JPH0748978B2 - How to make acidic dairy foods - Google Patents

How to make acidic dairy foods

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Publication number
JPH0748978B2
JPH0748978B2 JP1342599A JP34259989A JPH0748978B2 JP H0748978 B2 JPH0748978 B2 JP H0748978B2 JP 1342599 A JP1342599 A JP 1342599A JP 34259989 A JP34259989 A JP 34259989A JP H0748978 B2 JPH0748978 B2 JP H0748978B2
Authority
JP
Japan
Prior art keywords
pectin
milk
hydrate
acidic dairy
acidic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP1342599A
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Japanese (ja)
Other versions
JPH03201943A (en
Inventor
創一郎 田中
川本  裕巳
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Kanebo Ltd
Original Assignee
Kanebo Ltd
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Priority to JP1342599A priority Critical patent/JPH0748978B2/en
Publication of JPH03201943A publication Critical patent/JPH03201943A/en
Publication of JPH0748978B2 publication Critical patent/JPH0748978B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、乳蛋白の沈澱が防止された酸性乳食品の製法
に関するものである。
TECHNICAL FIELD The present invention relates to a method for producing an acidic dairy food product in which precipitation of milk proteins is prevented.

(従来の技術) 一般に、酸成分と乳成分とを含有する酸性乳食品として
は、牛乳,脱粉乳,全脂粉乳等の乳成分に、乳酸菌・酵
母等のスターターを接種して発酵させた発酵乳、および
乳酸菌飲料や、乳成分に有機酸、果汁等の酸成分を加え
た酸性乳飲料等が知られている。
(Prior Art) Generally, as an acidic dairy food containing an acid component and a dairy component, a fermented product obtained by inoculating a starter such as lactic acid bacteria or yeast to a fermented milk component such as milk, dry milk, or whole milk powder. Known are milk and lactic acid beverages, and acidic milk beverages obtained by adding an acid component such as an organic acid or fruit juice to a milk component.

これら酸性乳食品は、保存中に酸によって乳蛋白が凝固
し、沈澱、分離し易いという問題があった。
These acidic dairy foods have a problem that milk protein is coagulated by an acid during storage and easily precipitated and separated.

そこで、乳蛋白の凝固、沈澱を防止する方法として、例
えば、特公昭63−20493号公報においては、豆乳を乳酸
発酵させ、ソフトカードを形成させた後、酸成分を添加
する方法が開示されている。この方法は、予め豆乳を乳
酸発酵することによって、豆乳中の乳蛋白を緩慢に凝固
させ、酸成分を添加した時の乳蛋白の急激な凝固を防止
するものである。しかし、この方法においては、乳酸発
酵を行うための多大な設備が必要であり、またpHを等電
点以下となるよう調整する等、製造条件の管理が煩雑と
なる。
Therefore, as a method of preventing coagulation and precipitation of milk protein, for example, Japanese Patent Publication No. 63-20493 discloses a method in which soy milk is lactic acid fermented to form a soft curd, and then an acid component is added. There is. In this method, lactic acid fermentation of soy milk is carried out in advance to slowly coagulate milk protein in soy milk and prevent rapid coagulation of milk protein when an acid component is added. However, this method requires a large amount of equipment for performing lactic acid fermentation, and management of production conditions is complicated, such as adjusting the pH to be below the isoelectric point.

また、特公昭63−57021合公報においては、ペクチン、
カラギナン等の乳蛋白反応性ゲル化剤と乳成分等を混合
溶解した後、発酵乳を添加する方法が開示されている。
この方法は、予め乳蛋白反応性ゲル化剤と乳成分とを反
応させることにより、酸成分と乳蛋白とが反応するのを
防止するものである。しかし、この方法においては、乳
蛋白を十分にゲル化剤と反応させるために多量のゲル化
剤を添加するので、冷却時に増粘、ゲルセットを起こし
てしまう。したがってこの方法では、飲料や冷菓ミック
ス等の流動性のある液状物の製造には応用することがで
きなかった。
Moreover, in Japanese Patent Publication No. 63-57021, pectin,
A method is disclosed in which a milk protein-reactive gelling agent such as carrageenan and a milk component are mixed and dissolved, and then fermented milk is added.
This method prevents the acid component and the milk protein from reacting by reacting the milk protein-reactive gelling agent with the milk component in advance. However, in this method, a large amount of gelling agent is added in order to sufficiently react the milk protein with the gelling agent, so that thickening and gel setting occur during cooling. Therefore, this method could not be applied to the production of fluid liquids such as beverages and frozen dessert mixes.

また、上記方法の他、果汁等の酸成分を限外過、透析
等の方法で処理し、酸成分を減少させたり、あるいは、
乳成分中の蛋白量を減らす等の方法も行なわれている
が、これらの方法においては、酸性乳食品本来の風味が
少なく、おいしさに欠けるという問題があった。
In addition to the above method, the acid component of fruit juice or the like is treated by a method such as ultrafiltration or dialysis to reduce the acid component, or,
Although methods such as reducing the amount of protein in milk components have been carried out, these methods have a problem that the original flavor of acidic dairy foods is low and the taste is not good.

(発明が解決しようとする課題) 本発明はこのような事情に鑑みなされたものであって、
その目的とするところは、酸性乳食品を過剰に増粘させ
たり、風味を損なうことなく、簡便に酸性乳食品の乳蛋
白凝固、沈澱を防止し得る酸性乳食品の製法を提供する
にある。
(Problems to be Solved by the Invention) The present invention has been made in view of such circumstances,
An object of the invention is to provide a method for producing an acidic dairy food which can easily prevent milk protein coagulation and precipitation of the acidic dairy food without excessively thickening or impairing the flavor of the acidic dairy food.

(課題を解決するための手段) 上記の目的は、乳成分を含む酸性乳食品を製造するに際
し、予めペクチンを水に溶解せしめたのち、エージング
し、引き続いて得られたペクチン水和物を、他の原料に
混合し、乳成分の均質化を行い、酸性乳食品中の乳蛋白
とペクチン水和物との複合体の粒子径を2μ以下とする
ことを特徴とする酸性乳食品の製法によって達成され
る。
(Means for Solving the Problems) The above-mentioned object is, in producing an acidic dairy food containing a milk component, after previously dissolving pectin in water, aging, and subsequently obtained pectin hydrate, According to a method for producing an acidic dairy food, which is characterized by mixing with other raw materials, homogenizing milk components, and making the particle size of the complex of milk protein and pectin hydrate in the acidic dairy food 2 μm or less. To be achieved.

すなわち、本発明者らは、従来、ペクチンを、乳成分等
の他の原料に単に溶解させ、混合するだけでは乳蛋白の
凝固、沈澱を防止できないのは、ペクチンが充分に水和
していないからではないかと想起し検討を行なった。そ
の結果、ペクチンを予め水に溶解させたのち、エージン
グすることにより充分に水和させ、得られたペクチン水
和物を、他の原料と混合、均質化すると、少量のペクチ
ンで乳蛋白の凝固、沈澱を防止し、かつ過剰に増粘する
ことなく酸性乳食品を製造することができることを見い
出し本発明に到達した。
That is, the present inventors have been unable to prevent the coagulation and precipitation of milk proteins by simply dissolving pectin in other raw materials such as milk components and mixing them, because the pectin is not sufficiently hydrated. I thought that it might be because of this, and examined it. As a result, pectin was dissolved in water in advance and then sufficiently aged to be hydrated. The obtained pectin hydrate was mixed with other raw materials and homogenized, and a small amount of pectin coagulated milk protein. The inventors have found that an acidic dairy food can be produced without preventing precipitation and without excessive thickening, and reached the present invention.

次に、本発明を詳しく説明する。Next, the present invention will be described in detail.

まず、本発明に用いるペクチンとしては、ローメトキシ
ルペクチン(以下、LMペクチンと記す)、ハイメトキシ
ルペクチン(以下、HMペクチンと記す)が挙げられ、こ
れらは単独でも、もしくは併用してもよい。例えば、粘
度の低い飲料には、HMペクチンを用いると少量で乳蛋白
凝固、沈澱を防止でき、かつ過剰な増粘も起こらないの
で好適である。
First, examples of pectin used in the present invention include low methoxyl pectin (hereinafter referred to as LM pectin) and high methoxyl pectin (hereinafter referred to as HM pectin), and these may be used alone or in combination. For example, HM pectin is suitable for beverages having a low viscosity, because a small amount of HM pectin can prevent milk protein coagulation and precipitation and also prevent excessive thickening.

また、ペクチンを溶解する水としては、一般に食品の製
造に用いる水でよく、必要に応じて水にアルコール、香
料、色素、糖類等を加えるようにしてもよい。ただし、
糖類は、ペクチンと水との水和を遅延させる原因となる
ので、短時間でペクチンの水和物を得るためには、糖類
の添加量は、ペクチン水和物全体重量中の20重量%(以
下、%と記す)以下とすることが好ましい。
The water for dissolving pectin may be water generally used for producing foods, and alcohol, flavors, pigments, sugars, etc. may be added to the water as necessary. However,
Since saccharides cause a delay in hydration of pectin and water, in order to obtain a hydrate of pectin in a short time, the addition amount of saccharide is 20% by weight based on the total weight of the pectin hydrate ( Hereinafter, it will be referred to as%).

次に、ペクチン水和物は、例えば、エージングを行うこ
とにより得られる。すなわち、まず、ペクチンを水と共
に撹拌しながら、50〜80℃に加熱、溶解した後、好まし
くは30℃以下、更に好ましくは5〜10℃程度に冷却し、
エージングをする。
Next, the pectin hydrate is obtained, for example, by performing aging. That is, first, while stirring pectin with water, after heating to 50 to 80 ° C. to dissolve it, preferably it is cooled to 30 ° C. or lower, more preferably about 5 to 10 ° C.,
Aging.

エージングは、最終的に得られる酸性乳食品中の乳蛋白
とペクチン水和物との複合体の粒子径が2μ以下となる
ように行う。すなわち、エージングによってペクチンを
水和状態にした後、他の原料と混合すると、上記複合体
の粒子径が2μ以下となり、酸性乳食品中に均一に分散
することができるのである。
The aging is performed so that the particle size of the complex of the milk protein and the pectin hydrate in the finally obtained acidic dairy food is 2 μm or less. That is, when the pectin is hydrated by aging and then mixed with another raw material, the particle diameter of the above complex becomes 2 μm or less, and the complex can be uniformly dispersed in the acidic dairy food.

複合体の粒子径が2μを超えている場合には、エージン
グが不充分であったために、ペクチンが水和しないま
ま、他の原料と混合されたことが原因となっており、そ
の結果として、乳蛋白の凝固や沈殿が生じてしまう。
When the particle size of the complex exceeds 2μ, the aging was insufficient, and this is because the pectin was mixed with other raw materials without being hydrated. As a result, Milk protein coagulates and precipitates.

このとき、ペクチンの添加量は、ペクチン水和物全体重
量中の10%以下にすることが望ましい。ペクチンの添加
量が10%を超えると、ペクチンと水との水和が不充分と
なり易く、また、エージングに時間がかかるようにな
る。
At this time, the amount of pectin added is preferably 10% or less of the total weight of pectin hydrate. If the amount of pectin added exceeds 10%, hydration of pectin and water tends to be insufficient, and aging will take a long time.

また、ペクチンの水和に要する時間は、ペクチンの種
類、濃度によって異なるので、ペクチン水和物の製造条
件、保管条件にあわせ、適宜設定すればよい。例えば、
5%のHMペクチン水和物を得るには、エージング時間
は、12時間程度で充分である。
Further, the time required for hydration of pectin varies depending on the type and concentration of pectin, and may be appropriately set according to the production conditions and storage conditions of pectin hydrate. For example,
An aging time of about 12 hours is sufficient to obtain 5% HM pectin hydrate.

このようにして得られたペクチン水和物を用いて、酸性
乳食品は、例えば次のようにして製造される。すなわ
ち、粉乳、練乳等の乳成分と発酵乳、有機酸、果汁等の
酸成分、及び必要に応じて、糖類、着色料、着香料、塩
類、乳化剤等の諸原料を常法に従い、混合溶解し、上記
ペクチン水和物を加えて、均質化、冷却することによ
り、酸性乳食品が得られる。
Using the pectin hydrate thus obtained, an acidic dairy food is produced, for example, as follows. That is, milk components such as milk powder and condensed milk and fermented milk, organic acids, acid components such as fruit juice, and, if necessary, various raw materials such as sugars, colorants, flavors, salts and emulsifiers are mixed and dissolved according to a conventional method. Then, the above pectin hydrate is added, and the mixture is homogenized and cooled to obtain an acidic dairy food.

このとき、ペクチン水和物の添加量は、ペクチン濃度と
して酸性乳食品全体重量中の0.4%以上にすることが望
ましい。ペクチンの濃度が0.4%未満だと乳蛋白の凝
固、沈澱を防止できにくくなる。
At this time, the amount of pectin hydrate added is preferably 0.4% or more of the total weight of the acidic milk food as a pectin concentration. If the pectin concentration is less than 0.4%, it becomes difficult to prevent coagulation and precipitation of milk protein.

本発明においては、乳成分を均質化することが重要であ
る。乳成分の均質化は、酸成分等の諸原料と共に、ペク
チン水和物を添加した後に行ってもよく、あるいは、ペ
クチン水和物を添加する前に行ってもよい。また、乳成
分を単独で予め均質化しておいてもよい。
In the present invention, it is important to homogenize the milk component. The milk component may be homogenized after adding the pectin hydrate together with various raw materials such as the acid component or before adding the pectin hydrate. Alternatively, the milk component may be homogenized in advance.

特に、乳成分に酸成分を加えると、乳蛋白の凝固によっ
て乳成分の粒子が大きくなる傾向にある。そこで、乳成
分の粒子径は、乳成分の90%以上が10μ以下となるよう
酸成分の添加量や添加する時期に留意することが望まし
い。乳成分の粒子径が10μを越えると、均質化しても微
粒子化しにくく、ペクチン水和物を添加しても、乳蛋白
の凝固、沈澱が防止できにくくなる。また、均質化した
乳成分の粒子径は、2μ未満であることが好ましい。
In particular, when an acid component is added to the milk component, the milk protein particles tend to become large due to the coagulation of milk protein. Therefore, regarding the particle size of the milk component, it is desirable to pay attention to the amount and timing of addition of the acid component so that 90% or more of the milk component becomes 10 μ or less. When the particle size of the milk component exceeds 10 μ, it is difficult to form fine particles even if homogenized, and it becomes difficult to prevent coagulation and precipitation of milk protein even if pectin hydrate is added. The homogenized milk component preferably has a particle size of less than 2 μm.

このようにして得られた酸性乳食品中の乳蛋白は、ペク
チン水和物と反応して複合体を形成し、酸成分による乳
蛋白凝固、沈澱を防止し得ると考えられる。この乳蛋白
とペクチン水和物との複合体の粒子径は、2μ以下とな
るようにする。粒子径が2μを超えると、酸成分によっ
て生じる乳蛋白の凝固物の粒子径が大きくなり、沈殿を
生じる。
It is considered that the milk protein in the acidic dairy food thus obtained reacts with pectin hydrate to form a complex and can prevent milk protein coagulation and precipitation due to an acid component. The particle size of the complex of milk protein and pectin hydrate is set to 2 μm or less. When the particle size exceeds 2 μ, the particle size of the milk protein coagulation product generated by the acid component becomes large and precipitation occurs.

また、ペクチンと共に、カラギナン、ファーセレラン、
ローカストビーンガム、タマリンドガム、キサンタンガ
ム等のゲル化剤を用いるようにしてよい。これらは、ペ
クチン水和物調製時に添加しても、他の原料中に添加し
てもよいが、ペクチンの水和を短時間で行うためには、
他の原料中に添加する方が望ましい。
Also, with pectin, carrageenan, fur cerelan,
A gelling agent such as locust bean gum, tamarind gum and xanthan gum may be used. These may be added at the time of preparing pectin hydrate or may be added to other raw materials, but in order to hydrate pectin in a short time,
It is desirable to add it to other raw materials.

また、酸性乳食品は、果肉、ジャム、ソース等を加える
ようにしてもよい。なお、酸性乳食品のpHは、3.0以上
にすることが、風味、及び乳蛋白凝固、沈澱防止の点で
望ましい。
Moreover, pulp, jam, sauce, etc. may be added to the acidic dairy food. In addition, it is desirable that the pH of the acidic dairy food is 3.0 or more from the viewpoint of flavor, coagulation of milk protein, and prevention of precipitation.

(発明の効果) 以上のように、本発明の酸性乳食品の製法は、ペクチン
を予め水溶液にしたのち、エージングすることにより、
充分水和させたペクチン水和物を用いることにより、少
量のペクチンで酸性乳食品の乳蛋白の凝固、沈澱を防止
することができる。したがって、特に飲料のような流動
性の高い液状食品を、過剰に増粘させることなく、製造
することができる。
(Effect of the invention) As described above, the method for producing an acidic dairy food of the present invention is to prepare pectin in an aqueous solution in advance, and then by aging,
By using a sufficiently hydrated pectin hydrate, a small amount of pectin can prevent the coagulation and precipitation of milk proteins in acidic dairy foods. Therefore, a liquid food having a high fluidity such as a beverage can be produced without excessively increasing the viscosity.

更に、ペクチン水和物の濃度や、酸性乳食品への添加量
を変えることによって、飲料、冷菓ミックス、ヨーグル
ト、ゲル状デザート等乳成分や酸成分の量、種類によら
ず種々の酸性乳食品を製造することができる。
Furthermore, by varying the concentration of pectin hydrate and the amount added to acidic dairy foods, various acidic dairy foods can be used regardless of the amount and type of milk and acid components such as beverages, frozen dessert mixes, yogurt, and gelled desserts Can be manufactured.

また、乳成分、酸成分、pHを操作することなく、乳蛋白
の凝固、沈澱を防止できるので、酸性乳食品本来の風味
を損なうことがない。
Further, coagulation and precipitation of milk proteins can be prevented without manipulating milk components, acid components and pH, so that the original flavor of acidic dairy foods is not impaired.

また、発酵醸造用設備、限外過設備等の設備を必要と
せず、従来の設備を用いて簡便に製造することができ
る。
Further, it does not require equipment such as fermenting and brewing equipment and ultrafiltration equipment, and can be simply produced using conventional equipment.

つぎに本発明を実施例に基づき、具体的に説明する。Next, the present invention will be specifically described based on Examples.

〔実施例1〜4,比較例1〕 表1に示す条件で上述の方法に従い、ペクチン水和物を
調製した。次にこのペクチン水和物を用いて表2に示す
配合及び条件で原料を混合し、均質化を行い、酸性乳飲
料を調製した。
[Examples 1 to 4 and Comparative Example 1] Pectin hydrate was prepared according to the method described above under the conditions shown in Table 1. Next, using this pectin hydrate, the raw materials were mixed according to the formulation and conditions shown in Table 2 and homogenized to prepare an acidic milk drink.

次に調製した酸性乳飲料を、200g/本充填密封し、5℃
で保管した時の乳蛋白の沈澱の有無を目視で確認した。
Next, the prepared acidic milk drink is filled and sealed at 200g / main, 5 ℃
The presence / absence of precipitation of milk protein when it was stored in 1. was visually confirmed.

その結果を表2にあわせて示す。The results are also shown in Table 2.

以上の結果から、実施例の酸性乳飲料は、いずれも乳蛋
白の凝固、沈澱がみられず、保存安定性に優れた酸性乳
飲料であった。
From the above results, the acidic milk beverages of the examples were all acidic milk beverages in which coagulation and precipitation of milk protein were not observed and storage stability was excellent.

これに対し、比較例1は、エージングを行わなかったの
で、ペクチンが充分に水和しなかったために、酸性乳飲
料中の乳蛋白とペクチン水和物との複合体の粒子径が2
μを超えてしまい、保存中に乳蛋白の凝固、沈殿が起こ
り好ましくなかった。
On the other hand, in Comparative Example 1, paging was not sufficiently hydrated because aging was not performed, and therefore the particle size of the complex of milk protein and pectin hydrate in the acidic milk drink was 2
Since it exceeded μ, coagulation and precipitation of milk protein during storage were unfavorable.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】乳成分を含む酸性乳食品を製造するに際
し、予めペクチンを水に溶解せしめたのち、エージング
し、引き続いて得られたペクチン水和物を、他の原料に
混合し、乳成分の均質化を行い、酸性乳食品中の乳蛋白
とペクチン水和物との複合体の粒子径を2μ以下とする
ことを特徴とする酸性乳食品の製法。
1. When producing an acidic dairy food containing a dairy component, pectin is dissolved in water in advance and then aged, and subsequently the obtained pectin hydrate is mixed with other raw materials to prepare a dairy component. The method for producing an acidic dairy food, characterized in that the particle size of the complex of milk protein and pectin hydrate in the acidic dairy food is 2 μm or less.
JP1342599A 1989-12-28 1989-12-28 How to make acidic dairy foods Expired - Fee Related JPH0748978B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1342599A JPH0748978B2 (en) 1989-12-28 1989-12-28 How to make acidic dairy foods

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1342599A JPH0748978B2 (en) 1989-12-28 1989-12-28 How to make acidic dairy foods

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JP11003907A Division JP3066000B2 (en) 1999-01-11 1999-01-11 Acidic milk food

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JPH03201943A JPH03201943A (en) 1991-09-03
JPH0748978B2 true JPH0748978B2 (en) 1995-05-31

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Families Citing this family (3)

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Publication number Priority date Publication date Assignee Title
US6261626B1 (en) 1997-06-23 2001-07-17 Danisco A/S Methods of obtaining selected pectin fractions, such fractions and their use
US6855363B1 (en) 1997-06-23 2005-02-15 Danisco A/S Methods of obtaining selected pectin fractions, such fractions and their use
JP3387457B2 (en) 1999-08-27 2003-03-17 不二製油株式会社 Acidic protein food, its production method and stabilizer

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63263045A (en) * 1987-04-21 1988-10-31 Meiji Milk Prod Co Ltd Preparation of concentrated liquid fermented milk containing carbon dioxide gas
JPS6416130A (en) * 1987-07-10 1989-01-19 Nec Corp Mobile body communication terminal

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