JPH06158498A - Production of nonwoven fabric - Google Patents

Production of nonwoven fabric

Info

Publication number
JPH06158498A
JPH06158498A JP4297161A JP29716192A JPH06158498A JP H06158498 A JPH06158498 A JP H06158498A JP 4297161 A JP4297161 A JP 4297161A JP 29716192 A JP29716192 A JP 29716192A JP H06158498 A JPH06158498 A JP H06158498A
Authority
JP
Japan
Prior art keywords
fiber
nonwoven fabric
web
fibers
split
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP4297161A
Other languages
Japanese (ja)
Inventor
Toshiya Hotta
敏哉 堀田
Masahiko Ikeda
雅彦 池田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Ltd
Original Assignee
Teijin Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teijin Ltd filed Critical Teijin Ltd
Priority to JP4297161A priority Critical patent/JPH06158498A/en
Publication of JPH06158498A publication Critical patent/JPH06158498A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a method for readily obtaining nonwoven fabric, excellent in process passableness in a process to the formation of a web such as a carding step and capable of being readily split and fibrillated in a process for making a high-pressure fluid stream act and assuming soft hand. CONSTITUTION:The nonwoven fabric is prepared by a method for using splittable conjugate fiber composed of mutually incompatible components, carding the fiber, making a high-pressure fluid stream act thereon, carrying out splitting, fibrillating and fiber interlacing. In the method, the conjugate fiber having 3.0-7.0 ratio of the area of the incompatible contact part to the surface area of the conjugate fiber is used. When the area ratio is >=3.0 to <=7.0, the splitting and fibrillating are hardly caused under the stress applied to the time for forming the web. Thereby, the card passableness is good. On the other hand, the splitting and fibrillating under the stress acting by the high-pressure liquid stream are sufficiently advanced to provide the nonwoven fabric assuming soft hand.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、柔軟な風合を呈する不
織布の製造方法に関する。さらに詳しくは、分割型複合
繊維を用いた、極細繊維からなる不織布を効率良く製造
することのできる方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a non-woven fabric having a soft texture. More specifically, the present invention relates to a method capable of efficiently producing a nonwoven fabric made of ultrafine fibers using splittable conjugate fibers.

【0002】[0002]

【従来の技術】一般に細繊度の繊維を使用した不織布
は、風合がソフト化することは周知のことであり、かか
る極細繊維を得る方法として幾多の提案がなされてきて
いる。最も有用な方法としては、溶解性(溶媒又は酸、
アルカリ溶液に対する)の異なる2種以上のポリマーに
より海島型繊維を形成し、海成分を溶解除去して極細繊
維となす方法が挙げられる。しかし、かかる方法におい
ては溶剤処理工程や溶剤回収工程が必要であり、工程的
に複雑となる欠点があるし、またコスト的にも不利であ
る。
2. Description of the Related Art Generally, it is well known that a non-woven fabric using fine fibers has a soft texture, and various proposals have been made as a method for obtaining such ultra fine fibers. The most useful method is solubility (solvent or acid,
There is a method in which sea-island type fibers are formed by two or more kinds of polymers having different alkali solutions), and sea components are dissolved and removed to form ultrafine fibers. However, in such a method, a solvent treatment step and a solvent recovery step are required, and there are drawbacks that the process becomes complicated, and the cost is disadvantageous.

【0003】また別の方法としては、互いに親和性のな
いポリマー、例えばポリエステル/ポリアミド、ポリエ
ステル/ポリオレフィン、ポリアミド/ポリオレフィン
などからなる複合繊維を、パフ掛け、ニードルパンチン
グ、高圧水流処理等の機械的衝撃により分割極細繊維化
する方法が、特開昭62―133164号公報、特開昭
62―268861号公報等に提案されている。
As another method, composite fibers composed of polymers having no affinity for each other, for example, polyester / polyamide, polyester / polyolefin, polyamide / polyolefin, etc., are subjected to mechanical impact such as puffing, needle punching, high-pressure water treatment and the like. A method of forming ultrafine fibers by the method described above is proposed in JP-A-62-133164 and JP-A-62-268861.

【0004】しかしながら、かかる方法により得られる
複合繊維は、ポリマー間の親和性が乏しいため、機械捲
縮を付与する際あるいはカード工程を通過させてウエブ
を形成する際に、成分割れが生じて生産性が著しく低下
するといった問題がある。
However, since the composite fiber obtained by such a method has a poor affinity between polymers, component cracks are produced when mechanical crimping is applied or when a web is formed by passing through a card process, and thus produced. However, there is a problem that the property significantly decreases.

【0005】[0005]

【発明が解決しようとする課題】本発明は、上記従来技
術の問題点に鑑みなされたもので、その目的は、機械捲
縮付与工程、カード工程等ウエブを形成するまでは分割
フィブリル化し難く、高圧流体流を作用させて不織布と
なす際には分割フィブリル化及び単繊維のランダムな絡
み合いが容易に達成し得る、柔軟な風合を呈する不織布
の製造方法を提供することにある。
SUMMARY OF THE INVENTION The present invention has been made in view of the above problems of the prior art, and its purpose is to make it difficult to form divided fibrils until a web is formed in a mechanical crimping step, a card step, etc. It is an object of the present invention to provide a method for producing a nonwoven fabric exhibiting a soft texture, which can easily achieve split fibrillation and random entanglement of single fibers when a high-pressure fluid flow is applied to form the nonwoven fabric.

【0006】[0006]

【課題を解決するための手段】本発明者らは、上記目的
を達成するため鋭意検討した結果、分割型複合繊維の表
面積に対する成分間の接触面積の割合を大きくすること
により、機械捲縮付与時又はカード通過時に複合界面に
作用する単位面積当りの応力は低下し、その結果ウエブ
形成までの工程通過性は良好となること、また前記割合
を一定値以下にすれば高圧液体流による分割フィブリル
化は従来と同様にできることを見い出し本発明に到達し
た。
Means for Solving the Problems As a result of intensive studies to achieve the above object, the present inventors have found that mechanical crimping is imparted by increasing the ratio of the contact area between components to the surface area of splittable conjugate fiber. The stress per unit area acting on the composite interface at the time of card passage or at the time of passing through the card is reduced, and as a result, the process passability up to web formation is improved. The inventors have found that the same can be achieved as in the past, and have reached the present invention.

【0007】すなわち、本発明によれば、互いに非相溶
性の成分からなり、その少なくとも一つの成分が残りの
成分によって多層に分割配置されてなる分割型複合繊維
をカードにてウエブとした後、高圧液体流を噴射するこ
とにより、繊維の分割フィブリル化を発生させると共に
ランダムな絡み合いを行わせ一体構造とする不織布の製
造方法において、前記複合繊維が下記条件を満足するこ
とを特徴とする不織布の製造方法、 3.0≦R≦7.0 (式中、Rは、複合繊維の表面積S0 と、互いに非相溶
性成分の接触総面積S1との比S1 /S0 を表わす)が
提供される。
That is, according to the present invention, a splittable conjugate fiber composed of mutually incompatible components, at least one of which is divided into multiple layers by the remaining components, is made into a web with a card, By injecting a high-pressure liquid flow, in a method for producing a nonwoven fabric which causes split fibrillation of fibers and performs random entanglement to form an integral structure, the composite fiber satisfies the following conditions: Manufacturing method, 3.0 ≦ R ≦ 7.0 (where R represents the ratio S 1 / S 0 of the surface area S 0 of the composite fiber and the total contact area S 1 of mutually incompatible components). Provided.

【0008】以下に本発明の詳細な説明をする。本発明
における分割型複合繊維の横断面の具体例としては、た
とえば図1に示すように、相互接着性を有しない2種類
(A成分、B成分)あるいはそれ以上の非相溶性の熱可
塑性重合体成分が交互に配列した断面形状のものをいう
が、複数のフィブリルに分割できるものであればこれに
限定するものではない。
The present invention will be described in detail below. As a specific example of the cross section of the splittable conjugate fiber in the present invention, as shown in FIG. 1, for example, two kinds (component A, component B) or more incompatible thermoplastic polymers having no mutual adhesiveness are used. It refers to a cross-sectional shape in which coalescing components are alternately arranged, but is not limited to this as long as it can be divided into a plurality of fibrils.

【0009】本発明においては、上記の分割型複合繊維
は、その表面積S0 に対する、互いに非相溶性である成
分の接触面積の総和S1 の比(R=S1 /S0 )が、
3.0以上7.0以下であることに最大の特徴を有し、
特に4.0以上6.0以下であることが好ましい。面積
比Rがこの範囲にある場合には、押込み捲縮等による機
械捲縮付与時、及びカード通過時に複合繊維に作用する
応力程度では分割フィブリル化は進行せず、その結果良
好なカード通過性が得られる。一方高圧液体流による処
理時には、複合繊維に作用する応力は充分に大きいので
従来と同様に分割フィブリル化させることが可能で、且
つ繊維間のランダムな絡合いも達成されてソフトな風合
を呈する不織布が得られる。
In the present invention, the splittable conjugate fiber described above has a ratio (R = S 1 / S 0 ) of the total contact area S 1 of the mutually incompatible components to the surface area S 0 thereof.
The greatest feature is that it is 3.0 or more and 7.0 or less,
Particularly, it is preferably 4.0 or more and 6.0 or less. When the area ratio R is in this range, split fibrillation does not proceed at the stress level acting on the composite fiber when mechanical crimping is given by indentation crimping or the like and when passing through the card, resulting in good card passing property. Is obtained. On the other hand, during the treatment with the high-pressure liquid flow, the stress acting on the composite fiber is sufficiently large so that it can be split into fibrils as in the conventional case, and the random entanglement between the fibers is also achieved to provide a soft texture. A non-woven fabric is obtained.

【0010】これに対してRが3.0未満の場合には、
互いに非相溶性である成分の接触面積が小さすぎ、複合
繊維に作用する応力の接触単位面積当りの応力が増大し
て分割フィブリル化し易くなり、カード通過性が低下す
る。一方7.0を越える場合には、非相溶性である成分
の接触面積が大きくなりすぎ、高圧流体流を噴射させて
繊維の分割フィブリル化させる際の効率が低下し、得ら
れる不織布の柔軟性が低下するため好ましくない。
On the other hand, when R is less than 3.0,
The contact areas of the components which are incompatible with each other are too small, the stress per unit area of contact acting on the composite fiber increases, the split fibrils are easily formed, and the card passing property is deteriorated. On the other hand, when it exceeds 7.0, the contact area of the incompatible component becomes too large, the efficiency at the time of jetting a high-pressure fluid flow to form fibers into split fibrils decreases, and the flexibility of the resulting nonwoven fabric is reduced. Is decreased, which is not preferable.

【0011】本発明における互いに非相溶性の2種の熱
可塑性重合体成分の組合せとは、たとえばポリエステル
とポリプロピレン、ポリエステルとナイロン、ナイロン
とポリプロピレンのようなものをいう。
In the present invention, the combination of two thermoplastic polymer components which are incompatible with each other means, for example, polyester and polypropylene, polyester and nylon, nylon and polypropylene.

【0012】本発明で用いる分割型複合繊維は、特公昭
39―29636号公報、特開昭50―5650号公報
等で公知の方法によって複合紡糸した未延伸糸を集束し
て延伸後、機械捲縮を付与しながら油剤を付着させ、有
限繊維長に切断して短繊維とすることにより得ることが
できる。また、本発明の不織布を得る上では、分割型複
合繊維を湿熱または乾熱など適当な方法で熱処理して沸
水面積収縮率を20%以下にしておくことが好ましい。
The splittable conjugate fiber used in the present invention is obtained by bundling unstretched composite spun yarns by a method known in Japanese Patent Publication No. 39-29636 and Japanese Patent Laid-Open No. 50-5650, stretching them, and then mechanically winding them. It can be obtained by adhering an oil agent while imparting crimp and cutting it into finite fiber lengths to form short fibers. In order to obtain the nonwoven fabric of the present invention, it is preferable to heat the splittable conjugate fiber by an appropriate method such as wet heat or dry heat so that the boiling water area shrinkage rate is 20% or less.

【0013】分割型複合繊維の太さは1〜20デニール
程度のものが用いられ、分割フィブリル化によって形成
される少なくとも一つの成分からなる分割フィブリル化
単繊維のデニールは0.5デニール以下が好ましく、さ
らに好ましくは0.3デニール以下であり、0.5デニ
ールを超えると肌触りが硬いものとなり、例えば人工皮
革用基布、衛生材料用カバーストック材としての適性が
失われる。
The thickness of the splittable conjugate fiber is about 1 to 20 denier, and the denier of the split fibrillated single fiber composed of at least one component formed by split fibrillation is preferably 0.5 denier or less. More preferably, it is 0.3 denier or less, and if it exceeds 0.5 denier, it becomes hard to the touch, and loses its suitability as a base fabric for artificial leather and a cover stock material for sanitary materials.

【0014】分割型複合繊維の捲縮数は5〜25ケ/イ
ンチの範囲が好ましい。捲縮数が5ケ/インチ未満で
は、繊維同志のからみが弱くなり圧縮回復性も低下す
る。逆に25ケ/インチを超えると開繊し難くなり、ウ
エブにした時の嵩も小さくなる。
The number of crimps of the splittable conjugate fiber is preferably in the range of 5 to 25 per inch. When the number of crimps is less than 5 / inch, the entanglement between the fibers becomes weak and the compression recovery property also deteriorates. On the other hand, if it exceeds 25 per inch, it becomes difficult to open the fiber, and the bulk of the web becomes small.

【0015】分割型複合短繊維の繊維長は15〜80mm
の範囲が好ましい。繊維長が15mm未満ではカーディン
グ時得られるウエブが綿切れして取扱いが不良となる。
逆に繊維長が80mmを超えるとネップを生じるなど工程
上のトラブルが起り、均一なウエブを得ることが難しく
なる。
The fiber length of the splittable composite short fibers is 15 to 80 mm.
Is preferred. If the fiber length is less than 15 mm, the web obtained during carding will be cut and the handling will be poor.
On the other hand, if the fiber length exceeds 80 mm, process troubles such as nep will occur and it will be difficult to obtain a uniform web.

【0016】本発明においては、かかる分割型複合短繊
維を常法によりカードにてウエブを形成させた後、更に
カード上りのウエブ中の分割型複合短繊維の分割フィブ
リル化を促進させランダムな絡み合いを起させるため、
高圧液体流をウエブ表面に衝突させる。
In the present invention, after the split type composite short fibers are formed into a web by a card by a conventional method, the split type composite short fibers in the web ascending the card are further promoted to form split fibrils and are randomly entangled. To cause
The high pressure liquid stream impinges on the web surface.

【0017】液体流として使用する液体は水または温水
が取扱いの容易さから望ましい。また、液体流の噴射ノ
ズルの孔径は0.05〜1.0mm、好ましくは0.1〜
0.4mmであり、噴射圧力は100〜200kg/cm2
あり、噴射孔とウエブの間隔は1〜15cmが好適であ
り、間隔が広くなれば、噴射液体流と空気が混じり合い
分割交絡効果が小さくなる。このようにして不織布の目
付を10〜300g/m 2 の範囲にすれば、ソフトな風
合を呈し、人工皮革用基布、衛生材料用カバーストック
材等として有用な不織布が製造できる。
The liquid used as the liquid stream is water or hot water.
Is desirable because it is easy to handle. In addition,
The diameter of the hole is 0.05 to 1.0 mm, preferably 0.1 to
0.4 mm, injection pressure 100-200 kg / cm2so
Yes, the distance between the injection hole and the web is preferably 1 to 15 cm
If the distance becomes wider, the jet flow and air will mix.
The division confounding effect becomes small. In this way the non-woven eye
10 to 300 g / m 2If it is in the range, soft wind
The base cloth for artificial leather and cover stock for sanitary materials
A non-woven fabric useful as a material can be manufactured.

【0018】[0018]

【作用】以上詳細に説明したように、本発明の不織布の
製造方法においては、互いに非相溶性の成分が接触接合
した面積の総和の、複合繊維表面積に対する比が3.0
以上の複合繊維を用いているので、押込み捲縮付与装置
等の機械捲縮を付与する工程、カーディングしてウエブ
となす工程等において複合繊維に負荷される応力程度で
は、該負荷応力が全接触面に分散されて単位面積当りの
応力が小さくなるためと推定され、複合繊維の分割フィ
ブリル化が進行せず、品質の良好なウエブが安定して得
られるのである。
As described in detail above, in the method for producing a non-woven fabric of the present invention, the ratio of the total area where the incompatible components are contact-bonded to the composite fiber surface area is 3.0.
Since the above composite fibers are used, the stress applied to the composite fibers in the process of applying a mechanical crimp such as an indentation crimp applying device, the process of forming a web by carding, etc. It is presumed that this is because the stress per unit area is dispersed due to the dispersion on the contact surface, the split fibril formation of the composite fiber does not proceed, and a good quality web can be stably obtained.

【0019】一方、同面積比は上限を7.0としている
ので、圧力100kg/cm2 以上といった高速液体流を作
用させる場合の単位接触面積当りの負荷応力は十分大き
くでき、分割フィブリル化及びランダムな絡み合いは従
来と同様にできるのである。
On the other hand, since the upper limit of the same area ratio is 7.0, the load stress per unit contact area when a high-speed liquid flow such as a pressure of 100 kg / cm 2 or more can be sufficiently increased, and split fibrillation and random fibrillation can be performed. The entanglement can be performed in the same manner as in the past.

【0020】[0020]

【発明の効果】したがって、本発明によれば、分割型複
合繊維を用いて効率良くウエブを作成でき、また高速液
体流により効率良く分割フィブリル化及び繊維のランダ
ム絡合ができ、且つ得られた不織布はソフトな風合を呈
し人工皮革用基布、カバーストック材などの衛生材料用
として優れた特性を有するといった特徴を有する。
Therefore, according to the present invention, it is possible to efficiently produce a web by using splittable conjugate fibers, efficiently split fibers and randomly entangle fibers by using a high-speed liquid flow. The non-woven fabric is characterized by exhibiting a soft texture and having excellent properties as a sanitary material such as a base fabric for artificial leather and a cover stock material.

【0021】[0021]

【実施例】以下実施例により本発明をさらに詳細に説明
する。
The present invention will be described in more detail with reference to the following examples.

【0022】ポリエチレンテレフタレートをA成分と
し、ナイロン6をB成分として、重量比1:1の割合で
溶融複合紡糸し、1000m/分で巻き取って図1〜3
に示されると同様の横断面を有する分割型複合未延伸糸
を得た。この未延伸糸を引き揃えて延伸温度90℃で
3.5倍にローラ延伸し、押し込み捲縮機にて18山/
25mmの機械捲縮を付与した後130℃にて30分間熱
処理を行い、次いで51mmの長さに切断して単繊維繊度
3デニールの短繊維を得た。得られた短繊維をローラー
カードにより60m/分の速度で目付け40g/m2
ウエブとした。この段階では繊維の分割フィブリル化は
ほとんど見られずカード通過性も極めて良好であった。
Polyethylene terephthalate as component A and nylon 6 as component B were melt-composite spun at a weight ratio of 1: 1 and wound at 1000 m / min.
A split-type composite undrawn yarn having a cross section similar to that shown in FIG. The unstretched yarns are aligned and roller-stretched 3.5 times at a stretching temperature of 90 ° C., and 18 threads / in a crimping machine.
After applying a mechanical crimp of 25 mm, it was heat treated at 130 ° C. for 30 minutes and then cut into a length of 51 mm to obtain a short fiber having a single fiber fineness of 3 denier. The obtained short fibers were made into a web having a basis weight of 40 g / m 2 with a roller card at a speed of 60 m / min. At this stage, split fibril formation of the fibers was hardly observed, and the card passing property was also very good.

【0023】次に、直径0.1mmの孔が0.6mmピッチ
で1列に配置された噴射ノズル群から圧力120kg/cm
2 で柱状水流が噴き当てられる装置を用い、上記ウエブ
を3回繰り返して分割フィブリル化及び絡合させた後、
130℃で20分間熱風乾燥した。得られたシートを顕
微鏡で観察したところ、本発明にかかる不織布では分割
型複合繊維の95%以上が剥離分割されており、極めて
ソフトな風合を呈するものであった。
Next, a pressure of 120 kg / cm is applied from a group of injection nozzles in which holes having a diameter of 0.1 mm are arranged in a row at a pitch of 0.6 mm.
Using a device in which a columnar water stream is sprayed at 2 , after repeating the above web three times to form split fibrils and entangle,
It was dried with hot air at 130 ° C. for 20 minutes. When the obtained sheet was observed with a microscope, 95% or more of the splittable conjugate fibers were peeled and split in the nonwoven fabric according to the present invention, and exhibited an extremely soft texture.

【0024】[0024]

【表1】 [Table 1]

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明で使用する分割型複合繊維の横断図の一
例を示す。
FIG. 1 shows an example of a cross-sectional view of a splittable conjugate fiber used in the present invention.

【図2】本発明外の分割型複合繊維横断図の一例(Rが
3未満)を示す。
FIG. 2 shows an example (R is less than 3) of a cross section of a splittable conjugate fiber outside the present invention.

【図3】本発明外の分割型複合繊維横断図の一例(Rが
7を越える)を示す。
FIG. 3 shows an example of a cross section of a splittable conjugate fiber outside the present invention (R exceeds 7).

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 互いに非相溶性の成分からなり、その少
なくとも一つの成分が残りの成分によって多層に分割配
置されてなる分割型複合繊維をカードにてウエブとした
後、高圧液体流を噴射することにより、繊維の分割フィ
ブリル化を発生させると共にランダムな絡み合いを行わ
せ一体構造とする不織布の製造方法において、前記複合
繊維が下記条件を満足することを特徴とする不織布の製
造方法。 3.0≦R≦7.0 (式中、Rは、複合繊維の表面積S0 と、互いに非相溶
性成分の接触総面積S1との比S1 /S0 を表わす)
1. A web of splittable conjugate fibers composed of mutually incompatible components, at least one of which is divided into multiple layers by the rest of the components, and then jetted with a high-pressure liquid stream. Thus, in the method for producing a non-woven fabric in which the fibers are split into fibrils and are randomly entangled to form an integral structure, the composite fiber satisfies the following conditions. 3.0 ≦ R ≦ 7.0 (In the formula, R represents the ratio S 1 / S 0 of the surface area S 0 of the composite fiber and the total contact area S 1 of mutually incompatible components)
JP4297161A 1992-11-06 1992-11-06 Production of nonwoven fabric Pending JPH06158498A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4297161A JPH06158498A (en) 1992-11-06 1992-11-06 Production of nonwoven fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4297161A JPH06158498A (en) 1992-11-06 1992-11-06 Production of nonwoven fabric

Publications (1)

Publication Number Publication Date
JPH06158498A true JPH06158498A (en) 1994-06-07

Family

ID=17842983

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4297161A Pending JPH06158498A (en) 1992-11-06 1992-11-06 Production of nonwoven fabric

Country Status (1)

Country Link
JP (1) JPH06158498A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2845696A1 (en) * 2002-10-15 2004-04-16 Elysees Balzac Financiere Non-woven fabric contains majority of microfibres made from materials with higher melting point than thermally bonded fibres

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2845696A1 (en) * 2002-10-15 2004-04-16 Elysees Balzac Financiere Non-woven fabric contains majority of microfibres made from materials with higher melting point than thermally bonded fibres
EP1420097A1 (en) * 2002-10-15 2004-05-19 Financiere Elysees Balzac Microfibrous nonwovens, complexes and manufacturing processes

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