JPH07242947A - Production of high ductility hot rolled high tensile strength steel plate excellent in corrosion resistance - Google Patents

Production of high ductility hot rolled high tensile strength steel plate excellent in corrosion resistance

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Publication number
JPH07242947A
JPH07242947A JP3230394A JP3230394A JPH07242947A JP H07242947 A JPH07242947 A JP H07242947A JP 3230394 A JP3230394 A JP 3230394A JP 3230394 A JP3230394 A JP 3230394A JP H07242947 A JPH07242947 A JP H07242947A
Authority
JP
Japan
Prior art keywords
rolling
corrosion resistance
steel sheet
hot
steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3230394A
Other languages
Japanese (ja)
Inventor
Norio Imai
規雄 今井
Nozomi Komatsubara
望 小松原
Tokiaki Nagamichi
常昭 長道
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP3230394A priority Critical patent/JPH07242947A/en
Publication of JPH07242947A publication Critical patent/JPH07242947A/en
Pending legal-status Critical Current

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  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

PURPOSE:To produce a hot rolled high tensile strength steel plate provided with excellent corrosion resistance, ductility, bore expandability and weldability. CONSTITUTION:This is a method for producing a high ductility hot rolled high tensile strength steel plate excellent in corrosion resistance and bore expandability in which a steel having a compsn. contg. 0.05 to 0.25% C, <=2.5% Si, <=2.5% sol. Al, 0.8 to 2.5% Mn, 0.10 to 0.80% Cu, 0.020 to 0.15% P and 0.01 to 0.50% Ni and satisfying (So+Al) >=1.0 is treated in the following process to form its structure into a one essentially consisting of polygonal ferrite and contg. retained austenite by >=5% in a volume ratio. It is held under heating to 1000 to 1100 deg.C and is immediately subjected to hot rough rolling at >=50% total draft, and the rough rolling is finished at 880 to 940 deg.C. Successively, it is subjected to finish rolling at >=60% total draft, and the finish rolling is ended at 780 to 840 deg.C. Next, it is subjected to accelerated cooling to 300 to 450 deg.C at 10 to 50 deg.C/s cooling rate and is coiled. The same steel may be incorporated with specified amounts of one or more kinds among Ca, Zr, rare earth elements, Nb, Ti and V.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、自動車や産業機械等
における高強度部材用鋼板として好適な、耐食性、延性
および穴拡げ性に優れ、かつ溶接性も備えた加工用熱延
高張力鋼板の製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hot-rolled high-tensile steel sheet for working, which is suitable as a steel sheet for high-strength members in automobiles, industrial machines, etc., which has excellent corrosion resistance, ductility and hole expandability, and also has weldability. It relates to a manufacturing method.

【0002】[0002]

【従来の技術】連続熱間圧延によって製造される熱延鋼
板は、比較的安価な構造用材料として自動車や各種の産
業機械等で広く使用されるようになったが、このような
用途に用いられる部材の大部分はプレス加工で成形され
る場合が多い。従って、「高強度と高加工性の両立」に
対する要求が強い。
2. Description of the Related Art Hot-rolled steel sheets produced by continuous hot rolling have been widely used as relatively inexpensive structural materials in automobiles and various industrial machines. Most of the members to be molded are often formed by pressing. Therefore, there is a strong demand for "combination of high strength and high workability".

【0003】一般に鋼板の強度増加を図ると加工性が低
下するが、高強度と高加工性が両立する鋼板として、例
えば特開昭55−44551 号公報に示されているようなDP
鋼 (Dual Phase鋼) が知られている。
Generally, when the strength of a steel sheet is increased, the workability is deteriorated, but as a steel sheet having both high strength and high workability, for example, a DP as disclosed in JP-A-55-44551.
Steel (Dual Phase steel) is known.

【0004】このDP鋼は〔フェライト+マルテンサイ
ト〕の二相組織鋼であり、「降伏比が低く延性が高い」
ことを特徴としている。しかし、この鋼のJIS 5号引張
試験片による特性では、60キロ級ハイテン〔引張強さ(T
S):60kgf/mm2〕で伸び(EL)が約30%、引張強さ・伸びバ
ランス(TS×EL)の値が2000未満、また80キロ級ハイテ
ン〔TS:80kgf/mm2 〕でELが約20%、(TS×EL)の値が
1800未満というのが、それぞれその限界であり、DP鋼
でもそれ以上の高延性化には対応できない。
This DP steel is a [ferrite + martensite] dual-phase structure steel and has a "low yield ratio and high ductility".
It is characterized by that. However, the characteristics of this steel according to JIS No. 5 tensile test piece are 60 kg class high tensile strength [tensile strength (T
(S): 60kgf / mm 2 ], elongation (EL) is about 30%, tensile strength / elongation balance (TS × EL) value is less than 2000, and 80kg class high tensile strength [TS: 80kgf / mm 2 ] EL Is about 20%, and the value of (TS × EL) is
The limit is less than 1800, and DP steel cannot cope with higher ductility.

【0005】一方、これとは別に、高強度鋼板の延性を
大幅に向上させる手段として「残留オーステナイトの変
態誘起塑性(以下、TRIPという)を利用する方法」
が提案されている(例えば、特開昭55−145121号公報参
照)。この方法によると、TSが110kgf/mm2以上でELは22
%以上を示し、(TS×EL)の値が2400を超える高延性高
強度鋼板の製造が可能であると考えられる。しかしなが
らこの方法では、C含有量を0.40〜0.85重量% (以下、
成分割合を表す%は重量%とする) と高めに調整する必
要があることから、得られる鋼板は溶接性の点で劣り、
自動車用鋼板として広く使用することは困難である。
On the other hand, apart from this, as a means for significantly improving the ductility of high-strength steel sheets, "method of utilizing transformation-induced plasticity of retained austenite (hereinafter referred to as TRIP)"
Has been proposed (see, for example, JP-A-55-145121). According to this method, TS is 110 kgf / mm 2 or more and EL is 22
%, And it is considered possible to manufacture high-ductile high-strength steel sheets with a (TS × EL) value of more than 2400. However, in this method, the C content is 0.40 to 0.85% by weight (hereinafter,
It is necessary to adjust the content of the steel sheet to a higher value (% representing the composition ratio is to be a weight%), so the resulting steel sheet is inferior in terms of weldability,
It is difficult to widely use it as a steel sheet for automobiles.

【0006】低いC含有量の下で残留オーステナイトを
確保して鋼板の高延性を得る手段として、0.2 %前後の
C、1.5 %前後のSi、1.5 %前後のMnを含有する鋼を熱
間圧延し、Ar3点近傍で仕上圧延を行い、40℃/s以上の
冷却速度で加速冷却した後、400 ℃近傍で巻き取る方法
が提案されている (特開昭63−4017号公報参照) 。しか
しこの方法では、伸びはDP鋼に比べて大幅に向上させ
ることができるものの、結晶粒径が比較的粗大であるた
め加工性の重要な指標の一つである穴拡げ性は改善され
ず、得られる熱延鋼板の穴拡げ性はDP鋼並みの30%程
度しかない。
As a means to secure retained austenite and obtain high ductility of a steel sheet under a low C content, a steel containing about 0.2% C, about 1.5% Si, and about 1.5% Mn is hot-rolled. However, a method has been proposed in which finish rolling is performed in the vicinity of Ar 3 point, accelerated cooling is performed at a cooling rate of 40 ° C./s or more, and then winding is performed in the vicinity of 400 ° C. (see Japanese Patent Laid-Open No. 63-4017). However, with this method, although the elongation can be greatly improved as compared with DP steel, since the crystal grain size is relatively coarse, hole expansibility, which is one of the important indicators of workability, is not improved, The hole expandability of the hot-rolled steel sheet obtained is only about 30% that of DP steel.

【0007】従って、上記の方法による鋼板は、伸びフ
ランジ性が要求されるような部品に対しては使用するこ
とができず、穴拡げ性についても充分に満足できる加工
用熱延高張力鋼板の出現が強く望まれている。
Therefore, the steel sheet produced by the above method cannot be used for parts requiring stretch-flangeability, and is a hot-rolled high-tensile steel sheet for working which is sufficiently satisfactory in hole expansibility. Appearance is strongly desired.

【0008】近年、自動車燃費規制の強化に伴い、車体
の軽量化を促進するために自動車足廻り部品などに使用
される薄鋼板は、高張力・薄肉化される傾向にある。し
かし、道路凍結防止材の使用の拡大に伴い、これらの鋼
板には同時に耐食性も求められており、防錆処理を施し
た鋼板の使用量も増大している。
[0008] In recent years, with the tightening of regulations on fuel consumption of automobiles, thin steel sheets used for undercarriage parts of automobiles in order to promote weight reduction of vehicle bodies have tended to have high tension and thin wall. However, with the expansion of the use of road anti-icing materials, these steel sheets are required to have corrosion resistance at the same time, and the amount of rust-prevented steel sheets used is also increasing.

【0009】ところで、鋼板に耐食性を付与する手法と
しては、亜鉛系めっき鋼板に代表されるように鋼板の表
面に保護皮膜をめっきする方法がある。しかし、亜鉛め
っき鋼板をアーク溶接した場合に、重ねすみ肉溶接部に
めっき皮膜中の亜鉛の蒸発に起因したブローホール等の
溶接欠陥が多発し、疲労強度の低下を招くなど、継手の
信頼性を損ない、十分な部品強度が得られないという問
題点を生じる。
By the way, as a method of imparting corrosion resistance to a steel sheet, there is a method of plating a protective film on the surface of the steel sheet as represented by a zinc-based plated steel sheet. However, when arc-welding galvanized steel sheets, welding defects such as blowholes frequently occur in the lap fillet weld due to evaporation of zinc in the plating film, leading to reduced fatigue strength. And the problem that sufficient component strength cannot be obtained occurs.

【0010】そこで、溶接性劣化の問題のない、耐食性
鋼に代表されるような鋼板母材に少量のCu、P、Crなど
の元素を添加して緻密な腐食皮膜を形成させるもの (特
開昭54−9113号参照) がある。しかし、このような鋼板
においても、さらに強度を上げて更なる薄肉化を行おう
とした場合、耐食性が不十分となる問題が生じ、よりい
っそうの母材耐食性が望まれている。
Therefore, a small amount of elements such as Cu, P, and Cr are added to a steel plate base material represented by corrosion-resistant steel, which does not cause the problem of deterioration of weldability, to form a dense corrosion film (Japanese Patent Laid-Open No. 2000-242242). (See No. 54-9113). However, even in such a steel sheet, when the strength is further increased and the thickness is further reduced, there arises a problem that the corrosion resistance becomes insufficient, and further higher base metal corrosion resistance is desired.

【0011】[0011]

【発明が解決しようとする課題】本発明は上記の問題点
を解決するためになされたものであり、本発明の目的
は、耐食性、延性および穴拡げ性に加えて溶接性も備え
た加工用熱延高張力鋼板の製造方法を提供することにあ
る。
SUMMARY OF THE INVENTION The present invention has been made to solve the above problems, and an object of the present invention is to provide welding properties in addition to corrosion resistance, ductility and hole expandability. It is to provide a method for manufacturing a hot-rolled high-tensile steel plate.

【0012】[0012]

【課題を解決するための手段】本発明の要旨は、次の
(1)〜(3) の高延性熱延高張力鋼板の製造方法にある。
The summary of the present invention is as follows.
The method for producing a high-ductility hot-rolled high-strength steel sheet according to (1) to (3).

【0013】(1) 重量%で、C:0.05〜0.25%、Si:2.
5 %以下、sol.Al:2.5 %以下、Mn:0.8〜2.5 %、Cu:
0.10〜0.80%、P: 0.020〜0.15%およびNi:0.01〜0.
50%を含有し、かつ(Si+Al)≧1.0 %を満足し、残部
はFeおよび不可避的不純物からなる鋼を、下記〜の
工程と条件で処理し、体積率で5%以上の残留オーステ
ナイトを含むポリゴナルフェライト主体の組織とするこ
とを特徴とする耐食性および穴拡げ性の優れた高延性熱
延高張力鋼板の製造方法。
(1) C: 0.05 to 0.25% by weight, Si: 2.
5% or less, sol.Al: 2.5% or less, Mn: 0.8 to 2.5%, Cu:
0.10-0.80%, P: 0.020-0.15% and Ni: 0.01-0.
Steel containing 50% and satisfying (Si + Al) ≥ 1.0%, the balance being Fe and unavoidable impurities, is processed by the following steps and conditions, and contains 5% or more by volume of retained austenite. A method for producing a high-ductility hot-rolled high-strength steel sheet excellent in corrosion resistance and hole expansibility, characterized by having a structure mainly composed of polygonal ferrite.

【0014】1000〜1100℃に加熱保持してから、直ち
に合計圧下率が50%以上の熱間粗圧延を行い、 880〜94
0 ℃で粗圧延を終了する。
After heating and holding at 1000 to 1100 ° C., hot rough rolling with a total reduction of 50% or more is immediately performed, and 880 to 94
The rough rolling is completed at 0 ° C.

【0015】引き続き合計圧下率が60%以上の仕上圧
延を施し、 780〜840 ℃で仕上圧延を終了する。
Subsequently, finish rolling with a total reduction of 60% or more is performed, and the finish rolling is completed at 780 to 840 ° C.

【0016】次いで10〜50℃/sの冷却速度で 300〜45
0 ℃まで加速冷却する。
Then, at a cooling rate of 10 to 50 ° C./s, 300 to 45
Accelerated cooling to 0 ° C.

【0017】その後巻き取る。Then, it is wound up.

【0018】(2) 上記(1) の成分に、加えて更に、重量
%で、Ca:0.0002〜0.010 %、Zr:0.01〜0.10%および
希土類元素: 0.002〜0.10%のうちの1種または2種以
上を含む鋼を、上記(1) の工程で処理し、体積率で5%
以上の残留オーステナイトを含むポリゴナルフェライト
主体の組織とすることを特徴とする耐食性および穴拡げ
性に優れた高延性熱延高張力鋼板の製造方法。
(2) In addition to the above component (1), in addition, one or two of Ca: 0.0002 to 0.010%, Zr: 0.01 to 0.10%, and rare earth element: 0.002 to 0.10% in weight%. Steel containing more than one kind is treated in the above step (1), and the volume ratio is 5%.
A method for producing a high-ductility hot-rolled high-strength steel sheet excellent in corrosion resistance and hole expansibility, characterized by having a structure mainly composed of polygonal ferrite containing retained austenite as described above.

【0019】(3) 上記(1) または(2) の成分に、加えて
更に、重量%で、Nb: 0.005〜0.10%、Ti: 0.005〜0.
10%およびV: 0.005〜0.20%のうちの1種または2種
以上を含む鋼を、上記 (1)の工程で処理し、体積率で5
%以上の残留オーステナイトを含むポリゴナルフェライ
ト主体の組織とすることを特徴とする、いずれかの耐食
性および穴拡げ性に優れた高延性熱延高張力鋼板の製造
方法。
(3) In addition to the above component (1) or (2), in addition, in% by weight, Nb: 0.005 to 0.10%, Ti: 0.005 to 0.
10% and V: 0.005 to 0.20% of steel containing one or more of them is treated in the above step (1) to obtain a volume ratio of 5
% Of retained austenite is used as a main structure of polygonal ferrite, and a method for producing a high-ductility hot-rolled high-strength steel sheet excellent in any of corrosion resistance and hole expandability.

【0020】上記の「ポリゴナルフェライト主体の組
織」とは、残留オーステナイト以外の組織(例えばベイ
ナイト)がポリゴナルフェライトの性質に格別な影響を
及ぼさない程度に止まる「実質的にポリゴナルフェライ
トからなる組織」を意味する。
The above-mentioned "structure mainly composed of polygonal ferrite" means that "a structure other than retained austenite (for example, bainite)" is "substantially composed of polygonal ferrite" to such an extent that the properties of the polygonal ferrite are not significantly affected. Means "organization".

【0021】本発明者らは前記目的を達成すべく、特に
溶接性において満足が得られるC含有量の範囲で、自動
車用等としても充分な高強度を示し、かつ「優れた耐食
性、延性と穴拡げ性につながるTRIP効果を利用する
に充分な量」のオーステナイトを有する熱延高張力鋼板
の実現可能性を求めて種々の検討を重ねた結果、以下の
A)〜C)に示す新知見を得た。
In order to achieve the above object, the inventors of the present invention show a sufficiently high strength even for automobiles, etc., particularly in the range of C content where satisfactory weldability is obtained, and "excellent corrosion resistance and ductility. As a result of various investigations for feasibility of a hot-rolled high-strength steel sheet having an amount of austenite sufficient to utilize the TRIP effect leading to hole expandability, the following results were obtained.
The new findings shown in A) to C) were obtained.

【0022】A)低温加熱、低温熱間圧延によりフェライ
ト粒を微細化できる。
A) Ferrite grains can be refined by low temperature heating and low temperature hot rolling.

【0023】従来の熱延プロセスでは、スラブ加熱温度
が高いためオーステナイト粒は粗大となり、また、高温
で行われる粗圧延後のオーステナイト粒も粗大なもので
あった。そのため、仕上圧延により最終的に得られるフ
ェライト粒もあまり微細化することができなかった。そ
の理由を次に詳述する。
In the conventional hot rolling process, since the slab heating temperature is high, the austenite grains are coarse, and the austenite grains after rough rolling performed at high temperature are also coarse. Therefore, the ferrite grains finally obtained by finish rolling could not be refined so much. The reason will be described in detail below.

【0024】熱延鋼板は、板厚 200mm以上の連続鋳造ス
ラブを、加熱−粗圧延−仕上圧延−巻取の各工程からな
るホットストリップミルラインで板厚3mm程度まで熱間
圧延することによって製造される。このうち仕上圧延は
一般に6台または7台から構成されるタンデムミルで連
続高速圧延される。ところで、仕上圧延では、加熱によ
る発熱よりも主に圧延ロールを通じての抜熱の方が大き
く、鋼板の温度が低下する。圧延開始前の鋼板の温度が
低いと、仕上圧延の終了温度が低下しすぎたり、あるい
は鋼板の変形抵抗が増加し圧延加重が大きくなりすぎる
という問題が生じる。そのため、従来、低温での大圧下
仕上圧延は不可能であった。
The hot-rolled steel sheet is produced by hot rolling a continuously cast slab having a sheet thickness of 200 mm or more to a sheet thickness of about 3 mm in a hot strip mill line consisting of heating-rough rolling-finish rolling-winding steps. To be done. Of these, finish rolling is generally performed at a high speed in a tandem mill composed of 6 or 7 units. By the way, in finish rolling, heat removal mainly through a rolling roll is larger than heat generation due to heating, and the temperature of the steel sheet decreases. If the temperature of the steel sheet before the start of rolling is low, the finish temperature of finish rolling may be too low, or the deformation resistance of the steel sheet may be increased and the weight of rolling may be too large. Therefore, conventionally, large reduction finish rolling at low temperature was impossible.

【0025】本発明者らは種々の検討を行った結果、鋼
板の温度補償を行いながら仕上圧延を行うことによっ
て、低合金鋼においても低温で大圧下仕上圧延が行える
ことを見いだした。
As a result of various studies, the present inventors have found that by performing finish rolling while compensating the temperature of the steel sheet, it is possible to perform large reduction finish rolling at low temperature even for low alloy steel.

【0026】すなわち、仕上圧延機に例えば通電加熱を
適用し鋼板の温度補償を行うことで、仕上圧延前の鋼板
の温度を低下させることができる。このため、スラブ加
熱温度と粗圧延温度を低下させることができる。1100℃
以下でのスラブ低温加熱により、スラブ中に微細に析出
している炭窒化物の再固溶が抑制されるため、オーステ
ナイト粒の粗大化が抑制され、比較的な微細なオーステ
ナイト粒が得られる。
That is, the temperature of the steel sheet before finish rolling can be lowered by applying, for example, electric heating to the finish rolling machine to compensate the temperature of the steel sheet. Therefore, the slab heating temperature and the rough rolling temperature can be lowered. 1100 ° C
By heating the slab at a low temperature below, re-solution of carbonitride finely precipitated in the slab is suppressed, so that coarsening of austenite particles is suppressed and comparatively fine austenite particles are obtained.

【0027】また、低温で粗圧延を行うことで、オース
テナイトの加工−再結晶が繰り返されて粗圧延終了時に
微細で均一なオーステナイト粒が得られる。さらに、低
温で仕上圧延を開始することによってオーステナイトの
加工硬化が促進され、実質的に低温大圧下仕上圧延が達
成され、従来の熱延プロセスでは得ることのできなかっ
た非常に微細なフェライト粒が得られる。
Further, by carrying out rough rolling at a low temperature, processing-recrystallization of austenite is repeated and fine and uniform austenite grains are obtained at the end of rough rolling. Furthermore, by starting finish rolling at a low temperature, work hardening of austenite is promoted, substantially low temperature large reduction finish rolling is achieved, and very fine ferrite grains that could not be obtained by the conventional hot rolling process. can get.

【0028】B)フェライト結晶粒の微細化により穴拡げ
性を向上させることができる。
B) The hole expandability can be improved by refining the ferrite crystal grains.

【0029】熱間仕上圧延時に鋼板の温度補償(例えば
通電加熱を適用)を行い、上記の低温加熱、低温熱間圧
延を実施した結果、粒度番号で14番以上の極めて微細な
ポリゴナルフェライト粒を持ち、残留オーステナイトと
ベイナイト相が均一微細に分散された鋼板を得た。そし
て、このような金属組織を得ることで、伸びと同時に穴
拡げ性も大幅に向上させることが可能であることを見い
だした。
As a result of performing temperature compensation (for example, applying current heating) of the steel sheet during hot finish rolling and performing the above low temperature heating and low temperature hot rolling, extremely fine polygonal ferrite grains with a grain size number of 14 or more. And a retained austenite and bainite phase were uniformly dispersed. It was also found that, by obtaining such a metal structure, it is possible to significantly improve the hole expandability as well as the elongation.

【0030】C)フェライト結晶粒の微細化とSi、Alを含
有することで、微量のCu、P、Niの添加による耐食性が
一段と向上する。
C) By refining the ferrite crystal grains and containing Si and Al, the corrosion resistance is further improved by adding a trace amount of Cu, P and Ni.

【0031】微量のCu、P、Niを添加した鋼に、上記の
熱間圧延を実施し結晶粒を微細化した鋼板について、湿
乾サイクル試験を行い最大穴あき深さを調査した。そし
て、微量のCu、P、Niの添加による耐食性向上の効果
は、フェライト結晶粒の微細化とSi、Alの含有の2条件
が揃うことで、さらに大きくなることを見いだした。
The steel sheet to which trace amounts of Cu, P and Ni were added was subjected to the above-mentioned hot rolling, and the steel sheet obtained by refining the crystal grains was subjected to a wet-dry cycle test to investigate the maximum perforation depth. Then, it was found that the effect of improving the corrosion resistance by adding a small amount of Cu, P, and Ni is further increased by making the ferrite crystal grains fine and the inclusion of Si and Al.

【0032】なお、鋼板にフェライト結晶粒の微細化と
Si、Alの含有の条件が揃うことで、微量のCu、P、Niの
添加による鋼板の耐食性が一段と向上する理由は明らか
ではないが、フェライト結晶粒の微細化によって孔食の
進行が抑制され鋼板表面全体での均一腐食が進行するこ
と、および比較的安定な酸化物を生成するSi、Alによっ
てさらに腐食生成物の安定性が増大することによると考
えられる。
It is to be noted that the ferrite crystal grains are refined on the steel sheet.
Although it is not clear why the addition of a small amount of Cu, P, and Ni further improves the corrosion resistance of the steel sheet by adjusting the conditions for the inclusion of Si and Al, the progress of pitting corrosion is suppressed by the refinement of ferrite crystal grains. It is considered that this is due to the fact that uniform corrosion progresses on the entire surface of the steel sheet and that the stability of the corrosion products is further increased by Si and Al which generate relatively stable oxides.

【0033】[0033]

【作用】次に、本発明において素材鋼の化学組成および
鋼板の組織、ならびにその製造条件について前記のよう
に限定した理由を、その作用と共に詳述する。%は重量
%を意味する。
Next, the reason why the chemical composition of the raw material steel, the structure of the steel sheet, and the manufacturing conditions thereof are limited as described above in the present invention will be described in detail together with the operation thereof. % Means% by weight.

【0034】A)素材鋼の化学組成および鋼板の組織 C:0.05〜0.25% Cは、熱延後の冷却過程において、フェライト変態の進
行にともない未変態オーステナイト中に濃縮してオース
テナイトを安定化させるとともに、鋼板の強化に寄与す
る元素である。C含有量が0.05%未満では強度確保とオ
ーステナイト安定化の効果が十分ではない。一方、0.25
%を超えると溶接性が顕著に劣化する上、ポリゴナルフ
ェライト量が減少してベイナイト量が増加しすぎるため
に、穴拡げ性が劣化し、耐食性も低下する。従って、C
含有量の範囲は0.05〜0.25%と定めた。
A) Chemical composition of raw steel and microstructure of steel sheet C: 0.05 to 0.25% C stabilizes austenite in the untransformed austenite as the ferrite transformation progresses in the cooling process after hot rolling. Together, it is an element that contributes to strengthening the steel sheet. If the C content is less than 0.05%, the effects of securing strength and stabilizing austenite are not sufficient. On the other hand, 0.25
%, The weldability remarkably deteriorates, and the amount of polygonal ferrite decreases and the amount of bainite increases too much, so that the hole expandability deteriorates and the corrosion resistance also decreases. Therefore, C
The content range was set to 0.05 to 0.25%.

【0035】Si:2.5 %以下 Siは、ポリゴナルフェライトの生成を促進してCが未変
態オーステナイト中へ濃縮するのを助け、またセメンタ
イトの析出を遅らせる作用を有している。従って、オー
ステナイトを残留させるために極めて有効な元素であ
り、またポリゴナルフェライトを固溶強化し、鋼板強度
を高めるのに有効な元素でもある。さらにCu、P、Niに
よる耐食性を結晶粒微細化とともに一層向上させる効果
をもつ。しかし、2.5 %を超えるとこれらの効果が飽和
する上に、硬質なマルテンサイトが生成しやすくなっ
て、穴拡げ性の劣化を招く。よって、Si含有量は2.5 %
以下と定めた。ただし、後述するようにsol.Alとの関係
で含有量を制御する。
Si: 2.5% or less Si has the effect of promoting the formation of polygonal ferrite, helping C to concentrate in untransformed austenite, and delaying the precipitation of cementite. Therefore, it is an extremely effective element for remaining austenite, and is also an effective element for solid-solution strengthening the polygonal ferrite and increasing the strength of the steel sheet. Furthermore, it has the effect of further improving the corrosion resistance by Cu, P, and Ni together with the refinement of crystal grains. However, when the content exceeds 2.5%, these effects are saturated, and hard martensite is likely to be formed, resulting in deterioration of hole expansibility. Therefore, the Si content is 2.5%
The following was set. However, the content is controlled in relation to sol.Al as described later.

【0036】sol.Al:2.5 %以下 AlはSiと同様にフェライト安定化元素であり、ポリゴナ
ルフェライト生成を促進してCの未変態オーステナイト
への濃縮を促進し、かつセメンタイトの析出を遅らせる
ため、オーステナイトの残留を促進する作用を有する。
また、Cu、P、Niによる耐食性を結晶粒微細化とともに
一層向上させる効果をもつ。さらに、その作用は同じ重
量%のSi添加よりも顕著である。しかし、Al含有量がso
l.Alとして2.5 %を超えるとその効果が飽和する上に、
介在物の生成を促進し、延性と穴拡げ性が劣化する。従
って、sol.Alの含有量は2.5 %以下と定めた。
Sol.Al: 2.5% or less Al is a ferrite stabilizing element like Si, and promotes the formation of polygonal ferrite to promote the concentration of C in untransformed austenite and delays the precipitation of cementite. , Has the effect of promoting the retention of austenite.
Further, it has the effect of further improving the corrosion resistance of Cu, P and Ni together with the refinement of crystal grains. Moreover, the effect is more pronounced than the addition of the same weight% of Si. However, if the Al content is so
The effect is saturated when l.Al exceeds 2.5%, and
It promotes the formation of inclusions and deteriorates ductility and hole expandability. Therefore, the content of sol.Al was set to 2.5% or less.

【0037】Si+Al:1.0 %以上 SiとAlは、上記のようにオーステナイトの残留を促進す
る作用を有し、またCu、P、Niによる耐食性を結晶粒微
細化とともに一層向上させる効果をもつ。これらの効果
を得るためには、SiとAlの合計含有量を1.0 %以上とす
る必要がある。
Si + Al: 1.0% or more Si and Al have the function of promoting the retention of austenite as described above, and also have the effect of further improving the corrosion resistance of Cu, P and Ni together with the refinement of crystal grains. In order to obtain these effects, the total content of Si and Al must be 1.0% or more.

【0038】従って、Si+Alの合計含有量は1.0 %以上
とした。
Therefore, the total content of Si + Al is set to 1.0% or more.

【0039】Mn: 0.8〜2.5 % Mnはオーステナイト安定化元素であり、未変態オーステ
ナイトのMs 点を低下させるとともに焼入性を向上さ
せ、未変態オーステナイトがパーライト変態するのを抑
制する。しかし、Mn含有量が0.8 %未満ではこの効果が
得られない。一方、2.5 %を超えると熱間圧延後の冷却
過程で十分な量のポリゴナルフェライトを生成させるこ
とが困難となり、そのため未変態オーステナイト中への
Cの濃縮が不十分となって、オーステナイトを安定化さ
せることができない。従って、Mn含有量の範囲は 0.8〜
2.5 %と定めた。
Mn: 0.8 to 2.5% Mn is an austenite stabilizing element, which lowers the Ms point of untransformed austenite and improves the hardenability, and suppresses the transformation of untransformed austenite into pearlite. However, this effect cannot be obtained when the Mn content is less than 0.8%. On the other hand, if it exceeds 2.5%, it becomes difficult to form a sufficient amount of polygonal ferrite in the cooling process after hot rolling, so that the concentration of C in the untransformed austenite becomes insufficient and the austenite is stabilized. I can't make it happen. Therefore, the range of Mn content is 0.8-
It was set at 2.5%.

【0040】Cu:0.10〜0.80% Cuは耐食性を向上させるための主要な成分であり、緻密
な腐食皮膜の生成を通じて耐食性を向上させる効果を有
する。しかし、その含有量が0.10%未満ではこの効果を
得ることができず、一方、0.80%を超えるとこの効果が
飽和して経済性を損なう。従って、Cu含有量の範囲は0.
10〜0.80%と定めた。
Cu: 0.10 to 0.80% Cu is a main component for improving the corrosion resistance and has the effect of improving the corrosion resistance through the formation of a dense corrosion film. However, if the content is less than 0.10%, this effect cannot be obtained, while if it exceeds 0.80%, this effect is saturated and the economic efficiency is impaired. Therefore, the range of Cu content is 0.
It was set at 10 to 0.80%.

【0041】P: 0.020〜0.15% Pも緻密な腐食皮膜の生成を通じて耐食性を高める作用
を有する。しかし、その含有量が0.020 %未満ではこの
効果を得ることができず、一方、0.15%を超えると靱
性、穴拡げ性を劣化させる。従って、P含有量の範囲は
0.020〜0.15%とした。
P: 0.020 to 0.15% P also has the effect of enhancing corrosion resistance through the formation of a dense corrosion film. However, if the content is less than 0.020%, this effect cannot be obtained, while if it exceeds 0.15%, the toughness and hole expandability deteriorate. Therefore, the range of P content is
It was set to 0.020 to 0.15%.

【0042】Ni:0.01〜0.50% NiはCu添加に伴う熱間加工性の低下を防止する作用のほ
か、耐食性を向上させる作用を有する。しかし、その含
有量が0.01%未満ではこれらの効果を得ることができ
ず、一方、0.50%を超えると経済性を損なう。従って、
Ni含有量の範囲は0.01〜0.50%と定めた。
Ni: 0.01 to 0.50% Ni has the function of preventing the deterioration of hot workability associated with the addition of Cu, and the function of improving corrosion resistance. However, if the content is less than 0.01%, these effects cannot be obtained, while if it exceeds 0.50%, the economical efficiency is impaired. Therefore,
The range of Ni content was set to 0.01 to 0.50%.

【0043】本発明方法の対象となる素材鋼では、次の
各元素群から1種以上を選んで含有させることができ
る。
The raw material steel to be subjected to the method of the present invention may contain at least one selected from the following element groups.

【0044】Ca、Zrおよび希土類元素:これらの元素は
いずれも、介在物の形態を調整して冷間加工性を改善す
る作用を有しているため、必要により1種以上含有させ
る。
Ca, Zr, and rare earth elements: Each of these elements has the effect of adjusting the form of inclusions to improve cold workability, so at least one element is contained if necessary.

【0045】Caの場合ではその含有量が0.0002%未満、
Zrの場合ではその含有量が0.01%未満、希土類元素の場
合ではその含有量が0.002 %未満であると、上記の効果
が得られない。一方、Ca含有量が0.010 %を、Zr含有量
が0.10%を、希土類元素含有量が0.10%をそれぞれ超え
ると、逆に鋼中の介在物が多くなりすぎて加工性が劣化
する。従って、Ca含有量の範囲は0.0002〜0.010 %、Zr
含有量の範囲は0.01〜0.10%、希土類元素含有量の範囲
は0.01〜0.10%とそれぞれ定めた。
In the case of Ca, its content is less than 0.0002%,
If the content of Zr is less than 0.01% and the content of rare earth element is less than 0.002%, the above effect cannot be obtained. On the other hand, if the Ca content exceeds 0.010%, the Zr content exceeds 0.10%, and the rare earth element content exceeds 0.10%, conversely, the amount of inclusions in the steel becomes too large and the workability deteriorates. Therefore, the range of Ca content is 0.0002 to 0.010%, Zr
The content range is 0.01 to 0.10%, and the rare earth element content range is 0.01 to 0.10%.

【0046】Nb、TiおよびV:Nb、TiおよびVはいずれ
も、フェライト地に炭窒化物として析出し、鋼板の高強
度化に有効に作用する元素であり、必要により1種以上
含有させる。
Nb, Ti and V: Nb, Ti and V are all elements which are precipitated as carbonitrides on the ferrite material and effectively act to increase the strength of the steel sheet, and if necessary, one or more of them may be contained.

【0047】いずれの場合もその含有量が0.005 %未満
では所望の効果が得られず、一方、NbおよびTiではいず
れも0.10%を、Vでは0.20%を超えると、その効果が飽
和してしまうため経済的ではない。従って、Nb及びTi含
有量の範囲はそれぞれ 0.005〜0.10%、V含有量の範囲
は 0.005〜0.20%と定めた。
In any case, if the content is less than 0.005%, the desired effect cannot be obtained, while if Nb and Ti exceed 0.10% and V exceeds 0.20%, the effect is saturated. Because it is not economical. Therefore, the ranges of Nb and Ti contents were set to 0.005 to 0.10%, and the range of V content was set to 0.005 to 0.20%.

【0048】さらに、上記のCa、Zrおよび希土類元素の
群ならびにNb、TiおよびVの群から、それぞれ1種以上
を選んで、上記含有量の範囲内で複合添加を行うことが
できる。
Further, it is possible to select one or more kinds from the group of Ca, Zr and rare earth elements and the group of Nb, Ti and V, and to carry out composite addition within the above content range.

【0049】なお、鋼中に不可避的に混入する不純物と
しては、S、CrおよびMo等が挙げられるが、例えばSに
ついては、できればその含有量を以下のように抑制する
のが望ましい。
The impurities that are inevitably mixed in the steel include S, Cr and Mo. For example, it is desirable to suppress the content of S as follows.

【0050】S:Sは硫化物系介在物を形成して加工性
を低下させる不純物元素であるため、その含有量は0.05
%以下に抑えるのが望ましい。しかし、一段と優れた加
工性を確保しようとする観点からは0.003 %以下とする
ことがより好ましい。
S: S is an impurity element which forms sulfide inclusions and deteriorates workability, so its content is 0.05.
It is desirable to keep the percentage below. However, it is more preferably 0.003% or less from the viewpoint of ensuring further excellent workability.

【0051】上述の化学組成の素材鋼は、例えば転炉、
電気炉または平炉等により溶製される。鋼種もリムド
鋼、キャップド鋼、セミキルド鋼またはキルド鋼のいず
れでもよい。素材鋼片の製造についても、「造塊−分塊
圧延」あるいは「連続鋳造」のいずれの手段によっても
構わない。
The raw steel having the above-mentioned chemical composition is, for example, a converter,
It is melted in an electric furnace or open furnace. The steel type may also be rimmed steel, capped steel, semi-killed steel or killed steel. The production of the raw steel billet may be performed by any means of "ingot-bulk rolling" or "continuous casting".

【0052】本発明方法による鋼板の組織において、体
積率で5%以上の残留オーステナイトを含んだポリゴナ
ルフェライト主体のものとする理由は、次のとおりであ
る。
The reason why the structure of the steel sheet according to the method of the present invention is mainly composed of polygonal ferrite containing 5% or more of retained austenite by volume is as follows.

【0053】すなわち、延性は主にポリゴナルフェライ
トにより確保されるが、一段と延性を向上させるために
は残留オーステナイトが体積率で5%以上必要である。
That is, the ductility is mainly secured by polygonal ferrite, but in order to further improve the ductility, the residual austenite needs to be 5% or more by volume.

【0054】B)熱延鋼板の製造条件 本発明においては、熱間圧延に供する素材鋼スラブを10
00〜1100度に加熱保持してから、直ちに合計圧下率が50
%以上の熱間粗圧延を行い、 880〜940 ℃で粗圧延を終
了した後、引き続き、合計圧下率が60%以上の仕上圧延
を施し、 780〜840 ℃で仕上圧延を終了し、10〜50℃/s
の冷却速度にて 300〜450 ℃まで加速冷却して巻き取る
ことにより、体積率で5%以上のオーステナイトを残留
させるとともに、延性と穴拡げ性を向上させるに十分な
微細なポリゴナルフェライト主体の組織を得ることが可
能である。
B) Manufacturing Conditions for Hot Rolled Steel Sheet In the present invention, 10 raw steel slabs to be subjected to hot rolling are used.
After heating and holding at 00 ~ 1100 degrees, the total reduction rate is immediately 50
% Hot rolling at a temperature of 880 to 940 ℃, then finish rolling at a total reduction of 60% or more, finish rolling at 780 to 840 ℃, and finish rolling at 10 to 10 50 ° C / s
By accelerating cooling to 300-450 ℃ at the cooling rate and winding up, 5% or more of austenite by volume ratio remains, and the fine polygonal ferrite-based main component is sufficient to improve ductility and hole expansibility. It is possible to get an organization.

【0055】素材鋼スラブを1000〜1100℃に加熱するこ
とにより合金元素をオーステナイト中に固溶させるとと
もに、低温加熱によりオーステナイト粒の粗大化を防止
することができる。加熱温度が1000℃を下回ると、粗圧
延時の温度低下により上記の粗圧延時の下限温度を満た
すことができなくなる。一方、1100℃を超えるとオース
テナイト粒が粗大となり、仕上圧延後にオーステナイト
粒から生成するポリゴナルフェライト粒を十分に微細化
できない。
By heating the raw steel slab to 1000 to 1100 ° C., the alloying elements can be solid-solved in austenite, and heating at low temperature can prevent coarsening of austenite grains. If the heating temperature is lower than 1000 ° C., the above lower limit temperature during rough rolling cannot be satisfied due to the temperature decrease during rough rolling. On the other hand, when the temperature exceeds 1100 ° C, the austenite grains become coarse, and the polygonal ferrite grains generated from the austenite grains after finish rolling cannot be sufficiently refined.

【0056】上記加熱後、直ちに合計圧下率が50%以上
の熱間粗圧延を行い、 880〜940 ℃で圧延を終了するこ
とで均一で微細なオーステナイト粒が得られる。合計圧
下率が50%を下回るか、粗圧延終了温度が940 ℃を超え
ると、仕上圧延後にオーステナイト粒から生成するポリ
ゴナルフェライト粒を十分に微細化することができな
い。一方、粗圧延終了温度が880 ℃を下回ると、仕上圧
延時の温度低下により鋼板の変形抵抗が増加し、圧延荷
重が大きくなりすぎるために、次工程の仕上圧延時の合
計圧下率の下限を満たすことができないばかりでなく、
仕上圧延終了温度の下限も満たすことができない。
Immediately after the above heating, hot rough rolling with a total rolling reduction of 50% or more is performed, and by rolling at 880 to 940 ° C., uniform and fine austenite grains can be obtained. If the total rolling reduction is less than 50% or the rough rolling end temperature exceeds 940 ° C, the polygonal ferrite grains generated from the austenite grains after finish rolling cannot be sufficiently refined. On the other hand, if the rough rolling finish temperature is lower than 880 ° C, the deformation resistance of the steel sheet increases due to the temperature decrease during finish rolling, and the rolling load becomes too large.Therefore, the lower limit of the total reduction rate during finish rolling in the next process is set. Not only can we not meet,
The lower limit of the finish rolling finish temperature cannot be satisfied.

【0057】上記粗圧延終了後、引き続き合計圧下率が
60%以上の仕上圧延を施し、 780〜840 ℃で仕上圧延を
終了することで、オーステナイトを微細化するとともに
オーステナイトを加工硬化させて、ポリゴナルフェライ
トの生成を促進させる。このため、仕上圧延後10〜50℃
/sの冷却速度で加速冷却する間に、十分な量のポリゴナ
ルフェライトを生成させることができる。
After completion of the rough rolling, the total rolling reduction is
By finishing rolling at 60% or more, and finishing rolling at 780 to 840 ° C, the austenite is refined and the austenite is work hardened to promote the formation of polygonal ferrite. Therefore, after finish rolling, 10 to 50 ℃
A sufficient amount of polygonal ferrite can be generated during accelerated cooling at a cooling rate of / s.

【0058】このとき、上記の合計圧下率および仕上温
度を確保するために、鋼板の温度補償を行うのが望まし
い。その手段は問わないが、例えば特開平4−356314号
公報に示されるような直接通電加熱法が適している。
At this time, it is desirable to perform temperature compensation of the steel sheet in order to secure the above-mentioned total rolling reduction and finishing temperature. Any means may be used, but for example, a direct electric heating method as disclosed in JP-A-4-356314 is suitable.

【0059】合計圧下率が60%を下回るか、仕上温度が
840 ℃を超えると、オーステナイトの加工硬化が不十分
となり、ポリゴナルフェライト粒が十分に微細化せず、
穴拡げ性が劣化し、耐食性も低下する。仕上温度を780
℃未満にすると、熱間圧延中にフェライトが生成して加
工フェライトとなるため、加工性が劣化してしまう。
The total rolling reduction is less than 60% or the finishing temperature is
If the temperature exceeds 840 ° C, the work hardening of austenite becomes insufficient and the polygonal ferrite grains do not become sufficiently fine,
Hole expandability deteriorates, and corrosion resistance also decreases. Finishing temperature 780
If the temperature is lower than 0 ° C., ferrite is generated during hot rolling and becomes work ferrite, which deteriorates workability.

【0060】仕上圧延後の冷却速度が10℃/s未満では、
冷却中にパーライトが生成し、オーステナイトが残留し
ない。一方、冷却速度が50℃/sを超えると、十分な量の
フェライトが生成せず、オーステナイトが残留しない。
When the cooling rate after finish rolling is less than 10 ° C./s,
Perlite is formed during cooling and no austenite remains. On the other hand, when the cooling rate exceeds 50 ° C./s, a sufficient amount of ferrite is not formed and austenite does not remain.

【0061】上記の加速冷却は、鋼板の温度が 300〜45
0 ℃になるまで行い、この温度範囲で巻き取る必要があ
る。巻取温度が450 ℃を超えるとパーライトが生成し、
オーステナイトが十分に残留しない。一方、300 ℃を下
回る温度域で巻取りを行うとマルテンサイトの生成が促
進され、延性と穴拡げ性が劣化する。
In the above accelerated cooling, the temperature of the steel sheet is 300 to 45.
It is necessary to carry out the treatment until it reaches 0 ° C and wind it in this temperature range. When the winding temperature exceeds 450 ℃, pearlite is generated,
Not enough austenite remains. On the other hand, when the coiling is carried out in a temperature range below 300 ° C, the formation of martensite is promoted, and the ductility and hole expansibility are deteriorated.

【0062】以上の本発明に係わる熱延鋼板は、C含有
量が0.05〜0.25%の範囲であるから、高強度部材用鋼板
に要求されるレベルの溶接性を具備し、さらにTRIP
を利用するに十分な量の残留オーステナイトを有する。
しかも、結晶粒径を微細化することによって、従来の残
留オーステナイト鋼板の弱点であった穴拡げ性も向上し
た高延性鋼板である。さらに、溶接性を損なうことな
く、耐食性にも優れた鋼板である。
The hot-rolled steel sheet according to the present invention described above has a C content in the range of 0.05 to 0.25%, and therefore has the weldability of the level required for a steel sheet for high strength members.
Have a sufficient amount of residual austenite to utilize.
Moreover, by making the crystal grain size finer, the high ductility steel sheet has improved hole expandability, which was a weak point of the conventional retained austenite steel sheet. Further, it is a steel sheet excellent in corrosion resistance without impairing weldability.

【0063】従って、本発明によれば、溶接性が良好で
あるとともに、残留オーステナイトを生成させることで
引張強度と伸びバランス(TS×EL)が良好で、しかも穴
拡げ性と耐食性の優れた熱延鋼板を得ることができる。
Therefore, according to the present invention, the weldability is good, the tensile strength and elongation balance (TS × EL) are good by forming retained austenite, and the heat expandability and corrosion resistance are excellent. A rolled steel plate can be obtained.

【0064】なお、本発明の方法で製造された鋼板に溶
融亜鉛メッキ、合金化溶融亜鉛メッキ、電気メッキ等の
表面処理を施した場合には、優れた延性と穴拡げ性に加
え、さらに優れた耐食性を兼ね備えた表面処理鋼板を得
ることができる。
When the steel sheet produced by the method of the present invention is subjected to surface treatment such as hot dip galvanizing, hot dip galvanizing, and electroplating, in addition to excellent ductility and hole expansibility, It is possible to obtain a surface-treated steel sheet having excellent corrosion resistance.

【0065】[0065]

【実施例】表1、表2に示す化学組成の素材鋼スラブを
表3、表4に示す条件で圧延し、厚さ2.3mm の鋼板を製
造した。鋼種A〜Tは本発明で定める組成を満足する鋼
であり、鋼U〜Z、αおよびβは比較例鋼である。
Example A raw steel slab having the chemical composition shown in Tables 1 and 2 was rolled under the conditions shown in Tables 3 and 4 to produce a steel plate having a thickness of 2.3 mm. Steel types A to T are steels satisfying the composition defined in the present invention, and steels U to Z, α and β are comparative example steels.

【0066】得られた鋼板から、JIS 5号引張試験片を
採取し、機械的性質を調査した。また、厚さ 2.3mm×幅
120mm ×長さ120mm の鋼板試験片にφ14mmの孔をクリア
ランス15%で打ち抜き、円錐ポンチを用いて穴拡げ性を
調査した。さらに、鋼板中央部からX線試験用の試験片
を採取し、残留オーステナイト量の調査も実施した。
From the obtained steel sheet, JIS No. 5 tensile test pieces were sampled and their mechanical properties were investigated. Also, thickness 2.3 mm x width
A φ14 mm hole was punched out from a 120 mm × 120 mm long steel plate test piece with a clearance of 15%, and the hole expandability was investigated using a conical punch. Further, a test piece for X-ray test was sampled from the central portion of the steel sheet, and the amount of retained austenite was also investigated.

【0067】耐食性については、鋼板から幅30mm×長さ
70mmの試験片を切り出し、「湿潤保持 (湿度:95%以
上、温度:室温で16時間保持)→塩水噴霧(5%食塩
水、35℃×6時間保持)→乾燥(50℃×2時間保持)」
を1サイクルとする腐食試験を行い、最大腐食深さの変
化を調べた。これらの結果を表3、表4に併せて示す。
Regarding corrosion resistance, from the steel plate, width 30 mm x length
A 70 mm test piece was cut out, and "wet keeping (humidity: 95% or more, temperature: holding at room temperature for 16 hours) → salt spray (5% saline, holding at 35 ° C x 6 hours) → drying (holding at 50 ° C x 2 hours) ) "
The corrosion test was carried out with 1 cycle as a cycle, and the change in the maximum corrosion depth was investigated. The results are also shown in Tables 3 and 4.

【0068】表3、表4から明らかなように、本発明で
定める条件で製造された熱延鋼板では、TSが 70kgf/mm2
以上の高強度とELが30%以上の高延性を達成していると
同時に、穴拡げ率が80%以上の優れた打ち抜き加工性を
示し、さらに、従来の耐食鋼に比べて耐食性にも優れて
おり、高耐食性、高強度かつ高加工性を同時に満足して
いることがわかる。
As is clear from Tables 3 and 4, TS was 70 kgf / mm 2 in the hot-rolled steel sheet manufactured under the conditions specified in the present invention.
While achieving the above high strength and high ductility with EL of 30% or more, it exhibits excellent punching workability with a hole expansion ratio of 80% or more. Furthermore, it has excellent corrosion resistance compared to conventional corrosion resistant steel. Therefore, it is understood that high corrosion resistance, high strength and high workability are satisfied at the same time.

【0069】一方、C含有量が本発明で定める範囲を超
える鋼種Uによる鋼板を用いた試験No.28 では、伸びは
比較的高いものの、穴拡げ性と耐食性が低下している。
C含有量が本発明の範囲を下回る鋼種Wによる鋼板を用
いた試験No.30 では、強度が大幅に低下している。
On the other hand, in the test No. 28 using the steel sheet of the steel type U whose C content exceeds the range defined in the present invention, although the elongation is relatively high, the hole expandability and the corrosion resistance are deteriorated.
In Test No. 30 using the steel sheet of the steel type W having the C content below the range of the present invention, the strength is significantly reduced.

【0070】Siとsol.Alの合計含有量が本発明で定める
範囲を下回る鋼種Vによる鋼板を用いた試験No.29 で
は、強度、伸び、穴拡げ性および耐食性がいずれも低下
している。
In Test No. 29 using a steel sheet of steel type V in which the total content of Si and sol.Al is less than the range defined in the present invention, strength, elongation, hole expansibility and corrosion resistance are all deteriorated.

【0071】Mn含有量が本発明で定める範囲を下回る鋼
種Xによる鋼板を用いた試験No.31では、強度、伸びと
もに低下している。
In the test No. 31 using the steel sheet according to the steel type X whose Mn content is below the range defined by the present invention, both strength and elongation are lowered.

【0072】Si含有量が本発明で定める範囲を超える鋼
種Yによる鋼板を用いた試験No.32では、穴拡げ性が劣
化している。
In Test No. 32 using the steel sheet of the steel type Y having the Si content exceeding the range specified in the present invention, the hole expansibility is deteriorated.

【0073】PまたはCu含有量が本発明で定める範囲を
下回る、それぞれ鋼種Zまたは鋼種αによる鋼板を用い
た試験No.33 と試験No.34 では、耐食性が低下してい
る。
In the test No. 33 and the test No. 34 using the steel sheet of the steel grade Z or the steel grade α, respectively, in which the P or Cu content is less than the range defined by the present invention, the corrosion resistance is lowered.

【0074】P含有量が本発明で定める範囲を超える鋼
種βによる鋼板をを用いた試験No.35 では、穴拡げ性が
低下している。
In Test No. 35 using the steel sheet of the steel type β in which the P content exceeds the range defined in the present invention, the hole expansibility is deteriorated.

【0075】仕上圧延終了温度が本発明で定める範囲を
超える試験No.22 では、ポリゴナルフェライト粒の微細
化が十分でなく、穴拡げ性と耐食性が低下している。
In Test No. 22 in which the finishing rolling finishing temperature exceeds the range defined by the present invention, the polygonal ferrite grains were not sufficiently refined, and the hole expandability and the corrosion resistance were deteriorated.

【0076】巻取温度が本発明で定める範囲を超える条
件で製造された試験No.21 では、残留オーステナイトが
十分に生成せず、伸びが低下している。巻取温度が本発
明で定める範囲を下回る条件で製造された試験No.23 で
は、残留オーステナイトが十分に生成せず、伸びが低下
し、また穴拡げ性も良好でない。
In Test No. 21, which was manufactured under the condition that the coiling temperature exceeded the range defined by the present invention, retained austenite was not sufficiently generated and the elongation was reduced. In Test No. 23, which was manufactured under the condition that the winding temperature was lower than the range defined by the present invention, retained austenite was not sufficiently generated, elongation was reduced, and hole expandability was not good.

【0077】仕上圧延終了温度、冷却速度等が本発明で
定める範囲外の条件で製造された試験No.24 では、残留
オーステナイトが十分に生成せず、伸びが低下してい
る。
In Test No. 24, which was manufactured under conditions in which the finish rolling finish temperature, the cooling rate, etc. were out of the ranges defined in the present invention, retained austenite was not sufficiently generated and the elongation was reduced.

【0078】熱間粗圧延の合計圧下率、その終了温度、
仕上圧延の合計圧下率等が本発明で定める範囲外の条件
で製造された試験No.25 、26および27では、いずれもポ
リゴナルフェライト粒の微細化が十分でなく、穴拡げ性
と耐食性が低下している。
Total reduction of hot rough rolling, its end temperature,
In the test Nos. 25, 26 and 27, which were manufactured under the conditions in which the total rolling reduction of finish rolling was out of the range defined in the present invention, the polygonal ferrite grains were not sufficiently refined, and the hole expandability and corrosion resistance were not sufficient. It is falling.

【0079】[0079]

【表1】 [Table 1]

【0080】[0080]

【表2】 [Table 2]

【0081】[0081]

【表3】 [Table 3]

【0082】[0082]

【表4】 [Table 4]

【0083】[0083]

【発明の効果】本発明によれば、耐食性、強度、延性、
穴拡げ性および溶接性がいずれも優れる高加工性熱延高
張力鋼板を安定して製造することができる。この鋼板を
自動車の足廻り部品等の産業機器部材に適用すれば、そ
れらの製品の性能や寿命を一段と改善することが可能と
なるなど、産業上極めて有用な効果がもたらされる。
According to the present invention, corrosion resistance, strength, ductility,
A highly workable hot-rolled high-strength steel sheet having excellent hole expandability and weldability can be stably manufactured. When this steel sheet is applied to industrial equipment members such as undercarriage parts of automobiles, it is possible to further improve the performance and life of those products, which brings about extremely useful effects in industry.

フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C22C 38/16 Continuation of front page (51) Int.Cl. 6 Identification code Office reference number FI technical display area C22C 38/16

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】重量%で、C:0.05〜0.25%、Si:2.5 %
以下、sol.Al:2.5 %以下、Mn:0.8〜2.5 %、Cu:0.10
〜0.80%、P: 0.020〜0.15%およびNi:0.01〜0.50%
を含有し、かつ(Si+Al)≧1.0 %を満足し、残部はFe
および不可避的不純物からなる鋼を、1000〜1100℃に加
熱保持してから、直ちに合計圧下率が50%以上の熱間粗
圧延を行い、 880〜940 ℃で粗圧延を終了した後、引き
続き合計圧下率が60%以上の仕上圧延を施し、 780〜84
0 ℃で仕上圧延を終了し、10〜50℃/sの冷却速度にて 3
00〜450 ℃まで加速冷却した後巻き取り、体積率で5%
以上の残留オーステナイトを含むポリゴナルフェライト
主体の組織とすることを特徴とする耐食性および穴拡げ
性の優れた高延性熱延高張力鋼板の製造方法。
1. C: 0.05 to 0.25%, Si: 2.5% by weight
Below, sol.Al: 2.5% or less, Mn: 0.8 to 2.5%, Cu: 0.10.
~ 0.80%, P: 0.020 ~ 0.15% and Ni: 0.01 ~ 0.50%
And satisfies (Si + Al) ≥ 1.0% with the balance being Fe
And steel containing unavoidable impurities are heated and held at 1000 to 1100 ° C, and then hot rough rolling with a total reduction of 50% or more is immediately performed, and after rough rolling at 880 to 940 ° C is completed, the total rolling is continued. Finish rolling with a rolling reduction of 60% or more, 780 ~ 84
Finish rolling at 0 ℃, 3 at the cooling rate of 10 ~ 50 ℃ / s
After accelerating cooling to 00-450 ℃, wind it up, 5% by volume
A method for producing a high-ductility hot-rolled high-strength steel sheet excellent in corrosion resistance and hole expansibility, characterized by having a structure mainly composed of polygonal ferrite containing retained austenite as described above.
【請求項2】重量%で、C:0.05〜0.25%、Si:2.5 %
以下、sol.Al:2.5 %以下、Mn:0.8〜2.5 %、Cu:0.10
〜0.80%、P: 0.020〜0.15%およびNi:0.01〜0.50%
を含有し、かつ(Si+Al)≧1.0 %を満足し、更にCa:
0.0002〜0.0100%、Zr:0.01〜0.10%および希土類元
素: 0.002〜0.10%のうちの1種または2種以上を含
み、残部はFeおよび不可避的不純物からなる鋼を、1000
〜1100℃に加熱保持してから、直ちに合計圧下率が50%
以上の熱間粗圧延を行い、 880〜940 ℃で粗圧延を終了
した後、引き続き合計圧下率が60%以上の仕上圧延を施
し、 780〜840 ℃で仕上圧延を終了し、10〜50℃/sの冷
却速度にて 300〜450 ℃まで加速冷却した後巻き取り、
体積率で5%以上の残留オーステナイトを含むポリゴナ
ルフェライト主体の組織とすることを特徴とする耐食性
および穴拡げ性の優れた高延性熱延高張力鋼板の製造方
法。
2. C: 0.05 to 0.25%, Si: 2.5% by weight
Below, sol.Al: 2.5% or less, Mn: 0.8 to 2.5%, Cu: 0.10.
~ 0.80%, P: 0.020 ~ 0.15% and Ni: 0.01 ~ 0.50%
And (Si + Al) ≥ 1.0%, and Ca:
Steel containing at least one of 0.0002 to 0.0100%, Zr: 0.01 to 0.10%, and rare earth element: 0.002 to 0.10%, the balance being Fe and inevitable impurities, 1000
Immediately after heating and holding at ~ 1100 ℃, the total rolling reduction is 50%.
After performing the above hot rough rolling and finishing the rough rolling at 880 ~ 940 ℃, finish rolling with a total reduction of 60% or more, finish the finish rolling at 780 ~ 840 ℃, 10 ~ 50 ℃ After accelerated cooling to 300-450 ℃ at a cooling rate of / s, winding,
A method for producing a high-ductility hot-rolled high-strength steel sheet having excellent corrosion resistance and hole expandability, which has a structure mainly composed of polygonal ferrite containing 5% or more by volume of retained austenite.
【請求項3】請求項1または2の成分に、加えて更に、
Nb: 0.005〜0.10%、Ti: 0.005〜0.10%およびV:
0.005〜0.20%のうちの1種または2種以上を含む鋼
を、1000〜1100℃に加熱保持してから、直ちに合計圧下
率が50%以上の熱間粗圧延を行い、 880〜940 ℃で粗圧
延を終了した後、引き続き合計圧下率が60%以上の仕上
圧延を施し、 780〜840 ℃で仕上圧延を終了し、10〜50
℃/sの冷却速度にて 300〜450 ℃まで加速冷却した後巻
き取り、体積率で5%以上の残留オーステナイトを含む
ポリゴナルフェライト主体の組織とすることを特徴とす
る、いずれかの耐食性および穴拡げ性の優れた高延性熱
延高張力鋼板の製造方法。
3. In addition to the component of claim 1 or 2, further
Nb: 0.005-0.10%, Ti: 0.005-0.10% and V:
Steel containing one or more of 0.005 to 0.20% is heated and held at 1000 to 1100 ° C, and then immediately hot rough rolled with a total reduction of 50% or more at 880 to 940 ° C. After finishing the rough rolling, finish rolling with a total rolling reduction of 60% or more is continued, finish rolling at 780 to 840 ℃, and finish rolling to 10 to 50
One of the corrosion resistance characteristics is characterized by accelerating cooling to 300 to 450 ° C at a cooling rate of ℃ / s, and then winding it to obtain a structure mainly composed of polygonal ferrite containing 5% or more of retained austenite by volume. A method for producing a high-ductility hot-rolled high-strength steel sheet having excellent hole expandability.
JP3230394A 1994-03-02 1994-03-02 Production of high ductility hot rolled high tensile strength steel plate excellent in corrosion resistance Pending JPH07242947A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3230394A JPH07242947A (en) 1994-03-02 1994-03-02 Production of high ductility hot rolled high tensile strength steel plate excellent in corrosion resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3230394A JPH07242947A (en) 1994-03-02 1994-03-02 Production of high ductility hot rolled high tensile strength steel plate excellent in corrosion resistance

Publications (1)

Publication Number Publication Date
JPH07242947A true JPH07242947A (en) 1995-09-19

Family

ID=12355185

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3230394A Pending JPH07242947A (en) 1994-03-02 1994-03-02 Production of high ductility hot rolled high tensile strength steel plate excellent in corrosion resistance

Country Status (1)

Country Link
JP (1) JPH07242947A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1007731C2 (en) * 1997-12-08 1999-06-09 Hoogovens Staal Bv Method and device for manufacturing a ferritically rolled steel strip.
US6773522B1 (en) 1997-12-08 2004-08-10 Corus Staal Bv Process and device for producing a high-strength steel strip
CN110684925A (en) * 2019-10-10 2020-01-14 邯郸钢铁集团有限责任公司 High-strength wear-resistant corrosion-resistant hot-rolled steel strip and production method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1007731C2 (en) * 1997-12-08 1999-06-09 Hoogovens Staal Bv Method and device for manufacturing a ferritically rolled steel strip.
WO1999029446A1 (en) * 1997-12-08 1999-06-17 Corus Staal Bv Process and device for producing a ferritically rolled steel strip
US6616778B1 (en) 1997-12-08 2003-09-09 Corus Staal Bv Process and device for producing a ferritically rolled steel strip
US6773522B1 (en) 1997-12-08 2004-08-10 Corus Staal Bv Process and device for producing a high-strength steel strip
CN110684925A (en) * 2019-10-10 2020-01-14 邯郸钢铁集团有限责任公司 High-strength wear-resistant corrosion-resistant hot-rolled steel strip and production method thereof

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