JPH08208439A - Hair cosmetic - Google Patents

Abstract

PURPOSE: To prepare a hair cosmetic containing a polysiloxane-oxyalkylene copolymer and an amino-modified or ammonium-modified polymer silicone and capable of repairing hair by bonding split hair parts. CONSTITUTION: This hair cosmetic contains 0.1-50wt.% polysiloxane-oxyalkylene polymer of formula I (R<1> and R<2> are each a 2-4C divalent hydrocarbon; (a) is 1-1000; (b) and (c) are each 0-1000 with the proviso that (b) and (c) are not simultaneously 0; (x) is 1-100) and 0.1-50wt.% amino-modified or ammonium- modified polymer silicone of formula II (R<3> is methyl, etc.; R<4> and R<5> are each methyl, OH, etc.; (m+n) is 3000-20000 and (n)/(m) is (1/500) to (1/10000)). Touch feeling of whole hair is improved and split hair parts can efficiently be bonded by combinedly using the compound of formula I with the compound of formula II.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair cosmetic composition, and more particularly to a hair cosmetic composition capable of adhering and repairing split ends of hair.

[0002]

2. Description of the Related Art Conventionally, for the purpose of coating the split ends of hair, dimethyl silicone gum, polyvinylpyrrolidone-based polymers, acrylic acid-based polymers, polysaccharides, poly Peptides etc. are mixed. In addition, recently, it has been reported that a hair cosmetic in which one type of polysiloxane-oxyalkylene copolymer is used in combination with a silicone derivative has a good feel and is excellent in the adhesion of split ends (Japanese Patent Laid-Open No. Hei 10). 6-157247). However, with these methods, although the feel was good, the adhesive effect of the split ends was still incomplete. Also, when other polymer compounds are mixed, there is an adhesive effect, but once peeled off, the effect is not reproducible, and there is a problem in feeling such as squeaking, dryness, and stiffening. There were many problems in appearance such as flaking. Therefore, there has been a demand for a hair cosmetic composition that solves these problems, can efficiently bond split ends, and imparts a good feel to the hair.

[0003]

Under the circumstances, as a result of intensive studies, the present inventors have combined a specific polysiloxane-oxyalkylene copolymer with a high molecular weight amino-modified or ammonium-modified polymer silicone. It was found that a hair cosmetic which improves the feel of the hair as a whole and can adhere the split ends efficiently can be obtained, and the present invention has been completed.

That is, the present invention is a hair cosmetic containing the following components (A) and (B).

(A) One or more polysiloxane-oxyalkylene copolymers represented by the general formula (1).

[0006]

Embedded image

(In the formula, R ¹ and R ² each represent a divalent hydrocarbon group having 2 to 4 carbon atoms, a represents a number from 1 to 1000, and b and c each represent a number from 0 to 1000. Indicates.
However, b = c = 0 is not satisfied. x shows the number of 1-100. )

(B) The molecular weight represented by the general formula (2) is 2
One or two or more of the amino-modified or ammonium-modified polymer silicones of 0,000 to 1,500,000.

[0009]

[Chemical 4]

[In the formula, R ³ represents a methyl group or a part thereof represents a phenyl group, and R ⁴ represents the same as R ⁵ or a methyl group or a hydroxyl group. R ⁵ represents a formula R ⁶ Z {R ⁶ represents a divalent alkylene group having 3 to 6 carbon atoms, and Z represents —NR ⁷ ₂ ,
_{^{N + R 7 3 A -,}} -NR 7 (CH 2) a NR 7 2, -NR 7 (CH
_{^{2) a N + R 7 3}} A - and _{^{-NR 7 (CH 2) a N}} (R 7) C =
O (R ⁸ ) (R ⁷ represents hydrogen or an alkyl group having 1 to 4 carbon atoms, R ⁸ represents an alkyl group having 1 to 4 carbon atoms, A is a chlorine atom, a bromine atom or an iodine atom. And a is an integer of 2 to 6.) represents a monovalent group selected from the group consisting of } Represents a substituent having an amino group or an ammonium group represented by m, n is a positive integer, and m + n is 3,000 to 2
Represents an integer of 50,000, n / m is 1/500 to 1/1
It is 10,000. ]

The polysiloxane-oxyalkylene copolymer as the component (A) used in the present invention is represented by the above general formula (1). Among these, in particular, in the formula, a and b + c are 10 to 500, x is 1
50 is preferable.

These components (A) are contained in an amount of 0.1 to 0.1% in the total composition.
It is preferable to add 50.0% by weight, particularly 0.5 to 30.0% by weight. If it is less than 0.1% by weight, a sufficient effect cannot be obtained, and if it exceeds 50.0% by weight, the usability is poor and the stability is deteriorated.

The polysiloxane-oxyalkylene copolymer of the present invention comprises a polyoxyalkylene compound having a reactive end group and a dihydrocarbylsiloxane liquid having an end group which reacts with the reactive end group of the polyoxyalkylene compound. Can be produced by reacting Examples of the polysiloxane-oxyalkylene copolymer of the present invention include those commercially available under the trade name Silwet F-178 series manufactured by Nippon Unicar Co., Ltd.

The amino-modified or ammonium-modified polymeric silicone having a molecular weight of 200,000 to 1,500,000 represented by the general formula (2) of the component (B) used in the present invention is m +
n is 3,000 to 20,000, and preferably,
It is 4,000 to 10,000. If it is less than 3,000, it is oily and the effect of preventing hair damage is insufficient.
When it exceeds 0, it becomes difficult to dissolve in other raw materials such as silicone oil, and it is difficult to mix it with cosmetics or detergents.
That is, according to JP-A-58-210005, m +
It is already known to incorporate a silicone having an amino group and an ammonium group in which n is 1 to 2,000 into a hair cosmetic composition. However, since these silicones are oily, the effect of preventing hair damage is insufficient. The molecular weight of the amino-modified or ammonium-modified polymer silicone of the present invention is 200,000 to 1,500,000.
When it is less than 200,000, it is not rubbery and sticky,
When it exceeds 1.5 million, solubility in a solvent such as liquid silicone oil and isoparaffin deteriorates.

The amino-modified or ammonium-modified polymer silicone represented by the general formula (2) has n / m of 1
/ 500 to 1 / 10,000, more preferably 1
/ 500 to 1/2000. If it exceeds 1/500, the content of amino groups or ammonium groups in the silicone becomes high, and a crosslinking reaction or the like occurs during the production, and it is not preferable from the viewpoint of raw material odor. When it is less than 1 / 10,000, the interaction with hair becomes insufficient, and the durability of the hair damage prevention effect deteriorates.

The amino-modified or ammonium-modified polymer silicone as the component (B) can be produced by the same production method as that for general amino-modified or ammonium-modified silicone. For example, it can be prepared by subjecting γ-aminopropylmethyldiethoxysilane, cyclic dimethylpolysiloxane and hexamethyldisiloxane to polycondensation reaction in the presence of an alkali catalyst. The amino-modified or ammonium-modified polymer silicone used in the present invention is a soft rubber-like substance, which does not cause stickiness on the hair or scalp even when used in a large amount or continuously for a long time, gives excellent gloss, and imparts a smooth feel. In addition, it can be an extremely excellent hair cosmetic that can prevent hair damage.

The amount of amino-modified or ammonium-modified polymer silicone compounded in the present invention is 0.1-50.0% by weight, preferably 2.0-3, based on the total amount of the hair cosmetic composition.
It is 0.0% by weight. If it is less than 0.1% by weight, a sufficient effect cannot be obtained, and if it exceeds 50.0% by weight, dissolution becomes difficult. In particular, when this cosmetic is used as a rinse effect agent, it is 0.1 to 10.0% by weight, preferably 0.2 to 8.0% by weight, based on the total weight of the cosmetic for hair. If it is less than 0.1% by weight, a sufficient effect cannot be obtained, and conversely, if it exceeds 10.0% by weight, the solubility of the amino-modified or ammonium-modified polymer silicone is deteriorated, which is not preferable.

When the amino-modified or ammonium-modified polymeric silicone of the present invention is added to the composition, it is preferably dissolved in a liquid oil and added. Of course, they may be separately blended in the hair composition and dissolved in the system.
Examples of the liquid oil include chain silicone, cyclic silicone, and isoparaffin hydrocarbon.
The chain silicone can be represented by the following general formula.

[0019]

Embedded image

(In the formula, m represents an integer of 0 to 650.) Examples of such a chain silicone oil include dimethylpolysiloxane (viscosity 0.65 to 5 cSt / 25 ° C.).
Etc. The cyclic silicone is represented by the following general formula.

[0021]

[Chemical 6]

(In the formula, p represents an integer of 3 to 7.)

Specific examples of these compounds include octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and tetradecamethylcyclohexasiloxane, which are referred to by the following general names.

Examples of the isoparaffinic hydrocarbons include isoparaffinic hydrocarbons having a boiling point in the range of 60 to 260 ° C. under normal pressure. For example, Isopar A (registered trademark), C and D, same E,
Same G, same H, same K, same L, same M, Shelsol 71 (registered trademark) from Shell, Saltor 100 from Philip
(Registered trademark), or 130, 220, or the like.

The above low boiling point oil may be used alone or in combination of two or more kinds, and the total blending amount is 1 to 50 with respect to the amino-modified or ammonium-modified polymer silicone.
Double (weight) is preferable, and it is 10 in the total amount of the hair cosmetic composition.
It is preferable to select it so as to be ˜80 wt%. When used as a detergent, it is preferably within 20% by weight.

In addition to the above essential constituents, the hair cosmetic composition of the present invention contains liquid paraffin, squalane, a lanolin derivative, a higher grade compound, within the quantitative and qualitative ranges that do not impair the effects of the present invention, depending on the purpose. Alcohol, various ester oils, avocado oil, palm oil, beef tallow, jojoba oil, silicone oil, polyalkylene glycol polyether and its carboxylic acid oligoester compounds, oil components such as terpene hydrocarbon oil, ethylene glycol, propylene glycol, 1, Water-soluble polyhydric alcohols such as 3-butylene glycol, glycerin, sorbitol, polyethylene glycol, moisturizers such as hyaluronic acid, chondroitin sulfate, and pyrrolidone carboxylate, ultraviolet absorbers, ultraviolet scattering agents, acrylic resins, silicone resins, polyvinyl Resins such as pyrrolidone, large Protein, gelatin, collagen, silk fibroin, protein or protein hydrolyzate, such as elastin, ethyl paraben, preservatives such as butyl paraben, various amino acids, biotin, activators such as pantothenic acid derivatives, .gamma.-oryzanol, sodium dextran sulfate,
Blood circulation promoters such as vitamin E derivatives and nicotinic acid derivatives,
An antiseborrheic agent such as sulfur and thiantol, a diluent such as ethanol, isopropanol and tetrachlorodifluoroethane, a thickener such as carboxyvinyl polymer, a drug, a fragrance, a coloring agent and the like may be appropriately blended as necessary.

The dosage form of the present invention is optional and can be selected from three types: solubilizing system, emulsifying system, powder dispersion system, oil-water two-layer system, oil-water-powder.
Any layer system or the like may be used. In the case of an emulsifying system, an oil phase containing an amino-modified or ammonium-modified polymeric silicone is used after being emulsified with an emulsifier such as a nonionic surfactant, a cationic surfactant, an anionic surfactant or a mixture thereof. Further, at the time of emulsification, an emulsifier is dissolved in a water-soluble polyhydric alcohol, an oil component containing an amino-modified or ammonium-modified polymer silicone is added and emulsified to prepare an emulsified composition, and the composition is diluted with water. It is also possible to make an emulsion.

As the emulsifier used in that case, polyoxyethylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene cholesteryl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glyceryl fatty acid ester, polyoxyethylene hydrogenated castor oil. , Polyethylene glycol fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, nonionic activator such as polyether modified silicone, stearyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, cetyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, cetyl pyridinium chloride Cationic activators such as sodium cetyl sulfate, polyoxyethylene lauryl ether Sodium, sodium lauryl sulfate, potassium coconut oil fatty acids, anionic surfactants, such as coconut oil fatty acid methyl taurine sodium. As the water-soluble polyhydric alcohol, ethylene glycol, propylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, dipropylene glycol, glycerin, diglycerin, triglycerin, tetraglycerin, glucose, maltose, multi Examples include tall, sucrose, fructose, xylitol, sorbitol, maltotriose, threitol, erythritol, starch, reduced sugar reducing alcohol, and hyaluronic acid, and one or more of these may be used.

The hair cosmetic composition of the present invention is capable of improving the feel of the hair as a whole, and moreover, the split ends can be efficiently adhered and restored.

[0030]

EXAMPLES Next, the present invention will be further described with reference to examples, but the present invention is not limited to these examples.
All compounding amounts are weight%.

Examples 1 to 5 and Comparative Examples 1 to 5 Hair cosmetics having the compositions shown in Table 1 and Table 2 were produced by a conventional method, and the split ends adhesion effect and the feel thereof were evaluated.
The results are shown in Tables 1 and 2.

(Evaluation method) Japanese female split ends hair 30 cm
After bundling / 5g and shampooing, about 5g of the composition is applied directly to the hair and then rinsed lightly. Then, brushing was performed until it was dried with a dryer with a brush.

Adhesion effect: The degree of peeling after passing the brush 10 times was evaluated. ⊚: It is adhered and does not come off at all. ○: Not adhered and peeled. □; It adheres, but peels off slightly. Δ: Bonded, but almost peeled off. X: Not adhered.

Feeling: A: Very good feeling overall. ◯: Feels good overall. Δ: The overall feel is not so good. X: The overall feeling is very bad.

[0035]

[Table 1] ─────────────────────────────── Example Ingredients (% by weight) ───────── ─────── 1 2 3 4 5 ─────────────────────────────── Polysiloxane-oxyalkylene co-weight Combined ^{* 1} 6 16 36 11 21 Polyoxyethylene hydrogenated castor oil (EO = 60) 2 3 4 3 4 Ammonium-modified silicone ^{* 2} 4 6 6 2-Amino-modified silicone ^{* 3} − − − 36 Amino-modified silicone ^{* 4} − − − − − (Product name: Torre Silicone SM8702C) Acrylic resin Alkanol amine liquid (50%) − − − − − Polyvinylpyrrolidone / vinyl acetate copolymer − − − − − Polyvinyl phenyl pyridine / Dimethylaminoethyl methacrylate copolymer − − − − − Ethanol − − − − − Ion-exchanged water Remainder Remainder Remaining part Remaining part Remaining part ─────────────────────────────── Split ends adhesion effect ○ ○ ○ ◎ ◎ ◎ Feeling ◎ ◎ ◎ ◎ ◎ ◎ ─ ──────────────────────────────

[0036]

[Table 2] ─────────────────────────────── Comparative Example Components (% by weight) ──────── ────── 1 2 3 4 5 ───────────────────────────────Polysiloxane-oxyalkylene copolymer ^{* 1} 6 − − − 5 Polyoxyethylene hydrogenated castor oil (EO = 60) 2 3 2 3 3 Ammonium-modified silicone ^{* 2} − − − − − Amino-modified silicone ^{* 3} − − − − − Amino-modified silicone ^{* 4} − − − − 10 (Brand name: Toray Silicone SM8702C) Acrylic resin Alkanolamine liquid (50%) − − 22 − − Polyvinylpyrrolidone / vinyl acetate copolymer − 12 − − − Polyvinyl phenyl pyridine / Dimethylaminoethyl methacrylate copolymer − − − 22 − Ethanol − − 42 82 50 Deionized water balance Part Remaining part Remaining part ─────────────────────────────── Split ends adhesion effect △ △ × □ △ Feeling △ ◎ × × △ ───────────────────────────────

* 1: In the general formula (1), R ¹ and R ² are —CH ₂
CH (CH ₃ ) CH _2- , a = 50, b = 40, c = 40, x = 10

[0038] * 2: In the general formula (2), R ³ is methyl, R ⁴ is hydroxyl, R ⁵ is ^{_{- (CH 2) 3 N +}} (CH 3) 3 Cl -, m = 18000, n = 2 , Molecular weight: 1.3 million

* 3: In the general formula (2), R ³ and R ⁴ are methyl groups, R ⁵ is-(CH ₂ ) ₃ N (CH ₃ ) ₂ , m = 5000, n = 5, molecular weight: 37
Ten thousand

* 4: Molecular weight: 8000

Example 6 Shampoo A shampoo having the following composition was produced by a conventional method. When the obtained shampoo was washed with hair and blown with a drier under the same conditions as in Example 1, it was excellent in the split ends adhesion effect and feel.

(Formulation) (1) N-lauroyl-N′-carboxymethyl-N ′-(2-hydroxyethyl) ethylenediamine TEA salt 11.0% by weight (2) Polyoxyethylene (5) lauryl sulfosuccinate diester Sodium 6.0 (3) Lauric acid diethanolamide 3.0 (4) N- (2-dodecyl) hexadecyl-N, N, N-trimethylammonium chloride 2.0 (5) Coconut oil fatty acid amide propyl betaine 2.0 (6) Polysiloxane-oxyalkylene copolymer 2.0 (in the general formula (1), R ¹ and R ² are —CH ₂ CH ₂ CH ₂ —, a = 10, b = 30, c = 30, x = 10) (7) Amino-modified polymer silicone 2.0 (in the general formula (2), R ³ and R ⁴ are methyl groups, and R ⁵ is-(CH ₂ ) ₃ N (CH ₃ ) (CH ₂ ) ₂ N (CH _{3 ) 2} , m = 10000, n = 5, molecular weight: 740,000) (8) Fragrance 0.3 (9) Deionized water balance

Example 7 Hair Cream A hair cream having the following composition was produced by a conventional method. When the obtained hair cream was used in the same manner as in Example 1, it was excellent in the split ends adhesion effect and feel.

(Compounding Formulation) (1) Polysiloxane-oxyalkylene copolymer 25.0% by weight (in the general formula (1), R ¹ and R ² are —CH ₂ CH (CH ₃ ) CH ₂ —, a = 60, b = 80, c = 10, x = 10) (2) Amino-modified polymer silicone 6.0 (in the general formula (2), R ³ is a methyl group, R ⁴ is a hydroxyl group, and R ⁵ is ^{_{- (CH 2) 3 n +}} (CH 3) 3 Cl -, m = 18000, n = 2, molecular weight: 1.3 million) (3) glycerin 3.0 (4) polyoxyethylene hardened castor oil (120EO) 3. 0 (5) N-methacryloylethyl N, N-dimethylammonium α-methylcarboxybetaine stearyl methacrylate copolymer 3.0 (6) Ethanol 10.0 (7) Polyvinyl alcohol 1.0 (8) Perfume proper amount (9 ) Ion-exchanged water balance

Example 8 Treatment Foam A treatment foam having the following composition was produced by a conventional method. When the obtained treatment foam was used in the same manner as in Example 1, it was excellent in split ends adhesion effect and feel.

(Compounding Formulation) (1) Polysiloxane-oxyalkylene copolymer 4.0% by weight (in the general formula (1), R ¹ and R ² are —CH ₂ CH (CH ₃ ) CH ₂ —, a = 60, b = 0, c = 80, x = 80) (2) Octyldodecyl myristate 2.0 (3) Dipropylene glycol 2.0 (4) Stearyltrimethylammonium chloride 1.0 (5) Amino Modified Polymer Silicone 4.0 (In the general formula (2), 10% of R ³ is a phenyl group, the rest is a methyl group, R ⁴ is a methyl group, and R ⁵ is-(CH ₂ ) ₃ N ⁺ (CH ₃ ). ₃ Cl ⁻ , m = 10000, n = 2, molecular weight: 740,000) (6) Glycerin 4.0 (7) Liquid paraffin 5.0 (8) Polyoxyethylene sorbitan monostearate 1.0 (9) Ethanol 10 .0 (10) Methylparaben 0.1 (11) Perfume 0.2 (12) Propellant (LPG) 10.0 (13) Ion-exchanged water The balance

[0047]

As described above, the hair cosmetic composition of the present invention is capable of efficiently adhering and repairing the split ends of hair and improving the feel of the hair as a whole. .

Claims (3)

[Claims] 1. A hair cosmetic composition comprising the following components (A) and (B): (A) One or more polysiloxane-oxyalkylene copolymers represented by the general formula (1). Embedded image (In the formula, R ¹ and R ² each represent a divalent hydrocarbon group having 2 to 4 carbon atoms, and a represents a number of 1 to 1000,
b and c each represent a number from 0 to 1000. However, b
= C is not 0. x shows the number of 1-100. ) (B) The molecular weight represented by the general formula (2) is 200,000 to 150.
One or more kinds of various amino-modified or ammonium-modified polymer silicones. Embedded image [In the formula, R ³ represents a methyl group or a part thereof represents a phenyl group, and R ⁴ represents the same as R ⁵ or a methyl group or a hydroxyl group. R ⁵ is a formula R ⁶ Z {R ⁶ represents a divalent alkylene group having 3 to 6 carbon atoms, Z is —NR ⁷ ₂ , —N ⁺ R ⁷ _{3
^{A -, -NR 7 (CH 2}} ) a NR 7 2, -NR 7 (CH 2) a N +
R ⁷ ₃ A ^- and _{^{-NR 7 (CH 2) a N}} (R 7) C = O
(R ⁸ ) (R ⁷ represents hydrogen or an alkyl group having 1 to 4 carbon atoms, R ⁸ represents an alkyl group having 1 to 4 carbon atoms, and A represents a chlorine atom, a bromine atom or an iodine atom. And a is an integer of 2 to 6.) represents a monovalent group selected from the group consisting of: } Represents a substituent having an amino group or an ammonium group represented by m, n is a positive integer, and m + n is 3,000 to 20,
Represents an integer of 000, n / m is 1/500 to 1/10,
000. ] 2. The component (A) is 0.1 to 50.0% by weight.
And the component (B) is contained in an amount of 0.1 to 50.0% by weight. 3. 0.5 to 30.0% by weight of component (A)
And the component (B) is contained in an amount of 2.0 to 30.0% by weight.