JPH06510072A - carburetor fuel additive - Google Patents

carburetor fuel additive

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Publication number
JPH06510072A
JPH06510072A JP5504100A JP50410092A JPH06510072A JP H06510072 A JPH06510072 A JP H06510072A JP 5504100 A JP5504100 A JP 5504100A JP 50410092 A JP50410092 A JP 50410092A JP H06510072 A JPH06510072 A JP H06510072A
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Japan
Prior art keywords
additive
viscosity
cleanliness
cst
gasoline
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JP5504100A
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Japanese (ja)
Inventor
ミューラー ペーター
ラインハルト ベッカー
キースリング ディーター
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モビル オイル エージー
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/143Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/06Use of additives to fuels or fires for particular purposes for facilitating soot removal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1616Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1625Hydrocarbons macromolecular compounds
    • C10L1/1633Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
    • C10L1/1641Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing aliphatic monomers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/234Macromolecular compounds
    • C10L1/238Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Lubricants (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるため要約のデータは記録されません。 (57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 キャブレターの燃料添加剤 この発明はガソリンエンジンの吸引機構に関する清浄維持性能の技術的改善を達 成すること、及び既知のガソリン添加剤のコスト対利益の比率を最適化すること を目的として、既知の添加剤技術に活性燃量成分を使用することに関するもので ある。[Detailed description of the invention] carburetor fuel additive This invention has achieved technical improvement in the cleanliness maintenance performance of the suction mechanism of a gasoline engine. and to optimize the cost-benefit ratio of known gasoline additives. Concerning the use of active fuel components in known additive technology for the purpose of be.

石油の分留物(軽い物から重い物まで、中性かつ透明な原料)をガソリン添加剤 におけるキャリアオイル/活性成分として使うことは知られている。ガソリンエ ンジンの吸引機構における清浄維持性能に関する有効性へのこれらの分留物の影 響は、その濃度の関数として現れることが知られている。Petroleum fractions (neutral and transparent raw materials ranging from light to heavy) are used as gasoline additives. It is known for use as a carrier oil/active ingredient in Gasoline The impact of these fractions on the effectiveness of cleanliness maintenance in the engine suction system. It is known that the sound appears as a function of its concentration.

バルブの清浄性に対する要請と達成されるべき有効性の度合いは、特に最近にお いて確実に高まってきており、現存するキャリアオイル技術は、もはやこれらに 見合う程に十分ではない、オクタン要求値の増大とオイルの高濃度化は、従来の 石油分留物を高濃度で使用する場合、臨界的であるとみなされるべきである。The requirements for valve cleanliness and the degree of effectiveness to be achieved have increased especially recently. Existing carrier oil technology is no longer compatible with these technologies. Increased octane requirements and higher oil concentrations are not commensurate with conventional Petroleum fractions should be considered critical when used in high concentrations.

様々な石油分留物やそれらの混合物、及び完全な合成キャリアオイルは、これま でのところ、満足な結果を得ることに失敗している。Various petroleum fractions, mixtures thereof, and fully synthetic carrier oils are So far, I have failed to obtain satisfactory results.

既知の商業上取得可能な、ポリエーテルアミンを基剤とする添加剤■ (データ シー)A)は、その使用においては満足な結果を与えることが示されている。し かし、製造業者によって示された濃度で通用した場合でも、臨界燃料や野外実地 試用において十分な吸引パルプ清浄維持性能を示すには程遠い。Known commercially available polyether amine-based additives (data C) A) has been shown to give satisfactory results in its use. death However, even if the concentrations indicated by the manufacturer are acceptable, critical fuels and field It is far from showing sufficient suction pulp cleanliness maintenance performance in trial use.

濃度の増加は性能に影響を与えると期待されるが、添加する活性成分として従来 のキャリアオイルを用いたテスト(300秒(sec)タービンヘースオイル、 データシートB)によると、キャリアオイルを加えることによって改善されるべ き添加剤有効性の度合いは限られるため、また、加えることのできるキャリアオ イルの量は、他の要素(例えば、オクタン要求値の増大、オイルの高濃度化や定 量ポンプの流量の限界)によって限られ、さらには、選んだキャリアオイルに依 存するため、実用上ものになる解答として残された余地は狭いものである。Increased concentration is expected to affect performance, but conventionally as an added active ingredient Test using carrier oil (300 seconds (sec)) Turbine head oil, According to data sheet B), it should be improved by adding carrier oil. Additives have a limited degree of effectiveness, and carrier oxides that can be added are The amount of oil depends on other factors (e.g., increased octane requirements, higher oil concentrations, is limited by the pump's flow rate limitations) and further depends on the carrier oil chosen. Therefore, there is little room left for a practical answer.

本発明が基づくところの目的は、燃料に対する付加的添加剤として使われる時に 、清浄維持及び清浄性能に関してこれまでのところ使われている添加剤の有効性 を、より高い添加剤濃度を必要とすることなく、増大させる活性成分を得ること である。The object on which the invention is based is that when used as an additional additive to fuels, , the effectiveness of the additives used so far in terms of cleanliness maintenance and cleaning performance. of active ingredients without the need for higher additive concentrations. It is.

本発明による従来にない水素化された低揮発性活性成分の使用の結果、濃度の関 数としての最大有効性が、有効性における明確な改善の方向へ移動した。一方、 ベース添加剤は、従来のキャリアオイルと同し濃度レベル、かつ、同じ添加割合 に維持された。As a result of the use of unconventional hydrogenated low volatility active ingredients according to the present invention, concentration The maximum effectiveness as a number has moved in the direction of a clear improvement in effectiveness. on the other hand, Base additives are at the same concentration level and addition ratio as conventional carrier oils. was maintained.

本発明による活性成分の100°Cにおける粘度の範囲は4゜0か゛ら8.0c STであり、粘度指数は120から160である。The viscosity of the active ingredient according to the invention at 100°C ranges from 4°0 to 8.0°C. ST, and the viscosity index is 120 to 160.

本発明による活性成分の濃度は50から1000 pρ■/wtであり、特に重 要なのは200から800 ppm/1IItの範囲である。The concentration of the active ingredient according to the invention is between 50 and 1000 pρ■/wt, in particular The important range is 200 to 800 ppm/1IIt.

他のベース添加剤技術(マンニッヒ基剤、添加剤■)とスクシンイミド/ポリイ ソブチレン(添加剤■)の、異なるテストエンジン(MB M102E、レター  F2N。Other base additive technologies (Mannich bases, additives) and succinimide/polyyl Different test engines (MB M102E, letter) for sobutylene (additive ■) F2N.

トヨタカムリ及びBMW 528i) 、異なるテストプログラム、8つの異な る車のモデルでの路上テスト、さらに異なる燃料によるテストは、関与するベー ス添加剤に発明による活性成分を加えた結果として、有効性に改善を示した。Toyota Camry and BMW 528i), different test programs, 8 different Road tests on different car models, as well as tests with different fuels, are As a result of the addition of the active ingredient according to the invention to the gas additive, an improvement in effectiveness was shown.

以下に示す表は、異なる量の本発明による活性成分の付加による、従来の添加剤 r、n、mの有効性の平均的な改善を示している。この改善は異なる吸引バルブ テストにおいて達せられ、関与する従来の添加剤技術に対して「%の改善」のよ うに表示されている。これに対して、添加剤Iに従来のキャリアオイルを加える ことにより得られた改善はたった6%である。The table shown below shows the conventional additives with addition of different amounts of active ingredient according to the invention. It shows the average improvement in the effectiveness of r, n, m. This improvement has a different suction valve Achieved in testing, such as a “% improvement” over the conventional additive technology involved. The sea urchin is displayed on the screen. In contrast, adding a conventional carrier oil to Additive I The improvement obtained by this is only 6%.

活性成分を加えることによる有効性の増加本発明による活性 濃度 添加剤 成分の濃度(%) 改善(%)100% 添加剤I 50 12 ]00% 添加剤1 75 22 100% 添加剤1 100 38 ]00% 添加剤I 0 0 100% 添加剤II 100 29 100% 添加剤■ 0 0 100% 添加剤II[10011 基本的に本発明は、異なった化学技術による既知のガソリン添加剤に対して、有 効性を高める性質を持つキャリアオイルとしての、従来にない水素化された低揮 発性活性成分を使用することにある。上記有効性の改善は明らかにキャリアオイ ルの濃度の増加から期待されるものを越えており、それゆえ本発明による活性成 分の特質に帰するべきものである。Increased effectiveness by adding active ingredients Activity according to the invention Concentration Additive Component concentration (%) Improvement (%) 100% Additive I 50 12 ]00% Additive 1 75 22 100% Additive 1 100 38 ]00% Additive I 0 0 100% Additive II 100 29 100% Additive ■ 0 0 100% Additive II [10011 Basically, the present invention provides a unique Unconventional hydrogenated, low-volatility carrier oil with efficacy-enhancing properties. It consists in using active ingredients. The above improvement in effectiveness is clearly due to the carrier oil. exceeds what would be expected from an increase in the concentration of active ingredients according to the present invention. It is something that should be attributed to the characteristics of the individual.

本発明による活性成分の代表的仕様は、次の表に示されるとおり、水素添加分解 されたベースオイルのものである。Typical specifications for active ingredients according to the present invention are as shown in the following table: The base oil is

テ ス ト 方 法 最小値 代表値 最大値色、 ASTM D1500 < 0.5比重 g/ml D 1298 0.822 0.826 0.850引 火点 ’CD92 217 233 240流動点 ’CD97 −18 −2 0 粘度 40.0”CcST DIN 51562 24.3粘度100.0℃c sT DIN 51562 5.00 5.16 5.20粘度指数 D 22 70 145 149 153データシートA ガソリンエンジンの吸引機構清浄維持性能のためのガソリン添加剤であって、キ ャブレターの清浄及び清浄維持の優秀な性能を保証すると同時に、吸引バルブ内 の沈澱物を著しく削減することを目的とする。さらに、この添加剤は注入ノズル の清浄及び清浄維持の優秀な性能を提供する。Test method Minimum value Representative value Maximum value Color, ASTM D1500 < 0.5 specific gravity g/ml D 1298 0.822 0.826 0.850 Flash point 'CD92 217 233 240 Pour point 'CD97 -18 -2 0 Viscosity 40.0”CcST DIN 51562 24.3 Viscosity 100.0℃c sT DIN 51562 5.00 5.16 5.20 Viscosity index D 22 70 145 149 153 Datasheet A A gasoline additive for maintaining the cleanliness of the suction mechanism of gasoline engines. Guarantees excellent performance in cleaning and maintaining cleanliness of the suction valve. The purpose is to significantly reduce the amount of sediment. Additionally, this additive can be added to the injection nozzle Provides excellent performance in cleaning and maintaining cleanliness.

これらの性質は異なったガソリンに異なったヨー口・ンパのテスト方法を用いる テストによって証明された。これらはシノーR5キャブレター清浄性テスト、デ ジヨー205G7I注大ノズルテスト、オペルカデット、VWボロ及びメルセデ スベンツM102E吸引バルブテストを含む。These properties use different mouth and gas test methods for different gasolines. Proven by testing. These are Shino R5 carburetor cleanliness tests, Jyo 205G7I large nozzle test, Opel Kadett, VW Boro and Mercede Includes Sventz M102E suction valve test.

これらの結果は、もし推奨濃度で使われるなら、添加剤■は吸引機構の清浄性を 完全に制御できるということを確認するものである。吸引機構の沈澱物の除去に より、動作性を改善し、燃料消費を削減し、性能を復活させ、排気放射を削減す ることができる。These results indicate that, if used at the recommended concentrations, the additive ■ improves the cleanliness of the suction mechanism. It confirms that you have complete control. For removing sediment from the suction mechanism Improve operability, reduce fuel consumption, restore performance and reduce exhaust emissions. can be done.

推奨濃度: 物理的: 15°Cにおける比重: 890 g/kg粘度 40’C: 95cST O°C1100cST 引火点、PMCC,”C47 化学的データ: 窒素1重量% 0.42 データシートB 代表的解析データ テス ト 方法 最小値 代表値 最大値色、 ASTM D1500 2.5 COC引火点 ’CD92 246 PM引火点 ’CD92 228 流動点 ”CD97 −9 −6 粘度 40.0°CcST DIN51562 81 85.5 89.0粘度 100.0’CcsT DIN51562 10.3粘度指数 D 2270  102 102ラムスポトム残留 0.15 炭素 重量% 硫黄 重量% D 2622 0.70補正書の写しく翻訳文)提出書 (特許法第184条の8) 平成 6年 2月25日Recommended concentration: Physical: Specific gravity at 15°C: 890 g/kg Viscosity 40’C: 95cST O°C1100cST Flash point, PMCC, “C47 Chemical data: Nitrogen 1% by weight 0.42 Data sheet B Representative analysis data Test method Minimum value Representative value Maximum value Color, ASTM D1500 2.5 COC flash point 'CD92 246 PM flash point 'CD92 228 Pour point "CD97 -9 -6 Viscosity 40.0°CcST DIN51562 81 85.5 89.0 Viscosity 100.0’CcsT DIN51562 10.3 Viscosity Index D 2270 102 102 Lumspotom residual 0.15 Carbon weight% Sulfur weight% D 2622 0.70 Copy and translation of amendment) Submission form (Article 184-8 of the Patent Act) February 25, 1994

Claims (1)

【特許請求の範囲】 1.ガソリンエンジンの吸引機構の清浄維持性能の改善、及びガソリン添加剤の コスト対利益の比率の最適化のための、添加剤技術における水素化された低揮発 性活性成分の使用。 2.以下の仕様の活性成分としての水素添加分解されたベースオイル。 テスト 方法 最小値 代表値 最大値色,ASTM  D1500  <0. 5比重g/ml  D1298  0.822 0.826 0.850引火点 ℃    D92    217   233   240流動点℃    D 97    −18   −20粘度40.0℃ cST    DIN515 62 24.3粘度100.0℃cST    DIN51562 5.00  5.16 5.20粘度指数    D2270  145      149   153[Claims] 1. Improving the cleanliness maintenance performance of the suction mechanism of gasoline engines and improving the cleanliness of gasoline additives. Hydrogenated low volatility in additive technology for optimization of cost-benefit ratio Use of sexually active ingredients. 2. Hydrogenated base oil as active ingredient with the following specifications. Test method Minimum value Representative value Maximum value Color, ASTM D1500 <0. 5 Specific gravity g/ml D1298 0.822 0.826 0.850 Flash point ℃   D92   217  233  240 Pour point ℃   D 97 -18 -20 Viscosity 40.0℃ cST DIN515 62 24.3 Viscosity 100.0℃cST DIN51562 5.00 5.16 5.20 Viscosity Index D2270 145 149 153
JP5504100A 1991-08-27 1992-08-14 carburetor fuel additive Pending JPH06510072A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4128381,3 1991-08-27
DE4128381A DE4128381A1 (en) 1991-08-27 1991-08-27 CARBURETTOR FUEL ADDITIVE
PCT/EP1992/001862 WO1993004147A1 (en) 1991-08-27 1992-08-14 Carburetor fuel additive

Publications (1)

Publication Number Publication Date
JPH06510072A true JPH06510072A (en) 1994-11-10

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP5504100A Pending JPH06510072A (en) 1991-08-27 1992-08-14 carburetor fuel additive

Country Status (5)

Country Link
EP (1) EP0600953A1 (en)
JP (1) JPH06510072A (en)
AU (1) AU2413192A (en)
DE (1) DE4128381A1 (en)
WO (1) WO1993004147A1 (en)

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DE19804756A1 (en) * 1998-02-06 1999-08-12 Basf Ag Solid fuel additives

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AU2413192A (en) 1993-03-16
EP0600953A1 (en) 1994-06-15
DE4128381A1 (en) 1993-03-04
WO1993004147A1 (en) 1993-03-04

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