JPH06321656A - Production of lightweight inorganic product - Google Patents

Production of lightweight inorganic product

Info

Publication number
JPH06321656A
JPH06321656A JP13645493A JP13645493A JPH06321656A JP H06321656 A JPH06321656 A JP H06321656A JP 13645493 A JP13645493 A JP 13645493A JP 13645493 A JP13645493 A JP 13645493A JP H06321656 A JPH06321656 A JP H06321656A
Authority
JP
Japan
Prior art keywords
diatomaceous earth
pulp
weight
cement
inorganic product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13645493A
Other languages
Japanese (ja)
Other versions
JP3378610B2 (en
Inventor
Takeshi Yonezu
猛 米津
Katsumune Nagai
克宗 永井
Akira Matsuoka
章 松岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daiken Trade and Industry Co Ltd
Original Assignee
Daiken Trade and Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daiken Trade and Industry Co Ltd filed Critical Daiken Trade and Industry Co Ltd
Priority to JP13645493A priority Critical patent/JP3378610B2/en
Publication of JPH06321656A publication Critical patent/JPH06321656A/en
Application granted granted Critical
Publication of JP3378610B2 publication Critical patent/JP3378610B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/18Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/10Compositions or ingredients thereof characterised by the absence or the very low content of a specific material
    • C04B2111/12Absence of mineral fibres, e.g. asbestos
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/30Nailable or sawable materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

PURPOSE:To produce a lightweight inorg. product having a non-asbestos compsn. and excellent in practical strength and suitability to nailing by extrusion molding. CONSTITUTION:The molar ratio of CaO to SiO2 contained in a mixture contg. cement, diatomaceous earth, pulp and water as essential components is regulated to 0.7-1.2, the diatomaceous earth content is regulated to 25-35wt.% and the weight ratio of the pulp to the diatomaceous earth is regulated to 0.2-0.3. The resulting mixture is kneaded and extrusion-molded as usual and calcium silicate hydrate is formed by treatment in an autoclave.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、ノンアスベスト組成で
押出し成形による軽量無機質製品の製造方法の改良に関
するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an improved method for producing a lightweight inorganic product by extrusion molding with a non-asbestos composition.

【0002】[0002]

【従来の技術】従来より、セメントを原料とする無機質
製品を効率よく工業的に製造する方法として押出し成形
が広く用いられている。特に軽量な無機質製品を得るた
めには、一般的にパーライトやシラスバルーン等の軽量
骨材の添加が行われている。
2. Description of the Related Art Extrusion molding has been widely used as a method for efficiently and industrially producing an inorganic product made of cement as a raw material. In order to obtain a particularly lightweight inorganic product, a lightweight aggregate such as pearlite or shirasu balloon is generally added.

【0003】一方、近年、アスベストの有害性からノン
アスベスト組成への代替が必要条件となりつつあり、ガ
ラス繊維、パルプ、ポリプロピレンやビニロン等の合成
繊維が代替材料として使用されている。
On the other hand, in recent years, it has become a necessary condition to substitute non-asbestos composition because of the harmfulness of asbestos, and synthetic fibers such as glass fiber, pulp, polypropylene and vinylon are used as substitute materials.

【0004】[0004]

【発明が解決しようとする課題】しかし、前者の軽量化
に関しては、これらの軽量骨材は脆く破壊されやすいの
で、押出し成形の工程中において破壊されるため十分な
軽量化を実現することができなかった。
However, regarding the former weight reduction, since these lightweight aggregates are brittle and easily broken, they are destroyed during the extrusion molding process, so that sufficient weight reduction can be realized. There wasn't.

【0005】また、後者のノンアスベスト組成に関して
は、ようやく前述したような代替材料が見つかってきた
段階であり、実用上の使用強度、切断・切削等の加工性
や釘打ち性、押出し成形性、経済性等を総合的に考える
と、これらの代替材料を使いこなしていく製造方法の確
立においては、まだまだ不十分と言わざるを得ない。
With regard to the latter non-asbestos composition, it is at the stage where the above-mentioned alternative materials have finally been found, and the practical use strength, workability such as cutting and cutting, nailability, extrusion moldability, Considering the economic efficiency and the like, it must be said that it is still insufficient in establishing a manufacturing method that makes full use of these alternative materials.

【0006】そこで本発明はこれらの問題点に鑑み、押
出し成形により製造される、軽量かつノンアスベスト組
成の軽量無機質製品の製造方法を提供することを目的と
するものである。
In view of these problems, it is an object of the present invention to provide a method for producing a lightweight inorganic product having a non-asbestos composition which is produced by extrusion molding.

【0007】[0007]

【課題を解決するための手段】前記目的を達成するため
に本発明の軽量無機質製品の製造方法について鋭意研究
を行った結果、セメント原料にけいそう土とパルプを添
加し、けいそう土の含有率及び、けいそう土とパルプの
添加比率を特定の範囲で選択し、オートクレーブで反応
させる方法を見出すに至った。
[Means for Solving the Problems] In order to achieve the above object, as a result of earnest research on a method for producing a lightweight inorganic product of the present invention, as a result of adding diatomaceous earth and pulp to a cement raw material and containing diatomaceous earth. The inventors have found a method in which the rate and the addition ratio of diatomaceous earth and pulp are selected within a specific range and the reaction is carried out in an autoclave.

【0008】すなわち、本発明にかかる軽量無機質製品
の製造方法は、セメントと、けいそう土と、パルプと、
水とを必須成分とした混合物において、含まれるCaO
とSiOのモル比を、CaO/SiO=0.7〜
1.2とし、けいそう土の含有率を25〜35重量%と
し、けいそう土とパルプの重量比を、パルプ/けいそう
土=0.2〜0.3とし、該混合物を押出し成形し、オ
ートクレーブ処理してカルシウムシリケート水和物を生
成させることを特徴としている。
That is, the method for producing a lightweight inorganic product according to the present invention comprises cement, diatomaceous earth, pulp, and
CaO contained in a mixture containing water as an essential component
And SiO 2 molar ratio is CaO / SiO 2 = 0.7-
1.2, the content of diatomaceous earth is 25 to 35% by weight, the weight ratio of diatomaceous earth to pulp is pulp / diatomaceous earth = 0.2 to 0.3, and the mixture is extruded. It is characterized in that it is autoclaved to produce calcium silicate hydrate.

【0009】本発明に使用するセメントとは、ポルトラ
ンドセメント、アルミナセメント、高炉スラグセメン
ト、フライアッシュセメント等の、無機質製品に一般的
に使用されるものである。けいそう土は産地によって不
純物含有量が多少異なるが、特に限定するものではな
く、かさ比重も概ね0.1程度の軽量なものが一般的に
使用されているので、これを利用すれば良く限定はしな
い。セメントとけいそう土を、CaOとSiOのモル
比が、CaO/SiO=0.7〜1.2となるように
調整することによって、後述するオートクレーブ処理に
よってケイカル反応がし易く、特に物性的に安定したト
バモライトに代表されるカルシウムシリケート水和物を
生成させることができる。
The cement used in the present invention is generally used for inorganic products such as Portland cement, alumina cement, blast furnace slag cement and fly ash cement. The diatomaceous earth has a slightly different impurity content depending on the production area, but it is not particularly limited, and a lightweight material having a bulk specific gravity of about 0.1 is generally used. I don't. By adjusting the cement and diatomaceous earth so that the molar ratio of CaO and SiO 2 is CaO / SiO 2 = 0.7 to 1.2, a calcareous reaction is easily caused by the autoclave treatment described later, and the physical properties are particularly high. A stable calcium silicate hydrate represented by tobermorite can be produced.

【0010】また、けいそう土を多量に添加すると吸水
率が大きくなるため、従来は、けい石粉等を主体にして
不足のSiOを補充していたが、本研究において、け
いそう土の添加量が35重量%以下では、オートクレー
ブ処理を行い安定したカルシウムシリケート水和物を生
成することにより、飽和吸水率は大きくなるものの飽和
状態までの時間が長く初期吸水による体積変化が小さい
ため、凍結融解試験においてもクラック等の劣化は見ら
れず耐久性に関しては実用上問題ないことを見出だし
た。
Further, since the water absorption rate increases when a large amount of diatomaceous earth is added, conventionally, a shortage of SiO 2 was supplemented mainly by silica stone powder, but in the present study, addition of diatomaceous earth was carried out. If the amount is 35% by weight or less, autoclave treatment is performed to generate stable calcium silicate hydrate, and the saturated water absorption rate increases, but the time until saturation is long and the volume change due to initial water absorption is small, so freeze-thaw In the test, no deterioration such as cracks was observed, and it was found that there is no practical problem with respect to durability.

【0011】また、けいそう土は多孔質構造により、か
さ比重が軽くケイカル反応後も構造が保持されるため軽
量化に貢献すると共に、流動性に優れるため押出し成形
においても最適であるが、添加量が25重量%を下まわ
ると、これらの効果も不十分である。但し、けいそう土
の添加量によってはSiOが不足する場合もありけい
石粉等で補足することもあるが、できるだけ、けいそう
土のみで調整することが望ましい。
The diatomaceous earth, which has a porous structure, has a light bulk specific gravity and retains the structure even after the Caikal reaction, which contributes to weight reduction and is excellent in fluidity, and therefore is most suitable for extrusion molding. If the amount is less than 25% by weight, these effects are insufficient. However, depending on the amount of diatomaceous earth added, SiO 2 may be insufficient and may be supplemented with silica stone powder, but it is desirable to adjust with diatomaceous earth as much as possible.

【0012】パルプは、本発明で得られる軽量無機質製
品の強度を高めると共に切断・切削等の加工性や釘打ち
性を向上させ、さらに、保水性によって押出し成形性を
高める効果がある。種類として、針葉樹、広葉樹、故紙
等によって限定されるものではないが、本発明に使用さ
れる原料の混合性からみて繊維長は1mm以下であるこ
とが望ましい。パルプ自体は強固な結合力を持たないの
で多量に添加すると逆に製品強度が低下する。したがっ
て、けいそう土とパルプの重量比を、パルプ/けいそう
土=0.2〜0.3の範囲とすることが好ましい。
[0012] Pulp has the effects of increasing the strength of the lightweight inorganic product obtained in the present invention, improving the workability of cutting / cutting and nailing, and further improving the extrusion formability by water retention. The type is not limited to softwood, hardwood, waste paper, etc., but the fiber length is preferably 1 mm or less in view of the mixing property of the raw materials used in the present invention. Since the pulp itself does not have a strong binding force, the addition of a large amount will reduce the product strength. Therefore, the weight ratio of diatomaceous earth to pulp is preferably in the range of pulp / diatomaceous earth = 0.2 to 0.3.

【0013】その他、適量の水と必要に応じてメチルセ
ルロース、カルボキシメチルセルロース等の増粘材が使
用される。また、本発明の主旨とは関係ない品質改善や
製造を円滑にするための補助剤の添加については特に限
定しない。
In addition, an appropriate amount of water and, if necessary, a thickening agent such as methyl cellulose and carboxymethyl cellulose are used. Further, addition of an auxiliary agent for improving quality and facilitating production, which is not related to the gist of the present invention, is not particularly limited.

【0014】従来より広く一般的に用いられている混合
機や押出し成形機を用いて、これらの原料を均一に混合
し押出し成形を行う。これらの操作条件は使用する装置
に応じて最適条件を設定すれば良い。オートクレーブ処
理条件に関しても、得られる軽量無機質製品の品質レベ
ルと処理コストからその都度選択されるべきものであっ
て、特に限定するものではない。
These raw materials are uniformly mixed and extrusion-molded by using a mixer and an extrusion-molding machine which have been widely and generally used. Optimal conditions for these operating conditions may be set according to the device used. Regarding the autoclave treatment condition, it should be selected each time from the quality level of the obtained light weight inorganic product and the treatment cost, and is not particularly limited.

【0015】[0015]

【実施例】以下、本発明の実施例及び比較例を用いてさ
らに詳細に説明する。 (実施例)本発明で使用した材料は以下の通りである。
市販の普通ポルトランドセメント、秋田産の粒度150
メッシュ以下で水分15%以下のけいそう土、繊維長1
mm以下で水分8%以下の広葉樹(ユーカリ)パルプ、
市販のメチルセルロース。
EXAMPLES Hereinafter, the present invention and comparative examples will be described in more detail. (Example) The materials used in the present invention are as follows.
Commercially available ordinary Portland cement, grain size 150 from Akita
Diatomaceous earth with a mesh or less and a water content of 15% or less, fiber length 1
Hardwood (Eucalyptus) pulp with mm or less and a water content of 8% or less,
Commercially available methyl cellulose.

【0016】セメント、けいそう土、メチルセルロース
をニーダーで約1分混練後、パルプを添加してさらに約
2分混練し、水を添加してさらに約3分混練した後、真
空押出し成形機で成形し板状成形体を得た。
Cement, diatomaceous earth and methylcellulose were kneaded in a kneader for about 1 minute, then pulp was added and kneaded for about 2 minutes, water was added and kneaded for about 3 minutes, and then molded by a vacuum extrusion molding machine. A plate-shaped molded body was obtained.

【0017】ついで、この成形体を室内で1日間放置し
て取扱いのできる強度に達した後、オートクレーブで1
80℃−8時間反応させ、その後、乾燥機にて60℃−
2日間さらに100℃−数時間乾燥して所望の軽量無機
質製品を得た。
Then, the molded body was left indoors for one day to reach a strength at which it could be handled, and then it was autoclaved for 1 day.
80 ℃ -8 hours to react, then in the dryer 60 ℃-
Further drying for 2 days at 100 ° C for several hours gave the desired lightweight inorganic product.

【0018】配合については、けいそう土の含有率(乾
燥基体)及びけいそう土とパルプの重量比とに応じた配
合量を後述の表1から表4に示した。但し、各原料の配
合量は重量部で示した。
Regarding the blending, the blending amount depending on the content rate of diatomaceous earth (dry base) and the weight ratio of diatomaceous earth to pulp is shown in Tables 1 to 4 below. However, the blending amount of each raw material is shown in parts by weight.

【0019】けいそう土の含有率を20重量%とした配
合について表1に示す。
Table 1 shows a composition in which the content of diatomaceous earth is 20% by weight.

【0020】[0020]

【表1】 けいそう土の含有率を25重量%とした配合について表
2に示す。
[Table 1] Table 2 shows the composition with the diatomaceous earth content of 25% by weight.

【0021】[0021]

【表2】 けいそう土の含有率を35重量%とした配合について表
3に示す。
[Table 2] Table 3 shows the composition with the diatomaceous earth content of 35% by weight.

【0022】[0022]

【表3】 けいそう土の含有率を40重量%とした配合について表
4に示す。
[Table 3] Table 4 shows the composition in which the diatomaceous earth content is 40% by weight.

【0023】[0023]

【表4】 本発明の実施例で得られた軽量無機質製品の曲げ強度及
び釘打ち性と、けいそう土の含有率及びけいそう土とパ
ルプの重量比との関係について図1に示した。
[Table 4] The relationship between the bending strength and nailability of the lightweight inorganic products obtained in the examples of the present invention, the content of diatomaceous earth, and the weight ratio of diatomaceous earth to pulp are shown in FIG.

【0024】曲げ強度に関しては100kg/cm
上あれば実用上も問題ないことが分かった。また、釘打
ち時にクラックが入ることもなく容易に釘打ちできたも
のはプロットを黒塗りした。以上より図1を詳細に検討
した結果を以下に示す。
Regarding the bending strength, it has been found that there is no practical problem if it is 100 kg / cm 2 or more. In addition, plots were painted black for those that could be easily nailed without cracking during nailing. The results of a detailed examination of FIG. 1 are shown below.

【0025】けいそう土の含有率が20%及び40%で
は、曲げ強度が100kg/cm以上のプロットが全
く無く全体的に低い値を示したが、これは、含まれるC
aOとSiOのモル比が、CaO/SiO=0.7
〜1.2の範囲外にあるため、トバモライトの生成が有
効に行われないことが一因と考えられる。また、けいそ
う土の含有率が25%及び35%では、全体的に曲げ強
度が高い値を示していたが、けいそう土とパルプの重量
比が、パルプ/けいそう土=0.2未満では釘打ち性が
悪く、0.3を越えると曲げ強度が100kg/cm
以下に低下する。したがって、けいそう土の含有率が2
5%〜35%でかつ、けいそう土とパルプの重量比が、
パルプ/けいそう土=0.2〜0.3において曲げ強度
及び釘打ち性に優れた軽量無機質製品が得られ、これら
の比重を測定したところ1.0前後であり、押出し成形
性にも問題無かった。
At the diatomaceous earth contents of 20% and 40%, the bending strength was 100 kg / cm 2 or more, and there was no plot at all, which was a low value as a whole.
The molar ratio of aO to SiO 2 is CaO / SiO 2 = 0.7.
It is considered that one of the reasons is that the generation of tobermorite is not effectively performed because it is outside the range of 1.2. When the content of diatomaceous earth was 25% and 35%, the bending strength was generally high, but the weight ratio of diatomaceous earth to pulp was pulp / diatomaceous earth = less than 0.2. The nailability is poor, and if it exceeds 0.3, the bending strength is 100 kg / cm 2
It drops below. Therefore, the diatomaceous earth content is 2
5% to 35% and the weight ratio of diatomaceous earth to pulp is
When pulp / diatomaceous earth = 0.2 to 0.3, lightweight inorganic products excellent in bending strength and nailing property were obtained. The specific gravity of these products was about 1.0, and there was a problem with extrusion moldability. There was no

【0026】(比較例1)共通の使用材料は実施例と同
様とし、セメント100重量部、けいそう土30重量
部、メチルセルロース1重量部、アスベスト25重量部
及び必要量の水を一連の実施例と同様の方法で混練し、
押出し成形後、養生しオートクレーブで反応させ乾燥
後、無機質製品を得た。得られた無機質製品は曲げ強度
が101kg/cmで強度は十分であるが、比重1.
4で重く、ひじょうに硬いため釘打ちし難く無理に打つ
と割れが発生した。なお、押出し成形性には問題無かっ
た。
(Comparative Example 1) The common material used is the same as that of the embodiment, and 100 parts by weight of cement, 30 parts by weight of diatomaceous earth, 1 part by weight of methylcellulose, 25 parts by weight of asbestos and a necessary amount of water are used in a series of examples. Knead in the same way as
After extrusion molding, curing, reaction in an autoclave and drying, an inorganic product was obtained. The bending strength of the obtained inorganic product is 101 kg / cm 2, which is sufficient, but the specific gravity is 1.
No. 4 was heavy and very hard, so it was difficult to nail and a crack occurred when it was forcibly struck. There was no problem in extrusion moldability.

【0027】(比較例2)共通の使用材料は実施例と同
様とし、セメント100重量部、パーライト50重量
部、メチルセルロース3重量部、ポリプロピレン繊維5
重量部及び必要量の水を一連の実施例と同様の方法でに
混練し、押出し成形後、養生しオートクレーブで反応さ
せ乾燥後、無機質製品を得た。得られた無機質製品は比
重1.3で軽量化が不十分でパーライト添加の効果がな
く、曲げ強度が82kg/cmで強度の低下が大きか
った。釘打ち性は比較例1に比較して若干良かった。な
お、押出し成形性には問題無かった。
(Comparative Example 2) Commonly used materials are the same as those in the example, and 100 parts by weight of cement, 50 parts by weight of perlite, 3 parts by weight of methylcellulose, and polypropylene fiber 5 are used.
Parts by weight and the required amount of water were kneaded in the same manner as in a series of examples, extrusion-molded, cured, reacted in an autoclave and dried to obtain an inorganic product. The resulting inorganic product had a specific gravity of 1.3, was not sufficiently lightened, had no effect of adding pearlite, and had a large reduction in strength at a bending strength of 82 kg / cm 2 . The nailability was slightly better than that of Comparative Example 1. There was no problem in extrusion moldability.

【0028】以上の結果より、本発明に基ずく実施例に
おいては比較例に対して、軽量でかつ曲げ強度及び釘打
ち性に優れた軽量無機質製品が得られた。
From the above results, in the examples based on the present invention, lightweight inorganic products which were lighter in weight and excellent in bending strength and nailing property were obtained as compared with the comparative examples.

【0029】[0029]

【発明の効果】以上の説明から明らかなように、本発明
にかかる軽量無機質製品の製造方法によれば、実用強度
を低下することなく比重を従来に比較して約3割減少す
ることができると共に、釘打ち性に優れた軽量無機質製
品を得ることができる。また、製造工程において、有害
なアスベストを使用することなく容易に押出し成形がで
きるという効果が得られる。
As is apparent from the above description, according to the method for manufacturing a lightweight inorganic product of the present invention, the specific gravity can be reduced by about 30% as compared with the conventional one without lowering the practical strength. At the same time, it is possible to obtain a lightweight inorganic product having excellent nailing properties. In addition, in the manufacturing process, there is an effect that extrusion molding can be easily performed without using harmful asbestos.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の実施例で得られた軽量無機質製品の曲
げ強度と、けいそう土の含有率及びけいそう土とパルプ
の重量比との関係を表す図である。
FIG. 1 is a diagram showing the relationship between the bending strength, the diatomaceous earth content, and the weight ratio of diatomaceous earth to pulp of the lightweight inorganic products obtained in the examples of the present invention.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 //(C04B 28/18 14:08 2102−4G 16:02 Z 2102−4G 24:38) A 2102−4G ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Internal reference number FI Technical display area // (C04B 28/18 14:08 2102-4G 16:02 Z 2102-4G 24:38) A 2102-4G

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 セメントと、けいそう土と、パルプと、
水とを必須成分とした混合物において、含まれるCaO
とSiOのモル比を、CaO/SiO=0.7〜
1.2とし、けいそう土の含有率を25〜35重量%と
し、けいそう土とパルプの重量比を、パルプ/けいそう
土=0.2〜0.3とし、該混合物を押出し成形した
後、オートクレーブ処理してカルシウムシリケート水和
物を生成させることを特徴とする軽量無機質製品の製造
方法。
1. Cement, diatomaceous earth, pulp,
CaO contained in a mixture containing water as an essential component
And SiO 2 molar ratio is CaO / SiO 2 = 0.7-
1.2, the diatomaceous earth content was 25 to 35% by weight, the diatomaceous earth to pulp weight ratio was pulp / diatomaceous earth = 0.2 to 0.3, and the mixture was extruded. Then, a method for producing a lightweight inorganic product, which comprises subjecting it to an autoclave treatment to produce a calcium silicate hydrate.
JP13645493A 1993-05-14 1993-05-14 Manufacturing method of lightweight inorganic products Expired - Fee Related JP3378610B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13645493A JP3378610B2 (en) 1993-05-14 1993-05-14 Manufacturing method of lightweight inorganic products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13645493A JP3378610B2 (en) 1993-05-14 1993-05-14 Manufacturing method of lightweight inorganic products

Publications (2)

Publication Number Publication Date
JPH06321656A true JPH06321656A (en) 1994-11-22
JP3378610B2 JP3378610B2 (en) 2003-02-17

Family

ID=15175496

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13645493A Expired - Fee Related JP3378610B2 (en) 1993-05-14 1993-05-14 Manufacturing method of lightweight inorganic products

Country Status (1)

Country Link
JP (1) JP3378610B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006044991A (en) * 2004-08-04 2006-02-16 Matsushita Electric Works Ltd Method of manufacturing ceramic building material
JP2006076874A (en) * 2004-08-11 2006-03-23 Kuraray Co Ltd Non-asbestos hydraulic sheet

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006044991A (en) * 2004-08-04 2006-02-16 Matsushita Electric Works Ltd Method of manufacturing ceramic building material
JP2006076874A (en) * 2004-08-11 2006-03-23 Kuraray Co Ltd Non-asbestos hydraulic sheet
JP4667998B2 (en) * 2004-08-11 2011-04-13 株式会社クラレ Non-asbestos hydraulic paperboard

Also Published As

Publication number Publication date
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