JPH0688009A - Colored resin composition - Google Patents
Colored resin compositionInfo
- Publication number
- JPH0688009A JPH0688009A JP26412692A JP26412692A JPH0688009A JP H0688009 A JPH0688009 A JP H0688009A JP 26412692 A JP26412692 A JP 26412692A JP 26412692 A JP26412692 A JP 26412692A JP H0688009 A JPH0688009 A JP H0688009A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- resin
- ethylene
- propylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、色むら（色分れ）のな
い黒色〜灰色の着色樹脂成形品を得るのに有用な樹脂着
色組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a resin coloring composition useful for obtaining a black to gray colored resin molded product having no color unevenness (color separation).
【０００２】[0002]
【従来の技術】本発明における着色の対象となる樹脂
は、無機充填剤（一般にタルク等）を含み得るエチレン
・プロピレン−ブロック共重合体を主体とする樹脂であ
り、この樹脂は耐衝撃性が大きいことが特徴で、自動車
部品、家電製品、その他の必要な成形品として広く使用
されている。ポリエチレンやポリプロピレン樹脂等のポ
リオレフィン樹脂を、黒色〜灰色に着色するための着色
用顔料としては、一般にカーボンブラック及び二酸化チ
タンが用いられている。顔料の中でも、特にカーボンブ
ラック及び二酸化チタンは着色力が優れており、経済的
にも安価であることから多量に使用されている。2. Description of the Related Art The resin to be colored in the present invention is a resin mainly composed of an ethylene / propylene-block copolymer which may contain an inorganic filler (generally talc or the like). Characterized by its large size, it is widely used in automobile parts, home appliances, and other necessary molded products. Carbon black and titanium dioxide are generally used as coloring pigments for coloring polyolefin resins such as polyethylene and polypropylene resins from black to gray. Among the pigments, carbon black and titanium dioxide are particularly used in large amounts because they have excellent coloring power and are economically inexpensive.
【０００３】[0003]
【発明が解決しようとしている問題点】一般に、無機充
填剤を０〜４０重量部含有するエチレン・プロピレン−
ブロック共重合体を主体とする樹脂を黒色〜灰色に着色
するには、通常のカーボンブラック及び二酸化チタンを
配合し、これを溶融押出してペレット化している。しか
し、このペレットを押出成形機や、射出成形機に供して
成形品に成形した場合、成形加工時の溶融樹脂の流れ方
向の異方性によって、部分的に着色されずに成形品表面
が筋状又は帯状に白くなる色むら（色分れ）が生じる欠
陥があった。尚、この色むら（色分れ）は成形品のほぼ
同一ケ所に発生する特徴があり、一般的な着色剤の混ざ
りむら（混合不足）とは異なっている。前記の色むら
（色分れ）発生を防止するために、例えば、エチレン・
プロピレン−ブロック共重合体を主体とする樹脂の黒色
着色においてカーボンブラックに替えて鉄黒を使用する
方法が提案されている（特公昭６２−１４５７６号公
報）。DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention Generally, ethylene-propylene containing 0 to 40 parts by weight of an inorganic filler is used.
In order to color the resin mainly composed of the block copolymer from black to gray, ordinary carbon black and titanium dioxide are blended and melt-extruded and pelletized. However, when these pellets are subjected to extrusion molding machines or injection molding machines and molded into molded products, due to the anisotropy of the flow direction of the molten resin during molding, they are not partially colored and the surface of the molded product is streaked. There was a defect that color irregularity (color separation) that turned white or band-shaped was observed. It should be noted that this color unevenness (color separation) is generated in almost the same place of the molded product, which is different from general color unevenness of the colorants (insufficient mixing). In order to prevent the occurrence of color unevenness (color separation), for example, ethylene
A method has been proposed in which iron black is used instead of carbon black in black coloring of a resin mainly composed of a propylene-block copolymer (Japanese Patent Publication No. 62-14576).
【０００４】ところが、鉄黒はカーボンブラックに比較
して着色濃度が乏しいため、カーボンブラックと同じよ
うな着色濃度を出すためには、カーボンブラックの約７
〜１０倍の量の鉄黒を必要とする。その結果、エチレン
・プロピレン−ブロック共重合体を主体とする複合材料
の着色においては、着色剤の経費がかかるうえ、鉄黒を
多量に使用すると耐衝撃性の高いことに特徴のあるエチ
レン・プロピレン−ブロック共重合体を主体とする樹脂
成形品の強度が損なわれる欠点がある。従って本発明の
目的は、エチレン・プロピレン−ブロック共重合体を主
体とする樹脂をカーボンブラック及び二酸化チタンで着
色する際、樹脂の物性低下を起こさないで、しかも無機
質充填剤とともに使用した場合にも、色むら（色分れ）
なく着色成形することができる樹脂着色組成物を提供す
ることを目的とする。However, iron black has a lower coloring density than carbon black. Therefore, in order to obtain the same coloring density as carbon black, about 7 times that of carbon black is required.
-10 times more iron black is needed. As a result, when coloring a composite material mainly composed of an ethylene / propylene-block copolymer, the cost of the colorant is high, and when a large amount of iron black is used, the impact resistance is high. There is a drawback that the strength of the resin molded product mainly composed of the block copolymer is impaired. Therefore, an object of the present invention is to prevent the deterioration of the physical properties of the resin when coloring the resin mainly composed of ethylene / propylene-block copolymer with carbon black and titanium dioxide, and also to use it together with the inorganic filler. , Color unevenness (color separation)
It is an object of the present invention to provide a resin coloring composition that can be colored and molded without any treatment.
【０００５】[0005]
【問題点を解決するための手段】上記目的は以下の本発
明によって達成される。即ち、本発明は、エチレン・プ
ロピレン−ブロック共重合体を主体とする樹脂１００重
量部当たり、無機充填剤０〜４０重量部、カーボンブラ
ック０．０１〜２０重量部、二酸化チタン０．０１〜２
０重量部及びモンタン酸化エステルワックス０．０５〜
１０重量部含有することを特徴とする樹脂着色組成物で
ある。The above object can be achieved by the present invention described below. That is, in the present invention, the inorganic filler is 0 to 40 parts by weight, the carbon black is 0.01 to 20 parts by weight, and the titanium dioxide is 0.01 to 2 per 100 parts by weight of the resin mainly composed of the ethylene / propylene-block copolymer.
0 parts by weight and montan oxide ester wax 0.05 to
The resin coloring composition is characterized by containing 10 parts by weight.
【０００６】[0006]
【作用】本発明者等は、前記の樹脂成形時に発生する色
むらを防止する着色処方について、種々研究を重ねた結
果、樹脂組成物にモンタン酸エステルワックスを配合す
ることにより、前記色むら（色分れ）の発生が防止され
ることを見出し、この知見に基づき本発明を完成した。The inventors of the present invention have conducted various studies on the coloring prescription for preventing the above-mentioned color unevenness occurring during resin molding, and as a result, by adding a montanic acid ester wax to the resin composition, the above-mentioned color unevenness ( It was found that the occurrence of (color separation) was prevented, and the present invention was completed based on this finding.
【０００７】[0007]
【好ましい実施態様】次に好ましい実施態様を挙げて本
発明を更に詳細に説明する。本発明で使用するエチレン
・プロピレン−ブロック共重合体を主体とする樹脂と
は、実際はポリプロピレン樹脂にエチレン・プロピレン
共重合体をブレンドされた樹脂組成物であり、通常、ホ
モポリプロピレン樹脂５０〜９９重量部に対してエチレ
ン・プロピレン共重合体を１〜５０重量部の割合でブレ
ンドされたものである。即ち、この様な樹脂は、例え
ば、第一重合槽でプロピレンを重合してポリプロピレン
樹脂を生成させ、該ポリプロピレン樹脂を含有した重合
液をそのまま第二反応槽に移し、プロピレンガスととも
にエチレンガスを第二反応槽に供給して、エチレン・プ
ロピレン共重合体を生成させ、この際、第一反応槽で生
成したポリプロピレン樹脂との均一なブレンド物として
製造することができる。BEST MODE FOR CARRYING OUT THE INVENTION Next, the present invention will be described in more detail with reference to preferred embodiments. The resin mainly composed of ethylene / propylene-block copolymer used in the present invention is actually a resin composition obtained by blending an ethylene / propylene copolymer with a polypropylene resin, and usually 50 to 99% by weight of homopolypropylene resin. The ethylene / propylene copolymer is blended in a ratio of 1 to 50 parts by weight based on 1 part by weight. That is, such a resin is obtained by, for example, polymerizing propylene in the first polymerization tank to produce a polypropylene resin, transferring the polymerization liquid containing the polypropylene resin as it is to the second reaction tank, and adding ethylene gas together with propylene gas to the first reaction tank. It is fed to a two-reaction tank to produce an ethylene / propylene copolymer, which can be produced as a uniform blend with the polypropylene resin produced in the first reaction vessel.
【０００８】本発明に用いるエチレン・プロピレン−ブ
ロック共重合体を主体とする樹脂の製造方法は、特公昭
４０−１１６２３号公報等に記載されている。上記の製
造方法において、原料ガスのプロピレン又はエチレンに
少量の炭素数４〜６のオレフィンを混合して同様に製造
した樹脂組成物も本発明のエチレン・プロピレン−ブロ
ック共重合体を主体とする樹脂として使用することがで
きる。本発明に用いるエチレン・プロピレン−ブロック
共重合体を主体とする樹脂の平均分子量は、特に制限は
ないが、通常ＭＦＲで表して０．１〜３０程度のものを
使用することができる。A method for producing a resin mainly composed of an ethylene / propylene-block copolymer used in the present invention is described in JP-B-40-11623. In the above production method, a resin composition produced in the same manner by mixing a small amount of an olefin having 4 to 6 carbon atoms with propylene or ethylene as a raw material gas is also a resin mainly comprising the ethylene / propylene-block copolymer of the present invention. Can be used as The average molecular weight of the resin mainly composed of the ethylene / propylene-block copolymer used in the present invention is not particularly limited, but those having an MFR of about 0.1 to 30 can be used.
【０００９】本発明で所望により使用する無機充填剤と
は、例えば、シリカ、アルミナ、タルク、クレー、炭酸
カルシウム、硫酸バリウム、無水石膏等であり、好まし
くはタルクが一般的である。これらの無機充填剤は、エ
チレン・プロピレン−ブロック共重合体に対して０〜４
０重量部の割合で配合される。本発明で使用するカーボ
ンブラックは、ファーネスタイプ、チャンネルタイプの
いずれかでもよい。又、二酸化チタンは硫酸法及び塩素
法で製造されたもののいずれでもよい。これらのカーボ
ンブラックは、エチレン・プロピレン−ブロック共重合
体を主体とする樹脂１００重量部当たり０．０１〜２０
重量部の割合で配合される。又、二酸化チタンは、エチ
レン・プロピレン−ブロック共重合体を主体とする樹脂
１００重量部当たり０．０１〜２０重量部の割合で配合
される。The inorganic filler optionally used in the present invention is, for example, silica, alumina, talc, clay, calcium carbonate, barium sulfate, anhydrous gypsum, etc., and talc is generally preferred. These inorganic fillers are 0 to 4 relative to the ethylene / propylene-block copolymer.
It is blended in a ratio of 0 parts by weight. The carbon black used in the present invention may be either a furnace type or a channel type. Further, the titanium dioxide may be one produced by the sulfuric acid method or the chlorine method. These carbon blacks are contained in an amount of 0.01 to 20 per 100 parts by weight of a resin mainly composed of an ethylene / propylene-block copolymer.
It is blended in a ratio of parts by weight. Titanium dioxide is added in an amount of 0.01 to 20 parts by weight based on 100 parts by weight of a resin mainly composed of ethylene / propylene-block copolymer.
【００１０】本発明に使用するモンタン酸エステルワッ
クスとは、密度：０．９４〜１．１０ｇ／ｃｃ、酸価：
１〜２００、鹸化価：５０〜２００程度のもので、エチ
レン・プロピレン−ブロック共重合体を主体とする樹脂
１００重量部当たり０．０５〜１０重量部、好ましくは
０．１〜２％重量部の割合で使用することが好適であ
る。モンタン酸エステルワックスの含有量が０．０５重
量部未満では、本発明の目的とする色むら（色分れ）の
発生をなくすことができず、一方、１０重量部より多く
含有するものは、得られる成形品の物性を低下させるこ
とがあるので好ましくない。尚、本発明においては前記
のカーボンブラック顔料及び二酸化チタン顔料の他、従
来プラスチックの着色に一般に使用されている顔料、例
えば、アゾ系、フタロシアニン系、キナクリドン系、ア
ンスラキノン系、ジオキサジン系、ペリレン系、インジ
コ系、インダスレン系等の有機顔料、コバルトブルー、
黄鉛、ベンガラ、酸化クロム、群青、紺青等の無機顔料
も併用することができる。The montanic acid ester wax used in the present invention has a density of 0.94 to 1.10 g / cc and an acid value of:
1 to 200, saponification value: about 50 to 200, and 0.05 to 10 parts by weight, preferably 0.1 to 2% by weight, per 100 parts by weight of the resin mainly comprising ethylene / propylene-block copolymer. It is preferable to use it in a ratio of. When the content of the montanic acid ester wax is less than 0.05 parts by weight, the occurrence of color unevenness (color separation), which is the object of the present invention, cannot be eliminated, while the content of more than 10 parts by weight is It is not preferable because the physical properties of the obtained molded product may be deteriorated. In the present invention, in addition to the above carbon black pigment and titanium dioxide pigment, pigments generally used for coloring conventional plastics such as azo type, phthalocyanine type, quinacridone type, anthraquinone type, dioxazine type and perylene type pigments. , Indico type, indanthrene type organic pigments, cobalt blue,
Inorganic pigments such as yellow lead, red iron oxide, chromium oxide, ultramarine blue and navy blue can also be used together.
【００１１】本発明の樹脂着色組成物の必須成分は、前
記の成分であるが、その他必要に応じて各種担体樹脂、
分散剤、紫外線吸収剤、安定剤等の添加剤を適宜配合す
ることができる。本発明の樹脂着色組成物は、各種の形
態をとることができるが、例えば、必須成分を混合機
（ヘンシェルミキサー）で混合後、この混合物を押出機
等の混練機で溶融混練し、ペレット状に賦形して成形材
料として供給することができる。又、バンバリーミキサ
ー、ミキシングロール等の混練機でもよい。又、樹脂に
添加する着色剤等が低濃度範囲の場合には、いわゆるカ
ラーコンパウンドとして使用し、そのまま成形に供する
ことが出来、又、着色剤等が高濃度範囲のものは、これ
を樹脂で希釈して使用する着色マスターバッチとして使
用することが出来る。The essential components of the resin coloring composition of the present invention are the above-mentioned components, but if necessary, various carrier resins,
Additives such as a dispersant, an ultraviolet absorber and a stabilizer can be appropriately added. The resin coloring composition of the present invention can take various forms. For example, after mixing the essential components with a mixer (Henschel mixer), the mixture is melt-kneaded with a kneader such as an extruder, and then pelletized. And can be supplied as a molding material. Further, a kneader such as a Banbury mixer or a mixing roll may be used. Further, when the colorant added to the resin is in a low concentration range, it can be used as a so-called color compound and can be directly subjected to molding. It can be used as a colored masterbatch to be diluted and used.
【００１２】[0012]
【実施例】次に実施例及び比較例を挙げて本発明を更に
具体的に説明する。 実施例１ エチレン・プロピレン−ブロック共重合体を主体とする
樹脂（エチレン含有量８重量部、ＭＦＲ＝１．８）７
８．４重量部、タルク（平均粒子径：２．３μｍ）２
０．０重量部、ファーネスタイプカーボンブラック（粒
子径：３０μｍ）０．５重量部、二酸化チタン（粒子
径：０．３μｍ）１．０重量部及びモンタン酸エステル
ワックスＡ（酸価：９０、鹸化価：１２０）０．１重量
部をヘンシェルミキサーで均一に混合し、常法に従って
押出成形機で押出成形を行い着色ペレットを得た。上記
ペレットを射出成形機（名機製作所製 ７０Ｚ）を用い
て１２０×１００×３ｍｍの板状成形品を成形した（成
形条件＝温度：２２０℃、金型温度：４０℃）。この成
形品の色むら（色分れ）発生の状況を肉眼で観察した。
その結果を下記表１に示す。EXAMPLES Next, the present invention will be described more specifically with reference to Examples and Comparative Examples. Example 1 Resin mainly composed of ethylene / propylene-block copolymer (ethylene content 8 parts by weight, MFR = 1.8) 7
8.4 parts by weight, talc (average particle size: 2.3 μm) 2
0.0 parts by weight, furnace type carbon black (particle size: 30 μm) 0.5 parts by weight, titanium dioxide (particle size: 0.3 μm) 1.0 part by weight, and montanic acid ester wax A (acid value: 90, saponification Value: 120) 0.1 part by weight was uniformly mixed with a Henschel mixer, and extrusion-molded with an extruder according to a conventional method to obtain colored pellets. A 120 × 100 × 3 mm plate-shaped molded product was molded from the pellets using an injection molding machine (70Z manufactured by Meiki Seisakusho) (molding condition = temperature: 220 ° C., mold temperature: 40 ° C.). The appearance of color unevenness (color separation) in this molded product was observed with the naked eye.
The results are shown in Table 1 below.
【００１３】実施例２ エチレン・プロピレン−ブロック共重合体を主体とする
樹脂（エチレン含有量８重量部、ＭＦＲ＝１．８）７
６．０重量部、タルク（平均粒子径：２．３μｍ）２
０．０重量部、ファーネスタイプカーボンブラック（粒
子径：３０μｍ）１．０重量部、二酸化チタン（粒子
径：０．３μｍ）１．０重量部及びモンタン酸エステル
ワックスＡ（酸価：９０、鹸化価：１２０）２．０重量
部を混合し、以下実施例１と同様に評価してその結果を
下記表１に示した。Example 2 Resin mainly composed of ethylene / propylene-block copolymer (ethylene content 8 parts by weight, MFR = 1.8) 7
6.0 parts by weight, talc (average particle size: 2.3 μm) 2
0.0 part by weight, furnace type carbon black (particle size: 30 μm) 1.0 part by weight, titanium dioxide (particle size: 0.3 μm) 1.0 part by weight, and montanic acid ester wax A (acid value: 90, saponification Value: 120) 2.0 parts by weight were mixed and evaluated in the same manner as in Example 1 below. The results are shown in Table 1 below.
【００１４】実施例３ エチレン・プロピレン−ブロック共重合体を主体とする
樹脂（エチレン含有量８重量部、ＭＦＲ＝１．８）７
８．４重量部、タルク（平均粒子径：２．３μｍ）２
０．０重量部、ファーネスタイプカーボンブラック（粒
子径：３０μｍ）０．５重量部、二酸化チタン（粒子
径：０．３μｍ）１．０重量部及びモンタン酸エステル
ワックスＢ（酸価：５０、鹸化価：１５０）０．１重量
部を混合し、以下実施例１と同様に評価してその結果を
下記表１に示した。Example 3 Resin mainly composed of ethylene / propylene-block copolymer (ethylene content 8 parts by weight, MFR = 1.8) 7
8.4 parts by weight, talc (average particle size: 2.3 μm) 2
0.0 parts by weight, furnace type carbon black (particle size: 30 μm) 0.5 parts by weight, titanium dioxide (particle size: 0.3 μm) 1.0 part by weight, and montanic acid ester wax B (acid value: 50, saponification (Value: 150) 0.1 part by weight was mixed and evaluated in the same manner as in Example 1 and the results are shown in Table 1 below.
【００１５】実施例４ エチレン・プロピレン−ブロック共重合体を主体とする
樹脂（エチレン含有量８重量部、ＭＦＲ＝１．８）７
６．０重量部、タルク（平均粒子径：２．３μｍ）２
０．０重量部、ファーネスタイプカーボンブラック（粒
子径：３０μｍ）１．０重量部、二酸化チタン（粒子
径：０．３μｍ）１．０重量部及びモンタン酸エステル
ワックスＢ（酸価：５０、鹸化価：１５０）２．０重量
部を混合し、以下実施例１と同様に評価してその結果を
下記表１に示した。Example 4 Resin mainly composed of ethylene / propylene-block copolymer (ethylene content 8 parts by weight, MFR = 1.8) 7
6.0 parts by weight, talc (average particle size: 2.3 μm) 2
0.0 part by weight, furnace type carbon black (particle size: 30 μm) 1.0 part by weight, titanium dioxide (particle size: 0.3 μm) 1.0 part by weight and montanic acid ester wax B (acid value: 50, saponification (Value: 150) 2.0 parts by weight were mixed and evaluated in the same manner as in Example 1 below. The results are shown in Table 1 below.
【００１６】比較例１ エチレン・プロピレン−ブロック共重合体を主体とする
樹脂（エチレン含有量８重量部、ＭＦＲ＝１．８）７
８．５重量部、タルク（平均粒子径：２．３μｍ）２
０．０重量部、ファーネスタイプカーボンブラック（粒
子径：３０μｍ）０．５重量部及び二酸化チタン（粒子
径：０．３μｍ）１．０重量部を混合し、以下実施例１
と同様に評価してその結果を下記表１に示した。Comparative Example 1 Resin mainly composed of ethylene / propylene-block copolymer (ethylene content 8 parts by weight, MFR = 1.8) 7
8.5 parts by weight, talc (average particle size: 2.3 μm) 2
0.0 part by weight, furnace type carbon black (particle size: 30 μm) 0.5 part by weight and titanium dioxide (particle size: 0.3 μm) 1.0 part by weight were mixed, and the following Example 1 was used.
The results are shown in Table 1 below.
【００１７】比較例２ エチレン・プロピレン−ブロック共重合体を主体とする
樹脂（エチレン含有量８重量部、ＭＦＲ＝１．８）７
８．０重量部、タルク（平均粒子径：２．３μｍ）２
０．０重量部、ファーネスタイプカーボンブラック（粒
子径：３０μｍ）１．０重量部及び二酸化チタン（粒子
径：０．３μｍ）１．０重量部を混合し、以下実施例１
と同様に評価してその結果を下記表１に示した。Comparative Example 2 Resin mainly composed of ethylene / propylene-block copolymer (ethylene content 8 parts by weight, MFR = 1.8) 7
8.0 parts by weight, talc (average particle size: 2.3 μm) 2
0.0 part by weight, 1.0 part by weight of furnace-type carbon black (particle size: 30 μm) and 1.0 part by weight of titanium dioxide (particle size: 0.3 μm) were mixed, and the following Example 1 was used.
The results are shown in Table 1 below.
【００１８】[0018]
【表１】 色むら（色分れ）評価基準 ○：色むら（色分れ）発生せず、均一に着色されてい
る。 ×：白っぽい線が出る。[Table 1] Evaluation standard of color unevenness (color separation) ○: Color unevenness (color separation) does not occur and it is uniformly colored. X: A whitish line appears.
【００１９】[0019]
【発明の効果】以上の如き本発明によれば、本発明の着
色組成物を常法に従って、各種の形状に成形加工する
と、その成形品が複雑な形状を有するものであっても、
その際に受ける複雑な溶融樹脂の流れ方向による色むら
（色分れ）がなく、表面の着色が非常に均一で優れた着
色成形品を提供することができる。According to the present invention as described above, when the colored composition of the present invention is molded into various shapes according to a conventional method, even if the molded article has a complicated shape,
It is possible to provide a colored molded article which is free from complicated color unevenness (color separation) due to the flowing direction of the molten resin and which has very uniform surface coloring.
Claims (2)
体を主体とする樹脂１００重量部当たり、無機充填剤０
〜４０重量部、カーボンブラック０．０１〜２０重量
部、二酸化チタン０．０１〜２０重量部及びモンタン酸
化エステルワックス０．０５〜１０重量部含有すること
を特徴とする樹脂着色組成物。1. An inorganic filler of 0 parts per 100 parts by weight of a resin mainly comprising an ethylene / propylene-block copolymer.
-40 parts by weight, 0.01 to 20 parts by weight of carbon black, 0.01 to 20 parts by weight of titanium dioxide, and 0.05 to 10 parts by weight of montan oxide ester wax are contained in the resin coloring composition.
体を主体とする樹脂が、ホモポリプロピレン樹脂５０〜
９９重量部とエチレン・プロピレン共重合体１〜５０重
量部とからなる請求項１に記載の樹脂着色組成物。2. A resin mainly comprising an ethylene / propylene-block copolymer is a homopolypropylene resin of 50 to 50.
The resin coloring composition according to claim 1, which comprises 99 parts by weight and 1 to 50 parts by weight of an ethylene / propylene copolymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4264126A JP2817129B2 (en) | 1992-09-08 | 1992-09-08 | Resin coloring composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4264126A JP2817129B2 (en) | 1992-09-08 | 1992-09-08 | Resin coloring composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0688009A true JPH0688009A (en) | 1994-03-29 |
| JP2817129B2 JP2817129B2 (en) | 1998-10-27 |
Family
ID=17398838
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4264126A Expired - Lifetime JP2817129B2 (en) | 1992-09-08 | 1992-09-08 | Resin coloring composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2817129B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001262073A (en) * | 2000-03-01 | 2001-09-26 | Clariant Gmbh | Preparation of pigmented powder coating material |
| JP2013253229A (en) * | 2012-05-08 | 2013-12-19 | Mitsubishi Rayon Co Ltd | Polyolefin resin composition and molded product |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63112639A (en) * | 1986-10-30 | 1988-05-17 | Idemitsu Kosan Co Ltd | Polyolefin resin composition |
| JPH02221957A (en) * | 1989-02-23 | 1990-09-04 | Fuji Photo Film Co Ltd | Main body of container for photographic film cartridge |
-
1992
- 1992-09-08 JP JP4264126A patent/JP2817129B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63112639A (en) * | 1986-10-30 | 1988-05-17 | Idemitsu Kosan Co Ltd | Polyolefin resin composition |
| JPH02221957A (en) * | 1989-02-23 | 1990-09-04 | Fuji Photo Film Co Ltd | Main body of container for photographic film cartridge |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001262073A (en) * | 2000-03-01 | 2001-09-26 | Clariant Gmbh | Preparation of pigmented powder coating material |
| JP2013253229A (en) * | 2012-05-08 | 2013-12-19 | Mitsubishi Rayon Co Ltd | Polyolefin resin composition and molded product |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2817129B2 (en) | 1998-10-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100378334B1 (en) | Color preparations for the production of masterbatches | |
| JPH03200841A (en) | Material for coloring synthetic resin molding in pattern, its preparation, and synthetic resin molding colored therewith | |
| JP3571780B2 (en) | Polypropylene resin compound for molding | |
| JP3330046B2 (en) | Masterbatch for coloring polypropylene-based composite materials | |
| JP3375263B2 (en) | Masterbatch for coloring high flow ethylene / propylene-copolymer | |
| JP3375262B2 (en) | Masterbatch for coloring polypropylene-based composite materials | |
| JPH08325422A (en) | Colorant composition for polypropylene | |
| JPH0688009A (en) | Colored resin composition | |
| JPS63113057A (en) | Resin composition | |
| CA1184330A (en) | Color pigment for use in the production of thermoplastic articles | |
| JPH0925447A (en) | Colored master batch containing filler | |
| JP2000169664A (en) | Polypropylene coloring composition excellent in color development stability | |
| JPH06271741A (en) | Propylene resin composition | |
| JP2001150474A (en) | Injection molding method, injection-molded molding, and master batch | |
| JPH01225655A (en) | Colored polypropylene composition | |
| JPH0676536B2 (en) | Polypropylene coloring composition | |
| JPH0572417B2 (en) | ||
| JPH08325423A (en) | Colorant composition for highly crystalline polypropylene | |
| JPH0419264B2 (en) | ||
| JP2000129192A (en) | Colorant composition for polypropylene | |
| JPH09255831A (en) | Resin composition for coloring and its utilization | |
| JPH08311294A (en) | Polyolefin composition for injection molding | |
| JPS6214576B2 (en) | ||
| JP2005036186A (en) | Resin composition for coloring and colored resin molding using the composition | |
| JPH0243249A (en) | Polyolefin composition for injection molding |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 9 Free format text: PAYMENT UNTIL: 20070821 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 10 Free format text: PAYMENT UNTIL: 20080821 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090821 Year of fee payment: 11 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 11 Free format text: PAYMENT UNTIL: 20090821 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100821 Year of fee payment: 12 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 13 Free format text: PAYMENT UNTIL: 20110821 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 14 Free format text: PAYMENT UNTIL: 20120821 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120821 Year of fee payment: 14 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130821 Year of fee payment: 15 |
|
| EXPY | Cancellation because of completion of term | ||
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 15 Free format text: PAYMENT UNTIL: 20130821 |