JPH07109498A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPH07109498A JPH07109498A JP25810693A JP25810693A JPH07109498A JP H07109498 A JPH07109498 A JP H07109498A JP 25810693 A JP25810693 A JP 25810693A JP 25810693 A JP25810693 A JP 25810693A JP H07109498 A JPH07109498 A JP H07109498A
- Authority
- JP
- Japan
- Prior art keywords
- detergent composition
- group
- composition
- acyl
- skin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は洗浄剤組成物に関し、更
に詳しくは、皮膚及び毛髪に対し低刺激性であり、起泡
力が高く、泡質及び泡の持続性に優れ、使用感が良好
で、かつ保湿効果が高い洗浄剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a detergent composition, and more specifically, it is hypoallergenic to skin and hair, has a high foaming power, is excellent in foam quality and foam lasting, and has a feeling of use. The present invention relates to a detergent composition which is good and has a high moisturizing effect.
【0002】[0002]
【従来の技術及び発明が解決しようとする課題】従来、
身体用洗浄剤組成物は、一般にアニオン性界面活性剤を
主成分としており、これらのうち、皮膚洗浄剤として
は、石鹸、すなわち高級脂肪酸塩が、一方、頭髪洗浄剤
としては、アルキル硫酸塩やアルキルスルホン酸塩が主
として使用されている。2. Description of the Related Art Conventionally, the problems to be solved by the invention
Body-cleansing compositions generally contain anionic surfactants as main ingredients. Among them, skin cleansing agents are soaps, that is, higher fatty acid salts, while hair cleansing agents are alkylsulfates and Alkyl sulfonates are mainly used.
【0003】しかし、石鹸は、すすぎ時にきしみやつっ
ぱりを生じさせる、一方、アルキル硫酸塩やアルキルス
ルホン酸塩は、洗浄力には優れるものの、皮膚に対する
刺激性が大であるという欠点をそれぞれ有している。こ
のため、使用感に優れ、かつ皮膚に対し低刺激性の界面
活性剤であるN−アシル化アミノ酸型界面活性剤を洗浄
剤組成物の主基剤として使用することが試みられている
(例えば特開平5−156299号公報)が、このもの
は、単独では、起泡性、泡質及び泡の持続性において、
未だ十分満足のいく実用レベルをもたらすものではな
い。However, soaps cause squeaks and tautness during rinsing, while alkylsulfates and alkylsulfonates have the detergency, but have the drawback that they are very irritating to the skin. ing. Therefore, it has been attempted to use an N-acylated amino acid type surfactant, which is a surfactant having an excellent feeling of use and a mildness to the skin, as a main base of a detergent composition (for example, Japanese Patent Application Laid-Open No. 5-156299) discloses that, in itself, in terms of foamability, foam quality and foam sustainability,
It does not yet bring a satisfactory level of practical use.
【0004】そこで、皮膚に対し低刺激性で、使用感も
良好であって、かつ起泡力、泡質及び泡の持続性に優
れ、しかも保湿効果の高い洗浄剤組成物の開発が望まれ
ていた。Therefore, it is desired to develop a detergent composition which is mild to the skin, has a good feeling in use, is excellent in foaming power, foam quality and foam lasting and has a high moisturizing effect. Was there.
【0005】[0005]
【課題を解決するための手段】本発明者らは、かかる実
情に鑑み鋭意検討した結果、特定の二級アミド型N−ア
シルアミノ酸塩とカチオンポリマー及びトリグリセリド
とを組合せ配合することにより、皮膚に対し低刺激性
で、使用感も良好であって、かつ起泡力、泡質及び泡の
持続性に優れ、しかも保湿効果の高い洗浄剤組成物が得
られることを見出し、本発明を完成するに至った。Means for Solving the Problems As a result of intensive studies in view of such circumstances, the present inventors have found that by combining a specific secondary amide-type N-acyl amino acid salt with a cationic polymer and triglyceride, it is possible to apply to the skin. On the other hand, it was found that a detergent composition having a low irritation, a good feeling in use, an excellent foaming power, a foam quality and a foam lasting property and a high moisturizing effect can be obtained, and the present invention is completed. Came to.
【0006】すなわち、本発明は、下記成分(A)、
(B)及び(C); (A)次の一般式(1)That is, the present invention provides the following component (A),
(B) and (C); (A) The following general formula (1)
【0007】[0007]
【化3】R1CONH(CH2)mCOOM1 (1)[Chemical 3] R 1 CONH (CH 2 ) m COOM 1 (1)
【0008】(式中、R1CO−は炭素数10〜16の
アシル基を示し、mは1又は2の数を示し、M1 は、m
が1のときナトリウム原子、カリウム原子又はアルカノ
ールアンモニウム基を、mが2のときカリウム原子又は
アルカノールアンモニウム基をそれぞれ示す)で表わさ
れる二級アミド型N−アシルアミノ酸塩、(B)カチオ
ンポリマー、(C)次の一般式(2)(In the formula, R 1 CO- represents an acyl group having 10 to 16 carbon atoms, m represents a number of 1 or 2, and M 1 represents m.
Represents a sodium atom, potassium atom or alkanol ammonium group when 1 is 1, and represents a potassium atom or alkanol ammonium group when m is 2), a secondary amide type N-acyl amino acid salt, (B) a cationic polymer, C) The following general formula (2)
【0009】[0009]
【化4】 [Chemical 4]
【0010】(式中、R2 、R3 、R4 はそれぞれ、同
一又は異なって、炭素数6〜24のアシル基を示す)で
表わされるトリグリセリド、を含有することを特徴とす
る洗浄剤組成物を提供するものである。A detergent composition comprising a triglyceride represented by the formula: wherein R 2 , R 3 and R 4 are the same or different and each represents an acyl group having 6 to 24 carbon atoms. It is to provide things.
【0011】本発明に用いられる成分(A)の二級アミ
ド型N−アシルアミノ酸塩は、水道水中に含まれるカル
シウムと反応して潤滑性の高い板状結晶を生成する性質
を有するため、これを配合した洗浄剤組成物に洗浄後の
滑り等の良好な使用感を付与する作用を示すものであ
る。ここで、二級アミド型N−アシルアミノ酸塩とカル
シウムとの反応により生成する板状結晶の潤滑性は、例
えば乾燥豚皮(アロアスク、抗体化成工業(株)製)を
生理食塩水で再生したものの上における該板状結晶の静
摩擦係数を測定することにより求められ、該係数値が含
水時から乾燥時に至るまでブランクの場合より低いもの
を良好と評価する。The secondary amide type N-acyl amino acid salt of the component (A) used in the present invention has the property of reacting with calcium contained in tap water to form highly lubricious plate crystals. It shows the effect of imparting a good feeling of use such as slippage after washing to a detergent composition containing the above. Here, the lubricity of the plate-like crystals produced by the reaction of the secondary amide type N-acyl amino acid salt and calcium is, for example, regeneration of dried pig skin (Aroask, manufactured by Antibody Chemical Industry Co., Ltd.) with physiological saline. It is determined by measuring the coefficient of static friction of the plate-shaped crystals on the product, and those having a coefficient value lower than that of the blank from the time of containing water to the time of drying are evaluated as good.
【0012】前記一般式(1)中、R1CO−で示され
るアシル基の炭素数は10〜16であり、特に12〜1
4であることが好ましく、具体例としてはカプリノイル
基、ラウロイル基、ミリストイル基等が挙げられる。こ
れらは特に生成する板状結晶の潤滑性及び洗浄時の泡立
ちが良好である。In the above general formula (1), the acyl group represented by R 1 CO-- has 10 to 16 carbon atoms, particularly 12 to 1 carbon atoms.
It is preferably 4, and specific examples thereof include a caprinoyl group, a lauroyl group, and a myristoyl group. These are particularly good in the lubricity of the plate crystals produced and in foaming during washing.
【0013】また、上記二級アミド型N−アシルアミノ
酸塩は、N−アシル基が直鎖アシル基で構成される二級
アミド型構造であることが特に好ましい。すなわち、こ
のような構造をとる場合、板状結晶の生成が促進され、
生成した結晶が潤滑性に優れ、べたつきの少ないもので
あって、特に好ましい感触が得られる。アルカノールア
ンモニウムとしては、モノエタノールアンモニウム、ジ
エタノールアンモニウム及びトリエタノールアンモニウ
ムが挙げられる。また、一般式(1)中、mが2であ
り、かつM1 がナトリウムであるものは、クラフト点が
高く、水溶性に劣るため、液体洗浄剤に用いる場合には
好ましくない。The secondary amide-type N-acyl amino acid salt preferably has a secondary amide-type structure in which the N-acyl group is a straight-chain acyl group. That is, when such a structure is adopted, the production of plate crystals is promoted,
The produced crystals are excellent in lubricity and less sticky, and a particularly preferable feeling can be obtained. Alkanol ammonium includes monoethanol ammonium, diethanol ammonium and triethanol ammonium. Further, in the general formula (1), those in which m is 2 and M 1 is sodium have a high Kraft point and are inferior in water solubility, and therefore are not preferable when used in a liquid detergent.
【0014】成分(A)の本発明洗浄剤組成物への配合
量は、該組成物が固形の場合、10〜80重量%(以
下、単に「%」で示す)、特に60〜80%であること
が好ましく、液体又はペースト状の場合、2〜60%、
特に5〜40%が使用感が良好であることから特に好ま
しい。The amount of the component (A) to be added to the detergent composition of the present invention is 10 to 80% by weight (hereinafter simply referred to as "%"), particularly 60 to 80% when the composition is solid. 2 to 60% in the case of liquid or paste,
Particularly, 5 to 40% is particularly preferable because it gives a good feeling in use.
【0015】本発明に用いられる成分(B)のカチオン
ポリマーの好ましい例としては、次の(1)〜(10)
に示すものが挙げられる。 (1)四級化ビニルピロリドンとアミノエチルメタクリ
レートとの共重合物(例えばGAF社製ガフコート75
5)。 (2)アジピオン酸とジメチルアミノヒドロキシプロピ
レンジエチレントリアミンとの共重合物(例えばSAN
DOZ社製カルテレチンF4)。 (3)ポリ−(N,N−ジメチル−3,5−メチレンピ
ペリジニウムクロライド)(例えばMERCK社製マー
コート100)。 (4)N,N−ジメチル−3,5−メチレンピペリジニ
ウムクロライドとアクリルアミドとの共重合物(例えば
MERCK社製マーコート550)。 (5)アクリルアミドとβ−メタクリロキシエチルトリ
メチルアンモニウムとの共重合物(例えばハーキユレス
社製レチン220)。 (6)四級化グアーガム(例えばMEYHALL社製ジ
ャガーC−13)。 (7)ポリエチレンイミン(例えば日本触媒工業社製エ
ポミリP−100)。 (8)カチオン化セルロース(例えばUCC社製ポリマ
ーJR−400)。 (9)ポリアミンとポリグリコールとの縮合物(例えば
HENKEL社製ポリコートH)。 (10)アジピオン酸ジメチル−アミノヒドロキシプロ
ピルジエチルトリアミン共重合体。Preferred examples of the cationic polymer of the component (B) used in the present invention include the following (1) to (10)
The items shown in are listed. (1) Copolymerization product of quaternized vinylpyrrolidone and aminoethyl methacrylate (for example, GAF coat 75
5). (2) Copolymer of adipic acid and dimethylaminohydroxypropylenediethylenetriamine (eg SAN
Calteretin F4 manufactured by DOZ). (3) Poly- (N, N-dimethyl-3,5-methylenepiperidinium chloride) (for example, Mercoat 100 manufactured by MERCK). (4) A copolymer of N, N-dimethyl-3,5-methylenepiperidinium chloride and acrylamide (for example, Mercoat 550 manufactured by MERCK). (5) A copolymer of acrylamide and β-methacryloxyethyltrimethylammonium (for example, Retin 220 manufactured by Herquiures). (6) Quaternized guar gum (for example, Jaguar C-13 manufactured by MEYHALL). (7) Polyethyleneimine (for example, Epomilli P-100 manufactured by Nippon Shokubai Co., Ltd.). (8) Cationized cellulose (for example, polymer JR-400 manufactured by UCC). (9) Condensate of polyamine and polyglycol (for example, Polycoat H manufactured by HENKEL). (10) A dimethyl adipate-aminohydroxypropyl diethyltriamine copolymer.
【0016】これらのうち、ポリ−(N,N−ジメチル
−3,5−メチレンピペリジニウムクロライド)、N,
N−ジメチル−3,5−メチレンピペリジニウムクロラ
イドとアクリルアミドとの共重合物、カチオン化セルロ
ース等が特に好ましいものとして挙げられる。Of these, poly- (N, N-dimethyl-3,5-methylenepiperidinium chloride), N,
Particularly preferred are copolymers of N-dimethyl-3,5-methylenepiperidinium chloride and acrylamide, cationized cellulose and the like.
【0017】成分(B)の本発明洗浄剤組成物への配合
量は、0.01〜5.0%、特に0.05〜2.0%が
使用感及び泡立ちが良好であることから好ましい。The content of the component (B) in the detergent composition of the present invention is preferably 0.01 to 5.0%, more preferably 0.05 to 2.0% because the feeling of use and foaming are good. .
【0018】本発明に用いられる成分(C)のトリグリ
セリド(以下、トリアシルグリセリンということがあ
る)を表わす前記一般式(2)中、R2 、R3 及びR4
で表わされるアシル基は炭素数6〜24、好ましくは8
〜18であり、更に直鎖型、分岐鎖型又は不飽和炭素結
合を有するアシル基が好ましく、具体例としては、直鎖
型のオクタノイル基、カプリノイル基、ラウロイル基、
ミリストイル基等、分岐型の2−エチルヘキサノイル基
等及び不飽和炭素結合型のトリオレイル基等が挙げられ
る。R 2 , R 3 and R 4 in the above general formula (2) representing the triglyceride of the component (C) used in the present invention (hereinafter sometimes referred to as triacylglycerin).
The acyl group represented by has 6 to 24 carbon atoms, preferably 8
And a straight-chain, branched-chain or acyl group having an unsaturated carbon bond is preferable, and specific examples thereof include a straight-chain octanoyl group, a caprinoyl group and a lauroyl group.
Examples thereof include a myristoyl group and the like, a branched 2-ethylhexanoyl group and the like, and an unsaturated carbon bond-type trioleyl group.
【0019】成分(C)の本発明洗浄剤組成物への配合
量は、0.1〜20%、特に0.5〜10%が泡立ち及
び保湿効果が良好であることから好ましい。The content of the component (C) in the detergent composition of the present invention is preferably 0.1 to 20%, more preferably 0.5 to 10%, since the foaming and moisturizing effect is good.
【0020】本発明の洗浄剤組成物には、必要に応じ、
その他の活性剤、例えば高級脂肪酸塩、アルキル硫酸
塩、アルキルスルホン酸塩、ポリオキシエチレンアルキ
ル硫酸塩、アルキルベンゼンスルホン酸塩、N−アシル
サルコシン塩、N−アシル−N−メチルタウリン塩、ア
ルファオレフィンスルホン酸塩、アルキルエーテル酢酸
塩、ポリオキシエチレンアルキルエーテル酢酸塩等のア
ニオン性界面活性剤、ポリオキシエチレンアルキルエー
テル、糖エステル系、糖エーテル系、糖アミド系等のノ
ニオン性界面活性剤、イミダゾリン系、ベタイン系等の
両性界面活性剤を、本発明の効果を損なわない範囲にお
いて、任意に併用することもできる。The cleaning composition of the present invention, if necessary,
Other activators such as higher fatty acid salts, alkyl sulfates, alkyl sulfonates, polyoxyethylene alkyl sulfates, alkylbenzene sulfonates, N-acyl sarcosine salts, N-acyl-N-methyl taurine salts, alpha olefin sulfones. Acid salts, alkyl ether acetates, polyoxyethylene alkyl ether acetates and other anionic surfactants, polyoxyethylene alkyl ethers, sugar ester-based, sugar ether-based, sugar amide-based nonionic surfactants, imidazoline-based An amphoteric surfactant such as a betaine-based surfactant can be optionally used in combination as long as the effect of the present invention is not impaired.
【0021】更に、本発明洗浄剤組成物には、その他の
添加剤として、洗浄剤に通常用いられる成分を、本発明
の効果を損なわない範囲で、任意に併用することができ
る。例えば、プロピレングリコール、ソルビトール、グ
リセリン等の保湿剤、カルボキシビニルポリマー、メチ
ルセルロース、エタノール、ポリオキシエチレングリコ
ールジステアレート等の粘度調整剤、パール化剤、香
料、色素、紫外線吸収剤、酸化防止剤、殺菌剤、抗炎症
剤、防腐剤などを配合することができる。Further, the detergent composition of the present invention may optionally contain, as other additives, components usually used in the detergent, as long as the effects of the present invention are not impaired. For example, propylene glycol, sorbitol, humectants such as glycerin, carboxyvinyl polymer, methyl cellulose, ethanol, viscosity modifiers such as polyoxyethylene glycol distearate, pearling agents, fragrances, dyes, ultraviolet absorbers, antioxidants, A bactericidal agent, an anti-inflammatory agent, a preservative and the like can be added.
【0022】本発明の洗浄剤組成物は、前記成分を常法
に従い混合、加熱、攪拌等することにより、固形状、ゲ
ル状、ペースト状、液状等所望の剤型に製造することが
できる。本発明の洗浄剤組成物は皮膚、毛髪等の身体洗
浄用として適するものであり、特に皮膚洗浄用とするこ
とが好ましい。The detergent composition of the present invention can be produced in a desired dosage form such as solid, gel, paste and liquid by mixing, heating and stirring the above components in a conventional manner. The cleansing composition of the present invention is suitable for cleaning the body of skin, hair and the like, and particularly preferably for cleaning the skin.
【0023】[0023]
【発明の効果】本発明の洗浄剤組成物は、皮膚に対し低
刺激性で、使用感も良好であって、かつ起泡力、泡質及
び泡の持続性に優れ、しかも保湿効果の高いものであ
り、特に皮膚洗浄用として好適である。The detergent composition of the present invention has a low irritation to the skin, a good feeling in use, an excellent foaming power, a foam quality and a long-lasting foam, and a high moisturizing effect. In particular, it is suitable for cleaning the skin.
【0024】[0024]
【実施例】以下に本発明を実施例により具体的に説明す
るが、本発明はこれらに限定されるものではない。EXAMPLES The present invention will be described in detail below with reference to examples, but the present invention is not limited thereto.
【0025】実施例1 下記表1、表2及び表3に記載の配合組成よりなる洗浄
剤組成物を下記方法により調製した。 (製造法)加熱した精製水に各成分を混合することによ
り洗浄剤を得た。これらの洗浄剤組成物について、泡立
ち量を下記(泡立ち量の測定方法)により測定し、下記
評価基準により評価した。また、使用感を下記(使用感
の評価方法及び評価基準)に基づいて評価し、また保湿
効果を下記方法により評価した。その結果を下記表1、
表2及び表3に併せて示す。尚、No.12〜16の洗
浄剤組成物は、比較品である。Example 1 A cleaning composition having the composition shown in Table 1, Table 2 and Table 3 below was prepared by the following method. (Production method) A cleaning agent was obtained by mixing each component with heated purified water. With respect to these detergent compositions, the amount of foaming was measured by the following (method for measuring the amount of foaming), and evaluated according to the following evaluation criteria. The feeling of use was evaluated based on the following (evaluation method and evaluation criteria for feeling of use), and the moisturizing effect was evaluated by the following method. The results are shown in Table 1 below.
It is also shown in Table 2 and Table 3. Incidentally, No. Detergent compositions 12 to 16 are comparative products.
【0026】(泡立ち量の測定方法)各洗浄剤組成物を
用いて、25倍希釈水溶液をそれぞれ調製し、この溶液
100ml(液温40℃)を目盛り付きメスシリンダーに
注入した。次いで、攪拌羽根を上記溶液中に設置し、攪
拌開始から30秒後に於て生じた泡の体積(ml)を測定
し、泡立ち量とした。尚、攪拌羽根の回転数は1000
rpm であり、5秒毎に反転させた。 ・評価基準 ◎;泡立ち量250ml以上 ○;泡立ち量200ml以上250ml未満 △;泡立ち量150ml以上200ml未満 ×;泡立ち量150未満(Method of measuring the amount of foaming) A 25-fold diluted aqueous solution was prepared using each detergent composition, and 100 ml of this solution (liquid temperature 40 ° C.) was injected into a graduated graduated cylinder. Next, a stirring blade was placed in the above solution, and the volume (ml) of the foam generated 30 seconds after the start of stirring was measured and defined as the foaming amount. The rotation speed of the stirring blade is 1000
rpm and reversed every 5 seconds.・ Evaluation criteria ◎; foaming amount of 250 ml or more ○; foaming amount of 200 ml or more and less than 250 ml △; foaming amount of 150 ml or more and less than 200 ml ×; foaming amount of less than 150
【0027】(使用感の評価方法及び評価基準)各洗浄
剤組成物を用いて、男女各10名の被験者に身体の洗浄
をさせ、その際の官能評価を行った。評価は次の基準に
より平均値を算出し、該平均値が4.5以上を非常に良
好(◎)、3.5〜4.4を良好(○)、2.5〜3.
4をふつう(△)、2.4以下を不良(×)と判定し
た。 (1)すすぎ時の泡切れ 5;泡切れが良い 4;泡切れがやや良い 3;ふつう 2;泡切れがやや悪い 1;泡切れが悪い (2)すすぎ時の滑り、(3)すすぎ後の滑り及び
(4)乾燥後の滑り 5;滑りが良い 4;滑りがやや良い 3;ふつう 2;滑りがやや悪い 1;滑りが悪い(Evaluation Method and Evaluation Criteria for Feeling of Use) Using each detergent composition, 10 test subjects of each sex were made to wash their bodies, and a sensory evaluation was performed. For evaluation, an average value was calculated according to the following criteria, and when the average value was 4.5 or more, it was very good (⊚), 3.5 to 4.4 was good (∘), and 2.5 to 3.
4 was normal (Δ), and 2.4 or less was judged as defective (x). (1) Defoaming during rinsing 5; Good defoaming 4; Good defoaming 3; Normal 2; Bad defoaming 1; Bad defoaming (2) Sliding during rinsing, (3) After rinsing And (4) slippage after drying 5; good slippage 4; good slippage 3; normal 2; poor slippage 1; bad slippage
【0028】(保湿効果の測定)各被験者の前腕内側を
水洗し、水気をタオルで軽くふき取り、20℃、40%
RHの恒温恒湿室内で20分乾燥後、皮膚の電導度をコ
ンダクタンス測定装置(IBS(株)製:スキコン20
0)を用いて測定した。その後、各洗浄剤組成物にて同
部位を1分間洗浄処理した後、20分乾燥後のコンダク
タンスの比率を算出し、表1、表2及び表3に併せて平
均値を示した。保湿効果は、(洗浄後のコンダクタンス
値/(洗浄前のコンダクタンス値)により得られる。数
値が大きい程、保湿効果が高い。(Measurement of Moisturizing Effect) The inside of the forearm of each test subject was washed with water, and the water was wiped off with a towel lightly at 20 ° C. and 40%.
After drying for 20 minutes in a constant temperature and humidity room of RH, the conductance measuring device (manufactured by IBS Co., Ltd .: Skicon 20) for measuring the electric conductivity of the skin
0) was used. Then, the same site was washed with each detergent composition for 1 minute, and the conductance ratio after 20 minutes of drying was calculated, and the average values are shown in Table 1, Table 2 and Table 3 together. The moisturizing effect is obtained by (conductance value after cleaning / (conductance value before cleaning). The larger the value, the higher the moisturizing effect.
【0029】[0029]
【表1】 [Table 1]
【0030】[0030]
【表2】 [Table 2]
【0031】[0031]
【表3】 [Table 3]
【0032】*1:UCC社製 カチオン化セルロース *2:MERCK社製 N,N−ジメチル−3,5−メチ
レンピペリジウムクロライドとアクリルアミドとの共重
合体 *3:MERCK社製 ポリ−(N,N−ジメチル−3,
5−メチレンピペリジウムクロライド)* 1: UCC cationized cellulose * 2: MERCK N, N-dimethyl-3,5-methylenepiperidinium chloride copolymer with acrylamide * 3: MERCK poly- (N, N-dimethyl-3,
5-methylene piperidin chloride)
【0033】表1、表2及び表3に示す結果より明らか
なように、本発明品(1〜11)はいずれも、比較品
(12〜16)に比し、泡立ち、使用感及び保湿効果に
優れるものであることがわかる。しかも、本発明品は皮
膚に対する刺激性が極めて低いものであった。As is clear from the results shown in Table 1, Table 2 and Table 3, all the products of the present invention (1 to 11) had a foaming effect, a feeling of use and a moisturizing effect as compared with the comparative products (12 to 16). It turns out that it is excellent. Moreover, the product of the present invention had extremely low skin irritation.
【0034】実施例2 下記に組成を示す洗顔料又はボディシャンプーを下記方
法により製造した。Example 2 A face wash or body shampoo having the following composition was produced by the following method.
【0035】[0035]
【表4】 (組成) (%) (1)ラウロイル−β−アラニントリエタノールアミン 20 (2)ポリマーJR400 0.2 (3)2−エチルヘキサン酸トリグリセリン 1 (4)ラウリン酸トリエタノールアミン 4 (5)ミリスチン酸トリエタノールアミン 5 (6)ラウロイルアマイドプロピルジメチル カルボキシベタイン 3 (7)香料 0.5 (8)ジブチルヒドロキシトルエン 0.2 (9)エタノール 3 (10)精製水 バランスTable 4 (Composition) (%) (1) Lauroyl-β-alanine triethanolamine 20 (2) Polymer JR400 0.2 (3) Triglycerin 2-ethylhexanoate 1 (4) Triethanolamine laurate 4 (5) Triethanolamine myristic acid 5 (6) Lauroyl amide propyl dimethyl carboxybetaine 3 (7) Perfume 0.5 (8) Dibutylhydroxytoluene 0.2 (9) Ethanol 3 (10) Purified water balance
【0036】(製造法)加熱した(10)に(1)〜
(5)を溶解し、冷却後(6)〜(8)を添加し、液状
洗浄剤組成物を製造する。(Production method) (1) to (10) which has been heated
After dissolving (5) and cooling, (6) to (8) are added to produce a liquid detergent composition.
【0037】得られた洗浄剤組成物で身体を洗浄したと
ころ、該組成物は、泡立ち、泡持ち及び泡切れが良く、
かつすすぎ時から乾燥後まで滑りが良好で、使用感に優
れ、しかも保湿効果に優れており、また、皮膚に対し極
めて刺激性の低いものであった。When the body was washed with the obtained detergent composition, the composition had good foaming, foam retention and defoaming,
In addition, it had good slipperiness from the time of rinsing to after drying, was excellent in feeling of use, was excellent in moisturizing effect, and had extremely low irritation to the skin.
【0038】実施例3 下記に組成を示す洗顔料又はボディシャンプーを下記方
法により製造した。Example 3 A face wash or body shampoo having the following composition was produced by the following method.
【0039】[0039]
【表5】 (組成) (%) (1)ラウロイル−β−アラニントリエタノールアミン 10 (2)ポリマーJR400 0.2 (3)2−エチルヘキサン酸トリグリセリン 1 (4)2−ラウリル−N−カルボキシメチル−N− ヒドロキシエチルイミダゾリニウムベタイン 8 (5)ラウリン酸カリウム 4 (6)ラウロイルアマイドプロピルジメチル カルボキシベタイン 3 (7)香料 0.6 (8)ジブチルヒドロキシトルエン 0.3 (9)エタノール 4 (10)精製水 バランス[Table 5] (Composition) (%) (1) Lauroyl-β-alanine triethanolamine 10 (2) Polymer JR400 0.2 (3) Triglycerin 2-ethylhexanoate 1 (4) 2-lauryl-N- Carboxymethyl-N-hydroxyethyl imidazolinium betaine 8 (5) Potassium laurate 4 (6) Lauroyl amide propyl dimethyl carboxy betaine 3 (7) Perfume 0.6 (8) Dibutylhydroxytoluene 0.3 (9) Ethanol 4 (10) Purified water balance
【0040】(製造法)加熱した(10)に(1)〜
(5)を溶解し、冷却後(7)〜(10)を添加し、液
体洗浄剤組成物を製造する。(Production method) (1) to (10) heated
After dissolving (5) and cooling, (7) to (10) are added to produce a liquid detergent composition.
【0041】得られた洗浄剤組成物で身体を洗浄したと
ころ、該組成物は、泡立ち、泡持ち及び泡切れが良く、
かつすすぎ時から乾燥後まで滑りが良好で、使用感に優
れ、しかも保湿効果に優れており、また、皮膚に対し極
めて刺激性の低いものであった。When the body was washed with the obtained detergent composition, it was found that the composition had good foaming, foam retention and defoaming,
In addition, it had good slipperiness from the time of rinsing to after drying, was excellent in feeling of use, was excellent in moisturizing effect, and had extremely low irritation to the skin.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C11D 1:48 3:20) ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display location C11D 1:48 3:20)
Claims (1)
し、mは1又は2の数を示し、M1 は、mが1のときナ
トリウム原子、カリウム原子又はアルカノールアンモニ
ウム基を、mが2のときカリウム原子又はアルカノール
アンモニウム基をそれぞれ示す)で表わされる二級アミ
ド型N−アシルアミノ酸塩、(B)カチオンポリマー、
(C)次の一般式(2) 【化2】 (式中、R2 、R3 、R4 はそれぞれ、同一又は異なっ
て、炭素数6〜24のアシル基を示す)で表わされるト
リグリセリド、を含有することを特徴とする洗浄剤組成
物。1. The following components (A), (B) and (C); (A) the following general formula (1): R 1 CONH (CH 2 ) m COOM 1 (1) (wherein R 1 CO- represents an acyl group having 10 to 16 carbon atoms, m represents a number of 1 or 2, M 1 represents a sodium atom, a potassium atom or an alkanol ammonium group when m is 1, and m is 2 A potassium atom or an alkanol ammonium group respectively), a secondary amide type N-acyl amino acid salt, (B) a cationic polymer,
(C) The following general formula (2): (Wherein R 2 , R 3 and R 4 are the same or different and each independently represent an acyl group having 6 to 24 carbon atoms), and a triglyceride represented by the formula:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25810693A JP3250341B2 (en) | 1993-10-15 | 1993-10-15 | Detergent composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25810693A JP3250341B2 (en) | 1993-10-15 | 1993-10-15 | Detergent composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH07109498A true JPH07109498A (en) | 1995-04-25 |
JP3250341B2 JP3250341B2 (en) | 2002-01-28 |
Family
ID=17315588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP25810693A Expired - Lifetime JP3250341B2 (en) | 1993-10-15 | 1993-10-15 | Detergent composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3250341B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000071652A3 (en) * | 1999-05-26 | 2001-09-27 | Procter & Gamble | Detergent compositions comprising polymeric suds volume and suds duration enhancers |
US6903064B1 (en) | 1999-05-26 | 2005-06-07 | Procter & Gamble Company | Detergent composition comprising polymeric suds volume and suds duration enhancers |
US20120009127A1 (en) * | 2010-07-12 | 2012-01-12 | Conopco, Inc., D/B/A Unilever | Foam enhancement of fatty acyl glycinate surfactants |
WO2019008937A1 (en) | 2017-07-04 | 2019-01-10 | L'oreal | Foaming cleanser |
-
1993
- 1993-10-15 JP JP25810693A patent/JP3250341B2/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000071652A3 (en) * | 1999-05-26 | 2001-09-27 | Procter & Gamble | Detergent compositions comprising polymeric suds volume and suds duration enhancers |
US6903064B1 (en) | 1999-05-26 | 2005-06-07 | Procter & Gamble Company | Detergent composition comprising polymeric suds volume and suds duration enhancers |
US20120009127A1 (en) * | 2010-07-12 | 2012-01-12 | Conopco, Inc., D/B/A Unilever | Foam enhancement of fatty acyl glycinate surfactants |
US8501808B2 (en) * | 2010-07-12 | 2013-08-06 | Conopco, Inc. | Foam enhancement of fatty acyl glycinate surfactants |
WO2019008937A1 (en) | 2017-07-04 | 2019-01-10 | L'oreal | Foaming cleanser |
Also Published As
Publication number | Publication date |
---|---|
JP3250341B2 (en) | 2002-01-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP3018122B2 (en) | Detergent composition | |
JP2824158B2 (en) | Detergent composition | |
JP2587262B2 (en) | Detergent composition | |
JP3545372B2 (en) | Skin cleansing composition | |
JP3250341B2 (en) | Detergent composition | |
JP3644564B2 (en) | Cleaning composition | |
JP2511690B2 (en) | Detergent composition | |
JP2630529B2 (en) | Detergent composition | |
JPH08245982A (en) | Cleaning agent composition | |
JP3403542B2 (en) | Detergent composition | |
JPS59138298A (en) | Transparent gel detergent composition | |
JP3443945B2 (en) | Detergent composition | |
JP6157322B2 (en) | Cleaning composition | |
JP2963567B2 (en) | Detergent composition | |
JP2005179303A (en) | Detergent composition | |
JPH06264091A (en) | Detergent composition | |
JPS63183519A (en) | Liquid detergent composition | |
JP2630526B2 (en) | Detergent composition | |
JP3203532B2 (en) | Detergent composition | |
JPH05156287A (en) | Detergent composition | |
JPH08253793A (en) | Detergent composition | |
JP2002154947A (en) | Liquid body cleanser composition | |
JP3087400B2 (en) | Detergent composition | |
JP2630527B2 (en) | Detergent composition | |
JP2630528B2 (en) | Detergent composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20101116 Year of fee payment: 9 |
|
FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 9 Free format text: PAYMENT UNTIL: 20101116 |
|
FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 9 Free format text: PAYMENT UNTIL: 20101116 |
|
FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20111116 Year of fee payment: 10 |
|
FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20111116 Year of fee payment: 10 |
|
FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 11 Free format text: PAYMENT UNTIL: 20121116 |
|
FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 11 Free format text: PAYMENT UNTIL: 20121116 |
|
FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20131116 Year of fee payment: 12 |
|
EXPY | Cancellation because of completion of term |