JPH07140730A - High-speed developing method for electrostatic charge image - Google Patents
High-speed developing method for electrostatic charge imageInfo
- Publication number
- JPH07140730A JPH07140730A JP5286982A JP28698293A JPH07140730A JP H07140730 A JPH07140730 A JP H07140730A JP 5286982 A JP5286982 A JP 5286982A JP 28698293 A JP28698293 A JP 28698293A JP H07140730 A JPH07140730 A JP H07140730A
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- carrier
- magnetic
- developer
- developing
- electrostatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Magnetic Brush Developing In Electrophotography (AREA)
- Dry Development In Electrophotography (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、電子写真法、静電写真
法、静電印刷法などに用いられる静電荷像の高速現像方
法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a high-speed developing method for an electrostatic charge image used in electrophotography, electrostatic photography, electrostatic printing and the like.
【0002】[0002]
【従来の技術】磁性キャリアとトナーからなる現像剤は
電子写真法を利用する複写機に広く用いられており、静
電荷像現像に際しては、現像剤担持体表面に現像剤の磁
気ブラシを形成し、この磁気ブラシを静電荷像担持体に
接触、摺擦させてトナー像を形成させている。2. Description of the Related Art A developer composed of a magnetic carrier and a toner is widely used in a copying machine utilizing an electrophotographic method. When developing an electrostatic image, a magnetic brush of the developer is formed on the surface of a developer carrier. The toner image is formed by contacting and rubbing the magnetic brush with the electrostatic image carrier.
【0003】しかし、短時間に多量の複写物が得られる
高速複写機においては、本現像方法を適用するにあた
り、種々の問題が発生する。However, in a high-speed copying machine capable of obtaining a large number of copies in a short time, various problems occur when applying the present developing method.
【0004】それらの内、出力画像に影響を与える問題
としては、静電荷像担持体を高速に回転させる必要があ
ることから、静電荷像のハーフトーンやベタ部に現像さ
れたトナー層を、その高速性が故、磁気ブラシの擦過に
より周方向へ乱し、いわゆる「掃き目」を発生させてし
まう点がある。これは、出力画像において、ベタ部の荒
れや擦過傷による濃度ムラ、細線部の切れなどの問題と
して現れる。Among them, the problem affecting the output image is that the electrostatic charge image carrier must be rotated at a high speed, so that the halftone of the electrostatic charge image or the toner layer developed in the solid part is Due to its high speed, there is a point that it is disturbed in the circumferential direction by rubbing of the magnetic brush, and so-called "sweep" is generated. This appears in the output image as problems such as unevenness in the solid portion and uneven density due to scratches, and breaks in fine line portions.
【0005】また、加えて、その高速性が故、遠心力の
増大により磁気ブラシを構成する磁性キャリアの飛散量
が増加し、一部が静電荷像担持体表面へ付着する場合が
ある。その場合、磁性キャリアが付着したまま転写部や
クリーニング部を通過することになり、付着磁性キャリ
アは静電荷像担持体を傷つけてしまう。その結果、その
傷跡が静電荷像を乱し、結果として出力画像の乱れを発
生させる問題もある。さらに、付着磁性キャリアによる
傷は、静電荷像担持体の耐用性の低下を招き、実用上の
大きな問題となる。In addition, due to its high speed, the scattering amount of the magnetic carrier constituting the magnetic brush may increase due to the increase in centrifugal force, and a part of the magnetic carrier may adhere to the surface of the electrostatic image carrier. In that case, the magnetic carrier passes through the transfer section and the cleaning section while being attached, and the attached magnetic carrier damages the electrostatic image carrier. As a result, there is also a problem that the scar disturbs the electrostatic charge image, resulting in disorder of the output image. Further, the scratches caused by the adhered magnetic carrier reduce the durability of the electrostatic image carrier, which is a serious problem in practical use.
【0006】従来は、磁気ブラシの擦過力を低減させる
ために種々の方法が取られていた。しかし、いずれも充
分な対策とはなっていない。Conventionally, various methods have been taken to reduce the rubbing force of magnetic brushes. However, none of them are sufficient measures.
【0007】例えば、現像剤担持体の周面の移動線速と
静電荷像担持体の周面の移動線速の差をできる限り小さ
くして擦過力を低減させる方法、また、現像剤担持体と
静電荷像担持体間の距離Dsdを広げたり、磁気ブラシの
高さを低くしたりすることにより磁気ブラシの擦過力を
低減させる方法などが取られているが、いずれの方法に
おいても、現像領域へ搬送される現像剤の量を減らすこ
とになり、画像濃度の低下を招いている。For example, a method of reducing the frictional force by minimizing the difference between the moving linear velocity of the peripheral surface of the developer carrying member and the moving linear velocity of the peripheral surface of the electrostatic charge image carrying member, and a developer carrying member. A method of reducing the rubbing force of the magnetic brush by widening the distance Dsd between the electrostatic charge image carrier and the electrostatic charge image carrier or reducing the height of the magnetic brush has been adopted. The amount of developer conveyed to the area is reduced, resulting in a decrease in image density.
【0008】また、この画像濃度の低下を、現像剤中の
トナー濃度を高くすることにより補う方法も提案されて
いるが、高速複写機においてはトナー飛散の問題が顕著
に発生し、適切な対策とは言えない。Although a method of compensating for this decrease in image density by increasing the toner density in the developer has been proposed, a problem of toner scattering occurs remarkably in a high speed copying machine, and an appropriate countermeasure is taken. It can not be said.
【0009】[0009]
【発明が解決しようとする課題】本発明は、磁性キャリ
アとトナーからなる現像剤を使用する従来の現像方法を
静電荷像担持体の周面の移動線速Vpが400mm/sを越え
るような高速域で使用する場合の欠点を解消し、ハーフ
トーンやベタ部のトナー層の乱れである現像掃き目を防
止し、それに加え、静電荷像担持体へのキャリアの付着
を抑えることにより、静電荷像担持体表面の擦過傷の発
生を防止し、細線の切れがなく、濃度が高く均一でかつ
輪郭のはっきりした画像を高速に得ることができる現像
方法を提供するものである。SUMMARY OF THE INVENTION The present invention provides a conventional developing method using a developer composed of a magnetic carrier and a toner such that the moving linear velocity Vp of the peripheral surface of the electrostatic image carrier exceeds 400 mm / s. By eliminating the disadvantages of using in the high-speed range, preventing halftones and development sweeps, which are disturbances of the toner layer in the solid area, and suppressing the adhesion of carriers to the electrostatic image carrier, It is intended to provide a developing method capable of preventing generation of scratches on the surface of a charge image carrier, obtaining a uniform image having a high density without causing breakage of fine lines and having a clear contour at high speed.
【0010】[0010]
【課題を解決するための手段】体積基準50%粒径D50
(μm)、体積基準25%粒径D25(μm)、75%粒径D75
(μm)がそれぞれ、 45≦D50≦75 0.7×D50<D25 1.5×D50>D75 の関係を満足する磁性キャリアからなる電子写真用現像
剤を用い、静電潜像が形成される静電荷像担持体と、そ
れに対向する位置にあり、現像領域へ現像剤を搬送する
現像剤担持体およびその内部に固定された複数の磁極か
ら構成されるマグネットロールからなる磁気ブラシ現像
器で構成され、そのマグネットロールの現像主磁極位置
が、マグネットロールと静電荷像担持体の中心軸を結ん
だ面に対し、現像剤搬送方向の上流側5〜20°の範囲に
設定され、かつ、現像主磁極よりもさらに上流側に磁気
ブラシ穂高さを規制する部材が位置し、その規制部材と
現像剤担持体間の距離Hcutが0.25〜0.75mmであり、さら
に、現像剤担持体と静電荷像担持体間の最接近距離であ
る現像ニップ距離Dsdが0.30〜0.80mm、かつ、 1.20<Dsd/Hcut<1.60 であり、かつ、その位置における両者の移動方向が同方
向、つまり互いに回転方向が逆方向であり、かつ、現像
領域における現像剤担持体の周面の移動線速Vs(mm/
s)、静電荷像担持体の周面の移動線速Vp(mm/s)が 1.0≦Vs/Vp≦3.0 (ただし、400≦Vp≦800、400≦Vs
≦2400) の関係を満足する静電荷像の高速現像装置を用いた現像
方法により、前述の課題を解決することができる。[Means for solving the problem] Volume-based 50% particle diameter D50
(Μm), volume-based 25% particle size D25 (μm), 75% particle size D75
An electrostatic charge image bearing on which an electrostatic latent image is formed by using an electrophotographic developer composed of a magnetic carrier whose (μm) each satisfies the relation of 45 ≦ D50 ≦ 75 0.7 × D50 <D25 1.5 × D50> D75 The magnetic brush developing device is composed of a body, a developer carrier at a position facing the body, which conveys the developer to the developing area, and a magnet roll composed of a plurality of magnetic poles fixed inside the body. The position of the developing main magnetic pole of the roll is set in the range of 5 to 20 ° on the upstream side in the developer transport direction with respect to the surface connecting the central axes of the magnet roll and the electrostatic charge image bearing member, and more than the developing main magnetic pole. Further, a member for regulating the height of the magnetic brush bristles is located on the upstream side, the distance Hcut between the regulating member and the developer carrier is 0.25 to 0.75 mm, and further, between the developer carrier and the electrostatic image carrier. Development nip distance Dsd, which is the closest distance Is 0.30 to 0.80 mm, 1.20 <Dsd / Hcut <1.60, and the moving directions of the two are the same at that position, that is, the rotating directions are opposite to each other, and the developer carrier in the developing area is Moving linear velocity Vs (mm /
s), the moving linear velocity Vp (mm / s) of the peripheral surface of the electrostatic image carrier is 1.0 ≦ Vs / Vp ≦ 3.0 (where 400 ≦ Vp ≦ 800, 400 ≦ Vs
The above-described problems can be solved by a developing method using a high-speed developing device for an electrostatic charge image that satisfies the relationship of ≦ 2400).
【0011】以下に、本発明の詳細な構成について示
す。The detailed structure of the present invention will be described below.
【0012】(現像システム)本発明に用いられる現像
器および静電荷像担持体の構成の一例を図1に示す。(Developing System) FIG. 1 shows an example of the construction of the developing device and the electrostatic charge image carrier used in the present invention.
【0013】現像装置1は現像器本体1Aとトナー補給
部1Bとからなっていて、現像器本体1Aに内蔵する現
像剤担持体2の周面を静電荷像担持体10の周面に対し所
定の間隔を持って対向させ、静電荷像担持体10周面上の
静電荷像のトナーによる現像が行われる現像領域を形成
する位置に取り付け設定されている。現像器本体1Aの
内部には、主撹拌部材9A、補助撹拌部材9Bが回転駆
動可能な状態に支持されている。The developing device 1 comprises a developing device main body 1A and a toner replenishing portion 1B, and a peripheral surface of a developer carrying member 2 incorporated in the developing device main body 1A is predetermined with respect to an electrostatic charge image carrying member 10. They are opposed to each other with an interval of, and are installed and set at a position where a developing area for developing the electrostatic charge image on the peripheral surface of the electrostatic charge image carrier 10 is developed. A main stirring member 9A and an auxiliary stirring member 9B are rotatably supported inside the developing device main body 1A.
【0014】静電荷像担持体10は光導電層を有した感光
体であり、図1において時計方向に回転し、現像領域に
対して上流側に設けた帯電極11により静電荷像担持体表
面は一定の電位に帯電されている。The electrostatic charge image carrier 10 is a photoconductor having a photoconductive layer and rotates clockwise in FIG. 1 and a surface of the electrostatic charge image carrier is provided by a belt electrode 11 provided on the upstream side of the developing area. Is charged to a constant potential.
【0015】帯電した静電荷像担持体10は、現像領域E
の上流にて露光され、潜像、すなわち静電荷像が形成さ
れる。その後、現像領域Eにて現像が行われる。The charged electrostatic image carrier 10 has a developing area E.
And is exposed upstream to form a latent image, that is, an electrostatic image. After that, development is performed in the development area E.
【0016】現像剤担持体2は、図1において反時計方
向に回転し、その周面と前記静電荷像担持体10の周面と
の間である現像領域Eにおける最近接距離を現像ニップ
距離Dsdと称する。The developer carrier 2 rotates counterclockwise in FIG. 1, and the closest distance in the developing area E between the peripheral surface of the developer carrier 2 and the peripheral surface of the electrostatic image carrier 10 is the development nip distance. It is called Dsd.
【0017】前記現像剤担持体2が内包するマグネット
ロール3は、アルミニウム等の非磁性の棒材の外周面
に、現像に関わる磁極としての主磁極N1と、現像剤を
搬送するための搬送磁極の役割をする複数の副磁極を備
えた柱状の磁石体である。The magnet roll 3 contained in the developer carrying member 2 has a main magnetic pole N1 as a magnetic pole for development and a transport magnetic pole for transporting the developer on the outer peripheral surface of a non-magnetic rod material such as aluminum. It is a columnar magnet body having a plurality of auxiliary magnetic poles that play a role of.
【0018】さらに、前記現像剤担持体2の周面に対向
して、前記マグネットロール3の磁力により搬送される
現像剤量を現像に必要な量に制限するための磁気ブラシ
穂高さ規制部材4が設置されている。この穂高さ規制部
材4と現像剤担持体2との間の距離をHcutと称する。Further, a magnetic brush spike height regulating member 4 for limiting the amount of the developer conveyed by the magnetic force of the magnet roll 3 to the amount necessary for the development, facing the peripheral surface of the developer carrying member 2. Is installed. The distance between the height control member 4 and the developer carrying member 2 is referred to as Hcut.
【0019】現像装置1内にはトナーとキャリアからな
る現像剤を装填してあり、現像剤は主撹拌部材9Aおよ
び補助撹拌部材9Bによって撹拌された後、マグネット
ロール3の外周にあり回転する現像剤担持体2の外周面
に付着して磁気ブラシを形成し、穂高さ規制部材4によ
って現像剤層の厚みを規制された後、現像領域Eに達す
る。現像剤担持体2と静電荷像担持体の間には所定のバ
イアス電圧が印加されて現像が行われる。The developing device 1 is loaded with a developer consisting of toner and carrier, and the developer is stirred by the main stirring member 9A and the auxiliary stirring member 9B, and is then rotated on the outer circumference of the magnet roll 3 for development. The magnetic brush is formed by adhering to the outer peripheral surface of the agent carrier 2 and reaches the developing area E after the thickness of the developer layer is regulated by the spike height regulating member 4. A predetermined bias voltage is applied between the developer carrier 2 and the electrostatic image carrier to develop the image.
【0020】現像剤担持体と静電荷像担持体の間に印加
するバイアス電圧としては、静電荷像の最大、最小電位
の間の電界を形成する静電荷像と同極性の直流電圧を印
加するのが好ましいが、必要に応じて、静電荷像の最
大、最小電位の間で交互電界を形成する交流電圧を印加
しても良い。As the bias voltage applied between the developer carrier and the electrostatic charge image carrier, a DC voltage having the same polarity as the electrostatic charge image forming an electric field between the maximum and minimum potentials of the electrostatic charge image is applied. However, an AC voltage that forms an alternating electric field between the maximum and minimum potentials of the electrostatic charge image may be applied if necessary.
【0021】(現像器)本発明に用いられる現像剤担持
体には公知のものが使用できる。材質としてはアルミニ
ウム、ステンレスなどが使用可能である。また、現像剤
を現像領域へ長期に渡り高速かつ安定して搬送するため
には現像剤担持体表面に溶射処理、サンドブラスト処理
などの表面の粗面化処理をすることが有効である。(Developer) A known developer carrier can be used in the present invention. Aluminum, stainless steel, etc. can be used as the material. Further, in order to convey the developer to the developing area at a high speed and stably for a long period of time, it is effective to perform a surface roughening treatment such as a thermal spraying treatment or a sandblasting treatment on the surface of the developer carrying member.
【0022】また、現像剤担持体の外径は40〜80mmφ、
好ましくは50〜70mmφのものを用いるのが良い。The outer diameter of the developer carrying member is 40 to 80 mmφ,
It is preferable to use one having a diameter of 50 to 70 mm.
【0023】また、現像剤担持体の内部のマグネットロ
ールに使用する現像主磁極N1には、磁石幅10〜30mm、
磁束密度800〜1400Gauss、好ましくは900〜1200Gaussの
ものを用いると良好な結果を得られる。また、副磁極に
は、磁束密度が400〜800Gaussのものを用いるのが好ま
しい。Further, the developing main magnetic pole N1 used for the magnet roll inside the developer carrying member has a magnet width of 10 to 30 mm,
Good results can be obtained by using a magnetic flux density of 800 to 1400 Gauss, preferably 900 to 1200 Gauss. Moreover, it is preferable to use a magnetic pole having a magnetic flux density of 400 to 800 Gauss as the auxiliary magnetic pole.
【0024】さらに、現像主磁極N1の位置は、現像剤
搬送方向の上流側0〜30°の範囲が適切であるが、好ま
しくは5〜20°の範囲に設定するとより良好な結果を得
られる。Further, the position of the developing main magnetic pole N1 is appropriately set in the range of 0 to 30 ° on the upstream side in the developer conveying direction, but preferably, it is set in the range of 5 to 20 ° to obtain better results. .
【0025】また、主磁極、副磁極の総数は少なくとも
4個、好ましくは5〜10個で構成されると、現像剤の高
速搬送性が非常に安定する。When the total number of main magnetic poles and auxiliary magnetic poles is at least 4, preferably 5 to 10, the high-speed transportability of the developer is very stable.
【0026】また、現像主磁極よりもさらに上流側に磁
気ブラシ穂高さを規制する部材を配置し、その規制部材
と現像剤担持体間の距離Hcutは、0.25〜0.75mmの範囲が
適切であるが、より好ましくは0.30〜0.65mmの範囲で設
定すると、より良好な結果を得られる。Further, a member for regulating the height of the magnetic brush bristles is arranged further upstream than the main developing magnetic pole, and the distance Hcut between the regulating member and the developer carrying member is appropriately in the range of 0.25 to 0.75 mm. However, better results can be obtained by setting the range of 0.30 to 0.65 mm.
【0027】また、現像剤担持体に対向する位置に静電
荷像担持体を配置させる必要があるが、その場合、現像
剤担持体と静電荷像担持体間の最接近距離である現像ニ
ップ距離Dsdは0.30〜0.80mmの範囲が適切であるが、よ
り好ましくは0.45〜0.75mmの範囲で設定すると良好な結
果を得られる。Further, it is necessary to dispose the electrostatic charge image carrier at a position facing the developer carrier. In that case, the developing nip distance which is the closest distance between the developer carrier and the electrostatic image carrier. A suitable range of Dsd is 0.30 to 0.80 mm, but more preferred results are obtained by setting it in a range of 0.45 to 0.75 mm.
【0028】さらに、磁気ブラシの擦過力を低減し、同
時に高速に高画質を得るためにはDsdとHcutの距離比の
設定が非常に重要である。具体的にはDsd/Hcutの距離
比が1.20〜1.60、好ましくは1.25〜1.50の範囲でより良
好な結果が得られる。Further, it is very important to set the distance ratio between Dsd and Hcut in order to reduce the rubbing force of the magnetic brush and simultaneously obtain a high quality image. Specifically, better results are obtained when the Dsd / Hcut distance ratio is in the range of 1.20 to 1.60, preferably 1.25 to 1.50.
【0029】また、静電荷像担持体と現像剤担持体の回
転方向は、現像領域における両者の周面の移動方向が同
方向、つまり互いに回転方向が逆方向であり、かつ、現
像領域における現像剤担持体の周面の移動線速Vs(mm/
s)、静電荷像担持体の周面の移動線速Vp(mm/s)
が、 1.0≦Vs/Vp≦3.0 (ただし、400≦Vp≦800) の範囲とすると良好な結果を得られる。しかし、更に著
しい効果を得るためには、 1.2≦Vs/Vp≦2.6 (ただし、400≦Vp≦800) とするのが好ましい。Regarding the rotation directions of the electrostatic image carrier and the developer carrier, the peripheral surfaces of the electrostatic charge image carrier and the developer carrier move in the same direction, that is, the rotation directions are opposite to each other, and the development in the development region proceeds. Moving linear velocity Vs (mm /
s), moving linear velocity Vp (mm / s) on the peripheral surface of the electrostatic image carrier
However, good results are obtained when the range is 1.0 ≦ Vs / Vp ≦ 3.0 (however, 400 ≦ Vp ≦ 800). However, in order to obtain a more remarkable effect, it is preferable to set 1.2 ≦ Vs / Vp ≦ 2.6 (however, 400 ≦ Vp ≦ 800).
【0030】(トナー)本発明に用いられるトナーは、
公知のものを使用することができる。具体的には、少な
くとも結着樹脂、着色剤からなるトナーであり、さらに
必要に応じて離型剤、荷電制御剤、流動化剤、磁性体が
添加されたトナーでもよい。構成される材料には公知の
ものが用いられる。(Toner) The toner used in the present invention is
Known ones can be used. Specifically, it is a toner including at least a binder resin and a colorant, and may be a toner to which a release agent, a charge control agent, a fluidizing agent, and a magnetic material are further added as necessary. Known materials are used for the constituent materials.
【0031】また、本発明に用いられるトナーの体積基
準50%粒径は5〜15μmの範囲にあるものが好ましい。
さらに好ましくは、その粒度分布として、微粉側につい
ては体積基準50%粒径の0.4倍以下の粒径をもつトナー
が全体の10vol%以下、さらに粗粉側については体積基
準50%粒径の2.5倍以上の粒径をもつトナーが全体の0.5
vol%以下であるものを用いると現像剤中のトナーの混
合の均一さ、ひいては出力画像の均質さを増すことがで
き、より良好な結果を得られる。The volume-based 50% particle diameter of the toner used in the present invention is preferably in the range of 5 to 15 μm.
More preferably, as the particle size distribution, toner having a particle size of 0.4 times or less of the volume-based 50% particle size is 10 vol% or less of the whole on the fine powder side, and 2.5% of the volume-based 50% particle size on the coarse powder side. Toner with a particle size more than double is 0.5
If the content is less than vol%, the uniformity of the mixing of the toner in the developer and, by extension, the uniformity of the output image can be increased, and better results can be obtained.
【0032】また、トナーの製造方法についても公知の
方法を用いることができる。A known method can be used as the method for producing the toner.
【0033】(磁性キャリア心材)本発明に用いること
のできる磁性キャリアまたはその心材としては、磁場に
よってその方向に強く磁化する物質を用いることができ
る。(Magnetic Carrier Core Material) As the magnetic carrier or core material thereof that can be used in the present invention, a substance that is strongly magnetized in its direction by a magnetic field can be used.
【0034】具体的には、鉄、フェライト、マグネタイ
トをはじめとするニッケル、コバルトなどの強磁性を示
す金属あるいはこれらの金属を含む合金または化合物な
どを用いることができる。なお、ここでいうフェライト
とは、鉄を含有する磁性化合物を総称しており、スピネ
ル型には限定されない。More specifically, iron, ferrite, magnetite and other nickel, cobalt, and other ferromagnetic metals, or alloys or compounds containing these metals can be used. The term “ferrite” as used herein is a general term for magnetic compounds containing iron and is not limited to spinel type.
【0035】これらのうち、フェライトは磁化を適正な
範囲に収めることが比較的容易であり好ましい。Of these, ferrite is preferable because it is relatively easy to keep the magnetization within an appropriate range.
【0036】磁化を適正な範囲に収めることは、本発明
である高速な現像にあたっては重要な要素である。なぜ
なら、磁化が極端に高い場合は、小粒径のトナーの損傷
が発生しやすく、現像剤の耐久性の低下を招く恐れがあ
る。これは、高速複写機において、より顕著に現れる。
また、磁化が低すぎる場合は、磁性キャリアの飛散が発
生し、出力画像に悪影響を及ばす。これもまた、高速複
写機において顕著に現れる問題である。Keeping the magnetization within a proper range is an important factor in the high-speed development of the present invention. This is because when the magnetization is extremely high, the toner having a small particle size is likely to be damaged, and the durability of the developer may be deteriorated. This is more noticeable in high speed copying machines.
On the other hand, if the magnetization is too low, scattering of magnetic carriers occurs, which adversely affects the output image. This is also a problem that appears prominently in high-speed copying machines.
【0037】したがって、本発明に用いられる磁性キャ
リアまたは磁性キャリアに用いる心材としては、1000 O
eの外部磁場中における飽和磁化が40〜120emu/g、保
磁力が0〜100 Oeであることが好ましいが、飽和磁化が5
0〜100emu/g、保磁力が0〜30 Oeのものを使用すると
さらに良好な結果を与える。Therefore, the magnetic carrier used in the present invention or the core material used for the magnetic carrier is 1000 O
It is preferable that the saturation magnetization of e in the external magnetic field is 40 to 120 emu / g and the coercive force is 0 to 100 Oe, but the saturation magnetization is 5
Even better results are obtained when a material having a coercive force of 0 to 100 emu / g and a coercive force of 0 to 30 Oe is used.
【0038】また、フェライトは鉄粉やニッケル粉にく
らべ比重が小さいことから、トナーとの混合、撹拌が容
易になり、現像剤中におけるトナー濃度の均一化、また
トナーとの帯電量の適正化をする上で好ましい。具体的
には、比重が4.0〜5.5であることが好ましい。Further, since ferrite has a smaller specific gravity than iron powder or nickel powder, it becomes easy to mix and agitate with the toner, and the toner concentration in the developer is made uniform, and the charge amount with the toner is optimized. It is preferable in that Specifically, the specific gravity is preferably 4.0 to 5.5.
【0039】更に、フェライトは体積固有抵抗の制御に
ついても比較的容易で好ましい。本発明においては500
V印加時の磁性キャリアの体積固有抵抗が1×108〜1
×1014Ω・cm、好ましくは5×1011〜5×1013Ω・cmの
ものが良好な結果を与える。Further, ferrite is preferable because it is relatively easy to control the volume resistivity. In the present invention 500
The volume resistivity of the magnetic carrier when V is applied is 1 × 10 8 to 1
Good results are obtained with x10 14 Ω · cm, preferably 5 × 10 11 to 5 × 10 13 Ω · cm.
【0040】また、本発明に用いることのできる磁性キ
ャリアの粒径は、体積基準50%粒径D50が45〜75μmの
ものである。The particle size of the magnetic carrier that can be used in the present invention is such that the volume-based 50% particle size D50 is 45 to 75 μm.
【0041】その理由は、磁性キャリアの体積基準50%
粒径が過小の場合、静電荷像担持体への磁性キャリア付
着が発生しやすく、静電荷像担持体に傷を発生させる場
合がある。また、体積基準50%粒径が過大の場合は、磁
性キャリアの比表面積が小さくなり、必要量のトナーを
適正に摩擦帯電させることが困難となり、地カブリなど
の画像不良を引き起こすためである。The reason is 50% by volume of the magnetic carrier.
When the particle size is too small, magnetic carriers are likely to adhere to the electrostatic charge image bearing member, which may cause scratches on the electrostatic charge image bearing member. Further, if the volume-based 50% particle size is excessively large, the specific surface area of the magnetic carrier becomes small, and it becomes difficult to properly triboelectrically charge a required amount of toner, which causes image defects such as background fog.
【0042】また、磁性キャリアの粒度分布として、体
積基準50%粒径D50(μm)、体積基準25%粒径D25
(μm)、体積基準75%粒径D75(μm)がそれぞれ、 45≦D50≦75 0.7×D50<D25 1.5×D50>D75 の関係を満足させると現像剤に必要な均質さが得られ、
高速な現像速度領域においても均質な濃度を持つ出力画
像を得られる。As the particle size distribution of the magnetic carrier, volume-based 50% particle size D50 (μm), volume-based 25% particle size D25.
(Μm) and volume-based 75% particle size D75 (μm) satisfy the relations of 45 ≦ D50 ≦ 75 0.7 × D50 <D25 1.5 × D50> D75 respectively, the homogeneity necessary for the developer is obtained,
An output image having a uniform density can be obtained even in a high developing speed region.
【0043】(磁性キャリア被覆層)本発明に用いる磁
性キャリアは、必要に応じて磁性粒子表面に樹脂被覆層
を設けたものを使用しても良い。その場合、磁性粒子被
覆用樹脂としては、公知の重合法により得られる樹脂を
使用することができる。(Magnetic Carrier Coating Layer) The magnetic carrier used in the present invention may have a resin coating layer provided on the surface of the magnetic particles, if necessary. In that case, as the resin for coating the magnetic particles, a resin obtained by a known polymerization method can be used.
【0044】本発明に用いることのできる被覆用樹脂と
しては、公知の樹脂を使用できるが、具体的には、スチ
レン系樹脂、アクリル系樹脂、ビニル系樹脂、エチレン
系樹脂、ポリアミド系樹脂、ポリエステル系樹脂など、
もしくはこれらのうちの2種以上の共重合体や混合体か
らなる樹脂を用いることができる。As the coating resin which can be used in the present invention, known resins can be used. Specifically, styrene resins, acrylic resins, vinyl resins, ethylene resins, polyamide resins, polyesters. Such as resin
Alternatively, a resin composed of a copolymer or a mixture of two or more of these can be used.
【0045】樹脂の製造方法としては具体的に、溶液重
合法、懸濁重合法、乳化重合法、塊状重合法、in-situ
重合法などを用いることができる。Specific examples of the resin production method include a solution polymerization method, a suspension polymerization method, an emulsion polymerization method, a bulk polymerization method, and an in-situ polymerization method.
A polymerization method or the like can be used.
【0046】また、得られた樹脂を磁性粒子表面へ被覆
する方法としては、公知の被覆方法を用いることができ
る。As a method for coating the surface of the magnetic particles with the obtained resin, a known coating method can be used.
【0047】磁性粒子表面への樹脂の被覆方法としては
具体的に、前述の方法で得られた樹脂の分散溶液を磁性
粒子表面へ噴霧する方法、分散溶液中へ磁性粒子を浸漬
させる方法などの湿式コーティング方法や、微粒化した
被覆用樹脂を磁性粒子表面に静電気的に付着させ、その
後、磁性粒子に熱と機械的応力のどちらか一方もしくは
両方を加えることにより、磁性粒子表面に樹脂層を被
覆、固定化させる乾式コーティング方法を用いることが
できる。Specific examples of the method for coating the surface of the magnetic particles with the resin include a method of spraying the dispersion solution of the resin obtained by the above-mentioned method on the surface of the magnetic particles, a method of immersing the magnetic particles in the dispersion solution, and the like. A resin layer is formed on the magnetic particle surface by a wet coating method or by electrostatically adhering the atomized coating resin to the magnetic particle surface, and then applying either or both heat and mechanical stress to the magnetic particle. A dry coating method of coating and immobilizing can be used.
【0048】また、樹脂被覆を行う場合、磁性粒子への
樹脂の被覆量は、樹脂の比重にもよるが磁性粒子の単位
重量当たり0.1〜10%が好ましい。When the resin coating is performed, the coating amount of the resin on the magnetic particles is preferably 0.1 to 10% per unit weight of the magnetic particles, although it depends on the specific gravity of the resin.
【0049】(現像剤)本発明に用いられる現像剤は、
磁性キャリアとトナーから構成されるが、必要に応じて
滑剤やクリーニング助剤、流動化剤などの第3成分を混
合しても良い。(Developer) The developer used in the present invention is
Although it is composed of a magnetic carrier and a toner, a third component such as a lubricant, a cleaning aid and a fluidizing agent may be mixed if necessary.
【0050】また、本発明に用いられる現像剤中のトナ
ー濃度設定は、トナーや磁性キャリアの比重によっても
多少異なるが、重量比で磁性キャリアに対して3〜10%
の範囲で、特に4〜8%の範囲で混合させるのが好まし
い。Further, the toner concentration setting in the developer used in the present invention is slightly different depending on the specific gravity of the toner or the magnetic carrier, but the weight ratio is 3 to 10% with respect to the magnetic carrier.
It is preferable to mix them in the range of 4 to 8%.
【0051】また、磁性キャリアとトナーの混合に際し
ては、従来より公知の混合機を用いることができるが、
その際に現像剤に加わるストレスが小さいもののほうが
好ましい。具体的にはヘンシェルミキサーなどの撹拌型
よりもV型混合機、Wコーン混合機、ロッキングミキサ
ーなどの自転型の混合機のほうが良好な結果を得られ
る。When mixing the magnetic carrier and the toner, a conventionally known mixer can be used.
It is preferable that the stress applied to the developer at that time is small. Specifically, a rotation type mixer such as a V-type mixer, a W-cone mixer, a rocking mixer can obtain better results than a stirring type mixer such as a Henschel mixer.
【0052】(静電荷像担持体)本発明に用いる静電荷
像担持体としては従来より公知の感光体を使用すること
ができる。具体的には、各種有機感光体、非晶質シリコ
ン感光体、セレン感光体などを使用することができる。(Electrostatic Charge Image Bearing Member) As the electrostatic charge image bearing member used in the present invention, a conventionally known photoreceptor can be used. Specifically, various organic photoconductors, amorphous silicon photoconductors, selenium photoconductors and the like can be used.
【0053】(粒径測定方法)本発明に用いられる磁性
キャリアやトナーの体積基準粒径は、レーザー回折式粒
度分布測定装置HELOS(日本電子(株)製)により求める
ことができる。(Particle size measuring method) The volume standard particle size of the magnetic carrier or toner used in the present invention can be determined by a laser diffraction particle size distribution measuring device HELOS (manufactured by JEOL Ltd.).
【0054】(磁気特性測定方法)本発明に用いられる
磁性キャリアの磁気特性は、直流磁化特性自動記録装置
3257-35型(横河電機(株)製)により求めることができ
る。(Magnetic characteristic measuring method) The magnetic characteristic of the magnetic carrier used in the present invention is a direct current magnetization characteristic automatic recording apparatus.
It can be determined by Model 3257-35 (made by Yokogawa Electric Corp.).
【0055】[0055]
【作用】磁性キャリアとトナーからなる現像剤を使用す
る従来の現像方法を高速な複写速度域で使用する場合の
欠点を解消し、ハーフトーンやベタ部のトナー層の乱れ
である現像掃き目を防止し、それに加え、静電荷像担持
体への磁性キャリアの付着を抑えることにより、静電荷
像担持体表面の擦過傷の発生を防止し、細線の切れがな
く、濃度が高く均一でかつ輪郭のはっきりした画像を高
速に得るためには、鋭意検討の結果、磁気ブラシの穂の
高さと形状、現像領域の形状や大きさ、現像剤担持体と
静電荷像担持体の周面の移動線速などを最適な範囲に収
め、かつ現像剤の粒度分布を均一なものとすることが有
効であることを見いだした。[Function] The disadvantages of using the conventional developing method using a developer composed of a magnetic carrier and toner in a high copying speed range are solved, and the development sweep, which is a disturbance of the halftone or solid toner layer, is eliminated. In addition to this, by preventing the magnetic carrier from adhering to the electrostatic charge image carrier, the occurrence of scratches on the surface of the electrostatic charge image carrier is prevented, the fine lines are not broken, the density is high and the contour is uniform. In order to obtain clear images at high speed, as a result of diligent studies, the height and shape of the brush of the magnetic brush, the shape and size of the development area, the moving linear velocity of the peripheral surface of the developer carrier and the electrostatic image carrier. It was found that it is effective to keep the above in an optimum range and to make the particle size distribution of the developer uniform.
【0056】[0056]
【実施例】表1に示す粒度分布を有する磁性キャリア
A,B,C,Dを用意した。EXAMPLES Magnetic carriers A, B, C and D having the particle size distribution shown in Table 1 were prepared.
【0057】なお、磁性キャリアA〜Dは球状Cu-Znフ
ェライト粒子からなる磁性粒子表面に、磁性粒子重量に
対しスチレン/メチルメタクリレート共重合樹脂を2%
被覆した樹脂被覆キャリアである。The magnetic carriers A to D were composed of spherical Cu-Zn ferrite particles, and 2% of styrene / methylmethacrylate copolymer resin was added to the weight of the magnetic particles.
It is a coated resin-coated carrier.
【0058】[0058]
【表1】 [Table 1]
【0059】なお、本実施例の磁性キャリアには、飽和
磁化が58[emu/g]、保磁力が検知限界以下である実
質的に0[Oe]、体積固有抵抗が2.1×1013[Ωcm]の
樹脂被覆キャリアを使用した。The magnetic carrier of this example had a saturation magnetization of 58 [emu / g], a coercive force of substantially 0 [Oe] below the detection limit, and a volume resistivity of 2.1 × 10 13 [Ωcm. ] The resin-coated carrier of was used.
【0060】トナーは以下の要領にて得られたものを使
用した。The toner used was obtained in the following manner.
【0061】ポリエステル樹脂100重量部に対し、離型
剤としてカルナバワックス2重量部、着色剤としてカー
ボンブラック10重量部を混合し、混練機にて溶融混練を
行う。その後冷却、粗砕工程を経て、微粉砕を行い、体
積基準50%粒径が8.0μmおよび、6.8μmの2種のトナー
を得た。さらにその後、流動化剤として、トナー100重
量部に対しシリカ微粒子を1重量部外添混合し、本実施
例に用いるトナーa,bとした。To 100 parts by weight of polyester resin, 2 parts by weight of carnauba wax as a release agent and 10 parts by weight of carbon black as a colorant are mixed and melt-kneaded by a kneader. After that, the mixture was cooled, coarsely crushed, and finely pulverized to obtain two kinds of toner having volume-based 50% particle diameters of 8.0 μm and 6.8 μm. Thereafter, as a fluidizing agent, 1 part by weight of silica fine particles was externally added and mixed with 100 parts by weight of the toner to obtain toners a and b used in this example.
【0062】なお、本トナーの粒度分布については、表
2に記載した。また、トナーaは磁性キャリアA,Cと
混合し、トナーbは磁性キャリアB,Dと混合し本実施
例の現像剤としたThe particle size distribution of this toner is shown in Table 2. Toner a was mixed with magnetic carriers A and C, and toner b was mixed with magnetic carriers B and D to obtain the developer of this embodiment.
【0063】[0063]
【表2】 [Table 2]
【0064】現像剤の調製にあたっては、上記により得
られたトナーと磁性キャリアを、磁性キャリアに対する
トナーの重量比が5%となるように設定し、V型混合機
に投入、混合して、本実施例に用いる現像剤とした。な
お、磁性キャリアA,B,C,Dを用いた現像剤をそれ
ぞれ現像剤A,B,C,Dとした。In the preparation of the developer, the toner and the magnetic carrier obtained as described above are set so that the weight ratio of the toner to the magnetic carrier is 5%, and the mixture is put into a V-type mixer and mixed to form a toner. A developer used in the examples. The developers using the magnetic carriers A, B, C and D are referred to as developers A, B, C and D, respectively.
【0065】また、複写機はコニカU-Bix5082(コニカ
(株)製)の改造機を使用した。本改造機は必要に応じ
て、静電荷像担持体、現像剤担持体の周面の移動線速、
両者間距離Dsd、現像器内のHcut距離、現像主磁極位置
を任意に変更できるものである。The copying machine is Konica U-Bix5082 (Konica
A modified machine (made by Co., Ltd.) was used. This remodeling machine, if necessary, the moving linear velocity of the electrostatic charge image carrier, the peripheral surface of the developer carrier,
The distance Dsd between them, the Hcut distance in the developing device, and the developing main magnetic pole position can be arbitrarily changed.
【0066】なお、それ以外の現像条件は以下の通りで
ある。The developing conditions other than the above are as follows.
【0067】静電荷像電位:850〜60V 現像バイアス電位:直流200V 現像剤担持体:外径60mmφ アルミニウム製(表面を溶
射処理) 静電荷像担持体:外径108mmφ セレン感光体 現像主磁極:磁束密度1050Gauss 磁極幅18mm 副磁極数:4個 (評価方法) ・画像濃度 原稿濃度1.30のベタ部を複写し、その出力画像の白紙に
対する相対反射濃度を測定した。なお、濃度測定にはマ
クベス濃度計を使用し、画像濃度1.25以上は良好である
と判断した。Electrostatic charge image potential: 850-60V Development bias potential: DC 200V Developer carrier: Outer diameter 60 mmφ Made of aluminum (spraying the surface) Electrostatic image carrier: Outer diameter 108 mmφ Selenium photoreceptor Main magnetic pole: Magnetic flux Density 1050 Gauss, magnetic pole width 18 mm, number of auxiliary magnetic poles: 4 (evaluation method) -Image density A solid portion with an original density of 1.30 was copied, and the relative reflection density of the output image with respect to a blank sheet was measured. A Macbeth densitometer was used for density measurement, and image density of 1.25 or higher was judged to be good.
【0068】・ベタ部掃き目 原稿濃度1.00のベタ部を複写し、その出力画像を目視観
察することにより判断した。紙送り方向に擦過状の画像
乱れが未発生の場合は良好であり「○」、発生が見られ
る場合は不良であり「×」とした。Solid Area Sweep: A solid area having a document density of 1.00 was copied and judged by visually observing the output image. When there was no scratch-like image disturbance in the paper feeding direction, the result was “good” and when there was occurrence, it was poor and was “poor”.
【0069】・細線切れ 紙送り方向に対し垂直な方向に引かれた線幅100μmの細
線を複写し、その出力画像を顕微鏡にて拡大し、目視観
察することにより判断した。細線切れが未発生で問題の
ないものは「○」、細線100mm当たりの細線切れが2箇
所以下の場合は「△」、それよりも多く細線切れが発生
しているものは不良であり「×」とした。Fine line break A fine line having a line width of 100 μm drawn in a direction perpendicular to the paper feeding direction was copied, and the output image was magnified with a microscope and visually judged. If there are no fine line breaks and there is no problem, it is "○", if there are two or less fine line breaks per 100 mm of fine line, it is "△", and if more fine line breaks occur, it is a defect. "
【0070】・キャリア付着 出力画像の目視観察により判断した。キャリア付着が未
発生で問題のないものは「○」、キャリア付着が確認さ
れ不良であるものは「×」とした。-Adhering carrier Determined by visual observation of the output image. The case where the carrier adhesion did not occur and there was no problem was evaluated as “◯”, and the case where the carrier adhesion was confirmed and was defective was evaluated as “x”.
【0071】・ドラム傷 連続10kCの複写を行い、その後、静電荷像担持体(感光
体ドラム)を取り出し、周面の移動方向の傷の発生の有
無を目視観察により判断した。傷の発生が見られないも
のは良好であり「○」、周面の移動方向に傷が見られる
場合は不良であり「×」とした。Drum Scratch Continuous copying was carried out at 10 kC, after which the electrostatic image carrier (photosensitive drum) was taken out, and the presence or absence of scratches in the moving direction of the peripheral surface was judged by visual observation. The case where no scratch was observed was good and was “Good”, and the case where scratch was seen in the moving direction of the peripheral surface was bad and was bad.
【0072】(評価条件)実施例および比較例の評価条
件を表3に示す。(Evaluation Conditions) Table 3 shows the evaluation conditions for the examples and comparative examples.
【0073】[0073]
【表3】 [Table 3]
【0074】(評価結果)上記評価条件における評価結
果を表4に示す。(Evaluation Results) Table 4 shows the evaluation results under the above evaluation conditions.
【0075】[0075]
【表4】 [Table 4]
【0076】[0076]
【発明の効果】本発明による現像方法を用いれば、磁性
キャリアとトナーからなる現像剤を使用する従来の現像
方法を高速で使用する場合の欠点を解消し、高品質な画
像を高速に得ることができる。By using the developing method of the present invention, it is possible to eliminate the drawbacks of using a conventional developing method using a developer composed of a magnetic carrier and a toner at a high speed, and obtain a high quality image at a high speed. You can
【0077】具体的には、ハーフトーンやベタ部のトナ
ー層の乱れである現像掃き目を防止でき、さらに、静電
荷像担持体へのキャリアの付着を抑えることにより、静
電荷像担持体表面の擦過傷の発生を防止でき、その結
果、細線の切れのない、濃度が高く均一でかつ輪郭のは
っきりした画像を高速に得ることができる。Specifically, it is possible to prevent the development sweep, which is the halftone and the disturbance of the toner layer in the solid portion, and to suppress the adhesion of the carrier to the electrostatic charge image bearing member, so that the surface of the electrostatic charge image bearing member is suppressed. It is possible to prevent scratches from occurring, and as a result, it is possible to quickly obtain an image with high density, uniform and clear contours, without breaks in fine lines.
【図1】この発明に係る現像装置の断面図。FIG. 1 is a sectional view of a developing device according to the present invention.
1 現像装置(静電荷像担持体) 2 現像剤担持体 3 マグネットロール 4 穂立規制部材 10 静電荷像担持体 21 直流定電流電源 22 交流定電流電源 E 現像領域 Hcut 磁穂形成すきま Hsd 現像部間隙 Vs 現像電位(バイアス電圧) 1 developing device (electrostatic charge image carrier) 2 developer carrier 3 magnet roll 4 magnetizing member 10 electrostatic charge image carrier 21 DC constant current power supply 22 AC constant current power supply E development area Hcut magnetic spike forming gap Hsd development unit Gap Vs Development potential (bias voltage)
Claims (1)
準25%粒径D25(μm)、75%粒径D75(μm)がそれぞ
れ、 45≦D50≦75 0.7×D50<D25 1.5×D50>D75 の関係を満足する磁性キャリアからなる電子写真用現像
剤を用い、静電潜像が形成される静電荷像担持体と、そ
れに対向する位置にあり、現像領域へ現像剤を搬送する
現像剤担持体およびその内部に固定された複数の磁極か
ら構成されるマグネットロールからなる磁気ブラシ現像
器で構成され、そのマグネットロールの現像主磁極位置
が、マグネットロールと静電荷像担持体の中心軸を結ん
だ面に対し、現像剤搬送方向の上流側5〜20°の範囲に
設定され、かつ、現像主磁極よりもさらに上流側に磁気
ブラシ穂高さを規制する部材が位置し、その規制部材と
現像剤担持体間の距離Hcutが0.25〜0.75mmであり、さら
に、現像剤担持体と静電荷像担持体間の最接近距離であ
る現像ニップ距離Dsdが0.30〜0.80mm、かつ、 1.20<Dsd/Hcut<1.60 であり、かつ、その位置における両者の移動方向が同方
向、つまり互いに回転方向が逆方向であり、かつ、現像
領域における現像剤担持体の周面の移動線速Vs(mm/
s)、静電荷像担持体の周面の移動線速Vp(mm/s)が 1.0≦Vs/Vp≦3.0 (ただし、400≦Vp≦800、400≦Vs
≦2400) の関係を満足する、静電荷像の高速現像装置を用いる高
速現像方法。1. A volume-based 50% particle size D50 (μm), a volume-based 25% particle size D25 (μm), and a 75% particle size D75 (μm) are 45 ≦ D50 ≦ 75 0.7 × D50 <D25 1.5 ×, respectively. An electrophotographic developer composed of a magnetic carrier satisfying the relationship of D50> D75 is used, and the electrostatic charge image carrier on which an electrostatic latent image is formed, and a position opposite to the electrostatic image carrier are conveyed to the developing area. It is composed of a magnetic brush developing device composed of a developer carrier and a magnet roll composed of a plurality of magnetic poles fixed inside the developer carrier, and the main developing magnetic pole position of the magnet roll is the center of the magnet roll and the electrostatic image carrier. A member for controlling the height of the magnetic brush is set in the range of 5 to 20 ° on the upstream side in the developer conveying direction with respect to the surface connecting the shafts, and a member for regulating the height of the magnetic brush is located further upstream than the main developing magnetic pole. When the distance Hcut between the member and the developer carrier is 0.25 to 0.75 mm Furthermore, the developing nip distance Dsd, which is the closest distance between the developer carrier and the electrostatic image carrier, is 0.30 to 0.80 mm, 1.20 <Dsd / Hcut <1.60, and both of them at that position. The moving directions are the same, that is, the rotating directions are opposite to each other, and the moving linear velocity Vs (mm /
s), the moving linear velocity Vp (mm / s) of the peripheral surface of the electrostatic image carrier is 1.0 ≦ Vs / Vp ≦ 3.0 (where 400 ≦ Vp ≦ 800, 400 ≦ Vs
A high-speed developing method using a high-speed developing device for electrostatic images, which satisfies the relationship of ≦ 2400).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28698293A JP3538784B2 (en) | 1993-11-16 | 1993-11-16 | High-speed electrostatic image development method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28698293A JP3538784B2 (en) | 1993-11-16 | 1993-11-16 | High-speed electrostatic image development method |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH07140730A true JPH07140730A (en) | 1995-06-02 |
JP3538784B2 JP3538784B2 (en) | 2004-06-14 |
Family
ID=17711490
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Application Number | Title | Priority Date | Filing Date |
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JP28698293A Expired - Fee Related JP3538784B2 (en) | 1993-11-16 | 1993-11-16 | High-speed electrostatic image development method |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997019641A1 (en) | 1995-11-29 | 1997-06-05 | Sekisui Kagaku Kogyo Kabushiki Kaisya | Apparatus and method for diagnosing osteoporosis |
EP1333335A2 (en) * | 2001-12-20 | 2003-08-06 | Ricoh Company, Ltd. | Developing method for an image forming apparatus and developing device using the same |
EP1338926A2 (en) * | 2002-02-25 | 2003-08-27 | Konica Corporation | Image forming apparatus provided with developing device using magnetic brush developing method |
US6665511B2 (en) | 2001-06-22 | 2003-12-16 | Ricoh Company, Ltd. | Developing device and image forming apparatus including the same |
US6668147B2 (en) | 2001-08-10 | 2003-12-23 | Ricoh Company, Ltd. | Developing device, image forming device and process unit |
US6882818B2 (en) * | 2001-03-21 | 2005-04-19 | Ricoh Company, Ltd. | Image forming apparatus having a development apparatus forming a magnetic brush separated from a latent image carrier outside a development area |
US7392000B2 (en) * | 2003-10-13 | 2008-06-24 | Samsung Electronics Co., Ltd. | Image forming apparatus to control a linear velocity ratio |
-
1993
- 1993-11-16 JP JP28698293A patent/JP3538784B2/en not_active Expired - Fee Related
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997019641A1 (en) | 1995-11-29 | 1997-06-05 | Sekisui Kagaku Kogyo Kabushiki Kaisya | Apparatus and method for diagnosing osteoporosis |
US6882818B2 (en) * | 2001-03-21 | 2005-04-19 | Ricoh Company, Ltd. | Image forming apparatus having a development apparatus forming a magnetic brush separated from a latent image carrier outside a development area |
US6665511B2 (en) | 2001-06-22 | 2003-12-16 | Ricoh Company, Ltd. | Developing device and image forming apparatus including the same |
US6668147B2 (en) | 2001-08-10 | 2003-12-23 | Ricoh Company, Ltd. | Developing device, image forming device and process unit |
EP1333335A2 (en) * | 2001-12-20 | 2003-08-06 | Ricoh Company, Ltd. | Developing method for an image forming apparatus and developing device using the same |
EP1333335A3 (en) * | 2001-12-20 | 2003-11-05 | Ricoh Company, Ltd. | Developing method for an image forming apparatus and developing device using the same |
EP1338926A2 (en) * | 2002-02-25 | 2003-08-27 | Konica Corporation | Image forming apparatus provided with developing device using magnetic brush developing method |
EP1338926A3 (en) * | 2002-02-25 | 2005-04-13 | Konica Corporation | Image forming apparatus provided with developing device using magnetic brush developing method |
US7392000B2 (en) * | 2003-10-13 | 2008-06-24 | Samsung Electronics Co., Ltd. | Image forming apparatus to control a linear velocity ratio |
Also Published As
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---|---|
JP3538784B2 (en) | 2004-06-14 |
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