter of 5 cm, and a length of 30 cm,
A cat inhibition product was prepared, and the repellent effect test was conducted outdoors, and was measured every week for 8 weeks as in Examples 1 to 3. Outdoors, 40 sunny days and 1 rainy day
It was 6 days. As Comparative Example 2, cinnamon oil was mixed with a mixed solution of ethanol and water and sprayed and sprayed. The effect was judged to be effective when the dog or cat was disliked by approaching it directly to the dog or cat, and judged to be no effect if there was no change.

As a result, as shown in Table 4, the repellent strength and repellent persistence were far longer than those of Comparative Example 2 depending on the content, and the repellent effect was maintained.

[0045]

[Table 3]

[0046]

[Table 4]

(Example 7) As Example 7, cinnamon oil containing biodegradable chitosan and cellulose and having a repellent effect on dogs and cats was used. It was prepared by enclosing it in a spray can so as to chemically foam in a liquid system. This is sprayed into a blocky state as shown in Fig. 1, and a blockage-imparting substance for dogs and cats having a foaming ratio of 5 times and a major axis of 10 cm is prepared and embedded in outdoor soil for 6 months. The repellent effect and biodegradability were confirmed every month. As for the repellent effect, the nose of 10 dogs was made to smell directly as in Example 4, the reaction of the dogs was observed, and it was confirmed that 6 or more dogs were effective. The biodegradability of the inhibitor was visually confirmed. The biodegradability was confirmed by digging up from the soil and visually confirming the condition.
As Comparative Example 3, a repellent for dogs and cats containing no biodegradable material was used to compare the repellent effect and the persistence of the repellent.

As a result, as shown in Table 6, in Example 7, the biodegradability started from the 3rd month and the repellent effect gradually disappeared as compared with Comparative Example 3. And this is effective in terms of disposal.

[0049]

[Table 5]

[0050]

[Table 6]

[0051]

[Table 7]

(Embodiment 8)

Acrylic resin was used as the main ingredient at the compounding ratio shown in Table 8 and the spout of capsicum, which is a repellent for mice, was compounded and mechanically foamed to increase the expansion ratio to 3 times.
After heating at 10 ° C. for 2 minutes, it was further heated at 150 ° C. for 3 minutes to be cured. A rat rat inhibition product was prepared in a container as shown in FIG. As Comparative Example 4, an acrylic emulsion-type plastic coating material was prepared by adding a capsicum extract to the mixture shown in Table 8 and applied to a flat plate made of an acrylic resin with a brush having a length of 4 cm and a width of 2 cm. I did the test. Each indoors for 8 weeks,
The repellent effect on rats was confirmed every week. To confirm the repellent effect, close the center of a 200 cm square cage with an opening / closing septum made of acrylic resin, put an inhibitor on it, and leave a rat A cage and a rat B cage that escapes due to the repellent effect. Was set up. Then, the rat rat inhibitor containing the capsicum exudate was released in the A cage, 20 rat rats were released, the septum was opened and observed, and the number of rat rats escaping into room B was counted.

As a result, as shown in Table 9, all of the brown rats escaped to the B cage in 8 weeks, and the inhibitory effect of the inhibitor was observed, and in Comparative Example 4, the inhibitory effect was not observed after 3 weeks.

[0055]

[Table 8]

[0056]

[Table 9]

[0057]

As described above, the present invention provides a foamable synthetic resin,
A natural foamable polymer and a foamable inorganic material are used individually or in combination in the foamable material.
Inhibiting behavioral components against microorganisms, etc., or inhibiting components such as life activity inhibiting components, etc., and directly adhering to the installation location for these animals, microorganisms, etc., foaming and curing, or installing in a suitable shape Then, in order to form a foamy inhibition-imparting substance for animals / microorganisms, etc., and prevent or kill the invasion of the animals / microorganisms, etc., an inhibitory action from the foamy inhibition-imparting substance is given.

Further, the foaming-inhibition-imparting substance of an inhibitory component for animals, microorganisms and the like according to the present invention can be provided at any place, and at the same time when it is directly attached and foamed,
In addition to being able to set in a state where it is adhered and fixed in position, and when the foam-like inhibitor imparting substance has closed cells, the inhibitory component is retained in each bubble to enable sustained release. In addition to being able to adjust the degree of foaming, it prevents rapid release under the influence of rainwater and the atmosphere from the outside, and when the bubbles are continuous bubbles, it releases the inhibitory component immediately. . In particular, by using such adhesiveness, foaming property, etc., it can be set by adhering to the gap of furniture, the lower surface of the shelf, the vertical wall surface, etc., and in addition to installation adaptability, adhesion adaptability, shape adaptability, It has peeling properties after use. Further, since it is foamed, it has a buffering property even when it comes into contact with or collides with it, and the skin on the surface of the foam becomes a reinforcing surface layer for the inhibition-imparting substance, and when the internal components are released. It also serves as an adjustment film.

[0059]

[Brief description of drawings]

FIG. 1 is an explanatory view of a block inhibition-imparting substance in the present invention.

FIG. 2 is an explanatory view in which the inhibition-imparting substance of the present invention is contained in a container.

FIG. 3 is an explanatory view of an obstruction-imparting substance filled in a gap of furniture.

FIG. 4 is an explanatory view of the installation state of the obstacle imparting substance in the sandbox.

FIG. 5 is a cross-sectional explanatory view of a rod-shaped inhibition imparting substance buried in the ground.

FIG. 6 is an explanatory diagram of an inhibitory substance placed on a veranda.

[Explanation of symbols]

 1. Bulk inhibition inhibitor 2. Container 3. Furniture 4. Gap 5. Furniture side 6. Sandbox 7. Outer frame 8. Rod-shaped inhibition imparting agent 9. Handrail 10. Surface 11. Lower surface 12. side

 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Yuji Murakami 3-1, Asahi-cho, Takatsuki-shi Sunstar Stock Association In-house (72) Inventor Kosuke Torii 7-1 Akita-cho, Takatsuki-shi Sunstar Giken Co., Ltd. (72) Inventor Shinji Okuda 7-1 Akita-cho, Takatsuki-shi Sunstar Giken Co., Ltd. (72) Inventor Motoya Kamiyama 7-1 Akita-cho, Takatsuki-shi Sunstar Giken Co., Ltd.

Claims (16)

[Claims] 1. A non-foaming and adhesive foaming material containing an inhibitor against animals and microorganisms is directly attached to a portion against animals and microorganisms, and foamed and cured, or formed into an appropriate shape. By installing the above-mentioned thing, a foam-like inhibition imparting substance for animals, microorganisms, etc. is formed.
A method for imparting inhibition to animals, microorganisms, etc., which comprises causing an inhibitory component to act on the animals, microorganisms, etc. from the foamed inhibition imparting agent for microorganisms, etc. 2. The animal according to claim 1, wherein the foaming material is one kind or a combination of two or more kinds selected from a foaming synthetic resin, a foaming natural polymer and a foaming inorganic material. A method for imparting inhibition to microorganisms and the like. 3. The method for imparting inhibition to animals, microorganisms and the like according to claim 1, wherein a behavior inhibiting component is used as the inhibiting component. 4. A repellent, a fragrance, a magnet, as a behavior-inhibiting component.
The method for imparting inhibition to animals, microorganisms, etc. according to claim 3, which comprises a combination of one or more selected from agricultural chemicals. 5. The method for imparting inhibition to animals, microorganisms and the like according to claim 4, wherein a vaporizable substance is used as the repellent. 6. The method for imparting inhibition to animals, microorganisms and the like according to claim 1, wherein a vital activity inhibiting component is used as the inhibiting component. 7. A bactericidal agent, an antibacterial agent, as a life activity inhibiting component,
7. The method for imparting inhibition to animals, microorganisms, etc. according to claim 6, comprising one kind or a combination of two or more kinds selected from agricultural chemicals and fragrances. 8. The method for imparting inhibition to animals, microorganisms, etc. according to any one of claims 1 to 7, which comprises utilizing a foam-like inhibitor-imparting substance that is adhered to the action site of the inhibitor component in a lump or rod shape. 9. One or more species selected from dogs, cats, mice, snakes, cockroaches, mosquitoes, flies, weevil, mites, centipedes, pitworms, molds, yeasts and bacteria as animals / microorganisms. A method for imparting inhibition to animals, microorganisms, etc. according to any one of claims 1 to 8. 10. The method for imparting inhibition to animals, microorganisms, etc. according to any one of claims 1 to 9, wherein the foamed state is a closed cell. 11. The method for imparting inhibition to animals, microorganisms, etc. according to any one of claims 1 to 9, wherein the foamed state is one having open cells. 12. An animal- and microorganism-inhibiting substance which is contained in a container in which a non-foaming and foamable material containing an inhibitory component against animals and microorganisms is contained in a container. 13. One or two selected from a foamable synthetic resin, a foamable natural polymer, and a foamable inorganic material as the foamable material.
The animal or microorganism inhibition-imparting substance according to claim 12, which is used in combination with one or more species. 14. The animal-microorganism inhibition-imparting substance according to claim 12 or 13, wherein a life-activity-inhibiting component, a behavior-inhibiting component, or a combination thereof is used as the inhibiting component. 15. A substance for inhibiting animals, microorganisms and the like, which is a combination of one or more selected from action repellents, fragrances, magnetism and agricultural chemicals as action inhibiting components. 16. A substance for inhibiting animals, microorganisms, etc., which is a combination of one or more kinds selected from bactericides, antibacterial agents, agricultural chemicals, and fragrances as components for inhibiting life activity.