JPH0621312A - Manufacture of package - Google Patents

Manufacture of package

Info

Publication number
JPH0621312A
JPH0621312A JP4177286A JP17728692A JPH0621312A JP H0621312 A JPH0621312 A JP H0621312A JP 4177286 A JP4177286 A JP 4177286A JP 17728692 A JP17728692 A JP 17728692A JP H0621312 A JPH0621312 A JP H0621312A
Authority
JP
Japan
Prior art keywords
pins
package
brazing material
pin
ceramic substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4177286A
Other languages
Japanese (ja)
Other versions
JP3049948B2 (en
Inventor
Masahito Hirozawa
雅仁 廣澤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujitsu Ltd
Fujitsu Integrated Microtechnology Ltd
Original Assignee
Fujitsu Ltd
Fujitsu Integrated Microtechnology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujitsu Ltd, Fujitsu Integrated Microtechnology Ltd filed Critical Fujitsu Ltd
Priority to JP4177286A priority Critical patent/JP3049948B2/en
Publication of JPH0621312A publication Critical patent/JPH0621312A/en
Application granted granted Critical
Publication of JP3049948B2 publication Critical patent/JP3049948B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48151Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48245Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • H01L2224/48247Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a bond pad of the item
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/484Connecting portions
    • H01L2224/48463Connecting portions the connecting portion on the bonding area of the semiconductor or solid-state body being a ball bond
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/80Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
    • H01L2224/85Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a wire connector
    • H01L2224/85909Post-treatment of the connector or wire bonding area
    • H01L2224/8592Applying permanent coating, e.g. protective coating
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/15Details of package parts other than the semiconductor or other solid state devices to be connected
    • H01L2924/161Cap
    • H01L2924/1615Shape
    • H01L2924/16195Flat cap [not enclosing an internal cavity]

Landscapes

  • Lead Frames For Integrated Circuits (AREA)

Abstract

PURPOSE:To smoothen the surface of an Ni member considerably to prevent creeping-up of brazing material by performing a heat treatment in a reducing atmosphere containing a specific amount of hydrogen after forming Ni pins, Ni-plated Mo studs or the like. CONSTITUTION:In producing Ni pins that are put in the ceramic substrate of a package, nail-head Ni pins or straight pins are formed first. Then, the Ni pins are placed in a furnace to be heated at 900-950 deg.C in a reducing atmosphere containing a part of hydrogen and one to three parts of nitrogen. As a result, the Ni pins have mat-finished surfaces 1-mum thick or thinner. The surfaces are much smoother than the unheated surfaces. Brazing material is applied to the Ni pins and the ceramic substrate, and a PGA ceramic package is completed. Due to the very smooth Ni surface, creeping-up of molten brazing material is prevented. This prevents heavily brazed portions plated with Ni and expansion in the diffusion process, and can reduce the amount of brazing material.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は,PGA(Pin Gr
id Allay)タイプのセラミックパッケージ等の
製造方法に関する。
The present invention relates to a PGA (Pin Gr)
The present invention relates to a method for manufacturing a ceramic package or the like of an id Array type.

【0002】近年,半導体デバイスの高集積化にともな
い,ピン数の多いPGAタイプのパッケージが多く使用
され,信頼性の高い開発技術が必要とされている。
In recent years, with the high integration of semiconductor devices, PGA type packages with a large number of pins are often used, and a highly reliable development technique is required.

【0003】[0003]

【従来の技術】図4,図5は従来例の説明図である。図
において,1はパッケージ,2はセラミック基板,3は
Niピン,12はプリント基板である。
2. Description of the Related Art FIGS. 4 and 5 are explanatory views of a conventional example. In the figure, 1 is a package, 2 is a ceramic substrate, 3 is a Ni pin, and 12 is a printed circuit board.

【0004】従来,PGAタイプのセラミックパッケー
ジにおいて,図4に示すように,パッケージ1をプリン
ト基板12に半田付けして,パッケージ内のLSIチップ
とプリント基板の配線接続を行なうピンの材質には,K
OVAR(コバール)が多く用いられてきた。
Conventionally, in a PGA type ceramic package, as shown in FIG. 4, when the package 1 is soldered to the printed board 12, the material of the pins for connecting the wiring between the LSI chip in the package and the printed board is as follows. K
OVAR (Kovar) has been widely used.

【0005】しかし,表面実装されるプリント基板12と
パッケージ1との熱伝導率(NiはKOVERの5倍程
度)の差が問題となる多ピン,微細ピッチの最近のパッ
ケージでは,しばしばニッケル(Ni)ピン3が使用さ
れる。
However, in a recent multi-pin, fine-pitch package in which the difference in thermal conductivity between the surface-mounted printed circuit board 12 and the package 1 (Ni is about 5 times KOVER) is a problem, nickel (Ni) is often used. ) Pin 3 is used.

【0006】[0006]

【発明が解決しようとする課題】しかし,Niピン3を
使用した場合には,次のような問題が発生する。図5
(a)に示すように,Niピン3のロー付けは,一般に
800〜900 ℃で行なわれるが, その際,図5(b)に示
すようにNiピン3の頭部から軸方向にロー材5が這い
上がり, そのため, セラミック基板2とNiピン3の接
合部のロー材5が不足する。
However, when the Ni pin 3 is used, the following problems occur. Figure 5
As shown in (a), brazing of the Ni pin 3 is generally performed.
It is carried out at 800 to 900 ° C. At that time, the brazing material 5 crawls from the head of the Ni pin 3 in the axial direction as shown in Fig. 5 (b). Lack of brazing material 5.

【0007】その対策として, 図5(c)に示すよう
に,ロー材5の量を多くすると, ロー付けするロー材5
のセラミック基板2との境界部分で, セラミック基板2
にクラックが発生してしまう。
As a countermeasure, as shown in FIG. 5 (c), when the amount of the brazing material 5 is increased, the brazing material 5 to be brazed is increased.
At the boundary with the ceramic substrate 2 of
Will crack.

【0008】本発明は, Niピン3等のセラミック基板
2への半田付けにおいて,Niピン3へのロー材の這い
上がり防止し,高品質のセラミック基板2を得ることを
目的とする。
It is an object of the present invention to obtain a high quality ceramic substrate 2 by preventing the brazing material from creeping up onto the Ni pin 3 when soldering the Ni pin 3 or the like to the ceramic substrate 2.

【0009】[0009]

【課題を解決するための手段】図1は本発明の原理説明
図であり,パッケージへ装填するNiピン, 或いは,N
iめっきMoスタッドの製造フローである。図2は本発
明実施前後のNi材表面の顕微鏡で観察した状態のスケ
ッチ図である。
FIG. 1 is a diagram for explaining the principle of the present invention, in which a Ni pin or N loaded in a package is used.
It is a manufacturing flow of i plating Mo stud. FIG. 2 is a sketch diagram of the state of the Ni material surface observed before and after the present invention with a microscope.

【0010】図において,1はパッケージ,2はセラミ
ック基板,3はNiピン,4はスタッド,5はロー材,
6は底板,7は放熱フィン,8はキャップ,9はチッ
プ,10はワイヤ, 11はリードである。
In the figure, 1 is a package, 2 is a ceramic substrate, 3 is a Ni pin, 4 is a stud, 5 is a brazing material,
6 is a bottom plate, 7 is a radiation fin, 8 is a cap, 9 is a chip, 10 is a wire, and 11 is a lead.

【0011】Niピン3へのロー材5の這い上がり防止
方法として,ネールヘッドピン,ストレートピン等をN
i材よりNiピン3に成形後,水素雰囲気中で 900〜95
0 ℃の熱処理を行なってから, Niピン3にロウ材5を
付け,セラミック基板2にロウ付けをして,PGAタイ
プのセラミックパッケージが完成する。
As a method of preventing the brazing material 5 from creeping up onto the Ni pin 3, nail head pins, straight pins, etc.
900 ~ 95 in hydrogen atmosphere after molding from i material to Ni pin 3
After heat treatment at 0 ° C., the brazing material 5 is attached to the Ni pins 3 and the ceramic substrate 2 is brazed to complete a PGA type ceramic package.

【0012】すなわち,本発明の目的は,パッケージ1
のセラミック基板2に装填するNiピン3の製造に際
し, 図1(a)の製造フローに示すように,該Niピン
3を成形する工程と,成形された該Niピン3を熱処理
する工程と,熱処理された該Niピン3を, 該セラミッ
ク基板2にロー材5を用いてロー付けする工程とを含む
ことにより,或いは, パッケージ1のセラミック基板2
に装填するスタッド4の製造に際し, 図1(b)の製造
フローに示すように,該スタッド4であるMo素材を成
形する工程と,成形された該スタッド4をNiめっきす
る工程と,Niめっきされた該スタッド4を熱処理する
工程と,熱処理された該スタッド4を, 該セラミック基
板2にロー材5を用いてロー付けする工程とを含むこと
により,そして,前記熱処理は, Niピン3,スタッド
4,両方とも,還元雰囲気中,900 〜 950℃で行なわれ
ることにより達成される。
That is, the object of the present invention is to provide a package 1
When manufacturing the Ni pin 3 to be loaded on the ceramic substrate 2 of FIG. 1, as shown in the manufacturing flow of FIG. 1A, a step of molding the Ni pin 3, a step of heat-treating the molded Ni pin 3, A step of brazing the heat-treated Ni pin 3 to the ceramic substrate 2 by using a brazing material 5, or the ceramic substrate 2 of the package 1.
As shown in the manufacturing flow of FIG. 1 (b), when manufacturing the stud 4 to be loaded into the stud 4, a step of forming the Mo material that is the stud 4, a step of Ni-plating the formed stud 4, and a Ni-plating step. The heat treatment of the heat treated stud 4 and the step of brazing the heat treated stud 4 to the ceramic substrate 2 using a brazing material 5, and the heat treatment includes the Ni pin 3, This can be achieved by performing both studs 4 and 900 in a reducing atmosphere at 900 to 950 ° C.

【0013】[0013]

【作用】本発明においては,Niピン3やNiめっきM
oスタッド4等のNi材を成形後に,水素を含む還元雰
囲気中において熱処理する事により,図2に示すよう
に,Ni材の表面が非常に滑らかとなり,凹凸がなくな
り,また,熱処理によりNi材がロー材5との反応を阻
害し,ロー材5の這い上がりが生じにくくなる。
In the present invention, the Ni pin 3 and the Ni plating M are used.
By heat treating the Ni material such as o stud 4 in a reducing atmosphere containing hydrogen as shown in FIG. 2, the surface of the Ni material becomes very smooth and has no irregularities. Inhibits the reaction with the brazing material 5 and makes it difficult for the brazing material 5 to creep up.

【0014】[0014]

【実施例】図3は本発明の第2の実施例の説明図であ
る。図において,1はパッケージ,2はセラミック基
板,4はスタッド,5はロー材,6は底板,7は放熱フ
ィン,8はキャップ,9はチップ,10はワイヤ, 11はリ
ードである。
FIG. 3 is an explanatory view of the second embodiment of the present invention. In the figure, 1 is a package, 2 is a ceramic substrate, 4 is a stud, 5 is a brazing material, 6 is a bottom plate, 7 is a radiation fin, 8 is a cap, 9 is a chip, 10 is a wire, and 11 is a lead.

【0015】本発明の第1の実施例として,パッケージ
へロー付けするピンの製造について説明する。Ni材を
図4に示したようなネールヘッド型のNiピン3,或い
はストレートピンに成形加工する。その時ピン軸の表面
は図2(a)に示すように,数μm程度の皺状の凹凸面
となっている。
As a first embodiment of the present invention, the manufacture of pins to be brazed to a package will be described. The Ni material is formed into a nail head type Ni pin 3 or a straight pin as shown in FIG. At that time, the surface of the pin shaft is a wrinkled uneven surface of about several μm, as shown in FIG.

【0016】このNiピン3をコンベア式の炉にいれ,
水素1に対して窒素1〜3の還元雰囲気中において,90
0 〜950 ℃で熱処理する。単体のNiピンの熱処理時間
は凡そ1時間である。
Put the Ni pin 3 in a conveyor type furnace,
90% in a reducing atmosphere of 1 to 3 nitrogen and 1 to 3 nitrogen
Heat treatment is performed at 0 to 950 ° C. The heat treatment time for a single Ni pin is about 1 hour.

【0017】熱処理すると,Niピン3の表面は,図2
(b)に示すように,1μm以下の梨地面となり,熱処
理前に比べて非常に滑らかな面となっている。銅(C
u)28%,銀(Ag)72%からなるBAg−8ロー
材5を塗布し,PGAパッケージ用のセラミック基板2
に格子状に数百本のピンを 800〜900 ℃でロー付けし
て, PGAパッケージを製作する。
After the heat treatment, the surface of the Ni pin 3 is shown in FIG.
As shown in (b), the textured surface is 1 μm or less, which is a very smooth surface compared to before the heat treatment. Copper (C
u) A BAg-8 brazing material 5 composed of 28% and silver (Ag) 72% is applied, and a ceramic substrate 2 for a PGA package 2
A few hundred pins are brazed in a grid at 800-900 ° C to make a PGA package.

【0018】本発明の第2の実施例として,パッケージ
へフィンをロー付けするためのNiめっきMoスタッド
4の製造について説明する。高出力半導体素子では,放
熱のため,図3(a)に示すような多層の放熱フィン7
をパッケージ1のセラミック基板2に,底板6を介して
装着する。装着のため,底板6のスタッド4にロー材5
を付け,放熱フィン7をロー付けする際,図3(b)に
示すように,ロー材の這い上がりが生じて,放熱フィン
7の固定が不完全なものとなり,放熱効果が低減する。
そのため,スタッド4を成形後,第一の実施例のNiピ
ン3と同様な条件で,コンベア炉内で熱処理してから使
用する。これにより,ロー材5の這い上がりが防止さ
れ。放熱フィン7の放熱効果も所望の値に達することが
できた。
As a second embodiment of the present invention, the production of the Ni-plated Mo stud 4 for brazing the fin to the package will be described. In a high-power semiconductor device, for heat dissipation, a multilayer heat dissipation fin 7 as shown in FIG.
Is mounted on the ceramic substrate 2 of the package 1 via the bottom plate 6. For mounting, brazing material 5 on stud 4 of bottom plate 6
When the heat radiation fins 7 are brazed to each other, as shown in FIG. 3B, the brazing material creeps up, and the heat radiation fins 7 are imperfectly fixed, and the heat radiation effect is reduced.
Therefore, after forming the stud 4, the stud 4 is used after being heat-treated in the conveyor furnace under the same conditions as the Ni pin 3 of the first embodiment. This prevents the brazing material 5 from climbing up. The heat radiation effect of the heat radiation fin 7 could reach a desired value.

【0019】[0019]

【発明の効果】以上説明したように,セラミックパッケ
ージに装填するNi材のピン或いはフィン止め具を成形
後本発明の如く熱処理すれば,Ni材の表面が非常に滑
らかとなり,ロウ材の這い上がりが防止される。
As described above, when the Ni material pins or fin stoppers to be loaded into the ceramic package are molded and then heat treated as in the present invention, the surface of the Ni material becomes very smooth and the brazing material climbs. Is prevented.

【0020】その結果,ロー材の多いところに発生する
Niめっきや拡散工程での膨れ防止でき,またピンのロ
ー材を半分以下に低減でき,パッケージの歩留り上昇,
品質向上に寄与するところが大きい。
As a result, it is possible to prevent Ni plating that occurs in a lot of brazing material and swelling in the diffusion process, reduce the brazing material of the pin to less than half, and increase the package yield,
It greatly contributes to quality improvement.

【図面の簡単な説明】[Brief description of drawings]

【図1】 本発明の原理説明図FIG. 1 is an explanatory view of the principle of the present invention.

【図2】 本発明実施前後のNi材表面状態FIG. 2 Surface condition of Ni material before and after the present invention

【図3】 本発明の第2の実施例の説明図FIG. 3 is an explanatory diagram of a second embodiment of the present invention.

【図4】 従来例の説明図(その1)FIG. 4 is an explanatory diagram of a conventional example (No. 1)

【図5】 従来例の説明図(その2)FIG. 5 is an explanatory diagram of a conventional example (No. 2)

【符号の説明】[Explanation of symbols]

1はパッケージ 2はセラミック基板 3はNiピン 4はスタッド 5はロー材 6は底板 7は放熱フィン 8はキャップ 9はチップ 10はワイヤ 11はリード 1 is a package 2 is a ceramic substrate 3 is a Ni pin 4 is a stud 5 is a brazing material 6 is a bottom plate 7 is a radiation fin 8 is a cap 9 is a chip 10 is a wire 11 is a lead

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 パッケージ(1) のセラミック基板(2) に
装填するニッケル(Ni)ピン(3) の製造に際し, 該Niピン(3) を成形する工程と, 成形された該Niピン(3) を熱処理する工程と, 熱処理された該Niピン(3) を, 該セラミック基板
(2) にロー材(5) を用いてロー付けする工程とを含むこ
とを特徴とするパッケージの製造方法。
1. A step of molding the nickel (Ni) pin (3) to be loaded on the ceramic substrate (2) of the package (1), and a step of molding the nickel pin (3). ) Is heat-treated, and the heat-treated Ni pin (3) is attached to the ceramic substrate.
A method of manufacturing a package, comprising the step (2) of brazing with the brazing material (5).
【請求項2】 パッケージ(1) のセラミック基板(2) に
装填するスタッド(4) の製造に際し, 該スタッド(4) であるモリブデン(Mo)素材を成形す
る工程と, 成形された該スタッド(4) をNiめっきする工程と, Niめっきされた該スタッド(4) を熱処理する工程と, 熱処理された該スタッド(4) を, 該セラミック基板
(2) にロー材(5) を用いてロー付けする工程とを含むこ
とを特徴とするパッケージの製造方法。
2. A step of forming a molybdenum (Mo) material, which is the stud (4), in the production of the stud (4) to be loaded on the ceramic substrate (2) of the package (1), and the formed stud ( 4) is Ni-plated, the Ni-plated stud (4) is heat treated, and the heat-treated stud (4) is
A method of manufacturing a package, comprising the step (2) of brazing with the brazing material (5).
【請求項3】 前記Niピン(3), 或いは, スタッド
(4) の熱処理は, 還元雰囲気中,900 〜 950℃で行なわ
れることを特徴とする請求項1或いは2記載のパッケー
ジの製造方法。
3. The Ni pin (3) or stud
The package manufacturing method according to claim 1 or 2, wherein the heat treatment (4) is performed at 900 to 950 ° C in a reducing atmosphere.
JP4177286A 1992-07-06 1992-07-06 Package manufacturing method Expired - Fee Related JP3049948B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4177286A JP3049948B2 (en) 1992-07-06 1992-07-06 Package manufacturing method

Applications Claiming Priority (1)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001217341A (en) * 2000-02-03 2001-08-10 Ngk Spark Plug Co Ltd Wiring board with lead pin
US6555757B2 (en) 2000-04-10 2003-04-29 Ngk Spark Plug Co., Ltd. Pin solder jointed to a resin substrate, made having a predetermined hardness and dimensions
US6648211B2 (en) 2000-10-13 2003-11-18 Ngk Spark Plug Co., Ltd. Pin standing resin-made substrate, method of making pin standing resin-made substrate, pin and method of making pin
US6660946B2 (en) 2000-04-10 2003-12-09 Ngk Spark Plug Co., Ltd. Pin standing resin-made substrate, method of making pin standing resin-made substrate, pin and method of making pin
US6960729B2 (en) 2001-07-27 2005-11-01 Ngk Spark Plug Co., Ltd. Upright-pin-joined resin substrate, method of producing the substrate, pins, and method of producing the pins

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001217341A (en) * 2000-02-03 2001-08-10 Ngk Spark Plug Co Ltd Wiring board with lead pin
US6555757B2 (en) 2000-04-10 2003-04-29 Ngk Spark Plug Co., Ltd. Pin solder jointed to a resin substrate, made having a predetermined hardness and dimensions
US6660946B2 (en) 2000-04-10 2003-12-09 Ngk Spark Plug Co., Ltd. Pin standing resin-made substrate, method of making pin standing resin-made substrate, pin and method of making pin
US6648211B2 (en) 2000-10-13 2003-11-18 Ngk Spark Plug Co., Ltd. Pin standing resin-made substrate, method of making pin standing resin-made substrate, pin and method of making pin
US6960729B2 (en) 2001-07-27 2005-11-01 Ngk Spark Plug Co., Ltd. Upright-pin-joined resin substrate, method of producing the substrate, pins, and method of producing the pins

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