JPH08118105A - Surface-coated cemented carbide alloy cutting tool with tungsten carbide group having hard coating layer excellent in interlayer adhesion - Google Patents

Abstract

PURPOSE: To provide a coated cemented carbide alloy cutting tool having hard coating layers excellent in interlayer adhesion. CONSTITUTION: In a coated cemented carbide alloy cutting tool, the surface of a cemented carbide alloy base body comprises a first layer, TiN layer with granulated crystal structure, a second layer, TiCN layer with longitudinal growth crystal structure, a third layer, TiCO or TiCNO layer with granulated crystal structure, and a forth layer, Al2 O3 with structure mainly comprising copper type granulated crystal, and in addition, a fifth layer, TiN layer with granulated crystal structure when necessary. In addition, a hard coating layer, in which at least W and Co out of the components composing the base body of the grain boundaries of the first and second layers are diffusively contained, has layer thickness of 3 to 30μm in average.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention has a hard coating layer having excellent interlayer adhesion, and therefore exhibits excellent cutting performance over a long period of time when used for cutting, for example, mild steel having a large cutting resistance. The present invention relates to a surface-coated tungsten carbide based cemented carbide cutting tool (hereinafter referred to as a coated cemented carbide cutting tool).

[0002]

2. Description of the Related Art Conventionally, as described in Japanese Patent Publication No. 57-1585 and Japanese Patent Publication No. 59-52703, for example, an entirely homogeneous tungsten carbide based cemented carbide substrate and a binder phase forming component have been used. For example, a tungsten carbide based cemented carbide substrate having a surface portion in which the content of Co or the like is relatively high compared to the inside of the substrate, that is, a surface portion having a binder phase enriched zone (hereinafter, these are collectively referred to as cemented carbide substrate. On the surface of the titanium nitride (hereinafter referred to as TiN), the second layer of titanium carbonitride (hereinafter referred to as TiCN), and the titanium carbonate (to Less than,
TiCO) or titanium oxycarbonitride (hereinafter TiC)
A hard coating layer comprising a third layer of NO), a fourth layer of aluminum oxide (hereinafter referred to as Al ₂ O ₃ ) and, if necessary, a fifth layer of TiN, has an average layer thickness of 3 to 30 μm. It is well known that the coated cemented carbide cutting tool formed in (4) is mainly used for machining of alloy steel and cast iron and milling.

[0003]

On the other hand, in recent years, the use of FA in cutting machines has been remarkable, and in conjunction with the demand for labor saving in cutting work, cutting tools tend to be required to be versatile. For carbide cutting tools, there is no problem if this is used for cutting alloy steel or cast iron, etc.
Particularly when used for cutting mild steel with high cutting resistance, the interlayer adhesion of the hard coating layer is not sufficient, so that the hard coating layer is liable to delamination and chipping, which causes a relatively short service life. At present.

[0004]

Therefore, the present inventors have
From the viewpoints described above, as a result of focusing on the above-mentioned conventional coated carbide cutting tool and conducting a study for improving the interlayer adhesion of the hard coating layer constituting the same, (a) the above conventional coated carbide In the hard coating layer constituting the cutting tool, the adhesion of the TiN layer of the first layer to the cemented carbide substrate is extremely high, but the adhesion between the constituent layers is low, which causes delamination and chipping. It is likely to occur. (B) In the hard coating layer constituting the conventional coated carbide cutting tool, the first TiN layer and the second TiCN layer
The layer, the TiCO layer and the TiCNO layer of the third layer, and the TiN layer of the fifth layer formed as necessary all have a granular crystal structure, and the Al ₂ O ₃ layer of the fourth layer has an alpha type crystal structure. However, the TiCN layer of the second layer has a vertically elongated crystal structure, and the Al ₂ O ₃ layer of the fourth layer has a structure mainly composed of kappa-type crystals, preferably 50% by volume or more of kappa-type crystals. Occupying, and the remainder having a mixed structure from alpha-type crystals, and more preferably a structure substantially consisting of kappa-type crystals, the T of the first layer with respect to the second layer is
iN layer, third TiCO layer, and TiCNO layer, and third TiCO layer for the fourth layer, TiCN
The adhesiveness of the O layer and the TiN layer of the fifth layer is remarkably improved. (C) After forming the second TiCN layer, 10 to 100 to
1 to 5 at a temperature of 850 to 1100 ° C. in a hydrogen atmosphere of rr
When the heat treatment is performed under the condition of holding time, at least W and Co components among the components constituting the cemented carbide substrate diffuse and move to the grain boundaries of the first and second layers due to the capillary phenomenon, and At least W and Co are contained also in the grain boundaries of the above, and as a result, the interlayer adhesion is further improved in combination with the improvement of the inter-grain adhesion. The research results shown in (a) to (c) above were obtained.

The present invention has been made on the basis of the above-mentioned research results, and a first layer of TiN layer, a second layer of TiCN layer, a third layer of TiCO layer or a third layer of TiCO layer is formed on the surface of a cemented carbide substrate. A TiCNO layer, a fourth layer Al ₂ O ₃ layer, and if necessary, a hard coating layer formed of a TiN layer of a fifth layer with an average layer thickness of 3 to 30 μm, in a coated carbide cutting tool, (A) The first layer, the third layer, and the fifth layer have a granular crystal structure, the second layer has a vertically elongated crystal structure, and the fourth layer has a structure mainly composed of kappa-type crystals, and (B) The crystal grain boundaries of the first layer and the second layer contain at least W and Co of the components constituting the cemented carbide substrate, and the hard coating according to (a) and (b) above. Coated carbide cutting with excellent adhesion between layers Again and again it has the characteristics.

The TiCN layer having the longitudinal crystal structure of the second layer of the hard coating layers constituting the coated cemented carbide cutting tool of the present invention is as described in, for example, JP-A-6-8010. A) the reaction gas composition, in volume%, TiCl _4: 1 to 4
_{%, CH 3 CN: 0.1~5%} , N 2: 0~35
%, H ₂ : remaining, (a) reaction temperature: 850 to 950 ° C., and (c) atmosphere pressure: 30 to 200 torr. On the other hand, TiC having a granular crystal structure
The N layer is usually (a) with a reaction gas composition and volume% of TiCl ₄ : 1 to 5
_{%, CH 4: 2~7%,} N 2: 15~30%,
H ₂ : Remaining, (a) Reaction temperature: 950 to 1050 ° C., (c) Atmospheric pressure: 30 to 200 torr. Further, the Al ₂ O ₃ layer having a structure mainly composed of copper-type crystals has (a) a reaction gas composition and a volume% at an initial stage of 1 to 12
0 _{minutes, AlCl 3: 1~20%, H} 2: remainder, _{or,, AlCl 3: 1~20%,} HCl: 1~20% and / or _{H 2 S: 0.05~5%, H} 2: and the rest, and, _{thereafter, AlCl 3: 1~20%, CO} 2: 0.
5 to 30%, H ₂ : remaining, or AlCl ₃ : 1 to 2
_{0%, CO 2: 0.5~30%} , HCl: 1~20
% And / or H ₂ S: 0.05 to 5%, H ₂ : remaining, (a) reaction temperature: 850 to 1000 ° C., (c) atmosphere pressure: 30 to 200 torr.

Further, the hard coating layer constituting the coated cemented carbide cutting tool of the present invention is formed on the surface of the cemented carbide substrate by the chemical vapor deposition method and / or the physical vapor deposition method under the above-mentioned conditions and ordinary conditions. First, the first TiN layer is vapor-deposited, then the second
The TiCN layer of the fourth layer to the Al ₂ O ₃ layer of the fourth layer are further formed by sequentially vapor-depositing the TiN layer of the fifth layer, if necessary. In some cases, the C component in the cemented carbide substrate may diffuse and form a solid solution in the TiN layer of the layer. In this case, part or all of the first layer becomes TiCN.

Further, the average layer thickness of the hard coating layer is 3 to
The value of 30 μm is set so that the desired excellent wear resistance cannot be ensured when the average layer thickness is less than 3 μm, while the fracture resistance sharply decreases when the average layer thickness exceeds 30 μm. The average layer thickness of the first TiN layer is 0.1 to 5 μm, that of the second TiCN layer is 3 to 20 μm, and that of the third TiCO layer or TiCNO layer is 0. 01 to 2 μm, Al of the fourth layer
_It is desirable that the ₂ O ₃ layer has an average layer thickness of 0.1 to 15 μm, and the fifth TiN layer has an average layer thickness of 0.1 to 5 μm.

[0009]

Next, the coated carbide cutting tool of the present invention will be described in detail with reference to examples. As the raw material powder, a medium-grain WC powder having an average particle diameter of 3 μm and a coarse-grain WC having the same particle diameter of 5 μm
Powder, 1.5 μm (Ti, W) C (weight ratio, same below, TiC / WC = 30/70) powder, 1.2 μm
(Ti, W) CN (TiC / TiN / WC = 24/2)
0/56) powder and Co powder of 1.2 μm were prepared, these raw material powders were compounded to the compounding composition shown in Table 1, wet-mixed for 72 hours with a ball mill, dried, and then I
SO / CNMG120408 (for cemented carbide substrates A to D)
And SEEN42AFTN1 (for cemented carbide substrate E)
Cemented carbide base bodies A to E were manufactured by press-molding into a green compact having the shape defined in 1. and vacuum sintering the green compact under the conditions shown in Table 1. Further, the above cemented carbide substrate B was kept at a temperature of 1400 ° C. for 1 hour in a CH ₄ gas atmosphere of 100 torr and then subjected to carburizing treatment by slow cooling. After the treatment, carbon and Co attached to the substrate surface were removed. 1 from the surface by removing with acid and barrel polishing
Maximum Co content at 0 μm: 15% by weight, depth: 4
A Co enriched zone of 0 μm was formed on the substrate surface. Also,
In the cemented carbide substrates A and D, as-sintered, a Co-enriched zone having a maximum Co content of 9 wt% and a depth of 20 μm was formed on the surface at a position of 15 μm from the surface, The remaining cemented carbide substrates C and E did not have the Co-enriched zone formed and had an overall homogeneous structure. Further, Table 1 shows the internal hardness (Rockwell hardness A scale) of each of the cemented carbide substrates AE.

Then, the surfaces of these cemented carbide substrates A to E were subjected to honing, using a conventional chemical vapor deposition apparatus, under the conditions shown in Table 2 under the conditions shown in Table 2 and the compositions shown in Tables 3 to 6 A crystalline structure and a hard coating layer having an average layer thickness are formed, and after that, a heat treatment is performed in a hydrogen atmosphere of 35 torr at a temperature of 1050 ° C. for a predetermined time within a range of 1 to 5 hours after forming the second layer. Thus, the coated carbide cutting tools 1 to 7 of the present invention were manufactured, and the conventional coated carbide cutting tools 1 to 7 were manufactured without performing the heat treatment. Regarding the first and second hard coating layers constituting the various coated carbide cutting tools obtained as a result, each layer is observed with a transmission electron microscope (TEM), and 5 grain boundaries are appropriately specified for each layer. Then, the W and Co contents of this specific grain boundary were quantitatively analyzed by an energy dispersive X-ray measuring device. The results are shown in Tables 3 to 6 as average values.

Further, the above coated carbide cutting tools 1 to 5 of the present invention.
For the conventional coated carbide cutting tools 1 to 5, the conditions of work material: round bar of mild steel, cutting speed: 335 m / min., Feed: 0.26 mm / rev., Depth of cut: 2 mm, cutting time: 20 minutes Continuous cutting test of mild steel at, and work material: square bar of mild steel, cutting speed: 305 m / min., Feed: 0.26 mm / rev., Depth of cut: 1.5 mm, cutting time: 25 minutes The mild steel was subjected to an intermittent cutting test, and the flank wear width of the cutting edge was measured in each cutting test. The results of these measurements are shown in Tables 4 and 6. Further, regarding the coated carbide cutting tools 6 and 7 of the present invention and the conventional coated carbide cutting tools 6 and 7, the work material: square bar of mild steel, cutting speed: 305 m / min., Feed: 0.36 mm / blade, cutting Milling of mild steel was performed under the following conditions: 2.5 mm, cutting time: 30 minutes, and the flank wear width of the cutting edge was measured. The measurement results are also shown in Tables 4 and 6.

[0012]

[Table 1]

[0013]

[Table 2]

[0014]

[Table 3]

[0015]

[Table 4]

[0016]

[Table 5]

[0017]

[Table 6]

[0018]

From the results shown in Tables 3 to 6, the coated carbide cutting tools 1 to 7 of the present invention are not susceptible to delamination or chipping of the hard coating layer despite the cutting of mild steel having high cutting resistance. While it does not occur and shows excellent wear resistance,
Conventionally, the coated carbide cutting tools 1 to 7 clearly show that the interlayer adhesion in the hard coating layer is insufficient, and delamination and chipping occur in the cutting of mild steel, resulting in a relatively short service life. is there. As described above, the coated cemented carbide cutting tool according to the present invention has a hard coating layer having excellent interlayer adhesion, so that it can cut not only alloy steel and cast iron, but also mild steel having a high cutting resistance. Even when used for cutting, excellent cutting performance is exhibited over a long period of time.

Claims (2)

[Claims] 1. A first layer of titanium nitride, titanium carbonitride, on the surface of a wholly homogeneous tungsten carbide-based cemented carbide substrate or a tungsten carbide-based cemented carbide substrate having a binder phase enriched zone on its surface. Surface-coated tungsten carbide-based cemented carbide formed by forming a hard coating layer having an average layer thickness of 3 to 30 μm, the hard coating layer including a second layer of, a third layer of titanium carbonate or titanium oxycarbonitride and a fourth layer of aluminum oxide. In an alloy cutting tool, (a) the first layer and the third layer have a granular crystal structure, the second layer has a vertically elongated crystal structure, and the fourth layer has a structure mainly composed of copper crystals, and b) The hard coating layer is characterized in that at least W and Co of the components constituting the substrate are diffused and contained in the crystal grain boundaries of the first layer and the second layer, and the hard coating layer has excellent interlayer adhesion. Surface coated tongue carbide Cutting tool made of gusten base cemented carbide. 2. A titanium nitride first layer, titanium carbonitride, on the surface of an entirely homogeneous tungsten carbide based cemented carbide substrate or a tungsten carbide based cemented carbide substrate having a binder phase enriched zone on the surface. Second layer of titanium dioxide, a third layer of titanium carbonate or titanium oxycarbonitride, and a fourth layer of aluminum oxide.
Layer, and a hard coating layer consisting of a fifth layer of titanium nitride.
A surface-coated tungsten carbide-based cemented carbide cutting tool formed to have an average layer thickness of ˜30 μm, wherein (a) the first layer, the third layer, and the fifth layer have a granular crystal structure, and the second layer. Is a vertically elongated crystal structure, the fourth layer has a structure mainly composed of copper crystals, and (b) at least one of the components constituting the substrate is present at the crystal grain boundaries of the first layer and the second layer. W and Co are diffused and contained. A surface-coated tungsten carbide-based cemented carbide cutting tool having excellent hard coating layer interlayer adhesion.