JPH07102299A - Foaming toilet detergent composition - Google Patents
Foaming toilet detergent compositionInfo
- Publication number
- JPH07102299A JPH07102299A JP28546793A JP28546793A JPH07102299A JP H07102299 A JPH07102299 A JP H07102299A JP 28546793 A JP28546793 A JP 28546793A JP 28546793 A JP28546793 A JP 28546793A JP H07102299 A JPH07102299 A JP H07102299A
- Authority
- JP
- Japan
- Prior art keywords
- foam
- weight
- detergent composition
- foaming
- hydrochloric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明はトイレ用洗浄剤組成物に
関し、特に、泡吐出容器に用いた時、優れた発泡性を有
するとともに、細かい泡質を有し、垂直面においても保
持性に優れた泡を生成する起泡性トイレ用洗浄剤組成物
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a toilet cleaner composition, and in particular, when used in a foam discharge container, it has excellent foamability, fine foam quality, and retainability even on a vertical surface. TECHNICAL FIELD The present invention relates to a foaming toilet cleaner composition that produces excellent foam.
【０００２】[0002]
【従来の技術】トイレの汚れは、排泄物が付着し、経時
により変質した汚れや、水道水に微量に含まれるカルシ
ウムや鉄分、ケイ酸が蓄積した汚れである。これらの洗
浄には、塩酸を主体とした酸性の洗浄剤、次亜塩素酸ナ
トリウムを主体としたアルカリ性の洗浄剤、あるいは研
磨剤を配合した中性の洗浄剤等が提案されている。特に
尿や鉄分が付着して変質した黄ばみ汚れに対しては、塩
酸を主体にした酸性の洗浄剤が最も適している。また、
使用時にかけたり、あるいはこぼしたりしたところが分
かるように着色したり、塩酸臭をマスキングするために
香料を添加したり、さらに、垂直面での保持性を高めて
洗浄力を向上させるために粘性を付与することが行われ
る。2. Description of the Related Art Toilet stains are stains that have been excreted and deteriorated over time, and stains that contain trace amounts of calcium, iron and silicic acid contained in tap water. For such cleaning, an acidic cleaning agent mainly containing hydrochloric acid, an alkaline cleaning agent mainly containing sodium hypochlorite, or a neutral cleaning agent containing an abrasive has been proposed. In particular, for yellowish stains that have deteriorated due to urine or iron deposits, an acidic detergent mainly containing hydrochloric acid is most suitable. Also,
When using it, or coloring it so that you can see where it spilled, adding a fragrance to mask the hydrochloric acid odor, and further increasing the holding power on the vertical surface to improve the detergency Granting is done.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、従来の
強酸性洗浄剤では、塩酸臭のマスキングが不十分であっ
たり、垂直面での保持力を高めるために安定性のある粘
性を付与することは困難であった。本発明は、泡吐出容
器に用いたとき、塩酸臭のマスキングとともに垂直面で
の保持性の優れた泡を生成する起泡性トイレ用洗浄剤組
成物を提供することを目的とする。However, conventional strong acid detergents do not sufficiently mask the odor of hydrochloric acid or impart stable viscosity in order to increase the holding power on a vertical surface. It was difficult. An object of the present invention is to provide a foaming toilet cleaner composition which, when used in a foam discharge container, produces a foam having excellent retention on a vertical surface as well as masking a hydrochloric acid odor.
【０００４】[0004]
【課題を解決するための手段】酸性洗浄剤を泡吐出容器
に用いた時、発泡性に優れ、きめの細かい泡質でしかも
吐出後の保持性に優れた泡を生成させるべく検討した結
果、モノアルキル４級アンモニウム塩と非イオン界面活
性剤および塩化ジメチルアリルアンモニウムとアクリル
アミドの共重合ポリマーを添加することにより目的が達
成出来ることを見い出した。[Means for Solving the Problems] When an acidic cleaning agent is used in a foam discharge container, as a result of studies to generate foam having excellent foaming property, fine-grained foam quality, and excellent retention after discharge, It has been found that the object can be achieved by adding a monoalkyl quaternary ammonium salt, a nonionic surfactant and a copolymer of dimethylallyl ammonium chloride and acrylamide.
【０００５】すなわち、本発明は（ａ）鉱酸、（ｂ）モ
ノアルキル４級アンモニウム塩、（ｃ）非イオン界面活
性剤、（ｄ）塩化ジメチルアリルアンモニウムとアクリ
ルアミドの共重合ポリマーを含有することを特徴とする
起泡性トイレ用洗浄剤組成物を提供するものである。That is, the present invention contains (a) a mineral acid, (b) a monoalkyl quaternary ammonium salt, (c) a nonionic surfactant, and (d) a copolymer of dimethylallylammonium chloride and acrylamide. The present invention provides a foamable toilet cleaner composition comprising:
【０００６】[0006]
【作用】本発明に用いる鉱酸としては、塩酸が最も良い
が、必要により硫酸、リン酸、硝酸も使用できる。鉱酸
の配合量は、１重量％以下では洗浄性が不十分であり、
１０重量％を越えると劇物指定となるために安全性が問
題である。As the mineral acid used in the present invention, hydrochloric acid is the best, but sulfuric acid, phosphoric acid and nitric acid can be used if necessary. If the blending amount of the mineral acid is 1% by weight or less, the detergency is insufficient,
If it exceeds 10% by weight, it is designated as a deleterious substance and safety is a problem.
【０００７】本発明で用いられるモノアルキル４級アン
モニウム塩は、以下の一般式（Ｉ）〜（ＩＩＩ）で示さ
れるものである。The monoalkyl quaternary ammonium salt used in the present invention is represented by the following general formulas (I) to (III).
【化１】 （式中Ｒ１は炭素数８〜２２の直鎖あるいは分岐鎖のア
ルキル基またはアルケニル基であり、Ｘは塩素、臭素な
どのハロゲンを表わす。）[Chemical 1] (In the formula, R 1 is a linear or branched alkyl group or alkenyl group having 8 to 22 carbon atoms, and X represents halogen such as chlorine or bromine.)
【化２】 （式中Ｒ２は炭素数８〜２２の直鎖あるいは分岐鎖のア
ルキル基またはアルケニル基であり、Ｘは塩素、臭素な
どのハロゲンを表わす。）[Chemical 2] (In the formula, R 2 is a linear or branched alkyl group or alkenyl group having 8 to 22 carbon atoms, and X represents halogen such as chlorine or bromine.)
【化３】 （式中Ｒ３は炭素数８〜２２の直鎖あるいは分岐鎖のア
ルキル基またはアルケニル基であり、ｘおよびｙはエチ
レンオキサイド付加モル数でｘ＋ｙ＝２〜１５であり、
Ｘは塩素、臭素などのハロゲンを表す。） 配合量は０．０１〜２重量％が好ましい。０．０１重量
％以下では効果が不十分であり、２重量％を越えると浄
化槽トイレの場合には活性汚泥に悪影響を与えるおそれ
がある。[Chemical 3] (In the formula, R 3 is a linear or branched alkyl group or alkenyl group having 8 to 22 carbon atoms, x and y are ethylene oxide addition mole number, and x + y = 2 to 15,
X represents halogen such as chlorine and bromine. ) The blending amount is preferably 0.01 to 2% by weight. If it is less than 0.01% by weight, the effect is insufficient, and if it exceeds 2% by weight, it may adversely affect the activated sludge in the case of a septic tank toilet.
【０００８】非イオン界面活性剤としては、ポリオキシ
エチレンアルキルエーテル、ポリオキシエチレンアルキ
ルフェニルエーテル、ポリオキシエチレンポリオキシプ
ロピレンブロックポリマー、高級脂肪酸アルカノールア
ミドまたはそのエチレンオキサイド付加物などがある。
中でも一般式（ＩＶ）で表される非イオン界面活性剤が
良い。Examples of nonionic surfactants include polyoxyethylene alkyl ethers, polyoxyethylene alkylphenyl ethers, polyoxyethylene polyoxypropylene block polymers, higher fatty acid alkanolamides and ethylene oxide adducts thereof.
Among them, the nonionic surfactant represented by the general formula (IV) is preferable.
【化４】 （式中Ｒ４は炭素数８〜２２の直鎖あるいは分岐鎖のア
ルキル基またはアルケニル基であり、ｎはエチレンオキ
サイド付加モル数で３〜２０の整数を表わす。） 配合量は０．１〜１０重量％が好ましい。[Chemical 4] (In the formula, R 4 is a linear or branched alkyl group or alkenyl group having 8 to 22 carbon atoms, and n represents an integer of 3 to 20 in terms of the number of moles of ethylene oxide added.) 10% by weight is preferred.
【０００９】塩化ジメチルアリルアンモニウムとアクリ
ルアミドの共重合ポリマーは、一般式（Ｖ）で表わされ
るコポリマーである。The copolymer of dimethylallylammonium chloride and acrylamide is a copolymer represented by the general formula (V).
【化５】 （式中ｌ＝０のときｍ＝１、ｌ＝１のときｍ＝０であ
り、ｐ／ｑモル比が１／１〜１／３０、分子量が約５０
０，０００である。） 配合量は０．０１〜０．５重量％が好ましい。０．０１
重量％以下では効果が不十分であり、０．５重量％を越
えると溶液の粘性が高くなり、泡吐出容器に用いた時に
起泡性が見られなくなる。[Chemical 5] (In the formula, m = 1 when l = 0, m = 0 when l = 1, the p / q molar ratio is 1/1 to 1/30, and the molecular weight is about 50.
It is 10,000. ) The blending amount is preferably 0.01 to 0.5% by weight. 0.01
If it is less than 0.5% by weight, the effect is insufficient, and if it exceeds 0.5% by weight, the viscosity of the solution becomes high and the foaming property is not observed when it is used in a foam discharge container.
【００１０】このほか、水溶性溶剤、顔料や染料などの
着色剤、香料等を任意成分として配合することができ
る。水溶性溶剤としては、エタノール、プロパノール、
イソプロパノールなどの低級アルコール類、ジエチレン
グリコールブチルエーテル、プロピレングリコールブチ
ルエーテルなどのグリコールエーテル類等が挙げられ
る。着色剤としては、Ｃ．Ｉ．ピグメントブルー１５、
Ｃ．Ｉ．ピグメントグリーン３６、Ｃ．Ｉ．ピグメント
イエロー１などの顔料、Ｃ．Ｉ．アシッドグリーン２
８、Ｃ．Ｉ．アシッドイエロー３などの染料が使用でき
る。In addition, a water-soluble solvent, a colorant such as a pigment or a dye, and a fragrance may be added as optional components. Water-soluble solvents include ethanol, propanol,
Lower alcohols such as isopropanol, glycol ethers such as diethylene glycol butyl ether, propylene glycol butyl ether and the like can be mentioned. As the colorant, C.I. I. Pigment Blue 15,
C. I. Pigment Green 36, C.I. I. Pigment Yellow 1 and the like, C.I. I. Acid green 2
8, C.I. I. A dye such as Acid Yellow 3 can be used.
【００１１】[0011]
【発明の効果】本発明の組成物は、泡吐出容器に用いた
とき、優れた発泡性と、きめ細かい泡質を有するととも
に、泡の保持性に優れるために、塩酸臭のマスキング効
果とともに垂直面での洗浄性の向上が期待できる。INDUSTRIAL APPLICABILITY The composition of the present invention, when used in a foam discharge container, has excellent foamability and fine foam quality, and since it has excellent foam retention, it has a masking effect on hydrochloric acid odor and a vertical surface. It can be expected to improve the cleaning performance.
【００１２】[0012]
【実施例】以下に本発明の実施例を示すが、本発明はこ
れらの実施例に限定されるものではない。EXAMPLES Examples of the present invention will be shown below, but the present invention is not limited to these examples.
【００１３】表１に示す組成物を調製し、泡吐出容器を
用いて各組成物の特性を調べるために以下の試験方法に
よって試験した。なお、表中の組成は重量％で表した。The compositions shown in Table 1 were prepared and tested by the following test methods to investigate the properties of each composition using a foam discharge container. In addition, the composition in the table is expressed by weight%.
【００１４】[0014]
【表１】 [Table 1]
【００１５】試験方法 １）起泡性の評価 １１０メッシュの孔径を有するスクリーンをつけた泡吐
出容器の組成物を入れ、５００ｍｌのメスシリンダーに
容器を１０回押して泡を吐出させたときの泡の容量を測
定した。起泡性の評価は以下の基準により行った。 ◎：泡の容量が２００ｍｌ以上である。 ○：泡の容量が１００ｍｌ以上２００ｍｌ未満である。 △：泡の容量が５０ｍｌ以上１００ｍｌ未満である。 ×：泡の容量が５０ｍｌ未満である。Test Method 1) Evaluation of Foamability A composition of a foam discharge container provided with a screen having a pore size of 110 mesh was put, and the foam was discharged when the container was pushed 10 times into a 500 ml measuring cylinder. The capacity was measured. The foamability was evaluated according to the following criteria. A: The volume of foam is 200 ml or more. ◯: The volume of foam is 100 ml or more and less than 200 ml. Δ: The volume of foam is 50 ml or more and less than 100 ml. X: The volume of foam is less than 50 ml.
【００１６】２）泡質の評価 泡吐出容器により吐出した泡の状態を１０人のパネラー
が肉眼で観察し、以下の基準により評価した。 ○：８人以上のパネラーがきめが細かい泡であると評価
した。 △：６〜７人のパネラーがきめが細かい泡であると評価
した。 ×：５人以下のパネラーがきめか細かい泡であると評価
した。2) Evaluation of foam quality The state of foam discharged from the foam discharge container was visually observed by 10 panelists and evaluated according to the following criteria. ◯: Eight or more panelists evaluated that the foam had fine texture. Δ: 6 to 7 panelists evaluated that the foam had fine texture. Poor: Five or less panelists evaluated that the foam was fine or fine.
【００１７】３）保持性の評価 泡吐出容器により容器を１０回押して吐出した時、吐出
直後の泡の容量と５分後の泡の容量を測定し、次式によ
り泡の保持率を算出した。 ◎：保持率が８０％以上であり、泡の保持性に優れてい
る。 ○：保持率が６０〜８０％であり、泡の保持性が良好で
ある。 △：保持率が４０〜６０％であり、泡の保持性は普通で
ある。 ×：保持率が４０％未満であり、泡の保持性が劣ってい
る。3) Evaluation of Retainability When the container was pushed 10 times by the foam discharge container and discharged, the volume of foam immediately after discharge and the volume of foam after 5 minutes were measured, and the foam retention rate was calculated by the following formula. . ⊚: The retention rate is 80% or more, and the foam retention is excellent. Good: The retention rate is 60 to 80%, and the foam retention is good. (Triangle | delta): Retention rate is 40-60%, and the foam retention property is normal. X: The retention rate is less than 40%, and the foam retention property is poor.
【００１８】４）洗浄性の評価 鉄錆汚れを付着させた白色半磁器タイルを垂直に立て、
泡吐出容器を用いて組成物を泡状にして汚れの表面に付
着させ、５分間放置した後セルローススポンジで軽く５
０回こすり洗いし、流水で１分間すすいだ後風乾してタ
イル表面の反射率を測定し、次式により汚れ除去率を算
出した。 Ｒｗ：洗浄後のタイルの反射率（％） Ｒｓ：洗浄前のタイルの反射率（％） Ｒｏ：汚染後のタイルの反射率（％） 洗浄性は汚れの除去率から以下の基準により評価した。 ◎：除去率が８０％以上であり、洗浄性が優れている。 ○：除去率が６０〜８０％であり、洗浄性が良好であ
る。 △：除去率が４０〜６０％であり、洗浄性は普通であ
る。 ×：除去率が４０％未満であり、洗浄性か劣っている。4) Evaluation of Detergency A white semi-porcelain tile with iron rust stains was erected vertically,
Use a foam discharge container to make the composition foam and attach it to the surface of the stain, leave it for 5 minutes, and then gently lighten it with a cellulose sponge.
After scrubbing for 0 times, rinsing with running water for 1 minute, and air-drying, the reflectance of the tile surface was measured, and the stain removal rate was calculated by the following formula. R w : Tile reflectance after washing (%) R s : Tile reflectance before washing (%) R o : Tile reflectance after contamination (%) It was evaluated by. A: The removal rate is 80% or more, and the cleanability is excellent. Good: The removal rate is 60 to 80%, and the cleanability is good. (Triangle | delta): The removal rate is 40-60%, and the washability is normal. X: The removal rate is less than 40%, and the cleanability is poor.
【００１９】５）塩酸臭のマスキング効果の評価 泡吐出容器を用いて組成物を１０００ｍｌのビーカーに
１０回吐出したときのにおいについて１０人のパネラー
により官能試験を行い、以下の基準により評価した。 ○：８人以上のパネラーが塩酸臭がしないと判定した。 △：６〜７人のパネラーが塩酸臭がしないと判定した。 ×：５人以下のパネラーが塩酸臭がしないと判定した。5) Evaluation of masking effect of hydrochloric acid odor A sensory test was conducted by 10 panelists on the odor when the composition was discharged 10 times into a 1000 ml beaker using a foam discharge container, and evaluated according to the following criteria. A: Eight or more panelists judged that there was no smell of hydrochloric acid. Δ: 6 to 7 panelists judged that there was no smell of hydrochloric acid. X: 5 or less panelists judged that there was no hydrochloric acid odor.
Claims (4)
ドの共重合ポリマー を含有することを特徴とする起泡性トイレ用洗浄剤組成
物。1. A foaming product containing (a) a mineral acid, (b) a monoalkyl quaternary ammonium salt, (c) a nonionic surfactant, and (d) a copolymer of dimethylallylammonium chloride and acrylamide. Cleaning composition for sex toilet.
０１〜２重量％、（ｃ）を０．１〜１０重量％、（ｄ）
を０．０１〜０．５重量％の割合で含有する請求項１記
載の起泡性トイレ用洗浄剤組成物。2. The amount of (a) is 1 to 10% by weight, and the amount of (b) is 0.
01 to 2% by weight, (c) 0.1 to 10% by weight, (d)
The foamable toilet cleaner composition according to claim 1, which comprises 0.01 to 0.5% by weight.
請求項２記載の起泡性トイレ用洗浄剤組成物。3. The foamable toilet cleaner composition according to claim 1, wherein the mineral acid (a) is hydrochloric acid.
が塩化ラウリルトリメチルアンモニウムである請求項１
ないし請求項２記載の起泡性トイレ用洗浄剤組成物。4. The (b) monoalkyl quaternary ammonium salt is lauryl trimethyl ammonium chloride.
The foamable toilet cleaner composition according to claim 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28546793A JPH07102299A (en) | 1993-10-07 | 1993-10-07 | Foaming toilet detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28546793A JPH07102299A (en) | 1993-10-07 | 1993-10-07 | Foaming toilet detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07102299A true JPH07102299A (en) | 1995-04-18 |
Family
ID=17691899
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP28546793A Pending JPH07102299A (en) | 1993-10-07 | 1993-10-07 | Foaming toilet detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07102299A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1125896A1 (en) * | 2000-02-18 | 2001-08-22 | Laboratorio Chimico Farmaceutico Sammarinese S.A. | Method for reducing the emission of unpleasant odors from a water closet and foaming composition for carrying out the same |
| JP2003238996A (en) * | 2002-02-22 | 2003-08-27 | Kao Corp | Concentrated liquid cleaning agent for flush toilet |
| JP2003238997A (en) * | 2002-02-22 | 2003-08-27 | Kao Corp | Concentrated liquid cleaning agent for flush toilet |
| JP2008303318A (en) * | 2007-06-08 | 2008-12-18 | Lion Corp | Liquid detergent product |
| US7501387B2 (en) | 2002-02-22 | 2009-03-10 | Kao Corporation | Antifouling detergent for hard surfaces |
| US7544649B2 (en) | 2002-02-22 | 2009-06-09 | Kao Corporation | Antifouling detergent for hard surfaces |
| WO2012137605A1 (en) * | 2011-04-01 | 2012-10-11 | 花王株式会社 | Detergent composition for hard surface |
-
1993
- 1993-10-07 JP JP28546793A patent/JPH07102299A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1125896A1 (en) * | 2000-02-18 | 2001-08-22 | Laboratorio Chimico Farmaceutico Sammarinese S.A. | Method for reducing the emission of unpleasant odors from a water closet and foaming composition for carrying out the same |
| JP2003238996A (en) * | 2002-02-22 | 2003-08-27 | Kao Corp | Concentrated liquid cleaning agent for flush toilet |
| JP2003238997A (en) * | 2002-02-22 | 2003-08-27 | Kao Corp | Concentrated liquid cleaning agent for flush toilet |
| US7501387B2 (en) | 2002-02-22 | 2009-03-10 | Kao Corporation | Antifouling detergent for hard surfaces |
| US7544649B2 (en) | 2002-02-22 | 2009-06-09 | Kao Corporation | Antifouling detergent for hard surfaces |
| JP2008303318A (en) * | 2007-06-08 | 2008-12-18 | Lion Corp | Liquid detergent product |
| WO2012137605A1 (en) * | 2011-04-01 | 2012-10-11 | 花王株式会社 | Detergent composition for hard surface |
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