JPH06329950A - Inorganic coating composition - Google Patents
Inorganic coating compositionInfo
- Publication number
- JPH06329950A JPH06329950A JP14283793A JP14283793A JPH06329950A JP H06329950 A JPH06329950 A JP H06329950A JP 14283793 A JP14283793 A JP 14283793A JP 14283793 A JP14283793 A JP 14283793A JP H06329950 A JPH06329950 A JP H06329950A
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- Prior art keywords
- weight
- parts
- pts
- silicate
- sericite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、クラックのない強固な
塗膜を得ることで、付着した薬品や各種汚れをきれいに
払拭し、或いは油性筆記具による筆記部を簡単に消去で
きる無機塗料組成物に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an inorganic coating composition capable of cleanly wiping off adherent chemicals and various stains or easily erasing a writing part by an oil-based writing instrument by obtaining a strong coating film without cracks. It is a thing.
【０００２】[0002]
【従来の技術】従来のホワイトボード等への筆記は、水
性マーカーを使用していたが、特に水回り部では飛散水
や水蒸気によって筆記が消えることがあり、使用が不便
であった。また、工場や台所等の化粧板では、その塗装
面に薬品やソース等の滴下により払拭してもその汚れが
落ち難いものであった。これは筆記面や塗装面がケイ酸
アルカリ水溶液を結合剤とした無機塗料等で形成されて
いるため、筆記板や塗装した被塗物が熱的影響で歪みが
起こると筆記面や塗装面のガラス質塗膜に微細なクラッ
クが生じることから、インキ、薬品やソース等がクラッ
クにしみ込むことが原因とされている。2. Description of the Related Art Conventional writing on a whiteboard or the like uses a water-based marker. However, the writing may be erased by splashed water or water vapor, especially in the area around the water, which is inconvenient to use. Further, in the case of a decorative plate in a factory or a kitchen, it is difficult to remove the stain even if the coated surface is wiped off by dropping chemicals or sauce. This is because the writing surface and the coating surface are formed with an inorganic coating material that uses an alkaline silicate aqueous solution as a binder, so if the writing plate or the coated object is distorted due to thermal influence, Since fine cracks are generated in the glassy coating film, it is considered that ink, chemicals, sauces, etc. penetrate into the cracks.
【０００３】[0003]
【発明が解決しようとする課題】そこで本発明は、微細
なクラックの発生を防止して耐汚染性能及び耐薬品性能
を向上させることで各種汚れを容易に払拭でき、油性筆
記部も簡単に消去できる無機塗料組成物を提供するもの
である。Therefore, according to the present invention, various stains can be easily wiped off by preventing the generation of fine cracks and improving the stain resistance and the chemical resistance, and the oily writing part can be easily erased. The present invention provides a possible inorganic coating composition.
【０００４】[0004]
【課題を解決するための手段】このため本発明は、アル
カリ金属シリケートに、ケイ酸カルシウム或いはリン酸
亜鉛を添加し、無機充填材として、コレマナイト（2Ca
O,3B2O3,5H2O）或いはウレキサイト（Na2O,2CaO,5B2O3,
16H2O）を主成分とした天然ガラスを平均粒径３０ミク
ロンで厚み１．０μｍ以下の微細な鱗片状として混合
し、さらに平均粒度３０μｍ以下の微粉状絹雲母（セリ
サイト）を配合した構成としている。その配合は、アル
カリ金属シリケート１００重量部に、ケイ酸カルシウム
或いはリン酸亜鉛を５〜７０重量部添加し、無機充填材
のコレマナイト或いはウレキサイトの鱗片状天然ガラス
を５〜２００重量部混合し、微粉状絹雲母を１０〜３０
重量部配合することが適当である。Therefore, according to the present invention, calcium silicate or zinc phosphate is added to an alkali metal silicate to obtain a colemanite (2Ca) as an inorganic filler.
O, 3B 2 O 3 , 5H 2 O) or urexite (Na 2 O, 2CaO, 5B 2 O 3 ,)
16H 2 O) as a main component, natural glass is mixed in the form of fine flakes having an average particle size of 30 μm and a thickness of 1.0 μm or less, and finely powdered sericite (average particle size of 30 μm or less) is added. I am trying. The compounding is to add 100 parts by weight of alkali metal silicate to 5 to 70 parts by weight of calcium silicate or zinc phosphate, and mix 5 to 200 parts by weight of inorganic filler of colemanite or urexite scale-like natural glass to obtain fine powder. Sericid mica 10-30
It is suitable to blend in parts by weight.
【０００５】ここで無機充填材として、コレマナイト
（2CaO,3B2O3,5H2O）或いはウレキサイト（Na2O,2CaO,5
B2O3,16H2O）を主成分とした天然ガラスを用いるのは、
コレマナイト或いはウレキサイトに含有するB2O3成分の
ガラス化により強固な塗膜が形成されるためである。な
お、他の天然ガラスにコレマナイト或いはウレキサイト
を混合させてもよいが、コレマナイト或いはウレキサイ
トの混合量は少なくとも無機充填材総量の約１０重量％
を必要とし、最適は３０重量％以上である。[0005] Here, the inorganic filler, colemanite (2CaO, 3B 2 O 3, 5H 2 O) or ulexite (Na 2 O, 2CaO, 5
B 2 O 3 , 16H 2 O) is the main component of natural glass
This is because a strong coating film is formed by vitrification of the B 2 O 3 component contained in colemanite or urexite. Although other natural glass may be mixed with cholemanite or urexite, the amount of cholemanite or urexite mixed is at least about 10% by weight of the total amount of the inorganic filler.
The optimum is 30% by weight or more.
【０００６】また、コレマナイト或いはウレキサイトを
含有した無機充填材の配合量は、ノンアスベスト板、セ
メント製品、石綿スレート板等の被塗物によって異な
り、歪みの大きな被塗物には多く配合し、吸水率の大き
な被塗物は少なく配合し、バインダーとしてのアルカリ
金属シリケート１００重量部に対して５〜２００重量部
と広い範囲で配合調整できるのである。コレマナイト或
いはウレキサイトを含有した天然ガラスを平均粒径３０
μｍで厚み１．０μｍ以下の鱗片状としたのは、良好に
混在できると共に、被覆力の強い塗膜とするためであ
る。Further, the compounding amount of the inorganic filler containing colemanite or urexite varies depending on the object to be coated such as non-asbestos board, cement product, asbestos slate board, etc. It is possible to mix a small amount of an object to be coated having a large ratio and to adjust the content in a wide range of 5 to 200 parts by weight with respect to 100 parts by weight of the alkali metal silicate as a binder. Natural glass containing colemanite or urexite has an average particle size of 30
The scale-like shape having a thickness of 1.0 μm or less in μm is to form a coating film which can be mixed well and has a strong covering power.
【０００７】さらに、平均粒度３０μｍ以下の微粉状絹
雲母（セリサイト）を配合したのは、塗装面を平滑にで
きて表面での付着物の離型性、即ち付着物の付着状態を
弱くして浮き離れを良好にすることで払拭を容易にする
ためである。その配合量は、無機充填材のコレマナイト
或いはウレキサイトを含んだ鱗片状天然ガラスに対して
５〜３０重量％が適切であり、特に１０〜２５重量％が
最適である。Furthermore, the addition of finely powdered sericite (sericite) having an average particle size of 30 μm or less makes it possible to smooth the coated surface and weaken the releasability of the adhered matter on the surface, that is, the adhered state of the adhered matter. This is for facilitating the wiping by improving the floating. The blending amount is appropriately 5 to 30% by weight, and particularly preferably 10 to 25% by weight, based on the scale-like natural glass containing the inorganic filler cholemannite or urexite.
【０００８】[0008]
【作用】本発明によると、コレマナイト（2CaO,3B2O3,5
H2O）或いはウレキサイト（Na2O,2CaO,5B2O3,16H2O）の
B2O3成分のガラス化により強固な塗膜が形成されるので
あり、それらが鱗片状であるため良好に混在されて薄い
塗膜を形成できるのである。また、微粉状絹雲母の配合
により塗装面を平滑にできて表面での付着物の払拭性を
容易にでき、塗膜面は、鱗片状ガラスにより、深みのあ
るメタリック調の仕上げとなって高級感のある筆記面や
化粧板を形成できるのである。According to the present invention, colemanite (2CaO, 3B 2 O 3, 5
H 2 O) or urexite (Na 2 O, 2CaO, 5B 2 O 3 , 16H 2 O)
A strong coating film is formed by vitrification of the B 2 O 3 component, and since they are scaly, they can be mixed well and a thin coating film can be formed. In addition, the surface of the coating can be easily wiped off by smoothing the coated surface by blending finely powdered sericite, and the surface of the coating film is a metallic finish with a deep metallic finish due to the glass flake. It is possible to form a writing surface and a decorative plate with a feeling.
【０００９】[0009]
【実施例１】ケイ酸ナトリウム１００重量部、硬化剤と
してケイ酸カルシウム５重量部とリン酸亜鉛１０重量
部、平均粒径３０μｍで厚み１．０μｍ以下の鱗片状と
したコレマナイト８０重量部とウレキサイト２０部、顔
料として酸化チタン３３重量部とチタン黄１重量部、平
均粒度３０μｍ以下の微粉状絹雲母２５重量部、さらに
極薄フレーク状をした厚み０．５μｍ以下のガラスフレ
ーク１０重量部とを水５０部と共にボールミルで１０分
混合し、これをノンアスベスト板にスプレー塗装し、２
９０゜Ｃの熱風で３５分乾燥して厚み２８μｍの塗膜を
得た。Example 1 100 parts by weight of sodium silicate, 5 parts by weight of calcium silicate as a curing agent, 10 parts by weight of zinc phosphate, 80 parts by weight of scale-like colemanite having an average particle size of 30 μm and a thickness of 1.0 μm or less, and urexite. 20 parts, 33 parts by weight of titanium oxide as a pigment, 1 part by weight of titanium yellow, 25 parts by weight of fine powder sericite with an average particle size of 30 μm or less, and 10 parts by weight of glass flakes with a thickness of 0.5 μm or less in the form of ultra-thin flakes. Mix with 50 parts of water in a ball mill for 10 minutes, spray-paint this on non-asbestos board, and
It was dried with hot air at 90 ° C. for 35 minutes to obtain a coating film having a thickness of 28 μm.
【００１０】塗膜面は、鱗片状ガラスにより、深みのあ
るメタリック調の仕上げができ、高級感のある化粧板を
形成できたのである。また、微粉状絹雲母により塗装面
を平滑にできたのである。この塗膜のクラックの有無、
密着性能実験結果及び払拭消去試験結果を他例と共に表
１に示す。また、他の塗膜性能試験の結果を表２に示
す。さらに、耐薬品性能と耐汚染性能の試験結果を表３
に示す。The coated surface was made of scaly glass and had a metallic finish with a deep finish, and it was possible to form a high-quality decorative board. Moreover, the coated surface could be made smooth by the finely powdered sericite. Presence or absence of cracks in this coating,
The results of the adhesion performance experiment and the wiping and erasing test are shown in Table 1 together with other examples. Table 2 shows the results of other coating performance tests. Table 3 shows the test results of chemical resistance and stain resistance.
Shown in.
【００１１】[0011]
【実施例２】ケイ酸ナトリウム１００重量部、硬化剤と
してケイ酸カルシウム７重量部リン酸亜鉛３重量部、平
均粒径３０μｍで厚み１．０μｍ以下の鱗片状としたコ
レマナイト１１０重量部と、顔料として酸化チタン２８
重量部と、平均粒度３０μｍ以下の微粉状絹雲母１７重
量部、微分金属粉１１重量部を水５０部と共にボールミ
ルで１５分混合し、これをアルミニウム板にスプレー塗
装し、１８０゜Ｃの熱風で２０分乾燥して厚み３０μｍ
の磁着性塗膜を得た。Example 2 100 parts by weight of sodium silicate, 7 parts by weight of calcium silicate as a curing agent, 3 parts by weight of zinc phosphate, 110 parts by weight of scaly colemanite having an average particle diameter of 30 μm and a thickness of 1.0 μm or less, and a pigment. As titanium oxide 28
Part by weight, 17 parts by weight of finely powdered sericite with an average particle size of 30 μm or less, and 11 parts by weight of differential metal powder are mixed with 50 parts of water in a ball mill for 15 minutes, spray-coated on an aluminum plate, and heated with 180 ° C. hot air. 30 minutes after drying for 20 minutes
To obtain a magnetically attractable coating film.
【００１２】[0012]
【実施例３】ケイ酸ナトリウム７０重量部とケイ酸カリ
ウム３０重量部、硬化剤としてケイ酸カルシウム１１重
量部とリン酸亜鉛１重量部、平均粒径３０μｍで厚み
１．０μｍ以下の鱗片状としたコレマナイト９０重量部
と、顔料として酸化チタン３６重量部とチタン黄１重量
部、平均粒度３０μｍ以下の微粉状絹雲母２１重量部を
水５０部と共にボールミルで７分混合し、これを厚み５
ミリの鋼板にスプレー塗装し、２００゜Ｃの熱風で２５
分乾燥して厚み２５μｍの塗膜を得た。Example 3 70 parts by weight of sodium silicate and 30 parts by weight of potassium silicate, 11 parts by weight of calcium silicate as a curing agent and 1 part by weight of zinc phosphate, and scales having an average particle diameter of 30 μm and a thickness of 1.0 μm or less. 90 parts by weight of colemanite, 36 parts by weight of titanium oxide as a pigment, 1 part by weight of titanium yellow, and 21 parts by weight of finely powdered sericite having an average particle size of 30 μm or less were mixed with 50 parts of water in a ball mill for 7 minutes to give a thickness of 5
Spray paint on millimeter steel plate and apply hot air at 200 ° C for 25
After minute drying, a coating film having a thickness of 25 μm was obtained.
【００１３】[0013]
【実施例４】ケイ酸カリウム７０重量部とケイ酸リチウ
ム３０重量部、硬化剤としてケイ酸カルシウム１重量部
リン酸亜鉛９重量部、平均粒径３０μｍで厚み１．０μ
ｍ以下の鱗片状としたコレマナイト１１０重量部とウレ
キサイト１０重量部、顔料として酸化チタン２８重量
部、平均粒度３０μｍ以下の微粉状絹雲母２３重量部、
厚み０．５μｍ以下のガラスフレーク１５重量部、微分
金属粉５重量部とを水５０部と共にボールミルで１２分
混合し、これをノンアスベスト板にロールコーターで塗
装し、２７０゜Ｃの熱風で３５分乾燥して厚み３３μｍ
の磁着性塗膜を得た。Example 4 70 parts by weight of potassium silicate and 30 parts by weight of lithium silicate, 1 part by weight of calcium silicate as a curing agent, 9 parts by weight of zinc phosphate, an average particle size of 30 μm and a thickness of 1.0 μm.
110 parts by weight of scale-like cholemanite and 10 parts by weight of urexite, 28 parts by weight of titanium oxide as a pigment, 23 parts by weight of finely divided sericite having an average particle size of 30 μm or less,
15 parts by weight of glass flakes having a thickness of 0.5 μm or less and 5 parts by weight of differential metal powder are mixed together with 50 parts of water by a ball mill for 12 minutes, and the mixture is coated on a non-asbestos plate with a roll coater. Minute drying to a thickness of 33 μm
To obtain a magnetically attractable coating film.
【００１４】[0014]
【実施例５】ケイ酸ナトリウム５０部とケイ酸カリウム
５０重量部、硬化剤としてケイ酸カルシウム６重量部と
リン酸亜鉛５重量部、平均粒径３０μｍで厚み１．０μ
ｍ以下の鱗片状としたコレマナイト２５重量部とウレキ
サイト１１０重量部、顔料として酸化チタン２６重量部
とチタン黄２重量部、厚み０．５μｍ以下のガラスフレ
ーク９重量部、平均粒度３０μｍ以下の微粉状絹雲母１
８重量部を水５０部と共にボールミルで２０分混合し、
これをノンアスベスト板にスプレー塗装し、２８０゜Ｃ
の熱風で２５分乾燥して厚み３５μｍの塗膜を得た。Example 5 50 parts by weight of sodium silicate and 50 parts by weight of potassium silicate, 6 parts by weight of calcium silicate as a curing agent and 5 parts by weight of zinc phosphate, an average particle diameter of 30 μm and a thickness of 1.0 μm.
25 parts by weight of scale-like colemanite and 110 parts by weight of urexite, 26 parts by weight of titanium oxide and 2 parts by weight of titanium yellow as a pigment, 9 parts by weight of glass flakes having a thickness of 0.5 μm or less, and a fine powder form having an average particle size of 30 μm or less Sericite 1
Mix 8 parts by weight with 50 parts of water in a ball mill for 20 minutes,
This is spray-painted on a non-asbestos board, and it is 280 ° C.
Was dried with hot air for 25 minutes to obtain a coating film having a thickness of 35 μm.
【００１５】[0015]
【表１】 [Table 1]
【００１６】[0016]
【表２】 [Table 2]
【００１７】[0017]
【表３】 [Table 3]
【００１８】このように、すべての実施例とも、耐煮沸
試験８時間後の塗膜にクラック発生がなく、ゴバン目テ
ープテスト密着性能試験も良好であった。また、市販の
油性マーカーの筆記も濡れ布による払拭で良好に消去で
きたのである。さらに、クラックが生じないことから耐
薬品性能、耐汚染性能が良好となったのである。As described above, in all of the examples, no cracks were formed in the coating film after 8 hours of the boiling resistance test, and the burlap tape test adhesion performance test was also good. In addition, the writing on the commercially available oil-based marker could be erased well by wiping with a wet cloth. Furthermore, since no cracks were generated, the chemical resistance and stain resistance were improved.
【００１９】なお、これらの原料に金属粉を混合した実
施例ではすれば磁着塗料となって、ノンアスベスト板や
アルミニウム板等の非磁着材の塗膜面を磁着体にでき、
磁石クリップ等を吸着できてメモ等を備えることができ
るのである。In the examples in which metal powder is mixed with these raw materials, a magnetic coating material can be obtained, and the coated surface of a non-magnetic material such as a non-asbestos plate or an aluminum plate can be used as a magnetic material.
A magnetic clip or the like can be adsorbed and a memo or the like can be provided.
【００２０】なお、厚み０．５μｍ以下の極薄フレーク
状のガラスフレークを配合すれば、ケイカル板のよう
に、軽量で吸水率が高く熱歪みの大きい被塗物に対して
被覆力をより強くして安定した強固な塗膜を平均２０μ
ｍ以下の薄膜に形成できるためであり、１〜３０重量部
の混合が適当である。By adding glass flakes in the form of ultra-thin flakes having a thickness of 0.5 μm or less, the covering power of a coating material having a light weight, a high water absorption rate and a large thermal strain, such as a silica plate, becomes stronger. And stable and strong coating film on average 20μ
This is because a thin film having a thickness of m or less can be formed, and 1 to 30 parts by weight is suitable for mixing.
【００２１】[0021]
【発明の効果】本発明によると、無機充填材として、コ
レマナイト或いはウレキサイトを含有した天然ガラスを
微細な鱗片状としているためそのB2O3成分のガラス化に
よって被覆力が向上し、被塗物との密着が促進し強固な
塗膜となってクラックの発生がないことから耐薬品性能
及び耐汚染性能も良好な塗膜が得られ、これと共に、微
粉状絹雲母を混合したため塗膜面を平滑にでき表面での
付着物の払拭性を容易にできて油性マーカーによる筆記
の消去、各種汚れを拭き取りできる効果が大きく、塗膜
面は、深みのあるメタリック調で高級感のある化粧板を
形成できるのである。請求項２のものでは、各種被塗物
を問わず広い範囲で良好な塗膜が得られるのである。EFFECTS OF THE INVENTION According to the present invention, natural glass containing colemanite or urexite as an inorganic filler is made into a fine scaly form, so that the coating power is improved by vitrification of the B 2 O 3 component, and the coated object Adhesion with is promoted and a strong coating film is formed without cracks, so a coating film with good chemical resistance and stain resistance is obtained. It is smooth and easy to wipe off adhered substances on the surface, it has a great effect of erasing writing with an oil-based marker and wiping off various stains, and the coated surface has a deep metallic tone and a high-quality decorative plate It can be formed. According to the second aspect of the present invention, a good coating film can be obtained in a wide range regardless of various kinds of objects to be coated.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 山田 幸司 愛知県半田市花園町６丁目20番地23 (72)発明者 山田 文隆 愛知県半田市花園町６丁目20番地23 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Koji Yamada 6-20, Hanazonocho, Handa-shi, Aichi 23 (72) Inventor Fumitaka Yamada 6-20 23 Hanazono-cho, Handa-shi, Aichi
Claims (2)
シウム或いはリン酸亜鉛を添加し、無機充填材として、
コレマナイト（2CaO,3B2O3,5H2O）或いはウレキサイト
（Na2O,2CaO,5B2O3,16H2O）を主成分とした天然ガラス
を平均粒径３０ミクロンで厚み１．０μｍ以下の微細な
鱗片状として混合し、さらに平均粒度３０μｍ以下の微
粉状絹雲母（セリサイト）を配合したことを特徴とする
無機塗料組成物。1. An inorganic filler comprising calcium silicate or zinc phosphate added to an alkali metal silicate,
Natural glass mainly composed of colemanite (2CaO, 3B 2 O 3 , 5H 2 O) or urexite (Na 2 O, 2CaO, 5B 2 O 3 , 16H 2 O) with an average particle size of 30 microns and a thickness of 1.0 μm or less The fine powdery sericite (sericite) having an average particle size of 30 μm or less is mixed, and the inorganic coating composition is obtained.
に、ケイ酸カルシウム或いはリン酸亜鉛を５〜７０重量
部添加し、無機充填材のコレマナイト或いはウレキサイ
トの鱗片状天然ガラスを５〜２００重量部混合し、微粉
状絹雲母を１０〜３０重量部配合した請求項１の無機塗
料組成物。2. To 100 parts by weight of an alkali metal silicate, 5 to 70 parts by weight of calcium silicate or zinc phosphate is added, and 5 to 200 parts by weight of an inorganic filler, cholemanite or natural glass of flake, is mixed. The inorganic coating composition according to claim 1, which comprises 10 to 30 parts by weight of finely divided sericite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05142837A JP3140612B2 (en) | 1993-05-21 | 1993-05-21 | Inorganic coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05142837A JP3140612B2 (en) | 1993-05-21 | 1993-05-21 | Inorganic coating composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06329950A true JPH06329950A (en) | 1994-11-29 |
| JP3140612B2 JP3140612B2 (en) | 2001-03-05 |
Family
ID=15324772
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP05142837A Expired - Fee Related JP3140612B2 (en) | 1993-05-21 | 1993-05-21 | Inorganic coating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3140612B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000023528A1 (en) * | 1998-10-19 | 2000-04-27 | Toto Ltd. | Stainproof material and method for manufacturing the same, and coating composition and apparatus therefor |
| JP2003129000A (en) * | 2001-10-25 | 2003-05-08 | Tomomi Hirota | Coating material by which magnet is effectively used and coated article given by using the coating material |
| JP2007167754A (en) * | 2005-12-21 | 2007-07-05 | Paint Staff:Kk | Object having inorganic coating film and its manufacturing method |
| KR100772977B1 (en) * | 2006-11-24 | 2007-11-02 | (주)동양리빙퀘스트 | Preparing method of salified sol for coating interior materials |
| JP2007327000A (en) * | 2006-06-09 | 2007-12-20 | Koji Yamada | Inorganic coating composition |
| JP5818285B1 (en) * | 2014-09-19 | 2015-11-18 | 株式会社サムギョンＭｓｍ | A sericite finishing composition for indoor building containing non-toxic adhesive components |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9140279B2 (en) | 2012-09-25 | 2015-09-22 | The Young Engineers, Inc. | Magnetic mount |
| JP6813989B2 (en) * | 2016-08-23 | 2021-01-13 | 三菱重工業株式会社 | Crosshead internal combustion engine |
-
1993
- 1993-05-21 JP JP05142837A patent/JP3140612B2/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000023528A1 (en) * | 1998-10-19 | 2000-04-27 | Toto Ltd. | Stainproof material and method for manufacturing the same, and coating composition and apparatus therefor |
| US6673433B1 (en) | 1998-10-19 | 2004-01-06 | Toto Ltd. | Stainproof material and method for manufacturing the same, and coating composition and apparatus thereof |
| JP2003129000A (en) * | 2001-10-25 | 2003-05-08 | Tomomi Hirota | Coating material by which magnet is effectively used and coated article given by using the coating material |
| JP2007167754A (en) * | 2005-12-21 | 2007-07-05 | Paint Staff:Kk | Object having inorganic coating film and its manufacturing method |
| JP2007327000A (en) * | 2006-06-09 | 2007-12-20 | Koji Yamada | Inorganic coating composition |
| KR100772977B1 (en) * | 2006-11-24 | 2007-11-02 | (주)동양리빙퀘스트 | Preparing method of salified sol for coating interior materials |
| JP5818285B1 (en) * | 2014-09-19 | 2015-11-18 | 株式会社サムギョンＭｓｍ | A sericite finishing composition for indoor building containing non-toxic adhesive components |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3140612B2 (en) | 2001-03-05 |
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