JPH08203111A - Optical pickup device - Google Patents

Optical pickup device

Info

Publication number
JPH08203111A
JPH08203111A JP7009994A JP999495A JPH08203111A JP H08203111 A JPH08203111 A JP H08203111A JP 7009994 A JP7009994 A JP 7009994A JP 999495 A JP999495 A JP 999495A JP H08203111 A JPH08203111 A JP H08203111A
Authority
JP
Japan
Prior art keywords
holding member
light source
diffraction grating
receiving element
optical pickup
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP7009994A
Other languages
Japanese (ja)
Other versions
JP3497589B2 (en
Inventor
Naohito Shiga
直仁 志賀
Takae Hayashi
孝枝 林
Daisuke Matsuo
大介 松尾
Kazunari Tokuda
一成 徳田
Takeshi Yamazaki
健 山崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Olympus Corp
Original Assignee
Olympus Optical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Olympus Optical Co Ltd filed Critical Olympus Optical Co Ltd
Priority to JP00999495A priority Critical patent/JP3497589B2/en
Publication of JPH08203111A publication Critical patent/JPH08203111A/en
Application granted granted Critical
Publication of JP3497589B2 publication Critical patent/JP3497589B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

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  • Diffracting Gratings Or Hologram Optical Elements (AREA)
  • Optical Head (AREA)

Abstract

PURPOSE: To obtain an optical pickup device capable of shutting out the oxygen and moisture from the outside world and preventing the moisture absorption and oxidation deterioration of the photodetectors in an internal space. CONSTITUTION: This optical pickup device includes an objective lens which focuses the luminous flux from a light source 1 onto a disk, the photodetectors 4 which detect the reflected light from this disk, diffraction gratings 5, 6 which are disposed in the luminous flux from the light source 1 to the disk, a holder which holds this objective lens, a substrate 11 which supports the light source 1 and the photodetectors 4 and a holding member 8 which holds the substrate 11 and the diffraction gratings 5, 6. The light source 1 and the photodetectors 4 as well as the substrate 11 for supporting the light source 1 and the photodetectors 4 are housed in the inside space formed out of the diffraction gratings 5, 6, the holding member 8 and an adhesive 9 for joining the diffraction gratings 5, 6 to this holding member 8. A part of the diffraction gratings 5, 6 facing the inside space and/or a part of the holding member 8 is coated with a resin film 10 having a gas barrier property.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、光ディスク(以下「デ
ィスク」という。)への情報の記録、再生に用いられる
光学式ピックアップ装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an optical pickup device used for recording and reproducing information on an optical disc (hereinafter referred to as "disc").

【0002】[0002]

【従来の技術】近年、光ピックアップの様々な技術が開
示されており、例えば特開平1−237935号公報に
光学式ピックアップ装置が開示されている。この光学式
ピックアップ装置は、図4に示すようなもので、光源1
からの光束をディスク2上に集束させる対物レンズ3
と、前記ディスク2からの反射光を検出する受光素子4
と、前記光源1から前記ディスク2に至る光束中に設け
られ前記光源1からの光束を前記ディスク2上のピット
信号を読むための0次光及びトラッキングずれを読むた
めの1次光に分ける第1の回折格子5と、前記ディスク
2からの反射光を分岐して前記受光素子4に導く第2の
回折格子6とを具備し、前記対物レンズ3を保持する円
筒状の保持体7と、前記光源1及び受光素子4を固着し
た基板11と回折格子5、6とを保持する筒状の保持部
材8を設け、この保持部材8を前記保持体7内に前記光
源1から射出される光束の光軸を中心として回動可能に
保持したものである。
2. Description of the Related Art In recent years, various techniques of an optical pickup have been disclosed, for example, an optical pickup device is disclosed in Japanese Patent Laid-Open No. 1-237935. This optical pickup device is as shown in FIG.
Objective lens 3 for focusing the light flux from the laser beam on the disk 2
And a light receiving element 4 for detecting the reflected light from the disk 2.
And a light beam from the light source 1, which is provided in the light beam from the light source 1 to the disc 2, is divided into a 0th-order light beam for reading a pit signal on the disc 2 and a 1st-order light beam for reading a tracking shift. A cylindrical holding body 7 for holding the objective lens 3; and a second diffraction grating 6 for branching the reflected light from the disc 2 and guiding it to the light receiving element 4. A cylindrical holding member 8 for holding the substrate 11 to which the light source 1 and the light receiving element 4 are fixed and the diffraction gratings 5 and 6 is provided, and the holding member 8 is placed in the holding body 7 and the luminous flux emitted from the light source 1 is provided. It is rotatably held around the optical axis of the.

【0003】[0003]

【発明が解決しようとする課題】しかし、最近は小型化
・軽量化によりプラスチック材料の使用が多くなってい
る中で、上述した従来技術においては反射光を検出する
受光素子4が湿気や酸素を防ぐ構造ではない上に、殆ど
密閉構造になるため、高湿度下においては次のような問
題があった。
However, in recent years, while plastic materials have been used more and more due to miniaturization and weight reduction, in the above-mentioned prior art, the light receiving element 4 for detecting reflected light detects moisture and oxygen. Since it is not a preventive structure and the structure is almost sealed, it has the following problems under high humidity.

【0004】第1に、前記回折格子5、6や接着剤及び
保持部材8が吸湿するので、受光素子4や光源1及び受
光素子4や光源1を支持しているシリコン製の基板11
に湿気がかかり、これらの表面に微少電流が流れたり微
少電流が発生して次第に炭化し、トラッキングエラー信
号、フォーカシングエラー信号の検出機能が低下してし
まう。また、回折格子5、6の吸湿で寸法精度変化を生
じる。
First, since the diffraction gratings 5 and 6 and the adhesive and the holding member 8 absorb moisture, the light receiving element 4, the light source 1, and the silicon substrate 11 supporting the light receiving element 4 and the light source 1 are absorbed.
The surface is exposed to moisture, and a minute current flows on these surfaces, or a minute current is generated, and the carbon is gradually carbonized, and the detection function of the tracking error signal and the focusing error signal deteriorates. Further, the dimensional accuracy changes due to the moisture absorption of the diffraction gratings 5 and 6.

【0005】第2に、前記受光素子4は酸素に弱く、酸
素雰囲気下及び吸い込んだ湿気と酸素の共存下で次第に
酸化して劣化し、本来受光されるはずの信号が得られ
ず、長期的にはエラーになってしまう現象が発生する。
Secondly, the light receiving element 4 is weak to oxygen, and gradually oxidizes and deteriorates in an oxygen atmosphere and in the presence of absorbed moisture and oxygen, so that a signal which should be received originally cannot be obtained, and the light receiving element 4 is long-term. Will cause an error.

【0006】本発明は、かかる従来の問題点に鑑みてな
されたものであり、請求項1乃至3に係る発明の目的
は、回折格子を保持部材に接合(接着)する接着剤及び
保持部材自体が吸湿すること及び共存酸素による受光素
子の酸化劣化による検出機能低下を樹脂被覆により防止
した光学式ピックアップ装置を提供することにある。
The present invention has been made in view of the above conventional problems, and an object of the inventions according to claims 1 to 3 is to provide an adhesive for bonding (bonding) a diffraction grating to a holding member and the holding member itself. It is an object of the present invention to provide an optical pickup device in which a resin coating prevents the deterioration of the detection function due to the absorption of moisture and the oxidation deterioration of the light receiving element due to coexisting oxygen.

【0007】また、請求項4及び5に係る発明の目的
は、回折格子を保持部材に接合する接着剤や保持部材が
吸湿すること及び共存酸素による受光素子の酸化劣化に
よる検出機能低下を高機能化部材の採用により防止した
光学式ピックアップ装置を提供することにある。
Further, the object of the inventions according to claims 4 and 5 is to improve the detection function due to the fact that the adhesive or the holding member for bonding the diffraction grating to the holding member absorbs moisture and the coexisting oxygen causes the deterioration of the light receiving element due to the oxidation deterioration. An object of the present invention is to provide an optical pickup device which is prevented by the adoption of the activating member.

【0008】さらに、請求項6に係る発明の目的は、回
折格子と保持部材とを接着する接着剤や保持部材が吸湿
することと、共存酸素による受光素子の酸化劣化によ
る、検出機能低下を安価な部材の採用により防止した光
学式ピックアップ装置を提供することにある。
Further, the object of the invention according to claim 6 is to reduce the deterioration of the detection function due to the fact that the adhesive or the holding member for adhering the diffraction grating and the holding member absorbs moisture, and the coexisting oxygen causes oxidative deterioration of the light receiving element. Another object of the present invention is to provide an optical pickup device which is prevented by adopting various members.

【0009】[0009]

【課題を解決するための手段】上記課題を解決するため
に、請求項1に係る発明は、光源からの光束をディスク
上に集束させる対物レンズと、前記ディスクからの反射
光を検出する受光素子と、前記光源から前記ディスクに
至る光束中に設けられた回折格子と、前記対物レンズを
保持する保持体と、前記光源及び受光素子を支持する基
板と、この基板及び回折格子を保持する保持部材とを具
備する光学式ピックアップ装置において、前記光源と受
光素子と前記光源及び受光素子を支持する基板とを、前
記回折格子と前記保持部材と前記回折格子を前記保持部
材に接合する接着剤とで形成される内部空間に収納し、
前記内部空間内に面する前記回折格子の一部及び/又は
前記保持部材の一部を、ガスバリア性を有する樹脂で被
覆した構成とした。
In order to solve the above-mentioned problems, the invention according to claim 1 proposes an objective lens for converging a light beam from a light source onto a disc, and a light-receiving element for detecting the reflected light from the disc. A diffraction grating provided in the light flux from the light source to the disc; a holder for holding the objective lens; a substrate for supporting the light source and the light receiving element; and a holding member for holding the substrate and the diffraction grating. In the optical pickup device comprising: a light source, a light receiving element, a substrate supporting the light source and the light receiving element, the diffraction grating, the holding member, and an adhesive for bonding the diffraction grating to the holding member. Stored in the formed internal space,
A part of the diffraction grating and / or a part of the holding member facing the inner space is covered with a resin having a gas barrier property.

【0010】請求項2に係る発明は、前記回折格子及び
ガスバリア性を有する樹脂に低吸湿性材料を含有したも
のである。また、請求項3に係る発明は、前記ガスバリ
ア性を有する樹脂に酸素捕集剤を含有したものである。
According to a second aspect of the present invention, the resin having the diffraction grating and the gas barrier property contains a low hygroscopic material. Further, the invention according to claim 3 is such that the resin having the gas barrier property contains an oxygen scavenger.

【0011】ここで、前記ガスバリア性樹脂としては、
水蒸気や空気を通しにくい材料、例えば、ポリアミド樹
脂、エチレン・ビニルアルコール樹脂、エチレン・酸化
ビニル樹脂、ポリアリレート樹脂、アクリロニトリル樹
脂、ポリエチレン樹脂、ポリプロピレン樹脂、非晶質ポ
リオレフィン樹脂等を1種又は2種以上積層して用い
る。また、前記低吸湿性材料としては、分子中に極性基
を有しない材料、例えば、ポリエチレン樹脂、ポリプロ
ピレン樹脂、非晶質ポリオレフィン樹脂、フッ素樹脂等
を用いる。被覆の方法としては、樹脂を溶剤に溶解した
ものを塗布・乾燥・溶融・焼き付け等行ったり、成形加
工時に二色成形のような方法で行う。
Here, as the gas barrier resin,
Materials that do not allow water vapor or air to pass through, such as polyamide resin, ethylene / vinyl alcohol resin, ethylene / vinyl oxide resin, polyarylate resin, acrylonitrile resin, polyethylene resin, polypropylene resin, amorphous polyolefin resin, etc. The above is used by stacking. As the low hygroscopic material, a material having no polar group in the molecule, for example, polyethylene resin, polypropylene resin, amorphous polyolefin resin, fluororesin or the like is used. As a coating method, a resin dissolved in a solvent is applied, dried, melted, baked, or a method such as two-color molding is used at the time of molding.

【0012】一方、前記酸素捕集剤としては、例えば、
(1) 少なくとも鉄粉と金属ハロゲン化物とを含有するも
の、(2) 少なくとも不飽和脂肪酸化合物及び/又は不飽
和基を有する鎖状炭化水素重合物と酸化促進触媒と塩基
性物質と吸着物質とを含有するもの、(3) 少なくとも下
記化1に示すような骨格構造を有する化合物及び/又は
その誘導体と遷移金属化合物とリン化合物からなるも
の、等を用いる。
On the other hand, examples of the oxygen scavenger include:
(1) containing at least iron powder and a metal halide, (2) chain hydrocarbon polymer having at least unsaturated fatty acid compound and / or unsaturated group, oxidation-promoting catalyst, basic substance and adsorbing substance (3) at least a compound having a skeletal structure represented by the following chemical formula 1 and / or a derivative thereof, a transition metal compound and a phosphorus compound, and the like are used.

【0013】[0013]

【化1】 Embedded image

【0014】上述した(1) の鉄粉としては、自身が酸化
されて、酸素を吸収する粉末状の金属鉄が用いられる。
そのような鉄粉としては、例えば、電解鉄粉、還元鉄
粉、噴霧鉄粉、噴霧鉄粉合金等の鉄粉類、鋳鉄、鋼、鉄
合金等の鉄製品を粉砕して粉末状にしたもの、及びこれ
らの部分酸化物等が挙げられる。もちろん鉄粉は不純物
を含む物でも良い。
As the iron powder of the above (1), powdery metallic iron which itself is oxidized and absorbs oxygen is used.
As such iron powder, for example, electrolytic iron powder, reduced iron powder, atomized iron powder, iron powder such as atomized iron powder alloy, cast iron, steel, iron products such as iron alloys are pulverized into powder form. And partial oxides thereof. Of course, the iron powder may contain impurities.

【0015】また、金属ハロゲン化物としては、例え
ば、塩化ナリトウム、塩化カリウム等のアルカリ金属の
塩化物、塩化マグネシウム、塩化カルシウム等のアルカ
リ土類金属の塩化物、塩化アルミニウム、塩化第一鉄、
塩化第二鉄等の各種塩化物、臭化ナトリウム、臭化カリ
ウム等のアルカリ金属の臭化物、臭化マグネシウム、臭
化カルシウム等のアルカリ土類金属の臭化物、臭化鉄、
臭化ニッケル等の各種臭化物、ヨウ化ナトリウム、ヨウ
化カリウム等のアルカリ金属のヨウ化物、ヨウ化マグネ
シウム、ヨウ化カルシウム等のアルカリ土類金属のヨウ
化物、ヨウ化鉄等の各種ヨウ化物等が挙げられる。これ
らの中で、人体への安全衛生性の見地から金属塩化物が
好ましく、塩化ナトリウム、塩化マグネシウム、塩化カ
ルシウム、塩化第一鉄、塩化第二鉄等が特に好ましい。
金属ハロゲン化物の使用量は、水分の量や拡散速度にも
よるが、効果的な量としては、鉄粉100重量部に対し
て0.01〜20重量部、好ましくは0.2〜5重量部
の範囲で用いられる。この他に、粉末フィラーを混入さ
せても良い。
Examples of metal halides include chlorides of alkali metals such as sodium chloride and potassium chloride, chlorides of alkaline earth metals such as magnesium chloride and calcium chloride, aluminum chloride and ferrous chloride.
Various chlorides such as ferric chloride, alkali metal bromides such as sodium bromide and potassium bromide, alkaline earth metal bromides such as magnesium bromide and calcium bromide, iron bromide,
Various bromides such as nickel bromide, alkali metal iodides such as sodium iodide and potassium iodide, alkaline earth metal iodides such as magnesium iodide and calcium iodide, and various iodides such as iron iodide. Can be mentioned. Among these, metal chlorides are preferable from the viewpoint of safety and health to the human body, and sodium chloride, magnesium chloride, calcium chloride, ferrous chloride, ferric chloride and the like are particularly preferable.
The amount of the metal halide used depends on the amount of water and the diffusion rate, but an effective amount is 0.01 to 20 parts by weight, preferably 0.2 to 5 parts by weight with respect to 100 parts by weight of the iron powder. Used in part range. In addition to this, a powder filler may be mixed.

【0016】粉末フィラーとしては、水に難溶性又は不
溶性の物質が用いられる。粒度は60メッシュ以下、好
ましくは100メッシュ以下のものが用いられる。粉末
フィラーの粒度が60メッシュを越える場合には、粉末
フィラー同士の間隙に鉄粉が入り込み、鉄粉の分散が十
分に行われない。
As the powder filler, a substance which is hardly soluble or insoluble in water is used. The particle size is 60 mesh or less, preferably 100 mesh or less. When the particle size of the powder filler exceeds 60 mesh, the iron powder enters the gaps between the powder fillers and the iron powder is not sufficiently dispersed.

【0017】上述した(2) の不飽和脂肪酸化合物とは、
炭素数が10以上で炭素原子間の二重結合を一つ以上有
したものであり、即ち不飽和脂肪酸、不飽和脂肪酸エス
テル及び不飽和脂肪酸塩である。不飽和脂肪酸化合物の
例として、オレイン酸、リノール酸、リノレン酸、アラ
キドン酸、パリナリン酸、ダイマー酸、リチノレイン酸
又は、リシノール酸等の不飽和脂肪酸、及びこれら不飽
和脂肪酸のエステル及びこれらエステル類を含有する油
脂、上記不飽和脂肪酸の金属塩等が挙げられる。
The unsaturated fatty acid compound (2) mentioned above is
It has 10 or more carbon atoms and one or more double bonds between carbon atoms, that is, unsaturated fatty acids, unsaturated fatty acid esters and unsaturated fatty acid salts. Examples of unsaturated fatty acid compounds, oleic acid, linoleic acid, linolenic acid, arachidonic acid, parinaric acid, dimer acid, ritinoleic acid or unsaturated fatty acids such as ricinoleic acid, and esters of these unsaturated fatty acids and these esters Examples thereof include oils and fats contained therein, metal salts of the above unsaturated fatty acids, and the like.

【0018】不飽和基を有する鎖状炭化水素重合物と
は、炭素数が10以上で、炭素原子間の二重結合を一つ
以上有したもの及びその誘導体である。該誘導体の置換
基として、例えば水酸基、ホルミル基等が存在していて
も良い。不飽和基を有する鎖状炭化水素重合物の例とし
て、ブタジエン、イソプレン、ピペリレン、1,3−ペ
ンタジエンの重合体が挙げられる。これらの化合物は必
ずしも純物質である必要はなく、不飽和脂肪酸及びその
塩、不飽和基を有する炭化水素重合物及びその誘導体の
2種以上の混合物であっても良い。好ましくは、不飽和
脂肪酸の遷移金属塩或いは、不飽和脂肪酸の遷移金属塩
と不飽和脂肪酸の混合物、又はこれらの混合物に更に不
飽和基を有する炭化水素重合物を加えたものである。
The chain hydrocarbon polymer having an unsaturated group is a chain hydrocarbon polymer having 10 or more carbon atoms and at least one double bond between carbon atoms, and derivatives thereof. As a substituent of the derivative, for example, a hydroxyl group or a formyl group may be present. Examples of chain hydrocarbon polymers having an unsaturated group include polymers of butadiene, isoprene, piperylene, and 1,3-pentadiene. These compounds do not necessarily have to be pure substances, and may be a mixture of two or more kinds of unsaturated fatty acids and salts thereof, hydrocarbon polymers having unsaturated groups and derivatives thereof. Preferably, it is a transition metal salt of an unsaturated fatty acid, a mixture of a transition metal salt of an unsaturated fatty acid and an unsaturated fatty acid, or a mixture of these and a hydrocarbon polymer having an unsaturated group.

【0019】酸化促進触媒としては、Fe、Ni、C
o、V、Pt等の遷移金属とその化合物、ラジカル重合
開始剤等が挙げられる。塩基性物質として好ましくは、
アルカリ金属又はアルカリ土類金属の酸化物、水酸化
物、炭酸塩、有機酸塩及び有機アミン類等が挙げられ
る。吸着物質として好ましくは、天然パルプ、合成パル
プからなる紙とか合成紙、シリカゲル、活性炭、ゼオラ
イト、活性白土等が例として挙げられる。
As the oxidation accelerating catalyst, Fe, Ni, C
Examples thereof include transition metals such as o, V, and Pt, compounds thereof, radical polymerization initiators, and the like. Preferably as the basic substance,
Examples thereof include alkali metal or alkaline earth metal oxides, hydroxides, carbonates, organic acid salts and organic amines. Preferred examples of the adsorbing substance include paper made of natural pulp and synthetic pulp, synthetic paper, silica gel, activated carbon, zeolite, activated clay and the like.

【0020】組成物中の各構成成分比は、特に限定しな
いが、不飽和脂肪酸化合物等の主剤100重量部に対し
て、触媒は0.01〜10重量部、塩基性物質は1〜
1,000重量部、吸着物質は10〜1,000重量部
からなることが好ましい。
The ratio of each component in the composition is not particularly limited, but 0.01 to 10 parts by weight of the catalyst and 1 to 10 parts by weight of the basic substance are used with respect to 100 parts by weight of the main agent such as unsaturated fatty acid compound.
It is preferable that 1,000 parts by weight and the adsorbing substance are 10 to 1,000 parts by weight.

【0021】上述した(3) の化1の骨格構造を有する化
合物及び/又はその誘導体とは、その骨格構造を分子中
に少なくとも1個有する化合物であり、具体的には、ベ
ンジルアミン、3−メチルベンジルアミン、メタキシリ
レンジアミン、パラキシリレンジアミン、N,N'−ジメチ
ルメタキシリレンジアミン、N,N,N',N' −テトラメチル
メタキシリレンジアミン、N,N'−ジメチルパラキシリレ
ンジアミン、N,N,N',N' −テトラメチルパラメタキシリ
レンジアミン、N,N'−ジメチルメタキシリレンジアミ
ン、N,N,N',N' −テトラエチルメタキシリレンジアミ
ン、N,N'−ジエチルパラキシリレンジアミン、N,N,N',
N' −テトラエチルパラキシリレンジアミン、1,3,
5−トリス(アミノメチル)ベンゼン、メタキシリレン
ジアミン又はパラキシリレンジアミンと有機カルボン
酸、例えば、ステアリン酸、オレイン酸、ラウリル酸、
トール油脂肪酸等のモノカルボン酸及びアジピン酸、セ
バシン酸、ダイマー酸等のジカルボン酸との塩及びアミ
ド、エポキシ樹脂硬化剤として広く使用されているメタ
キシリレンジアミン又はパラキシリレンジアミンとホル
ムアルデヒド及びフェノールとの反応によって得られる
マンニッヒ塩基、メタキシリレンジアミン又はパラキシ
リレンジアミンとアクリロニトリル、メチルメタクリレ
ート等のビニル化合物との付加体、メタキシリレンジア
ミン又はパラキシリレンジアミンとエポキシ化合物、例
えばビスフェノールA系エポキシ樹脂、ビスフェノール
F系エポキシ樹脂、ブチルグリシジルエーテル等との付
加体、及びこれら硬化剤により硬化されたエポキシ樹脂
硬化物、テトラグリシジルメタキシリレンジアミンで代
表されるアミノ基含有エポキシ化合物、メタキシリレン
ジイソシアネート、パラキシリレンジイソシアネートで
代表されるイソシアネート化合物とそれぞれから誘導さ
れるポリウレタン等を例示することができるが、これら
のものを複数配合して使用することもできる。上記の中
で好ましいものは、メタキシリレンジアミン、下記化2
で表される化合物、ポリアミド、及びテトラグリシジル
メタキシリレンジアミンである。
The compound and / or derivative thereof having the skeleton structure of the chemical formula 1 of the above (3) is a compound having at least one skeleton structure in the molecule, and specifically, benzylamine, 3- Methylbenzylamine, metaxylylenediamine, paraxylylenediamine, N, N'-dimethylmetaxylylenediamine, N, N, N ', N'-tetramethylmethaxylylenediamine, N, N'-dimethylparaxylyl Diamine, N, N, N ', N'-Tetramethylparameter xylylenediamine, N, N'-Dimethylmetaxylylenediamine, N, N, N', N'-Tetraethylmethaxylylenediamine, N, N '-Diethylparaxylylenediamine, N, N, N',
N'-tetraethylparaxylylenediamine, 1,3
5-tris (aminomethyl) benzene, meta-xylylenediamine or para-xylylenediamine and organic carboxylic acids such as stearic acid, oleic acid, lauric acid,
Salts and amides of monocarboxylic acids such as tall oil fatty acids and dicarboxylic acids such as adipic acid, sebacic acid and dimer acid, and metaxylylenediamine or paraxylylenediamine and formaldehyde and phenol widely used as epoxy resin curing agents. Mannich base, adduct of metaxylylenediamine or paraxylylenediamine and vinyl compound such as acrylonitrile and methylmethacrylate, obtained by reaction with, metaxylylenediamine or paraxylylenediamine and epoxy compound, for example, bisphenol A epoxy Resin, bisphenol F-based epoxy resin, adduct with butyl glycidyl ether, etc., cured epoxy resin with these curing agents, amino group represented by tetraglycidyl metaxylylenediamine Yes epoxy compounds, m-xylylene diisocyanate, but the polyurethane are derived from each with an isocyanate compound represented by para-xylylene diisocyanate and the like can be exemplified, can be used by multiple blending these things. Among the above, metaxylylenediamine and the following chemical formula 2 are preferable.
A compound represented by, a polyamide, and tetraglycidyl metaxylylenediamine.

【0022】[0022]

【化2】 Embedded image

【0023】遷移金属化合物としては、Co、Mn、C
u、Fe、Ni、Rh等の遷移金属の酢酸塩、ステアリ
ン酸塩、ナフテン酸塩等のモノカルボン酸塩、ジカルボ
ン酸塩及びキレート化合物等が挙げられる。上記の中で
特に好ましい遷移金属化合物は、酢酸コバルト、ステア
リン酸コバルト、アセチルアセトンコバルト、アセチル
アセトン鉄、酢酸マンガンである。これらの化合物は1
種もしくは2種以上併用することができ、全組成物に対
して金属成分として1〜10,000ppmの範囲、好
ましくは10〜1,000ppmの範囲で添加される。
As the transition metal compound, Co, Mn, C
Examples thereof include acetates of transition metals such as u, Fe, Ni and Rh, monocarboxylates such as stearates and naphthenates, dicarboxylates and chelate compounds. Among the above, particularly preferable transition metal compounds are cobalt acetate, cobalt stearate, acetylacetone cobalt, acetylacetone iron, and manganese acetate. These compounds are 1
One kind or two or more kinds can be used in combination, and it is added as a metal component in the range of 1 to 10,000 ppm, preferably 10 to 1,000 ppm with respect to the entire composition.

【0024】リン化合物としては、リン酸塩、亜リン酸
塩、次亜リン酸塩が挙げられる。具体例としては、リン
酸三ナトリウム、リン酸三カリウム、リン酸水素二ナト
リウム、リン酸水素二カリウム、リン酸二水素ナトリウ
ム、リン酸二水素カリウム、亜リン酸ナトリウム、亜リ
ン酸カリウム、次亜リン酸ナトリウム、次亜リン酸カリ
ウム、リン酸鉄等が挙げられる。これらリン化合物は、
それぞれ1種もしくは2種以上併用することができ、全
組成物に対してリン成分として1〜10,000ppm
の範囲、好ましくは10〜1,000ppmの範囲で添
加される。
Examples of the phosphorus compound include phosphate, phosphite and hypophosphite. Specific examples include trisodium phosphate, tripotassium phosphate, disodium hydrogen phosphate, dipotassium hydrogen phosphate, sodium dihydrogen phosphate, potassium dihydrogen phosphate, sodium phosphite, potassium phosphite, and Examples thereof include sodium phosphite, potassium hypophosphite, iron phosphate and the like. These phosphorus compounds are
Each of them can be used alone or in combination of two or more, and as a phosphorus component relative to the total composition, 1 to 10,000 ppm
Is added, preferably in the range of 10 to 1,000 ppm.

【0025】請求項4に係る発明は、光源からの光束を
ディスク上に集束する対物レンズと、前記ディスクから
の反射光を検出する受光素子と、前記光源から前記ディ
スクに至る光束中に設けられた回折格子と、前記対物レ
ンズを保持する保持体と、前記光源及び受光素子を支持
する基板と、この基板及び回折格子を保持する保持部材
とを具備する光学式ピックアップ装置において、前記光
源と受光素子と前記光源及び受光素子を支持する基板と
を、前記回折格子と前記保持部材と前記回折格子を前記
保持部材に接合する接着剤とで形成される内部空間に収
納し、前記接着剤及び/又は前記保持部材中に、前記酸
素捕集剤を含有することとした。
According to a fourth aspect of the present invention, an objective lens for focusing the light flux from the light source on the disc, a light receiving element for detecting the reflected light from the disc, and a light flux from the light source to the disc are provided. In the optical pickup device, a diffraction grating, a holder for holding the objective lens, a substrate for supporting the light source and the light receiving element, and a holding member for holding the substrate and the diffraction grating are provided. An element and a substrate that supports the light source and the light receiving element are housed in an internal space formed by the diffraction grating, the holding member, and an adhesive that bonds the diffraction grating to the holding member. Alternatively, the oxygen scavenger is included in the holding member.

【0026】ここで、接着剤中に酸素捕集剤を含有させ
るには、前記の各種酸素捕集剤を各種未硬化液状接着剤
中に混合・撹拌してから接着部に塗布し、乾燥・硬化等
を行う。ここで用いる接着剤は、市販の各種高分子系の
物が用いられるが、前記問題点を回避する観点から、請
求項5に係る発明は、低吸湿材料をベース材料としたも
のを用いることとした。前記保持部材中に前記酸素捕集
剤を含有させるには、保持部材の成形前に低吸湿性成形
材料と各種酸素捕集剤とを溶解又は溶融したり粉体同士
を混練・混合して添加する。
Here, in order to include an oxygen scavenger in the adhesive, the above-mentioned various oxygen scavengers are mixed and stirred in various uncured liquid adhesives, and then applied to the adhesive portion and dried. Curing etc. As the adhesive used here, commercially available various polymeric materials are used, but from the viewpoint of avoiding the above problems, the invention according to claim 5 uses a low hygroscopic material as a base material. did. In order to contain the oxygen scavenger in the holding member, the low hygroscopic molding material and various oxygen scavengers are dissolved or melted before the holding member is molded, or the powders are kneaded and mixed to be added. To do.

【0027】請求項6に係る発明は、光源からの光束を
ディスク上に集束させる対物レンズと、前記ディスクか
らの反射光を検出する受光素子と、前記光源から前記デ
ィスクに至る光束中に設けられた回折格子と、前記対物
レンズを保持する保持体と、前記光源及び受光素子を支
持する基板と、この基板及び回折格子を保持する保持部
材を具備している光学式ピックアップ装置において、前
記光源と受光素子と前記光源及び受光素子を支持する基
板とを、前記回折格子と前記保持部材と前記回折格子を
前記保持部材に接合する接着剤とで形成される内部空間
に収納し、前記内部空間内に、前記酸素捕集剤を内包す
る酸素捕集剤包装体を設置することとした。
According to a sixth aspect of the present invention, an objective lens for focusing the light flux from the light source on the disc, a light receiving element for detecting the reflected light from the disc, and a light flux from the light source to the disc are provided. An optical pickup device comprising: a diffraction grating; a holder for holding the objective lens; a substrate for supporting the light source and the light receiving element; and a holding member for holding the substrate and the diffraction grating. The light receiving element, the light source, and the substrate supporting the light receiving element are housed in an internal space formed by the diffraction grating, the holding member, and an adhesive that bonds the diffraction grating to the holding member. Then, an oxygen scavenger package containing the oxygen scavenger was installed.

【0028】ここで、酸素捕集剤包装体としては、前記
各種の酸素捕集剤を、通気性包装材料に包装して用いた
り、樹脂バインダー等を添加して、加圧や溶解・溶融等
により顆粒状、錠剤状、シート状等の各種形状に成形し
て用いる。通気性包装材料としては、例えば、和紙と有
孔ポリエチレンフィルムを積層接着した袋の外側に更に
ポリエステルフィルムとポリエチレンフィルムで積層接
着し穿孔したもの等から作られた袋であり、密封は通常
ヒートシールにより行われる。設置の方法としては、例
えば、前記包装体を両面粘着テープを介して前記空間内
の光学有効径外に固着する。
Here, as the oxygen scavenger package, the various oxygen scavengers described above are used by being packaged in a breathable packaging material, or by adding a resin binder or the like to pressurizing, dissolving or melting. It is used after being molded into various shapes such as granules, tablets and sheets. The breathable packaging material is, for example, a bag made by laminating and adhering a polyester film and a polyethylene film to the outside of a bag in which Japanese paper and a perforated polyethylene film are laminated and adhered, and the sealing is usually a heat seal. Done by. As an installation method, for example, the package is fixed to the outside of the optically effective diameter in the space via a double-sided adhesive tape.

【0029】[0029]

【作用】請求項1に係る発明の作用は、前記回折格子と
前記保持部材と前記回折格子を前記保持部材に接合する
接着剤とで形成される前記内部空間に面する前記回折格
子の一部及び/又は前記保持部材の一部を、ガスバリア
性の樹脂で被覆したので、前記内部空間外から回折格子
や保持部材の材料中を侵入してくる酸素と水分を、被覆
した樹脂層でシャットアウトすることができ、前記内部
空間内の受光素子を吸湿及び酸化劣化を防止できる。
The action of the invention according to claim 1 is that a part of the diffraction grating facing the internal space formed by the diffraction grating, the holding member, and an adhesive for joining the diffraction grating to the holding member. And / or since a part of the holding member is covered with a gas barrier resin, oxygen and water that enter the material of the diffraction grating or the holding member from outside the internal space are shut out by the covered resin layer. It is possible to prevent moisture absorption and oxidative deterioration of the light receiving element in the internal space.

【0030】請求項2に係る発明の作用は、請求項1で
のガスバリア性樹脂と前記回折格子の材料に、低吸湿材
料を採用したので、回折格子自体も全体的に疎水性とな
り、より外界からの水分をシャットアウトし易くするこ
とができる。
With the operation of the invention according to claim 2, since the low hygroscopic material is adopted as the material of the gas barrier resin and the diffraction grating in claim 1, the diffraction grating itself becomes hydrophobic as a whole, and the external environment is improved. The water from can be easily shut out.

【0031】請求項3に係る発明の作用は、請求項1で
のガスバリア性樹脂に酸素補集剤を含有させたので、樹
脂中を透過しようとする酸素と水分、更には前記内部空
間中の酸素と水分までも吸収して除去する為、確実に前
記受光素子を吸湿と酸化劣化から保護することができ
る。
Since the gas barrier resin according to claim 1 contains the oxygen scavenger, the function of the invention according to claim 3 is to allow oxygen and water to pass through the resin, and further, to collect oxygen in the internal space. Since even oxygen and water are absorbed and removed, the light receiving element can be reliably protected from moisture absorption and oxidative deterioration.

【0032】この酸素捕集剤の作用は、前述の手段での
(1) のような鉄粉と金属ハロゲン化物との組み合わせの
場合、雰囲気中の酸素により鉄粉が酸化される際、雰囲
気中の水分も金属ハロゲン化物により鉄粉へ移行し、酸
化に寄与する。また、金属ハロゲン化物は酸化の触媒と
しても作用する、この時、粉末フィラーを添加すると、
粉末フィラーは鉄粉粒子間に入り込み鉄粉を分散させ、
酸化反応で発せられる熱を速やかに外部に放出すると共
に、鉄粉の凝集を防止し鉄粉凝集部の高温化を防止す
る。但し、前記内部空間が小空間である場合は、この粉
末フィラーは添加する必要がない。
The action of this oxygen scavenger is the same as in the above-mentioned means.
In the case of the combination of iron powder and metal halide as in (1), when the iron powder is oxidized by oxygen in the atmosphere, the moisture in the atmosphere is also transferred to the iron powder by the metal halide and contributes to the oxidation. . In addition, the metal halide also acts as a catalyst for oxidation. At this time, if powder filler is added,
The powder filler enters between the iron powder particles to disperse the iron powder,
The heat generated by the oxidation reaction is quickly released to the outside, and the iron powder is prevented from aggregating to prevent the iron powder agglomerating part from becoming hot. However, when the internal space is a small space, it is not necessary to add this powder filler.

【0033】前述の手段での(2) のような不飽和脂肪酸
化合物及び/又は不飽和基を有する鎖状炭化水素重合物
と酸化促進触媒と塩基性化合物と吸着物質との組み合わ
せの場合、前記不飽和脂肪酸化合物及び/又は不飽和基
を有する鎖状炭化水素重合物を単独で用いる他、組成物
の形状を維持して酸素や水分との接触面積を増大させる
為に、紙、不織布、パーライト、活性炭、ゼオライト等
の吸着物質に含浸したり混合したりコートしたりして吸
着させる。前記不飽和脂肪酸化合物及び/ 又は不飽和基
を有する鎖状炭化水素重合物は、酸化促進触媒の存在下
で酸素と水分により不飽和基が付加反応により酸化され
る。塩基性物質は、前記不飽和脂肪酸化合物及び/又は
不飽和基を有する鎖状炭化水素重合物が酸化されて発生
する酸性の副生成物を吸収するものである。
In the case of the combination of the unsaturated fatty acid compound and / or the chain hydrocarbon polymer having an unsaturated group, the oxidation accelerating catalyst, the basic compound and the adsorbing substance as described in (2) in the above-mentioned means, In addition to using the unsaturated fatty acid compound and / or the chain hydrocarbon polymer having an unsaturated group alone, in order to maintain the shape of the composition and increase the contact area with oxygen and water, paper, nonwoven fabric, pearlite It is adsorbed by being impregnated with, mixed with, or coated with an adsorbent such as activated carbon or zeolite. In the unsaturated fatty acid compound and / or the chain hydrocarbon polymer having an unsaturated group, the unsaturated group is oxidized by an addition reaction with oxygen and water in the presence of an oxidation accelerating catalyst. The basic substance absorbs an acidic by-product generated by the oxidation of the unsaturated fatty acid compound and / or the chain hydrocarbon polymer having an unsaturated group.

【0034】前述の手段での(3) のような化1に示す骨
格構造を有する化合物と遷移金属化合物とリン化合物と
の組み合わせの場合、機構は十分解明されていないが、
前記(1) や(2) に記載した場合よりも効率良く酸素を補
修する組成として最近注目を集めている。
In the case of the combination of the compound having the skeleton structure shown in Chemical formula 1 such as (3), the transition metal compound and the phosphorus compound by the above-mentioned means, the mechanism has not been sufficiently clarified,
Recently, it has been drawing attention as a composition that repairs oxygen more efficiently than in the cases described in (1) and (2) above.

【0035】請求項4に係る発明の作用は、前記内部空
間を構成する前記保持部材と前記回折格子とを固着する
為の接着剤及び/又は前記保持部材中に前記酸素捕集剤
を含有したことで、前記回折格子と前記保持部材と前記
回折格子を前記保持部材に接合する接着剤とで形成され
る前記内部空間内の酸素と水分とを、効率良く吸収・除
去し、前記内部空間内に収納されている受光素子の吸湿
や酸化劣化を防止できる。
According to a fourth aspect of the present invention, an adhesive for fixing the holding member and the diffraction grating forming the internal space and / or the holding member contains the oxygen scavenger. This efficiently absorbs and removes oxygen and water in the internal space formed by the diffraction grating, the holding member, and an adhesive that bonds the diffraction grating to the holding member, and It is possible to prevent moisture absorption and oxidative deterioration of the light receiving element housed in.

【0036】請求項5に係る発明の作用は、前記請求項
4における接着剤や保持部材に低吸湿材料を含有させた
ので、構成材料自体の疎水性を上げて水分透過を防止
し、より吸湿や酸化劣化を防止できるものである。
The effect of the invention according to claim 5 is that the adhesive and the holding member according to claim 4 contain a low hygroscopic material, so that the constituent material itself is made more hydrophobic to prevent moisture permeation and to further absorb moisture. And oxidative deterioration can be prevented.

【0037】請求項6に係る発明の作用は、前記保持部
材と前記回折格子とこれら回折格子と保持部材とを固着
する為の接着剤とで形成される前記内部空間内に、前記
酸素捕集剤を内包する酸素捕集剤包装体を設置すること
により、前記内部空間が密閉度の高い空間の場合は、前
記内部空間構成材料に樹脂の被覆や酸素捕集剤を混入さ
せる等種々の細工をせずに、単に前記内部空間内に酸素
捕集剤を入れておくだけで、十分に前記内部空間中の酸
素と水分とを除去し、前記内部空間内に収納されている
前記受光素子の吸湿や酸化劣化を防止できる。
According to a sixth aspect of the present invention, the oxygen scavenger is formed in the internal space formed by the holding member, the diffraction grating, and an adhesive for fixing the diffraction grating and the holding member. By installing an oxygen scavenger package containing an agent, when the internal space is a highly sealed space, various work such as coating the internal space constituent material with a resin or mixing an oxygen scavenger Without, simply by placing an oxygen scavenger in the internal space, to sufficiently remove oxygen and moisture in the internal space, of the light-receiving element housed in the internal space Moisture absorption and oxidative deterioration can be prevented.

【0038】[0038]

【実施例】【Example】

[第1実施例]図1は本実施例に係る光学式ピックアッ
プ装置の要部の縦断面図である。尚、図1に示す光学式
ピックアップ装置において図4に示す従来装置と同一の
機能を有するものには同一の符号を付して示す。
[First Embodiment] FIG. 1 is a longitudinal sectional view of a main portion of an optical pickup device according to the present embodiment. In the optical pickup device shown in FIG. 1, components having the same functions as those of the conventional device shown in FIG. 4 are designated by the same reference numerals.

【0039】(構成)本実施例の光学式ピックアップ装
置は、光源1からの光束をディスク(図示省略)上に集
束させるための図1には図示しない対物レンズと、前記
ディスク2からの反射光を検出する一対の受光素子4
と、前記光源1からディスクに至る光束中に設けた回折
格子5、6と、前記対物レンズを保持する図1には図示
しない保持体と、前記光源1及び受光素子4を支持する
シリコン製の基板11と、前記受光素子4と前記基板1
1とを前記回折格子5、6と所定の距離を隔てて保持す
るように、上部内面に前記回折格子5、6を嵌合保持す
る為の段部を備えて前記基板11及び回折格子5、6を
保持する保持部材8とを具備している。
(Structure) The optical pickup device of this embodiment has an objective lens (not shown in FIG. 1) for focusing the light beam from the light source 1 on a disc (not shown), and the reflected light from the disc 2. Pair of light receiving elements 4 for detecting light
1, diffraction gratings 5 and 6 provided in the light flux from the light source 1 to the disk, a holding body (not shown in FIG. 1) for holding the objective lens, and a silicon-made support for the light source 1 and the light receiving element 4. Substrate 11, light receiving element 4 and substrate 1
In order to hold 1 and the diffraction gratings 5 and 6 at a predetermined distance from each other, a step portion for fitting and holding the diffraction gratings 5 and 6 is provided on the upper inner surface, and the substrate 11 and the diffraction grating 5 are provided. And a holding member 8 for holding 6.

【0040】前記対物レンズと、この対物レンズを保持
する保持体とは従来例として説明した図4の対物レンズ
3及び保持体7を使用している。吸湿率0.1重量%以
下である低吸湿性プラスチック材料である非晶質ポリオ
レフィン樹脂、例えば、日本ゼオン株式会社・商品名Z
EONEX、三井石油化学株式会社・商品名APO、日
本合成ゴム株式会社・商品名アートン等により成形され
た平板状成形品の表裏面に形成されている前記回折格子
6は、有底円筒状の保持部材8の上部内面に、保持部材
8の上端面と面一になるようにして、接着剤9により固
着されている。
The objective lens 3 and the holder 7 shown in FIG. 4 described as a conventional example are used as the objective lens and the holder for holding the objective lens. Amorphous polyolefin resin, which is a low hygroscopic plastic material having a moisture absorption rate of 0.1% by weight or less, for example, Zeon Co., Ltd., trade name Z
The diffraction grating 6 formed on the front and back surfaces of a flat-plate molded article molded by EONEX, Mitsui Petrochemical Co., Ltd., trade name APO, Japan Synthetic Rubber Co., Ltd., trade name Arton, etc., has a bottomed cylindrical shape. The upper surface of the member 8 is fixed with an adhesive 9 so as to be flush with the upper end surface of the holding member 8.

【0041】また、光源1と受光素子4とこれら光源1
及び受光素子4を支持するシリコン製の基板11とは、
回折格子5と保持部材8とで形成される内部空間内に収
納されている。
Further, the light source 1, the light receiving element 4 and these light sources 1
And the silicon substrate 11 that supports the light receiving element 4,
It is housed in an internal space formed by the diffraction grating 5 and the holding member 8.

【0042】前記保持部材8は、低吸湿プラスチック材
料である非晶質ポリオレフィン樹脂、例えば、日本ゼオ
ン株式会社・商品名ZEONEX、三井石油化学株式会
社・商品名APO、日本合成ゴム株式会社・商品名アー
トン等により形成されている。前記回折格子5、6の外
周面と前記保持部材8の内周面との間の空隙には、前述
の如く接着剤9が介在されており、前記内部空間内に面
した回折格子5、6の光学性能有効範囲外、及び保持部
材8の一部分に樹脂皮膜10を被覆している。
The holding member 8 is an amorphous polyolefin resin which is a low hygroscopic plastic material, for example, ZEON Corporation, trade name ZEONEX, Mitsui Petrochemical Co., Ltd., trade name APO, Japan Synthetic Rubber Co., Ltd., trade name. It is formed by Arton. The adhesive 9 is interposed in the space between the outer peripheral surfaces of the diffraction gratings 5 and 6 and the inner peripheral surface of the holding member 8 as described above, and the diffraction gratings 5 and 6 facing the interior space are described. The resin film 10 is coated on the outside of the effective optical performance range, and on a part of the holding member 8.

【0043】前記樹脂皮膜10は、酸素捕集剤として鉄
微粉と塩化ナトリウムを主成分とする三菱瓦斯化学製
「エージレス」(商品名)を10重量%含有し分散した
ガスバリア性の低吸湿プラスチック材料である非晶質ポ
リオレフィン樹脂、例えば日本ゼオン株式会社・商品名
ZEONEX、三井石油化学株式会社・商品名APO、
日本合成ゴム株式会社・商品名アートン等を、トルエ
ン、キシレン等の特定の有機溶剤により溶解させた固形
分70重量%溶液を、接着剤9で回折格子5、6と保持
部材8とを固着する前に、前記内部空間内の所定位置に
約30μmの厚さに塗布し、常温で溶剤を揮発させて形
成した。
The resin film 10 contains a gas barrier low hygroscopic plastic material containing 10% by weight of "Ageless" (trade name) manufactured by Mitsubishi Gas Chemical Co., Ltd., which contains iron fine powder and sodium chloride as main components as oxygen scavengers. Amorphous polyolefin resin, such as ZEON CORPORATION, trade name ZEONEX, Mitsui Petrochemical Co., Ltd., trade name APO,
Nippon Synthetic Rubber Co., Ltd., trade name ARTON, etc., dissolved in a specific organic solvent such as toluene, xylene, etc. to fix a 70% by weight solid content solution to the diffraction gratings 5, 6 and the holding member 8 with an adhesive 9. Previously, it was applied to a predetermined position in the internal space to a thickness of about 30 μm, and the solvent was volatilized at room temperature to form it.

【0044】(作用)本実施例の光学式ピックアップ装
置によれば、回折格子5自体をガスバリア性で低吸湿性
プラスチック材料で構成した上、内部空間内に面した保
持部材8と回折格子5の表面の一部分を、酸素捕集剤を
混入させたガスバリア性の低吸湿性樹脂で被覆し、樹脂
皮膜10を形成した為、内部空間内の酸素と水分を吸収
・除去でき、また、外部からの内部空間への酸素と水分
の透過をシャットアウトできた。
(Operation) According to the optical pickup device of this embodiment, the diffraction grating 5 itself is made of the gas barrier property and low hygroscopic plastic material, and the holding member 8 and the diffraction grating 5 facing the inside space are formed. Since a part of the surface is covered with a gas barrier low hygroscopic resin mixed with an oxygen scavenger to form the resin film 10, oxygen and water in the internal space can be absorbed and removed, and also from the outside. It was possible to shut out the permeation of oxygen and water into the internal space.

【0045】(効果)内部空間内の受光素子4の酸化劣
化や吸湿による寸法変化や微少電流の発生等を防止で
き、エラーの発生やフォーカシングエラー信号やトラッ
キングエラー信号の検出機能の低下等を防止でき、高信
頼性の光学式ピックアップ装置を提供できる。
(Effect) Oxidative deterioration of the light receiving element 4 in the internal space, dimensional change due to moisture absorption, generation of minute current, etc. can be prevented, and occurrence of error and deterioration of detection function of focusing error signal and tracking error signal are prevented. It is possible to provide a highly reliable optical pickup device.

【0046】[第2実施例]図2に実施例2に係る光学
式ピックアップ装置の要部の縦断面図を示す。本実施例
の光学式ピックアップ装置が実施例1の装置と異なる点
は、実施例1では回折格子5、6が保持部材8の上部内
面に嵌合される状態で接着剤9により固着され、前記内
部空間に面する保持部材8と回折格子5の表面の一部に
酸素捕集剤入りの樹脂皮膜10を形成したのに対して、
回折格子5,6を保持部材18の上端面に接着剤19を
介して載置し、前記保持部材18と前記接着剤19中に
酸素捕集剤を混入させた点である。本実施例での保持部
材18と接着剤19のベース樹脂には、実施例1で採用
した低吸湿性プラスチック材料である非晶質ポリオレフ
ィン樹脂を使用した。
[Second Embodiment] FIG. 2 is a vertical sectional view showing the main part of an optical pickup device according to a second embodiment. The optical pickup device of this embodiment is different from the device of the first embodiment in that the diffraction gratings 5 and 6 are fixed to the inner surface of the upper part of the holding member 8 by the adhesive 9 in the first embodiment. While the resin film 10 containing the oxygen scavenger was formed on a part of the surfaces of the holding member 8 and the diffraction grating 5 facing the internal space,
The diffraction gratings 5 and 6 are placed on the upper end surface of the holding member 18 via an adhesive 19, and an oxygen scavenger is mixed in the holding member 18 and the adhesive 19. As the base resin of the holding member 18 and the adhesive 19 in this embodiment, the amorphous polyolefin resin, which is the low hygroscopic plastic material adopted in Embodiment 1, is used.

【0047】保持部材18は、ベース樹脂100重量部
に対し実施例1と同様の酸素捕集剤を20重量部を混入
した成形材料により成形した。また、接着剤19は、ベ
ース樹脂100重量部に対し実施例1と同様の酸素捕集
剤を10重量部混入したものをトルエンに45重量%溶
解させた溶液を用い、これを接着部に塗布後、保持部材
18と回折格子5とを貼り合わせ、圧締しながらトルエ
ンを揮発させて接着した。その他の構成は、実施例1と
同様であるので、その説明は省略する。
The holding member 18 was formed from a molding material in which 20 parts by weight of the same oxygen scavenger as in Example 1 was mixed with 100 parts by weight of the base resin. As the adhesive 19, a solution prepared by dissolving 10 parts by weight of the same oxygen scavenger as in Example 1 in 100 parts by weight of the base resin and dissolving 45% by weight in toluene was applied to the adhesive part. After that, the holding member 18 and the diffraction grating 5 were attached to each other, and toluene was volatilized and adhered while being pressed. The other configurations are similar to those of the first embodiment, and thus the description thereof is omitted.

【0048】実施例2に係る光学式ピックアップ装置に
よれば、実施例1の場合と同様の作用、効果の他、樹脂
皮膜10の形成工程がない為、より低コスト化が可能と
なるという効果を奏する。
According to the optical pickup device of the second embodiment, in addition to the same actions and effects as those of the first embodiment, there is no step of forming the resin film 10, so that the cost can be further reduced. Play.

【0049】[第3実施例]図3に実施例3に係る光学
式ピックアップ装置の要部の縦断面図を示す。
[Third Embodiment] FIG. 3 is a vertical sectional view of the essential parts of an optical pickup device according to a third embodiment.

【0050】(構成)実施例3に係る光学式ピックアッ
プ装置の構成は実施例1の場合と同様であるが、実施例
1では前記内部空間に面する保持部材8と回折格子5の
表面の一部に酸素捕集剤入りの樹脂皮膜10を形成させ
たのに対し、実施例3では、前記内部空間内に酸素捕集
剤を内包した酸素捕集剤包装体12を2個設置したこと
が特徴である。本実施例で使用した酸素補修剤は、メタ
キシリレンジアミンと遷移金属化合物とリン化合物を使
用した「RPシステム」(商品名・三菱ガス化学製)の
RP剤を使用し、これを紙とポリエチレンとを積層した
包装紙で包み込んだものを酸素捕集剤包装体12として
図示しない両面テープを介して保持部材8に固定・設置
した。その他の構成は、実施例1と同様であるので、そ
の説明は省略する。
(Structure) The structure of the optical pickup device according to the third embodiment is the same as that of the first embodiment, but in the first embodiment, one of the surfaces of the holding member 8 and the diffraction grating 5 facing the internal space. While the resin film 10 containing the oxygen scavenger was formed on the part, in Example 3, two oxygen scavenger packages 12 containing the oxygen scavenger were installed in the internal space. It is a feature. As the oxygen repairing agent used in this example, an RP agent of “RP system” (trade name, manufactured by Mitsubishi Gas Chemical Co., Inc.) using metaxylylenediamine, a transition metal compound and a phosphorus compound was used. What was wrapped with the wrapping paper which laminated | stacked and was fixed and set to the holding member 8 as the oxygen scavenger package 12 through the double-sided tape which is not shown in figure. The other configurations are similar to those of the first embodiment, and thus the description thereof is omitted.

【0051】また、実施例1と同様の作用・効果の他、
本実施例では実施例1のような樹脂皮膜10の形成工程
がなく、実施例2のように酸素捕集剤を混入させた樹脂
を特注製作したりする必要がなく、市販材料を流用でき
る為、より低コスト化が可能となった。
In addition to the actions and effects similar to those of the first embodiment,
In this example, there is no step of forming the resin film 10 as in Example 1, there is no need to custom-make a resin mixed with an oxygen scavenger as in Example 2, and a commercially available material can be used. , Lower cost is possible.

【0052】[0052]

【発明の効果】以上説明した本発明によれば、以下の効
果を奏する。
According to the present invention described above, the following effects can be obtained.

【0053】請求項1記載の発明によれば、外界から回
折格子や保持部材の材料中に侵入してくる酸素と水分
を、被覆した樹脂層でシャットアウトすることができ、
前記内部空間内の受光素子を吸湿及び酸化劣化を防止で
きる光学式ピックアップ装置を提供することができる。
According to the first aspect of the present invention, oxygen and water which enter the material of the diffraction grating or the holding member from the outside can be shut out by the covered resin layer,
It is possible to provide an optical pickup device capable of preventing moisture absorption and oxidative deterioration of the light receiving element in the internal space.

【0054】請求項2記載の発明によれば、回折格子自
体も全体的に疎水性となり、より外界からの水分をシャ
ットアウトし易くすることができる光学式ピックアップ
装置を提供することができる。
According to the second aspect of the invention, it is possible to provide an optical pickup device in which the diffraction grating itself is entirely hydrophobic, and water from the outside can be more easily shut out.

【0055】請求項3記載の発明によれば、ガスバリア
性樹脂に酸素補集剤を含有させたので、樹脂中を透過し
ようとする酸素と水分、更には前記内部空間中の酸素と
水分までも吸収して除去する為、確実に前記受光素子を
吸湿と酸化劣化から保護することができる光学式ピック
アップ装置を提供することができる。
According to the third aspect of the present invention, since the gas barrier resin contains the oxygen scavenger, oxygen and moisture which are to permeate through the resin, and further oxygen and moisture in the internal space are also included. Since it is absorbed and removed, it is possible to provide an optical pickup device capable of reliably protecting the light receiving element from moisture absorption and oxidative deterioration.

【0056】請求項4記載の発明によれば、酸素補修剤
の作用で前記内部空間内の酸素と水分とを、効率良く吸
収・除去し、前記内部空間内に収納されている受光素子
の吸湿や酸化劣化を防止できる光学式ピックアップ装置
を提供することができる。
According to the invention described in claim 4, oxygen and water in the internal space are efficiently absorbed and removed by the action of the oxygen repairing agent, and the moisture absorption of the light receiving element housed in the internal space is performed. It is possible to provide an optical pickup device capable of preventing deterioration due to oxidation.

【0057】請求項5記載の発明によれば、請求項4に
おける接着剤や保持部材に低吸湿材料を含有させたの
で、構成材料自体の疎水性を上げて水分透過を防止し、
より吸湿や酸化劣化を防止できる光学式ピックアップ装
置を提供することができる。
According to the invention described in claim 5, since the low hygroscopic material is contained in the adhesive or the holding member in claim 4, the constituent material itself is increased in hydrophobicity to prevent water permeation,
It is possible to provide an optical pickup device that can further prevent moisture absorption and oxidative deterioration.

【0058】請求項6記載の発明によれば、前記内部空
間内に酸素捕集剤を入れておくだけで、十分に前記内部
空間中の酸素と水分とを除去し、前記内部空間内に収納
されている前記受光素子の吸湿や酸化劣化を防止できる
光学式ピックアップ装置を提供することができる。
According to the sixth aspect of the present invention, oxygen and water in the internal space can be sufficiently removed and stored in the internal space only by inserting the oxygen scavenger into the internal space. It is possible to provide an optical pickup device capable of preventing moisture absorption and oxidative deterioration of the existing light receiving element.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の実施例1の光学式ピックアップ装置の
主要部を示す縦断面図である。
FIG. 1 is a longitudinal sectional view showing a main part of an optical pickup device according to a first embodiment of the present invention.

【図2】本発明の実施例1の光学式ピックアップ装置の
主要部を示す縦断面図である。
FIG. 2 is a vertical sectional view showing a main part of the optical pickup device according to the first embodiment of the present invention.

【図3】本発明の実施例1の光学式ピックアップ装置の
主要部を示す縦断面図である。
FIG. 3 is a vertical sectional view showing a main part of the optical pickup device according to the first embodiment of the present invention.

【図4】従来装置の概略斜視図である。FIG. 4 is a schematic perspective view of a conventional device.

【符号の説明】[Explanation of symbols]

1 光源 2 ディスク 3 対物レンズ 4 受光素子 5 回折格子 6 回折格子 8 保持部材 9 接着剤 10 樹脂被膜 11 基板 12 酸素補修剤包装体 DESCRIPTION OF SYMBOLS 1 light source 2 disk 3 objective lens 4 light receiving element 5 diffraction grating 6 diffraction grating 8 holding member 9 adhesive 10 resin film 11 substrate 12 oxygen repair agent package

───────────────────────────────────────────────────── フロントページの続き (72)発明者 徳田 一成 東京都渋谷区幡ヶ谷2丁目43番2号 オリ ンパス光学工業株式会社内 (72)発明者 山崎 健 東京都渋谷区幡ヶ谷2丁目43番2号 オリ ンパス光学工業株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Issei Tokuda 2-43-2 Hatagaya, Shibuya-ku, Tokyo Olympus Optical Co., Ltd. (72) Inventor Ken Yamazaki 2-43-2 Hatagaya, Shibuya-ku, Tokyo Olympus Optical Industry Co., Ltd.

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 光源からの光束をディスク上に集束させ
る対物レンズと、前記ディスクからの反射光を検出する
受光素子と、前記光源から前記ディスクに至る光束中に
設けられた回折格子と、前記対物レンズを保持する保持
体と、前記光源及び受光素子を支持する基板と、この基
板及び回折格子を保持する保持部材とを具備する光学式
ピックアップ装置において、 前記光源と受光素子と前記光源及び受光素子を支持する
基板とを、前記回折格子と前記保持部材と前記回折格子
を前記保持部材に接合する接着剤とで形成される内部空
間に収納し、前記内部空間内に面する前記回折格子の一
部及び/又は前記保持部材の一部を、ガスバリア性を有
する樹脂で被覆したことを特徴とする光学式ピックアッ
プ装置。
1. An objective lens for focusing a light beam from a light source on a disc, a light receiving element for detecting reflected light from the disc, a diffraction grating provided in the light beam from the light source to the disc, An optical pickup device comprising: a holder that holds an objective lens; a substrate that supports the light source and the light receiving element; and a holding member that holds the substrate and the diffraction grating, the light source and the light receiving element, the light source and the light receiving element. A substrate supporting the element is housed in an internal space formed by the diffraction grating, the holding member, and an adhesive that bonds the diffraction grating to the holding member, and the diffraction grating facing the inside of the internal space is formed. An optical pickup device characterized in that a part and / or a part of the holding member is coated with a resin having a gas barrier property.
【請求項2】 前記回折格子及びガスバリア性を有する
樹脂に低吸湿性材料を含有したことを特徴とする特許請
求項1に記載の光学式ピックアップ装置。
2. The optical pickup device according to claim 1, wherein the resin having the diffraction grating and the gas barrier property contains a low hygroscopic material.
【請求項3】 前記ガスバリア性を有する樹脂に酸素捕
集剤を含有したことを特徴とする特許請求項1又は2に
記載の光学式ピックアップ装置。
3. The optical pickup device according to claim 1, wherein the resin having gas barrier properties contains an oxygen scavenger.
【請求項4】 光源からの光束をディスク上に集束させ
る対物レンズと、前記ディスクからの反射光を検出する
受光素子と、前記光源から前記ディスクに至る光束中に
設けられた回折格子と、前記対物レンズを保持する保持
体と、前記光源及び受光素子を支持する基板と、この基
板及び回折格子を保持する保持部材を具備する光学式ピ
ックアップ装置において、 前記光源と受光素子と前記光源及び受光素子を保持する
基板とを、前記回折格子と前記保持部材と前記回折格子
及び前記保持部材を接合する接着剤とで形成される内部
空間に収納し、前記接着剤及び/又は前記保持部材中
に、酸素捕集剤を含有したことを特徴とする光学式ピッ
クアップ装置。
4. An objective lens for focusing a light beam from a light source on a disc, a light receiving element for detecting a reflected light from the disc, a diffraction grating provided in the light beam from the light source to the disc, An optical pickup device comprising: a holder that holds an objective lens; a substrate that supports the light source and the light receiving element; and a holding member that holds the substrate and the diffraction grating, the light source and the light receiving element, the light source and the light receiving element. A substrate for holding, is housed in an internal space formed by the diffraction grating and the holding member and an adhesive for joining the diffraction grating and the holding member, in the adhesive and / or the holding member, An optical pickup device comprising an oxygen scavenger.
【請求項5】 前記回折格子及び、前記接着剤及び/又
は保持部材に低吸湿性材料を含有したことを特徴とする
請求項4に記載の光学式ピックアップ装置。
5. The optical pickup device according to claim 4, wherein the diffraction grating and the adhesive and / or the holding member contain a low hygroscopic material.
【請求項6】 光源からの光束をディスク上に集束させ
る対物レンズと、前記ディスクからの反射光を検出する
受光素子と、前記光源から前記ディスクに至る光束中に
設けられた回折格子と、前記対物レンズを保持する保持
体と、前記光源及び受光素子を支持する基板と、この基
板及び回折格子を保持する保持部材を具備する光学式ピ
ックアップ装置において、 前記光源と受光素子と前記光源及び受光素子を支持する
基板とを、前記回折格子と前記保持部材と前記回折格子
を前記保持部材に接合する接着剤とで形成される内部空
間に収納し、前記内部空間内に、酸素捕集剤を内包する
酸素捕集剤包装体を設置したことを特徴とする光学式ピ
ックアップ装置。
6. An objective lens for focusing a light beam from a light source on a disc, a light receiving element for detecting reflected light from the disc, a diffraction grating provided in the light beam from the light source to the disc, An optical pickup device comprising: a holder that holds an objective lens; a substrate that supports the light source and the light receiving element; and a holding member that holds the substrate and the diffraction grating, the light source and the light receiving element, the light source and the light receiving element. A substrate supporting the same is housed in an internal space formed by the diffraction grating, the holding member, and an adhesive that bonds the diffraction grating to the holding member, and an oxygen scavenger is included in the internal space. An optical pickup device characterized in that an oxygen scavenger package is installed.
JP00999495A 1995-01-25 1995-01-25 Optical pickup device Expired - Fee Related JP3497589B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP00999495A JP3497589B2 (en) 1995-01-25 1995-01-25 Optical pickup device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP00999495A JP3497589B2 (en) 1995-01-25 1995-01-25 Optical pickup device

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004231731A (en) * 2003-01-29 2004-08-19 Mitsubishi Gas Chem Co Inc Gas barrier coating material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004231731A (en) * 2003-01-29 2004-08-19 Mitsubishi Gas Chem Co Inc Gas barrier coating material

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