JPH06297100A - Vertical type continuous casting method for metal and device therefor - Google Patents
Vertical type continuous casting method for metal and device thereforInfo
- Publication number
- JPH06297100A JPH06297100A JP11391693A JP11391693A JPH06297100A JP H06297100 A JPH06297100 A JP H06297100A JP 11391693 A JP11391693 A JP 11391693A JP 11391693 A JP11391693 A JP 11391693A JP H06297100 A JPH06297100 A JP H06297100A
- Authority
- JP
- Japan
- Prior art keywords
- molten metal
- inert gas
- mold
- ingot
- pit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Continuous Casting (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は金属の竪型連続鋳造方法
とその装置に関し、特に溶湯状態の金属の酸化を防いで
鋳塊の品質を向上させたものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for vertical casting of metal and its apparatus, and more particularly to improving the quality of ingot by preventing the oxidation of molten metal.
【0002】[0002]
【従来の技術】非鉄金属特にアルミニウム及びその合金
の圧延、押出、鍛造用の鋳塊は大部分が連続鋳造法、特
に竪型連続鋳造法により製造されている。この方法の一
つは所謂DC鋳造と呼ばれるもので、上下開放鋳型内に
その上方の出湯ノズルから溶湯を供給し、鋳型内の溶湯
上に配した浮子式の溶湯分配装置により出湯量を制御し
つつ、鋳型内壁から抜熱することで凝固殻を形成し、さ
らに鋳型下部から冷却剤を噴射しつつ鋳塊を引き出すこ
とで完全に凝固させる鋳造法である。この際、鋳型と鋳
塊との摩擦を減少させるために、潤滑剤を鋳型内面に事
前に塗布したり鋳造中に連続的に供給したりする。Most of the ingots for rolling, extrusion and forging of non-ferrous metals, especially aluminum and its alloys, are manufactured by a continuous casting method, especially a vertical continuous casting method. One of the methods is so-called DC casting, in which the molten metal is supplied into the upper and lower open molds from the molten metal nozzle above, and the amount of molten metal is controlled by a float type molten metal distributor arranged on the molten metal in the mold. Meanwhile, it is a casting method in which the solidified shell is formed by removing heat from the inner wall of the mold, and the ingot is pulled out while injecting the coolant from the lower part of the mold to completely solidify. At this time, in order to reduce the friction between the mold and the ingot, the lubricant is applied to the inner surface of the mold in advance or continuously supplied during casting.
【0003】この方法の問題点の一つは、鋳型内溶湯の
表面が大気に接しているため、反応性の強い溶湯の場合
は鋳型内溶湯面において大気中の酸素等と反応し、酸化
物を生成してしまうことにある。生成した酸化物が鋳塊
表面や鋳塊内部に混入すると鋳塊品質の著しい劣化をま
ねくだけでなく、酸化物量が多すぎると鋳塊の冷却が不
均一となるため、溶湯が凝固しきれなくなり鋳型の下部
から湯漏れが生じて鋳造が不可能となる。特に非常に反
応性の強いAl−Li系合金溶湯では、酸化物の生成が
著しく大気雰囲気での鋳造は不可能である。One of the problems of this method is that since the surface of the molten metal in the mold is in contact with the atmosphere, in the case of a highly reactive molten metal, it reacts with oxygen in the atmosphere on the surface of the molten metal in the mold to form oxides. Is generated. If the produced oxide mixes on the surface of the ingot or inside the ingot, not only will the quality of the ingot be significantly deteriorated, but if the amount of oxide is too large, the ingot will be cooled unevenly and the molten metal will not be able to solidify. Molten metal leaks from the bottom of the mold, making casting impossible. In particular, in the case of an Al-Li alloy melt having a very strong reactivity, the formation of oxides is remarkable, and casting in an air atmosphere is impossible.
【0004】また他の問題点は、Al−Li系合金溶湯
のような反応性の強い溶湯の場合、潤滑油と溶湯とが反
応し煙を発生することである。煙が発生すると、鋳型内
溶湯面が監視できないため鋳造作業が非常に困難かある
いは全く不可能になる。Another problem is that in the case of a highly reactive melt such as an Al-Li alloy melt, the lubricating oil reacts with the melt to generate smoke. When smoke is generated, the casting operation is very difficult or even impossible because the surface of the molten metal in the mold cannot be monitored.
【0005】上記2点の問題は単独では解決の可能性が
あるものの、それぞれの解決法が他の問題点をより深刻
化してしまう。即ち大気との反応を抑制すべく鋳型上部
に透明の囲いを設け、その内部を不活性ガスで置換する
と、発生した煙の排出が不可能になるため内部が全く監
視不能になってしまう。逆に煙の排出を効率よく行うべ
く溶湯表面に気流を発生させると、たとえ不活性ガス気
流であろうと大気を巻き込むため、溶湯と大気との接触
効率が高まり、酸化物生成が助長されてしまう。Although the above two problems may be solved by themselves, each solution makes other problems more serious. That is, if a transparent enclosure is provided on the upper part of the mold in order to suppress reaction with the atmosphere and the interior is replaced with an inert gas, the smoke produced cannot be discharged, and the interior cannot be monitored at all. On the contrary, if an air flow is generated on the surface of the molten metal in order to efficiently discharge smoke, the atmosphere will be involved even if it is an inert gas stream, so the efficiency of contact between the molten metal and the atmosphere will be increased, and oxide formation will be promoted. .
【0006】[0006]
【発明が解決しようとする課題】本発明の目的は、鋳型
内溶湯の表面を不活性ガスで保護することで酸化反応を
抑制し、なお且つ潤滑油と溶湯との反応により生成する
煙を効果的に排出することで、内部の監視が可能な竪型
連続鋳造方法とその装置を提供することにある。An object of the present invention is to suppress the oxidation reaction by protecting the surface of the molten metal in the mold with an inert gas and to effectively produce smoke produced by the reaction between the lubricating oil and the molten metal. The object of the present invention is to provide a vertical continuous casting method and apparatus capable of monitoring the inside by discharging the material.
【0007】[0007]
【課題を解決するための手段】即ち本発明の方法は、上
下に開放した筒状鋳型内に上方から金属溶湯を供給し、
凝固した鋳塊を下方へ引き抜く竪型連続鋳造方法におい
て、溶湯上面を強制排気させられ且つ正圧状態に保持さ
れた不活性ガスで覆うことを特徴とするものである。[Means for Solving the Problems] That is, according to the method of the present invention, a molten metal is supplied from above into a cylindrical mold that is open vertically.
In a vertical continuous casting method in which a solidified ingot is drawn downward, the molten metal upper surface is forcibly evacuated and covered with an inert gas that is maintained in a positive pressure state.
【0008】また本発明の装置は、上下に開放した筒状
鋳型と、該鋳型内に上方から供給される金属溶湯に冷却
剤を噴射してこれを凝固する冷却装置と、鋳塊を下方に
引き抜くシリンダーと、引き抜かれる鋳塊を内部に収容
しその内部雰囲気を排気する排気装置を備えたピットを
有し、さらに上記溶湯上面部を覆い不活性ガスの流入口
と排気口を備えた雰囲気カバーを設け、且つ該排気口を
上記ピット内に連通したことを特徴とするものであり、
この際上記雰囲気カバーの一部を透明材質で形するのは
有効である。Further, the apparatus of the present invention comprises a cylindrical mold which is opened up and down, a cooling device which injects a cooling agent into a molten metal which is supplied into the mold from above and solidifies the molten metal, and an ingot is moved downward. Atmosphere cover having a cylinder for drawing out and a pit equipped with an exhaust device for accommodating the ingot to be drawn out and exhausting the internal atmosphere, and further having an inlet for inert gas and an exhaust port for covering the upper surface of the molten metal Is provided, and the exhaust port is communicated with the inside of the pit,
At this time, it is effective to form a part of the atmosphere cover with a transparent material.
【0009】[0009]
【作用】鋳型内溶湯の表面における酸化反応を抑制する
ためには、鋳型上面を不活性ガスで置換する必要があ
る。確実な雰囲気制御のためには、さらに鋳型上面にカ
バーを設け、その内部を不活性ガス雰囲気としなくては
ならない。そしてカバーの一部は透明な材質とし、内部
が監視できるようにする。In order to suppress the oxidation reaction on the surface of the molten metal in the mold, it is necessary to replace the upper surface of the mold with an inert gas. In order to reliably control the atmosphere, it is necessary to further provide a cover on the upper surface of the mold and make the inside thereof an inert gas atmosphere. Part of the cover is made of transparent material so that the inside can be monitored.
【0010】ところがカバーを設けることで、発生する
煙の排出が不可能となってしまう。そこでこの問題を解
決するためにはカバーに不活性ガスの導入口と排気口と
を設け、カバー内部が不活性ガス流により換気されるよ
うにすればよい。However, the provision of the cover makes it impossible to discharge the generated smoke. Therefore, in order to solve this problem, an inlet and an outlet for the inert gas may be provided in the cover so that the inside of the cover is ventilated by the flow of the inert gas.
【0011】しかしながら充分な換気を行うためには不
活性ガス流量も多くなり、従ってガス流量の増加にとも
ないカバー内部の圧力も上昇する。竪型連続鋳造特に所
謂DC鋳造の場合、鋳型内面と鋳塊との間には常に部分
的な隙間が生じているが、カバー内部即ち鋳型内溶湯面
での圧力が上昇すると、鋳型内面と鋳塊との隙間から不
活性ガスが鋳型下部に流出してしまう。このようにガス
の流出が生じると、鋳型下端から噴射される冷却剤と鋳
塊との隙間に不活性ガス膜が不均一に形成されてしま
い、凝固が不均一になるため鋳塊品質が劣化し、さらに
鋳塊に割れが発生し、最終的には鋳型下部から凝固しき
れない溶湯が漏れだし、鋳造が不可能になってしまう。However, in order to perform sufficient ventilation, the flow rate of the inert gas also increases, so that the pressure inside the cover rises as the gas flow rate increases. In vertical continuous casting, especially in so-called DC casting, there is always a partial gap between the inner surface of the mold and the ingot, but when the pressure inside the cover, that is, the molten metal surface in the mold increases, the inner surface of the mold and the casting The inert gas flows out to the lower part of the mold through the gap with the lump. When the gas flows out in this way, an inert gas film is unevenly formed in the gap between the coolant injected from the lower end of the mold and the ingot, and the ingot quality deteriorates because the solidification becomes uneven. Moreover, cracks occur in the ingot, and the molten metal that does not solidify finally leaks from the lower part of the mold, making casting impossible.
【0012】そこで不活性ガス流量を増大したままカバ
ー内部の圧力上昇を防止するためには排気口を大きくす
ることが考えられる。しかし、排気口を大きくすると外
気の逆流が生じてしまうという問題、さらに不活性がス
流量の増大が必要になるという問題が生ずる。そして不
活性ガス流量の極端な増大は、不経済なだけでなく、鋳
塊品質維持のために適切に制御すべき鋳型内の溶湯温度
の低下を生じることになる。Therefore, it is conceivable to enlarge the exhaust port in order to prevent the pressure inside the cover from rising while the flow rate of the inert gas is increased. However, if the exhaust port is enlarged, there is a problem that a backflow of outside air occurs, and further, there is a problem that inertness requires an increase in flow rate. Then, the extreme increase in the flow rate of the inert gas is not only uneconomical, but also causes a decrease in the melt temperature in the mold that must be properly controlled to maintain the quality of the ingot.
【0013】またカバー内部の圧力上昇を防止するため
の他の手段として、排気口からの強制排気が考えられ
る。しかしカバー内部の圧力を適切且つ一定に保つため
には、流入する不活性ガス量と排気量との流量バランス
を厳密に制御しなくてはならず、極めて困難が伴う。即
ちもし排気量が不活性ガス流入量を上回ると、カバー内
部が負圧になってしまう。このような場合は、鋳型内面
と鋳塊との隙間から冷却剤が鋳型上部に侵入し、冷却剤
と溶湯とが直接接触してしまい、爆発の可能性が生じ極
めて危険である。Further, as another means for preventing the pressure increase inside the cover, forced exhaust from the exhaust port can be considered. However, in order to keep the pressure inside the cover appropriate and constant, the flow rate balance between the inflowing inert gas amount and the exhaust gas amount must be strictly controlled, which is extremely difficult. That is, if the exhaust amount exceeds the inert gas inflow amount, the inside of the cover becomes negative pressure. In such a case, the coolant penetrates into the upper part of the mold through the gap between the inner surface of the mold and the ingot, and the coolant and the molten metal come into direct contact with each other, possibly causing an explosion, which is extremely dangerous.
【0014】従ってこれらの問題解決のためには、必要
な不活性ガス流量を確保しつつ、カバー内部を安定して
若干の正圧になるように、不活性ガス流入量と排気量と
のバランスを制御しなくてはならない。Therefore, in order to solve these problems, a balance between the inflow amount of the inert gas and the exhaust amount is ensured so that a necessary positive flow rate of the inert gas is secured and the inside of the cover is stably maintained at a slight positive pressure. Must be controlled.
【0015】ところで竪型連続鋳造設備特に所謂DC鋳
造設備においては、製造される鋳塊は鋳型の下方に設け
たピット内に引き抜かれる場合がほとんどである。そし
て連続鋳造に用いる冷却剤はほとんどの場合、水あるい
は何らかの水溶液であって高温の鋳塊と接して水蒸気が
多量に発生するため、通常ピット内を強制排気する。By the way, in the vertical continuous casting equipment, especially the so-called DC casting equipment, the ingot to be produced is almost always drawn into a pit provided below the mold. In most cases, the coolant used for continuous casting is water or some kind of aqueous solution, and a large amount of water vapor is generated in contact with the high temperature ingot.
【0016】本発明者らはこのピット内の強制排気に着
目した。即ち雰囲気制御用のカバーに設けた排気口の排
気管をピット内に導くことで、排気量の制御が自動的に
可能になることを見いだした。これは強制排気されてい
るピットにカバー内部が連通しているため、カバー内が
外部特に鋳型の下方のピット内より負圧になることはあ
りえず、さらにカバー内には不活性ガスが流入するた
め、外部特に鋳型下方のピット内よりも若干の正圧が維
持されるからである。このようにピット内の強制排気を
利用することで、必要な不活性ガス流量を確保しつつ、
カバー内部を安定して若干の正圧になるように換気する
ことが可能になり本発明の完成に至った。The present inventors have paid attention to the forced exhaust in the pit. That is, it was found that the exhaust amount can be automatically controlled by introducing the exhaust pipe of the exhaust port provided in the atmosphere control cover into the pit. This is because the inside of the cover communicates with the pit that is forcibly evacuated, so the inside of the cover cannot become a negative pressure than the outside, especially inside the pit below the mold, and the inert gas flows into the cover. Therefore, a slight positive pressure is maintained outside, especially in the pit below the mold. By using the forced exhaust in the pit in this way, while securing the necessary inert gas flow rate,
It has become possible to ventilate the inside of the cover in a stable manner so as to have a slight positive pressure, thus completing the present invention.
【0017】[0017]
【実施例】以下図面に示す実施例に沿って説明する。図
1は連続鋳造状態における本発明に係る装置の一つの実
施例の説明図である。溶湯は出湯ノズル(1)を通り、
浮子式溶湯分配装置(2)により出湯量を制御しつつ、
上下開放鋳型(3)に供給される。冷却剤は図示しない
冷却剤供給管を通って鋳型(3)内の冷却剤室(4)に
導かれ、さらにスリット(5)を通って鋳塊(6)に噴
射され、鋳塊(6)は底台(7)とともにシリンダー
(8)によつて下方のピット(9)内に引き出される。
また鋳型と鋳塊との摩擦を減少するために、潤滑剤を鋳
型内面に事前に塗布し、あるいは鋳造中に潤滑油供給口
(10)より連続的に供給する。Embodiments will be described below with reference to embodiments shown in the drawings. FIG. 1 is an explanatory view of one embodiment of the apparatus according to the present invention in a continuous casting state. The molten metal passes through the tap nozzle (1),
While controlling the amount of molten metal discharged by the float type molten metal distributor (2),
It is supplied to the upper and lower open mold (3). The coolant is guided to a coolant chamber (4) in the mold (3) through a coolant supply pipe (not shown), further injected through a slit (5) to the ingot (6), and the ingot (6). Is pulled out into the lower pit (9) by the cylinder (8) together with the base (7).
Further, in order to reduce the friction between the mold and the ingot, a lubricant is applied to the inner surface of the mold in advance or is continuously supplied from the lubricating oil supply port (10) during casting.
【0018】この際、鋳型(3)の上面に雰囲気カバー
(11)を設置し、該カバー(11)の不活性ガス流入口
(12)より不活性ガスを流入することでカバー(11)の
内部を不活性ガス雰囲気として溶湯(16)表面の酸化を
防止する。また鋳型内部が監視できるようにするため、
カバー(11)の上面は透明な材質の監視窓(13)とす
る。さらに潤滑油と溶湯とが反応して発生する煙が換気
されるよう強制排気用の排気管(14)をカバー(11)の
他端に設け、排気管(14)はピット内に導く。At this time, an atmosphere cover (11) is installed on the upper surface of the mold (3), and an inert gas is introduced from an inert gas inlet port (12) of the cover (11) to cover the cover (11). The inside is made an inert gas atmosphere to prevent the surface of the molten metal (16) from being oxidized. Also, in order to be able to monitor the inside of the mold,
The upper surface of the cover (11) is a monitoring window (13) made of a transparent material. Further, an exhaust pipe (14) for forced exhaust is provided at the other end of the cover (11) so that smoke generated by the reaction of the lubricating oil and the molten metal is ventilated, and the exhaust pipe (14) is introduced into the pit.
【0019】そしてカバー(11)内の強制排気はピット
(9)内の強制排気ダクト(15)によりピット内排気と
同時に行う。このためカバー(11)内部が外部特に鋳型
(3)の下方のピット内より負圧になることはありえ
ず、さらにカバー(11)内部には不活性ガスが流入する
ため、外部特に鋳型(3)の下部よりも若干の正圧が維
持される。このようにカバー(11)内部の安定した圧力
制御により、確実な雰囲気制御と安定な鋳造条件の維持
が可能となる。The forced exhaust in the cover (11) is performed simultaneously with the exhaust in the pit by the forced exhaust duct (15) in the pit (9). For this reason, the inside of the cover (11) cannot have a negative pressure from the outside, especially from the inside of the pit below the mold (3), and since the inert gas flows into the inside of the cover (11), the outside, especially the mold (3) ) A slight positive pressure is maintained than the lower part. Thus, stable pressure control inside the cover (11) enables reliable atmosphere control and stable maintenance of casting conditions.
【0020】図1に示す本発明の装置により、表1に示
す条件にて 150mm×350mm のサイズのAA8090合金を鋳造
した。AA8090合金はLiをおよそ 2.5%含み、極めて酸
化性が強いため、本発明の効果を確認するのに最適の合
金である。比較例1として本発明例と同様の条件だが、
ピット内排気のみを停止して鋳造した例を示し、また比
較例2として本発明例と同様の条件だが、カバー内部を
Ar置換した後不活性ガス流入口、排気口とも閉塞し鋳
型内の換気を停止して鋳造した。これらの鋳造装置によ
り連続鋳造を行いその結果を表2に示した。Using the apparatus of the present invention shown in FIG. 1, an AA8090 alloy having a size of 150 mm × 350 mm was cast under the conditions shown in Table 1. The AA8090 alloy contains Li in an amount of about 2.5% and has an extremely strong oxidative property, and is therefore an optimum alloy for confirming the effect of the present invention. As Comparative Example 1, under the same conditions as those of the present invention,
An example in which only the exhaust in the pit is stopped and casting is performed is shown. Further, as Comparative Example 2, under the same conditions as in the example of the present invention, after the inside of the cover is replaced with Ar, the inert gas inlet port and the exhaust port are closed to ventilate the mold. Stopped and casted. Continuous casting was performed using these casting devices, and the results are shown in Table 2.
【0021】[0021]
【表1】 [Table 1]
【0022】[0022]
【表2】 [Table 2]
【0023】表2より本発明例によれば健全な鋳塊を製
造できたのに対し、比較例1及び2では鋳塊製造自体が
不可能であり、鋳塊品質の比較すらできなかった。From Table 2, according to the example of the present invention, a sound ingot could be produced, whereas in Comparative Examples 1 and 2, ingot production itself was impossible, and even comparison of ingot quality was not possible.
【0024】[0024]
【発明の効果】本発明によれば酸化性の強い金属溶湯で
あっても、連続鋳造により健全な鋳塊が安定して製造で
きる等の顕著な効果がある。なお本発明は実施例に示し
た装置に限定されものではなく、同様な思想のいかなる
装置にも適用されるものである。EFFECTS OF THE INVENTION According to the present invention, even a molten metal having a strong oxidizing property has a remarkable effect that a sound ingot can be stably produced by continuous casting. The present invention is not limited to the device shown in the embodiment, but can be applied to any device having a similar idea.
【図1】本発明の実施例を示す説明図である。FIG. 1 is an explanatory diagram showing an embodiment of the present invention.
1 出湯ノズル 2 浮子式溶湯分配装置 3 上下開放鋳型 4 冷却剤室 5 スリット 6 鋳塊 7 底台 8 シリンダー 9 ピット 10 潤滑油供給口 11 雰囲気カバー 12 不活性ガス流入口 13 監視窓 14 排気管 15 強制排気ダクト 16 溶湯 1 Hot-water Nozzle 2 Float-type Molten Metal Distributor 3 Vertical Open Mold 4 Coolant Chamber 5 Slit 6 Ingot 7 Bottom Stand 8 Cylinder 9 Pit 10 Lubricant Supply Port 11 Atmosphere Cover 12 Inert Gas Inlet 13 Monitoring Window 14 Exhaust Pipe 15 Forced exhaust duct 16 Molten metal
Claims (3)
属溶湯を供給し、凝固した鋳塊を下方へ引き抜く竪型連
続鋳造方法において、溶湯上面を強制排気させられ且つ
正圧状態に保持された不活性ガスで覆うことを特徴とす
る金属の竪型連続鋳造方法。1. In a vertical continuous casting method in which a molten metal is supplied from above into a vertically open cylindrical mold and a solidified ingot is drawn out downward, the molten metal upper surface is forcibly exhausted and kept in a positive pressure state. A vertical continuous casting method for metal, which is characterized in that it is covered with the inert gas.
上方から供給される金属溶湯に冷却剤を噴射してこれを
凝固する冷却装置と、鋳塊を下方に引き抜くシリンダー
と、引き抜かれる鋳塊を内部に収容しその内部雰囲気を
排気する排気装置を備えたピットを有し、さらに上記溶
湯上面部を覆い不活性ガスの流入口と排気口を備えた雰
囲気カバーを設け、且つ該排気口を上記ピット内に連通
したことを特徴とする金属の竪型連続鋳造装置。2. A cylindrical mold opened vertically, a cooling device for injecting a cooling agent into a molten metal supplied from above into the mold to solidify it, a cylinder for pulling out an ingot downward, and a withdrawal. A pit having an exhaust device for accommodating the ingot to be exhausted therein and for exhausting the internal atmosphere, and further, providing an atmosphere cover having an inflow port and an exhaust port for the inert gas, which covers the upper surface of the molten metal, and A vertical vertical metal casting apparatus having an exhaust port communicating with the inside of the pit.
成した請求項2記載の竪型連続鋳造装置。3. The vertical continuous casting apparatus according to claim 2, wherein a part of the atmosphere cover is made of a transparent material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11391693A JP3171723B2 (en) | 1993-04-16 | 1993-04-16 | Vertical continuous casting method and apparatus for metal |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11391693A JP3171723B2 (en) | 1993-04-16 | 1993-04-16 | Vertical continuous casting method and apparatus for metal |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH06297100A true JPH06297100A (en) | 1994-10-25 |
JP3171723B2 JP3171723B2 (en) | 2001-06-04 |
Family
ID=14624408
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11391693A Expired - Lifetime JP3171723B2 (en) | 1993-04-16 | 1993-04-16 | Vertical continuous casting method and apparatus for metal |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3171723B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101305994B1 (en) * | 2013-01-28 | 2013-09-12 | (주)티씨씨특수합금 | Oxidation-proof enclosed in the mold of an inert gas blowing device |
JP2015520029A (en) * | 2012-05-17 | 2015-07-16 | アルメックス ユーエスエー, インコーポレイテッド | Process and method for minimizing the potential for explosion in direct chill casting of aluminum lithium alloy |
JP2016513017A (en) * | 2013-02-04 | 2016-05-12 | アルメックス ユーエスエー, インコーポレイテッド | Process and equipment for direct chill casting |
JP2017505378A (en) * | 2013-12-13 | 2017-02-16 | コンステリウム イソワールConstellium Issoire | Method for producing an aluminum-copper-lithium alloy product with improved fatigue properties |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101790844B1 (en) * | 2015-08-06 | 2017-10-26 | 서울대학교산학협력단 | Cultivation version sterilization of young leaf vegetables |
-
1993
- 1993-04-16 JP JP11391693A patent/JP3171723B2/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015520029A (en) * | 2012-05-17 | 2015-07-16 | アルメックス ユーエスエー, インコーポレイテッド | Process and method for minimizing the potential for explosion in direct chill casting of aluminum lithium alloy |
KR101305994B1 (en) * | 2013-01-28 | 2013-09-12 | (주)티씨씨특수합금 | Oxidation-proof enclosed in the mold of an inert gas blowing device |
JP2016513017A (en) * | 2013-02-04 | 2016-05-12 | アルメックス ユーエスエー, インコーポレイテッド | Process and equipment for direct chill casting |
JP2017505378A (en) * | 2013-12-13 | 2017-02-16 | コンステリウム イソワールConstellium Issoire | Method for producing an aluminum-copper-lithium alloy product with improved fatigue properties |
JP2017507240A (en) * | 2013-12-13 | 2017-03-16 | コンステリウム イソワールConstellium Issoire | Aluminum-copper-lithium alloy products with improved fatigue properties |
Also Published As
Publication number | Publication date |
---|---|
JP3171723B2 (en) | 2001-06-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4504914B2 (en) | Aluminum ingot manufacturing method, aluminum ingot, and protective gas for manufacturing aluminum ingot | |
KR100416668B1 (en) | Steel strip casting method and casting apparatus | |
JP3003914B2 (en) | Method for producing copper alloy containing active metal | |
RU2141883C1 (en) | Apparatus for horizontal direct metal casting to metal mold or permanent mold, metal mold or permanent mold | |
US2734240A (en) | Vacuum pouring apparatus | |
JPH06297100A (en) | Vertical type continuous casting method for metal and device therefor | |
US4541865A (en) | Continuous vacuum degassing and casting of steel | |
JP2797829B2 (en) | Tundish infusion tube | |
CA1092779A (en) | Lead casting seal | |
JPS61259855A (en) | Gas venting device in casting | |
CN111715855B (en) | Casting method for 1Cr17Ni2 or 5CrNiMoV steel ingot | |
CA1226717A (en) | Continuous vacuum degassing and casting of steel | |
JPH0824996A (en) | Vertical type continuous casting method for metal billet and apparatus thereof | |
JP3115189B2 (en) | Vertical continuous casting of metal | |
CA2047384C (en) | Method and apparatus for hot top casting of reactive metals | |
Wang | Aluminum alloy ingot casting and continuous processes | |
CN219233948U (en) | Ladle for vacuum ingot casting | |
US4848755A (en) | Apparatus for adding liquid alloying ingredient to molten steel | |
JPH0531568A (en) | Plasma melting/casting method | |
JPS60250860A (en) | Continuous casting method of active molten metal | |
EP0332751B1 (en) | Method for adding liquid alloying ingredient to molten steel | |
JP5612881B2 (en) | Magnesium alloy continuous casting method and continuous casting apparatus, and magnesium alloy billet | |
JPH01313165A (en) | Continuous casting method partially containing semi-molten metal | |
KR101175631B1 (en) | System for refining continuous casting materials and method thereof | |
JPH0824995A (en) | Vertical type continuous casting method for metal and apparatus thereof |