JPH08141404A - Deodorization catalyst - Google Patents
Deodorization catalystInfo
- Publication number
- JPH08141404A JPH08141404A JP6286590A JP28659094A JPH08141404A JP H08141404 A JPH08141404 A JP H08141404A JP 6286590 A JP6286590 A JP 6286590A JP 28659094 A JP28659094 A JP 28659094A JP H08141404 A JPH08141404 A JP H08141404A
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- JP
- Japan
- Prior art keywords
- air
- oxide carrier
- deodorizing catalyst
- catalyst
- active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Catalysts (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Treating Waste Gases (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、新規な活性成分を有す
る脱臭触媒にかかり、特に家電住宅設備から発生する空
気中の不快臭気成分を含むガスを酸化分解するための脱
臭触媒に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a deodorizing catalyst having a novel active ingredient, and more particularly to a deodorizing catalyst for oxidatively decomposing a gas containing an unpleasant odor component in the air generated from home electric appliances.
【０００２】[0002]
【従来の技術】空気中に含まれる臭気成分を除去するた
めの脱臭方法として例えば、混練成形物（特開昭５２−
１５２６６１号公報）や活性炭等の吸着剤を用いること
が知られている。これらの吸着剤を用いる方法では、空
気中のＳＯ2 との反応速度が遅いため、除去性能が悪
く、また、通気時間と共に除去性能が低下するため吸着
剤の寿命が短い等の欠点があった。2. Description of the Related Art As a deodorizing method for removing odorous components contained in air, for example, a kneaded molded article (JP-A-52-52)
It is known to use an adsorbent such as activated carbon or the like. The methods using these adsorbents have the drawbacks that the removal performance is poor because the reaction rate with SO 2 in the air is slow, and that the life of the adsorbent is short because the removal performance decreases with aeration time. .
【０００３】これらの欠点を解決するため、活性炭にＫ
ＩＯ3 を担持する方法が提案されている。この方法では
活性炭に担持されたヨウ素が活性炭のＣ−Ｃ結合に入り
込み、非常に不安定な型となるため、空気中の酸素を吸
着しやすくなり、吸着した酸素と空気中のＳＯ2 の触媒
作用を起こし、（１）式の反応速度が速くなって、吸着
剤として高性能となる。In order to solve these drawbacks, K
A method of carrying IO 3 has been proposed. In this method, the iodine supported on the activated carbon enters the C—C bond of the activated carbon and becomes a very unstable type, so that oxygen in the air is easily adsorbed, and the adsorbed oxygen and the SO 2 catalyst in the air are catalyzed. It causes the action, the reaction rate of the formula (1) becomes faster, and the performance becomes high as an adsorbent.
【０００４】 ＳＯ2 ＋（Ｏ）＋Ｈ2Ｏ → Ｈ2ＳＯ4 ……（１） また、活性炭にＫ2ＣＯ3等のアルカリを担持した吸着剤
は、ＨＣｌの吸着については活性炭からなる吸着剤の場
合に比較して高性能となる。SO 2 + (O) + H 2 O → H 2 SO 4 (1) Further, an adsorbent in which activated carbon carries an alkali such as K 2 CO 3 is an adsorbent made of activated carbon for adsorbing HCl. The performance is higher than that of.
【０００５】このように、活性炭にＫＩＯ3 ，Ｋ2ＣＯ3
を担持することによって空気中のＳＯ2 ，ＨＣｌ等の
酸性ガスを効率よく除去できる。As described above, KIO 3 , K 2 CO 3 is added to the activated carbon.
By supporting the above, acidic gases such as SO 2 and HCl in the air can be efficiently removed.
【０００６】これらの薬品を活性炭に担持する方法とし
ては成型した活性炭を薬品を溶解した液に浸漬後、水切
りし、乾燥していた。As a method for supporting these chemicals on the activated carbon, the molded activated carbon was immersed in a liquid in which the chemicals were dissolved, drained and dried.
【０００７】[0007]
【発明が解決しようとする課題】しかし、この方法で
は、活性炭が脆くなり、通風時に発塵量が増加するこ
と、特にハニカム状に成型した活性炭の場合にはヒビ割
れが発生するなどの問題があった。However, this method has a problem that the activated carbon becomes brittle and the amount of dust generated during ventilation is increased, and cracks particularly occur in the case of activated carbon molded in a honeycomb shape. there were.
【０００８】本発明の目的は、上記した従来技術の課題
を解決し、臭気成分の除去性能に優れ、活性炭のように
薬品の担持の際に強度が低下せず、かつ、通気時間にお
ける除去性能の寿命の長い脱臭触媒を提供することにあ
る。The object of the present invention is to solve the above-mentioned problems of the prior art, to be excellent in the ability to remove odorous components, not to lower the strength when carrying a chemical such as activated carbon, and to be capable of removing the material in aeration time. It is to provide a deodorizing catalyst having a long life.
【０００９】[0009]
【課題を解決するための手段】上記目的を達成するため
に、本発明では、空気中に含有する臭気成分を吸着する
層を酸化物担体に施しており少なくとも活性アルミナと
シリカとゼオライトからなることを特徴とする脱臭触媒
としたものである。In order to achieve the above object, in the present invention, a layer for adsorbing an odorous component contained in the air is provided on an oxide carrier, which is composed of at least activated alumina, silica and zeolite. And a deodorizing catalyst.
【００１０】上記脱臭触媒において、酸化物担体に担持
された活性成分として、吸着層にＰｔＯ，ＣｅＯ2 ，Ｐ
ｄＯを配合してなる。この脱臭触媒は、空気中の臭気成
分を吸着し更に酸化し無臭化することから活性炭より寿
命を長くできる。In the above deodorizing catalyst, PtO, CeO 2 , P as an active component supported on the oxide carrier is adsorbed on the adsorption layer.
It contains dO. Since this deodorizing catalyst adsorbs odorous components in the air and further oxidizes it to make it odorless, it has a longer life than activated carbon.
【００１１】上記活性成分が担持された酸化物担体とし
て、コージェライトが好ましい。これにより、活性炭の
ように薬品の担持の際に強度が低下するのを防ぐことが
できる。Cordierite is preferable as the oxide carrier carrying the above-mentioned active ingredient. As a result, it is possible to prevent the strength from being lowered when carrying a chemical such as activated carbon.
【００１２】酸化物担体表面に少なくとも活性アルミナ
とシリカとゼオライトからなる吸着層とＰｔＯ及びＰｄ
Ｏからなる金属触媒層を担体上にコートしても良いし、
直接触媒溶液に含浸等の方法で浸漬しても良い。An adsorption layer composed of at least activated alumina, silica and zeolite and PtO and Pd are formed on the surface of the oxide carrier.
A metal catalyst layer composed of O may be coated on the carrier,
It may be directly immersed in the catalyst solution by a method such as impregnation.
【００１３】上記活性成分を担持した酸化物担体の形状
として、ハニカム状、板状、３次元網目構造、粒状等が
ある。The shape of the oxide carrier carrying the above-mentioned active ingredient includes a honeycomb shape, a plate shape, a three-dimensional network structure, a granular shape and the like.
【００１４】酸化物担体に活性成分が担持され、活性成
分として少なくとも活性アルミナとシリカとゼオライト
とＰｔＯ，ＣｅＯ2 ，ＰｄＯからなる脱臭触媒を含む触
媒層は、空気清浄器における吸入口と貫流ファンの空間
に、または、空調機器における熱交換器の前段又は後段
に、または、冷凍機器における冷凍空間に備えることが
できる。The catalyst layer in which an active component is supported on an oxide carrier and which contains a deodorizing catalyst composed of at least active alumina, silica, zeolite, PtO, CeO 2 , and PdO as active components is used as a suction port and a through-flow fan in an air purifier. It can be provided in a space, in a front stage or a rear stage of a heat exchanger in an air conditioner, or in a refrigerating space in a refrigerating device.
【００１５】[0015]
【作用】以上述べたように、本発明のハニカム脱臭触媒
によれば、空気中の臭気成分は活性化された触媒表面に
より、吸着、酸化分解され無臭化される。As described above, according to the honeycomb deodorizing catalyst of the present invention, the odorous components in the air are adsorbed, oxidatively decomposed and deodorized by the activated catalyst surface.
【００１６】これにより、活性炭のような薬品の担持の
際に強度が低下することを防ぐことができ、また、吸着
寿命が短い活性炭に対し寿命の長い脱臭触媒にすること
が出来る。This makes it possible to prevent the strength from deteriorating when a chemical such as activated carbon is loaded, and to use a deodorizing catalyst having a long life as compared with an activated carbon having a short adsorption life.
【００１７】[0017]
【実施例】以下に本発明を実施例により具体的に説明す
る。EXAMPLES The present invention will be specifically described below with reference to examples.
【００１８】（実施例１）図１は本発明の臭気成分吸着
層を酸化物担体に施した状態を断面図で示したものであ
る。(Embodiment 1) FIG. 1 is a sectional view showing a state in which an odor component adsorption layer of the present invention is applied to an oxide carrier.
【００１９】図１において、少なくとも活性アルミナと
シリカとゼオライトの混合溶液にハニカム状の酸化物担
体１を浸漬し焼成する。この時形成されたものが吸着層
２である。尚、混合溶液をハニカム状の酸化物担体１に
コートして吸着層２を形成させてもよい。In FIG. 1, a honeycomb-shaped oxide carrier 1 is dipped in a mixed solution of at least activated alumina, silica and zeolite and fired. What is formed at this time is the adsorption layer 2. The mixed solution may be coated on the honeycomb-shaped oxide carrier 1 to form the adsorption layer 2.
【００２０】この構成により、空気中の臭気成分はハニ
カム状の酸化物担体１に形成された吸着層２に吸着され
無臭化される。これにより、空気中の臭気は確実に吸着
し除去することができる。また、酸化物担体１の形状に
より、浸漬やコートする方法を選択し、製造コスト及び
作り易さによる歩留の向上が期待できる。With this structure, the odorous components in the air are adsorbed by the adsorption layer 2 formed on the honeycomb-shaped oxide carrier 1 and deodorized. Thereby, the odor in the air can be surely adsorbed and removed. Further, depending on the shape of the oxide carrier 1, a dipping or coating method can be selected, and it is expected that the production cost and the ease of manufacture will improve the yield.
【００２１】（実施例２）図２は本発明の臭気成分の吸
着・酸化層を酸化物担体に施した状態を断面図で示した
ものである。(Embodiment 2) FIG. 2 is a sectional view showing a state in which an odorous component adsorption / oxidation layer of the present invention is applied to an oxide carrier.
【００２２】図２において、少なくとも活性アルミナと
シリカとゼオライトとＰｔＯ，ＣｅＯ2 ，ＰｄＯの混合
溶液にハニカム状の酸化物担体１を浸漬し焼成する。こ
の時形成されたものが吸着・酸化層３である。In FIG. 2, the honeycomb-shaped oxide carrier 1 is dipped in a mixed solution of at least activated alumina, silica, zeolite, PtO, CeO 2 , and PdO and fired. What was formed at this time is the adsorption / oxidation layer 3.
【００２３】尚、混合溶液をハニカム状の酸化物担体１
にコートして吸着・酸化層３を形成させてもよい。The mixed solution is used as a honeycomb-shaped oxide carrier 1.
Alternatively, the adsorption / oxidation layer 3 may be formed by coating.
【００２４】この構成により、空気中の臭気成分はハニ
カム状の酸化物担体１に形成された吸着・酸化層３に吸
着と同時に酸化分解され無臭化する。この時、吸着され
た臭気成分が酸化分解されることによって吸着・酸化層
３の吸着能力が再生される。With this structure, the odorous components in the air are oxidatively decomposed and deodorized at the same time as being adsorbed by the adsorption / oxidation layer 3 formed on the honeycomb-shaped oxide carrier 1. At this time, the adsorbing ability of the adsorbing / oxidizing layer 3 is regenerated by the oxidative decomposition of the adsorbed odorous components.
【００２５】これにより、空気中の臭気は確実に吸着し
除去され、吸着した臭気は酸化分解し吸着と酸化を同時
に行うことができ脱臭触媒の再生ができる。また、酸化
物担体１の形状により、浸漬やコートする方法を選択
し、製造コスト及び作り易さによる歩留の向上が期待で
きる。さらに臭気の確実な除去により不快感がなくなり
環境浄化に寄与する。Thus, the odor in the air is surely adsorbed and removed, and the adsorbed odor is oxidatively decomposed and adsorption and oxidation can be carried out at the same time, and the deodorizing catalyst can be regenerated. Further, depending on the shape of the oxide carrier 1, a dipping or coating method can be selected, and it is expected that the production cost and the ease of manufacture will improve the yield. Furthermore, the reliable removal of odor eliminates discomfort and contributes to environmental purification.
【００２６】（実施例３）図３は本発明の臭気成分の吸
着層と酸化層を酸化物担体に施した状態を断面図で示し
たものである。(Embodiment 3) FIG. 3 is a sectional view showing a state in which an odorous component adsorption layer and an oxidation layer of the present invention are applied to an oxide carrier.
【００２７】図３において、少なくとも活性アルミナと
シリカとゼオライトの混合溶液にハニカム状の酸化物担
体１を浸漬し焼成する。この時形成されたものが吸着層
２である。尚、混合溶液をハニカム状の酸化物担体１に
コートして吸着層２を形成させてもよい。In FIG. 3, the honeycomb-shaped oxide carrier 1 is dipped in a mixed solution of at least activated alumina, silica and zeolite and fired. What is formed at this time is the adsorption layer 2. The mixed solution may be coated on the honeycomb-shaped oxide carrier 1 to form the adsorption layer 2.
【００２８】次に、ＰｔＯ，ＣｅＯ2 ，ＰｄＯの混合溶
液に、上記の吸着層２を形成したハニカム状の酸化物担
体１を浸漬し焼成する。この時形成されたものが酸化層
４である。尚、ＰｔＯ，ＣｅＯ2 ，ＰｄＯの混合溶液を
ハニカム状の酸化物担体１に形成した吸着層２上にコー
トして酸化層４を形成させてもよい。Next, the honeycomb-shaped oxide carrier 1 on which the adsorption layer 2 is formed is immersed in a mixed solution of PtO, CeO 2 , and PdO and fired. The oxide layer 4 is formed at this time. The oxide layer 4 may be formed by coating a mixed solution of PtO, CeO 2 , and PdO on the adsorption layer 2 formed on the honeycomb-shaped oxide carrier 1.
【００２９】この構成により、空気中の臭気成分はハニ
カム状の酸化物担体１に形成された吸着層２に吸着され
ると同時に酸化層４により酸化分解され無臭化する。こ
の時、吸着された臭気成分が酸化分解されることによっ
て吸着層２の吸着能力が再生される。これにより、酸化
層４を別々に設けたことで貴金属の使用量を低減し安価
にすることができる。また、酸化物担体１の形状によ
り、浸漬やコートする方法を選択し、製造コスト及び作
り易さによる歩留の向上が期待できる。さらに、貴金属
の使用量を増すことにより触媒性能を向上できる。With this structure, the odorous component in the air is adsorbed by the adsorption layer 2 formed on the honeycomb-shaped oxide carrier 1 and, at the same time, is oxidized and decomposed by the oxide layer 4 to be deodorized. At this time, the adsorbability of the adsorption layer 2 is regenerated by the oxidative decomposition of the adsorbed odorous components. As a result, by providing the oxide layer 4 separately, the amount of precious metal used can be reduced and the cost can be reduced. Further, depending on the shape of the oxide carrier 1, a dipping or coating method can be selected, and it is expected that the production cost and the ease of manufacture will improve the yield. Further, the catalyst performance can be improved by increasing the amount of the noble metal used.
【００３０】（実施例４）図１〜３に示した実施例１〜
３のハニカム状の酸化物担体１はコージェライト担体で
あり、上記実施例１〜３の混合溶液に侵されることな
く、吸着層２、又は、吸着・酸化層３、又は、酸化層４
の各々の層を強固に形成することができる。(Embodiment 4) Embodiments 1 to 1 shown in FIGS.
The honeycomb-shaped oxide carrier 1 of No. 3 is a cordierite carrier, and the adsorption layer 2, the adsorption / oxidation layer 3, or the oxidation layer 4 is not affected by the mixed solutions of Examples 1 to 3 above.
Each of the layers can be firmly formed.
【００３１】図４に臭気成分における実施例ハニカム脱
臭触媒の寿命を示す。図４において、ａは従来の活性
炭、ｂは実施例ハニカム脱臭触媒である。FIG. 4 shows the life of the example honeycomb deodorizing catalyst in the case of odorous components. In FIG. 4, a is a conventional activated carbon and b is a honeycomb deodorizing catalyst of the embodiment.
【００３２】図４からも明らかなように、実施例ハニカ
ム脱臭触媒は従来の活性炭と比較し寿命が長いことが確
認された。これにより、従来にない寿命の長い脱臭触媒
ができる。As is apparent from FIG. 4, it was confirmed that the honeycomb deodorizing catalysts of Examples had a longer life than the conventional activated carbon. As a result, a deodorizing catalyst having a long life which has never been obtained can be obtained.
【００３３】以上の実施例のハニカム脱臭触媒は、例え
ば空気清浄器、空調機、冷蔵庫などに設置され、臭気成
分を無臭化する脱臭触媒として使用される。The honeycomb deodorizing catalyst of the above embodiments is installed in, for example, an air purifier, an air conditioner, a refrigerator, etc., and is used as a deodorizing catalyst for deodorizing odorous components.
【００３４】（実施例５）図５は、本発明のハニカム脱
臭触媒を設置した空気清浄器の概略断面図を示す。(Embodiment 5) FIG. 5 is a schematic sectional view of an air cleaner equipped with the honeycomb deodorizing catalyst of the present invention.
【００３５】図５において、５は空気清浄器本体、６は
吸入口、７はハニカム脱臭触媒を示し、８は貫流ファ
ン、９は排気口を示している。この空気清浄器５は、貫
流ファン８により臭気を含有する空気を吸入口５から吸
引し、本発明のハニカム脱臭触媒７を通すことにより臭
気成分を吸着・酸化分解し、脱臭された空気が排気口９
から排出され、室内の空気を清浄化するものである。こ
れにより、トイレ、台所、居間等のあらゆる部屋の脱臭
が可能である。従って、本発明により、従来にない長寿
命によりメンテナンスフリーの空気清浄器が可能であ
る。In FIG. 5, 5 is an air purifier body, 6 is an inlet, 7 is a honeycomb deodorizing catalyst, 8 is a once-through fan, and 9 is an exhaust port. The air purifier 5 sucks odor-containing air from the suction port 5 by the cross-flow fan 8 and passes the honeycomb deodorizing catalyst 7 of the present invention to adsorb and oxidize and decompose odorous components, and the deodorized air is exhausted. Mouth 9
It is discharged from the room and cleans the indoor air. As a result, it is possible to deodorize any room such as a toilet, kitchen or living room. Therefore, according to the present invention, it is possible to provide a maintenance-free air purifier with a long service life that has never existed before.
【００３６】（実施例６）図６は、本発明のハニカム脱
臭触媒を設置した空調機の概略断面図を示す。(Embodiment 6) FIG. 6 is a schematic sectional view of an air conditioner equipped with the honeycomb deodorizing catalyst of the present invention.
【００３７】図６において、１１は空調機本体、１２は
臭気成分を含んだ室内空気を吸引する吸入口、１３は本
発明のハニカム脱臭触媒を示し、１４は熱交換器、１５
は貫流ファン、１６は脱臭された空気を排出する排気口
を示す。この空調機も実施例５の空気清浄器と同様の機
能を有しており、この装置では、熱交換器１４により、
脱臭された空気の温度調整が行われて、排気口から室内
に循環されている。In FIG. 6, 11 is an air conditioner main body, 12 is an inlet for sucking indoor air containing odorous components, 13 is a honeycomb deodorizing catalyst of the present invention, 14 is a heat exchanger, and 15 is a heat exchanger.
Is a cross-flow fan, and 16 is an exhaust port for discharging deodorized air. This air conditioner also has the same function as the air purifier of the fifth embodiment, and in this device, the heat exchanger 14
The temperature of the deodorized air is adjusted and circulated in the room through the exhaust port.
【００３８】これにより、空気清浄器がなくとも部屋の
空調と同時に脱臭が可能であり利便性がある。従って、
本発明により、従来にない長寿命によりメンテナンスフ
リーの脱臭機能を備えた脱臭と空調を行える空調機が可
能である。Thus, it is possible to deodorize at the same time as air conditioning in the room without using an air purifier, which is convenient. Therefore,
According to the present invention, it is possible to provide an air conditioner capable of deodorizing and air conditioning with a maintenance-free deodorizing function due to a long service life that has not been available in the past.
【００３９】（実施例７）図７は、本発明のハニカム脱
臭触媒を設置した冷蔵庫の概略断面図を示す。(Embodiment 7) FIG. 7 is a schematic sectional view of a refrigerator in which the honeycomb deodorizing catalyst of the present invention is installed.
【００４０】図７において、２１は冷蔵庫本体であり、
２２は冷凍室、２３は冷蔵室等の収納室、２４は臭気成
分を含んだ冷気、２５は本発明のハニカム脱臭触媒を示
し、２６は脱臭された冷気を示す。冷蔵庫２１内にハニ
カム脱臭触媒を設けることにより、冷気の流れにより冷
蔵庫内の臭気を脱臭することができる。In FIG. 7, reference numeral 21 is a refrigerator body,
Reference numeral 22 is a freezing room, 23 is a storage room such as a refrigerating room, 24 is cold air containing an odor component, 25 is a honeycomb deodorizing catalyst of the present invention, and 26 is deodorized cold air. By providing the honeycomb deodorizing catalyst in the refrigerator 21, the odor in the refrigerator can be deodorized by the flow of cold air.
【００４１】これにより、食品臭気の除去が可能であ
る。従って本発明により、従来にない脱臭効果の向上が
期待でき、長寿命のメンテナンスフリーの冷凍機器が可
能である。As a result, the odor of food can be removed. Therefore, according to the present invention, an unprecedented improvement in deodorizing effect can be expected, and a long-life maintenance-free refrigerating machine is possible.
【００４２】[0042]
【発明の効果】以上のように本発明は、コージェライト
の酸化物担体と本発明の脱臭触媒を組み合わせたこと
で、従来のハニカム状に成形した活性炭のようにヒビ割
れや薬品の担持の際の強度劣化を防止できる。As described above, the present invention combines the cordierite oxide carrier with the deodorizing catalyst of the present invention to support cracking and chemical loading when activated carbon formed into a conventional honeycomb shape. The strength deterioration of can be prevented.
【００４３】また、上記酸化物担体上の吸着層により空
気中の臭気成分の除去を確実に行うことができる。Further, the odorous component in the air can be surely removed by the adsorption layer on the oxide carrier.
【００４４】脱臭触媒においては、吸着層に貴金属（Ｐ
ｔＯ，ＰｄＯ）を配合することにより臭気成分の酸化分
解を行い吸着と酸化を同時に行うことができ脱臭触媒の
再生ができる。In the deodorizing catalyst, the noble metal (P
By blending (tO, PdO), the odorous components can be oxidized and decomposed and adsorption and oxidation can be carried out at the same time, and the deodorizing catalyst can be regenerated.
【００４５】更に、吸着層に貴金属を担持したことで、
通気時間における除去性能の寿命の長い脱臭触媒を提供
することができる。Further, by supporting the noble metal on the adsorption layer,
It is possible to provide a deodorizing catalyst having a long life of removal performance in aeration time.
【００４６】また、本発明は不快臭気を除去することで
環境浄化に寄与する。次に、吸着層と酸化層を２層にす
ることで貴金属（ＰｔＯ，ＰｄＯ）の使用量を低減する
ことが可能であり安価な脱臭触媒を得ることができる。The present invention also contributes to environmental purification by removing unpleasant odors. Next, by forming the adsorption layer and the oxidation layer into two layers, it is possible to reduce the amount of precious metal (PtO, PdO) used and obtain an inexpensive deodorizing catalyst.
【００４７】また、逆に貴金属（ＰｔＯ，ＰｄＯ）の使
用量を増やすことによって必要に応じて触媒性能を向上
させることができる。On the contrary, by increasing the amount of the noble metal (PtO, PdO) used, the catalyst performance can be improved as required.
【００４８】更に形状においては、酸化物担体をハニカ
ム状、板状、３次元網目構造、粒状等のあらゆる形状が
可能であり取り付け構造等、必要に応じた脱臭触媒を提
供することができる。また、酸化物担体の形状により浸
漬やコートする方法を選択し製造コスト及び作り易さに
よる歩留の向上が期待できる。With respect to the shape, the oxide carrier can have any shape such as a honeycomb shape, a plate shape, a three-dimensional mesh structure, and a granular shape, and a deodorizing catalyst such as a mounting structure can be provided as required. Further, it is expected that the dipping or coating method is selected depending on the shape of the oxide carrier to improve the production cost and the yield due to the ease of manufacturing.
【００４９】使用用途においては、空気清浄器に使用し
た場合、トイレ、台所等あらゆる部屋の脱臭に効果があ
り、従来にない長寿命によりメンテナンスフリーの空気
清浄器が可能である。When used as an air purifier, it is effective in deodorizing all rooms such as toilets and kitchens, and a maintenance-free air purifier can be provided due to its unprecedented long life.
【００５０】空調機に使用した場合は、空気清浄器を使
用することなく部屋の空調と同時に脱臭が可能であり利
便性もたらすことができる。また、従来にない長寿命に
よりメンテナンスフリーの脱臭機能を備えた脱臭と空調
を行える空調機が可能である。When used in an air conditioner, it is possible to deodorize the room at the same time as air conditioning without using an air purifier, which brings convenience. Further, an air conditioner capable of deodorizing and air conditioning with a maintenance-free deodorizing function due to its unprecedented long life is possible.
【００５１】冷凍機器に使用した場合は、食品臭気の悪
臭を脱臭することができる。また、従来にない脱臭効果
の向上が期待でき、長寿命によりメンテナンスフリーの
冷凍機器が可能である。When used in a refrigerating machine, it can deodorize the bad odor of food odor. In addition, it is possible to expect an improvement in deodorizing effect that has never been seen before, and maintenance-free refrigeration equipment is possible due to its long life.
【００５２】上記用途に使用した場合においても、半永
久的に使用することが可能であり交換不要の脱臭触媒を
提供することができる。Even when it is used for the above purposes, it is possible to provide a deodorizing catalyst that can be used semipermanently and does not require replacement.
【図１】本発明の実施例１の臭気成分吸着層を酸化物担
体に施した状態を示した断面図FIG. 1 is a cross-sectional view showing a state in which an odor component adsorption layer of Example 1 of the present invention is applied to an oxide carrier.
【図２】本発明の実施例２の臭気成分の吸着・酸化層を
酸化物担体に施した状態を示した断面図FIG. 2 is a cross-sectional view showing a state in which an odorous component adsorption / oxidation layer of Example 2 of the present invention is applied to an oxide carrier.
【図３】本発明の実施例３の臭気成分の吸着層と酸化層
を酸化物担体に施した状態を示した断面図FIG. 3 is a cross-sectional view showing a state in which an odorous component adsorption layer and an oxidation layer of Example 3 of the present invention are applied to an oxide carrier.
【図４】本発明の実施例４のハニカム脱臭触媒の寿命を
示す特性図FIG. 4 is a characteristic diagram showing the life of the honeycomb deodorizing catalyst of Example 4 of the present invention.
【図５】本発明の実施例５のハニカム脱臭触媒を設置し
た空気清浄器の概略断面図FIG. 5 is a schematic cross-sectional view of an air purifier provided with a honeycomb deodorizing catalyst of Example 5 of the present invention.
【図６】本発明の実施例６のハニカム脱臭触媒を設置し
た空調機の概略断面図FIG. 6 is a schematic cross-sectional view of an air conditioner equipped with a honeycomb deodorizing catalyst of Example 6 of the present invention.
【図７】本発明の実施例７のハニカム脱臭触媒を設置し
た冷蔵庫の概略断面図FIG. 7 is a schematic cross-sectional view of a refrigerator equipped with a honeycomb deodorizing catalyst of Example 7 of the present invention.
１ ハニカム状の酸化物担体 ２ 吸着層 ３ 吸着・酸化層 ４ 酸化層 ５ 空気清浄器 ６，１２ 吸入口 ７，１３，２５ ハニカム脱臭触媒 ８，１５ 貫流ファン ９，１６ 排気口 １１ 空調機本体 １４ 熱交換器 ２１ 冷蔵庫本体 ２２ 冷凍室 ２３ 収納室 1 Honeycomb-shaped oxide carrier 2 Adsorption layer 3 Adsorption / oxidation layer 4 Oxidation layer 5 Air purifier 6,12 Inlet port 7,13,25 Honeycomb deodorizing catalyst 8,15 Cross-flow fan 9,16 Exhaust port 11 Air conditioner body 14 Heat exchanger 21 Refrigerator body 22 Freezing room 23 Storage room
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｂ０１Ｄ 53/81 53/86 (72)発明者 上野 孝浩 大阪府東大阪市高井田本通４丁目２番５号 松下冷機株式会社内 (72)発明者 伊藤 文弘 大阪府東大阪市高井田本通４丁目２番５号 松下冷機株式会社内 (72)発明者 橋本 一夫 大阪府東大阪市高井田本通４丁目２番５号 松下冷機株式会社内─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification number Reference number within the agency FI Technical indication location B01D 53/81 53/86 (72) Inventor Takahiro Ueno 4-2 Takaidahondori, Higashiosaka-shi, Osaka No. 5 In Matsushita Refrigerator Co., Ltd. (72) Inventor Fumihiro Ito 4-2-5 Takaidahondori, Higashiosaka-shi, Osaka Prefecture In Matsushita Refrigerator Co., Ltd. (72) Inventor Kazuo Hashimoto 4 Takaidamoto-dori, Higashi Osaka 2-5 Matsushita Cold Machinery Co., Ltd.
Claims (8)
を酸化物担体に施しており少なくとも活性アルミナとシ
リカとゼオライトからなることを特徴とする脱臭触媒。1. A deodorizing catalyst, characterized in that an oxide carrier is provided with a layer for adsorbing odorous components contained in the air, and is composed of at least activated alumina, silica and zeolite.
合してなる請求項１記載の脱臭触媒。2. The deodorizing catalyst according to claim 1, wherein PtO, CeO 2 , and PdO are mixed in the adsorption layer.
ージェライトよりなることを特徴とする請求項１記載の
脱臭触媒。3. The deodorizing catalyst according to claim 1, wherein the oxide carrier supporting the active ingredient is made of cordierite.
ナとシリカとゼオライトからなる吸着層と白金族金属か
らなる金属触媒層を含浸等の方法で吸着層表面に施した
ことを特徴とする請求項１記載の脱臭触媒。4. The surface of the oxide carrier is provided with an adsorption layer of at least activated alumina, silica and zeolite and a metal catalyst layer of platinum group metal on the surface of the adsorption layer by impregnation or the like. The deodorizing catalyst described.
が、ハニカム状、板状、３次元網目構造、粒状を有しカ
ートリッジタイプであることを特徴とする請求項１記載
の脱臭触媒。5. The deodorizing catalyst according to claim 1, wherein the oxide carrier supporting the active ingredient has a honeycomb shape, a plate shape, a three-dimensional network structure, and a granular shape, and is of a cartridge type.
入口と貫流ファンと吸入した空気を排気する排気口を具
備する空気清浄器において、吸入口と貫流ファンの空間
に、酸化物担体に活性成分が担持され、活性成分として
少なくとも活性アルミナとシリカとゼオライトとＰｔ
Ｏ，ＣｅＯ2 ，ＰｄＯからなる脱臭触媒を含む触媒層を
備えたことを特徴とする空気清浄器。6. An air purifier comprising an intake port for taking in air containing an odorous component, a cross-flow fan, and an exhaust port for exhausting the sucked air, wherein the oxide carrier has an active ingredient as an oxide carrier in the space of the intake port and the cross-flow fan. Supported, and at least active alumina, silica, zeolite, and Pt as active ingredients
An air purifier comprising a catalyst layer containing a deodorizing catalyst composed of O, CeO 2 , and PdO.
入口と、取り入れた空気を冷、暖房する熱交換器と冷、
暖房した空気を吸引、排気する貫流ファンと排気口を具
備した空調機器において、熱交換器の前段又は後段に、
酸化物担体に活性成分が担持され、活性成分として少な
くとも活性アルミナとシリカとゼオライトとＰｔＯ，Ｃ
ｅＯ2 ，ＰｄＯからなる脱臭触媒を含む触媒層を備えた
ことを特徴とする空調機器。7. An intake port for taking in air containing an odorous component, a heat exchanger for cooling and heating the taken-in air, and a cold box,
In an air conditioner equipped with a cross-flow fan that sucks in and exhausts heated air and an exhaust port, in the front or rear stage of the heat exchanger,
An active ingredient is supported on an oxide carrier, and at least active alumina, silica, zeolite, PtO, C as the active ingredient.
An air conditioner comprising a catalyst layer containing a deodorizing catalyst composed of eO 2 and PdO.
空間に、酸化物担体に活性成分が担持され、活性成分と
して少なくとも活性アルミナとシリカとゼオライトとＰ
ｔＯ，ＣｅＯ2 ，ＰｄＯからなる脱臭触媒を含む触媒層
を備えたことを特徴とする冷凍機器。8. In a refrigerating machine for circulating cold air, an active component is supported on an oxide carrier in a refrigerating space, and at least active alumina, silica, zeolite and P as active components.
A refrigerating machine comprising a catalyst layer containing a deodorizing catalyst composed of tO, CeO 2 , and PdO.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6286590A JPH08141404A (en) | 1994-11-21 | 1994-11-21 | Deodorization catalyst |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6286590A JPH08141404A (en) | 1994-11-21 | 1994-11-21 | Deodorization catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08141404A true JPH08141404A (en) | 1996-06-04 |
Family
ID=17706391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6286590A Pending JPH08141404A (en) | 1994-11-21 | 1994-11-21 | Deodorization catalyst |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH08141404A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001179040A (en) * | 1999-12-22 | 2001-07-03 | Matsushita Electric Works Ltd | Gas decomposer |
| CN112138706A (en) * | 2020-09-15 | 2020-12-29 | 大连理工大学 | Sulfur-tolerant hydrogenation catalyst for hydrogen transfer system and preparation method thereof |
-
1994
- 1994-11-21 JP JP6286590A patent/JPH08141404A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001179040A (en) * | 1999-12-22 | 2001-07-03 | Matsushita Electric Works Ltd | Gas decomposer |
| CN112138706A (en) * | 2020-09-15 | 2020-12-29 | 大连理工大学 | Sulfur-tolerant hydrogenation catalyst for hydrogen transfer system and preparation method thereof |
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