JPH0699670B2 - Peel-like PVC adhesive sheet with good outdoor weatherability - Google Patents
Peel-like PVC adhesive sheet with good outdoor weatherabilityInfo
- Publication number
- JPH0699670B2 JPH0699670B2 JP61218032A JP21803286A JPH0699670B2 JP H0699670 B2 JPH0699670 B2 JP H0699670B2 JP 61218032 A JP61218032 A JP 61218032A JP 21803286 A JP21803286 A JP 21803286A JP H0699670 B2 JPH0699670 B2 JP H0699670B2
- Authority
- JP
- Japan
- Prior art keywords
- pvc
- pearl
- sensitive adhesive
- pressure
- resin film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Description
【発明の詳細な説明】 〔産業上の利用分野 本発明は、パール顔料を含有するアクリル系粘着剤層
と、透明なPVC系樹脂フィルム層とを積層固定してなる
装飾用、屋外使用用PVC系粘着シートに関するもので、
本発明の屋外耐候性の良いパール調PVC系粘着シート
は、車輌等の各種被着体に貼り付けることにより、パー
ル顔料の持つ独持の色調を生かした装飾を施すことがで
きる。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a PVC for decorative or outdoor use, which is obtained by laminating and fixing an acrylic adhesive layer containing a pearl pigment and a transparent PVC resin film layer. System adhesive sheet,
The pearl-like PVC pressure-sensitive adhesive sheet having good outdoor weatherability of the present invention can be attached to various adherends such as a vehicle to give a decoration by utilizing the unique color tone of the pearl pigment.
パール調PVC粘着シートとしては、従来より種々のもの
が知られており、例えばメルク社のカタログには、パー
ル顔料を添加したPVC粘着シートが提案されている。Various types of pearl-like PVC pressure-sensitive adhesive sheets have been conventionally known, and for example, a PVC pressure-sensitive adhesive sheet to which a pearl pigment is added is proposed in the catalog of Merck.
また、パール顔料を表面処理し、耐候性をアップさせる
方法としては、例えば、特開昭59−78265号公報に記載
のものが知られている。Further, as a method of surface-treating a pearl pigment to improve weather resistance, for example, a method described in JP-A-59-78265 is known.
更に、自動車の塗装で代表されるように、アルキッドメ
ラミン等のPVC以外の樹脂にパール顔料を添加する塗装
方法も知られている。Furthermore, a coating method in which a pearl pigment is added to a resin other than PVC such as alkyd melamine is also known, as represented by automobile coating.
しかしながら、メルク社のカタログにおける如くPVCシ
ートに直接パール顔料を添加する系においては、通常の
パール顔料を添加したのでは、耐候性テストにおいて、
褐色の斑点状欠陥等が現れ、耐候性用途に使用するに
は、充分満足なものが得られない。However, in the system in which the pearl pigment is directly added to the PVC sheet as in the catalog of Merck Co., Ltd., if the usual pearl pigment is added, in the weather resistance test,
Brown spot-like defects appear, and the product is not sufficiently satisfactory for use in weather resistance applications.
また、特開昭59−78265号公報における如くパール顔料
を表面処理し、耐候性をアップさせる方法によっても、
充分耐候性の良いものが得られ難く、又得られたとして
も、パール顔料自体が非常に高価なものになってしまう
等の問題がある。Further, by a method of surface-treating a pearl pigment as described in JP-A-59-78265 to improve weather resistance,
There is a problem that it is difficult to obtain a pigment having sufficiently good weather resistance, and even if it is obtained, the pearl pigment itself becomes very expensive.
また、アルキッドメラミン等のPVC以外の樹脂にパール
顔料を添加する塗装方法によれば、PVC以外のPVC系樹脂
フィルム中にパール顔料を添加することが考えられる
が、そのようにしても、柔軟性、印刷性、耐候性、耐溶
剤性等の一般に屋外用装飾用粘着シートに必須とされる
特性をPVC系樹脂フィルムのように全て満足させるよう
なフィルムは得られない。Further, according to the coating method of adding a pearl pigment to a resin other than PVC such as alkyd melamine, it is conceivable to add a pearl pigment to a PVC resin film other than PVC. It is not possible to obtain a film such as a PVC resin film that satisfies all the properties generally required for an outdoor decorative pressure-sensitive adhesive sheet, such as printability, weather resistance, and solvent resistance.
従って、本発明の目的は、これらの従来技術が有してい
た上述の欠点を解決し、耐候性が非常に良好で、且つ柔
軟性、即ち優れた貼り適性を有し、更には、耐溶剤性、
印刷性に優れた比較的安価なパール調粘着シートを提供
することにある。Therefore, the object of the present invention is to solve the above-mentioned drawbacks that these conventional techniques have, very good weather resistance, and flexibility, that is, excellent sticking suitability, and further solvent resistance. sex,
It is to provide a relatively inexpensive pearl-like pressure-sensitive adhesive sheet having excellent printability.
本発明は、パール顔料を1.5〜30wt％含有するアクリル
系粘着剤層と、透明なPVC系樹脂フィルム層とを積層固
定してなることを特徴とする屋外耐候性の良いパール調
PVC系粘着シートを提供することによって、上記の目的
を達成したものである。The present invention is characterized by comprising an acrylic pressure-sensitive adhesive layer containing a pearl pigment in an amount of 1.5 to 30 wt% and a transparent PVC resin film layer laminated and fixed, and having a good outdoor weather resistance.
The above object is achieved by providing a PVC-based pressure-sensitive adhesive sheet.
以下、本発明の屋外耐候性の良いパール調PVC系粘着シ
ートについて詳述する。Hereinafter, the pearly PVC-based PSA sheet having good outdoor weatherability of the present invention will be described in detail.
本発明の屋外耐候性の良いパール調PVC系粘着シート
は、透明なPVC系樹脂フィルム層に粘着剤層を積層固定
したもので、該粘剤層には、パール顔料が含有されてい
る。The pearl-like PVC pressure-sensitive adhesive sheet having good outdoor weatherability of the present invention is obtained by laminating and fixing a pressure-sensitive adhesive layer on a transparent PVC resin film layer, and the pressure-sensitive adhesive layer contains a pearl pigment.
上記パール顔料としては、好ましくは、雲母タイプで、
平均粒径５〜80μのものが用いられる。又、パール顔料
は、パール顔料独持の真珠光沢、特異な色調を出すため
に、1.5〜30wt％、好ましくは2.5〜20wt％の範囲で粘着
剤層に含有される。1.5wt％未満の含有量では、パール
顔料独持の真珠光沢、特異な色調を出すためには不充分
であり、30wt％超の含有量では、却ってパール顔料独持
の真珠光沢、特異な色調が失われる傾向にあり、且つ粘
着材のもつ接着にも悪影響がでる傾向にある上、価格的
に好ましくない。The pearl pigment is preferably a mica type,
An average particle size of 5 to 80 μm is used. The pearl pigment is contained in the pressure-sensitive adhesive layer in an amount of 1.5 to 30% by weight, preferably 2.5 to 20% by weight in order to provide a pearl luster unique to the pearl pigment and a unique color tone. If the content is less than 1.5 wt%, it is not sufficient to produce the pearlescent pigment's own pearl luster and unique color tone.If the content exceeds 30 wt%, the pearl pigment has its own pearl luster and unique color tone. Is likely to be lost, and the adhesion of the pressure-sensitive adhesive material tends to be adversely affected, which is not preferable in terms of cost.
また、上記粘着剤層は、充な耐候性を得るために、アク
リル系樹脂、特に、アクリル系感圧粘着剤で形成され
る。好ましいアクリル系粘着剤層の厚みは20〜100μで
ある。又、アクリル系粘着剤層には、着色を施すことが
できる。又、アクリル系粘着剤層には、通常、剥離紙が
貼着される。Further, the pressure-sensitive adhesive layer is formed of an acrylic resin, particularly an acrylic pressure-sensitive adhesive in order to obtain sufficient weather resistance. The preferable thickness of the acrylic pressure-sensitive adhesive layer is 20 to 100 μm. Further, the acrylic pressure-sensitive adhesive layer can be colored. A release paper is usually attached to the acrylic pressure-sensitive adhesive layer.
また、上記PVC系樹脂フィルム層は、特に、耐候性、耐
溶剤（例えば耐ガソリン）性、印刷性等に優れたペース
トレジンで形成するのが好ましい。又、PVC系樹脂フィ
ルム層は、降伏応力5kg/mm2以下の柔軟なフィルムとし
て形成するのが好ましい。好ましいPVC系樹脂フィルム
層の厚みは10〜100μである。又、PVC系樹脂フィルム層
は、パール顔料独特の真珠光沢及び特異な色調を呈させ
る上で透明であることが必要であり、この場合、透明と
は、全線透過率にして、40％以上、このましくは60％以
上を意味する。又、PVC系樹脂フィルム層は、その表面
の印刷特性を良好にするため、表面張力が32dyne/cm以
上となるように調製するのが好ましい。又、PVC系樹脂
フィルム層には、例えば、紫外線吸収剤を0.2〜3wt％含
有させることができる。紫外線吸収剤としては、ベンゾ
トリアゾール系紫外線吸収剤、ベンゾフェノン系紫外線
吸収剤、シアノアクリレート系紫外線吸収剤等をいるこ
とができる。又、PVC系樹脂フィルム層には、上記の全
光線透過率、即ち透明性を損なわない範囲で着色するこ
とによりパール調色相に変化を持たせることができる
し、又、スクリーン印刷、オフセット印刷、グラビア印
刷、凸版印刷等の印刷を施すことができる。更に、PVC
系樹脂フィルム層には、透明ブライマーコートを施して
更に耐候性エッブを企てることもできる。In addition, it is particularly preferable that the PVC resin film layer is formed of a paste resin excellent in weather resistance, solvent resistance (for example, gasoline resistance), printability and the like. Further, the PVC resin film layer is preferably formed as a flexible film having a yield stress of 5 kg / mm 2 or less. The preferable thickness of the PVC resin film layer is 10 to 100 µ. Further, the PVC resin film layer is required to be transparent in order to exhibit a pearl luster peculiar to the pearl pigment and a unique color tone, and in this case, the term "transparent" means a total line transmittance of 40% or more, This means more than 60%. The PVC resin film layer is preferably prepared to have a surface tension of 32 dyne / cm or more in order to improve the printing characteristics of the surface. Further, the PVC resin film layer may contain, for example, 0.2 to 3 wt% of an ultraviolet absorber. Examples of the UV absorber may include a benzotriazole-based UV absorber, a benzophenone-based UV absorber, a cyanoacrylate-based UV absorber, and the like. In addition, the PVC resin film layer can have a change in the pearl hue by coloring in the above-mentioned total light transmittance, that is, a range that does not impair transparency, and screen printing and offset printing. Printing such as gravure printing and letterpress printing can be performed. Furthermore, PVC
The resin film layer may be coated with a transparent brimer coat to further provide a weather resistant ebb.
本発明において、上記のパール顔料含有アクリル系粘着
剤層は、パール顔料の持つ独持の色相を有する装飾層と
して働き、且つ本発明のPVC系粘着シートを被着体に貼
り付けるための接着機能を持つ。In the present invention, the pearl pigment-containing acrylic pressure-sensitive adhesive layer serves as a decorative layer having a unique hue of the pearl pigment, and has an adhesive function for sticking the PVC pressure-sensitive adhesive sheet of the present invention to an adherend. have.
また、透明な上記PVC系樹脂フィルム層は、本発明のPVC
粘着シートに柔軟性を付与する（粘着剤層はPVC系樹脂
フィルム層より更に柔軟であるため、粘着シートの柔軟
性は、PVC系樹脂フィルム層に支配される。）作用機能
を持つと共に、下層のパール顔料含有アクリル系粘着剤
層を、屋外使用における種々気象条件（光、熱、雨等）
から保護する作用機能を持つ。特に、例えば、パール顔
料含有アクリル系粘着剤層にパール顔料以外の一般着色
剤を併用使用した場合においても、この一般着色剤の屋
外耐候性を保護する作用機能を持つ。Further, the transparent PVC-based resin film layer is the PVC of the present invention.
Flexibility of the PSA sheet (Since the PSA layer is more flexible than the PVC resin film layer, the flexibility of the PSA sheet is governed by the PVC resin film layer). Acrylic adhesive layer containing pearl pigment is used for various outdoor weather conditions (light, heat, rain, etc.)
It has a function of protecting from. In particular, for example, even when a general colorant other than the pearl pigment is used in combination with the pearl pigment-containing acrylic pressure-sensitive adhesive layer, it has a function of protecting the outdoor weather resistance of the general colorant.
更に、透明なPVC系樹脂フィルム層は、その透明性を生
かして、下層のパール顔料含有アクリル系粘着剤層の持
つパール調色相をそのまま生かすことができるし、場合
によっては、その透明性を損なわない範囲で着色するこ
とにより下地パール調色相に変化を持たすことも可能で
ある。Furthermore, the transparent PVC resin film layer can utilize its transparency to utilize the pearl hue of the lower pearl pigment-containing acrylic pressure-sensitive adhesive layer as it is, and in some cases, the transparency can be improved. It is possible to give a change to the base pearl tone by coloring within a range that does not impair it.
加えて、透明なPVC系樹脂フィルム層、本発明のPVC粘着
シートを被着体に貼り付け使用した場合の耐溶剤性機
能、例えば、ガソリンが表面にかかった場合用における
保護機能を有し、更には、場合によって本発明のPVC系
粘着シートの上に更に印刷を施して使用する場合の印刷
性の良い支持体として働く。In addition, a transparent PVC resin film layer, a solvent resistance function when using the PVC pressure-sensitive adhesive sheet of the present invention stuck to an adherend, for example, having a protective function in the case where gasoline is applied to the surface, Furthermore, it may serve as a support having good printability when the PVC-based pressure-sensitive adhesive sheet of the present invention is further printed and used in some cases.
而して、本発明の屋外耐候性の良いパール調PVC系粘着
シートの製造は、例えば、アクリル系粘着剤にパール顔
料を均一に分散させ、これを剥離紙上に塗布し、乾燥さ
せアクリル系粘着剤層を形成し、該アクリル系粘着剤層
に透明なPVC系樹脂フィルム層を貼り合わせて行うこと
ができる。Thus, the production of a pearl-like PVC adhesive sheet having good outdoor weatherability of the present invention is carried out, for example, by uniformly dispersing a pearl pigment in an acrylic adhesive, applying it on a release paper, and drying it to obtain an acrylic adhesive. It can be carried out by forming an agent layer and adhering a transparent PVC resin film layer to the acrylic adhesive layer.
本発明の屋外耐候性の良いパール調PVC系粘着シート
は、装飾用粘着シートとして使用され、必要に応じ所望
のサイズ、形にカットし、簡単に所望の被着体に貼り付
けることができるもので、特に所望の被着体が曲面を有
するような場合においても、その柔軟性を生かし簡単に
曲面にフィットさせて貼り付けることができるものであ
る。そして、この貼り付けにより、パール顔料独持の真
珠光沢及び特異な色調を発揮して被着体（下地）を装飾
できるものである。A pearly PVC-based PSA sheet having good outdoor weatherability of the present invention is used as a decorative PSA sheet, and can be cut into a desired size and shape as necessary and easily attached to a desired adherend. In particular, even when a desired adherend has a curved surface, the flexibility can be utilized to easily fit and adhere to the curved surface. By this attachment, the adherend (base) can be decorated by exhibiting the pearl luster unique to the pearl pigment and a unique color tone.
次に、実施例を挙げ、本発明の屋外耐候性の良いパール
調PVC粘着シートを更に具体的に説明する。Next, the pearl-like PVC pressure-sensitive adhesive sheet of the present invention having good outdoor weatherability will be described more specifically with reference to Examples.
アクリル系粘着剤（日本カーバイト工業（株）製、商品
名:PE−121）100重量部に、架橋剤（日本ポリウレタン
工業（株）製、商品名：コロネートＬ）1.5重量部及び
パール顔料（メルク社製、商品名：イリオジン300 Gol
d Pearl）５重量部を加え、スターラーにて均一分散す
るように撹拌した。100 parts by weight of an acrylic adhesive (manufactured by Nippon Carbide Industry Co., Ltd., trade name: PE-121), 1.5 parts by weight of a crosslinking agent (manufactured by Nippon Polyurethane Industry Co., Ltd., trade name: Coronate L) and a pearl pigment ( Merck, trade name: Iriodin 300 Gol
d Pearl) (5 parts by weight) was added, and the mixture was stirred with a stirrer so as to be uniformly dispersed.
この混合液を、剥離紙（四国製紙（株）製、商品名:SP
−11SE）の上に塗布し、乾燥させ、厚み35μのアクリル
粘着剤層を造った。This mixed solution was applied to release paper (Shikoku Paper Co., Ltd., trade name: SP
-11SE) and then dried to form an acrylic pressure-sensitive adhesive layer having a thickness of 35 μm.
このアクリル粘着剤層の上に、透明で厚み50μ、降伏応
力2.8kg/mm2のPVCフィルム（日本カーバイト工業（株）
製、商品名：ハイエスペイント5085）を貼り合わせ、粘
着シートを得た。On this acrylic adhesive layer, a transparent PVC film with a thickness of 50μ and a yield stress of 2.8 kg / mm 2 (Nippon Carbide Industry Co., Ltd.)
Product name: Hyes Paint 5085) was attached to obtain an adhesive sheet.
得られた粘着シートは、独持のパール調色相を持つ色鮮
やかな粘着シートであった。更に、促進耐候性テストＷ
−Ｏ−M2000Hにおいて、殆ど変化がなく、耐候性の優れ
たものであった。The obtained pressure-sensitive adhesive sheet was a vivid pressure-sensitive adhesive sheet having a unique pearl hue. Furthermore, accelerated weather resistance test W
In -O-M2000H, there was almost no change and the weather resistance was excellent.
本発明の屋外耐候性の良いパール調PVC系粘着シート
は、パール顔料独持の真珠光沢及び特異な色調をも発揮
して被着体（下地）を装飾できるもので、耐候性が非常
に良好で、且つ柔軟性、即ち優れた貼り適性を有し、更
には、耐溶剤性、印刷性に優れ、比較的安価である等の
種々の効果を奏するもので、装飾用、屋外使用用PVC粘
着シートとしての価値の高いものである。The outdoor-use weather-resistant pearl-like PVC-based pressure-sensitive adhesive sheet of the present invention is capable of decorating an adherend (base) by exhibiting a pearl luster and a unique color tone that are unique to pearl pigments, and has very good weather resistance. In addition, it has various effects such as flexibility, that is, excellent sticking suitability, and further excellent solvent resistance, printability, and is relatively inexpensive. It is a PVC adhesive for decoration and outdoor use. It has a high value as a seat.
Claims (6)
ル系粘着剤層と、透明なPVC系樹脂フィルム層とを積層
固定してなることを特徴とする屋外耐候性の良いパール
調PVC系粘着シート。1. A pearl-like PVC adhesive having good weather resistance, comprising an acrylic adhesive layer containing 1.5 to 30 wt% of a pearl pigment and a transparent PVC resin film layer laminated and fixed. Sheet.
ある、特許請求の範囲第（１）項記載の屋外耐候性の良
いパール調PVC系粘着シート。2. A pearl-like PVC pressure-sensitive adhesive sheet having good weatherability according to claim 1, wherein the acrylic pressure-sensitive adhesive layer has a thickness of 20 to 100 μm.
ある、特許請求の範囲第（１）項又は第（２）項記載の
屋外耐候性の良いパール調PVC系粘着シート。3. A pearl-like PVC pressure-sensitive adhesive sheet having good outdoor weatherability according to claim (1) or (2), wherein the PVC resin film layer has a thickness of 10 to 100 μm.
んでいる、特許請求の範囲第（１）項乃至第（３）項の
何れかに記載の屋外耐候性の良いパール調PVC系粘着シ
ート。4. A pearl-like PVC adhesive having good outdoor weatherability according to any one of claims (1) to (3), wherein the PVC resin film layer contains an ultraviolet absorber. Sheet.
下の柔軟なフィルムである、特許請求の範囲第（１）項
乃至第（４）項の何れかに記載の屋外耐候性の良いパー
ル調PVC系粘着シート。5. The outdoor weather resistance according to any one of claims (1) to (4), wherein the PVC resin film layer is a flexible film having a yield stress of 5 kg / mm 2 or less. Good pearly PVC adhesive sheet.
且つその平均粒径が５〜80μであり、特許請求の範囲第
（１）項乃至第（５）項の何れかに記載の屋外耐候性の
良いパール調PVC系粘着シート。6. The pearl pigment is a mica type pearl pigment,
Further, the pearl tone PVC-based pressure-sensitive adhesive sheet according to any one of claims (1) to (5), which has an average particle diameter of 5 to 80 μm and has good outdoor weatherability.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61218032A JPH0699670B2 (en) | 1986-09-18 | 1986-09-18 | Peel-like PVC adhesive sheet with good outdoor weatherability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61218032A JPH0699670B2 (en) | 1986-09-18 | 1986-09-18 | Peel-like PVC adhesive sheet with good outdoor weatherability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6375081A JPS6375081A (en) | 1988-04-05 |
| JPH0699670B2 true JPH0699670B2 (en) | 1994-12-07 |
Family
ID=16713569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61218032A Expired - Fee Related JPH0699670B2 (en) | 1986-09-18 | 1986-09-18 | Peel-like PVC adhesive sheet with good outdoor weatherability |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0699670B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6716487B1 (en) | 1999-10-20 | 2004-04-06 | Sang G. Song | Decorative stickers from inkjet printing and method therefor |
| KR200280679Y1 (en) | 2002-02-16 | 2002-07-13 | 주식회사 다이아덤코리아 | Decotile ideastix sheet |
| JP2009051011A (en) * | 2007-08-23 | 2009-03-12 | Toyo Seikan Kaisha Ltd | Decorative laminated material, flexible container having the laminated material, and decorative lamination method |
| JP7285792B2 (en) * | 2020-01-14 | 2023-06-02 | 日本カーバイド工業株式会社 | Adhesive composition and laminate |
| JP2023183715A (en) * | 2022-06-16 | 2023-12-28 | スリーエム イノベイティブ プロパティズ カンパニー | decorative film |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4110701Y1 (en) * | 1964-03-31 | 1966-05-19 |
-
1986
- 1986-09-18 JP JP61218032A patent/JPH0699670B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6375081A (en) | 1988-04-05 |
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