JPH0818952B2 - Hair treatment composition - Google Patents
Hair treatment compositionInfo
- Publication number
- JPH0818952B2 JPH0818952B2 JP20437291A JP20437291A JPH0818952B2 JP H0818952 B2 JPH0818952 B2 JP H0818952B2 JP 20437291 A JP20437291 A JP 20437291A JP 20437291 A JP20437291 A JP 20437291A JP H0818952 B2 JPH0818952 B2 JP H0818952B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- acid
- agent
- treatment composition
- salts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Cosmetics (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は毛髪にはり／こしを付与
する毛髪処理剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair treatment composition for imparting hair / strain to hair.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】毛髪に
関する悩みの中には、髪にはり／こしがない、ボリュー
ムがないといった毛髪の低弾性に関するものが少なくな
い。これらの悩みを持った人々の欲求を満たすため、従
来より、はり／こし付与剤やコンディショニング剤を配
合した毛髪処理剤が数多く使用されている。しかし、こ
れらの大部分は毛髪表面への剤の吸着などにより効果が
発現されるものであって、洗髪時に落とされてしまうた
め、常時処理を行わねばならず、その手間ははなはだわ
ずらわしい。また、毛髪内部に浸透させて効果を発現さ
せようとする試がなされており、例えばナフタレンスル
ホン酸の水溶液で毛髪を処理することが報告されている
（Ｊ．Ｓｏｃ．Ｃｏｓｍｅｔ．Ｃｈｅｍ．，３６，８７
〜９９，１９８５）。しかし、これも毛髪への浸透性が
悪く、処理に長時間を要すると共に、効果も充分でなか
った。2. Description of the Related Art Among the problems concerning the hair, there are not a few problems concerning the low elasticity of the hair, such as lack of elasticity / strain and lack of volume. In order to satisfy the desires of those who have these concerns, a number of hair treatment agents containing a balm / strain-imparting agent and a conditioning agent have been conventionally used. However, most of these are effective due to the adsorption of the agent on the hair surface, etc., and are dropped during hair washing, so that the treatment must be carried out at all times, which is troublesome. In addition, trials have been made to penetrate the inside of the hair to exert an effect, and for example, treating the hair with an aqueous solution of naphthalenesulfonic acid has been reported (J. Soc. Cosmet. Chem., 36 , 36) . 87
~ 99, 1985). However, this also has poor permeability to hair, requires a long time for treatment, and is not sufficiently effective.
【０００３】[0003]
【課題を解決するための手段】このような実情におい
て、本発明者は鋭意研究を行った結果、還元剤と下記一
般式（１）で表されるナフタレンスルホン酸類による処
理を組合せて行えば、短時間の処理で毛髪の弾性を改善
し、毛髪にはり／こしを与えることができ、しかもこの
弾性は長期間保持されることを見出し、本発明を完成し
た。Under such circumstances, the present inventor has conducted diligent research, and as a result, if a treatment with a reducing agent and naphthalenesulfonic acid represented by the following general formula (1) is combined, The present invention has been completed by the finding that the elasticity of hair can be improved by a short-time treatment, and that the hair can be given a firmness / strain, and that this elasticity is maintained for a long time.
【０００４】従って本発明は、還元剤及び次の一般式
（１）Therefore, the present invention provides a reducing agent and the following general formula (1):
【０００５】[0005]
【化２】 Embedded image
【０００６】〔式中、Ａ１、Ａ２、Ａ３、Ａ６及びＡ７
の１個又は２個はスルホン基又はその塩を示し、他は水
素原子、水酸基、アミノ基又はアルキル基を示す〕で表
されるナフタレンスルホン酸類を含有する毛髪処理剤組
成物を提供するものである。[Wherein A 1 , A 2 , A 3 , A 6 and A 7
One or two of the above represent a sulfone group or a salt thereof, and the other represent a hydrogen atom, a hydroxyl group, an amino group or an alkyl group], and a hair treatment composition containing the naphthalenesulfonic acid is there.
【０００７】本発明の毛髪処理剤組成物において、還元
剤は、毛髪中のシスチンを切断し、毛髪を膨潤させて、
ナフタレンスルホン酸類が迅速に毛髪中に浸透する作用
をするものである。このような還元剤としては、チオグ
リコール酸及びその塩類（塩類として好ましいものはア
ンモニウム塩、ナトリウム塩、カリウム塩等のアルカリ
金属塩及びカルシウム塩等のアルカリ土類金属塩）、シ
ステイン及びその塩類（塩類として好ましいものは塩酸
塩）、Ｎ−アセチル−Ｌ−システイン及びその塩類（塩
類として好ましいものは塩酸塩）、亜硫酸塩及び亜硫酸
水素塩（塩類として好ましいものはアンモニウム塩、ナ
トリウム塩、カリウム塩等のアルカリ金属塩及びカルシ
ウム塩等のアルカリ土類金属塩）等が挙げられる。この
うち、特に、チオグリコール酸、チオグリコール酸アン
モニウム、Ｎ−アセチル−Ｌ−システイン、亜硫酸水素
ナトリウムが好ましい。In the hair treatment composition of the present invention, the reducing agent cleaves cystine in the hair to swell the hair,
It has the function of allowing naphthalene sulfonic acids to quickly penetrate into the hair. Such reducing agents include thioglycolic acid and salts thereof (preferably salts are alkali metal salts such as ammonium salts, sodium salts and potassium salts and alkaline earth metal salts such as calcium salts), cysteine and salts thereof ( Preferred salts are hydrochlorides, N-acetyl-L-cysteine and salts thereof (preferred salts are hydrochlorides), sulfites and bisulfites (preferred salts are ammonium salts, sodium salts, potassium salts, etc.). Alkali metal salts and alkaline earth metal salts such as calcium salts). Of these, thioglycolic acid, ammonium thioglycolate, N-acetyl-L-cysteine, and sodium bisulfite are particularly preferable.
【０００８】この還元剤は、ナフタレンスルホン酸類と
一緒に配合して一つの毛髪処理剤組成物とすることも、
また還元剤を含む第１剤とナフタレンスルホン酸類を含
む第２剤とに分けて調製することもできる。This reducing agent may be blended with naphthalene sulfonic acids to form a hair treatment composition.
It is also possible to separately prepare a first agent containing a reducing agent and a second agent containing naphthalenesulfonic acids.
【０００９】還元剤は、上記毛髪処理剤組成物又は第１
剤中に０．１〜１０重量％（以下単に％で示す）程度配
合するのが好ましく、１〜７％配合するのが特に好まし
い。０．１％未満では充分な効果を奏さず、１０％を超
えて配合しても、これ以上の効果の向上は認められず、
毛髪の損傷を増大させるだけである。また、これらに
は、アンモニア水、エタノールアミン、炭酸アンモニウ
ム、炭酸水素アンモニウムなどのアルカリ剤を加えて還
元作用を促進することもできる。The reducing agent is the above hair treating composition or the first
It is preferable to mix the agent in an amount of about 0.1 to 10% by weight (hereinafter referred to simply as%), and particularly preferably 1 to 7%. If it is less than 0.1%, the sufficient effect is not exhibited, and even if it exceeds 10%, no further improvement in the effect is observed.
It only increases hair damage. In addition, an alkaline agent such as aqueous ammonia, ethanolamine, ammonium carbonate or ammonium hydrogen carbonate may be added to these to promote the reducing action.
【００１０】本発明において用いるナフタレンスルホン
酸類（１）の具体例としては、例えば１−または２−ナ
フタレンスルホン酸、２，７−ナフタレンジスルホン
酸、２，６−ナフタレンジスルホン酸、１−ナフトール
−２−スルホン酸、２−ナフトール−６−スルホン酸、
２−ナフトール−７−スルホン酸、１−ナフトール−
３，６−ジスルホン酸、２−ナフトール−３，６−ジス
ルホン酸、２，３−ジヒドロキシナフタレン−６−スル
ホン酸、１，７−ジヒドロキシナフタレン−３−スルホ
ン酸、クロモトロープ酸（４，５−ジヒドロキシナフタ
レン−２，７−ジスルホン酸）、３，６−ジヒドロキシ
ナフタレン−２，７−ジスルホン酸、ガンマ酸（２−ア
ミノ−８−ナフトール−６−スルホン酸）、Ｊ酸（２−
アミノ−５−ナフトール−７−スルホン酸）、Ｈ酸（１
−アミノ−８−ナフトール−３，６−ジスルホン酸）、
７−アミノ−１，３−ナフタレンジスルホン酸、ブロエ
ナーズ酸（２−ナフチルアミン−６−スルホン酸）、ク
レーブズ酸（１−ナフチルアミン−７−スルホン酸）、
２−ナフチルアミン−１−スルホン酸、１−ナフチルア
ミン−６−スルホン酸、２，７−ジアミノ−１−ナフト
ール−３−スルホン酸、７，８−ジアミノ−１−ナフト
ール−３−スルホン酸、ナフタレンスルホン酸ホルマリ
ン重縮合物（重量平均縮合度２〜１００）、６−メチル
−２−ナフタレンスルホン酸、４−エチル−１−ナフタ
レンスルホン酸、５−イソプロピル−１−ナフタレンス
ルホン酸、５−ブチル−２−ナフタレンスルホン酸また
はそれらの塩が挙げられ、これらの中でも２−ナフタレ
ンスルホン酸、２，６−ナフタレンジスルホン酸、２，
７−ナフタレンジスルホン酸、Ｈ酸（１−アミノ−８−
ナフトール３，６−ジスルホン酸）、１−ナフタレンス
ルホン酸、クロモトロープ酸、２−ナフタレンスルホン
酸ホルマリン重縮合物（重量平均縮合度２〜５０）及び
それらの塩が特に好ましい。また、これらの塩として
は、ナトリウム塩、カリウム塩、カルシウム塩、アンモ
ニウム塩、有機４級アンモニウム塩が挙げられる。Specific examples of the naphthalene sulfonic acids (1) used in the present invention include 1- or 2-naphthalene sulfonic acid, 2,7-naphthalenedisulfonic acid, 2,6-naphthalenedisulfonic acid, 1-naphthol-2. -Sulfonic acid, 2-naphthol-6-sulfonic acid,
2-naphthol-7-sulfonic acid, 1-naphthol-
3,6-disulfonic acid, 2-naphthol-3,6-disulfonic acid, 2,3-dihydroxynaphthalene-6-sulfonic acid, 1,7-dihydroxynaphthalene-3-sulfonic acid, chromotropic acid (4,5- Dihydroxynaphthalene-2,7-disulfonic acid), 3,6-dihydroxynaphthalene-2,7-disulfonic acid, gamma acid (2-amino-8-naphthol-6-sulfonic acid), J acid (2-
Amino-5-naphthol-7-sulfonic acid), H acid (1
-Amino-8-naphthol-3,6-disulfonic acid),
7-amino-1,3-naphthalenedisulfonic acid, broenoic acid (2-naphthylamine-6-sulfonic acid), Cleve's acid (1-naphthylamine-7-sulfonic acid),
2-naphthylamine-1-sulfonic acid, 1-naphthylamine-6-sulfonic acid, 2,7-diamino-1-naphthol-3-sulfonic acid, 7,8-diamino-1-naphthol-3-sulfonic acid, naphthalene sulfone Acid formalin polycondensate (weight average condensation degree 2 to 100), 6-methyl-2-naphthalenesulfonic acid, 4-ethyl-1-naphthalenesulfonic acid, 5-isopropyl-1-naphthalenesulfonic acid, 5-butyl-2 -Naphthalene sulfonic acid or salts thereof are mentioned, and among these, 2-naphthalene sulfonic acid, 2,6-naphthalene disulfonic acid, 2,
7-naphthalenedisulfonic acid, H acid (1-amino-8-
Naphthol 3,6-disulfonic acid), 1-naphthalenesulfonic acid, chromotropic acid, 2-naphthalenesulfonic acid formalin polycondensate (weight average condensation degree 2 to 50) and salts thereof are particularly preferable. Examples of these salts include sodium salt, potassium salt, calcium salt, ammonium salt, and organic quaternary ammonium salt.
【００１１】ナフタレンスルホン酸類の上記毛髪処理剤
組成物及び第２剤への配合量は、０．１〜１０％、特に
１〜５％が好ましい。０．１％未満では毛髪処理の効果
が充分でなく、１０％を超えてもその増加分に見合うだ
けの効果の向上が得られない。The amount of naphthalene sulfonic acid compounded in the hair treatment composition and the second agent is preferably 0.1 to 10%, more preferably 1 to 5%. If it is less than 0.1%, the effect of hair treatment is not sufficient, and if it exceeds 10%, the effect corresponding to the increase cannot be improved.
【００１２】本発明の毛髪処理剤組成物及び第２剤に
は、ナフタレンスルホン酸類の溶解性を向上させ、毛髪
への浸透性を促進させるために有機溶剤を含有させるこ
とができる。The hair treatment composition and the second agent of the present invention may contain an organic solvent in order to improve the solubility of naphthalene sulfonic acids and to promote the penetration into hair.
【００１３】有機溶剤としては、次式（２）で表わされ
る化合物、次式（３）で表わされるＮ−アルキルピロリ
ドン又は炭素数１〜４のアルキレンカーボネートが挙げ
られる。Examples of the organic solvent include a compound represented by the following formula (2), an N-alkylpyrrolidone represented by the following formula (3) or an alkylene carbonate having 1 to 4 carbon atoms.
【００１４】[0014]
【化３】 〔式中、Ｒ１は水素原子、低級アルキル基又は基 素数１〜３の飽和もしくは不飽和の二価の炭化水素基）
を示し、Ｙ及びＺは水素原子又は水酸基を示し、ｐ、ｑ
及びｒは０〜５の整数を示す。但し、ｐ＝ｑ＝ｒ＝０で
Ｚ＝Ｈの場合、及びｐ＝ｑ＝ｒ＝０でＲ１＝Ｈ、Ｚ＝Ｏ
Ｈの場合を除く〕Embedded image [In the formula, R 1 represents a hydrogen atom, a lower alkyl group or a group. (Saturated or unsaturated divalent hydrocarbon group having a prime number of 1 to 3)
, Y and Z represent a hydrogen atom or a hydroxyl group, p, q
And r represent the integer of 0-5. However, when p = q = r = 0 and Z = H, and when p = q = r = 0, R 1 = H, Z = O
Except for H]
【００１５】[0015]
【化４】 〔式中、Ｒ４は炭素数１〜１８の直鎖又は分岐鎖のアル
キル基を示す〕[Chemical 4] [In the formula, R 4 represents a linear or branched alkyl group having 1 to 18 carbon atoms]
【００１６】これらの有機溶剤の具体例としては、例え
ばエタノール、イソプロパノール、ｎ−プロパノール、
ｎ−ブタノール、イソブタノール、エチレングリコー
ル、プロピレングリコール、１，３−ブタンジオール、
ベンジルアルコール、シンナミルアルコール、フェネチ
ルアルコール、ｐ−アニシルアルコール、ｐ−メチルベ
ンジルアルコール、フェノキシエタノール、２−ベンジ
ロキシエタノール、メチルカルビトール、エチルカルビ
トール、プロピルカルビトール、ブチルカルビトール、
トリエチレングリコールモノエチルエーテル、トリエチ
レングリコールモノブチルエーテル、グリセリン、Ｎ−
メチルピロリドン、Ｎ−オクチルピロリドン、Ｎ−ラウ
リルピロリドン等が挙げられる。Specific examples of these organic solvents include ethanol, isopropanol, n-propanol,
n-butanol, isobutanol, ethylene glycol, propylene glycol, 1,3-butanediol,
Benzyl alcohol, cinnamyl alcohol, phenethyl alcohol, p-anisyl alcohol, p-methylbenzyl alcohol, phenoxyethanol, 2-benzyloxyethanol, methylcarbitol, ethylcarbitol, propylcarbitol, butylcarbitol,
Triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, glycerin, N-
Methylpyrrolidone, N-octylpyrrolidone, N-laurylpyrrolidone and the like can be mentioned.
【００１７】斯かる有機溶剤の配合量は０．５〜５０
％、特に２〜３０％が好ましい。０．５未満では充分な
効果を奏さず、５０％を超えて配合しても、効果の向上
は認められない。また、水と有機溶媒との混合割合は、
溶剤の水溶性にもよるが、溶剤：水＝２０：８０〜５
０：５０が好ましい。The amount of such organic solvent compounded is 0.5 to 50.
%, Particularly 2 to 30% is preferable. If it is less than 0.5, the sufficient effect is not exhibited, and even if it exceeds 50%, the effect is not improved. Further, the mixing ratio of water and the organic solvent,
Depending on the water solubility of the solvent, solvent: water = 20: 80-5
0:50 is preferable.
【００１８】さらに本発明の毛髪処理剤組成物、第１剤
及び第２剤には、本発明の効果を損なわない範囲で、必
要に応じて、ヒドロキシエチルセルロース等の増粘剤、
界面活性剤、香料、パール化剤、色素、紫外線吸収剤、
酸化防止剤、防腐剤等を配合してもよい。また、毛髪や
皮膚の感触を向上させるために、カチオン化セルロース
などのカチオン性ポリマーや、ジメチルポリシロキサン
やアミノ変性シリコーンなどのシリコーン誘導体などを
配合することもできる。Further, in the hair treatment composition, the first agent and the second agent of the present invention, if necessary, a thickening agent such as hydroxyethyl cellulose, etc., within a range that does not impair the effects of the present invention,
Surfactants, fragrances, pearlizing agents, dyes, UV absorbers,
Antioxidants, preservatives and the like may be added. Further, in order to improve the feel of hair or skin, a cationic polymer such as cationized cellulose and a silicone derivative such as dimethylpolysiloxane or amino-modified silicone can be blended.
【００１９】本発明の毛髪処理剤組成物または第１剤及
び第２剤を用いる毛髪処理は次のようにして行われる。
すなわち、還元剤及びナフタレンスルホン酸類を含有す
る毛髪処理剤組成物を毛髪に塗布し、一定時間好ましく
は５〜３０分間放置後、洗い流す方法によって行われ
る。塗布する毛髪はドライの状態でも、洗髪後の湿った
状態でもよい。放置している間は、適当な温度まで好ま
しくは３０〜５０℃まで加温してもよい。また、他の方
法は、毛髪を、還元剤を含む第１剤で処理し、次いでナ
フタレンスルホン酸類を含む第２剤で処理することによ
って行われる。この方法において、第１剤による毛髪の
還元処理後すぐに第２剤を塗布しても良いし、またすす
いで還元剤を洗い流した後、第２剤を塗布しても良い。
第１剤及び第２剤による処理も、それぞれの処理後一定
時間（好ましくは５〜３０分間）、適当な温度まで（好
ましくは３０〜５０℃まで）加温しても良い。Hair treatment using the hair treatment composition of the present invention or the first and second agents is carried out as follows.
That is, a hair treatment composition containing a reducing agent and naphthalene sulfonic acids is applied to hair, left for a certain period of time, preferably 5 to 30 minutes, and then rinsed off. The hair to be applied may be dry or wet after washing. While standing, it may be heated to an appropriate temperature, preferably 30 to 50 ° C. Another method is performed by treating hair with a first agent containing a reducing agent and then with a second agent containing naphthalenesulfonic acids. In this method, the second agent may be applied immediately after the reduction treatment of the hair with the first agent, or the second agent may be applied after rinsing away the reducing agent.
The treatments with the first agent and the second agent may also be heated to a suitable temperature (preferably 30 to 50 ° C.) for a certain period of time (preferably 5 to 30 minutes) after each treatment.
【００２０】以上の如くして処理した毛髪は、過酸化水
素、過炭酸ナトリウム、過ホウ酸ナトリウム等の過酸化
物、臭素酸、臭素酸カリウム、臭素酸ナトリウム等臭素
酸塩等の酸化剤（好ましくは過酸化水素、臭素酸及び臭
素酸ナトリウム）を含む組成物で処理し、還元剤によっ
て切断したシスチン結合を再結合させるのが好ましい。The hair treated as described above is treated with peroxides such as hydrogen peroxide, sodium percarbonate and sodium perborate, and oxidizing agents such as bromates such as bromic acid, potassium bromate and sodium bromate ( It is preferable to treat with a composition containing hydrogen peroxide, bromic acid and sodium bromate) to recombine the cystine bond cleaved by the reducing agent.
【００２１】[0021]
【発明の効果】本発明の毛髪処理剤組成物によれば、短
時間の処理で毛髪に充分なはり／こしを付与することが
でき、且つその効果が長時間持続する。EFFECTS OF THE INVENTION According to the hair treatment composition of the present invention, it is possible to give sufficient hair / strain to the hair in a short time, and the effect lasts for a long time.
【００２２】[0022]
【実施例】次に実施例を挙げて説明するが、本発明はこ
れらの実施例に限定されるものではない。 実施例１〜４及び比較例１〜２ 表１の組成の毛髪処理剤組成物で、毛髪を４０℃にて３
０分間処理した。続いて８％の臭素酸ナトリウム水溶液
で毛髪を酸化処理し、水で洗い流し、ヘアドライヤーで
乾燥させ、比較試験を行った。 （１）使用した毛髪 今までにコールドパーマやブリーチ等の美容処理を行っ
ていない日本人女性の毛髪 （２）評価方法 １０ｇの毛髪の束を作り、その半分に毛髪処理を施し
た。専門パネラー５名で、毛髪のはり／こしについての
一対比較試験を行った。評価基準は次のとおりとした。 ◎：処理毛の方が非常にはり／こしを感じる ○：処理毛の方がはり／こしを感じる △：未処理毛と同程度である ×：未処理毛よりはり／こしがない さらにこの毛束を市販のシャンプーで４回洗浄、乾燥を
繰り返した後、上記と同様にはり／こしについて評価し
た。 （３）結果 表１のとおりである。The present invention will be described below with reference to examples, but the present invention is not limited to these examples. Examples 1 to 4 and Comparative Examples 1 to 2 With the hair treatment composition having the composition shown in Table 1, the hair was treated at 40 ° C. for 3 days.
It was processed for 0 minutes. Subsequently, the hair was oxidized with an 8% sodium bromate aqueous solution, rinsed with water, dried with a hair dryer, and a comparative test was conducted. (1) Hair used Hair of a Japanese woman who has not been subjected to cosmetic treatment such as cold perm or bleach up until now (2) Evaluation method A 10 g hair bundle was prepared, and half of the hair was treated. A pair of comparative tests were carried out on the hair beam / strain by five specialized panelists. The evaluation criteria are as follows. ⊚: Treated hair feels more stiff / strainer ○: Treated hair feels stiffer / strainer △: Same as untreated hair X: No stiffer / strainer than untreated hair Was repeatedly washed with a commercial shampoo four times and dried, and then evaluated for burrs / strains in the same manner as above. (3) Results Table 1 shows.
【００２３】[0023]
【表１】 [Table 1]
【００２４】実施例５〜８及び比較例３ 先ず、第１剤（チオグリコール酸アンモニウム６．０
％、炭酸水素アンモニウム３．０％、pH調整用アンモニ
ア水 pH＝８．５）で処理し（３０℃、１０分間）、水
洗した後、表２に示す組成の第２剤で処理した（４０
℃、３０分間）。続いて８％の臭素酸水溶液で毛髪酸化
処理を行い、水で洗い流し、ヘアドライヤーで乾燥さ
せ、比較試験を行った。その結果は表２のとおりであ
る。Examples 5 to 8 and Comparative Example 3 First, the first agent (ammonium thioglycolate 6.0) was used.
%, Ammonium hydrogencarbonate 3.0%, pH adjusting ammonia water pH = 8.5) (30 ° C., 10 minutes), washed with water, and then treated with a second agent having the composition shown in Table 2 (40
C, 30 minutes). Subsequently, hair was oxidized with an 8% aqueous bromic acid solution, rinsed with water, dried with a hair dryer, and a comparative test was conducted. The results are shown in Table 2.
【００２５】[0025]
【表２】 [Table 2]
【００２６】実施例９ 下記の組成の毛髪処理剤組成物を調製し、実施例１〜４
と同様に試験した。 （組成） ％ （１）Ｎ−アセチル−Ｌ−システイン 1.5 （２）２−ナフタレンスルホン酸ナトリウム 5.0 （３）水 バランス 未処理毛に比べ、充分なはり／こしが得られた。この
効果は、シャンプー４回を繰り返した後も認められた。Example 9 A hair treatment composition having the following composition was prepared, and Examples 1 to 4 were prepared.
The same test was performed. (Composition)% (1) N-acetyl-L-cysteine 1.5 (2) Sodium 2-naphthalene sulfonate 5.0 (3) Water balance Sufficient firmness / strain was obtained compared with untreated hair. This effect was observed even after repeating the shampoo 4 times.
【００２７】実施例１０ 下記の組成の毛髪処理剤組成物で毛髪を処理した（４０
℃、３０分間）。続いて流水中で５分間洗い流し、ヘア
ドライヤーで乾燥させ、比較試験を行った。 （組成） ％ （１）亜硫酸水素ナトリウム 4.0 （２）２−ナフタレンスルホン酸ナトリウム 5.0 （３）水 バランス 未処理毛に比べ、充分なはり／こしが得られた。この効
果は、シャンプー４回を繰り返した後も認められた。Example 10 Hair was treated with a hair treatment composition having the following composition (40
C, 30 minutes). Subsequently, it was rinsed in running water for 5 minutes, dried with a hair dryer, and a comparative test was conducted. (Composition)% (1) Sodium bisulfite 4.0 (2) Sodium 2-naphthalenesulfonate 5.0 (3) Water balance Sufficient firmness / strain was obtained compared to untreated hair. This effect was observed even after repeating the shampoo 4 times.
Claims (2)
個はスルホン基又はその塩を示し、他は水素原子、水酸
基、アミノ基又はアルキル基を示す〕で表されるナフタ
レンスルホン酸類を含有する毛髪処理剤組成物。1. A reducing agent and the following general formula (1): [In the formula, one or two of A 1 , A 2 , A 3 , A 6 and A 7
Wherein each represents a sulfonic group or a salt thereof, and the other represents a hydrogen atom, a hydroxyl group, an amino group or an alkyl group].
のナフタレンスルホン酸類を含有する第２剤からなる毛
髪処理剤組成物。2. A hair treatment composition comprising a first agent containing a reducing agent and a second agent containing the naphthalene sulfonic acids according to claim 1.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20437291A JPH0818952B2 (en) | 1991-08-14 | 1991-08-14 | Hair treatment composition |
| EP92113888A EP0529437B1 (en) | 1991-08-14 | 1992-08-14 | Hair treatment composition |
| DE69212254T DE69212254T2 (en) | 1991-08-14 | 1992-08-14 | Hair care products |
| AT92113888T ATE140382T1 (en) | 1991-08-14 | 1992-08-14 | HAIR CARE PRODUCTS |
| EP95103655A EP0672405B1 (en) | 1991-08-14 | 1992-08-14 | Hair treatment composition |
| DE69232205T DE69232205T2 (en) | 1991-08-14 | 1992-08-14 | Hair treatment composition |
| US08/864,973 US6217855B1 (en) | 1991-08-14 | 1997-05-29 | Hair treatment composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20437291A JPH0818952B2 (en) | 1991-08-14 | 1991-08-14 | Hair treatment composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0543422A JPH0543422A (en) | 1993-02-23 |
| JPH0818952B2 true JPH0818952B2 (en) | 1996-02-28 |
Family
ID=16489429
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20437291A Expired - Lifetime JPH0818952B2 (en) | 1991-08-14 | 1991-08-14 | Hair treatment composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0818952B2 (en) |
-
1991
- 1991-08-14 JP JP20437291A patent/JPH0818952B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0543422A (en) | 1993-02-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2592852B2 (en) | How to make hair permanent | |
| US5332570A (en) | Reducing solution for permanent wave | |
| US3654936A (en) | Process for straightening human hair | |
| US4963349A (en) | Permanent wave solution | |
| US6217855B1 (en) | Hair treatment composition | |
| US20120230935A1 (en) | Solvent composition for one-step permanent wave and hair straightener | |
| US20120174940A1 (en) | Hair treatment composition | |
| CA2105813C (en) | Method of increasing hair shine and repairing alkaline-damaged hair | |
| JPH08198732A (en) | Hair treating agent composition | |
| WO2002098381A1 (en) | Method of treating hair | |
| JP6940076B2 (en) | Hair treatment method | |
| EP0449133B1 (en) | Hair cosmetic composition | |
| CA1297794C (en) | Compositions used in permanent structure altering of hair | |
| US20060222613A1 (en) | Hair treating agent | |
| JP3453559B2 (en) | Single bath permanent wave former for damaged hair | |
| JPH01502982A (en) | Chemicals for permanent hair processing or hair removal | |
| JP5875303B2 (en) | Hair cosmetics | |
| JP3057147B2 (en) | Permanent wave intermediate treatment composition and permanent wave treatment method | |
| JPH0818953B2 (en) | Hair treatment composition | |
| JPH06502872A (en) | Fixatives and methods for permanent hair processing | |
| JPH0678216B2 (en) | Acid Permanent Wave Agent | |
| JP2013147476A (en) | Hair cosmetic | |
| JP7531795B2 (en) | Hair treatment products | |
| JPH0818952B2 (en) | Hair treatment composition | |
| JPH08143433A (en) | Permanent treating agent for hair |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080228 Year of fee payment: 12 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 13 Free format text: PAYMENT UNTIL: 20090228 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100228 Year of fee payment: 14 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100228 Year of fee payment: 14 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110228 Year of fee payment: 15 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120228 Year of fee payment: 16 |
|
| EXPY | Cancellation because of completion of term | ||
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120228 Year of fee payment: 16 |