JPH0790386A - Production of high strength cold rolled steel plate excellent in deep drawability and chemical convertibility - Google Patents
Production of high strength cold rolled steel plate excellent in deep drawability and chemical convertibilityInfo
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- JPH0790386A JPH0790386A JP23489593A JP23489593A JPH0790386A JP H0790386 A JPH0790386 A JP H0790386A JP 23489593 A JP23489593 A JP 23489593A JP 23489593 A JP23489593 A JP 23489593A JP H0790386 A JPH0790386 A JP H0790386A
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- deep drawability
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- rolled steel
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Abstract
Description
【0001】[0001]
【産業上の利用分野】この発明は、優れた深絞り性と化
成処理性とが要求される自動車用鋼板等の使途に有用な
高強度冷延鋼板に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a high-strength cold-rolled steel sheet which is useful for applications such as automobile steel sheets which are required to have excellent deep drawability and chemical conversion treatability.
【0002】[0002]
【従来の技術】従来、自動車の燃費向上に対応する車体
軽量化を目的として、引張強さが30〜45kgf/mm2 でかつ
優れた深絞り性を有する冷延鋼板が使用されてきた。こ
のように鋼板が優れた深絞り性を示すためには、鋼板の
機械的特性として、高いr値(ランクフォード値)と良
好な延性(El. )とをそなえていることが必要である。 2. Description of the Related Art Conventionally, a cold-rolled steel sheet having a tensile strength of 30 to 45 kgf / mm 2 and excellent deep drawability has been used for the purpose of reducing the weight of a vehicle body corresponding to the improvement of fuel consumption of an automobile. In order for the steel sheet to exhibit excellent deep drawability, it is necessary that the steel sheet has a high r value (Rankford value) and a good ductility (El.) As mechanical properties.
【0003】深絞り性の改善のためには各種の方法が提
案されている。例えば特公昭44-17268号公報、特公昭44
-17269号公報及び特公昭44-17270号公報には、低炭素リ
ムド鋼に2回冷延−焼鈍を施すことにより、r値を2.18
まで高めた冷延鋼板の製造方法が開示されている。しか
しながらこれらの方法は、冷間圧延と再結晶焼鈍とを2
回ずつ行わなければならず、そのために要するエネルギ
ー及びコストは莫大なものとなる。Various methods have been proposed for improving the deep drawability. For example, JP-B-44-17268, JP-B-44
-17269 and Japanese Examined Patent Publication No. 44-17270 disclose that the r value is 2.18 by subjecting a low carbon rimmed steel to cold rolling and annealing twice.
A method for manufacturing a cold-rolled steel sheet which has been improved to the above is disclosed. However, these methods involve cold rolling and recrystallization annealing.
It has to be performed one by one, and the energy and cost required therefor are enormous.
【0004】近年になって自動車の車体軽量化及び安全
性向上を目的として、引張強さが45〜65kgf/mm2 のより
高強度の鋼板を用いようとする機運が急速に高まってき
ていて、個々の自動車部品に対応して軟鋼から高張力鋼
まで幅広い強度レベルの鋼板の開発が肝要となってい
る。また、自動車用鋼板には、プレス成形の際に優れた
深絞り性を示すことが要求されることは言うまでもな
い。したがって、従来鋼と比べても同等あるいはそれ以
上の高いr値をそなえる鋼板について研究開発が進めら
れている。In recent years, there has been a rapid increase in the motivation to use higher strength steel sheets having a tensile strength of 45 to 65 kgf / mm 2 for the purpose of reducing the weight of automobile bodies and improving safety. It is essential to develop steel sheets with a wide range of strength levels, from mild steel to high-strength steel, corresponding to individual automobile parts. Needless to say, automobile steel sheets are required to exhibit excellent deep drawability during press forming. Therefore, research and development have been conducted on steel sheets having a high r-value that is equal to or higher than that of conventional steel.
【0005】従来、深絞り性を有する高強度冷延鋼板の
製造には、Si、Mn、P等を強化成分として含有させた低
炭素Alキルド鋼を、通常の熱間圧延を施した後に冷間圧
延を行い、引き続き再結晶焼鈍を施すことが一般的であ
った。しかしながら、高強度を得るためには上記の強化
成分を多量に含有させなければならず、そのため深絞り
性に好ましくない集合組織が形成され、r値の低い鋼板
しか得られていなかった。Conventionally, in the production of a high strength cold rolled steel sheet having deep drawability, a low carbon Al killed steel containing Si, Mn, P and the like as a strengthening component is subjected to ordinary hot rolling and then cooled. It was common to carry out hot rolling followed by recrystallization annealing. However, in order to obtain high strength, a large amount of the above-mentioned strengthening components must be contained, so that a texture unfavorable for deep drawability is formed and only a steel sheet having a low r value is obtained.
【0006】また、自動車用鋼板について特に要求され
る特性として塗装前処理すなわち化成処理性が挙げられ
る。この化成処理性が良好でないと、その後の焼き付け
塗装もうまくいかない。しかしながら、鋼板の高強度化
を目的にSi、Mn、P等の強化成分を多量に含有させなけ
ればならないため、化成処理性が著しく劣化する。[0006] Further, as a characteristic particularly required for a steel sheet for automobiles, there is a pretreatment for coating, that is, a chemical conversion treatment property. If the chemical conversion treatability is not good, the subsequent baking coating will not be successful. However, since a large amount of reinforcing components such as Si, Mn, and P must be contained for the purpose of increasing the strength of the steel sheet, the chemical conversion treatability is significantly deteriorated.
【0007】[0007]
【発明が解決しようとする課題】この発明は、上記の問
題を有利に解決するもので、鋼板成分及び製造条件を特
定することにより、従来より格段に優れた深絞り性と化
成処理性とを有する、引張強さ35〜65kgf/mm2 の冷延鋼
板を経済的に製造する方法を提案することを目的とす
る。SUMMARY OF THE INVENTION The present invention advantageously solves the above-mentioned problems. By specifying the steel sheet composition and manufacturing conditions, it is possible to obtain deep drawability and chemical conversion treatability that are far superior to those in the past. An object of the present invention is to propose a method for economically producing a cold-rolled steel sheet having a tensile strength of 35 to 65 kgf / mm 2 .
【0008】[0008]
【課題を解決するための手段】発明者らは、深絞り性と
化成処理性とを向上させるべく鋭意研究を重ねた結果、
以下のように鋼成分及び製造条件を限定することによ
り、優れた深絞り性と化成処理性とを有する冷延鋼板が
得られることを見出した。[Means for Solving the Problems] As a result of intensive research conducted by the inventors to improve deep drawing property and chemical conversion treatment property,
It has been found that a cold rolled steel sheet having excellent deep drawability and chemical conversion treatability can be obtained by limiting the steel components and manufacturing conditions as described below.
【0009】この発明の要旨構成は次のとおりである。 (1) C:0.01wt%以下、Si:0.1 〜2.0 wt%、Mn:0.5
〜3.0 wt%、Nb:0.001〜0.200 wt%、B:0.0001〜0.0
080wt%、Al:0.03〜0.20wt%、P:0.02〜0.20wt%、
S:0.05wt%以下及びN:0.01wt%以下を含み、かつ上
記C、Nbは、各含有量〔%C〕,〔%Nb〕が、次式〔%
Nb〕/〔%C〕:5〜25の関係を満たす条件で、さらに
上記Si,Mn,Pは、各含有量〔%Si〕,〔%Mn〕及び
〔%P〕が、 次式(3〔%Si〕/28+ 200〔%P〕/31)/(〔%M
n〕/55):15〜40 の関係を満足する条件で含有する基本成分になり、残部
はFe及び不可避的不純物よりなる鋼素材に、Ar3 変態点
以下、500 ℃以上の温度域にて潤滑を施しつつ合計圧下
量が50%以上95%以下になる圧延加工を施した後、熱延
板再結晶処理を施し、次いで圧下率50〜95%の冷間圧延
を施し、その後に700 〜950 ℃の温度域での再結晶焼鈍
を施し、引き続き浸炭処理を施すことを特徴とする深絞
り性と化成処理性とに優れた高強度冷延鋼板の製造方法
(第1発明)。The gist of the present invention is as follows. (1) C: 0.01 wt% or less, Si: 0.1 to 2.0 wt%, Mn: 0.5
~ 3.0 wt%, Nb: 0.001 to 0.200 wt%, B: 0.0001 to 0.0
080wt%, Al: 0.03-0.20wt%, P: 0.02-0.20wt%,
S: 0.05 wt% or less and N: 0.01 wt% or less, and the contents of C and Nb are represented by the following formula [% C], [% Nb]
Nb] / [% C]: Under the condition that the relationship of 5 to 25 is satisfied, the contents of Si, Mn, and P are as follows: [% Si], [% Mn], and [% P] [% Si] / 28 + 200 [% P] / 31) / ([% M
n] / 55): it becomes a basic component containing the condition satisfying the 15-40 relationship, balance the steel material consisting of Fe and unavoidable impurities, Ar 3 or less transformation point, at a temperature range of not lower than 500 ° C. After rolling with total reduction of 50% or more and 95% or less while lubricating, hot-rolled sheet recrystallization treatment is performed, and then cold rolling with a reduction of 50-95% is performed, and then 700- A method for producing a high-strength cold-rolled steel sheet excellent in deep drawability and chemical conversion treatability, which comprises performing recrystallization annealing in a temperature range of 950 ° C. and then performing carburizing treatment (first invention).
【0010】(2) 第1発明の鋼成分に加えてTi:0.005
〜0.06wt%を含有し、かつ、Ti含有量〔%Ti〕が、N,
S及びPの各含有量〔%N〕,〔%S〕及び〔%P〕と
の関係で次式 48(〔%Ti〕/48−〔%N〕/14−〔%S〕/32)×
〔%P〕≦0.0015 を満足する深絞り性と化成処理性とに優れた高強度冷延
鋼板の製造方法(第2発明)。(2) In addition to the steel composition of the first invention, Ti: 0.005
.About.0.06 wt%, and the Ti content [% Ti] is N,
The following formula 48 ([% Ti] / 48-[% N] / 14-[% S] / 32) is used in relation to the contents of S and P [% N], [% S] and [% P]. ×
A method for producing a high-strength cold-rolled steel sheet excellent in deep drawability and chemical conversion treatability satisfying [% P] ≦ 0.0015 (second invention).
【0011】(3) 第1発明又は第2発明の鋼成分に加え
て、Ni:0.01〜1.50wt%、Cu:0.1 〜1.5 wt%及びMo:
0.01〜1.50wt%の1種又は2種以上を含有する深絞り性
と化成処理性とに優れた高強度冷延鋼板の製造方法(第
3発明)。(3) In addition to the steel components of the first or second invention, Ni: 0.01-1.50 wt%, Cu: 0.1-1.5 wt% and Mo:
A method for producing a high-strength cold-rolled steel sheet which contains 0.01 to 1.50 wt% of one or more types and is excellent in deep drawability and chemical conversion treatability (third invention).
【0012】以下、この発明を開発する基礎となった研
究結果について述べる。 実験1 C:0.002 wt%、Si:0.1 〜2.0 wt%、Mn:0.5 〜3.0
wt%、P:0.02〜0.2wt%、S:0.005 wt%、Al:0.05w
t%、N:0.002 wt%、B:0.003 wt%及びNb:0.025 w
t%の成分組成になる種々の鋼スラブを1150℃で加熱−
均熱後、熱延仕上温度を700 ℃とする熱間圧延を潤滑を
施しつつ行った。引き続き得られた熱延板に、加熱速度
10℃/s、850 ℃で20 s均熱保持の再結晶焼鈍を施し、次
いで圧下率75%の冷間圧延を施した後、850 ℃、20sの
再結晶焼鈍を行い、引き続き脱炭処理を施した。The results of the research on which the present invention is based will be described below. Experiment 1 C: 0.002 wt%, Si: 0.1-2.0 wt%, Mn: 0.5-3.0
wt%, P: 0.02-0.2 wt%, S: 0.005 wt%, Al: 0.05w
t%, N: 0.002 wt%, B: 0.003 wt% and Nb: 0.025 w
Various steel slabs with t% composition are heated at 1150 ℃-
After soaking, hot rolling with a hot rolling finish temperature of 700 ° C was performed while lubricating. Continued heating rate for the hot-rolled sheet obtained
After performing recrystallization annealing at 10 ℃ / s and 850 ℃ for 20s soaking, followed by cold rolling with a rolling reduction of 75%, recrystallization annealing at 850 ℃ and 20s followed by decarburization treatment. gave.
【0013】かくして得られた冷延鋼板のr値に及ぼす
鋼成分の影響を調査した結果を図1に示す。図1から明
らかなように、鋼成分が、(3〔%Si〕/28+ 200〔%
P〕/31)/(〔%Mn〕/55):15〜40を満足する場合
において、r値が2.0 以上である特性が得られることが
判明した。FIG. 1 shows the results of an investigation of the effect of the steel components on the r value of the cold rolled steel sheet thus obtained. As is clear from Fig. 1, the steel composition is (3 [% Si] / 28 + 200 [%
P] / 31) / ([% Mn] / 55): In the case of satisfying 15 to 40, it was found that the characteristic that the r value was 2.0 or more was obtained.
【0014】実験2 C:0.002 wt%、Si:1.5 wt%、Mn:2.0 wt%、P:0.
10wt%、S:0.005 wt%、Al:0.05wt%、N:0.002 wt
%、Ni:0.5 wt%、B:0.003 wt%及びNb0.0025wt%の
成分組成になる鋼スラブ(Ar3 変態点:860 ℃)を1150
℃で加熱−均熱後、熱延仕上温度を600 〜980 ℃とする
潤滑又は無潤滑の熱間圧延を行った。引き続き得られた
熱延板を、加熱速度10℃/s、均熱条件850 ℃、20 sの再
結晶焼鈍を施した後、圧下率75%の冷間圧延を施し、次
いで850 ℃、20sの再結晶焼鈍を行った後、650 ℃で浸
炭処理を施した。Experiment 2 C: 0.002 wt%, Si: 1.5 wt%, Mn: 2.0 wt%, P: 0.
10 wt%, S: 0.005 wt%, Al: 0.05 wt%, N: 0.002 wt%
%, Ni: 0.5 wt%, B: 0.003 wt% and Nb 0.0025 wt% steel slab (Ar 3 transformation point: 860 ° C) of 1150
After heating and soaking at ℃, hot rolling was performed with or without lubrication at a hot rolling finish temperature of 600 to 980 ° C. Subsequently, the obtained hot-rolled sheet was subjected to recrystallization annealing at a heating rate of 10 ° C / s and a soaking condition of 850 ° C for 20 s, followed by cold rolling at a rolling reduction of 75%, and then at 850 ° C for 20 s. After recrystallization annealing, carburizing treatment was performed at 650 ° C.
【0015】かくして得られた冷延鋼板のr値に及ぼす
熱延仕上温度及び熱延時の潤滑の有無について調査した
結果を図2に示す。図2から明らかなように、潤滑を施
しつつ熱延仕上温度をAr3 変態点以下とすることによ
り、r値が2.0 以上である特性が得られる。FIG. 2 shows the results of an examination of the hot rolling finish temperature and the presence or absence of lubrication during hot rolling that affect the r value of the cold rolled steel sheet thus obtained. As is apparent from FIG. 2, when the hot rolling finish temperature is set to the Ar 3 transformation point or lower while lubrication is performed, the characteristic that the r value is 2.0 or higher is obtained.
【0016】さらに発明者らは、上記実験1,実験2よ
り得られた成分限定条件を満足する鋼において板厚方向
における炭素濃度を制御し、すなわち鋼板の片面又は両
面における板厚方向の炭素濃度分布について、表面から
板厚の10%に相当する深さ又はそれよりも表面寄りの層
での平均炭素濃度を母材の炭素濃度の1.3 倍以上とし、
かつその炭素濃度増加量が0.01wt%以下とすることによ
り、化成処理が大幅に向上した高強度冷延鋼板が製造可
能となることを見いだし、この発明に到ったのである。Furthermore, the inventors have controlled the carbon concentration in the plate thickness direction in the steel satisfying the component limiting conditions obtained in the above Experiment 1 and Experiment 2, that is, the carbon concentration in the plate thickness direction on one side or both sides of the steel plate. Regarding the distribution, the average carbon concentration in the layer corresponding to 10% of the plate thickness from the surface or in the layer closer to the surface is 1.3 times or more the carbon concentration of the base metal,
Further, it has been found that by setting the amount of increase in carbon concentration to 0.01 wt% or less, it becomes possible to manufacture a high-strength cold-rolled steel sheet with significantly improved chemical conversion treatment, and the present invention has been completed.
【0017】[0017]
【作用】上記したようにこの発明では、鋼成分は重要で
あり、かつそれに対応した製造条件でないと、優れた深
絞り性を確保することができない。以下、各成分、製造
条件について範囲を限定した理由について説明する。As described above, according to the present invention, the steel composition is important, and the excellent deep drawability cannot be secured unless the manufacturing conditions correspond to it. Hereinafter, the reasons for limiting the range of each component and manufacturing condition will be described.
【0018】1.組成 (1) C:0.01wt%以下 材質特性(深絞り性)上の要求による。すなわち、C量
が少ないほど深絞り性は向上するが、0.01wt%以下であ
れば悪影響を及ぼさないので0.01wt%以下に限定した。1. Composition (1) C: 0.01 wt% or less Due to requirements for material characteristics (deep drawability). That is, the deep drawability is improved as the amount of C is smaller, but if it is 0.01 wt% or less, no adverse effect is exerted, so the content is limited to 0.01 wt% or less.
【0019】(2) 0.1 〜2.0 wt% Siは、強度上の要求により含有させるものである。所望
の強度を得るには、0.1 wt%以上含有させる必要があ
り、また、2.0 wt%を超えて含有させると深絞り性等の
材料特性に悪影響を及ぼすため0.1 〜2.0 wt%の範囲に
限定した。 (3) Mn:0.5 〜3.0 wt% 強度上の要求による。すなわち、所望の強度を得るため
には0.5 wt%以上を含有させる必要があり、一方3.0 wt
%を超えて含有させると深絞り性等の材料特性に悪影響
を及ぼすため0.5 〜3.0 wt%の範囲に限定した。(2) 0.1 to 2.0 wt% Si is contained according to the strength requirement. In order to obtain the desired strength, it is necessary to contain 0.1 wt% or more, and if it exceeds 2.0 wt%, it adversely affects the material properties such as deep drawability, so it is limited to the range of 0.1 to 2.0 wt%. did. (3) Mn: 0.5-3.0 wt% Due to strength requirements. That is, it is necessary to contain 0.5 wt% or more to obtain the desired strength, while 3.0 wt%
If it is contained in excess of%, the material properties such as deep drawability are adversely affected, so the content is limited to 0.5 to 3.0 wt%.
【0020】(4) Nb:0.001 〜0.200 wt% Nbは、この発明において重要な成分である。Nbは、鋼中
の固溶Cを炭化物として析出固定させて低減し、深絞り
性に有利な{111}方位の結晶粒を優先的に形成させ
る効果がある。また、Nbを含有させることにより、仕上
圧延前組織が微細化し、熱延板焼鈍後に深絞り性に有利
な{111}方位を優先的に形成させる効果がある。そ
の含有量が0.001 wt%に満たないとこれらの効果はな
く、一方0.200 wt%を超えて含有させてもそれ以上の効
果の向上は見られないので0.001 〜0.200 wt%に限定し
た。(4) Nb: 0.001 to 0.200 wt% Nb is an important component in the present invention. Nb has the effect of precipitating and fixing the solid solution C in the steel as a carbide to reduce it and preferentially forming crystal grains in the {111} orientation, which is advantageous for deep drawability. In addition, the inclusion of Nb has the effect of making the pre-rolling structure finer and preferentially forming the {111} orientation advantageous for deep drawability after hot-rolled sheet annealing. If the content is less than 0.001 wt%, these effects do not occur. On the other hand, if the content exceeds 0.200 wt%, no further improvement in the effect is seen, so the content was limited to 0.001 to 0.200 wt%.
【0021】(5) B:0.0001〜0.0080wt% Bは、耐二次加工ぜい性を改善させるために含有させ
る。その含有量が0.0001wt%に満たないと効果はなく、
一方0.0080wt%を超えて含有させると深絞り性が劣化す
るため0.0001〜0.0080wt%に限定した。(5) B: 0.0001 to 0.0080 wt% B is contained in order to improve the secondary processing brittleness resistance. If the content is less than 0.0001 wt%, there is no effect,
On the other hand, if the content exceeds 0.0080 wt%, the deep drawability deteriorates, so the content was limited to 0.0001 to 0.0080 wt%.
【0022】(6) Al:0.03〜0.20wt% Alは、脱酸を行い、炭窒化物形成成分の歩留まりを向上
させるために必要量に応じて含有させるものであり、そ
の含有量が0.03wt%に満たないとその効果がなく、一方
0.20wt%を超えて含有させても、より一層の効果は得ら
れないため、0.03〜0.20wt%に限定した。(6) Al: 0.03 to 0.20 wt% Al is added according to the necessary amount in order to perform deoxidation and improve the yield of carbonitride forming components, and the content is 0.03 wt%. If less than%, the effect is not
Even if the content exceeds 0.20 wt%, no further effect can be obtained, so the content was limited to 0.03 to 0.20 wt%.
【0023】(7) P:0.02〜0.20wt% 強度上の要求による。すなわち、所望の強度を得るため
には0.002 wt%以上を含有させる必要があり、また0.20
wt%を超えて含有させると深絞り性等の材料特性に悪影
響を及ぼすため0.02〜0.20wt%に限定した。(7) P: 0.02 to 0.20 wt% According to strength requirements. That is, to obtain the desired strength, it is necessary to contain 0.002 wt% or more, and 0.20 wt% or more.
If it is contained in excess of wt%, it adversely affects the material properties such as deep drawability, so it was limited to 0.02 to 0.20 wt%.
【0024】(8) S:0.05wt%以下 S量が少なければ少ないほど、深絞り性は向上するが、
S量が0.05wt%以下であれば悪影響を及ぼさないので0.
05wt%以下に限定した。(8) S: 0.05 wt% or less The smaller the S content, the better the deep drawability.
If the amount of S is 0.05 wt% or less, it does not have an adverse effect.
Limited to less than 05wt%.
【0025】(9) N:0.01wt%以下 Nは、含有量が少なければ少ないほど、深絞り性が向上
するが、N量が0.01wt%以下であれば悪影響を及ぼさな
いのでかまわない。(9) N: 0.01 wt% or less If the content of N is smaller, the deep drawability is improved, but if the N content is 0.01 wt% or less, no adverse effect is exerted.
【0026】(10)〔%Nb〕/〔%C〕:5〜25 この発明では、上記C及びNbを、各含有量〔%C〕,
〔%Nb〕が次式 〔%Nb〕/〔%C〕:5〜25 の関係を満足する条件で含有させることが重要である。
〔%Nb〕/〔%C〕が5に満たない場合、鋼中に固溶C
が残留するので前述の請うかが得られない。また、〔%
Nb〕/〔%C〕が25より多い場合、鋼中に固溶Nbが多量
に残留するために熱延板の{111}再結晶集合組織は
発達せず、したがって冷延焼鈍板のr値は低い。したが
って、〔%Nb〕/〔%C〕:5〜25に限定した。(10) [% Nb] / [% C]: 5 to 25 In the present invention, the above C and Nb are contained in respective contents [% C],
It is important that the content of [% Nb] satisfies the following formula: [% Nb] / [% C]: 5 to 25.
When [% Nb] / [% C] is less than 5, solid solution C in steel
However, the above-mentioned contract cannot be obtained. Also,〔%
When Nb] / [% C] is more than 25, a large amount of solid solution Nb remains in the steel, so that the {111} recrystallization texture of the hot rolled sheet does not develop and therefore the r value of the cold rolled annealed sheet Is low. Therefore, it is limited to [% Nb] / [% C]: 5 to 25.
【0027】(11)この発明では、上記Si、Mn及びPを、
各含有量〔%Si〕,〔%Mn〕及び〔%P〕が、次式 (3〔%Si〕/28+ 200〔%P〕/31)/(〔%Mn〕/
55):15〜40 の関係を満足する条件で含有させることが必要である。
Si、Mn及びPは、上記のとおり固溶強化成分であり、所
要の強度に応じて含有させるものである。しかし、Si及
びPは、フェライト安定化成分であり、一方Mnは、オー
ステナイト安定化成分であるため、両安定化成分を適量
含有させることにより、変態点を制御する必要がある。
ここに、(3〔%Si〕/28+ 200〔%P〕/31)/
(〔%Mn〕/55)が15に満たないと、変態点が低下し、
一方40を超えると変態点が上昇しすぎるため、熱間圧延
時にオーステナイト域において熱延板結晶粒を微細化さ
せ、フェライト域において加工歪を蓄積することが困難
になる。したがって、15≦(3〔%Si〕/28+ 200〔%
P〕/31)/(〔%Mn〕/55)≦40に限定した。(11) In the present invention, the above Si, Mn and P are
Each content [% Si], [% Mn] and [% P] is calculated by the following formula (3 [% Si] / 28 + 200 [% P] / 31) / ([% Mn] /
55): It is necessary to contain it under the conditions that satisfy the relationship of 15-40.
Si, Mn, and P are solid solution strengthening components as described above, and are contained according to required strength. However, Si and P are ferrite stabilizing components, while Mn is an austenite stabilizing component. Therefore, it is necessary to control the transformation point by adding an appropriate amount of both stabilizing components.
Here, (3 [% Si] / 28 + 200 [% P] / 31) /
If ([% Mn] / 55) is less than 15, the transformation point will decrease,
On the other hand, if it exceeds 40, the transformation point rises too much, so that it becomes difficult to refine the crystal grains of the hot-rolled sheet in the austenite region during hot rolling and accumulate the working strain in the ferrite region. Therefore, 15 ≦ (3 [% Si] / 28 + 200 [%
P] / 31) / ([% Mn] / 55) ≦ 40.
【0028】(12)Ti:0.005 〜0.06wt% 第2発明においては、Tiを0.005 〜0.06wt%の範囲で含
有し、かつ、Ti含有量〔%Ti〕が、N,S及びPの各含
有量〔%N〕,〔%S〕及び〔%P〕との関係で次式 48(〔%Ti〕/48−〔%N〕/14−〔%S〕/32)×
〔%P〕≦0.0015 を満たすことが望ましい。Tiは、鋼中の固溶C,Nを析
出固定して減少し、深絞り性に有利な{111}方位を
優先的に形成させる効果がある。しかしながら、Tiは、
りん化物形成成分であり、鋼中に固溶Tiが多量に存在す
ると熱延板焼鈍中にTi−P化物が析出するため{11
1}集合組織が形成されず、その後に冷間圧延、焼鈍を
施してもr値は向上しない。そこでこの発明では、固溶
Ti量をP含有量との兼ね合いで定め、48(〔%Ti〕/48
−〔%N〕/14−〔%S〕/32)×〔%P〕が0.0015を
超えるとTi−P化物の析出量が多く、r値は劣化するた
めに 48(〔%Ti〕/48−〔%N〕/14−〔%S〕/32)×
〔%P〕≦0.0015 と限定した。(12) Ti: 0.005 to 0.06 wt% In the second invention, Ti is contained in the range of 0.005 to 0.06 wt% and the Ti content [% Ti] is N, S or P. In relation to the contents [% N], [% S] and [% P], the following formula 48 ([% Ti] / 48-[% N] / 14-[% S] / 32) x
It is desirable to satisfy [% P] ≦ 0.0015. Ti has the effect of precipitating and fixing the solid solutions C and N in the steel to reduce it, and preferentially forming the {111} orientation, which is advantageous for deep drawability. However, Ti is
It is a phosphide-forming component, and if a large amount of solid solution Ti is present in steel, Ti-P compound precipitates during hot-rolled sheet annealing {11
1} Texture is not formed, and even if cold rolling or annealing is performed thereafter, the r value is not improved. So, in this invention,
Determine the amount of Ti in consideration of the P content, 48 ([% Ti] / 48
When [-% N] / 14-[% S] / 32) x [% P] exceeds 0.0015, the amount of Ti-P compound precipitated is large and the r value deteriorates, so 48 ([% Ti] / 48). -[% N] / 14-[% S] / 32) x
It was limited to [% P] ≦ 0.0015.
【0029】第3発明では、Ni:0.01〜1.50wt%、Cu:
0.1 〜1.5 wt%及びMo:0.01〜1.50wt%の1種又は2種
以上を含有させる。これらの成分は、いずれも鋼の強化
成分である。 (13)Ni:0.01〜1.50wt% 強度上の要求による。すなわち、第3発明では所望の強
度に応じてNiを含有させるものであるが、その含有量が
0.01wt%に満たないと効果がなく、一方1.50wt%を超え
ると深絞り性等の材料特性上、悪影響を及ぼすので0.01
〜1.50wt%に限定した。In the third invention, Ni: 0.01-1.50 wt%, Cu:
One or more of 0.1 to 1.5 wt% and Mo: 0.01 to 1.50 wt% are contained. All of these components are reinforcing components of steel. (13) Ni: 0.01 to 1.50 wt% Due to strength requirements. That is, in the third invention, Ni is contained according to the desired strength, but the content is
If it is less than 0.01 wt%, it has no effect. On the other hand, if it exceeds 1.50 wt%, it adversely affects the material properties such as deep drawability.
Limited to ~ 1.50wt%.
【0030】(14)Cu:0.1 〜1.5 wt% Cuは、鋼を強化する作用があり、第3発明では所望の強
度に応じて含有させるものであるが、その含有量が0.1
wt%に満たないと効果がなく、一方1.5 wt%を超えると
深絞り性に悪影響を与えるので0.1 〜1.5 wt%に限定し
た。(14) Cu: 0.1 to 1.5 wt% Cu has the effect of strengthening the steel, and is contained according to the desired strength in the third invention, but the content is 0.1.
If it is less than wt%, it has no effect. On the other hand, if it exceeds 1.5 wt%, it adversely affects the deep drawability.
【0031】(15)Mo:0.01〜1.5 wt% Moは、鋼を強化する作用があり、第3発明では所望の強
度に応じて含有させるものであるが、その含有量が0.01
wt%に満たないと効果がなく、一方1.5 wt%を超えると
深絞り性に悪影響を与えるので0.01〜1.5 wt%に限定し
た。(15) Mo: 0.01 to 1.5 wt% Mo has the effect of strengthening the steel and is contained according to the desired strength in the third invention, but the content is 0.01.
If it is less than wt%, it has no effect, while if it exceeds 1.5 wt%, it adversely affects the deep drawability, so it was limited to 0.01 to 1.5 wt%.
【0032】2.製造条件 以下、この発明で製造条件について限定した理由につい
て説明する。 (1) 熱間圧延 熱間圧延工程では、Ar3 変態点以下、500 ℃以上の温度
域にて潤滑を施しつつ合計圧下量が50%以上95%以下に
なる仕上圧延工程を施す。ここに、熱間圧延をAr3 変態
点よりも高い温度域で行うと、圧延後にγ−α変態によ
り集合組織がランダム化するため、熱延板に{111}
集合組織が形成されず、そのため冷延−焼鈍後には低い
r値しか得られない。一方、500 ℃未満に仕上圧延温度
を低下させても、より高いr値は望めず、圧延荷重が増
大するのみであるので、仕上圧延温度はAr3 変態点以下
500 ℃以上に限定した。2. Manufacturing Conditions The reasons for limiting the manufacturing conditions in the present invention will be described below. (1) Hot rolling In the hot rolling step, a finish rolling step is performed in which the total reduction amount is 50% or more and 95% or less while performing lubrication in a temperature range of Ar 3 transformation point or less and 500 ° C. or more. If hot rolling is performed here in a temperature range higher than the Ar 3 transformation point, the texture becomes random due to γ-α transformation after rolling, so that {111} on the hot rolled sheet.
No texture is formed and therefore only low r-values are obtained after cold rolling-annealing. On the other hand, even if the finishing rolling temperature is lowered to less than 500 ° C, a higher r value cannot be expected and only the rolling load increases, so the finishing rolling temperature is below the Ar 3 transformation point.
Limited to above 500 ° C.
【0033】この仕上圧延の圧下率は、50%に満たない
と熱延板に{111}集合組織が形成されず、一方、95
%を超えると熱延板にr値に好ましくない集合組織が形
成するという不都合が生ずるので50%以上95%以下に限
定した。If the reduction ratio of this finish rolling is less than 50%, the {111} texture is not formed in the hot-rolled sheet, while
%, The disadvantage is that an unfavorable texture is formed in the hot-rolled sheet in the r value, so the content is limited to 50% or more and 95% or less.
【0034】さらに仕上圧延すなわちAr3 変態点以下の
圧延を無潤滑圧延にすると、ロールと鋼板との間の摩擦
力に起因するせん断変形により、深絞り性に好ましくな
い{110}方位の結晶粒が鋼板表層部に優先的に形成
され、r値の向上が望めないので深絞り性を確保するた
めには潤滑圧延とすることが必要である。Further, when finish rolling, that is, rolling below the Ar 3 transformation point is made non-lubricating rolling, due to shear deformation due to frictional force between the roll and the steel sheet, crystal grains of {110} orientation unfavorable for deep drawability. Is preferentially formed on the surface layer of the steel sheet, and the improvement of the r value cannot be expected. Therefore, in order to secure deep drawability, it is necessary to carry out lubrication rolling.
【0035】ここに上記圧延におけるロール径、ロール
の構造、潤滑剤の種類並びに圧延機の種類は任意で良
い。また、上記の圧延より前の工程については特に限定
するものではなく、例えば圧延素材については、連続鋳
造スラブを再加熱又は連続鋳造後、Ar3 変態点以下に降
温することなく直ちに、又は保温処理したものを粗圧延
にてシートバーにしたものを使用するのが好適である。Here, the roll diameter, the roll structure, the type of lubricant and the type of rolling mill in the above rolling may be arbitrary. Further, the process before the rolling is not particularly limited, for example, for the rolling material, after reheating or continuous casting of the continuous casting slab, immediately without lowering the temperature below the Ar 3 transformation point, or heat retention treatment. It is preferable to use a sheet bar obtained by rough rolling the obtained sheet.
【0036】(2) 熱延板再結晶処理工程 この発明の鋼は、熱延終了温度がAr3 変態点以下である
ため、熱延板は加工組織を呈している。そのため、この
熱延板には次いで再結晶処理を施して{111}方位の
結晶粒を形成させる必要がある。再結晶処理を施さない
と、熱延板に{111}方位が形成されないため、その
後の冷延−焼鈍によっても高いr値は望めない。この熱
延板再結晶処理は、熱延後の巻取工程又は再結晶焼鈍工
程によって行う。巻取工程より再結晶処理を施す場合に
は、巻取温度は650 ℃以上が適する。巻取温度が 650℃
に満たないと、熱延板は再結晶し難く、熱延板に{11
1}方位が形成され難いので、その後の冷延−焼鈍によ
ってもr値の向上は望めない。また再結晶焼鈍工程によ
り再結晶処理を施す場合には、バッチ焼鈍又は連続焼鈍
のいずれもが適するが連続焼鈍が好ましく、その焼鈍温
度は、700 〜950 ℃が好ましい。焼鈍温度が700 ℃より
低いと{111}集合組織が発達せず、950 ℃より高い
とα−γ変態により集合組織がランダム化する。(2) Hot-rolled sheet recrystallization treatment step In the steel of the present invention, the hot-rolled finish temperature is not higher than the Ar 3 transformation point, so that the hot-rolled sheet has a worked structure. Therefore, it is necessary to subsequently subject this hot-rolled sheet to recrystallization treatment to form crystal grains of {111} orientation. If the recrystallization treatment is not performed, the {111} orientation is not formed in the hot rolled sheet, so that a high r value cannot be expected even by the subsequent cold rolling-annealing. This hot-rolled sheet recrystallization treatment is performed by a winding step or a recrystallization annealing step after hot rolling. When performing recrystallization treatment from the winding step, the winding temperature is preferably 650 ° C or higher. Winding temperature is 650 ℃
If it is less than, it is difficult to recrystallize the hot rolled sheet,
Since it is difficult to form the 1} orientation, improvement of the r value cannot be expected even by subsequent cold rolling-annealing. When the recrystallization treatment is performed in the recrystallization annealing step, either batch annealing or continuous annealing is suitable, but continuous annealing is preferable, and the annealing temperature is preferably 700 to 950 ° C. If the annealing temperature is lower than 700 ° C, the {111} texture does not develop, and if it is higher than 950 ° C, the texture becomes random due to α-γ transformation.
【0037】(3) 冷間圧延工程 この工程は、高いr値を得るためは必要不可欠であり、
熱延焼鈍板を圧下率50〜95%で冷間圧延を行う。圧下率
の増加と共に、冷延−焼鈍後の鋼板のr値は向上する
が、圧下率が95%を超えるとr値はかえって劣化する。(3) Cold rolling step This step is indispensable for obtaining a high r value,
Cold rolling is performed on the hot rolled annealed sheet at a reduction rate of 50 to 95%. The r-value of the steel sheet after cold rolling-annealing increases as the rolling reduction increases, but the r-value rather deteriorates when the rolling reduction exceeds 95%.
【0038】(4) 冷延板焼鈍工程 加工組織となっている冷延板に700 〜950 ℃で焼鈍を施
すことによって{111}集合組織が発達し高いr値が
得られる。焼鈍温度が700 ℃より低い場合、再結晶組織
は未発達であり、得られるr値は低い。また、950 ℃よ
り高い温度で焼鈍を施すと、冷却過程においてオーステ
ナイトからフェライトへの変態を生ずるため、{11
1}再結晶集合組織はランダム化し、低いr値しか得ら
れない。この再結晶焼鈍は、箱型焼鈍法及び連続型焼鈍
法のいずれでもよいが、連続焼鈍法が好ましい。(4) Cold Rolled Sheet Annealing Process By annealing a cold rolled sheet having a worked structure at 700 to 950 ° C., a {111} texture is developed and a high r value is obtained. When the annealing temperature is lower than 700 ° C, the recrystallization structure is undeveloped and the obtained r value is low. Further, if annealing is performed at a temperature higher than 950 ° C, austenite-to-ferrite transformation occurs in the cooling process.
1} The recrystallization texture is randomized and only a low r value can be obtained. The recrystallization annealing may be either a box annealing method or a continuous annealing method, but the continuous annealing method is preferable.
【0039】(5) 浸炭処理 鋼板の両面あるいは片面における表層の炭素含有量を目
的とする特性に適合するように調整するのは重要であ
り、板厚方向でのC濃度分布が鋼板の片面又は両面にお
いて表面から板厚の10%に相当する深さ又は板厚の10%
の深さに満たない厚さの層にて、平均C濃度が母材の炭
素濃度の1.3 倍以上でありそのC濃度増加量は0.01wt%
以下であるようにする。このような浸炭処理は、再結晶
焼鈍後、引き続き500 ℃以上のフェライト域における加
熱保持中または冷却中に浸炭雰囲気とするか、再結晶焼
鈍後、一旦冷却した後に500 ℃以上のフェライト域に解
加熱し浸炭処理を行って処理する。かくして、{11
1}再結晶集合組織が十分発達した後にCが表面に侵入
するため、r値には悪影響を与えない。その一方で侵入
したCにより鋼板表面層の性状が変化し、それによって
化成処理性が改善されるのである。なお、Ar3 変態点よ
りも高い温度で浸炭処理を施すと、冷却過程においてオ
ーステナイトからフェライトへの変態を生ずるため、
{111}再結晶集合組織はランダム化し、低いr値し
か得られない。浸炭雰囲気としては、N2+H2を主体とす
るガス中にCOを適量添加したものを用いる。そして浸炭
条件は適切に選定する。また、特にCAL設備における
加熱、均熱及び冷却ゾーンのうち、均熱ゾーンにかけて
浸炭に適する条件で行う方法が効果的である。(5) Carburizing It is important to adjust the carbon content of the surface layer on both sides or one side of the steel sheet so as to match the desired characteristics, and the C concentration distribution in the sheet thickness direction should be one side or Depth equivalent to 10% of plate thickness from the surface on both sides or 10% of plate thickness
The average C concentration is 1.3 times or more of the carbon concentration of the base metal and the C concentration increase amount is 0.01 wt%
Do the following: Such a carburizing treatment is carried out after recrystallization annealing, and then in a carburizing atmosphere during heating and holding or cooling in the ferrite region of 500 ° C or higher, or after recrystallization annealing, after cooling once, it is dissolved in the ferrite region of 500 ° C or higher. It is treated by heating and carburizing. Thus, {11
1) C does not adversely affect the r value because C penetrates into the surface after the recrystallized texture is sufficiently developed. On the other hand, the invading C changes the properties of the steel sheet surface layer, thereby improving the chemical conversion treatability. If carburizing is performed at a temperature higher than the Ar 3 transformation point, austenite-to-ferrite transformation occurs in the cooling process.
The {111} recrystallized texture is randomized and only a low r value is obtained. As the carburizing atmosphere, a gas containing N 2 + H 2 as a main component and containing an appropriate amount of CO is used. And the carburizing conditions should be selected appropriately. In addition, among the heating, soaking, and cooling zones in the CAL facility, a method of performing the soaking zone under conditions suitable for carburization is particularly effective.
【0040】[0040]
【実施例】表1に示す種々の成分組成になる鋼スラブを
準備した。なお表1において、数値がこの発明の範囲を
外れるものには下線をひいてある。EXAMPLES Steel slabs having various compositional compositions shown in Table 1 were prepared. In Table 1, the numerical values outside the range of the present invention are underlined.
【0041】[0041]
【表1】 [Table 1]
【0042】これらのスラブに熱間圧延を施し、その後
熱延板焼鈍を行った。得られた熱延板を酸洗後、冷間圧
延を施し板厚0.7 mmの冷延鋼帯にした後、連続焼鈍設備
にて再結晶焼鈍を施し、次いで浸炭処理を施した。これ
らの熱延条件、熱延板焼鈍条件、冷延条件、冷延板焼鈍
条件及び浸炭処理条件を表2に示す。These slabs were hot-rolled and then hot-rolled sheet annealed. The obtained hot-rolled sheet was pickled, cold-rolled to form a cold-rolled steel strip having a sheet thickness of 0.7 mm, recrystallization annealed in a continuous annealing facility, and then carburized. Table 2 shows these hot rolling conditions, hot rolled sheet annealing conditions, cold rolling conditions, cold rolled sheet annealing conditions and carburizing treatment conditions.
【0043】[0043]
【表2】 [Table 2]
【0044】このようにして得られた冷延鋼板の材料特
性及び化成処理性について調べた結果を表2に併記し
た。ここにr値は、引張予ひずみを15%与え、3点法に
て求め、L方向(圧延方向)、D方向(圧延方向から45
度方向)及びC方向(圧延方向から90度方向)の値をr
値を測定し、平均のr値を r値=(rL +2rD +rC )/4 の式から求めた。さらに、化成処理性は、鋼板を脱脂、
水洗後、リン酸塩処理を施し、特に処理の初期(15秒)
におけるリン酸塩の核発生数を調べた。核の発生数が多
いほど、最終的に形成される化成処理膜は綿密になり、
その後の塗装膜の特性が優れていることがわかってい
る。この塗装膜の評価は、良好を○印、むらありを△
印、透けありを×印で表2に示した。Table 2 also shows the results of an examination of the material properties and chemical conversion treatability of the cold-rolled steel sheet thus obtained. Here, the r value is obtained by the three-point method by giving 15% of tensile prestrain, and L direction (rolling direction), D direction (45 from rolling direction).
Direction) and C direction (90 ° from rolling direction)
The value was measured, and the average r value was calculated from the formula r value = (r L + 2r D + r C ) / 4. Furthermore, the chemical conversion treatability degreases the steel sheet,
After washing with water, phosphate treatment is applied, especially at the beginning of the treatment (15 seconds)
The number of nuclei of phosphate was investigated. As the number of nuclei generated increases, the chemical conversion treatment film that is finally formed becomes more detailed,
It has been found that the properties of the subsequent coating film are excellent. The evaluation of this coating film is good for ○ and uneven for △.
Table 2 shows the mark and the presence of transparency.
【0045】[0045]
【発明の効果】この発明によれば、鋼成分及び製造方法
を限定することにより、従来よりも格段に優れた化成処
理性及び深絞り性を有する高強度冷延鋼板の製造が可能
となる。According to the present invention, by limiting the steel composition and the manufacturing method, it becomes possible to manufacture a high strength cold-rolled steel sheet having chemical conversion treatability and deep drawability which are far superior to those in the past.
【図面の簡単な説明】[Brief description of drawings]
【図1】鋼中のSi量、P量及びMn量が、製品のr値に及
ぼす影響を示すグラフである。FIG. 1 is a graph showing the influence of the Si content, P content, and Mn content in steel on the r value of a product.
【図2】製品のr値に及ぼす熱延仕上温度及び熱延時の
潤滑の有無の影響を示すグラフである。FIG. 2 is a graph showing the influence of hot rolling finish temperature and the presence / absence of lubrication during hot rolling on the r value of the product.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C22C 38/16 (72)発明者 今中 誠 千葉県千葉市中央区川崎町1番地 川崎製 鉄株式会社技術研究本部内 (72)発明者 坂田 敬 千葉県千葉市中央区川崎町1番地 川崎製 鉄株式会社技術研究本部内 (72)発明者 加藤 俊之 千葉県千葉市中央区川崎町1番地 川崎製 鉄株式会社技術研究本部内─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification number Reference number within the agency FI Technical indication location C22C 38/16 (72) Inventor Makoto Imanaka 1 Kawasaki-cho, Chuo-ku, Chiba-shi, Chiba Kawasaki Steel Corporate Research & Development Co., Ltd. (72) Inventor Takashi Sakata 1 Kawasaki-cho, Chuo-ku, Chiba, Chiba Prefecture Inside Steel Engineering Co., Ltd.
Claims (3)
b〕が、次式 〔%Nb〕/〔%C〕:5〜25 の関係を満たす条件で、さらに上記Si,Mn,Pは、各含
有量〔%Si〕,〔%Mn〕及び〔%P〕が、次式 (3〔%Si〕/28+ 200〔%P〕/31)/(〔%Mn〕/
55):15〜40 の関係を満足する条件で含有する基本成分になり、残部
はFe及び不可避的不純物よりなる鋼素材に、 Ar3 変態点以下、500 ℃以上の温度域にて潤滑を施しつ
つ合計圧下量が50%以上95%以下になる圧延加工を施し
た後、熱延板再結晶処理を施し、次いで圧下率50〜95%
の冷間圧延を施し、その後に700 〜950 ℃の温度域での
再結晶焼鈍を施し、引き続き浸炭処理を施すことを特徴
とする深絞り性と化成処理性とに優れた高強度冷延鋼板
の製造方法。1. C: 0.01 wt% or less, Si: 0.1 to 2.0 wt%, Mn: 0.5 to 3.0 wt%, Nb: 0.001 to 0.200 wt%, B: 0.0001 to 0.0080 wt%, Al: 0.03 to 0.20 wt. %, P: 0.02 to 0.20 wt%, S: 0.05 wt% or less and N: 0.01 wt% or less, and the above C and Nb are the respective contents [% C], [% N].
b] is a condition satisfying the following formula [% Nb] / [% C]: 5 to 25, and Si, Mn, and P are each content [% Si], [% Mn] and [% P] is the following formula (3 [% Si] / 28 + 200 [% P] / 31) / ([% Mn] /
55): it becomes a basic component containing the condition satisfying the 15-40 relationship, balance the steel material consisting of Fe and unavoidable impurities, Ar 3 or less transformation point, lubricating alms at a temperature range of not lower than 500 ° C. While rolling the total reduction amount to 50% or more and 95% or less, the hot rolled sheet is recrystallized, and then the reduction rate is 50 to 95%.
Cold rolled steel sheet, followed by recrystallization annealing in the temperature range of 700 to 950 ° C, followed by carburizing treatment. High strength cold rolled steel sheet with excellent deep drawability and chemical conversion treatability. Manufacturing method.
各含有量〔%N〕,〔%S〕及び〔%P〕との関係で次
式 48(〔%Ti〕/48−〔%N〕/14−〔%S〕/32)×
〔%P〕≦0.0015 を満足する請求項1記載の深絞り性と化成処理性とに優
れた高強度冷延鋼板の製造方法。2. The steel material contains Ti: 0.005 to 0.06 wt% in addition to the basic components, and the Ti content [% Ti] is the content of each of N, S and P [% N], In relation to [% S] and [% P], the following formula 48 ([% Ti] / 48-[% N] / 14-[% S] / 32) x
The method for producing a high-strength cold-rolled steel sheet having excellent deep drawability and chemical conversion treatability according to claim 1, which satisfies [% P] ≦ 0.0015.
絞り性と化成処理性とに優れた高強度冷延鋼板の製造方
法。3. The steel material contains one or more of Ni: 0.01 to 1.50 wt%, Cu: 0.1 to 1.5 wt% and Mo: 0.01 to 1.50 wt% in addition to the basic components. Alternatively, the method for producing a high-strength cold-rolled steel sheet having excellent deep drawability and chemical conversion treatability according to 2.
Priority Applications (1)
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JP23489593A JP3401297B2 (en) | 1993-09-21 | 1993-09-21 | Method for producing high-strength cold-rolled steel sheet excellent in deep drawability and chemical conversion property |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23489593A JP3401297B2 (en) | 1993-09-21 | 1993-09-21 | Method for producing high-strength cold-rolled steel sheet excellent in deep drawability and chemical conversion property |
Publications (2)
Publication Number | Publication Date |
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JPH0790386A true JPH0790386A (en) | 1995-04-04 |
JP3401297B2 JP3401297B2 (en) | 2003-04-28 |
Family
ID=16977994
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JP23489593A Expired - Fee Related JP3401297B2 (en) | 1993-09-21 | 1993-09-21 | Method for producing high-strength cold-rolled steel sheet excellent in deep drawability and chemical conversion property |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0936279A4 (en) * | 1997-08-05 | 2004-04-21 | Jfe Steel Corp | Thick cold rolled steel sheet excellent in deep drawability and method of manufacturing the same |
-
1993
- 1993-09-21 JP JP23489593A patent/JP3401297B2/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0936279A4 (en) * | 1997-08-05 | 2004-04-21 | Jfe Steel Corp | Thick cold rolled steel sheet excellent in deep drawability and method of manufacturing the same |
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Publication number | Publication date |
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JP3401297B2 (en) | 2003-04-28 |
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