JPH08112584A - Granular composite material, its secondary worked body and their production - Google Patents

Granular composite material, its secondary worked body and their production

Info

Publication number
JPH08112584A
JPH08112584A JP25070694A JP25070694A JPH08112584A JP H08112584 A JPH08112584 A JP H08112584A JP 25070694 A JP25070694 A JP 25070694A JP 25070694 A JP25070694 A JP 25070694A JP H08112584 A JPH08112584 A JP H08112584A
Authority
JP
Japan
Prior art keywords
composite material
less
granular
secondary processed
granular composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP25070694A
Other languages
Japanese (ja)
Other versions
JP3210813B2 (en
Inventor
Ikushi Tsujita
育司 辻田
Takuji Kajiwara
拓治 梶原
Osamu Yamase
修 山瀬
Toru Naruse
徹 成瀬
Shinji Matsuhiro
真治 松廣
Taketsugu Sugiguchi
剛継 杉口
Hiroshi Sarai
寛 皿井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHIYUUGAI KK
Toyota Motor Corp
Original Assignee
CHIYUUGAI KK
Toyota Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHIYUUGAI KK, Toyota Motor Corp filed Critical CHIYUUGAI KK
Priority to JP25070694A priority Critical patent/JP3210813B2/en
Publication of JPH08112584A publication Critical patent/JPH08112584A/en
Application granted granted Critical
Publication of JP3210813B2 publication Critical patent/JP3210813B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/52Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Landscapes

  • Processing Of Solid Wastes (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

PURPOSE: To produce a granular composite material capable of recycling materials from scrap and a secondary worked body of the composite material. CONSTITUTION: Shredder dust of scrap as starting material is freed of metals and passed through a crusher and a sieving machine to produce the objective granular composite material 1 having <=0.3g/cm<3> bulk density and about 10-20m/m size. The granular composite material 1 is caked with a fibrous thermoplastic resin 7 as a binder to produce the objective secondary worked body 6.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、廃材(たとえば、廃自
動車)のシュレッダーダスト(シュレッダーにかけられ
なくてもシュレッダーダスト程度のサイズにされたダス
トを含む、以下同じ)から材料リサイクルした、粒状複
合材料とその二次加工体(粒状複合材料を固めて固形体
としたもの)およびそれらの製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a granular composite material obtained by recycling materials from shredder dust (including scraps sized as shredder dust even if they are not shredded, the same applies hereinafter) of waste materials (for example, scrapped automobiles). The present invention relates to a material, a secondary processed body thereof (a solid material obtained by solidifying a granular composite material), and a manufacturing method thereof.

【0002】[0002]

【従来の技術】廃材の材料リサイクルは、たとえば実開
平5−85629号公報等で提案されている。廃材、と
りわけ廃車のシュレッダーダストのように、多種類の材
料を含む廃材は、従来、図12に示すように、鉄、非鉄
金属の回収が主目的とされ、残りのプラスチック、ゴ
ム、ウレタン、繊維等はその材料の多様性から材料リサ
イクルは無理と考えられ、専ら埋立て処分または焼却処
分されていた。
2. Description of the Related Art Material recycling of waste materials has been proposed, for example, in Japanese Utility Model Publication No. 5-85629. Waste materials containing various kinds of materials, such as waste materials, especially shredder dust of scrap vehicles, have conventionally been mainly aimed at recovering ferrous and non-ferrous metals as shown in FIG. 12, and the remaining plastic, rubber, urethane, and fibers. It was considered impossible to recycle materials due to the variety of materials, and they were disposed of in landfills or incinerated.

【0003】[0003]

【発明が解決しようとする課題】廃車シュレッダーダス
トのうちサイズが20mm以上のものの重量比率は図1
0に示す通りであり、サイズが20mm以上のものの容
積比率は図11に示す通りである。したがって、金属類
は重量では10%を占めていても容積にすると1%以下
であり、ほとんどすべてが、プラスチック、ゴム、ウレ
タン、繊維である。そして、廃車シュレッダーダストの
年間発生量は、1台当り165kg、年に500万台廃
車になるとして825、000トン/年にもなり、それ
らを埋立処分、焼却処分にすると埋立地の不足、CO2
等の多量発生という問題を生じる。本発明の目的は、シ
ュレッダーダストのうち金属を除いたもの、すなわちプ
ラスチック、ゴム、ウレタン、繊維を含むものを、他の
物の材料に利用できるように材料リサイクルした粒状複
合材料とその二次加工体、およびそれらの製造方法を提
供することにある。
The weight ratio of the scrapped car shredder dust having a size of 20 mm or more is shown in FIG.
0, and the volume ratio of those having a size of 20 mm or more is as shown in FIG. Therefore, even if metal accounts for 10% by weight, it is 1% or less by volume, and almost all are plastics, rubbers, urethanes, and fibers. The annual amount of scrapped vehicle shredder dust is 165 kg per vehicle, which amounts to 825,000 tons / year if 5 million vehicles are scrapped per year. If they are landfilled or incinerated, a shortage of landfills, CO 2
And the like occur in large numbers. The object of the present invention is to recycle granular shredder dust excluding metal, that is, plastic, rubber, urethane, and fibers so that it can be used as a material for other materials and its secondary processing. It is to provide a body and a manufacturing method thereof.

【0004】[0004]

【課題を達成するための手段】上記目的を達成するため
の本発明は次の通りである。 (1) シュレッダーダストを原材料とし、ウレタン、
繊維、プラスチック、ゴムを主成分とし、サイズが約1
0〜20mm以下の各種サイズとされ、嵩密度が0.3
g/cm3 以下に管理されている粒状複合材料。 (2) サイズが約10〜20mm以上のシュレッダー
ダストを複合材料の原材料に選定し、前記シュレッダー
ダストから、鉄、非鉄金属、ワイヤハーネスを選別除去
して、ウレタン、繊維、プラスチック、ゴムを主成分と
する軽い材料の混合物を選別し、前記軽い材料の混合物
を粉砕機により粉砕して前記約10〜20mmのサイズ
以下の各種のサイズとすることにより嵩密度が0.3g
/cm3 以下の基材とする、工程からなる粒状複合材料
の製造方法。 (3) 前記嵩密度が0.3g/cm3 以下の基材を、
さらに篩にかけて、篩上のウレタン、繊維を主成分とす
る軽いものと篩を通過したプラスチック、ゴムを主成分
とするやや重いものに大別する、工程をさらに有する
(2)記載の粒状複合材料の製造方法。 (4) シュレッダーダストを原材料とし約10〜20
mm以下の各種サイズに粉砕され嵩密度が0.3g/c
3 以下の粒状複合材料と、該粒状複合材料を固めて所
定形状の固形体となしている樹脂材と、から成る複合材
料二次加工体。 (5) 前記樹脂材が繊維状の熱可塑性樹脂材である
(4)記載の複合材料二次加工体。 (6) 前記樹脂材が粒状複合材料とつなぎ材とからな
る(4)記載の複合材料二次加工体。 (7) 前記樹脂材が複合繊維である(4)記載の複合
材料二次加工体。 (8) 前記樹脂材が複合繊維であり、前記固形体が自
動車防音材である(4)記載の複合材料二次加工体。 (9) 前記樹脂材がウレタン系接着剤であり、前記固
形体がU字溝である(4)記載の複合材料二次加工体。 (10) シュレッダーダストを原材料とし約10〜2
0mm以下の各種サイズに粉砕され嵩密度が0.3g/
cm3 以下の粒状複合材料と樹脂材とを混合し、該粒状
複合材料と樹脂材との混合物を加熱、固化して所定形状
の固形体となす、工程からなる複合材料二次加工体の製
造方法。 (11) さらに、前記固形体を、目的の形状に加熱プ
レス成形する(10)記載の複合材料二次加工体の製造
方法。
The present invention for achieving the above object is as follows. (1) Using shredder dust as raw material, urethane,
Contains fiber, plastic, and rubber as its main components, and has a size of about 1
Various sizes from 0 to 20 mm or less, with a bulk density of 0.3
Granular composite material controlled to g / cm 3 or less. (2) Shredder dust having a size of about 10 to 20 mm or more is selected as the raw material of the composite material, and iron, non-ferrous metal, and wire harness are selectively removed from the shredder dust, and urethane, fiber, plastic, and rubber are the main components. A bulk density of 0.3 g is obtained by selecting a mixture of light materials to be used and crushing the mixture of light materials by a crusher into various sizes of about 10 to 20 mm or less.
/ Cm 3 or less, a method for producing a granular composite material, which comprises the steps of: (3) The substrate having a bulk density of 0.3 g / cm 3 or less,
The granular composite material according to (2), which further has a step of sieving and roughly classifying it into urethane on the sieve, a light material containing fiber as a main component and a plastic that has passed through the screen, and a slightly heavy material containing rubber as a main component. Manufacturing method. (4) About 10 to 20 using shredder dust as raw material
Milled to various sizes less than mm, and has a bulk density of 0.3 g / c
A composite material secondary processed body comprising a granular composite material of m 3 or less and a resin material obtained by solidifying the granular composite material to form a solid body having a predetermined shape. (5) The composite material secondary processed body according to (4), wherein the resin material is a fibrous thermoplastic resin material. (6) The composite material secondary processed body according to (4), wherein the resin material comprises a granular composite material and a binder. (7) The composite material secondary processed body according to (4), wherein the resin material is a composite fiber. (8) The composite material secondary processed body according to (4), wherein the resin material is a composite fiber, and the solid body is an automobile soundproofing material. (9) The composite material secondary processed body according to (4), wherein the resin material is a urethane adhesive and the solid body is a U-shaped groove. (10) About 10 to 2 using shredder dust as raw material
It is crushed into various sizes of 0 mm or less and has a bulk density of 0.3 g /
A composite material secondary processed body comprising the steps of mixing a granular composite material having a size of 3 cm3 or less and a resin material, and heating and solidifying the mixture of the granular composite material and the resin material to form a solid body having a predetermined shape. Method. (11) The method for producing a composite material secondary processed body according to (10), wherein the solid body is heated and press-molded into a desired shape.

【0005】[0005]

【作用】上記(1)の粒状複合材料では、嵩密度が0.
3g/cm3 以下に管理されているため、粒の各々の材
質は多種であるにかかわらず、総じて比重がほぼ一定と
なり、他の物、たとえば防音材やU字溝等の原材料とし
て容易に利用され得るようになる。したがって、従来は
多種の材料を含むため利用不可能として埋設、焼却され
ていたものが、嵩密度基準で管理することにより、あた
かも1種類の材料を扱うが如くに、他の物への原材料と
して利用できるようになる。上記(2)の粒状複合材料
の製造方法は、上記(1)の粒状複合材料の得るための
方法で、シュレッダーダストから金属を除去した後、約
10〜20mm以下の各種サイズに粉砕することによ
り、嵩密度が0.3g/cm3 以下の粒状複合材料が自
動的に得られる。上記(3)の方法では、嵩密度が0.
3g/cm3 以下の基材を粉砕機の目より所定量大きい
(たとえば、+3mm)目の篩にかけて、篩上のものと
篩下(篩の目を通ったもの)のものとにわけることによ
り、自動的に、軽いもの(ウレタン、繊維等)とやや重
いもの(プラスチック、ゴム等)にわけることができ、
たとえば軽いものは防音材の原材料に、やや重いものは
U字溝の原材料にと、用途に応じて使いわけが可能とな
る。上記(4)では、複合材料が樹脂材で固められて二
次加工(固形化)されるので、とり扱いが容易であり、
固形化される形状を最終製品形状とすればそのまま最終
製品ともなる。上記(5)では、固めるための樹脂材が
繊維状であるため、固形体の強度が高い。最終製品が板
状防音材である場合、固形体とした段階でそのまま防音
材材料になり得る。上記(6)では、固めるための樹脂
材が粒状複合材料とつなぎ材(雑反毛、綿、麻、化繊
等)からなるため、固形体の強度がより高くなる。上記
(7)では、樹脂材が複合繊維であるため、固形体の強
度が高い。上記(8)では、自動車防音材が用途上の最
終製品であるため、シュレッダーダストに廃車シュレッ
ダーダストを用いた場合、車から車への材料リサイクル
がはかれる。上記(9)では、樹脂材がウレタン系接着
材であるため、固形体の硬さ、強度が高く、U字溝とし
て利用され得る。上記(10)では、樹脂材と混ぜて加
熱することにより所定形状の固形体に固められる。上記
(11)では、さらに加熱プレスによって所望の最終製
品形状に加工される。
In the granular composite material of the above (1), the bulk density is 0.
Since it is controlled to 3 g / cm 3 or less, the specific gravity is almost constant as a whole, regardless of the variety of materials used, and it can be easily used as a raw material for other materials such as soundproofing materials and U-shaped grooves. Can be done. Therefore, it has been buried and incinerated as unusable because it contains many kinds of materials in the past, but by managing it according to the bulk density standard, it can be used as a raw material for other things as if handling one kind of material. Will be available. The method for producing a granular composite material according to (2) above is a method for obtaining a granular composite material according to (1) above, in which metal is removed from shredder dust and then crushed into various sizes of about 10 to 20 mm or less. A granular composite material having a bulk density of 0.3 g / cm 3 or less is automatically obtained. In the method (3), the bulk density is 0.
By sieving a base material of 3 g / cm 3 or less with a sieve having a size larger than the size of the crusher by a predetermined amount (for example, +3 mm), and dividing it into one on the sieve and one on the sieve (passed through the sieve). , Can automatically be divided into lighter ones (urethane, fibers, etc.) and slightly heavier ones (plastic, rubber, etc.),
For example, a light material can be used as a soundproof material and a slightly heavy material can be used as a U-groove material, depending on the application. In the above (4), since the composite material is solidified with the resin material and is secondary processed (solidified), it is easy to handle,
If the shape to be solidified is the final product shape, it will be the final product as it is. In the above (5), since the resin material for hardening is fibrous, the strength of the solid body is high. When the final product is a plate-shaped soundproof material, it can be used as it is as a soundproof material when it is made into a solid body. In the above (6), since the resin material for hardening is composed of the granular composite material and the tie material (such as fluff, cotton, hemp, and synthetic fiber), the strength of the solid body becomes higher. In the above (7), since the resin material is the composite fiber, the strength of the solid body is high. In the above (8), since the automobile soundproofing material is the final product for use, when the scrapped vehicle shredder dust is used as the shredder dust, the material can be recycled from car to car. In (9) above, since the resin material is a urethane-based adhesive material, the solid body has high hardness and strength and can be used as a U-shaped groove. In the above (10), the solid material having a predetermined shape is solidified by mixing with the resin material and heating. In the above (11), it is further processed into a desired final product shape by hot pressing.

【0006】[0006]

【実施例】以下に、本発明の望ましい実施例を、図面を
参照して説明する。図1は本発明の第1実施例の粒状複
合材料1を示している。この粒状複合材料1は、シュレ
ッダーダスト、たとえば廃車シュレッダーダストを原材
料とし、ウレタン2、繊維3、プラスチック4、ゴム5
の各粒を主成分とし、各粒のサイズが約10〜20mm
以下(10〜20mmの篩を通ったもの)の各種サイズ
とされ、嵩密度が0.3g/cm3 以下(たとえば、
0.3g/cm3 〜0.05g/cm3 )に管理された
ものからなる。ここで、嵩密度は、粒状複合材料1を所
定容積の容器に押えつけないで満杯に入れ、その時の粒
状複合材料1の質量を容器容積で除した値として求めら
れる。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT A preferred embodiment of the present invention will be described below with reference to the drawings. FIG. 1 shows a granular composite material 1 according to the first embodiment of the present invention. This granular composite material 1 uses shredder dust, for example, scrap car shredder dust as a raw material, and has urethane 2, fibers 3, plastic 4, rubber 5
Each grain is the main component, and the size of each grain is about 10-20 mm
Various sizes below (those passed through a sieve of 10 to 20 mm) and a bulk density of 0.3 g / cm 3 or less (for example,
Consisting 0.3g / cm 3 ~0.05g / cm 3 ) to those managed. Here, the bulk density is obtained as a value obtained by fully loading the granular composite material 1 in a container having a predetermined volume without pressing it, and dividing the mass of the granular composite material 1 at that time by the container volume.

【0007】上記粒状複合材料1は、図2の方法により
製造される。まず、工程11でシュレッダーダストを用
意する。ついで、工程12でこのシュレッダーダストを
回転式篩機(目開きが10〜20mmにあるもの)にか
けて、サイズが約10〜20mm以上のダストを採取す
る(篩の上に残ったもの、工程13)。篩を通った小さ
な粉末状のダストは、廃棄、または他に利用すべく再生
する。ついで、工程14にて、約10〜20mm以上の
サイズのシュレッダーダストを磁選機にかけて鉄材を除
去する。ついで、工程15でシュレッダーダストを非鉄
金属選別機にかけてアルミ、銅等の非鉄金属を除去す
る。上記の磁選機、非鉄金属選別機は従来公知のもので
よい。ついで、工程16にワイヤーハーネスを除去す
る。ワイヤーハーネスは、粒状であるプラスチック、ゴ
ム、ウレタン、繊維等に比べて長く、格子櫛子を通すこ
と等により除去できる。ワイヤーハーネスを除去したも
のは、軽い粒状の混合物として選別採取される(工程1
7)。ついで、この軽い複合物を、工程18にて、回転
式粉砕機に少なくとも1段かけて、約10〜20mmの
サイズであった粒状ダストを約10〜20mmのサイズ
以下の各種サイズ、たとえば1、2、3、6、8、12
mm等に粉砕する。この工程で得られたものが基材(工
程19)であり、この基材の粒状物は、金属は含まず、
サイズが約10〜20mm以下の各種サイズの、プラス
チック、繊維、ウレタン、ゴムを主成分とする混合粒状
物からなる。この基材は、図3に示すように、嵩密度
は、基材上限と基材下限との間にあり、粒径が1〜20
mm(図では12mmまでを示した)の範囲では粒径に
よらず、ほぼ0.3g/cm3 以下(0.3〜0.05
g/cm3 )にある。したがって、粒径を工程18で粉
砕機にかけて、サイズ1〜20mmの各種サイズとする
ことにより、種々の材料、すなわちプラスチック、ゴ
ム、ウレタン、繊維を含むにかかわらず、自動的に嵩密
度を、0.3g/cm3 以下に管理できる。これによっ
て、他の物の原材料として再利用が容易になり、従来、
埋立、焼却されていたものを材料リサイクルできるよう
になる。
The above-mentioned granular composite material 1 is manufactured by the method shown in FIG. First, in step 11, shredder dust is prepared. Next, in step 12, the shredder dust is passed through a rotary sieving machine (those having openings of 10 to 20 mm) to collect dust of a size of about 10 to 20 mm or more (those remaining on the sieve, step 13). . The small, powdery dust that has passed through the screen is discarded or regenerated for other uses. Then, in step 14, the shredder dust having a size of about 10 to 20 mm or more is subjected to a magnetic separator to remove the iron material. Then, in step 15, the shredder dust is passed through a non-ferrous metal sorter to remove non-ferrous metals such as aluminum and copper. The magnetic separator and non-ferrous metal separator described above may be conventionally known ones. Then, in step 16, the wire harness is removed. The wire harness is longer than granular plastics, rubber, urethane, fibers, etc., and can be removed by passing through a lattice comb. The wire harness removed is sorted and collected as a light granular mixture (Step 1
7). This light composite is then run at least one stage in a rotary crusher in step 18 to remove granular dust that was about 10-20 mm in size to various sizes below about 10-20 mm, for example 1, 2, 3, 6, 8, 12
Mill to mm or the like. The material obtained in this step is the base material (step 19), and the granular material of this base material does not contain a metal,
It is composed of mixed granules having various sizes of about 10 to 20 mm or less, which are mainly composed of plastic, fiber, urethane and rubber. As shown in FIG. 3, this base material has a bulk density between the upper limit and the lower limit of the base material and a particle size of 1 to 20.
In the range of mm (up to 12 mm is shown in the figure), regardless of the particle size, approximately 0.3 g / cm 3 or less (0.3 to 0.05
g / cm 3 ). Therefore, by subjecting the particle size to various sizes of 1 to 20 mm by crushing in step 18, the bulk density is automatically reduced to 0 regardless of including various materials, that is, plastic, rubber, urethane and fiber. It can be controlled to less than 0.3 g / cm 3 . This makes it easy to reuse as a raw material for other things,
It will be possible to recycle materials that have been landfilled or incinerated.

【0008】さらに、図2に示すように、基材(プラス
チック、ゴム、ウレタン、繊維の粒状物)は、工程20
で、粉砕粒径+約3mmの目をもつ回転式篩機にかけら
れ、篩上に残った軽い粒状物(ウレタン、繊維を主成分
とする粒状物、以下、材料Aという)と(工程21で採
取)、篩下のやや重い粒状物(プラスチック、ゴムを主
成分とする粒状物、以下、材料Bという)と(工程22
で採取)に、大別される。プラスチック、ゴムは粉砕後
の材料の膨張(スプリングバック)による粒径拡大が小
で、粉砕機の粉砕粒径より約3mm大の径の目とした篩
を通り抜けるが、ウレタン、繊維は粉砕後の膨張による
粒径拡大が大で、篩の目を通り抜けることができず、こ
れによって、ウレタン、繊維を主成分とする粒状物と、
プラスチック、ゴムを主成分とする粒状物とに大別され
る。上記で、粉砕粒径が互いに異なる粉砕機で粉砕し、
その度毎にその粉砕粒径+3mmの篩で選別することに
より、粒状物は、たとえば、約12mmの粒径のA材
料、約12mmの粒径のB材料、約8mmの粒径のA材
料、約8mmの粒径のB材料、・・・、約1mmの粒径
のA材料、約1mmの粒径のB材料に分別できる。そし
て、それぞれの嵩密度を測定してプロットすると図3に
示すようになる。B材料は各種粒径でほぼ単一の嵩密度
を示す(嵩密度がほとんどばらつかない)が、A材料は
上限値と下限値との間(0.12〜0.03)でばらつ
く。ただし、そのばらつきは小さく、材料の比重はA材
料で約0.06,B材料で約0.23である。そして、
このことは粒径の変化、材料の変化の如何を問わずいえ
ることである。このため、多種の材料、1mm〜20m
mの種々の粒径を含んだ基材を、さらに比重がほぼ一定
の、扱い易い工業材料に分別できることを示し、材料リ
サイクルがさらに適切に、かつ容易になる。
Further, as shown in FIG. 2, the substrate (plastic, rubber, urethane, granular material of fibers) is processed in the step 20.
Then, the light granules (urethane, granules containing fibers as the main component, hereinafter referred to as material A) which were passed through a rotary sieving machine having a crushed particle size + about 3 mm and remained on the sieve and (in step 21) (Collection), a slightly heavy granular material under the sieve (a granular material mainly composed of plastic or rubber, hereinafter referred to as material B) and (step 22
(Collected in)). Plastic and rubber have a small particle size expansion due to expansion (spring back) of the material after crushing, and pass through a sieve with a diameter of about 3 mm larger than the crushed particle size of the crusher, but urethane and fiber are The expansion of the particle size due to expansion is large, and it cannot pass through the mesh of the sieve.
It is roughly classified into plastics and granular materials composed mainly of rubber. In the above, the crushed particles are crushed by different crushers,
By selecting each time with a crushed particle size + 3 mm sieve, the granular material is, for example, an A material having a particle size of about 12 mm, a B material having a particle size of about 12 mm, an A material having a particle size of about 8 mm, It can be classified into B material having a particle diameter of about 8 mm, ..., A material having a particle diameter of about 1 mm, and B material having a particle diameter of about 1 mm. Then, the respective bulk densities are measured and plotted, as shown in FIG. The material B exhibits a substantially uniform bulk density with various particle sizes (the bulk density hardly varies), while the material A varies between the upper limit value and the lower limit value (0.12 to 0.03). However, the variation is small, and the specific gravity of the material is about 0.06 for the A material and about 0.23 for the B material. And
This can be said regardless of changes in particle size and materials. Therefore, various materials, 1mm ~ 20m
It is shown that the base material containing various particle diameters of m can be further separated into industrial materials having a specific gravity that is almost constant and easy to handle, which makes the material recycling more appropriate and easy.

【0009】図4は、本発明の第2実施例である、粒状
複合材料を固形化した二次加工体6を示している。図4
中、1は第1実施例の粒状複合材料1であり、サイズが
約10〜20mm以下の各種サイズに粉砕され、嵩密度
が0.3g/cm3 の、ウレタン、繊維、プラスチッ
ク、ゴムを主成分とする混合材料である。また、7は、
粒状複合材料を固めて所定形状の固形体となしているバ
インダーとしての樹脂材である。樹脂材7は、熱可塑性
樹脂または熱硬化性樹脂からなる。樹脂材7は、熱を加
えられて粒状複合材料1と固形化される前は、繊維状の
熱可塑性樹脂であるポリエステル複合繊維の場合もあ
り、PEパウダ、フェノールパウダ等の各種繊維材につ
なぎ材としての雑反毛、綿、麻等の天然繊維を加える場
合もあり、さらにはウレタン系接着剤である場合もあ
る。繊維状熱可塑性樹脂を5〜10%混合することによ
り二次加工体6の防音効果(図7に車両防音材の防音効
果の試験例を示す)、強度(図8)が大となり、ウレタ
ン系接着剤の場合はブロック体への成形が容易となる。
また、二次加工体6は、ある場合は自動車用防音材8
(たとえばダッシュサイレンサー)であり、またある場
合はU字溝9である。防音材の場合は、粒状複合材料1
には望ましくは軽いA材料(ウレタン、繊維)が用いら
れ、樹脂材7には望ましくは繊維状熱可塑性樹脂が用い
られる。また、U字溝の場合は、粒状複合材料1には望
ましくは基材(工程19)またはやや重いB材料(プラ
スチック、ゴム)が用いられ、樹脂材7には望ましくは
ウレタン系接着剤が用いられる。
FIG. 4 shows a secondary processed body 6 in which a granular composite material is solidified, which is a second embodiment of the present invention. FIG.
Medium 1 is the granular composite material 1 of the first embodiment, which is mainly made of urethane, fiber, plastic, and rubber having a bulk density of 0.3 g / cm 3 crushed into various sizes of about 10 to 20 mm or less. It is a mixed material as an ingredient. Also, 7 is
It is a resin material as a binder which is formed by solidifying a granular composite material into a solid body having a predetermined shape. The resin material 7 is made of a thermoplastic resin or a thermosetting resin. Before the resin material 7 is solidified with the granular composite material 1 by being heated, it may be a polyester composite fiber which is a fibrous thermoplastic resin, and is connected to various fiber materials such as PE powder and phenol powder. In some cases, natural fibers such as fluff, cotton, and hemp are added as a material, and in some cases, a urethane adhesive is used. By mixing 5 to 10% of the fibrous thermoplastic resin, the soundproofing effect of the secondary processed body 6 (Fig. 7 shows a test example of the soundproofing effect of the vehicle soundproofing material), the strength (Fig. 8) becomes large, and the urethane type In the case of an adhesive, molding into a block becomes easy.
In addition, the secondary processed body 6 may be a soundproof material for automobiles 8 in some cases.
(For example a dash silencer) and in some cases a U-shaped groove 9. In the case of soundproof material, granular composite material 1
Is preferably a light A material (urethane, fiber), and the resin material 7 is preferably a fibrous thermoplastic resin. In the case of the U-shaped groove, the base material (step 19) or a slightly heavy B material (plastic, rubber) is preferably used for the granular composite material 1, and the urethane adhesive is preferably used for the resin material 7. To be

【0010】図5、図6、図9は二次加工体6の製造方
法を防音材、U字溝を例にとって示している。図5の製
造方法では、工程31において、コンベア36で繊維状
熱可塑性樹脂を予備解繊工程32に供給する。予備解繊
工程32では、解繊機37により繊維状熱可塑性樹脂を
予備解繊し、綿状のシートを作製する。ついで、廃材投
入工程33で、シュレッダーダストの基材(粒状複合材
料1、望ましくは軽いA材料)を綿状シートの上に一定
量均一に散布し、ついで混合解繊工程34にてこれを混
合解繊する。ついで、工程35で、混合解繊を行った綿
状のシートをオーブン40で加熱し、必要厚みに圧縮し
て冷却を行い、目的の二次加工体、たとえば車両用防音
材を得る。このような二次加工体は、繊維状樹脂を利用
したことにより通気性を有するとともに、強度を有す
る。また、繊維状樹脂を利用することにより製造工程か
ら出る有害物質も少なくなり、環境衛生面にもよい効果
がある。図6は、図5の工程にプレス工程41を加えた
もので、このプレス工程41において、プレス機42に
より、熱プレス成形、もしくは再度加熱して冷間プレス
成形を行い、最終形状の二次加工体、たとえば車両防音
材であるダッシュサイレンサー並びにフロアサイレンサ
ーに加工する。
5, 6, and 9 show a method of manufacturing the secondary processed body 6 by taking a soundproof material and a U-shaped groove as an example. In the manufacturing method of FIG. 5, in step 31, the fibrous thermoplastic resin is supplied to the preliminary defibration step 32 by the conveyor 36. In the preliminary defibration step 32, the fibrous thermoplastic resin is defibrated by the defibrating machine 37 to produce a cotton-like sheet. Then, in a waste material feeding step 33, a certain amount of shredder dust base material (granular composite material 1, preferably light A material) is evenly dispersed on the cotton-like sheet, and then mixed and defibrated in a mixing and defibrating step 34. Disentangle. Next, in step 35, the cotton-like sheet that has been subjected to mixed defibration is heated in an oven 40, compressed to a required thickness and cooled to obtain an intended secondary processed body, for example, a vehicle soundproofing material. Such a secondary processed body has air permeability and strength by using the fibrous resin. In addition, by using the fibrous resin, the amount of harmful substances emitted from the manufacturing process is reduced, which is also advantageous in terms of environmental hygiene. FIG. 6 shows a process in which a pressing process 41 is added to the process of FIG. 5, and in this pressing process 41, a press machine 42 performs hot press molding or re-heating to perform cold press molding to obtain a secondary shape of the final shape. It is processed into a processed body such as a dash silencer and a floor silencer which are soundproofing materials for vehicles.

【0011】図9は二次加工体6がU字溝である場合で
ある。工程51で粒サイズが20mm以上の廃車シュレ
ッダーダストから金属、ワイヤハーネスを除去したもの
57を用意する。ついで、粉砕工程52で回転式粉砕機
58により10〜20mmサイズ以下の各種サイズに粉
砕し、基材19を得る。この基材19を回転式篩工程5
3において、回転式篩機59により軽い材料Aとやや重
い材料Bに大別する。このうち、たとえばB材料を接着
剤混合工程54に送って、そこで混合機60によりウレ
タン系接着剤と混合する。この混合物を加熱成形工程5
5にて、プレス機61を利用して加熱成形し、回収固形
物採取工程56にて、U字溝62として採取される。従
来は廃車シュレッダーダストの樹脂分は埋設、焼却され
ていたが、図9の例ではU字溝62として再生される。
このU字溝は腐食がなく、耐久性にすぐれている。ま
た、従来のコンクリート製に比べて軽量なため、施工が
容易である。また、コンクリート製と異なり、鋸での切
断、釘、ボルトによる固定、接着等が可能であり、現物
組立を容易にする。
FIG. 9 shows the case where the secondary processed body 6 is a U-shaped groove. In step 51, scrap metal shredder dust having a grain size of 20 mm or more from which metal and wire harness are removed is prepared 57. Next, in the pulverizing step 52, the rotary pulverizer 58 pulverizes the material into various sizes of 10 to 20 mm or less to obtain the base material 19. This base material 19 is subjected to rotary sieving step 5
3, the material is divided into a light material A and a slightly heavy material B by the rotary sifter 59. Of these, for example, the B material is sent to the adhesive mixing step 54, where it is mixed with the urethane adhesive by the mixer 60. This mixture is subjected to a thermoforming step 5
In step 5, heat molding is performed using the press machine 61, and the solid material is collected as the U-shaped groove 62 in the collected solid material collecting step 56. Conventionally, the resin component of the scrapped vehicle shredder dust was buried and incinerated, but in the example of FIG. 9, it is regenerated as a U-shaped groove 62.
This U-shaped groove has no corrosion and has excellent durability. In addition, since it is lighter in weight than conventional concrete products, construction is easy. Also, unlike concrete, it can be cut with a saw, fixed with nails, bolts, glued, etc. to facilitate the actual assembly.

【0012】[0012]

【発明の効果】請求項1の粒状複合材料によれば、嵩密
度で管理され、粒径も20mm以下にほぼそろえられる
ので、多種の混合材にかかわらず、材料としての一様性
(比重、サイズ)が生まれ、材料リサイクルが可能とな
る。請求項2の粒状複合材料の製造方法によれば、従
来、金属が回収された後は材料リサイクルできないと思
われていた多種材料混合ダストを、粉砕、篩して嵩密度
で管理できるようになり、材料リサイクル可能な粒状複
合材料へと変化させることが可能になる。請求項3の方
法によれば、基材をさらに軽いものとやや重いものとに
分別するので、材料リサイクルにより適した複合材料が
得られる。請求項4の二次加工体によれば、樹脂材と混
合して所望の二次加工体にできる。請求項5によれば、
樹脂材に繊維状のものを用いたため、二次加工体の強度
が上る。請求項6によれば、固めるための樹脂材が粒状
複合材料とつなぎ材(雑反毛、綿、麻、化繊等)からな
るため、固形体の強度がより高くなる。請求項7によれ
ば、樹脂材に複合繊維を用いたため、二次加工体の強度
が上る。請求項8によれば、車両防音材に成形するの
で、廃車シュレッダーダストの車防音材への同一分野内
での材料リサイクルが可能となる。請求項9によれば、
U字溝にリサイクルしたので、軽量で施工性のよいU字
溝が得られる。請求項10の方法によれば、樹脂材と混
合して加熱固化するので、所望形状の二次加工体を容易
に製造できる。請求項11によれば、さらに加熱プレス
成形により、最終製品にまで容易に成形できる。
EFFECTS OF THE INVENTION According to the granular composite material of claim 1, since it is controlled by the bulk density and the particle size is almost equal to or less than 20 mm, the uniformity (specific gravity, (Size) is born, and the material can be recycled. According to the method for producing a granular composite material of claim 2, it is possible to pulverize, sieve, and manage the bulk density of the mixed dust of various materials, which has been conventionally thought that the material cannot be recycled after the metal is recovered. , It becomes possible to change the material into a recyclable granular composite material. According to the method of claim 3, since the base material is sorted into a lighter material and a slightly heavier material, a composite material more suitable for material recycling can be obtained. According to the secondary processed body of claim 4, a desired secondary processed body can be obtained by mixing with the resin material. According to claim 5,
Since the fibrous material is used as the resin material, the strength of the secondary processed body is increased. According to the sixth aspect, since the resin material for hardening is composed of the granular composite material and the tie material (such as fluff, cotton, hemp, and synthetic fiber), the strength of the solid body becomes higher. According to claim 7, since the composite fiber is used as the resin material, the strength of the secondary processed body is increased. According to the eighth aspect, since it is molded into the vehicle soundproof material, it is possible to recycle the waste car shredder dust into the vehicle soundproof material in the same field. According to claim 9,
Since it is recycled into a U-shaped groove, a U-shaped groove that is lightweight and has good workability can be obtained. According to the method of the tenth aspect, since the resin material is mixed and heated and solidified, a secondary processed body having a desired shape can be easily manufactured. According to the eleventh aspect, the final product can be easily molded by the hot press molding.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の第1実施例の粒状複合材料の混合の一
例を示す図である。
FIG. 1 is a diagram showing an example of mixing a granular composite material according to a first embodiment of the present invention.

【図2】本発明の粒状複合材料の製造方法を示すブロッ
ク図である。
FIG. 2 is a block diagram showing a method for producing a granular composite material of the present invention.

【図3】本発明の粒状複合材料の嵩密度と粒のサイズと
の関係を示すグラフである。
FIG. 3 is a graph showing the relationship between the bulk density and the grain size of the granular composite material of the present invention.

【図4】本発明の第2実施例の二次加工体の一例を示す
図である。
FIG. 4 is a diagram showing an example of a secondary processed body according to a second embodiment of the present invention.

【図5】本発明の二次加工体の製造方法を示すブロック
図である。
FIG. 5 is a block diagram showing a method for manufacturing a secondary processed body of the present invention.

【図6】図5の製造方法にさらにプレス成形工程を加え
たブロック図である。
6 is a block diagram in which a press molding step is further added to the manufacturing method of FIG.

【図7】本発明による防音材の透過損失と周波数との関
係を示すグラフである。
FIG. 7 is a graph showing the relationship between the transmission loss and the frequency of the soundproof material according to the present invention.

【図8】本発明においてバインダー樹脂が繊維状の場合
の二次加工体の引張強度とバインダー量との関係を示す
グラフである。
FIG. 8 is a graph showing the relationship between the tensile strength of the secondary processed product and the amount of binder when the binder resin is fibrous in the present invention.

【図9】本発明において二次加工体がU字溝である場合
の製造方法を示すブロック図である。
FIG. 9 is a block diagram showing a manufacturing method when the secondary processed body is a U-shaped groove in the present invention.

【図10】廃車シュレッダーダストのうち粒サイズが2
0mm以上のものの重量比率を示す円グラフである。
[Fig. 10] Grain size of scrap car shredder dust is 2
It is a pie chart which shows the weight ratio of 0 mm or more.

【図11】廃車シュレッダーダストのうち粒サイズが2
0mm以上のものの容積比率を示す円グラフである。
FIG. 11: Grain size of scrapped vehicle shredder dust is 2
It is a pie chart which shows the volume ratio of 0 mm or more.

【図12】従来の廃車シュレッダーダストの金属資源回
収工程を示すブロック図である。
FIG. 12 is a block diagram showing a conventional metal resource recovery process for scrapped vehicle shredder dust.

【符号の説明】[Explanation of symbols]

1 粒状複合材料 2 ウレタン粒 3 繊維粒 4 プラスチック粒 5 ゴム粒 6 二次加工体 7 樹脂材(バインダー) 1 Granular Composite Material 2 Urethane Granules 3 Fiber Granules 4 Plastic Granules 5 Rubber Granules 6 Secondary Processing Body 7 Resin Material (Binder)

───────────────────────────────────────────────────── フロントページの続き (72)発明者 山瀬 修 愛知県豊田市トヨタ町1番地 トヨタ自動 車株式会社内 (72)発明者 成瀬 徹 愛知県名古屋市中区千代田五丁目21番11号 株式会社中外内 (72)発明者 松廣 真治 愛知県名古屋市中区千代田五丁目21番11号 株式会社中外内 (72)発明者 杉口 剛継 愛知県名古屋市中区千代田五丁目21番11号 株式会社中外内 (72)発明者 皿井 寛 愛知県名古屋市中区千代田五丁目21番11号 株式会社中外内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Osamu Yamase 1 Toyota Town, Toyota City, Aichi Prefecture Toyota Motor Corporation (72) Inventor Toru Naruse 5-21-11 Chiyoda, Naka-ku, Aichi Prefecture Nagoya City Co., Ltd. Chugai (72) Inventor Shinji Matsuhiro 5-21-11 Chiyoda, Naka-ku, Nagoya-shi, Aichi Chugai Co., Ltd. (72) Gotsugu Sugiguchi 5-21-11 Chiyoda, Naka-ku, Nagoya, Aichi Company Chugai (72) Inventor Hiroshi Sarai 5-21-11 Chiyoda, Naka-ku, Nagoya, Aichi Prefecture Chugai Co., Ltd.

Claims (11)

【特許請求の範囲】[Claims] 【請求項1】 シュレッダーダストを原材料とし、ウレ
タン、繊維、プラスチック、ゴムを主成分とし、サイズ
が約10〜20mm以下の各種サイズとされ、嵩密度が
0.3g/cm3 以下に管理されている粒状複合材料。
1. Shredder dust as a raw material, urethane, fiber, plastic, rubber as a main component, various sizes of about 10 to 20 mm or less, and a bulk density controlled to 0.3 g / cm 3 or less. Granular composite material.
【請求項2】 サイズが約10〜20mm以上のシュレ
ッダーダストを複合材料の原材料に選定し、 前記シュレッダーダストから、鉄、非鉄金属、ワイヤハ
ーネスを選別除去して、ウレタン、繊維、プラスチッ
ク、ゴムを主成分とする軽い材料の混合物を選別し、 前記軽い材料の混合物を粉砕機により粉砕して前記約1
0〜20mmのサイズ以下の各種のサイズとすることに
より嵩密度が0.3g/cm3 以下の基材とする、工程
からなる粒状複合材料の製造方法。
2. A shredder dust having a size of about 10 to 20 mm or more is selected as a raw material for the composite material, and iron, non-ferrous metal, and wire harness are selectively removed from the shredder dust to remove urethane, fiber, plastic, and rubber. The mixture of light materials as the main component is selected, and the mixture of the light materials is crushed by a crusher to obtain the above-mentioned about 1
A method for producing a granular composite material, which comprises the steps of forming a base material having a bulk density of 0.3 g / cm 3 or less by setting various sizes of 0 to 20 mm or less.
【請求項3】 前記嵩密度が0.3g/cm3 以下の基
材を、さらに篩にかけて、篩上のウレタン、繊維を主成
分とする軽いものと篩を通過したプラスチック、ゴムを
主成分とするやや重いものに大別する、工程をさらに有
する請求項2記載の粒状複合材料の製造方法。
3. The base material having a bulk density of 0.3 g / cm 3 or less is further sieved, and urethane on the sieve, a light material having a fiber as a main component, a plastic passed through the sieve, and a rubber as main components. The method for producing a granular composite material according to claim 2, further comprising a step of roughly classifying into a slightly heavy one.
【請求項4】 シュレッダーダストを原材料とし約10
〜20mm以下の各種サイズに粉砕され嵩密度が0.3
g/cm3 以下の粒状複合材料と、 該粒状複合材料を固めて所定形状の固形体となしている
樹脂材と、から成る複合材料二次加工体。
4. Shredder dust as a raw material for about 10
It is crushed into various sizes up to 20 mm and has a bulk density of 0.3.
A composite material secondary processed body comprising a granular composite material of g / cm 3 or less and a resin material obtained by solidifying the granular composite material to form a solid body having a predetermined shape.
【請求項5】 前記樹脂材が繊維状の熱可塑性樹脂材で
ある請求項4記載の複合材料二次加工体。
5. The composite material secondary processed body according to claim 4, wherein the resin material is a fibrous thermoplastic resin material.
【請求項6】 前記樹脂材が粒状複合材料とつなぎ材と
からなる請求項4記載の複合材料二次加工体。
6. The composite material secondary processed body according to claim 4, wherein the resin material comprises a granular composite material and a binder.
【請求項7】 前記樹脂材が複合繊維である請求項4記
載の複合材料二次加工体。
7. The composite material secondary processed body according to claim 4, wherein the resin material is a composite fiber.
【請求項8】 前記樹脂材が複合繊維であり、前記固形
体が自動車防音材である請求項4記載の複合材料二次加
工体。
8. The composite material secondary processed body according to claim 4, wherein the resin material is a composite fiber, and the solid body is an automobile soundproofing material.
【請求項9】 前記樹脂材がウレタン系接着剤であり、
前記固形体がU字溝である請求項4記載の複合材料二次
加工体。
9. The resin material is a urethane adhesive,
The composite material secondary processed body according to claim 4, wherein the solid body is a U-shaped groove.
【請求項10】 シュレッダーダストを原材料とし約1
0〜20mm以下の各種サイズに粉砕され嵩密度が0.
3g/cm3 以下の粒状複合材料と樹脂材とを混合し、 該粒状複合材料と樹脂材との混合物を加熱、固化して所
定形状の固形体となす、工程からなる複合材料二次加工
体の製造方法。
10. Shredder dust is used as a raw material for about 1
It is crushed into various sizes of 0 to 20 mm or less and has a bulk density of 0.
A composite material secondary processed body comprising a step of mixing a granular composite material of 3 g / cm 3 or less and a resin material, and heating and solidifying the mixture of the granular composite material and the resin material into a solid body having a predetermined shape. Manufacturing method.
【請求項11】 さらに、前記固形体を、目的の形状に
加熱プレス成形する請求項10記載の複合材料二次加工
体の製造方法。
11. The method for manufacturing a composite material secondary processed body according to claim 10, further comprising hot pressing the solid body into a desired shape.
JP25070694A 1994-10-17 1994-10-17 Granular composite material, secondary processed product thereof, and method for producing the same Expired - Fee Related JP3210813B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP25070694A JP3210813B2 (en) 1994-10-17 1994-10-17 Granular composite material, secondary processed product thereof, and method for producing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP25070694A JP3210813B2 (en) 1994-10-17 1994-10-17 Granular composite material, secondary processed product thereof, and method for producing the same

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Publication Number Publication Date
JPH08112584A true JPH08112584A (en) 1996-05-07
JP3210813B2 JP3210813B2 (en) 2001-09-25

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1078724A3 (en) * 1999-08-24 2003-01-02 Toyoda Boshoku Kabushiki K. Method of manufacturing sound-proof products and the sound-proof products
GB2429454A (en) * 2005-08-23 2007-02-28 George Owen Shredding and encapsulation process for waste material
JP2008264618A (en) * 2007-04-17 2008-11-06 Toyota Motor Corp Elastic sheet material shaped from shredder dust of waste material
JP2009233494A (en) * 2008-03-26 2009-10-15 Nippon Mining & Metals Co Ltd Method and system for disposing of shredder dust
JP2016002993A (en) * 2014-06-16 2016-01-12 ダイニック株式会社 Composite molding material for vehicle interior material

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1078724A3 (en) * 1999-08-24 2003-01-02 Toyoda Boshoku Kabushiki K. Method of manufacturing sound-proof products and the sound-proof products
US6576172B1 (en) 1999-08-24 2003-06-10 Toyoda Boshoku Corporation Method of manufacturing sound-proof products
GB2429454A (en) * 2005-08-23 2007-02-28 George Owen Shredding and encapsulation process for waste material
JP2008264618A (en) * 2007-04-17 2008-11-06 Toyota Motor Corp Elastic sheet material shaped from shredder dust of waste material
JP2009233494A (en) * 2008-03-26 2009-10-15 Nippon Mining & Metals Co Ltd Method and system for disposing of shredder dust
JP2016002993A (en) * 2014-06-16 2016-01-12 ダイニック株式会社 Composite molding material for vehicle interior material

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