JPH07228841A - Coating material antifoulant to food, - Google Patents

Abstract

PURPOSE:To provide a coating material excellent in heat resistance, hardness and antifoulancy to food by dissolving or dispersing an alkyl silicate, a silicate, colloidal silica, an alkaline earth metal nitrate salt, a silicone resin and an inorganic filler in a solvent. CONSTITUTION:The coating is produced by dissolving or dispersing (A) 100 pts.wt. of an alkyl silicate of formula: (R<2>)nSi(OR<3>)4-n (R<2>, R<3> are 1-4C alkyl; m is 1-3), (B) 5-50 pts.wt. of a silicate of formula: Si(OR<1>)4 (R<1> is 1-4C alkyl), (C) 5-50 pts.wt. of colloidal silica, (D) 5-50 pts.wt. of an alkaline earth metal salt, (E) 2-25 pts.wt. of a silicone resin, (F) 10-100 pts.wt. of an inorganic filler in a solvent such as methanol.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a coating material having a high hardness and capable of forming a coating film on which food scorching or stains do not adhere strongly.

[0002]

2. Description of the Related Art A coating film formed of a heat-resistant paint is generally applied to the inner wall or surface of a cooking device for cooking food such as a microwave oven and a hot plate. This coating is required to have high hardness so that it will not be scratched even if it comes into contact with cooking equipment, and at the same time, it does not have a strong sticking or stain generated by cooking food, that is, so-called self-clearing. Is required.

Many paints or coatings containing an organosilicon polymer as one component have been proposed as coatings for forming coatings having heat resistance and self-cleaning properties. For example, JP-A-2-282636 discloses that
A coating film in which the lower layer is made of polytitanocarbosilane and the upper layer is made of fluororesin is disclosed. In addition, Japanese Patent Laid-Open No. 3-
Japanese Patent No. 45666 describes a coating composed of polyborosiloxane, a fluororesin, a sulfide such as molybdenum disulfide, and glass powder.

Various paints containing an organic silicon polymer as one component have been proposed as paints for forming a coating film having high hardness in addition to heat resistance. For example, JP-A-4-91177 discloses a polymetallocarbosilane,
Disclosed is a coating composition in which a silicone resin, an inorganic filler, and an alkoxide of a metal such as titanium, zirconium, or aluminum are dispersed or dissolved in an organic solvent.

[0005]

It is desired that a coating film applied to a food cooker has all of heat resistance, high hardness and food stain resistance. As described above, paints that form coating films individually satisfying these demands have been proposed, but at the same time, there are no coating films or coatings that satisfy all the properties at the same time. An object of the present invention is to provide a coating material capable of forming a coating film that simultaneously satisfies the above three characteristics.

[0006]

According to the present invention, the formula (R ² ) _n Si (OR ³ ) _4-n (wherein R ² and R ³ are alkyl groups having 1 to 4 carbon atoms, n is an integer of 1 to 3), and a silicate represented by the formula: Si (OR ¹ ) ₄ (wherein, R ¹ is an alkyl group having 1 to 4 carbon atoms). Provided is a food stain resistant coating in which colloidal silica, an alkali metal or alkaline earth metal nitrate, a silicone resin, and an inorganic filler are dissolved or dispersed in a solvent.

Specific examples of the alkyl silicate include methyltrimethoxysilane, methyltriethoxysilane,
Methyltributoxysilane, ethyltriethoxysilane, ethyltributoxysilane, butyltriethoxysilane, dimethyldimethoxysilane, dimethyldiethoxysilane, diethyldiethoxysilane, dibutyldiethoxysilane, trimethylmethoxysilane, trimethylethoxysilane, triethylethoxy Examples thereof include silane and tributylethoxysilane.

Specific examples of the silicate include tetramethoxysilane, tetraethoxysilane, tetrapropoxysilane and tetrabutoxysilane. The ratio of silicate used is preferably 5 to 50 parts by weight per 100 parts by weight of alkyl silicate. Sirique
In both cases where the use ratio of the toner is excessively low or conversely excessive, it is difficult to form the coating film, and even if the coating film is formed, pinholes are easily generated in the coating film.

There is no particular limitation on the combination of the silicate and the alkyl silicate, but methyl trimethoxysilane, ethyltriethoxysilane, methyltrimethoxysilane, methyltriethoxysilane, A combination of an alkyltrialkoxysilane such as tributoxysilane and a monoalkyltrialkoxysilane such as methyltrimethoxysilane, methyltriethoxysilane, ethyltriethoxysilane and butyltriethoxysilane can be preferably used.

The amount of colloidal silica used is preferably 5 to 50 parts by weight per 100 parts by weight of the alkyl silicate. If the proportion of colloidal silica used is too low, cracking of the coating tends to occur due to shrinkage during coating formation, and even if the proportion of use is excessively high, no difference will be observed in the crack prevention function. .

Specific examples of alkali metal or alkaline earth metal nitrates (hereinafter, both may be collectively referred to as "metal nitrates") include sodium nitrate.
Examples thereof include potassium nitrate, magnesium nitrate, calcium nitrate, and barium nitrate. The amount of the metal nitrate used is preferably 5 to 50 parts by weight per 100 parts by weight of the alkyl silicate. If the proportion of metal nitrate used is too small, the food stain resistance of the coating film will decrease,
Even if the usage ratio is increased in the past, the food stain resistance of the coating film is not further improved, and conversely the physical properties of the coating film are deteriorated.

Examples of silicone resins include polyorganosiloxanes, silicone oils, silicone varnishes and silicone rubbers. The silicone resin is preferably used in an amount of 2 to 25 parts by weight per 100 parts by weight of alkylalkoxysilane. If the proportion of silicone resin used is too small, the food stain resistance of the coating film will decrease, and even if the proportion of silicone resin used is too large, the food stain resistance of the coating film will be further improved. On the contrary, the physical properties of the coating film deteriorate.

Specific examples of the inorganic filler include magnesium, calcium, barium, titanium, zirconium, chromium, manganese, iron, cobalt, nickel, copper, zinc,
Examples include boron, aluminum, silicon oxides, carbides, nitrides, silicides, borides, lithium, sodium, potassium, magnesium, calcium, zinc borates, phosphates, and silicates.

The amount of the inorganic filler used is preferably 10 to 100 parts by weight per 100 parts by weight of the alkylalkoxysilane. If the proportion of the inorganic filler used is too small, the adhesion of the coating film to the material to be coated or the hardness of the coating will decrease, and if the proportion of the inorganic filler used is too large, the flexibility of the coating will decrease. Like

Specific examples of the solvent that dissolves or disperses the above-mentioned coating film forming components include 1 carbon atoms such as methanol, ethanol, propanol, butanol, pentanole and hexanole. -6 aliphatic alcohols such as acetone, methyl ethyl ketone and methyl isobutyl ketone. The use ratio of the solvent varies depending on the type and the use ratio of the coating film forming component, but can be appropriately determined by those skilled in the art according to the disclosure of the present invention. Two
It is 00 parts by weight.

The coating composition of the present invention can be prepared by dissolving or dispersing the film-forming components in a solvent in any order. The coating material of the present invention is applied to a metal base material, or a non-metal base material such as ceramics or bricks by a means known per se such as brush coating, roll coater, spraying, dipping, and the like. It is dried and baked.
The coating amount of the coating material is preferably ²⁰ to 100 g / m ² . If the coating amount is too small, pinholes are likely to occur in the coating film, and if the coating amount is excessively large, cracks are likely to occur in the coating film when the coating film is exposed to high temperature or cold heat cycles.

The baking temperature is 150 ° C. or higher, especially 200
It is preferably ˜400 ° C. If the baking temperature is excessively low, the coating components will not be sufficiently cured, and the strength of the coating film will be low and the impact resistance will be low. If the baking temperature is too high, special heating equipment will be required. In addition, after painting the paint,
When placed in a use environment of 0 ° C. or higher, the baking process can be omitted.

[0018]

EXAMPLES Examples will be shown below. The hardness of the coating film is JIS
The food stain resistance was determined by # 5400, and the presence or absence of charring and stains was visually observed after placing a lard on the coating film and heating at 300 ° C. for 1 hour, and was certified according to the following criteria. Good: Not observed at all. Acceptable: Some are observed. Poor: Remarkably observed. In the following, all "parts" indicate "parts by weight".

Example 1 100 parts of methyltrimethoxysilane, 25 parts of tetraethoxysilane, 25 parts of colloidal silica, 25 parts of sodium nitrate, 12.5 parts of methylphenylsilicone oil,
And 50 parts of silicon carbide powder was dissolved and dispersed in 75 parts of propanol to prepare a paint.

This coating material was applied to the surface of an aluminum substrate, predried at 150 ° C. for 20 minutes, and then baked at 250 ° C. for 20 minutes to form a coating film having a thickness of about 15 μm. The hardness of the obtained coating film was 7H, and the food stain resistance was “good”.

Example 2 Example 1 was repeated except that the baking temperature was changed to 300 ° C. The hardness of the obtained coating film was 9H, and the food stain resistance was “good”.

Example 3 Example 1 was repeated except that dimethyldimethoxysilane 100 was used instead of methyltrimethoxysilane.
The hardness of the obtained coating film was 7H, and the food stain resistance was "good to acceptable".

Example 4 Instead of tetraethoxysilane, tetrabutoxysilane 2
Example 1 was repeated except that 5 parts were used. The hardness of the obtained coating film was 7H, and the food stain resistance was "good to acceptable".

Example 5 Example 1 was repeated except that 25 parts of magnesium nitrate was used instead of sodium nitrate. The hardness of the obtained coating film was 7H, and the food stain resistance was "OK".

Claims (1)

[Claims] 1. The formula (R ² ) _n Si (OR ³ ) _4-n (wherein R ² and R ³ are alkyl groups having 1 to 4 carbon atoms, and n is an integer of 1 to 3). ), An alkyl silicate represented by the formula: Si (OR ¹ ) ₄ (wherein R ¹ is an alkyl group having 1 to 4 carbon atoms), colloidal silica, an alkali metal or an alkaline earth metal. A food stain resistant coating in which the nitrate, the silicone resin, and the inorganic filler are dissolved or dispersed in a solvent.