JPH08127514A - Make-up cosmetic - Google Patents

Abstract

PURPOSE: To prepare a make-up cosmetic not transferring a coating film of cosmetic to clothing, making a user wash face while wearing make-up. CONSTITUTION: This make-up cosmetic is obtained by strongly dispersing one or more kinds of powder of modified fine particles which are powders of fine particles having 5-100nm primary particle diameters and are subjected to surface treatment with a fluorine compound and an oily component containing trimethylsiloxysilicic acid and acrylic silicone strongly dispersing into a cyclic silicone-containing solvent and has 0-25% transfer ratio.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a make-up cosmetic which allows the face to be washed while applying makeup without the makeup coating film being transferred to clothes. More specifically, by using the cohesive force, the adhesive force and the adhesive force of the oily component of the fine particle powder, a film with a strong bond with the skin is formed and the transfer of the powder to clothes is suppressed. In addition, the present invention relates to makeup cosmetics for washing the face after sports with makeup applied.

[0002]

BACKGROUND OF THE INVENTION Foundations have conventionally been used as colorants such as iron oxide, concealing agents such as titanium oxide, extender pigments such as talc, functional powders such as resin powder and ultrafine titanium oxide. It consists of a body and oil.

These powders are fixed to the skin by the adhesive force of the powder itself and the binding force of the oil agent. However, their adhesive strength and bonding strength are generally weak,
It was not possible to prevent transfer of the decorative coating film to clothes or hands.

Particularly, when a plate-like powder such as talc is used, there is a problem that the transfer of the makeup coating film to clothes or hands increases.

In addition, even when a fluorine compound such as perfluoropolyether or fluorine-treated powder, which is often used in "lasting type" cosmetics in recent years, is used, the binding force between the powder and the skin is basically used. Was weak and could not prevent the transfer of the makeup coating film to clothes and hands.

On the other hand, the present inventors have found that in a slurry system in which fine particle powder is strongly dispersed in a solvent to form smaller secondary particles, strong aggregation of the fine particle powder occurs when the solvent evaporates. The use of force provides a strong bond between the skin and the pigment that replaces traditional binders,
By using this binding force, the makeup coating does not transfer to clothes,
It was found that a makeup cosmetic that can wash the face with makeup applied can be obtained.

Then, by using trimethylsiloxysilicic acid having a strong adhesive force and acrylic silicone as the oily component at the same time, and further using the modified fine particle powder surface-treated with a fluorine compound as the fine particle powder, It has been found that a makeup cosmetic in which the modified fine particle powder is fixed on the skin can be obtained.

Further, by blending a spherical resin powder having a specific particle diameter, it has succeeded in eliminating the tight feeling of the skin caused by trimethylsiloxysilicic acid and acrylic silicone.

Therefore, according to the present invention, by combining an oily component having a cohesive force of fine powder particles and a strong adhesive property with a fluorine compound having an excellent oil repellency, the makeup coating film does not transfer to clothes and the face is washed with makeup applied. The purpose of the present invention is to provide makeup cosmetics that can

[0010]

The present invention is a fine particle powder having a primary particle size in the range of 5 to 100 nm, the surface of which is one or more modified fine particle powders which are surface-treated with a fluorine compound. And a trimethylsiloxysilicic acid, an oily component containing acrylic silicone are strongly dispersed in a solvent containing a cyclic silicone, and the transfer rate is in the range of 0 to 25%. Regarding

That is, claim 1 of the present invention is a fine particle powder having a primary particle diameter in the range of 5 to 100 nm,
One or more modified fine particle powders whose surface has been surface-treated with a fluorine compound and an oily component containing trimethylsiloxysilicic acid and acrylic silicone are strongly dispersed in a solvent containing cyclic silicone, and transferred. The rate is 0-25%
It is a makeup cosmetic characterized by being in the range of.

According to claim 2 of the present invention, the primary particle size is 5 to 1
Fine particle powder in the range of 00 nm, one or more modified fine particle powders whose surface is surface-treated with a fluorine compound, and a spherical resin powder having an average primary particle diameter in the range of 0.1 to 1 μm At least one body and an oily component containing trimethylsiloxysilicic acid and acrylic silicone are strongly dispersed in a solvent containing cyclic silicone, and the transfer rate is 0.
It is a makeup cosmetic characterized by being in the range of -25%.

The structure of the present invention will be described in detail below. The fine particle powder used in the present invention has a primary particle diameter in the range of 5 to 100 nm. The primary particle size can be measured by observation with a transmission electron microscope (TEM) or scanning electron microscope (SE).
M) Use the particle size obtained from observation. When the shape of the fine particle powder is spherical, the diameter of the sphere is defined as the particle diameter, and when it is needle-shaped or rod-shaped, the minor diameter is defined as the particle diameter. In the case of an irregular type, the average particle size from the center is used as the particle size. Further, as the relationship between the particle size distribution and the primary particle size, when the particle size distribution is narrow, the average primary particle size may be used as the particle size. It is necessary to distinguish between the bodies.

In the fine particle powder used in the present invention, a powder having a primary particle size of less than 5 nm is not preferable because it is active and unstable and may cause problems such as alteration of cosmetics. If the primary particle size exceeds 100 nm, the surface-modified fine particle powder lacks in cohesive force, so that the amount to be blended must be limited.

The fine particle powder used in the present invention is preferably blended in the range of 20 to 100% by weight of the total powder blended in the makeup cosmetic.

The fine particle powder used in the present invention comprises a white powder and a colored powder. Examples of the white powder include titanium oxide, zinc oxide, aluminum oxide, silicon oxide (silicic anhydride), zirconium oxide, calcium carbonate, barium carbonate, barium sulfate and the like. It should be noted that the titanium oxide may be of a crystalline type such as rutile, anatase or amorphous, or an amorphous type. The colored powder may be an inorganic powder or an organic powder. For example, yellow iron oxide, red iron oxide, black iron oxide, iron-containing titanium oxide,
Low-order titanium oxide, cerium oxide, cobalt oxide, cobalt titanate, lithium cobalt titanate, titanium-titanium oxide sintered body, copper chlorophyll, porphyrin compound, gold, silver, platinum, carbon black, silicon carbide, organic pigment, Examples include organic dyes.

Each of these materials may be compounded or may be compounded with a powder of aluminum oxide, silicon oxide (silicic anhydride), zirconium oxide or the like. Further, surface treatment such as silicone treatment, silane coupling agent treatment, acylated lysine treatment, fatty acid treatment, metal soap treatment, amino acid treatment and the like may be performed.

Among these fine particle powders, colored powders such as iron oxide / titanium oxide sintered products and dye-dyed powders are preferable because color separation in cosmetics is less likely to occur. The shape is preferably spherical from the viewpoint of obtaining a strong cohesive force, but may be needle-shaped, rod-shaped, or amorphous.

Further, as an example of a method for producing fine particle powder,
Various methods such as a gas phase method, a liquid phase method and a plasma method can be mentioned, but any method may be used. Further, as a result of the difference in cohesive force between the fine particle powders depending on the manufacturing method, the secondary particle diameter is often greatly different. If it is within the specified range, the size of the secondary particle size does not matter.

In the makeup cosmetic of the present invention, among the above fine particle powders, at least one modified fine particle powder surface-treated with a fluorine compound is contained. As examples of the fluorine compound, conventionally known fluorine compounds can be used, and examples thereof include Teflon, perfluoroalkyl-modified organopolysiloxane, perfluoroalkyl phosphate, perfluoropolyether, fluorocarbon, fluorinated pitch, perfluoro. Examples thereof include alkyl / polyoxyalkylene co-modified organopolysiloxane, fluorinated fatty acid, perfluoroalcohol, fluorosilicone rubber, fluoroapatite, fluorinated acrylic resin, fluorinated methacrylic resin and the like.

Further, as a method for treating the fine particle powder, for example, in addition to the wet method, the vapor phase method, the dry method, the mechanochemical method and the like, a method using low temperature plasma and the like can be mentioned.

The treatment amount of the fluorine compound cannot be unconditionally shown because it varies depending on the specific surface area of the fine particle powder and the treatment method, but for example, it is 0.3 to 50 parts by weight with respect to 100 parts by weight of the fine particle powder. The range is mentioned. However,
If the oil repellency is low, the sebum resistance is weakened. Therefore, the minimum oil repellency is that the fine particle powder cannot be easily mixed when mixed with squalane.

In the makeup cosmetic of the present invention, the concept of "transfer rate" is proposed. The transfer rate referred to in the present invention indicates the degree to which a cosmetic transfers to another substance, and can be measured by the following method.

(Method of measuring transfer rate) Filter paper (manufactured by Toyo Roshi Kaisha, Ltd.
Two pieces of quantitative filter paper 5A (diameter 125 mm) are prepared, and 0.1 g of make-up cosmetics is evenly dropped or applied to the center of the filter paper A within a circle with a radius of 1.5 cm, and at 40 ° C. 1
After drying for 0 minutes, the L ^* value when the color of the central part is measured with a color difference meter is L1, and the L ^* value of the portion where the makeup cosmetic is not applied is L0. Then, insert another filter paper B into filter paper A.
Then, the filter paper A and the filter paper B are slowly moved by 3 cm while the weight of 1 kg is applied to the center of the filter paper B having a radius of 1.5 cm. L2 is the average value of the L ^* values when the filter paper A and the filter paper B were peeled off and the vicinity of the portion of the filter paper B that was in contact with the filter paper A and had the largest transfer amount was measured at several points. When the transfer rate is T (%), it can be expressed by T = [(L2-L0) / (L1-L0)] × 100.

When measuring the transfer rate, it should be noted that the data may differ depending on the colorimetric method. The inventor
Murakami Color Research Laboratory model CMS-1500 (measuring probe diameter 3 mm) is used to increase the number of samples and measurement points, and the average value is calculated. Also, 1
Be careful when applying a weight of kg, but it is preferable to use a rubber stopper or a silicone stopper having a diameter of 3 cm to apply the load. When a load is applied with metal, wood, hard plastic, or the like, the way the load is applied becomes uneven, and there is a problem that the value of the transfer rate tends to vary.

The range of the transfer rate used in the present invention is 0.
.About.25%. It is preferably 0 to 20%, more preferably 0 to 10%. Transfer rate is 25
When it exceeds%, there is a problem that the color is transferred to clothes.

In the makeup cosmetic of the present invention, various powders conventionally used in cosmetics can be used as powders other than the fine particle powder, and particularly the average primary particle diameter is 0. It is preferable to use spherical resin powder in the range of 0.1 to 1 μm. If the average primary particle size is less than 0.1 μm, there is a problem that the production of resin powder is difficult.
If it exceeds μm, there is a problem that the transfer rate increases. Examples of the spherical resin powder include nylon beads, silicone beads, urethane beads, Teflon beads, styrene beads, acrylic resin beads, silk powder, and the like, but nylon beads, silicone beads, and urethane beads are particularly preferable.

The compounding amount of the spherical resin powder is 1
The amount is preferably 0.5 to 10 parts by weight, more preferably 2 to 8 parts by weight, based on 00 parts by weight.

Examples of powders other than resin powders include yellow iron oxide, red iron oxide, black iron oxide, chromium oxide, cobalt oxide, ultramarine blue, navy blue, zinc oxide, titanium oxide, zirconia oxide, and silicon oxide. , Aluminum oxide, cerium oxide, titanium mica, barium sulfate, calcium carbonate, magnesium carbonate, aluminum silicate, magnesium silicate, pigment,
Examples include lake dyes, and surface treatments such as silicone treatment, fluorine compound treatment, silane coupling agent treatment, silane treatment, organic titanate treatment, acylated lysine treatment, fatty acid treatment, metal soap treatment, oil treatment, amino acid treatment and the like. You may give it. However, since plate-like minerals such as sericite reduce the transfer-preventing effect of the makeup cosmetics of the present invention, and also cause darkening, it is necessary to reduce the amount used. The amount of the plate-like mineral compounded is preferably 0 to 3 parts by weight, more preferably 0 part by weight, based on 100 parts by weight of the cosmetic.

Cyclic silicone is used as the solvent in the present invention. Examples of the cyclic silicone include octamethylcyclotetrasiloxane (a tetrameric cyclic silicone) and decamethylcyclopentasiloxane (a pentameric cyclic silicone).

Other solvent components include ethanol,
Lower alcohols such as isopropyl alcohol, isoparaffin, hexameric or higher cyclic silicones, tetramethyltetrahydrogencyclotetrasiloxane, ethers, LPG, fluorocarbons, N-methylpyrrolidone, fluoroalcohols, volatile linear silicones, etc. However, it is not particularly limited as long as it has a function as a solvent and there is no safety problem.

However, if water is contained, the growth rate of the film of the cosmetic material extends in the direction perpendicular to the skin, so that the transfer rate tends to increase. Therefore, the content of water is preferably 0 to 2 parts by weight, more preferably 0 part by weight, based on 100 parts by weight of the cosmetic. However, the water adsorbed on the fine particle powder and blended as a part of the fine particle powder is to be considered separately from this value.

The amount of the solvent component containing cyclic silicone is preferably 20 to 95 parts by weight, more preferably 30 to 100 parts by weight, based on 100 parts by weight of makeup cosmetics.
85 parts by weight.

The present invention requires a strong dispersion treatment in which fine powder particles are crushed by using a strong mechanical crushing force. That is, the fine particle powder usually forms a secondary agglomerate and is stabilized, and the cohesive force between particles is greatly reduced as compared with the primary particles alone. It is necessary to break this secondary agglomerate in order to give a stronger cohesive force when the cosmetic is used.

As a mechanical crushing method, a wet type crusher of continuous type and strong crushing force is generally preferable. For example, roller mill, paint conditioner, bead mill, sand mill, dyno mill, micros, diamond fine mill. An example is a device with a strong crushing power.
Examples of the pulverizing medium of the wet medium type pulverizer include alumina, zirconia, and glass beads, but are not particularly limited.

In addition, as a method for producing a makeup cosmetic of the present invention, a strongly dispersed slurry or paste for each color of fine particle powder is prepared, and the mixture is mixed by changing the mixing ratio for each color of the product. The method is preferred.

In the present invention, in addition to powders, oils, surfactants, ultraviolet absorbers, adhesives, bactericides, preservatives, antioxidants, anti-inflammatory agents, vitamins, fragrances, etc., which have been used in cosmetics in the past. It is possible to mix pigments and dyes. here,
Of the various components that are blended in cosmetics, powder, fine particle powder,
The components other than the solvent, the dye, and the dye are collectively called the oily component.

The mixing ratio of the powder component such as fine particle powder, resin powder and powder and the oil component is, for example, powder component 1
The oil component is preferably 1 to 100 parts by weight, more preferably 5 to 40 parts by weight, based on 00 parts by weight.

In the present invention, the oily components include trimethylsiloxysilicic acid and acrylic silicone. The total compounding amount of trimethylsiloxysilicic acid and acrylic silicone is 2 to 4 with respect to 100 parts by weight of makeup cosmetics.
It is preferably 0 part by weight. Trimethylsiloxysilicic acid and acrylic silicone help fix the powder, and acrylic silicone has a weak nonionic surface-active function, so it helps prevent the powder from aggregating in the solvent. Here, if it is 2 parts by weight or more, the ability to fix the powder is excellent, and if it is 40 parts by weight or less, the tackiness and
It is preferable in terms of feel.

The trimethylsiloxysilicic acid and acrylic silicone used in the present invention are preferably those dissolved in a solvent such as cyclic silicone or isoparaffin.

The acrylic silicone used in the present invention refers to organopolysiloxanes in which an organic functional group having an acrylic group and / or a methacrylic group is introduced into the side chain and / or terminal of a siloxane chain, and the molecular weight and modification rate are not particularly limited. Not done. Here, the modification rate refers to the ratio of the number of siloxanes introduced with an organic functional group to the total number of siloxanes. As the acrylic silicone, it is possible to use the one that has been conventionally used for hair setting agents etc. as it is, but since the offensive odor caused by the impurities derived from the organic functional group becomes a problem, the operation for reducing the impurities is performed. Preferably.

Examples of other oily components include higher alcohols such as cetyl alcohol, isostearyl alcohol, lauryl alcohol, hexadecyl alcohol and octyldodecanol, fatty acids such as isostearic acid, undecylenic acid and oleic acid, glycerin and sorbitol. , Polyhydric alcohols such as ethylene glycol, propylene glycol, polyethylene glycol, myristyl myristate, hexyl laurate, decyl oleate, isopropyl myristate, hexyldecyl dimethyloctanoate, glyceryl monostearate, diethyl phthalate, ethylene monostearate Glycol,
Esters such as octyl oxystearate, hydrocarbons such as liquid paraffin, petrolatum and squalane, waxes such as lanolin, reduced lanolin and carnauba wax, mink oil,
Examples thereof include cocoa butter, coconut oil, palm kernel oil, camellia oil, sesame oil, castor oil, olive oil and other oils and fats, ethylene / α-olefin / co-oligomers and the like.

As another example of the oily component in another form,
For example, dimethylpolysiloxane, methylhydrogenpolysiloxane, methylphenylpolysiloxane, polyoxyalkylene-modified organopolysiloxane, perfluoroalkyl / polyoxyalkylene co-modified organopolysiloxane, alkyl-modified organopolysiloxane, terminal-modified organopolysiloxane, fluorine Modified organopolysiloxane, amodimethicone, amino modified organopolysiloxane, silicone gel, acrylic silicone, trimethylsiloxysilicic acid, silicone RTV
Examples thereof include silicone compounds such as rubber and fluorine compounds such as perfluoropolyether, fluorinated pitch, fluorocarbon and fluoroalcohol.

Examples of the surfactant include anionic surfactant, cationic surfactant, nonionic surfactant,
Although a betaine-type surfactant can be used, it is preferable not to use it because it reduces sebum resistance and sweat resistance.

Examples of organic UV absorbers include para-aminobenzoic acid (hereinafter referred to as PABA), 2-ethylhexyl para-methoxycinnamate, 2-ethylhexyl para-dimethylaminobenzoate, 2-hydroxy-4-methoxybenzophenone, and the like. 2-hydroxy-4-methoxybenzophenone-5-sulfuric acid, 2,2'-dihydroxy-
4-methoxybenzophenone, p-methoxyhydrocinnamic acid diethanolamine salt, ethyldihydroxypropyl PABA, glyceryl PABA, homomenthyl salicylate, methyl-O-aminobenzoate, 2-ethylhexyl-2-cyano-3,3-diphenylacrylate, octyldimethyl. PABA, octyl methoxycinnamate, octyl salicylate, 2-phenyl-benzimidazole-5-sulfate, triethanolamine salicylate, 3- (4-methylbenzylidene) camphor, 2,4
-Dihydroxybenzophenine, 2,2 ', 4,4'-
Tetrahydroxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2-hydroxy-4-N-octoxybenzophenone, 4-isopropyldibenzoylmethane, butylmethoxydibenzoylmethane, 4- (3,4 -Dimethoxyphenylmethylene) -2,5-dioxo-1-imidazolidine propionate 2-ethylhexyl (soft shade DH,
Ajinomoto) and the like.

Among these oily components, in addition to trimethylsiloxysilicic acid and acrylic silicone, HLB value of 0.5
~ 6 polyoxyalkylene-modified organopolysiloxane, HLB value 0.5-6 perfluoroalkyl / polyoxyalkylene co-modified organopolysiloxane, dimethylpolysiloxane, methylphenylpolysiloxane,
It is preferable to mix one or more selected from silicone raw rubber, fluorine-modified organopolysiloxane, petrolatum, squalane, octyl oxystearate, ethylene / α-olefin / co-oligomer, and organic UV absorber into the makeup cosmetic composition. These oily components have a strong tendency to reduce the transfer rate and enhance the ultraviolet protection effect, as compared with other oily components. Here, when the HLB value is 0.5 or more, the function as a modified silicone is remarkable, and the HL
When the B value is 6 or less, the water resistance is excellent.

Examples of the makeup cosmetics of the present invention include foundations, makeup bases, eyeshadows, mascaras, correction cosmetics such as filter colors, sunscreens and the like, but sports applications are particularly preferable. Furthermore, local dyeing (fashion dyeing) is also possible. The form of the cosmetic may be liquid, spray, or mousse.

The make-up cosmetic composition of the present invention forms a dense film on the skin, and therefore has a higher UV protection effect than conventional products. Therefore, depending on the prescription, S
The PF value can be set.

[0049]

The present invention will be described in detail below with reference to Examples and Comparative Examples. The evaluation methods of the examples and comparative examples used in the present invention are as follows.

Measurement of Transfer Rate The method of measuring the transfer rate is as described above.

Sensory evaluation Twenty female panelists aged 20 to 40 were made to use the cosmetics prepared in the examples and comparative examples, and the transferability of the cosmetics to tissue paper and whether or not it was possible to wash the face only with water We obtained responses in a questionnaire format for two items. Before using the cosmetic, a double face wash was performed, and then the prototype was evaluated with the skin being dry.

The transferability to tissue paper (tissue-off property) was used as an index of transferability by using the total number of panelists who answered that transfer was difficult or difficult. Therefore, it is indicated that the larger the number, the more difficult the transfer is.

As for the face-washing property, whether or not the face-washing with water alone is possible is not felt after the face-washing.
The number of panelists who answered that was used as an index of facial cleansing property. Therefore, the larger the number is, the more the face can be washed.

Example 1, Comparative Examples 1 to 3 (foundation)

Example 1 A sample was prepared according to the formulation shown in Table 1. However, as the PF-treated pigment used below, a PF-treated pigment that had been surface-treated with a perfluoroalkyl phosphate ester diethanolamine salt at a pigment weight ratio of 5% was used.

[0056]

[Table 1]

Note: X-22-8011 manufactured by Shin-Etsu Chemical Co., Ltd.
The acrylic silicone has a pure content of 30% by weight, and the rest is decamethylcyclopentasiloxane. Therefore, the pure compounding amount of acrylic silicone in Table 1 is 6 parts.

(Manufacturing Method) The mixture of each component was strongly dispersed using a paint conditioner, and then filled in a closed container together with a stainless ball to obtain a product.

Comparative Example 1 (Example in which Fine Particle Titanium Oxide is not Used) The composition shown in Table 2 was used.

[0060]

[Table 2]

(Manufacturing Method) A mixture of each component was strongly dispersed using a paint conditioner, and then filled in a closed container together with stainless balls to obtain a product.

Comparative Example 2 (Example in which fine particle titanium oxide is not used, but trimethylsiloxysilicic acid and acrylic silicone are used) A formulation of Table 3 was prepared.

[0063]

[Table 3]

(Manufacturing Method) A mixture of each component was strongly dispersed using a paint conditioner, and then filled in a closed container together with stainless balls to obtain a product.

Comparative Example 3 (example in which fluorinated fine particle powder is used, but trimethylsiloxysilicic acid and acrylic silicone are not used) A formulation of Table 4 was prepared.

[0066]

[Table 4]

(Manufacturing Method) A mixture of each component was strongly dispersed using a paint conditioner, and then filled in a closed container together with stainless balls to obtain a product.

Table 5 shows the transfer rate measurement results for Example 1 and Comparative Examples 1 to 3.

[0069]

[Table 5]

[0070]

[Table 6]

From the results of Tables 5 and 6, it can be seen that the examples of the present invention have lower transfer rates than the comparative examples.
Comparative Example 1 shows an example in which the particulate titanium oxide is not used but the plate-like powder is used, but the transferability and the face washing property are poor. Further, in Comparative Example 2, in order to investigate the influence of trimethylsiloxysilicic acid and acrylic silicone, the same compounding amount as that in the Example was set. Although the transfer rate was certainly low, it was found that the transfer rate was not reached. Further, in Comparative Example 3, although the fluorine-treated fine particle powder was used, the influence when trimethylsiloxysilicic acid and acrylic silicone were not used was examined. Since the fluorine-treated powder has oil repellency, it has been found that the transferability becomes high unless a film forming agent such as trimethylsiloxysilicic acid or acrylic silicone is used.

[0072]

From the above, it is clear that the present invention provides a makeup cosmetic that allows the face to be washed with makeup without transferring the makeup coating to clothes.

Continuation of front page (51) Int.Cl. ⁶ Identification code Office reference number FI Technical display area A61K 7/48

Claims (3)

[Claims] 1. A fine particle powder having a primary particle diameter in the range of 5 to 100 nm, the surface of which is one or more modified fine particle powders, and trimethylsiloxysilicic acid or acrylic. An oily component containing silicone is strongly dispersed in a solvent containing cyclic silicone,
Also, a makeup cosmetic having a transfer rate in the range of 0 to 25%. 2. A fine particle powder having a primary particle diameter in the range of 5 to 100 nm, wherein the surface of the fine particle powder is one or more modified fine particle powders, and the average primary particle diameter is 0. One or more spherical resin powders in the range of 1 to 1 μm and an oily component containing trimethylsiloxysilicic acid and acrylic silicone are strongly dispersed in a solvent containing cyclic silicone, and the transfer rate is 0 to 25. Makeup cosmetics characterized by being in the range of%. 3. An oil component other than trimethylsiloxysilicic acid and acrylic silicone is a polyoxyalkylene-modified organopolysiloxane having an HLB value of 0.5 to 6, HLB.
Perfluoroalkyl / polyoxyalkylene co-modified organopolysiloxane having a value of 0.5 to 6, dimethylpolysiloxane, methylphenylpolysiloxane, silicone raw rubber, fluorine-modified organopolysiloxane, petrolatum, squalane, octyl oxystearate, ethylene / α -Makeup cosmetics according to claim 1 or 2, comprising at least one selected from olefin / co-oligomers and organic UV absorbers.