JPH06176903A - Electrode structure of cr-based cermet thin film - Google Patents
Electrode structure of cr-based cermet thin filmInfo
- Publication number
- JPH06176903A JPH06176903A JP4350375A JP35037592A JPH06176903A JP H06176903 A JPH06176903 A JP H06176903A JP 4350375 A JP4350375 A JP 4350375A JP 35037592 A JP35037592 A JP 35037592A JP H06176903 A JPH06176903 A JP H06176903A
- Authority
- JP
- Japan
- Prior art keywords
- thin film
- film
- electrode
- based cermet
- cermet thin
- Prior art date
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Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は歪ゲージや発熱抵抗体等
に使用されるCr系サーメット薄膜の電極構造に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a Cr-based cermet thin film electrode structure used for strain gauges, heating resistors and the like.
【0002】[0002]
【従来の技術】従来、Cr−O、Cr−Si−O、また
はCr−Al−O等を構成成分とするCr系サーメット
薄膜を歪ゲージや電熱抵抗素子として使用する場合に
は、Cr系サーメット薄膜上に例えば半田付け用の電極
を形成することが必要となる。この場合、通常、サーメ
ット薄膜上に、NiまたはCu等の金属膜を蒸着、スパ
ッタリング、湿式メッキ等の方法で成膜し、場合によっ
てはさらに半田濡れ性を良くするためにAu等の金属を
薄く成膜した後、半田付けをして電極を取り出してい
る。2. Description of the Related Art Conventionally, when a Cr-based cermet thin film containing Cr-O, Cr-Si-O, Cr-Al-O or the like as a constituent is used as a strain gauge or an electrothermal resistance element, a Cr-based cermet is used. For example, it is necessary to form electrodes for soldering on the thin film. In this case, usually, a metal film such as Ni or Cu is formed on the cermet thin film by a method such as vapor deposition, sputtering, and wet plating. In some cases, a metal such as Au is thinned to further improve solder wettability. After forming the film, the electrode is taken out by soldering.
【0003】[0003]
【発明が解決しようとする課題】ところが、上記従来の
構成では、半田とNiあるいはCuとの密着性は優れて
いるものの、酸化物であるサーメット薄膜とNiあるい
はCuの間の密着が不十分で、当該部分での剥がれが生
じやすいという問題があった。However, in the above-mentioned conventional structure, although the adhesion between the solder and Ni or Cu is excellent, the adhesion between the cermet thin film which is an oxide and Ni or Cu is insufficient. However, there is a problem that peeling is likely to occur at the portion.
【0004】さらに、サーメット薄膜を酸化雰囲気(酸
素、空気、または水溶液中など)に露出したり、処理を
行ったりした場合、サーメット薄膜表面が酸化してCr
O2リッチとなり、上述したサーメット薄膜と金属膜と
の密着性の低下を助長するという不具合があった。Further, when the cermet thin film is exposed to an oxidizing atmosphere (oxygen, air, or an aqueous solution, etc.) or treated, the surface of the cermet thin film is oxidized to cause Cr.
There is a problem that it becomes O 2 rich, which promotes the above-mentioned deterioration of the adhesion between the cermet thin film and the metal film.
【0005】本発明は上記実情に鑑みてなされたもので
あり、その目的は、酸化物を含み、しかも表面に酸化膜
を形成しやすいCr系サーメット薄膜に接合されて高い
密着性を示し、機械的強度に優れた電極構造を提供する
ことにある。The present invention has been made in view of the above circumstances, and an object thereof is to bond a Cr-based cermet thin film containing an oxide, which easily forms an oxide film on the surface, to exhibit high adhesion, It is to provide an electrode structure excellent in dynamic strength.
【0006】[0006]
【課題を解決するための手段】本発明の構成を図1で説
明する。基板1上に形成したCr系サーメット薄膜2の
表面には、CrまたはCrを主成分とする合金の薄膜か
らなる密着層3を設けてある。該密着層3上には、半田
付けまたはワイヤボンディングを行うためのベースとな
るNi、CuまたはAlよりなる電極膜4を形成してあ
る。The structure of the present invention will be described with reference to FIG. On the surface of the Cr-based cermet thin film 2 formed on the substrate 1, an adhesion layer 3 made of a thin film of Cr or an alloy containing Cr as a main component is provided. An electrode film 4 made of Ni, Cu or Al is formed on the adhesion layer 3 as a base for soldering or wire bonding.
【0007】[0007]
【作用】上記構成において、上記密着層3はCrまたは
Crを主成分とする合金からなり、Cr系サーメット薄
膜2と同一の元素を主たる構成成分とする。このため、
密着層3はサーメット薄膜2に対し良好な密着性を有
し、一方で、同じ金属膜である電極膜4に対する密着性
にも優れる。従って、サーメット薄膜2と電極膜4との
間に挿入されて電極部の接合強度を大幅に向上させ、剥
離等の発生を抑制する。In the above structure, the adhesion layer 3 is made of Cr or an alloy containing Cr as a main component, and contains the same elements as those of the Cr-based cermet thin film 2 as main constituent components. For this reason,
The adhesion layer 3 has good adhesion to the cermet thin film 2, and also has excellent adhesion to the electrode film 4, which is the same metal film. Therefore, it is inserted between the cermet thin film 2 and the electrode film 4 to significantly improve the bonding strength of the electrode portion and suppress the occurrence of peeling or the like.
【0008】[0008]
【実施例】図1に本発明の一実施例を示す。図におい
て、基板1上には、Cr−O、Cr−Si−O、または
Cr−Al−O等を構成成分とするCr系サーメット薄
膜2が形成してある。該サーメット薄膜2上には密着層
3が形成してある。上記密着層3は純Cr、あるいはC
rを主成分とする合金からなり、Crを主成分とする合
金としては具体的にはCr−Cu、Cr−Mo等が挙げ
られる。密着層3の膜厚は、通常10〜100nm程度で
あり、膜厚がこれより薄いと成膜の安定性が損なわれ、
厚くするのは経済的に不利である。さらに上記密着層3
上には、半田付けまたはワイヤボンディングのベースと
なるNi、CuまたはAlからなる電極膜4を成膜して
ある。FIG. 1 shows an embodiment of the present invention. In the drawing, a Cr-based cermet thin film 2 having Cr-O, Cr-Si-O, Cr-Al-O or the like as a constituent component is formed on a substrate 1. An adhesion layer 3 is formed on the cermet thin film 2. The adhesion layer 3 is pure Cr or C
The alloy containing r as a main component, and specific examples of the alloy containing Cr as a main component include Cr—Cu and Cr—Mo. The film thickness of the adhesion layer 3 is usually about 10 to 100 nm, and if the film thickness is smaller than this, the stability of film formation is impaired.
It is economically disadvantageous to make thick. Furthermore, the adhesion layer 3
An electrode film 4 made of Ni, Cu or Al, which serves as a base for soldering or wire bonding, is formed on the upper surface.
【0009】半田付けの際には、上記電極膜4上に直接
半田付けするか、あるいは、さらに半田濡れ性を良くす
るために、上記電極膜4上にAu、Ag等の金属薄膜5
を積層した後、上記金属薄膜5上に半田6付けしてもよ
い。なお、電極膜4にAlを使用した場合には、通常、
金属薄膜5を用いず、超音波で表面のAl2 03 膜を破
りながらアルミ半田(特殊半田)を付ける。At the time of soldering, the electrode film 4 is directly soldered, or in order to improve the solder wettability, a metal thin film 5 of Au, Ag or the like is formed on the electrode film 4.
After stacking, the solder 6 may be attached onto the metal thin film 5. When Al is used for the electrode film 4, usually,
Instead of using the metal thin film 5, aluminum solder (special solder) is applied while ultrasonically breaking the Al 2 O 3 film on the surface.
【0010】上記積層膜の成膜には、通常の真空成膜
法、例えば蒸着、スパッタリング、または減圧CVD法
等が使用できる。特に、上記密着層3を成膜した後、そ
のまま真空を破らずに上記電極膜4、金属薄膜5を連続
的に成膜することが望ましい。これにより、上記密着層
3表面が酸化して表面にCrO2 層が形成されることを
抑制し、上記密着層3と電極膜4、さらに電極膜4と金
属薄膜5各層間の密着性をより向上させることができ
る。For forming the above-mentioned laminated film, a usual vacuum film forming method such as vapor deposition, sputtering, or low pressure CVD method can be used. In particular, after forming the adhesion layer 3, it is desirable to continuously form the electrode film 4 and the metal thin film 5 without breaking the vacuum. Thereby, the surface of the adhesion layer 3 is prevented from being oxidized and a CrO 2 layer is formed on the surface, and the adhesion between the adhesion layer 3 and the electrode film 4, and between the electrode film 4 and the metal thin film 5 is further improved. Can be improved.
【0011】本発明の効果を調べるため、次のようにし
て積層膜を作製した。基板1上に形成されたCr系サー
メット薄膜2の上に、まず密着層3として純Crの膜を
スパッタリング法で50〜100nmの膜厚に成膜し、そ
のまま真空を破らずに半田付けのベースとなるNi層を
スパッタリング法で200〜600nmの膜厚に成膜して
電極膜4とした。さらに、そのまま真空を破らずに半田
濡れ性を良くするためのAu層を30〜150nmの膜厚
に連続して成膜して、金属薄膜5とし、Cr−Ni−A
uの3層からなる積層膜を形成した。In order to investigate the effect of the present invention, a laminated film was prepared as follows. On the Cr-based cermet thin film 2 formed on the substrate 1, first, a pure Cr film is formed as the adhesion layer 3 to a film thickness of 50 to 100 nm by a sputtering method, and the soldering base is used as it is without breaking the vacuum. A Ni layer to be formed was formed into a film having a thickness of 200 to 600 nm by a sputtering method to form an electrode film 4. Further, an Au layer for improving solder wettability without breaking the vacuum is continuously formed in a film thickness of 30 to 150 nm to form a metal thin film 5, and Cr-Ni-A is used.
A laminated film composed of three u layers was formed.
【0012】次に、上記のようにして得られた積層膜上
に半田6を盛り、これを溶解して銅線7を半田付けした
後、引っ張り試験を行った。その結果、膜の単位面積当
たりに換算した引っ張り力:約250〜300gf/mm2に
おいて銅線7が根元から引きちぎれた。密着層3とサー
メット薄膜2の界面における剥がれは生じなかった。こ
れに対し、密着層3を形成しない従来の構成の積層膜で
同様の引っ張り試験を行ったところ、引張り力:0〜3
0gf/mm2でサーメット薄膜2とNi電極膜4との間で剥
がれが生じた。かくして、本発明の構成を用いることに
より、電極膜4とサーメット薄膜2の密着性が著しく向
上していることがわかる。Next, a solder 6 was put on the laminated film obtained as described above, and this was melted to solder a copper wire 7, and then a tensile test was conducted. As a result, the copper wire 7 was torn from the root when the tensile force converted per unit area of the film was about 250 to 300 gf / mm 2 . No peeling occurred at the interface between the adhesive layer 3 and the cermet thin film 2. On the other hand, when a similar tensile test was performed on a laminated film having a conventional structure in which the adhesion layer 3 was not formed, the tensile force was 0 to 3
At 0 gf / mm 2 , peeling occurred between the cermet thin film 2 and the Ni electrode film 4. Thus, it can be seen that the adhesiveness between the electrode film 4 and the cermet thin film 2 is remarkably improved by using the constitution of the present invention.
【0013】なお、半田溶解の方法としては、熱風、赤
外線、ホットプレート、コテ等のどの方法を用いてもよ
く、いずれも同様の結果が得られた。As a method for melting the solder, any method such as hot air, infrared ray, hot plate, and iron may be used, and the same result was obtained.
【0014】[0014]
【発明の効果】以上のように、本発明によれば、Cr系
サーメット薄膜と電極膜の間の密着性を飛躍的に向上さ
せることができる。従って、良好な電気的特性と機械的
強度を有し、歪ゲージや発熱抵抗体等の電極として好適
に使用できる。As described above, according to the present invention, the adhesion between the Cr-based cermet thin film and the electrode film can be dramatically improved. Therefore, it has good electrical characteristics and mechanical strength, and can be suitably used as electrodes such as strain gauges and heating resistors.
【図1】本発明の一実施例を示す電極の部分拡大断面図
である。FIG. 1 is a partially enlarged sectional view of an electrode showing an embodiment of the present invention.
1 基板 2 Cr系サーメット薄膜 3 密着層 4 電極膜 5 金属薄膜 6 半田 7 銅線 1 Substrate 2 Cr-based cermet thin film 3 Adhesion layer 4 Electrode film 5 Metal thin film 6 Solder 7 Copper wire
Claims (1)
の表面に、CrまたはCrを主成分とする合金の薄膜か
らなる密着層を設け、該密着層上に、半田付けまたはワ
イヤボンディングを行うためのベースとなるNi、Cu
またはAlよりなる電極膜を形成したことを特徴とする
Cr系サーメット薄膜の電極構造。1. A Cr-based cermet thin film formed on a substrate is provided with an adhesive layer made of a thin film of Cr or an alloy containing Cr as a main component, and soldering or wire bonding is performed on the adhesive layer. Ni, Cu which is the base of
Alternatively, an electrode structure of a Cr-based cermet thin film is characterized in that an electrode film made of Al is formed.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4350375A JPH06176903A (en) | 1992-12-03 | 1992-12-03 | Electrode structure of cr-based cermet thin film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4350375A JPH06176903A (en) | 1992-12-03 | 1992-12-03 | Electrode structure of cr-based cermet thin film |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH06176903A true JPH06176903A (en) | 1994-06-24 |
Family
ID=18410065
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4350375A Withdrawn JPH06176903A (en) | 1992-12-03 | 1992-12-03 | Electrode structure of cr-based cermet thin film |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH06176903A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5455195A (en) * | 1994-05-06 | 1995-10-03 | Texas Instruments Incorporated | Method for obtaining metallurgical stability in integrated circuit conductive bonds |
EP3690389A4 (en) * | 2017-09-29 | 2021-07-21 | Minebea Mitsumi Inc. | Strain gauge |
US11454488B2 (en) | 2017-09-29 | 2022-09-27 | Minebea Mitsumi Inc. | Strain gauge with improved stability |
US11542590B2 (en) | 2017-09-29 | 2023-01-03 | Minebea Mitsumi Inc. | Strain gauge |
US11543309B2 (en) | 2017-12-22 | 2023-01-03 | Minebea Mitsumi Inc. | Strain gauge and sensor module |
US11692806B2 (en) | 2017-09-29 | 2023-07-04 | Minebea Mitsumi Inc. | Strain gauge with improved stability |
US11747225B2 (en) | 2018-04-05 | 2023-09-05 | Minebea Mitsumi Inc. | Strain gauge with improved stability and stress reduction |
US11774303B2 (en) | 2018-10-23 | 2023-10-03 | Minebea Mitsumi Inc. | Accelerator, steering wheel, six-axis sensor, engine, bumper and the like |
-
1992
- 1992-12-03 JP JP4350375A patent/JPH06176903A/en not_active Withdrawn
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5455195A (en) * | 1994-05-06 | 1995-10-03 | Texas Instruments Incorporated | Method for obtaining metallurgical stability in integrated circuit conductive bonds |
EP3690389A4 (en) * | 2017-09-29 | 2021-07-21 | Minebea Mitsumi Inc. | Strain gauge |
US11454488B2 (en) | 2017-09-29 | 2022-09-27 | Minebea Mitsumi Inc. | Strain gauge with improved stability |
US11542590B2 (en) | 2017-09-29 | 2023-01-03 | Minebea Mitsumi Inc. | Strain gauge |
US11543308B2 (en) | 2017-09-29 | 2023-01-03 | Minebea Mitsumi Inc. | Strain gauge |
US11692806B2 (en) | 2017-09-29 | 2023-07-04 | Minebea Mitsumi Inc. | Strain gauge with improved stability |
US11702730B2 (en) | 2017-09-29 | 2023-07-18 | Minebea Mitsumi Inc. | Strain gauge |
US11543309B2 (en) | 2017-12-22 | 2023-01-03 | Minebea Mitsumi Inc. | Strain gauge and sensor module |
US11747225B2 (en) | 2018-04-05 | 2023-09-05 | Minebea Mitsumi Inc. | Strain gauge with improved stability and stress reduction |
US11774303B2 (en) | 2018-10-23 | 2023-10-03 | Minebea Mitsumi Inc. | Accelerator, steering wheel, six-axis sensor, engine, bumper and the like |
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