JPH08165140A - Glaze and glazed product - Google Patents
Glaze and glazed productInfo
- Publication number
- JPH08165140A JPH08165140A JP30516594A JP30516594A JPH08165140A JP H08165140 A JPH08165140 A JP H08165140A JP 30516594 A JP30516594 A JP 30516594A JP 30516594 A JP30516594 A JP 30516594A JP H08165140 A JPH08165140 A JP H08165140A
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- glaze
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Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、人体に無害で、かつ、
夜間において長時間発光可能な釉薬製品に関する。BACKGROUND OF THE INVENTION The present invention is harmless to the human body and
The present invention relates to a glaze product that can emit light for a long time at night.
【０００２】[0002]
【従来の技術】従来、陶磁器製品、ガラス製品、金属製
品、ファインセラミックス製品は、その表面に光沢を持
たせるため、釉薬を焼き付けたものがある。2. Description of the Related Art Heretofore, some ceramic products, glass products, metal products, and fine ceramic products are baked with glaze in order to have a glossy surface.
【０００３】[0003]
【発明が解決しようとする課題】しかし、上記した各種
釉薬製品は専ら昼間における使用・鑑賞を目的としたも
のであるため、夜間において用いることができず、用途
が限定されていた。However, since the above-mentioned various glaze products are intended for use and appreciation exclusively in the daytime, they cannot be used at night and their applications are limited.
【０００４】そこで、本出願人は、この釉薬製品に用い
る釉薬中に蓄光体を添加することを考え、その製品化の
ため、各種釉薬中に蓄光体を添加する実験を行った。Therefore, the applicant of the present invention considered adding a phosphorescent substance to the glaze used in this glaze product, and conducted an experiment to add the phosphorescent substance to various glazes for commercialization thereof.
【０００５】その結果、通常の釉薬中に蓄光体を添加
し、焼きつけを行った場合は、釉薬が黒変し、釉薬製品
の製品価値が全く損なわれることが判明した。これは、
釉薬中に顔料との協同性を高めるため含まれている酸化
鉛や、顔料の発光性を高めるため含まれている酸化カド
ミウムが、蓄光体と反応して、上記した黒変を生じたと
考えられる。As a result, it has been found that when a phosphor is added to ordinary glaze and baked, the glaze turns black and the product value of the glaze product is impaired. this is,
It is considered that the lead oxide contained in the glaze to enhance the cooperativity with the pigment and the cadmium oxide contained in the glaze to enhance the luminescent properties of the pigment reacted with the phosphor to cause the above-mentioned black discoloration. .
【０００６】そこで、上記した酸化カドミウムや、酸化
鉛を含まない無機フリットからなる釉薬を用いるととも
に、蓄光体として無機蛍光体や蓄光体を用いて実験を行
ったところ、上記した黒変をまったく生じず、昼間のみ
ならず、夜間においても鮮やかに発色する釉薬製品を製
造することができた。Therefore, when a glaze consisting of the above-mentioned cadmium oxide and an inorganic frit containing no lead oxide was used and an experiment was carried out using an inorganic phosphor or a phosphor as a phosphor, the above-mentioned black discoloration was caused at all. In addition, it was possible to manufacture a glaze product that vividly colored not only in the daytime but also at night.
【０００７】本発明は、上記した知見に基づいて完成さ
れたものであり、夜間において長時間発光可能であり、
かつ、人体にも無害な釉薬及び同釉薬を用いた釉薬製品
を提供することを目的とする。The present invention has been completed based on the above-mentioned findings, and is capable of emitting light for a long time at night,
Moreover, it is an object to provide a glaze which is harmless to the human body and a glaze product using the glaze.
【０００８】[0008]
【課題を解決するための手段】本発明は、無鉛フリット
100 重量部と、無機蛍光体や蓄光体３〜50重量部と、バ
インダー30〜60重量部を混合して生成した釉薬に係るも
のである。SUMMARY OF THE INVENTION The present invention is a lead-free frit.
The present invention relates to a glaze produced by mixing 100 parts by weight, 3 to 50 parts by weight of an inorganic phosphor or phosphor and 30 to 60 parts by weight of a binder.
【０００９】ここに、無鉛フリットとは、文字通り、鉛
やカドミウム等を含まないフリットをいい、例えば、特
公昭５−５３７３５号公報に記載のものを用いることが
できる。１例として、以下の組成を有するものを用いる
ことができる。Here, the lead-free frit literally means a frit containing no lead, cadmium, or the like, and for example, the one described in Japanese Patent Publication No. 5-53735 can be used. As an example, one having the following composition can be used.
【００１０】SiO2 40 重量部 B2O3 26 重量部 K2O 6 重量部 ZrO3 5 重量部 BaO 5 重量部 Zr2O 5 重量部 Al2O3 3 重量部 Na2O 3 重量部 La2O3 2 重量部 かかる無鉛フリットを使用することで、紫外線の照射に
より蛍光を発する無機蛍光体や蓄光体と、焼成時の高温
の雰囲気においても化学変化が起きず、蛍光体や蓄光体
の機能を十分に発揮させることができる。SiO 2 40 parts by weight B 2 O 3 26 parts by weight K 2 O 6 parts by weight ZrO 3 5 parts by weight BaO 5 parts by weight Zr 2 O 5 parts by weight Al 2 O 3 3 parts by weight Na 2 O 3 parts by weight La 2 O 3 2 parts by weight By using such a lead-free frit, no chemical change occurs even in an inorganic phosphor or a phosphor that emits fluorescence upon irradiation with ultraviolet rays and in a high temperature atmosphere during firing, and the phosphor or phosphor The function can be fully exerted.
【００１１】また、無鉛フリットは人体に安全であり、
上記釉薬を用いた釉薬製品を使用する者の健康を害する
こともない。Further, the lead-free frit is safe for the human body,
It does not harm the health of the person who uses the glaze product using the glaze.
【００１２】紫外線の照射により蛍光を発する無機蛍光
体として、赤色の場合はY2O2S(付活剤としてEuを用い
る) 、緑色の場合はZn2,ZeO4 (付活剤としてMnを用い
る) 、青色の場合はBaMg2Al16O27 (付活剤としてEuを用
いる) を用いることができる。As an inorganic phosphor that emits fluorescence upon irradiation with ultraviolet rays, Y 2 O 2 S (using Eu as an activator) is used for red, Zn 2, ZeO 4 (Mn is used as an activator) for green. In the case of a blue color, BaMg 2 Al 16 O 27 (using Eu as an activator) can be used.
【００１３】また、紫外線の照射により蛍光を発する無
機蛍光体としては、天然に産出する鉱石の中で、紫外線
を照射することで発光する鉱石を破砕して砂状又は粉状
にしたものを用いることもできる。これらの鉱石は、特
願平４-76964号に記載するように、その産出地や種類に
より、産出量や品質、紫外線を照射したときの発光色や
その強さが夫々異なるが、多くの種類の中から選択する
ことができ、粉砕して天然発光石として安価に使用する
ことができる。かかる鉱石は、現在、約2000種類以上認
められているが、そのうちで、特に、カルシウム、マグ
ネシウム、カリウム、マンガン、ウラン、ハロゲン元素
を含んだものの使用が良発光性の観点から望ましい。As the inorganic fluorescent substance which emits fluorescence upon irradiation with ultraviolet rays, among the ores naturally produced, the ores which emit light upon irradiation with ultraviolet rays are crushed into a sandy or powdery state. You can also As described in Japanese Patent Application No. 4-76964, these ores differ in the amount and quality of production, the emission color when irradiated with ultraviolet rays, and their intensity, but there are many types. It can be selected from among, and can be crushed and used as a natural luminescent stone at low cost. About 2000 or more kinds of such ores have been recognized at present, and of these, it is particularly preferable to use those containing calcium, magnesium, potassium, manganese, uranium, and halogen elements from the viewpoint of good light emission.
【００１４】また、長時間放光可能な蓄光体としては、
例えば、特定の希土類元素 (Eu,Pr,Nd,Dy)で付活される
と共に、硼素で置換されたアルミン酸塩蛍光体を好適に
用いることができる。Further, as a light storing material capable of emitting light for a long time,
For example, an aluminate phosphor that is activated with a specific rare earth element (Eu, Pr, Nd, Dy) and is substituted with boron can be preferably used.
【００１５】バインダーは、好ましくはメタアクリル系
樹脂等からなるバインダー (例えば、ドイツ国デグナ社
製のNO.80431) を好適に用いることができる。As the binder, a binder preferably made of a methacrylic resin or the like (for example, NO.80431 manufactured by DEGNA, Germany) can be preferably used.
【００１６】また、本発明は、上記した釉薬を用いて、
以下の方法で製造した、陶磁器製品、ファインセラミッ
クス製品、ガラス製品、及び金属製品にも特徴を有す
る。Further, the present invention uses the above glaze,
It is also characterized by ceramic products, fine ceramic products, glass products, and metal products manufactured by the following methods.
【００１７】(釉薬製品が陶磁器製品の場合) 陶磁器原料を成形・乾燥し、乾燥成形体をつくる。(When the glaze product is a ceramic product) A ceramic raw material is molded and dried to form a dry molded product.
【００１８】同乾燥成形体を焼成して、素焼体をつく
る。この際、焼成温度は、例えば、磁器の場合は約1320
℃とし、陶器の場合は約1200℃とする。The dried molded body is fired to form a biscuit body. At this time, the firing temperature is, for example, about 1320 in the case of porcelain.
℃, about 1200 ℃ for pottery.
【００１９】常温で、素焼体の表面に筆、スプレー、
転写シート等を用いて絵付を行う。At room temperature, a brush, spray,
Painting is done using a transfer sheet.
【００２０】この絵付材料として、無鉛フリット100 重
量部に対して、無機蛍光体や蓄光体３〜50重量部と、無
鉛フリットを液化するためのメタアクリル系樹脂等から
なるバインダー (例えば、ドイツ国デグナ社製のNO.804
31) 40重量部を混合して生成した釉薬を用いる。As the painting material, 3 to 50 parts by weight of the inorganic phosphor or phosphor and 100 parts by weight of the lead-free frit and a binder made of methacrylic resin for liquefying the lead-free frit (for example, Germany NO.804 manufactured by Deguna
31) Use a glaze produced by mixing 40 parts by weight.
【００２１】絵付した素焼体を、780 ℃〜800 ℃の温
度で焼成して絵付を焼付け、本発明に係る釉薬製品を得
る。The unglazed body with the picture is baked at a temperature of 780 ° C. to 800 ° C. to bake the picture with the glazing product according to the present invention.
【００２２】なお、上記した工程において、単に素焼
体をつくるのではなく、乾燥成形体の表面に直接無機蛍
光体や蓄光体を含まない無鉛フリットを塗り、その後、
同様な温度で焼成して、釉焼きすることもできる。In the above-mentioned steps, instead of simply making a biscuit body, a lead-free frit containing no inorganic phosphor or phosphor is directly applied to the surface of the dry molded body, and then,
It is also possible to bake at the same temperature and to perform glaze baking.
【００２３】(釉薬製品がファインセラミックス製品の
場合) ファインセラミック原料を成形・乾燥し、例えば、板
状のセラミックス成形体をつくる。(When the glaze product is a fine ceramic product) A fine ceramic raw material is molded and dried to form, for example, a plate-shaped ceramic molded body.
【００２４】必要に応じてセラミックス成形体の表面
等を機械加工する。If necessary, the surface of the ceramic molded body is machined.
【００２５】常温で、セラミックス成形体の表面に
筆、スプレー、転写シート等を用いて絵付を行う。この
絵付材料として、無鉛フリット100 重量部に対して、無
機蛍光体や蓄光体３〜50重量部と、無鉛フリットを液化
するためのメタアクリル系樹脂等からなるバインダー
(例えば、ドイツ国デグナ社製のNO.80431) 40重量部と
を混合して生成した釉薬を用いる。At room temperature, painting is performed on the surface of the ceramic molded body using a brush, a spray, a transfer sheet or the like. As this painting material, a binder composed of 3 to 50 parts by weight of inorganic phosphor or phosphor and 100% by weight of lead-free frit and a methacrylic resin for liquefying the lead-free frit.
(For example, NO.80431 manufactured by DEGNA of Germany) is mixed with 40 parts by weight of a glaze.
【００２６】絵付したセラミックス成形体を、780 ℃
〜800 ℃の温度で焼成して絵付を焼付け、本発明に係る
釉薬製品を得る。The ceramic molded body with the picture is heated at 780 ° C.
The glaze product according to the present invention is obtained by baking at a temperature of up to 800 ° C. for baking the painting.
【００２７】(釉薬製品がガラス製品の場合) ガラス原料を融解・成形・冷却してガラス成形品をつ
くる。(When the glaze product is a glass product) The glass raw material is melted, molded and cooled to prepare a glass molded product.
【００２８】常温で、ガラス成形品の表面に筆、スプ
レー、転写シート等を用いて絵付を行う。この絵付材料
として、無鉛フリット100 重量部に対して、無機蛍光体
や蓄光体３〜50重量部と、無鉛フリットを液化するた
め、釉薬100 重量部に対してメタアクリル系樹脂等から
なるバインダー (例えば、ドイツ国デグナ社製のNO.804
31) 40重量部とを混合して生成した釉薬を用いる。At room temperature, the surface of the glass molded product is painted with a brush, a spray, a transfer sheet or the like. As the painting material, 3 to 50 parts by weight of the inorganic phosphor or phosphor and 100 parts by weight of the lead-free frit, and 100 parts by weight of the glaze for liquefying the lead-free frit, a binder made of methacrylic resin or the like ( For example, NO.804 manufactured by DEGNA of Germany
31) Use a glaze produced by mixing with 40 parts by weight.
【００２９】また、無鉛フリットは、上記した陶磁器用
の無鉛フリットより融点の低い無鉛フリット (例えば、
上記した無鉛フリットのSiO2の配合量を20重量部とした
もの) を用いる。Further, the lead-free frit is a lead-free frit having a melting point lower than that of the above-mentioned lead-free frit for ceramics (for example,
The above-mentioned lead-free frit containing 20 parts by weight of SiO 2 is used.
【００３０】絵付したガラス成形品を、560 ℃〜600
℃の温度で焼成して、絵付を焼付け、本発明に係る釉薬
製品を得る。A glass molded product with a picture is put at 560 ° C to 600 ° C.
The glaze product according to the present invention is obtained by baking at a temperature of ℃ and baking the painting.
【００３１】(釉薬製品が鉄やステンレス鋼からなる金
属製品の場合) 金属を鋳込んで金属成形品をつくる。(When the glaze product is a metal product made of iron or stainless steel) Metal is cast to form a metal molded product.
【００３２】常温で、金属成形品の表面に筆、スプレ
ー、転写シート等を用いて絵付を行う。この絵付材料と
して、無鉛フリット100 重量部に対して、無機蛍光体や
蓄光体３〜50重量部と、無鉛フリットを液化するため、
メタアクリル系樹脂等からなるバインダー (例えば、ド
イツ国デグナ社製のNO.80431) 40重量部とを混合して生
成した釉薬を用いる。At room temperature, the surface of the metal molded product is painted with a brush, a spray, a transfer sheet, or the like. As this painting material, to liquefy the lead-free frit with 3 to 50 parts by weight of the inorganic phosphor or the phosphorescent material per 100 parts by weight of the lead-free frit
A glaze produced by mixing 40 parts by weight of a binder made of a methacrylic resin or the like (for example, NO.80431 manufactured by DEGNA, Germany) is used.
【００３３】また、無鉛フリットは、上記した陶磁器用
の無鉛フリットと同じものを用いる。As the lead-free frit, the same lead-free frit for ceramics as described above is used.
【００３４】絵付した金属成形品を、780 ℃〜 800℃
の温度で焼成して絵付を焼付け、本発明に係る釉薬製品
を得る。A metal molded product with a picture is applied at 780 ° C to 800 ° C.
The composition is baked at the temperature of 1. to obtain the glaze product according to the present invention.
【００３５】[0035]
【実施例】以下、添付図 (図１〜図４) に示す実施例を
参照して、本発明に係る釉薬を用いて釉薬製品を製造す
る方法について説明する。EXAMPLE A method for producing a glaze product using the glaze according to the present invention will be described below with reference to the examples shown in the accompanying drawings (FIGS. 1 to 4).
【００３６】なお、本実施例は、釉薬製品が磁器からな
る灰皿の場合である。In this embodiment, the glaze product is an ashtray made of porcelain.
【００３７】まず、成形材料から鋳込成形技術やプレス
成形技術を用いて、図１に示すように、灰皿の形状を有
する成形素地をつくるとともに乾燥して乾燥成形体10を
つくる。First, as shown in FIG. 1, a molding base having the shape of an ashtray is formed from a molding material by using a casting molding technique or a press molding technique and dried to form a dry molded body 10.
【００３８】この乾燥成形体10の周面に、以下の組成を
有する無鉛フリットをメタアクリル系樹脂を用いて液化
したものを塗布した後乾燥させ、環状溝部14を切削加工
した後、1320℃の焼成温度で釉焼きし、図２に示すよう
に、釉焼き体11をつくる。A liquefied lead-free frit having the following composition using a methacrylic resin was applied to the peripheral surface of the dry molded body 10 and then dried, and after the annular groove 14 was cut, it was heated to 1320 ° C. The glaze is baked at the firing temperature to form a glaze body 11 as shown in FIG.
【００３９】このとき、切削成形した環状溝部14の表面
は釉薬が付着していない素焼状態であり、蛍光体を含ん
だ無鉛フリットの焼付をより確実に行うことができる。At this time, the surface of the cut and formed annular groove portion 14 is in a unglazed state in which no glaze is attached, so that the lead-free frit containing the phosphor can be baked more reliably.
【００４０】SiO2 40 重量部 B2O3 26 重量部 K2O 6 重量部 ZrO3 5 重量部 BaO 5 重量部 Zr2O 5 重量部 Al2O3 3 重量部 Na2O 3 重量部 La2O3 2 重量部 この環状溝部14内に、図３に示すように、上記した組成
を有する無鉛フリット100 重量部に対して特定の希土類
元素 (Eu,Pr,Nd,Dy)で付活されると共に、硼素で置換さ
れたアルミン酸塩蛍光体からなる蓄光体30重量部と、バ
インダー (ドイツ国デグナ社製のNO.80431) 40重量部を
混合して生成した釉薬15を充填して絵付を行う。SiO 2 40 parts by weight B 2 O 3 26 parts by weight K 2 O 6 parts by weight ZrO 3 5 parts by weight BaO 5 parts by weight Zr 2 O 5 parts by weight Al 2 O 3 3 parts by weight Na 2 O 3 parts by weight La 2 O 3 2 parts by weight As shown in FIG. 3, 100 parts by weight of the lead-free frit having the above composition is activated with a specific rare earth element (Eu, Pr, Nd, Dy) in the annular groove portion 14. In addition, 30 parts by weight of a phosphorescent aluminate phosphor substituted with boron and 40 parts by weight of a binder (NO.80431 manufactured by Deguna, Germany) were mixed and filled with a glaze 15 to paint. I do.
【００４１】この釉焼き体を、800 ℃の温度で焼成し
て、図４に示すように、釉薬製品としての灰皿16を製造
する。なお、かかる焼成によってバインダーは消失す
る。This glaze is baked at a temperature of 800 ° C. to manufacture an ashtray 16 as a glaze product as shown in FIG. Note that the binder disappears by such firing.
【００４２】この焼成工程においては、まず、焼成温度
を約６時間かけて800 ℃まで上昇し、次に、同焼成温度
を約10分間保持し、その後、約６時間かけて常温まで下
降する。In this firing step, first, the firing temperature is raised to 800 ° C. over about 6 hours, then the firing temperature is maintained for about 10 minutes, and then lowered to room temperature over about 6 hours.
【００４３】このようにして製造した灰皿16の使用にお
いて、昼間は、釉薬15はその鍔部17の上面に所望の色彩
の環状模様18を形成するとともに、釉薬15内に混合した
蓄光体は、光エネルギーを蓄積することになる。一方、
夜間において、室内を完全に暗くした場合においても、
昼間に充分に光エネルギーを貯えた蓄光体からの、長時
間にわたる、かつ、昼間とは異なった色彩の放光によっ
て、喫煙者は灰皿16の配置場所を容易に視認することが
でき、煙草を誤って畳等に落とす事故を確実に防止する
ことができる。In the use of the ashtray 16 manufactured in this way, during the daytime, the glaze 15 forms an annular pattern 18 of a desired color on the upper surface of the collar portion 17, and the phosphorescent substance mixed in the glaze 15 is It will store light energy. on the other hand,
Even if the room is completely dark at night,
The long-time light emission from the luminous body that stores enough light energy in the daytime and the emission of a color different from that in the daytime allows the smoker to easily recognize the location of the ashtray 16 and to smoke the cigarette. It is possible to reliably prevent accidents such as accidentally dropping it on a tatami mat or the like.
【００４４】また、かかる釉薬15中の無鉛フリットは、
蓄光体と、焼成時の高温雰囲気においても化学反応を生
じず、蓄光体の機能をそのまま維持することができる。
また、無鉛フリットは人体にも安全であり、灰皿16を使
用する喫煙者の健康を害することもない。The lead-free frit in the glaze 15 is
A chemical reaction does not occur even in a high temperature atmosphere during firing with the phosphor, and the function of the phosphor can be maintained as it is.
In addition, the lead-free frit is safe for the human body and does not harm the health of smokers who use the ashtray 16.
【００４５】さらに、単にプラスチック成形によって成
形したプラスチック製灰皿と比べると、耐熱性も格段に
向上している。Further, the heat resistance is remarkably improved as compared with a plastic ashtray which is simply formed by plastic molding.
【００４６】なお、上記した実施例では、釉薬製品が陶
磁器製品である灰皿の場合を参照して説明してきたが、
本発明は何ら上記した実施例に限定されるものではな
く、例えば、ファインセラミックス製品や、ガラス製品
や、金属製品にも好適に適用できるものである。In the above embodiments, the glaze product has been described with reference to the case of an ashtray which is a ceramic product.
The present invention is not limited to the above-described embodiments at all, and can be suitably applied to, for example, fine ceramic products, glass products, and metal products.
【００４７】また、具体的な使用例として、例えば、陶
磁器製品やファインセラミックス製品としては、タイル
や灰皿や電気スタンド等の用途が考えられ、ガラス製品
としては各種装飾品としての用途が考えられ、金属製品
としては各種ホーロー製品やトンネルのライニング材や
建築物の外壁材としての用途が考えられる。As specific examples of use, for example, ceramic products and fine ceramics products may be used for tiles, ashtrays, table lamps, and the like, and glass products may be used for various ornaments. As metal products, various applications such as enameled products, lining materials for tunnels, and outer wall materials for buildings can be considered.
【００４８】[0048]
【発明の効果】この発明によれば次のような効果を有す
る。The present invention has the following effects.
【００４９】本発明では、釉薬を、無鉛フリットに無
機蛍光体や蓄光体を混合させたものとしている。かかる
無鉛フリットを使用することで、紫外線の照射により蛍
光を発する無機蛍光体や蓄光体と、焼成時の高温の雰囲
気においても化学変化が起きず、蛍光体や蓄光体の機能
を発揮することができる。In the present invention, the glaze is a lead-free frit mixed with an inorganic phosphor or a phosphor. By using such a lead-free frit, it is possible to exert the function of the phosphor or the phosphorescent substance, without causing a chemical change even in the high temperature atmosphere during firing, with the inorganic phosphor or the phosphorescent substance that emits fluorescence upon irradiation with ultraviolet rays. it can.
【００５０】また、無鉛フリットは耐候性、耐熱性、
耐食性、耐汚染性にも優れており、長年月にわたって釉
薬製品を使用することができる。Further, the lead-free frit has weather resistance, heat resistance,
It has excellent corrosion resistance and stain resistance, and can be used as a glaze product for many years.
【００５１】さらに、無鉛フリットは人体に安全であ
り、上記釉薬を用いた釉薬製品を使用する者健康を害す
ることもない。Furthermore, the lead-free frit is safe for the human body and does not harm the health of the person using the glaze product using the glaze.
【図１】本発明に係る釉薬製品を製造するのに用いる成
形乾燥品の斜視図である。FIG. 1 is a perspective view of a molded dried product used to manufacture a glaze product according to the present invention.
【図２】釉焼製品の要部拡大説明図である。FIG. 2 is an enlarged explanatory view of a main part of a glaze baked product.
【図３】釉焼製品の要部拡大説明図である。FIG. 3 is an enlarged explanatory view of a main part of a glaze baked product.
【図４】本発明に係る釉薬製品としての灰皿の斜視図で
ある。FIG. 4 is a perspective view of an ashtray as a glaze product according to the present invention.
10 成形乾燥品 11 釉焼製品 14 環状溝部 15 釉薬 16 灰皿 17 鍔部 18 環状模様 10 Molded dried product 11 Glazed product 14 Annular groove 15 Glaze 16 Ashtray 17 Collar 18 Annular pattern
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ２３Ｄ 5/00 Ｊ ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI technical display location C23D 5/00 J
Claims (3)
蓄光体３〜50重量部と、バインダー30〜60重量部を混合
して生成した釉薬。1. A glaze produced by mixing 100 parts by weight of a lead-free frit, 3 to 50 parts by weight of an inorganic phosphor or phosphor and 30 to 60 parts by weight of a binder.
を特徴とする釉薬製品。2. A glaze product manufactured by using the glaze according to claim 1.
製品、ファインセラミックス製品のいずれかであること
を特徴とする請求項２記載の釉薬製品。3. The glaze product according to claim 2, wherein the glaze product is any one of a ceramic product, a glass product, a metal product and a fine ceramic product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30516594A JPH08165140A (en) | 1994-12-08 | 1994-12-08 | Glaze and glazed product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30516594A JPH08165140A (en) | 1994-12-08 | 1994-12-08 | Glaze and glazed product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08165140A true JPH08165140A (en) | 1996-06-25 |
Family
ID=17941854
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30516594A Pending JPH08165140A (en) | 1994-12-08 | 1994-12-08 | Glaze and glazed product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH08165140A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10101371A (en) * | 1996-09-27 | 1998-04-21 | Naigai Ceramics Kk | Inorganic artificial ceramics having light accumulating property and fluorescent characteristic and its production |
| JPH10171389A (en) * | 1996-12-10 | 1998-06-26 | Inax Corp | Light storage plate and method of using light storage plate |
| JPH11288233A (en) * | 1998-04-02 | 1999-10-19 | Nippon Carbide Ind Co Inc | Information display device |
| JP2000007421A (en) * | 1998-06-22 | 2000-01-11 | Shinto Paint Co Ltd | Production of ceramic product |
| JP2000007420A (en) * | 1998-06-18 | 2000-01-11 | Kanemasu:Kk | Production of luminous patterned ceramic and product obtained thereby |
| JP2000086329A (en) * | 1998-09-11 | 2000-03-28 | Kazuo Saito | Porcelain provided with glass and luminous agent |
| JP2001504552A (en) * | 1996-11-29 | 2001-04-03 | リーデル−デ ハーエン アクチェンゲゼルシャフト | Layered body having phosphorescent properties, method for producing the same, and use thereof |
| KR20010092981A (en) * | 2000-03-28 | 2001-10-27 | 김형순 | tile glaze and its manufacturing method |
| JP2003002765A (en) * | 2001-06-18 | 2003-01-08 | Iwasaki:Kk | Emulsifier, glaze, ceramic product, method for manufacturing emulsifier, method for manufacturing glaze and method for manufacturing ceramic product |
| JP2007001832A (en) * | 2005-06-27 | 2007-01-11 | Toyo Glass Co Ltd | Phosphorescent glass article and its manufacturing method |
| KR20170106997A (en) | 2015-08-28 | 2017-09-22 | 코아 가라스 가부시키가이샤 | Manufacturing method of glass-coated phosphorescent material and glass-coated phosphorescent material |
| CN108558449A (en) * | 2018-02-08 | 2018-09-21 | 福建省南安市荣达建材有限公司 | A kind of production method of fluorescence ceramic tile |
-
1994
- 1994-12-08 JP JP30516594A patent/JPH08165140A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10101371A (en) * | 1996-09-27 | 1998-04-21 | Naigai Ceramics Kk | Inorganic artificial ceramics having light accumulating property and fluorescent characteristic and its production |
| US6699598B2 (en) | 1996-11-29 | 2004-03-02 | Honeywell International Inc. | Laminar body having phosphorescent properties, process for producing it and its use |
| JP2001504552A (en) * | 1996-11-29 | 2001-04-03 | リーデル−デ ハーエン アクチェンゲゼルシャフト | Layered body having phosphorescent properties, method for producing the same, and use thereof |
| JPH10171389A (en) * | 1996-12-10 | 1998-06-26 | Inax Corp | Light storage plate and method of using light storage plate |
| JPH11288233A (en) * | 1998-04-02 | 1999-10-19 | Nippon Carbide Ind Co Inc | Information display device |
| JP2000007420A (en) * | 1998-06-18 | 2000-01-11 | Kanemasu:Kk | Production of luminous patterned ceramic and product obtained thereby |
| JP2000007421A (en) * | 1998-06-22 | 2000-01-11 | Shinto Paint Co Ltd | Production of ceramic product |
| JP2000086329A (en) * | 1998-09-11 | 2000-03-28 | Kazuo Saito | Porcelain provided with glass and luminous agent |
| KR20010092981A (en) * | 2000-03-28 | 2001-10-27 | 김형순 | tile glaze and its manufacturing method |
| JP2003002765A (en) * | 2001-06-18 | 2003-01-08 | Iwasaki:Kk | Emulsifier, glaze, ceramic product, method for manufacturing emulsifier, method for manufacturing glaze and method for manufacturing ceramic product |
| JP2007001832A (en) * | 2005-06-27 | 2007-01-11 | Toyo Glass Co Ltd | Phosphorescent glass article and its manufacturing method |
| KR20170106997A (en) | 2015-08-28 | 2017-09-22 | 코아 가라스 가부시키가이샤 | Manufacturing method of glass-coated phosphorescent material and glass-coated phosphorescent material |
| JPWO2017038687A1 (en) * | 2015-08-28 | 2018-06-14 | 興亜硝子株式会社 | Glass-coated phosphorescent material and method for producing glass-coated phosphorescent material |
| CN108558449A (en) * | 2018-02-08 | 2018-09-21 | 福建省南安市荣达建材有限公司 | A kind of production method of fluorescence ceramic tile |
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