JPH06341009A - Processing of jute fiber and processed article of banana fiber - Google Patents

Processing of jute fiber and processed article of banana fiber

Info

Publication number
JPH06341009A
JPH06341009A JP5165850A JP16585093A JPH06341009A JP H06341009 A JPH06341009 A JP H06341009A JP 5165850 A JP5165850 A JP 5165850A JP 16585093 A JP16585093 A JP 16585093A JP H06341009 A JPH06341009 A JP H06341009A
Authority
JP
Japan
Prior art keywords
fibers
fiber
jute
water
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5165850A
Other languages
Japanese (ja)
Inventor
Tomoji Tanaka
友爾 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP5165850A priority Critical patent/JPH06341009A/en
Publication of JPH06341009A publication Critical patent/JPH06341009A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/20Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen
    • D06L4/22Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents
    • D06L4/24Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents using chlorites or chlorine dioxide
    • D06L4/26Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen using inorganic agents using chlorites or chlorine dioxide combined with specific additives

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Paper (AREA)

Abstract

PURPOSE:To obtain pure-white, tough and soft jute fibers by bleaching jute fibers at low temperature, washing with water, treating with lactic acid, an organic acid and a lactic acid fermentation solution, opening. CONSTITUTION:Cultivated jute is collected, immersed in water, fermented and decomposed, bleached with water and lignin and tannin are removed from the jute with caustic soda and a peroxide. The dehydrated jute fibers are retreated with a peroxide, sodium percarbonate and a caustic alkali and centrifuged. The filtrate is electrolyzed, mixed with hydrogen peroxide and the jute fibers are bleached with a ClO2<-> solution as a bleaching solution and repeatedly dehydrated and washed with water. The jute fibers are treated with a lactic acid solution or a fermented lactic acid and optionally a monochloroacetic acid, dehydrated, washed with water and single fibers are opened in water by a combing and carding machine. The jute fiber is mixed with silk fiber and synthetic fiber, twisted, made into cloth or woven fabric and dyed or printed.

Description

【発明の詳細な説明】Detailed Description of the Invention

この発明は、従来の黄麻繊維が主として穀物の包装袋と
して、その他、敷物、壁布として多く使用されたが、そ
の主たる用途が包装袋に限られていた為、最近の合成繊
維クロスの代用袋に取って変わられ、その穀物への使用
が極端に減少し黄麻栽培の労力と手間のかかる産業は衰
退の一途をたどり、その新しい需要の開発が必要であっ
たが、剛毛で着色性が強い為に同じ麻でもグリーンラミ
ー麻繊維の様な靭軟性のある漂白しやすい長繊維の様な
衣類への用途には使用しえない欠点があったものを、純
白の漂白が低温で繊維の分解も少なく処理されたが、剛
毛性は失われないので、これを更に、水洗後に乳酸、有
機酸、乳酸発酵液で浸漬した靭軟性の繊維を水洗し、脱
水乾燥する以前に疎開して単繊維化して生糸や合成繊
維、綿花、羊毛繊と水液中で混合して混抄して、これを
一定量の混束を撚糸機に掛けてモノフラメント撚糸に加
工せしめ乾燥し又は、そのまま半乾燥の状態で紡繊する
時は、布地、繊布が作られる。これを更に、捺染又は、
プリント印刷して模様を印刷せしめたものは衣類やイン
テリア関係に利用され、建築壁材としても多くの用途が
開発される事を特徴としたものである。一般の黄麻は斜
陽産業として衰退の一途をたどっている加工栽培商品で
あるが、インドやパキスタン、スリランカ、中国では国
営企業が多く、その新企用途の開発によってその企業の
安定性を計ろうとしているが、この黄麻は、元々染黄色
に着色し、その脱入ろは容易ではなく、特に、粘土質に
よる繊維の沈着は製紙原料としても多くの欠点問題があ
り、しかも、剛毛である為綿花の様な繊維の縮み合が殆
どなく単繊維間の縮み合いがないから長尺のモノフラメ
ントの生産は困難であり、着色が難しく、脱色し易い欠
点があり、穀物をいれる包装袋に限定され、極めて太い
モノフラメントによって紡繊されていた為、その重量は
重く着色の繊細性に欠けていてその用途は自ら限界があ
った。しかし、麻の需要は根強く、和し原料やライス
紙、コンデンサー紙、紙紙幣に使用するには靭軟性のあ
るコウゾ、ミツマタやマニラ麻等が多く使用されてい
た。この為、この黄麻繊維を微生物で発酵して、繊維を
解束して軟化せしめる方法が一般に使用されていたが、
多量生産には問題があり、設備が膨大化する欠点があっ
た。又、この処理には時間がかかり過ぎる欠点があっ
た。そして、この黄麻を処理するには先ず、脱リグニ
ン、タンニンを行う必要がありミツマタやコウゾ繊維の
様に苛性アルカリで煮沸処理する時は、黄色はこの液に
よって二次的に繊維を黄色に着色して純白の繊維は得ら
れない為、次亜塩素カルシウムや次亜塩素ソーダーで加
熱処理して脱色を行っていたが、これでも黄色は取れな
い欠点があり、特に、繊維本来のフシ目の内部に浸透し
た粘土コロイド質は漂白剤では脱色出来ない欠点があ
り、製紙原料としては斑点ができ紙の品質が低下した。
そこで、常温漂白として、CLO2液とグリオキザール
液と過酸化水素液で軽く脱色した繊維を水洗いして乳酸
液や発酵乳酸液、有機酸液又は、モノクロール酢酸液で
浸積後、水洗いして脱酸する時は、繊維中の着色液は溶
出し、純白の軟質の繊維質が得られる。そして、脱皮困
難な皮殻質も除去される。この黄麻繊維は、まだ皮質繊
維の集束体を形成しているのでクシスキ機で繊維を繊維
芳香にスキ込む時は、長い単位繊維に変化し、脱落した
繊維は短繊維として製紙原料に使用する。この時に生じ
る短繊維は10%まであり、この短繊維に合成繊維、真
綿や生糸綿を混合して撚糸を行う時は、縮み合いが真綿
や生糸綿やその他の合成繊維によって向上して撚糸加工
が容易となり、染色に良い結果を作るので、撚糸原料に
も利用されるが、この黄麻の純白短繊維を綿と共に反毛
して混合してガーターに掛けて紡ぎ機で撚糸加工する時
は、混紡綿が出来るから撚糸の引っ張り強度は2倍以上
に強化される。次に、前記、長繊維に長繊維の生糸や合
成繊維を混紡した撚糸は、極めて細くて強靭な繊維が得
られるから撚糸し集束したものを衣料モノフラメントと
して紡織した布地や織布を作る時は、冬は暖かく、夏は
発汗に対して乾きやすい性質の織ぬのが得られ、一般の
酸性染料や塩基性染料にも染色しやすい織布が得られ
る。又、綿花や合成繊維と混紡した繊維も同様な結果を
得るばかりでなく、炭素繊維や金属繊維との混紡も前記
混紡によって加工が容易となる。そして、これらの繊維
を弦線にクローム、ゼラチン又は、ゼラチン固化したも
のを使用すると、生糸の弦より強靭なものが得られるば
かリでなく、キトサン乳酸液やポリビニールアセタール
液で処理して、皮膜を形成せしめたものは耐久姓の高い
撚糸が得られるが、防菌剤や防腐剤を混合し添加したも
のを塗布せしめたものは、ダニ除けとして効果があり、
カビ止めとしても有効である。又、壁布として、プリン
トした模様布はインテリア関係に使用され、起毛すれば
ジュータンとして利用され、人造皮革の原料布地として
も利用されるばかりでなく、屈曲強度が高いので自動車
用レザーとして有用である。そして、ジュート純白短繊
維は製紙原料として特に、オムツ紙にいれる時は、水切
れが良く、他のグリーンラミーやマニラ麻等にも代用さ
れるばかりでなく、ガラス繊維と混抄したものは、コー
シ材料として音響効果があり、メラミン、フェノール、
尿素樹脂の担体として、又、合成樹脂の強化材として有
用である。特に、空気フィルターや自動車排気ガスフィ
ルターに使用する時は、流動抵抗が小さく、耐熱性で瀘
紙として使用する時は、耐久性が保持される。この繊維
は他の綿花や木材パルプと異なり剛性があり、分解性が
少なく、耐久性に富んでいるので紙幣の原料や電線巻紙
にも使用され、プラスチックス芯材にも利用される。こ
の繊維をアルカリで処理したアルカリ繊維を沃化エチー
ルや臭化エチルで180℃で処理したエーテル化繊維は
プラスチックスの原料となり、オシメカバー紙の表面加
工紙にも利用される。この様に、黄麻繊維をより用途の
広い分野に利用するには、本来の欠点である、黄麻を純
白な麻に漂白する技術を本来の剛性による繊維の縮み合
いの少ない性質を靭軟化せしめ単繊維に分解しやすくす
る必要があり、前者の漂白について加熱漂白では繊維が
団子状に今塊化する欠点を常温処理で行う必要がある。
この為には、アルカリ処理でなく過酸化物による処理が
必要であり、公害排水として回収利用を電解によって行
う必要がある。又、発酵菌による繊維分解法では時間が
かかり過ぎる欠点があり、乳酸、有機酸モノクローム酢
酸の鷹揚によって、この処理時間を短縮した。そして、
一般にとれない汚水となる粘土、コロイド質の付着を剥
離する作用があるので、純白な黄麻が加工され、これら
は、高価なグリーンラミーやマニラ麻に代用され、又、
併用によって生産性を向上し、原価を低下する利点があ
る。又、従来加工されたジュート織布を過炭酸アルカリ
液に浸漬して、アルカリ水を電解回収し、脱リグニン、
タンニン濃縮液を回収して皮靭剤に利用し、又、バニリ
ンの原料に使用すると共に、水洗いした脱リグニン、タ
ンニン繊維布を水洗いし水で漂したものをCLO2過酸
化水素、グリオキザール水で常温処理したものを水洗い
して過炭酸ソーダーで処理したものを水洗いして乳酸
液、有機酸、モノクローム酢酸で処理して水洗いしたも
のを乾燥したものは、インテリアクロスとして壁材にプ
リント印刷して使用され、合成皮革の基材布として又、
ジャンバー衣料やネクタイ、洋服の芯材や敷物の基材と
して利用され、しかも剛毛性が靭軟性となり、又、この
従来の黄麻のモノフラメント撚糸紐を漂白加工したもの
は、織布の撚糸として衣布の原料糸として利用される。
特に、この漂白と乳酸加工によって従来の太いモノフラ
メントも脱タンニン、リグニン作用によって細いモノフ
ラメントに加工されるので紡織原料撚糸としてその利用
度は高く、衣類や装飾品、ハンドバック、床布等にも利
用され、その用途は拡大し、斜陽産業の体質を著しく改
善し、産業上有用な発明である。又、この処理はバナナ
繊維加工にも応用される。この発明の実施要領を図面に
よって、説明すると次の如くである。
In the present invention, the conventional burlap fiber was mainly used as a packaging bag for grains, and also as a rug or a wall cloth, but its main use was limited to the packaging bag. , Its use in cereals has been extremely reduced, and the labor and labor-intensive industry of burlap cultivation has been on the decline, and it has been necessary to develop new demand for it, but it is bristle and strongly colored. Therefore, even if it is the same hemp, it has a drawback that it can not be used for clothing such as long ram that is liable to bleach like green ramie fiber and easily bleached, but bleaching with pure white decomposes fiber at low temperature However, since it does not lose its bristleness, it is further washed with water to wash the tough and soft fibers soaked with lactic acid, organic acid, and lactic acid fermented liquid, and then loosened before being dehydrated and dried. It is made into raw silk, synthetic fiber, cotton, wool fiber, etc. When mixed and mixed in a liquid and mixed, a certain amount of a bundle is applied to a twisting machine to be processed into a mono-flamented twisted yarn and dried, or when the fiber is spun in a semi-dried state as it is, a fabric or a fiber cloth is used. Made This is further printed or
Printed and printed patterns are used for clothing and interiors, and are characterized by being used for many purposes as building wall materials. Common jute is a processed and cultivated product that is declining as a slant industry, but there are many state-owned enterprises in India, Pakistan, Sri Lanka, and China, and they are trying to measure the stability of those enterprises by developing their new uses. However, this jute originally has a dyed yellow color, and its removal is not easy. In particular, the deposition of fibers due to the clay nature has many drawbacks as a raw material for papermaking, and because it is bristle, cotton Since there is almost no fiber shrinkage like this and there is no shrinkage between single fibers, it is difficult to produce long mono-fractions, there are drawbacks that coloring is difficult and it is easy to decolorize, and it is limited to packaging bags containing cereals. Since it was spun by an extremely thick mono-fragment, its weight was heavy and lacked the delicacy of coloring, and its use was limited by itself. However, there is a strong demand for hemp, and in order to use it as a raw material for rice, rice paper, condenser paper, paper banknotes, Koso, Mitsumata, Manila hemp, etc., which have a softness, were often used. For this reason, a method of fermenting this jute fiber with microorganisms to unravel and soften the fiber was generally used,
There was a problem in mass production, and there was a drawback that the equipment became huge. Further, this treatment has a drawback that it takes too much time. In order to treat this jute, first, delignification and tannin must be performed, and when boiling with caustic alkali such as Mitsumata and Kozo fiber, yellow is used to secondarily color the fiber to yellow. Since it is not possible to obtain pure white fiber, it was decolorized by heating with hypochlorous calcium or sodium hypochlorite, but even this has the drawback that it does not remove yellow. The clay colloid that penetrated inside had the drawback that it could not be decolorized with a bleaching agent, and as a papermaking raw material there were spots and the quality of the paper deteriorated.
Therefore, as room temperature bleaching, the fibers lightly decolorized with CLO2 solution, glyoxal solution, and hydrogen peroxide solution are washed with water, immersed in lactic acid solution, fermented lactic acid solution, organic acid solution, or monochloroacetic acid solution, and then washed with water to remove. When acidified, the colored liquid in the fibers is eluted and pure white soft fibers are obtained. And the skin quality that is difficult to shed is also removed. Since the burlap fibers still form a bundle of cortical fibers, when the fibers are mixed into a fiber aroma by a combing machine, they are converted into long unit fibers, and the dropped fibers are used as short fibers for a papermaking raw material. The short fibers produced at this time are up to 10%, and when mixing synthetic fibers, cotton or raw cotton into twist fibers, the shrinkage is improved by the use of genuine cotton, raw cotton or other synthetic fibers, and twist processing It is also used as a twisting raw material because it makes it easy to dye and it is also used as a twisting raw material, but when this pure white short fiber of jute is fluffed and mixed with cotton and hung on a garter and twisted with a spinning machine, Since the blended cotton can be produced, the tensile strength of the twisted yarn is more than doubled. Next, since the twisted yarn obtained by mixing the raw fibers of the long fibers with the raw fibers of the long fibers or the synthetic fibers can obtain extremely fine and tough fibers, the twisted yarns and bundles are spun into a cloth or a woven fabric as a clothing monoflament. A woven cloth is obtained which is warm in winter at times and easily dries against sweating in summer, and can be easily dyed with general acid dyes and basic dyes. In addition, not only the same results can be obtained with fibers mixed with cotton or synthetic fibers, but also the mixed spinning with carbon fibers or metal fibers can be easily processed by the above-mentioned mixed spinning. Then, when these fibers are used for the chords of chrome, gelatin, or gelatin-solidified ones, it is not foolproof that they are stronger than raw silk strings, but they are treated with a chitosan lactic acid solution or a polyvinyl acetal solution, The one with the film formed can obtain a twisted yarn with high durability, but the one coated with the mixture of the antibacterial agent and the preservative is effective as a tick repellent,
It is also effective as a fungicide. In addition, as a wall cloth, the printed patterned cloth is used for interiors, and when raised, it is used as jutan, not only as a raw material fabric for artificial leather, but also because it has high bending strength, it is useful as automotive leather. is there. And, jute pure white short fiber is especially used as a papermaking raw material, especially when it is put in diaper paper, it drains well, and it is not only substituted for other green ramie, Manila hemp, etc., but also mixed with glass fiber, it is used as a koshi material. There is a sound effect, melamine, phenol,
It is useful as a carrier for urea resins and as a reinforcing material for synthetic resins. In particular, when it is used for an air filter or an automobile exhaust gas filter, it has a low flow resistance, and it has heat resistance, and when it is used as a paper filter, its durability is maintained. Unlike other cotton and wood pulp, this fiber has rigidity, is less degradable, and is highly durable, so it is also used as a raw material for banknotes, wire wrapping paper, and as a plastic core material. The etherified fiber obtained by treating the alkali fiber with alkali with ethyl iodide or ethyl bromide at 180 ° C. serves as a raw material for plastics and is also used as a surface-treated paper for omeme cover paper. In this way, in order to use jute fiber in a wider range of fields, the essential drawback is that the technique of bleaching jute into pure white hemp is used to soften the nature of the fiber with less shrinkage due to its original rigidity. It is necessary to make it easy to decompose into fibers, and in the former case of bleaching, it is necessary to carry out the defect that the fibers are agglomerated in the form of dumpling at room temperature.
For this purpose, a treatment with a peroxide is required instead of an alkali treatment, and it is necessary to collect and utilize it as pollution wastewater by electrolysis. In addition, the fiber decomposition method using a fermenting bacterium has a drawback that it takes too much time, and the processing time was shortened by levitation of lactic acid and organic acid, monochrome acetic acid. And
Since it has the action of removing clay, which becomes sewage that is not generally taken away, and the adhesion of colloidal substances, pure white burlap is processed, these are substituted for expensive green ramie and Manila hemp, and also
The combined use has the advantages of improving productivity and reducing costs. Also, a conventionally processed jute woven fabric is immersed in an alkaline percarbonate solution to electrolytically recover alkaline water, delignification,
The tannin concentrate is recovered and used as a toughening agent and also as a raw material for vanillin, and the delignified water that has been washed with water, the tannin fiber cloth that has been washed with water and floated in water are then washed with CLO2 hydrogen peroxide and glyoxal water at room temperature. The treated one is washed with water and treated with sodium percarbonate, washed with lactic acid, organic acid, and monoacetic acid and washed with water. As a base fabric of synthetic leather,
It is used as a base material for jumpers, ties, cores and rugs for clothes, and has bristleness that is tough and soft.In addition, the bleached monofilament twist string of conventional burlap is used as a woven thread. Used as a raw material thread for clothing.
In particular, this bleaching and lactic acid processing makes it possible to process conventional thick monofragments into thin monoflaments by detannining and lignining action, so it is highly used as a twisted yarn for textile materials, and is used for clothing and decorations, handbags, floor cloths, etc. It is also used for industrial purposes, its application is expanded, the constitution of the oblique sun industry is remarkably improved, and it is an industrially useful invention. This treatment is also applied to banana fiber processing. An embodiment of the present invention will be described below with reference to the drawings.

【図1】はフロシート図を示し、(A)は従来の工法で
作った織布や撚糸を漂白し、純白布、同撚糸を作ったも
ので、(B)は直接栽培地で黄麻を漂白、乳酸加工した
ものを示したものである。
[Fig. 1] shows a flow sheet diagram, (A) bleached woven fabric and twisted yarn made by a conventional method, and made pure white cloth and same twisted yarn. (B) Bleached jute directly in the cultivation area. , Lactic acid processed.

【図2】f黄麻の栽培地での処理工程図を示す。ピット
(1)(2)(3)(4)(5)(6)に20%苛性ア
ルカリ水5トンを入れ、過酸化水素水、又は、過炭酸ソ
ーダー100kgを入れて原料の生黄麻を篭(7)
(8)(9)(10)(11)(12)にそれぞれ50
0kgをいれて、浸漬する。浸漬液温は、25〜45℃
である。浸漬時間は3日間とする。この搬送には、上部
レール(13)によって滑車(14)によって上下昇降
し、移動する仕組になっている。3日間の浸漬が終われ
ば、ポンプで浸透したアルカリ水の抽出液をポンプで電
解槽(15)に送り隔膜(16)電解を行い陰極のアル
カリ水液は、パイプ(17)でポンプ(18)から貯液
槽(19)にアルカリ抽出液を貯液し、ポンプ(18)
でピット(1)(2)(3)(4)(5)(6)に再生
アルカリ液を送り、浸漬を続ける。浸漬1日後レールを
通じて篭(7)(8)(9)(10)(11)(12)
を通じて移動し、水洗いビット(19)(20)に浸漬
して水洗いし、そのアルカリ水液は、電解槽(21)
(22)に於いて脱アルカリして、アルカリを回収して
最初のアルカリ水液に導入し、再使用する。電解槽(1
9)(20)の陽極室(C)(C’)内の電解酸性液
は、黄麻原料の予備的殺菌処理に使用されて水槽(2
3)中に貯水されて生黄麻の呼び浸積して使用され、黄
泥の付着物を除去するが、排出する水は水で稀釈して放
水するこの電解槽(21)(22)の陰極室(D)
(D’)のアルカリ水液は、アルカリ水液として再生利
用し黄麻の浸漬水に利用する。最初のアルカリ液で処理
された黄麻は遠心分離器(E)で脱水されて、排水に
(E’)から濾液は電解槽(15)にパイプで導入し、
陽極酸化と脱アルカリ化が行われると共に遠心分離器
(E)中で水洗いを同時に行い、一次精製黄麻を取出し
水洗槽(19)(20)によって5時間水洗いしたもの
を(F)の遠心分離器で脱水して、その瀘液は電解槽
(22)(21)に導入されて隔膜電解されてアルカリ
液を陰極室(D)(D’)で回収し、再利用する。次に
水洗いされた黄麻は更に、10%の塩酸水槽(23)に
浸積し、10時間後に取り出し、乳酸又は、モノクロー
ル酢酸5%液中で脱塩酸後、浸積槽(24)中で浸漬
し、10時間後に純白になった時に遠心分離器(G)で
脱水処理し、濾液は貯液タンク(25)に貯水して電解
槽(26)で陽極室(C”)に導入して乳酸を回収濃化
したものを、ポンプで乳酸槽(24)に戻して再利用す
るが乳酸を石灰で中和して乳酸カルシウムとして回収
し、乳酸濃度を調整する。この乳酸カルシウムは塩酸液
で回収して塩酸乳酸混合液で処理するが、黄麻のアルカ
リ処理後の水洗いを経た黄麻を、この液で処理する時
は、乳酸の節減ともなるが、塩化カルシウムの副生物の
除去には水洗いが必要である。水洗水は、石灰で中和し
て乳酸カルシウムを回収し、塩酸は塩化カルシウムとし
て水洗い除去する。この塩酸中和槽(26)で中和した
瀘液は、中性化して排出し遠心分離器(H)で脱水した
乳酸カルシウム石灰泥物は回収して、乳酸液に再利用す
る。この乳酸カルシウムは酸分解槽(27)に導入され
て塩酸又は、硫酸で中和して乳酸を回収する。乳酸液槽
(24)で脱水された黄麻は、遠心分離器(27)で脱
水された後、乾燥室(28)で半乾燥され水分が50%
に達した中に、クシスキ機(29)でスキ取り、単繊維
にスキ取る。そして、副性する短繊維は回収し、漂白黄
麻の長繊維を採集し、これに生糸、合成繊維を混和し撚
糸機(30)で撚糸し、モノフラメントを作り、これを
ボビンに巻取機(31)でボビン巻として紡織機(3
2)で処理して布地に加工する。又、クシスキ機(2
9)でスキ取る時に生ずる短繊維は、乾燥し、綿花や短
合成繊維、ガラス繊維、炭素繊維、金属繊維と混合して
反毛機に掛けた後、混合機でガーター機で綿層を作り、
これを細分化して撚糸機に掛け、モノフラメントを作り
ボビン巻して紡織機で布地に加工する。西陣織の様な織
機に使用するモノフラメントは、常法に従って捺染し、
又は、金銀糸線状に加工したモノフラメントに再加工し
て、錦織地を作る。この漂白黄麻の長繊維は、スキ機
(29)でスキ取った繊維をロータリーカッターでカッ
ターした短繊維は和紙の原料に利用されるばかりでな
く、起毛繊維として着色したものを、代用ジュータンに
電気起毛機で起毛接着剤で繊維布に塗布した面に起毛し
て固着せしめて作る事が出来る。一般公知の黄麻の未漂
白繊維より成るモノフラメントは、黄麻繊維束を界面活
性剤と混合した機械油で吹き付けてスタンピング機械に
掛けて、繊維を物理的に軟化せしめて靭性の繊維束とし
て繊維を単離化したものを撚糸機で太いモノフラメント
化したものを紡織機で紡織して、クロス布地を作ってい
たが、これらの繊維では黄褐色泥色の着色布地や太いモ
ノフラメントしか出来ないから、、ソノリウムの裏地、
履利やドンゴロス袋や畳表の縫糸に限定され、その用途
が限られていた。しかし、この公知のモノフラメントや
クロス布地を、更に漂白再加工する時は、その用途は飛
躍的に拡大される。そして、太いモノフラメントの脱リ
グニン、タンニン化を前記方法でアルカリ浸漬処理し、
過酸化物アルカリで漂白した後、水洗いして乳酸処理で
処理し水洗乾燥したものは、脱リグニン、タンニン化に
よって太さは、細化して重量も20〜25%減量して純
白なモノフラメントになるから、これを染料で捺染した
モノフラメントは、最初の太さが3粍のものが1粍に細
化され、鮮明な着色モノフラメントが出来るのでインテ
リア関係の壁布用に利用され、衣類用にも供される。こ
の細化繊維をポリビニールアセタール化樹脂や繊維素エ
ーテルや桐油で処理して固化せしめる前に、起毛面を研
磨して取り去り伸延しながら乾燥した細分化せしめたモ
ノフラメントは強靭性でポリアミド繊維と同一の引張り
強度を示すから、電線の強化材として被服や芯材に利用
される。又、黄麻クロス布は漂白する事によって、やや
薄黄色のものから純白なものまで加工でき、その表面に
プリント印刷や捺染が出来るので、衣類や壁布、レザー
や合成皮革の裏地や洋服やネクタイの裏地の強化布とし
て利用され、履物等の表面紙に利用され、キャパスの下
地やハンドバック、テント布地等にも利用される。しか
し、この漂白加工に於ける従来の黄麻モノフラメントや
クコス布は処理する事によって30%収縮するので、加
工に際しては収縮分だけ余分に布幅や布長を計算に入れ
る必要がある。又、この漂白モノフラメントにポリエチ
レンパウダーを塗布いる時は、加熱加工によって防水性
が改善され、一般のパルプや線質が200℃以上で老化
する欠点を300℃に於いても変化がないので、耐熱性
として樹脂加工に多く利用される。ポリエステルや尿素
樹脂、フェノール、メラミン樹脂の芯材に使用する時に
油性やシリコン樹脂やボラン液で処理した乾燥物を使用
する時は、芯材の強度を15ぇも増大する特徴がある。
又、この漂白黄麻繊維をグリーンラミー繊維と紡織する
時は、その生産原価が■■■■のものが■■■■以下に
低下するので、極めて安価な商品に加工されるばかりで
なくグリーンラミー繊維自身も漂白が不充分であるの
で、黄色化しているものをこの漂白方法で純白化する事
が出来るので、グリーンラミー繊維の品質向上にも役立
つ。又、マニラ麻の様なロープ素材の代用品としても漂
白によって純白のロープができる。又、バナナ枝の繊維
を加工した長短繊維も黄麻と同様に処理される。又、こ
の電解透析に於ける電解電極は、シリコン、マンガン電
極やシリコン電極を使用し、隔膜としてはアルミナ繊維
布に弗化樹脂をラミネートした膜やポリビニール樹脂多
孔質が使用されるが、ポリ塩化ビニール樹脂に多孔化材
として尿素グライコールや硼酸エステルが使用される
が、これに、発泡剤のヂアゾ化合物の 厚い隔膜としては、炭酸カルシウム粉にエチレングライ
コールや尿素グライコールを混合したポリビニール樹脂
を硬化せしめた後、塩酸で処理した膜が使用される。
又、セラミックとしては、SiO246% AL2O3
38% CaO 8%Na2O 4% その他の高ア
ルミナ焼結体が使用される。この電極電力は燃料電池や
一般業務電力が使用されるが、電解電力を少なくする為
には、100気圧の高圧ガス中での電解透析が行われる
が、この時の隔膜には高圧アルミナセラミックやゲルマ
ニウムセラミックや焼結金属板が使用される。この電解
透析の20ボルト1アンペアーの電力が使用されるが、
この電解透析の高圧電解は電力量は1/10まで低下す
る。燃料電池はコンクの燐酸液で天然ガスが燃料として
低温分解した水素ガスが使用されるが、電極としてシリ
コンマンガンやシリコン焼結電極の表面に白金鍍金した
ものが使用される。陽極面に送る酸素ガス一般に空気が
使われるが、5%の酸素ガスとの混合ガスを使用される
が、この多孔板焼結板にモナズ石を付着せしめる時は、
ガスのイオン化が促進される。この電解電力は、2.4
Kw/1ton の割合で行われる。そして、アルカリ
液の浸漬ピットはコンクリートにタールピッチをライニ
ングしたものが使用されるが、各ピットはガラス繊維や
ナイロン繊維束が毛細管として次のピットに逆U字状と
して各ピットを循環して、最後のピットにポンプで排水
して電解槽に入る様にしてあるので、自動的に浸漬アル
カリリグニン、タンニン質糖液が移動し、電解される。
そして、そのリグニン、タンニン液は濃縮して回収され
る。この様に電解法では排水の浄化が行われるので公害
性を改善し、アルカリ性分の30〜60%が回収され
る。又、漂白地が海岸線近くでは海水液が使用され、漂
白にはこの電解液の陽極室の液が使用されると安価な生
産コストで漂白が出来る。又、乳酸液を軟化剤として繊
維の仕上げに利用すると、繊維の解疎化を促進すると共
に、タンニン酸で薄く染められた繊維の黄色は脱色さ
れ、又、泥コロイド沈着物や皮の剥離部分が剥離され、
繊維をアルカリだけで処理して漂白した時に残る黄褐色
の斑点を除去する効果があるばかりでなく、硫酸や塩酸
でアルカリ性を中和した繊維の様な硬化繊維やグリオキ
ザールとCLO2で処理した漂印に於ける繊維の硬化性
が予防される。この繊維の硬化性による欠点は、繊維を
解離して単繊維に加工る時は、クシスキ機によって繊維
は切断されやすく、長繊維の単離したものは得難いの
で、乳酸や有機酸が使用される。又、黄麻の生産地では
河川地帯がその栽培地であり、栽培後生産された黄麻を
採集したものは水漬して水中のバクテリアで分解して軟
質の黄麻を採集するが、この黄麻を更に加工するには、
30%の黄麻繊維の廃棄物が出来るが、これらの繊維を
アルカリ処理して漂白加工し、乳酸処理を行う時は、麻
パルプの減量が得られ、瀘紙や和紙の減量として又、オ
シメ紙の表面カバー紙として利用されるから現地での一
貫した作業はより効果的である。又、この方法では従来
法と異なり、常温で脱リグニン、タンニンを行うので繊
維の損傷が少なく加熱によって団子状繊維となる欠点を
補い、従って生産歩留も低温処理によって10%も向上
する。又、グリオキザールは漂白速度を高めると共に繊
維を硬化せしめるので、モノフラメント撚糸の強化に利
用されガラスやセラミック繊維の混合撚糸には硬化性が
著しいからポリエステルの強化繊維として使用される。
このポリエステル加工にはボラン処理やポリビニールア
セタール化樹脂が前処理されるとより効果的となる。
又、この黄麻繊維はコウゾ、ミツマタの代用品として利
用されるので和紙のコストを低下させる利点があるばか
りでなく、寿命が長く、老化性がパルプの様に起こらず
保存中、バラバラに破ける事がないのでコンデンサー紙
やコピー紙用に利用され、セラミックや合成繊維との混
抄が出来るので油の瀘過材や空気のフィルターとして
又、パッキング材として使用されるばかりでなく、吸音
効果が高く、断熱性なので断熱建材板として利用される
ほか、石膏ボードや壁土のスサ材として、又、コンクリ
ートのスサ材として利用される。この黄麻の長繊維は、
長さが3メートルから5メートルのものまであり、生糸
とは相容性があり、繊維の絡み合いにも黄麻単独のもの
より引張り力が高く、合成繊維の長繊維ともよく混和す
るが、クシスキ機に掛ける時に、一般黄麻にソフト21
の界面活性剤に油を混合した液やポリアクリル酸ソーダ
ー液で解踈せしめる時は、繊維の切断は少ないので量産
化の時はこの方法を1部利用する事も出来る。以上の如
く、この発明の特徴は従来の黄麻が剛毛性で加工中に短
繊維化されやすい欠点を黄褐色の色彩を保持する為、鮮
明な着色が困難であり、又、黄麻繊維の多くが太い撚糸
しか加工出来ずその為、撚糸から紡織したクロス布も厚
みが厚く又、重く、保温性にも欠点があり多くの用途に
利用出来ない欠点のあったものを、グリーンラミーやマ
ニラ麻繊維の様に純白に漂白する技術を開発し、従来加
工するのに必要なボイラー加熱を必要とせず、比較的低
温で処理し、脱リグニン、タンニンを苛性アルカリだけ
でなく過酸化物の併用によって行い、この液を隔膜電解
で回収したリグニン、タンニンは皮靭や香料の原料とし
て利用し、アルカリ成分は回収して、黄麻繊維のアルカ
リ処理に再利用して排水公害を改善せしめ、繊維の軟化
として、有機酸や乳酸、モノクロール酢酸を仕上げと中
和剤として使用する事によって、繊維のソフト化を単繊
維解離に利用する事によって、長繊維の収量を増大し短
繊維の収量を抑制し、必要に応じて過酸化物とグリオキ
ザールLO2との使用によって純白に漂白せしめる事に
よって、高価なグリーンラミー繊維に匹敵する純白繊維
に加工するので低廉な衣類や布地が作られる。この結
果、捺染やプリント印刷が鮮明に行われるので黄麻の用
途が穀物の包装袋に利用されていたものが、衣類やイン
テリア関係にも利用され、和紙原料として工業用粗材に
使用されると共に水切れがよいのでフィルターとして利
用され、耐久性のある和紙や複写コピー用紙の原料とし
て使用されるばかりでなく、長繊維と合成繊維や生糸や
ガラス繊維等の鉱物繊維と混和する事によって撚糸化が
容易となり、引張り強度が増大するので衣類や布地のほ
かにインテリア関係に利用され、特に、建材として又、
樹脂加工の強化材や電気材料として多くの用途が開発さ
れ、黄麻生産の斜陽化を改善し産業上有用な発明であ
る。又、バナナ繊維の加工にも応用されるので、パルプ
資源や衣料として有用である。
FIG. 2 shows a processing step diagram of f jute in the cultivated area. Fill pits (1) (2) (3) (4) (5) (6) with 5 tons of 20% caustic water, hydrogen peroxide solution or 100 kg of sodium percarbonate and put raw jute into the basket. (7)
50 for each of (8), (9), (10), (11), and (12)
Add 0 kg and dip. Immersion liquid temperature is 25-45 ° C
Is. Immersion time is 3 days. For this conveyance, the upper rail (13) moves up and down by the pulley (14) to move. When the immersion for 3 days is over, the pumped alkaline water extract is sent to the electrolytic cell (15) by the pump to perform the electrolysis of the diaphragm (16), and the cathode alkaline water solution is pumped by the pipe (17). The alkaline extract is stored in the liquid storage tank (19) from the pump (18)
Then, the regenerated alkaline liquid is sent to the pits (1), (2), (3), (4), (5) and (6), and the immersion is continued. One day after soaking, through the rail, baskets (7) (8) (9) (10) (11) (12)
And then wash it by immersing it in the washing bit (19) (20) and washing it with alkaline water.
In (22), the alkali is removed to recover the alkali, which is introduced into the first alkaline aqueous solution and reused. Electrolyzer (1
9) The electrolytic acid solution in the anode chambers (C) and (C ') of (20) is used for preliminary sterilization of jute raw material, and the water tank (2
3) It is stored in water and used by priming with fresh jute to remove deposits of yellow mud, but the discharged water is diluted with water and discharged, and the cathode of this electrolytic cell (21) (22) Room (D)
The alkaline water solution of (D ′) is reused as an alkaline water solution and used as immersion water for jute. The jute treated with the first alkaline solution is dehydrated in the centrifuge (E), and the filtrate from the drain (E ') is introduced into the electrolytic cell (15) by a pipe,
Anodizing and dealkalization are performed, and at the same time, water is washed in the centrifuge (E), the primary purified jute is taken out and washed in the water washing tanks (19) (20) for 5 hours, and then the centrifuge (F) is used. Then, the filtrate is dehydrated, and the filtrate is introduced into the electrolytic cells (22) and (21) and subjected to diaphragm electrolysis to recover the alkaline solution in the cathode chambers (D) and (D ′) and reuse it. Next, the washed jute was immersed in a 10% hydrochloric acid water tank (23), taken out 10 hours later, dehydrochlorinated in lactic acid or a 5% monochloroacetic acid solution, and then in an immersion tank (24). After being immersed and 10 hours later, when it became pure white, it was dehydrated by a centrifugal separator (G), and the filtrate was stored in a liquid storage tank (25) and introduced into an anode chamber (C ″) in an electrolytic cell (26). The concentrated and concentrated lactic acid is returned to the lactic acid tank (24) by a pump for reuse, but the lactic acid is neutralized with lime to be recovered as calcium lactate to adjust the lactic acid concentration. Although it is recovered and treated with a hydrochloric acid-lactic acid mixed solution, jute that has been washed with water after alkaline treatment of jute is treated with this solution, which also saves lactic acid, but to remove calcium chloride by-products, wash with water. The wash water should be neutralized with lime to remove calcium lactate. The hydrochloric acid neutralized in the hydrochloric acid neutralization tank (26) is neutralized, discharged, and dehydrated in the centrifuge (H) to recover calcium lactate lime mud. This calcium lactate is introduced into the acid decomposition tank (27) and neutralized with hydrochloric acid or sulfuric acid to recover lactic acid. The jute dehydrated in the lactic acid solution tank (24) is After being dehydrated in the centrifuge (27), it is semi-dried in the drying chamber (28) and has a moisture content of 50%.
While reaching the above, a combing machine (29) is used to scrape and single fibers are scraped. Then, by-product short fibers are collected, long fibers of bleached burlap are collected, raw silk and synthetic fibers are mixed and twisted by a twisting machine (30) to make a mono-flament, which is wound on a bobbin. Weaving machine (3)
It is processed in 2) and processed into a fabric. In addition, Kushiski machine
The short fibers produced during skimming in step 9) are dried, mixed with cotton, short synthetic fibers, glass fibers, carbon fibers, and metal fibers, and then applied to an anti-fluffing machine, then a cotton layer is formed with a garter machine with a mixing machine. ,
This is subdivided and put on a twisting machine to make a mono-flament, which is wound on a bobbin and processed into a cloth by a spinning machine. Mono-flamento used for looms such as Nishijin weave is printed according to the usual method,
Or, it is reprocessed into a mono-fragment processed into a gold-silver thread line, and a brocade fabric is made. The long fibers of this bleached burlap are not only used for the raw materials of Japanese paper, but the short fibers cut with a rotary cutter from the fibers skived by a skiing machine (29) are also used as colored fibers for the replacement jutan. It can be made by raising and fixing on the surface coated on the fiber cloth with a raising machine with a raising machine. The generally known mono-fragment composed of unbleached jute fibers is made by spraying jute fiber bundles with a mechanical oil mixed with a surfactant and applying them to a stamping machine to physically soften the fibers to form a tough fiber bundle. The isolated monofilament was thickly twisted with a yarn twisting machine to be weaved with a weaving machine to make a cloth cloth. I can't do it, sono lining,
It was limited to shoes, dongolos bags, and sewing threads on tatami mats, and its use was limited. However, when the known mono-fragment or cloth cloth is further bleached and reprocessed, its use is greatly expanded. Then, delignification and tanning of a thick mono-fragment are subjected to alkali immersion treatment by the above method,
After bleaching with a peroxide alkali, washing with water, treating with lactic acid, washing with water and drying, the thickness is thinned by delignification and tanning, and the weight is also reduced by 20 to 25% to give a pure white monofuramento. As a result, the mono-flament printed with a dye is used for interior-related wall cloths, because the initial thickness is 3-mesh, and it is made into 1-meme. Also used for clothing. Before the thinning fiber is treated with polyvinyl acetalized resin, fibrin ether or tung oil to solidify it, the brushed surface is polished and removed, and the monofragment, which is dried while stretching, is tough and is a polyamide fiber. Since it has the same tensile strength as that of, it is used as a reinforcing material for electric wires in clothing and core materials. Also, burlap cloth can be processed from light yellow to pure white by bleaching, and since it can be printed and printed on its surface, it can be used for clothing and wall cloths, leather and synthetic leather linings, clothes and ties. It is used as a reinforcing cloth for linings, is used as a surface paper for footwear, and is also used as a base for capas, handbags, and tent cloths. However, since the conventional jute monoflament or cocos cloth in this bleaching process shrinks by 30% by processing, it is necessary to calculate the width and length of cloth extra in shrinkage during processing. Also, when polyethylene powder is applied to this bleached monofragment, the waterproof property is improved by heat processing, and the general aging and deterioration of pulp and wire quality above 200 ° C does not change even at 300 ° C. As heat resistance, it is often used for resin processing. When used as a core material of polyester, urea resin, phenol, or melamine resin, the strength of the core material is increased by 15 when using an oily material or a dried product treated with a silicone resin or borane solution.
In addition, when this bleached jute fiber is spun with green ramie fiber, the production cost of the bleached burlap fiber is reduced to less than the following, so not only is it processed into an extremely inexpensive product, but also green ramie. Since the fibers themselves are not sufficiently bleached, the yellowed ones can be pure whitened by this bleaching method, which is also useful for improving the quality of the green ramie fibers. Also, as a substitute for a rope material such as Manila hemp, pure white rope can be made by bleaching. Also, long and short fibers obtained by processing fibers of banana branches are treated in the same manner as jute. The electrolytic electrode used in this electrolytic dialysis is a silicon or manganese electrode or a silicon electrode. As the diaphragm, a film obtained by laminating a fluororesin on an alumina fiber cloth or a porous polyvinyl resin is used. Urea Glycol and boric acid ester are used as a porous material for vinyl chloride resin. As the thick membrane, a membrane obtained by curing a polyvinyl resin obtained by mixing calcium glycol powder with ethylene glycol or urea glycol and then treating with hydrochloric acid is used.
Also, as the ceramic, SiO246% AL2O3
38% CaO 8% Na2O 4% Other high alumina sintered bodies are used. A fuel cell or general business power is used as this electrode power, but in order to reduce the electrolytic power, electrolytic dialysis is performed in a high pressure gas of 100 atm. At this time, a high pressure alumina ceramic or Germanium ceramics and sintered metal plates are used. This electrodialysis uses 20 volt 1 amp power,
The high-voltage electrolysis of this electrodialysis reduces the electric power to 1/10. In the fuel cell, hydrogen gas obtained by low-temperature decomposition of natural gas is used as a fuel in a phosphoric acid solution of conc, and silicon manganese or a silicon sintered electrode having a surface plated with platinum is used as an electrode. Oxygen gas sent to the anode surface Air is generally used, but a mixed gas with 5% oxygen gas is used. When monazite is attached to this porous plate sintered plate,
Gas ionization is promoted. This electrolysis power is 2.4
It is performed at a rate of Kw / 1 ton. The alkaline liquid dipping pit is made of concrete with tar pitch lining. In each pit, a glass fiber or nylon fiber bundle is used as a capillary to circulate each pit as an inverted U shape to the next pit, The last pit is drained by a pump to enter the electrolytic cell, so that the immersion alkaline lignin and tannin sugar solution are automatically moved and electrolyzed.
Then, the lignin and tannin solutions are concentrated and collected. As described above, in the electrolysis method, the wastewater is purified so that the pollution property is improved and 30-60% of the alkaline component is recovered. Further, when the bleaching ground is near the coastline, seawater liquid is used, and if the electrolyte solution of the anode chamber is used for bleaching, bleaching can be performed at a low production cost. Also, when lactic acid solution is used as a softening agent for finishing the fiber, it promotes the loosening of the fiber and decolorizes the yellow color of the fiber thinly dyed with tannic acid, and also the mud colloid deposits and peeled parts of the skin. Is peeled off,
Not only has the effect of removing the yellowish brown spots that remain when the fiber is treated with alkali only and bleached, it is also a cured fiber such as a fiber neutralized with sulfuric acid or hydrochloric acid, or a bleached product treated with glyoxal and CLO2. The curability of the fibers in is prevented. The drawback of this curability of the fiber is that when the fiber is dissociated and processed into a single fiber, the fiber is easily cut by a combing machine, and isolated long fibers are difficult to obtain, so lactic acid or organic acid is used. . Also, in the jute production area, the river area is the cultivation area, and the collected jute produced after cultivation is soaked in water and decomposed by bacteria in the water to collect soft jute. To process
30% burlap fiber waste is produced, but when these fibers are treated with alkali for bleaching and lactic acid treatment, hemp pulp weight is reduced, and as a weight loss for paper and Japanese paper Since it is used as the surface cover paper of the, the consistent work at the site is more effective. In addition, unlike the conventional method, this method performs delignification and tannin at room temperature, so that the damage of the fiber is small and the defect that the fiber becomes a dumpling fiber is compensated. Therefore, the production yield is improved by 10% by the low temperature treatment. Further, glyoxal increases the bleaching speed and hardens the fibers, and therefore it is used for reinforcing monofilament twisted yarns, and it is used as a reinforcing fiber of polyester because of its remarkable curability in mixed twisted yarns of glass and ceramic fibers.
This polyester processing becomes more effective when borane treatment or polyvinyl acetalized resin is pretreated.
Also, since this jute fiber is used as a substitute for Kozo and Mitsumata, it not only has the advantage of lowering the cost of Japanese paper, but also has a long life and does not cause aging like pulp and can be torn apart during storage. It is used for condenser paper and copy paper because it does not happen, and it can be mixed with ceramics and synthetic fibers, so it is not only used as a filter material for oil or air, or as a packing material, but also has a high sound absorbing effect. Since it is heat-insulating, it is used not only as a heat-insulating building material board, but also as a gypsum board and wall soil material, and as a concrete material. This jute filament is
It has a length of 3 to 5 meters, is compatible with raw silk, has a higher tensile force than burlap alone when entangled with fibers, and mixes well with synthetic long fibers, When you hang it on the general jute, soft 21
When unwinding with a liquid obtained by mixing the surfactant with oil or a sodium polyacrylate liquid, the fiber is not cut so a part of this method can be used for mass production. As described above, the characteristic feature of the present invention is that the conventional burlap has bristle property and is easily made into short fibers during processing because it retains a yellowish brown color, so that it is difficult to make clear coloring, and most of the burlap fibers are Since only thick twisted yarn can be processed, the cloth cloth spun from the twisted yarn is thick and heavy, and it has the drawback of being poor in heat retention and cannot be used for many purposes. In this way, we developed a technique of bleaching into pure white, did not require the boiler heating required for conventional processing, processed at a relatively low temperature, and carried out delignification and tannin by using not only caustic alkali but also peroxide, Lignin and tannin recovered from this solution by diaphragm electrolysis are used as raw materials for skin toughness and fragrances, alkaline components are recovered, and reused for alkaline treatment of jute fibers to improve wastewater pollution, and as a softening of fibers, By using machine acid, lactic acid, and monochloroacetic acid as finishing agents and neutralizing agents, the softening of fibers is utilized for single fiber dissociation, increasing the yield of long fibers and suppressing the yield of short fibers. Depending on the use of peroxide and glyoxal LO2, it is bleached to a pure white color to process it into a pure white fiber comparable to expensive green ramie fiber, thus making inexpensive clothing and fabrics. As a result, printing and printing are performed clearly, so that the use of burlap was used for grain packaging bags, but it is also used for clothing and interiors, and it is used as a raw material for washi as an industrial rough material. Not only is it used as a filter because it has good drainage, it is used as a raw material for durable Japanese paper and copy paper, but it can also be twisted by mixing long fibers with synthetic fibers and mineral fibers such as raw silk and glass fibers. Since it becomes easier and the tensile strength increases, it can be used for interiors as well as clothes and fabrics, especially as a building material,
Many applications have been developed as a reinforcing material for resin processing and electric materials, and it is an industrially useful invention because it improves the obliquity of jute production. Further, since it is also applied to the processing of banana fiber, it is useful as a pulp resource and clothing.

【図面の簡単な説明】[Brief description of drawings]

【図1】 黄麻繊維のフロシーシ図Fig. 1 Flossy diagram of jute fiber

【図2】 黄麻加工の工程図[Figure 2] Burlap processing process diagram

Claims (1)

【特許請求の範囲】[Claims] 後文記載の如く、栽培黄麻を常法に従い採集後、水漬し
て発酵分解して、一次、水漂白した黄麻繊維を苛性ソー
ダー液と過酸化物とを混合して、脱リグニン、タンニン
を行い、遠心分離した瀘液は回収してリグニンタンニン
液を濃縮して再利用するには、隔膜電解で脱アルカリを
行い、このアルカリ液を脱リグニン、タンニン用に再使
用する。そして、脱水した黄麻繊維は過酸化物、過炭酸
ソーダー、苛性アルカリで再処理して、遠心分離した瀘
液は電解して回収する。このアルカリ電解液は該繊維の
漂白液として過酸化水素と混合し、CLO2液で漂白し
ながら脱水して水洗いを繰返して二次漂白繊維として、
これを乳酸液や発酵乳酸液で浸漬して必要に応じてモノ
クロール酢酸液で処理したものを脱水して水洗いし、有
機酸、乳酸は電解で精製して再利用し、第三次漂白繊維
を作る。これを、水中で繊維をクシスキ機で単繊維に解
疎せしめたものを生糸や合成繊維と共に混和するが、こ
の添加繊維は長繊維のものが多く使用され短繊維はドラ
イ混紡用として回収し使用する。この様にして出来た長
繊維の混合繊維は撚糸機で撚糸されて、糸巻機で巻取ら
れ黄麻の剛毛繊維は予め乳酸液でソフト化されるが、繊
維の縮み合いが小さいのを生糸や合成繊維、綿花繊維で
カバーしながら撚糸を作り、これをボビンに巻き返して
紡繊して布地、繊布を作り、これを捺染又は、プリント
印刷して衣類を作り又、インテリア建材や敷布として利
用する事を特徴とした、黄麻繊維の加工品、及びバナナ
繊維加工品
As described in the following sentence, after cultivated jute is collected according to a conventional method, it is soaked in water for fermentation and decomposition, and the jute fiber bleached with water is mixed with caustic soda solution and peroxide to remove delignification and tannin. In order to collect the filtered filtrate and centrifuge, to concentrate and recycle the lignin tannin solution, dealkalize by diaphragm electrolysis and reuse this alkali solution for delignification and tannin. Then, the dehydrated jute fiber is re-treated with peroxide, sodium percarbonate and caustic, and the filtered filtrate is electrolyzed and collected. This alkaline electrolyte was mixed with hydrogen peroxide as a bleaching solution for the fiber, dehydrated while bleaching with a CLO2 solution, and repeatedly washed with water to obtain a secondary bleached fiber.
This is soaked in a lactic acid solution or a fermented lactic acid solution, optionally treated with a monochloroacetic acid solution, dehydrated and washed with water, and organic acids and lactic acid are purified by electrolysis and reused. make. This is mixed with raw silk or synthetic fiber, which is obtained by slackening the fibers into single fibers in water using a kushiski machine.The added fibers are often long fibers and short fibers are collected and used for dry blending. To do. The mixed fibers of long fibers thus produced are twisted by a twisting machine, and wound by a bobbin winding machine, and the bristle fibers of jute are softened in advance with a lactic acid solution. Make a twisted yarn while covering it with synthetic fiber or cotton fiber, rewind it on a bobbin and spin it to make a cloth or textile, and then print or print it to make clothes, or use it as an interior building material or bed sheet. Processed products of jute fiber and processed banana fibers characterized by
JP5165850A 1993-05-29 1993-05-29 Processing of jute fiber and processed article of banana fiber Pending JPH06341009A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5165850A JPH06341009A (en) 1993-05-29 1993-05-29 Processing of jute fiber and processed article of banana fiber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5165850A JPH06341009A (en) 1993-05-29 1993-05-29 Processing of jute fiber and processed article of banana fiber

Publications (1)

Publication Number Publication Date
JPH06341009A true JPH06341009A (en) 1994-12-13

Family

ID=15820188

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5165850A Pending JPH06341009A (en) 1993-05-29 1993-05-29 Processing of jute fiber and processed article of banana fiber

Country Status (1)

Country Link
JP (1) JPH06341009A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005290656A (en) * 2004-03-10 2005-10-20 Kyoto Kiito Kk Method for extracting fiber from abaca, fiber of abaca and woven fabric
CN1317434C (en) * 2003-12-19 2007-05-23 中华人民共和国上海出入境检验检疫局 Banana bast fiber, process for making same and use thereof
JP2008514824A (en) * 2004-09-25 2008-05-08 ▲力▼州摩▲維▼天然▲繊▼▲維▼材料有限公司 How to remove rubber from jute
CN101982571A (en) * 2010-09-10 2011-03-02 中国科学院过程工程研究所 Preparation method of banana fiber from banana stems and leaves by steam explosion degumming
WO2018219116A1 (en) * 2017-05-31 2018-12-06 大庆天之草生物新材料科技有限公司 Motion-type inactivation apparatus and method for fermented material
KR102202714B1 (en) * 2020-12-02 2021-01-14 주식회사 하이사이클 Processing method for making upcycled products of coffee bag jute

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1317434C (en) * 2003-12-19 2007-05-23 中华人民共和国上海出入境检验检疫局 Banana bast fiber, process for making same and use thereof
JP2005290656A (en) * 2004-03-10 2005-10-20 Kyoto Kiito Kk Method for extracting fiber from abaca, fiber of abaca and woven fabric
JP2008514824A (en) * 2004-09-25 2008-05-08 ▲力▼州摩▲維▼天然▲繊▼▲維▼材料有限公司 How to remove rubber from jute
JP4774404B2 (en) * 2004-09-25 2011-09-14 ▲力▼州摩▲維▼天然▲繊▼▲維▼材料有限公司 How to remove rubber from jute
CN101982571A (en) * 2010-09-10 2011-03-02 中国科学院过程工程研究所 Preparation method of banana fiber from banana stems and leaves by steam explosion degumming
WO2018219116A1 (en) * 2017-05-31 2018-12-06 大庆天之草生物新材料科技有限公司 Motion-type inactivation apparatus and method for fermented material
KR102202714B1 (en) * 2020-12-02 2021-01-14 주식회사 하이사이클 Processing method for making upcycled products of coffee bag jute

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