JPH0780234A - Rotary type gas separating apparatus - Google Patents

Rotary type gas separating apparatus

Info

Publication number
JPH0780234A
JPH0780234A JP5225731A JP22573193A JPH0780234A JP H0780234 A JPH0780234 A JP H0780234A JP 5225731 A JP5225731 A JP 5225731A JP 22573193 A JP22573193 A JP 22573193A JP H0780234 A JPH0780234 A JP H0780234A
Authority
JP
Japan
Prior art keywords
valve plate
gas
adsorption apparatus
lining
resin lining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP5225731A
Other languages
Japanese (ja)
Inventor
Sadamu Takahashi
定 高橋
Kunio Sagi
邦夫 佐木
Kazuaki Oshima
一晃 大嶋
Kiichiro Ogawa
紀一郎 小川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP5225731A priority Critical patent/JPH0780234A/en
Publication of JPH0780234A publication Critical patent/JPH0780234A/en
Withdrawn legal-status Critical Current

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  • Separation Of Gases By Adsorption (AREA)

Abstract

PURPOSE:To improve the durability and gas sealing properties of a rotary sliding part by lining either one of sliding face of a valve plate or an adsorption apparatus with a wear resistant resin, inserting an intermediate material made of a polymer material different from the resin lining between the wear resistant resin lining and one of the base materials of valve plate and the adsorption apparatus, and bonding the intermediate material to them. CONSTITUTION:A rotary type gas separation apparatus has an adsorption apparatus which has a plurality of partitioned chambers partitioned in circumferential direction and a valve plate 4 which is provided with two or more ports and brought into contact with the adsorption apparatus and the separation apparatus carries out continuous gas treatment by relative rotation of the valve plate 4 and the adsorption apparatus. In the rotary type gas separation apparatus, either one sliding face 16 of the valve plate 4 or the adsorption apparatus is lined with a wear resistant resin 18, an intermediate material 17 made of a polymer material different from the resin lining 18 and formed into a monolayer or a multilayer body is inserted between the resin lining material 18 and either one of base materials of the valve plate 14 or the adsorption apparatus, and it is bonded to them. As a result, the durability and gas sealing properties of the rotary sliding part are improved.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、混合ガスから特定ガス
を吸着により分離すると共に吸着されたガスを離脱させ
るようにした圧力スイング型の回転式ガス分離装置に関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pressure swing type rotary gas separation device for separating a specific gas from a mixed gas by adsorption and releasing the adsorbed gas.

【0002】[0002]

【従来の技術】ガス回収装置(溶剤回収装置、CO2
収装置等)やガス分離装置(N2 ,O 2 発生装置等)と
して圧力スイング方式のガス分離装置が使われる。図2
から図4に従来の圧力スイング方式ガス回収装置を示
す。原料ガスは、ブロアー13により昇圧されて下弁板
4の原料ガスポート8から、吸着塔1に供給される。こ
の吸着塔1は仕切板3により円周方向に複数の区画室2
に分割されており、区画室2に供給されたガスからは、
同区画室2に充填されている吸着剤によって選択的に特
定ガスが吸着され、吸着されなかったガスが上部弁板5
のポート9を経由して精製ガスとして排出される。
2. Description of the Related Art Gas recovery equipment (solvent recovery equipment, CO2Times
Collection device) and gas separation device (N2, O 2Generator etc.)
Then, a pressure swing type gas separator is used. Figure 2
Fig. 4 shows a conventional pressure swing type gas recovery device.
You The raw material gas is boosted by the blower 13 and is supplied to the lower valve plate.
From the raw material gas port 8 of No. 4, it is supplied to the adsorption tower 1. This
The adsorption tower 1 is divided into a plurality of compartments 2 in the circumferential direction by the partition plate 3.
The gas supplied to the compartment 2 is divided into
The adsorbent filled in the same compartment 2 selectively features
The constant gas is adsorbed, and the gas not adsorbed is the upper valve plate 5.
It is discharged as a purified gas via the port 9 of.

【0003】吸着塔1の回転に伴い特定ガスを吸着した
区画室2は、下弁板4の原料ガスポート8から離れてい
く。その後続いて、再生された吸着剤を充填している新
たな区画室が、原料ガスポート8に連通し供給されたガ
スから特定ガスを吸着して精製ガスを排出するようにな
る。
With the rotation of the adsorption tower 1, the compartment 2 in which the specific gas is adsorbed moves away from the raw material gas port 8 of the lower valve plate 4. Then, subsequently, the new compartment filled with the regenerated adsorbent adsorbs the specific gas from the gas supplied to the raw material gas port 8 and discharges the purified gas.

【0004】一方、原料ガスポート8から離れていった
特定ガス吸着済みの区画室2は、吸着塔1の回転に伴
い、下弁板4の特定ガス回収ポート7と連通するように
なり、同ポート7につながる真空ポンプ14で減圧され
て吸着していた特定ガスを脱離させ、これを回収させる
と共に吸着剤も再生され、再び、特定ガスを吸着できる
新生状態になる。このとき、特定ガスの脱離を容易にす
るため、上部弁板5のパージガスポート10から精製ガ
スをパージガスとして供給する。
On the other hand, the compartment 2 that has been adsorbed with the specific gas and has moved away from the raw material gas port 8 comes into communication with the specific gas recovery port 7 of the lower valve plate 4 as the adsorption tower 1 rotates. The specific gas that has been adsorbed by being decompressed by the vacuum pump 14 connected to the port 7 is desorbed and recovered, and the adsorbent is also regenerated, so that a new state in which the specific gas can be adsorbed is restored. At this time, in order to facilitate desorption of the specific gas, the purified gas is supplied as the purge gas from the purge gas port 10 of the upper valve plate 5.

【0005】吸着塔1は、駆動軸6からキー15を介し
て回転を与えられる。そして、上下の弁板4,5が吸着
塔1とつれ回らないように回り止め11が設けられてい
る。ところで、回転する吸着塔1と、弁板4,5とが接
触している面は、この間のガスリークを防ぐシール作用
を有する摺動面16であり、シール性向上を図るため、
この摺動面16にスプリング12で荷重を加え、シール
面に隙間が少なくなるように配慮している。
The adsorption tower 1 is rotated by a drive shaft 6 via a key 15. A detent 11 is provided to prevent the upper and lower valve plates 4 and 5 from moving around with the adsorption tower 1. By the way, the surface where the rotating adsorption tower 1 is in contact with the valve plates 4 and 5 is a sliding surface 16 having a sealing action to prevent gas leakage between them, and in order to improve the sealing performance,
A load is applied to the sliding surface 16 by the spring 12 so as to reduce the gap on the sealing surface.

【0006】[0006]

【発明が解決しようとする課題】回転する吸着塔1と弁
板4,5間の摺動面16は、乾燥面であり通常の炭素鋼
や低合金鋼の組み合わせ状態では小さな荷重(面圧)で
焼き付きや、異常摩耗を生じるため、ガスリーク量増
大、装置停止といった問題が生じる。このため、荷重
(面圧)を軽減したり、乾燥摺動性に優れた材料を組合
わせる等の方法を採用しているが、処理ガス量が増える
と、吸着塔径、弁板径が大きくなり、シール面の加工精
度低下により平坦度が得られなくなる。従って、荷重
(面圧)を軽減したのでは、摺動面のシール隙間を小さ
くできず、ガスリーク量を許容値におさめられない。
The sliding surface 16 between the rotating adsorption tower 1 and the valve plates 4 and 5 is a dry surface, and a small load (contact pressure) is applied in the normal combined state of carbon steel and low alloy steel. In this case, seizure and abnormal wear occur, which causes problems such as an increase in gas leak amount and device stoppage. For this reason, methods such as reducing the load (contact pressure) and combining materials with excellent dry slidability are adopted, but when the amount of treated gas increases, the adsorption tower diameter and valve plate diameter increase. As a result, the flatness cannot be obtained because the processing accuracy of the sealing surface is reduced. Therefore, if the load (surface pressure) is reduced, the seal gap on the sliding surface cannot be reduced, and the gas leak amount cannot be kept to an allowable value.

【0007】また、乾燥摺動性が良好なテフロン等の樹
脂材料を使用する場合、それらの樹脂材料を母材と接着
剤で接着することになるが、摺動面の摩擦発熱による温
度上昇の影響で、樹脂材料と母材との線膨張係数の違い
に起因した熱応力の繰り返しを受け、接着層が早期に剥
離してここからガスリークを起こす欠点がある。
Further, when resin materials such as Teflon having good dry slidability are used, these resin materials are bonded to the base material with an adhesive, but the temperature rise due to frictional heat generation of the sliding surface. Due to the influence, there is a drawback that thermal stress is repeated due to the difference in linear expansion coefficient between the resin material and the base material, the adhesive layer peels off early, and gas leaks from there.

【0008】本発明は、回転摺動部分の耐久性とガス密
封性を向上させると共に、大型のものも容易に製作する
ことのできる回転式ガス分離装置を提供することを課題
としている。
It is an object of the present invention to provide a rotary gas separation device capable of improving the durability and gas tightness of a rotary sliding portion and easily manufacturing a large size one.

【0009】[0009]

【課題を解決するための手段】本発明は、円周方向に区
画された複数個の区画室を有する吸着器、及び二つ以上
のポートを具え前記吸着器に当接される弁板を有し、同
弁板及び吸着器の相対回転により連続的にガス処理を行
う回転式ガス分離装置における前記課題を解決するた
め、前記弁板及び前記吸着器の少くともいづれか一方の
摺動面に耐摩耗樹脂ライニングを施し、かつ、同樹脂ラ
イニングとは別種の樹脂やプラスチック、ラバー等の高
分子材料を単層又は積層状態として形成させた中間部材
を、前記弁板及び吸着器の少くともいづれか一方の母材
と前記耐摩耗樹脂ライニング材の間に挿入接着した構成
を採用する。
The present invention has an adsorber having a plurality of compartments partitioned in the circumferential direction, and a valve plate having two or more ports and abutting against the adsorber. However, in order to solve the above-mentioned problems in the rotary gas separation device that continuously processes the gas by the relative rotation of the valve plate and the adsorber, at least one sliding surface of the valve plate and the adsorber is resistant. At least one of the valve plate and the adsorber is provided with an intermediate member which is provided with a wear resin lining and is formed of a polymer material such as resin, plastic, rubber or the like different from the resin lining in a single layer or a laminated state. The base material and the wear resistant resin lining material are inserted and bonded.

【0010】この中間部材の線膨張係数は表面摺動材の
線膨張係数より小さく、しかし母材の線膨張係数よりも
大きくし、また、中間材の縦弾性係数を表面樹脂材の縦
弾性係数に近づけるのが好ましい。
The coefficient of linear expansion of this intermediate member is smaller than that of the surface sliding material, but larger than that of the base material, and the longitudinal elastic coefficient of the intermediate material is the longitudinal elastic coefficient of the surface resin material. It is preferable to approach

【0011】[0011]

【作用】摺動性が良好な樹脂材料をライニングした場合
の接着層疲労剥離問題は、第一に、その原因である温度
上昇を抑えて解決する必要がある。このためには、摺動
面荷重(面圧)を下げることが要求されるが、この場
合、従来法ではシール隙間を小さく出来ない問題が背後
にあった。しかし、本発明では小さい荷重で大きな弾性
変形を生じる高分子系の中間部材(縦弾性係数が小さ
い)を耐摩耗樹脂ライニング材と母材との間に挿入した
構成を有することから、加工精度低下により増大したシ
ール隙間も少ない荷重で小さくでき、ライニング材の温
度上昇が抑制され剥離を防止する作用がある。
The function of the adhesive layer fatigue peeling when a resin material having good slidability is lined must first be solved by suppressing the temperature rise which is the cause. For this purpose, it is required to reduce the load (contact pressure) on the sliding surface. In this case, however, there is a problem that the conventional method cannot reduce the seal gap. However, in the present invention, since a polymer-based intermediate member (having a small longitudinal elastic coefficient) that causes large elastic deformation under a small load is inserted between the wear-resistant resin lining material and the base material, the processing accuracy is reduced. Due to this, the increased seal gap can be reduced with a small load, and the rise in the temperature of the lining material is suppressed, and peeling is prevented.

【0012】しかしながら、中間部材の線膨張係数が表
面の耐摩耗樹脂ライニング材と同じであれば、中間部材
を含めたライニング厚みが増した分、母材間での熱応力
が上昇し、温度上昇を抑制した効果が全くなくなる。そ
こで、中間部材の線膨張係数を表面のライニング材のそ
れに比べ小さくし、母材のそれよりも大きくすれば、厚
み増加による熱応力上昇以上に低減方向に作用する。ま
た、中間部材の縦弾性係数を表面の耐摩耗性樹脂材料の
それに近づけることも、熱応力軽減方向に作用するので
好ましい。
However, if the linear expansion coefficient of the intermediate member is the same as that of the wear-resistant resin lining material on the surface, the thermal stress between the base materials increases due to the increase in the lining thickness including the intermediate member, and the temperature rises. The effect of suppressing is completely lost. Therefore, if the linear expansion coefficient of the intermediate member is made smaller than that of the lining material on the surface and larger than that of the base material, the thermal stress due to the increase in thickness acts more than the increase in thermal stress. It is also preferable to make the longitudinal elastic modulus of the intermediate member close to that of the wear-resistant resin material on the surface because it acts in the direction of reducing thermal stress.

【0013】[0013]

【実施例】以下、本発明の一実施例による回転式ガス分
離装置を図面に基づいて具体的に説明する。なお、本実
施例による回転式ガス分離装置もその全体構造自体は図
2〜図4に示した従来の装置と変わらないので重複する
それらの説明は省略する。本実施例における下弁板4の
ライニング部分を図1に部分的に拡大して断面図で示し
てある。まず、中間部材17に対し耐摩耗性に優れた樹
脂材料18を接着剤(例えば二液エポキシ系の接着剤)
によって一体化させ、それを下弁板4の母材に接着して
いる。接着層19は、せん断強度が最も大きくなる厚み
にしている。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A rotary gas separation device according to an embodiment of the present invention will be specifically described below with reference to the drawings. The entire structure of the rotary gas separation apparatus according to this embodiment is the same as that of the conventional apparatus shown in FIGS. 2 to 4, and therefore redundant description will be omitted. The lining portion of the lower valve plate 4 in this embodiment is shown in a partially enlarged sectional view in FIG. First, an adhesive (for example, a two-component epoxy adhesive) is used to attach a resin material 18 having excellent wear resistance to the intermediate member 17.
The lower valve plate 4 is bonded to the base material of the lower valve plate 4. The adhesive layer 19 has a thickness that maximizes shear strength.

【0014】表面の耐摩耗樹脂ライニングとなる樹脂材
料18は、乾燥摺動条態で耐摩耗性、耐焼き付き性に優
れたもの(例えば、芳香族ポリエステル樹脂にPTFE
を充填したもの)で、摩耗寿命を考慮し最小限の厚みと
した。ここで、中間部材17は、耐摩耗性、耐焼き付き
性を全く考慮せず、弾性変形能が高く、樹脂材料で単層
のもの(例えば熱可塑性の耐熱樹脂であるポリエーテル
サルホンなど)を使用しているが、材質の異なる積層体
でも差し支えない。
The resin material 18 to be the abrasion resistant resin lining on the surface is a material having excellent abrasion resistance and seizure resistance in a dry sliding state (for example, aromatic polyester resin and PTFE.
(Filled with), the minimum thickness was taken into consideration in consideration of wear life. Here, the intermediate member 17 is made of a resin material having a single layer (for example, polyether sulfone which is a thermoplastic heat resistant resin) having a high elastic deformability without considering wear resistance and seizure resistance at all. Although it is used, a laminate of different materials can be used.

【0015】例えば、縦弾性係数が大きく弾性変形能が
少ない材料であっても、下弁板4の母材との接着強度を
高くできるのであれば、これを薄肉状態で中間部材17
に接着して二層状態の中材部間17として使用すること
もできる。以上は、上弁板5についても同様に行う。な
お、以上の実施例は吸着塔1が回転し弁板4,5が静止
される吸着塔回転型であり、耐摩耗樹脂ライニングをメ
ンテナンスが容易な弁板に設けているが、本発明を弁板
回転型へ適用の場合も本実施例と全く同様にできる。
For example, even if a material having a large longitudinal elastic modulus and a small elastic deformability is used, if the adhesive strength between the lower valve plate 4 and the base material can be increased, it is made thin and the intermediate member 17 is used.
It is also possible to use it as the space 17 between the intermediate members by adhering to. The above is similarly applied to the upper valve plate 5. In the above embodiment, the adsorption tower 1 is rotated and the valve plates 4 and 5 are stationary, and the abrasion resistant resin lining is provided on the valve plate which is easy to maintain. The case of application to the plate rotating type can be performed in exactly the same manner as this embodiment.

【0016】このように表面に耐摩耗樹脂ライニング材
を施し、そのライニング材の下に高分子系の中間部材を
入れているので中間部材の弾性変形によりシール隙間が
少くなり、また摺動面圧も小さくでき温度上昇によるラ
イニング材の剥離も防止される。以上、本発明を図示し
た実施例に基づいて具体的に説明したが、本発明がこれ
らの実施例に限定されず特許請求の範囲に示す本発明の
範囲内で、その形状、構造に種々の変更を加えてよいこ
とはいうまでもない。例えば、上記実施例では耐摩耗樹
脂ライニング材を弁板に設けているが、これを吸着塔の
摺動面に設けてもよいし、或いは弁板と吸着塔の両摺動
面に設けてもよい。
As described above, since the wear resistant resin lining material is applied to the surface and the polymer-based intermediate member is put under the lining material, the seal gap is reduced due to the elastic deformation of the intermediate member, and the sliding surface pressure is reduced. Can be made smaller, and peeling of the lining material due to temperature rise can be prevented. The present invention has been specifically described above based on the illustrated embodiments, but the present invention is not limited to these embodiments, and within the scope of the present invention set forth in the claims, various shapes and structures can be used. It goes without saying that changes may be made. For example, in the above embodiment, the wear-resistant resin lining material is provided on the valve plate, but it may be provided on the sliding surface of the adsorption tower, or it may be provided on both sliding surfaces of the valve plate and the adsorption tower. Good.

【0017】[0017]

【発明の効果】以上具体的に説明したように、本発明に
よれば、耐摩耗樹脂ライニングと中間部材の採用によっ
て回転式ガス分離装置の課題であった回転摺動部分の耐
久性とガス密封性を向上させることができる。また、大
型化時には従来は摺動面即ちシール面の加工精度を低下
させないように、特別な加工(手仕上げ等)が必要であ
ったが、本発明によれば中間部材の弾性効果により通常
の機械加工で済む様になり、コスト軽減が計れる。
As described above in detail, according to the present invention, the wear resistance resin lining and the intermediate member are used, and the durability and gas sealing of the rotary sliding portion, which have been problems of the rotary gas separator, have been solved. It is possible to improve the sex. Further, conventionally, when the size is increased, special processing (such as hand finishing) is required so as not to reduce the processing accuracy of the sliding surface, that is, the sealing surface. The cost can be reduced by machining.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例に係わる回転式ガス分離装置
における耐摩耗樹脂ライニング部分の部分的拡大縦断面
図。
FIG. 1 is a partially enlarged vertical cross-sectional view of a wear-resistant resin lining portion in a rotary gas separator according to an embodiment of the present invention.

【図2】従来の圧力スイングによる回転式ガス分離装置
を示す縦断面図。
FIG. 2 is a vertical cross-sectional view showing a conventional rotary gas separator using a pressure swing.

【図3】図2のA−A線に沿う断面図。3 is a sectional view taken along the line AA of FIG.

【図4】図2のB−B線に沿う断面図。4 is a sectional view taken along the line BB of FIG.

【符号の説明】[Explanation of symbols]

1 吸着塔 2 区画室 3 仕切板 4 下弁板 5 上弁板 6 駆動軸 7 特定ガス回収ポート 8 原料ガスポート 9 精製ガス排出ポート 10 パージガスポート 11 回り止め 12 スプリング 13 ブロアー 14 真空ポンプ 15 キー 16 摺動面 17 中間材 18 表面樹脂材料 19 接着層 1 adsorption tower 2 division chamber 3 partition plate 4 lower valve plate 5 upper valve plate 6 drive shaft 7 specific gas recovery port 8 raw material gas port 9 purified gas discharge port 10 purge gas port 11 whirl stop 12 spring 13 blower 14 vacuum pump 15 key 16 Sliding surface 17 Intermediate material 18 Surface resin material 19 Adhesive layer

───────────────────────────────────────────────────── フロントページの続き (72)発明者 小川 紀一郎 東京都千代田区丸の内二丁目5番1号 三 菱重工業株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Kiichiro Ogawa 2-5-1, Marunouchi, Chiyoda-ku, Tokyo Sanryo Heavy Industries Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 円周方向に区画された複数個の区画室を
有する吸着器、及び二つ以上のポートを具え前記吸着器
に当接される弁板を有し、同弁板及び同吸着器の相対回
転により連続的にガス処理を行う回転式ガス分離装置に
おいて、前記弁板及び前記吸着器の少くともいづれか一
方の摺動面に耐摩耗樹脂ライニングを施し、かつ、同樹
脂ライニングとは別種の高分子材料を単層又は積層状態
として形成させた中間部材を、前記弁板及び吸着器の少
くともいづれか一方の母材と前記耐摩耗樹脂ライニング
材の間に挿入接着したことを特徴とする回転式ガス分離
装置。
1. An adsorber having a plurality of compartments partitioned in the circumferential direction, and a valve plate having two or more ports and abutting on the adsorber, the valve plate and the adsorption plate In a rotary gas separation device for continuously performing gas treatment by relative rotation of a vessel, an abrasion resistant resin lining is applied to at least one sliding surface of the valve plate and the adsorber, and the resin lining is An intermediate member formed of a different type of polymer material as a single layer or a laminated state is inserted and bonded between at least one of the base material of the valve plate and the adsorber and the wear resistant resin lining material. Rotating gas separator.
JP5225731A 1993-09-10 1993-09-10 Rotary type gas separating apparatus Withdrawn JPH0780234A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5225731A JPH0780234A (en) 1993-09-10 1993-09-10 Rotary type gas separating apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5225731A JPH0780234A (en) 1993-09-10 1993-09-10 Rotary type gas separating apparatus

Publications (1)

Publication Number Publication Date
JPH0780234A true JPH0780234A (en) 1995-03-28

Family

ID=16833947

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5225731A Withdrawn JPH0780234A (en) 1993-09-10 1993-09-10 Rotary type gas separating apparatus

Country Status (1)

Country Link
JP (1) JPH0780234A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116531802A (en) * 2023-05-17 2023-08-04 甘肃省农业科学院农产品贮藏加工研究所 Cistanche deserticola polysaccharide obtaining and purifying equipment and method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116531802A (en) * 2023-05-17 2023-08-04 甘肃省农业科学院农产品贮藏加工研究所 Cistanche deserticola polysaccharide obtaining and purifying equipment and method
CN116531802B (en) * 2023-05-17 2024-04-05 甘肃省农业科学院农产品贮藏加工研究所 Cistanche deserticola polysaccharide obtaining and purifying equipment and method

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