JPS62133164A - Production of nonwoven fabric - Google Patents

Production of nonwoven fabric

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Publication number
JPS62133164A
JPS62133164A JP60271876A JP27187685A JPS62133164A JP S62133164 A JPS62133164 A JP S62133164A JP 60271876 A JP60271876 A JP 60271876A JP 27187685 A JP27187685 A JP 27187685A JP S62133164 A JPS62133164 A JP S62133164A
Authority
JP
Japan
Prior art keywords
split
fibers
short fibers
nonwoven fabric
denier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP60271876A
Other languages
Japanese (ja)
Inventor
誠 佐々木
正 松尾
純 吉田
喜茂 清水
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Rayon Co Ltd
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd
Priority to JP60271876A priority Critical patent/JPS62133164A/en
Publication of JPS62133164A publication Critical patent/JPS62133164A/en
Pending legal-status Critical Current

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  • Nonwoven Fabrics (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 〔浬東上の利用分野〕 本発明は薄くて肌触りの柔かい衛生材料として有用な不
織布の製造法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Application] The present invention relates to a method for producing a nonwoven fabric useful as a sanitary material that is thin and soft to the touch.

〔従来の技術〕[Conventional technology]

従来、衛生材料、特に紙おむつ、生理用ナプキンなどの
カバーストック材にはポリエステル、ポリプロピレン等
のスパンボンドが多く用いられてい次か、近年熱融着性
繊維による短繊維不織布が急激に普及している。
Traditionally, spunbond materials such as polyester and polypropylene have been widely used for sanitary materials, especially cover stock materials such as disposable diapers and sanitary napkins.In recent years, short fiber nonwoven fabrics made from heat-fusible fibers have become rapidly popular. .

一方、セルロース系のスパンボンドは吸水性が高く、ヘ
トつきやすいためカバーストック材としでは利用されず
内部の吸収材として用いらnている。
On the other hand, cellulose-based spunbond has high water absorption and tends to become sticky, so it is not used as a cover stock material but as an internal absorbent material.

また、かかる不織布の製造方式に限定することなく、一
般に不織布として1.5デニ一ル程度の短繊維を用いた
ものが工業的に製造さ牡ているが、肌触りが硬く、出来
るだけデニールを細くして肌触りを柔かくすることが望
まnでい友。
Furthermore, without being limited to the manufacturing method of such non-woven fabrics, non-woven fabrics using short fibers of about 1.5 denier are generally manufactured industrially, but they are hard to the touch and the denier should be as thin as possible. It is desirable to make the skin softer.

し発明が解決しようとする問題点〕 そこで、cL5デニールというような極細短繊維を用い
た不織布の製造も試みらtているが、このような極細デ
ニール短繊維は開繊か困難であり、開繊機速度が上らな
いため生産性か低下することからコスト上昇を招き、経
済的に不利である等の問題点を肩してい友。
[Problems to be Solved by the Invention] Therefore, attempts have been made to manufacture nonwoven fabrics using ultrafine short fibers such as cL5 denier, but such ultrafine denier short fibers are difficult to open. Since the speed of the spinning machine cannot be increased, productivity decreases, leading to an increase in costs, which is economically disadvantageous.

本発明者等は以上のような問題点を改良すべく鋭意研究
を重ね文結果、本発明を完成するに至つ1゜ し問題点を解決する友めの手段〕 本発明は互いに非相溶性の成分からなる分割型複合短繊
維をカードにてウェブとしt後、高圧液体流を噴射する
ことにより繊維全分割フィブリル化させてランダムな絡
み合いを行わせ一体構造とすることを特徴とする不織布
の製造法である。
The inventors of the present invention have carried out intensive research to improve the above-mentioned problems, and as a result, they have completed the present invention. A nonwoven fabric characterized in that splittable composite short fibers consisting of the following components are made into a web using a card, and then all of the fibers are split and fibrillated by jetting a high-pressure liquid stream to randomly entangle them to form an integral structure. It is a manufacturing method.

以下に本発明を更に詳細に説明する。The present invention will be explained in more detail below.

本発明に於ける分割型複合短繊維の横断面の具体例とし
ては、友とえは第1図(al〜(d)に示すように相互
接層性をMしない2種或いは−f:n以上の非相溶性の
熱可塑性重合体成分が交互に配列し友断面形状のもの全
いうが、複数のフィブリルに分割できるものであtば、
こnに限定さnるものではない。
As a specific example of the cross section of the splittable composite staple fiber in the present invention, as shown in FIG. All of the above incompatible thermoplastic polymer components are arranged alternately and have a cross-sectional shape, but if they can be divided into a plurality of fibrils,
It is not limited to this.

本発明に於ける互いに非相溶性の2種の熱可塑性重合体
成分の組合せとは、友とえはポリエステルとポリプロピ
レン、ポリエステルとナイロン、ナイロンとポリプロピ
レンのようなもの金いう。
In the present invention, the combination of two mutually incompatible thermoplastic polymer components includes combinations such as polyester and polypropylene, polyester and nylon, and nylon and polypropylene.

本発明で用いる分割型複合短繊維は、特公昭59−29
636号公報、特開昭50−5650号公報等で公知の
方法によって複合紡糸した未延伸糸を集束して延伸後、
機械捲縮を賦与し、有限繊維長に切断して短繊維とする
ことにより得ることが出来る。tfc、本発明の不織布
を得る上では、分割型複合短繊維全湿熱ま几は乾熱など
適当な方法で熱処理して沸水面槓収縮率を20チ以下に
しておくことが好ましいが、この熱処理はそnぞれ2種
の成分の接触面に熱収縮差による歪をも友らし後加工に
おける分割フィブリル化を促進させる効果を煮起させる
The splittable composite short fibers used in the present invention are
636, JP-A-50-5650, etc., composite spun undrawn yarns are bundled and stretched,
It can be obtained by mechanically crimping and cutting into finite fiber lengths to obtain short fibers. TFC, in order to obtain the nonwoven fabric of the present invention, it is preferable to heat-treat the split type composite staple fibers in a wet heat oven by an appropriate method such as dry heat to reduce the boiling water surface shrinkage to 20 inches or less. This also relieves the strain caused by the difference in heat shrinkage on the contact surfaces of the two components, and has the effect of promoting split fibrillation in post-processing.

分割型複合短繊維の太さは1〜5デニ一ル程度のものが
用いらn、分割フィブリル化によって形成さnる少なく
とも一部の成分からなる分割フィブリル化単繊維のデニ
ールは15デニール以下、好ましくは11デニール以下
とすることが必要で、α5デニールを超えると肌触りが
硬いものとな!ll、特に衛生材料用カバーストック材
としての適性が失わ扛てし1う。
The thickness of the splittable composite short fibers is about 1 to 5 deniers, and the denier of the split fibrillated single fibers formed by split fibrillation, which consists of at least a part of the components, is 15 deniers or less. Preferably, it should be 11 denier or less, and if it exceeds α5 denier, it will be hard to the touch! In particular, it loses its suitability as a cover stock material for sanitary materials.

また、分割型複合短繊維はカードで20重量%以下、高
圧液体流を噴射し友後で80重量係以上の単繊維が完全
に或いは一部分割さnることか好ましい。単繊維の分割
フィブリル化が中途でとどまり完全にばらばらにならな
い場合には未分割の太デニール単繊維と完全な分割フィ
ブリル化によって形成さ扛る細デニールフィブリル状繊
維との中間に数種の異なったデニールの繊維が混在する
ことになるが、本発明の目的を達成するのに何ら差し支
えるものではない。
Further, it is preferable that the splittable composite short fibers are 20% by weight or less in a card, and single fibers with a weight percentage of 80% or more are completely or partially split by spraying a high-pressure liquid stream. If split fibrillation of a single fiber remains midway and does not completely break apart, several different types of fibrillar fibers are formed between the unsplit thick denier single fiber and the thin denier fibrillar fiber formed by complete split fibrillation. Although denier fibers are mixed, this does not pose any problem in achieving the object of the present invention.

本発明に於ける分割型複合短繊維の分割セグメント数は
上述のデニール範囲t−満足する様に決めnば艮〈単繊
維中の一部の成分のセグメント数が多い方がフィブリル
化の利点が大きいが、実際にセグメント数を七扛はど多
くすることは困難であり、通常4〜8のセグメント数と
するのが繊維の製造上の容易さからも有利である。
The number of divided segments of the splittable composite staple fiber in the present invention is determined so as to satisfy the above-mentioned denier range (t). Although the number of segments is large, it is difficult to actually increase the number of segments to more than seven, and it is usually advantageous to have a number of segments of 4 to 8 from the viewpoint of ease of manufacturing the fiber.

ま九個々のセグメントのデニールは同一である必要はな
い。分割を上述の様にコントロールすることによりカー
ド速度を下げることなく、所期の性能を有する不織布が
得らnる。
The denier of the individual segments need not be the same. By controlling the splitting as described above, a nonwoven fabric having the desired performance can be obtained without reducing the carding speed.

分割型複合短繊維の繊維長は15〜80園、捲縮数は2
.5〜15ケ/インチの範囲が好ましい。繊維長が15
m未満ではカーディングによる分割フィブリル化の調整
が困難となり、また、得られるウェブが綿切扛して取扱
いが不良となる。逆に繊維長が80鏑を超えるとカーデ
ィングで分割したフィブリル繊維が切断さnたり、或い
はネップを生じるなど工程上のトラブルが起り、均一な
ウェブ上寿ることか難しくなる。
The fiber length of the split type composite staple fiber is 15 to 80, and the number of crimps is 2.
.. A range of 5 to 15 pieces/inch is preferred. Fiber length is 15
If it is less than m, it will be difficult to adjust the split fibrillation by carding, and the obtained web will be cut into pieces, making it difficult to handle. On the other hand, if the fiber length exceeds 80 fibers, problems occur during the process such as fibril fibers divided by carding being cut or neps occurring, making it difficult to maintain a uniform web.

捲縮数は2.5ケ/インチ未満では繊維同志のからみが
弱くなり圧縮回復性も低下する。逆に、15ケ/インチ
を超えると1¥1!尾が細かくなりすぎてちぢみ、ウェ
ブにした時の嵩も小さくなる。
When the number of crimps is less than 2.5 crimps/inch, the intertwining of the fibers becomes weak and the compression recovery property is also reduced. On the other hand, if it exceeds 15 pieces/inch, it is 1 yen 1! The tail becomes too fine and shrinks, and the bulk when made into a web becomes smaller.

本発明に於いては、かかる分割型複合短繊維を常法によ
りカードにてウェブを形成させ几後、更にカード上りの
ウェブ中の分割型複合短繊維の分割フィブリル化するも
のであるが、分割型複合短繊維の分割フィブリル化を促
進させランダムな絡み合いを起させる九め高圧液体流を
ウェブ表面に衝突させる。液体流として使用する液体は
水まtは温水が取扱いの容易さη為ら望ましい0 1友、液体流の噴射ノズルの孔径は[LO5〜1.0閣
、好ましくは(L1〜α4wI&が望ましい。
In the present invention, such splittable conjugate short fibers are formed into a web using a card by a conventional method, and after cooling, the splittable conjugate short fibers in the web on the card are further divided into fibrils. A high-pressure liquid stream is applied to the web surface to promote fibrillation of split composite short fibers and cause random entanglement. The liquid used as the liquid stream is preferably water or warm water for ease of handling.The hole diameter of the injection nozzle for the liquid stream is preferably LO5 to 1.0, preferably L1 to α4wI&.

噴射圧力は5〜50 K97m”Gであり、噴射孔とウ
ェブの間隔は1〜153が好適であり、間隔が広くなn
ば、噴射液体流と空気が混じりめい交絡効果が小さくな
る。このようにして不織布の目付を10〜10097m
2の範囲にすnば衛生材料用の不織布として好適なもの
が得らnる。
The injection pressure is 5 to 50K97m"G, and the spacing between the injection hole and the web is preferably 1 to 153mm, and the spacing is wide.
For example, the jetted liquid stream and air mix and the confounding effect is reduced. In this way, the basis weight of the nonwoven fabric can be increased from 10 to 10,097 m.
If it falls within the range of 2, a nonwoven fabric suitable for sanitary materials can be obtained.

〔実施例〕〔Example〕

以下に実施例を挙げて本発明を更に詳細に説明する。 The present invention will be explained in more detail with reference to Examples below.

実施例 固有粘度α63(オルソクロロフェノール中25℃)の
ポリエチレンテレフタレートヲ第1成分とし、M I 
15 (A8TM  D−123B、230℃)のポリ
プロピレンを第2取分として、2:1(容積比)の割合
で溶融複合紡糸し、1000m/分で巻き取って第1図
(a)と同様の横断面全有する分割型複合未延伸糸を得
几。この未延伸糸を引き揃えて延伸温度80℃で五5倍
にローラー延伸し単繊維繊度をλ0デニールとした後、
引続き押込み捲縮機にて10ケ/インチの機械捲Inを
賦与し、一旦コンテナにトウとして引きとつ几。このト
ウをオートクレーブに移し130℃の湿熱にて10分間
弛緩熱処理し友後32隠の長さに切断し友。この短繊維
をローラーカードにより100m/分の速度で開繊し4
0g/m2の目付t−Wするウェブとした後ロール巻し
友。
Example Polyethylene terephthalate with an intrinsic viscosity of α63 (in orthochlorophenol at 25°C) was used as the first component, and M I
The second fraction of polypropylene (A8TM D-123B, 230°C) was melt-spun at a ratio of 2:1 (volume ratio), and wound at 1000 m/min to produce the same material as in Fig. 1(a). A split type composite undrawn yarn with a full cross section was obtained. This undrawn yarn was pulled together and stretched with a roller 55 times at a drawing temperature of 80°C to make the single fiber fineness λ0 denier.
Subsequently, 10 pieces/inch of mechanical winding was applied using a push-crimping machine, and the material was once drawn into a container as a tow. This tow was transferred to an autoclave, subjected to relaxation heat treatment at 130°C for 10 minutes, and cut into 32 lengths. This short fiber was opened at a speed of 100 m/min using a roller card.
After forming a web with a basis weight of 0 g/m2, it is rolled.

次に第2図に示す高圧液体流噴射装置を用い、このウェ
ブ(3)ヲネットコンベア(4)上に供給し、ウェブ(
3)側〃為ら孔径α15Ia1、孔間距離1、Ommの
2ケの噴射ノズル(5)全周いて前後10に97 cm
2G 、後段20 Kfl/cm” Gの圧力で水流噴
射しウェブの構成繊維の分割フィブリル化と絡会化を行
つ次□なお、噴射使用済みの水はサクションボックス(
6)で除去した。噴射ノズル(5)とネットコンベア(
4)の間隔は501Iaでネットコンベア(4)の速度
は5m/分であった。引き吐きこの分割フィブリル化ウ
ェブを沸水浴(7)中で収縮させ乾W1!機(8)にて
乾燥し、@取磯(9)にて巻取り、4597m”の目付
を有する不織布を得た。カード上りのウェブ及び得らn
た不織布を光学顕微鏡によ!ll観察すると、そnぞれ
分割フィブリル化した複合短繊維と未分割の複合lPj
、線維が混在したものであり、カード上りウニの単繊維
か完全に或いは一部が分割フィブリル化し、かつ未分割
繊維と分割フィブリル化繊維、分割フィブリル化繊維と
分割フィブリル化繊維が互いにランダムに絡み合つ友も
のであつ友。
Next, using the high-pressure liquid jetting device shown in FIG.
3) Side: Two injection nozzles with hole diameter α15Ia1, distance between holes 1, Omm (5) 97 cm in front and back 10 all around.
2G, in the second stage, water is jetted at a pressure of 20 Kfl/cm"G to split and entangle the constituent fibers of the web. The water used for jetting is stored in a suction box (
6) was removed. Injection nozzle (5) and net conveyor (
The interval of 4) was 501 Ia, and the speed of the net conveyor (4) was 5 m/min. This split fibrillated web is then shrunk in a boiling water bath (7) and dried W1! It was dried in a machine (8) and rolled up in @ Toriiso (9) to obtain a nonwoven fabric having a basis weight of 4597 m''.
Under an optical microscope! When observed, split fibrillated composite short fibers and unsplit composite short fibers were observed.
, is a mixture of fibers, and the single fibers of the carded sea urchin are completely or partially split fibrillated, and the unsplit fibers and split fibrillated fibers, and the split fibrillated fibers and split fibrillated fibers are randomly intertwined with each other. A friend that goes well with you.

得らAN不織布の物性を以下に示す。The physical properties of the obtained AN nonwoven fabric are shown below.

1)未分割単繊維のデニール  zOデニール2)分割
フィブリル化単繊維のデニールポリエチレンテレフタレ
ート 1.24デニール yN IJ フロピレン      α13デニール3
)未分割単繊維の割合    15チ4)不織布の目付
       4597m25)不織布の厚さ    
    0.7m〔発明の効果〕 本発明によ扛は分割型複合短繊維を用いて効率良くウェ
ブとしt後、高圧液体を噴射することにより不織布とな
すことが出来、且つこの不織布は衛生材料用、と9わけ
カバーストック材として有用なるものである。
1) Denier of unsplit single fiber zO denier 2) Denier of split fibrillated single fiber Polyethylene terephthalate 1.24 denier yN IJ Flopylene α13 denier 3
) Proportion of undivided single fibers: 15 cm 4) Fabric weight of non-woven fabric: 4597 m 2) Thickness of non-woven fabric
0.7 m [Effects of the Invention] According to the present invention, a nonwoven fabric can be made into a nonwoven fabric by efficiently forming a web using splittable composite short fibers and then spraying high pressure liquid. , which makes it useful as a cover stock material.

第1図(a1〜(dlは本発明で使用する分割型複合短
繊維の例の横断面、第2図は本発明で使用する昼圧液体
流噴射装置の側面図である。
FIG. 1 (a1 to (dl) are cross sections of examples of split type composite short fibers used in the present invention, and FIG. 2 is a side view of a day pressure liquid jet injection device used in the present invention.

1.2・・・互いに非相溶性の重合体成分3・・・ウェ
ブ、  4・・・ネットコンベア、5・・・高圧液体流
噴射ノズル、 7・・・沸水浴、 8・・・乾燥機 代理人 弁理士  吉 沢 敏 夫(′□“−+  f
  ’Ejl+ (Q)       (b)       (C1(d
’r痺2図
1.2... Mutually incompatible polymer components 3... Web, 4... Net conveyor, 5... High pressure liquid jet nozzle, 7... Boiling water bath, 8... Dryer Agent Patent Attorney Toshio Yoshizawa (′□“−+ f
'Ejl+ (Q) (b) (C1(d
'r paralysis 2 diagram

Claims (1)

【特許請求の範囲】 1、互いに非相溶性の成分からなる分割型複合短繊維を
カードにてウェブとした後、高圧液体流を噴射すること
により、繊維を分割フィブリル化させてランダムな絡み
合いを行わせ一体構造とすることを特徴とする不織布の
製造法。 2、分割型複合短繊維がポリエステルとポリプロピレン
、ポリエステルとナイロン及びナイロンとポリプロピレ
ンの組合せの群から選ばれる組合せの分割型複合短繊維
である特許請求の範囲第1項記載の不織布の製造法。 3、短繊維の繊維長が15〜80mmである特許請求の
範囲第1項記載の不織布の製造法。 4、分割型複合短繊維から分割フィブリル化された少な
くとも一方の成分からなる分割フィブリル化単繊維のデ
ニールが0.5デニール以下である特許請求の範囲第1
項記載の不織布の製造法。
[Claims] 1. After forming a web of split composite short fibers made of components that are incompatible with each other using a card, the fibers are split into fibrils by spraying a high-pressure liquid stream to form random entanglements. A method for producing a non-woven fabric characterized by having an integral structure. 2. The method for producing a nonwoven fabric according to claim 1, wherein the splittable conjugate short fibers are a combination of splittable conjugate short fibers selected from the group of combinations of polyester and polypropylene, polyester and nylon, and nylon and polypropylene. 3. The method for producing a nonwoven fabric according to claim 1, wherein the short fibers have a fiber length of 15 to 80 mm. 4. Claim 1, in which the denier of the split fibrillated single fibers made of at least one component split and fibrillated from the splittable composite short fibers is 0.5 denier or less.
Method for manufacturing the nonwoven fabric described in Section 1.
JP60271876A 1985-12-03 1985-12-03 Production of nonwoven fabric Pending JPS62133164A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60271876A JPS62133164A (en) 1985-12-03 1985-12-03 Production of nonwoven fabric

Applications Claiming Priority (1)

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JP60271876A JPS62133164A (en) 1985-12-03 1985-12-03 Production of nonwoven fabric

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JPS62133164A true JPS62133164A (en) 1987-06-16

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JP60271876A Pending JPS62133164A (en) 1985-12-03 1985-12-03 Production of nonwoven fabric

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62181041A (en) * 1986-02-05 1987-08-08 花王株式会社 Absorbable article
US9205006B2 (en) 2013-03-15 2015-12-08 The Procter & Gamble Company Absorbent articles with nonwoven substrates having fibrils
US9504610B2 (en) 2013-03-15 2016-11-29 The Procter & Gamble Company Methods for forming absorbent articles with nonwoven substrates
US11090407B2 (en) 2017-03-09 2021-08-17 The Procter & Gamble Company Thermoplastic polymeric materials with heat activatable compositions
US11110013B2 (en) 2014-09-10 2021-09-07 The Procter & Gamble Company Nonwoven webs with hydrophobic and hydrophilic layers
US11129919B2 (en) 2016-03-09 2021-09-28 The Procter & Gamble Company Absorbent article with activatable material

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62181041A (en) * 1986-02-05 1987-08-08 花王株式会社 Absorbable article
US9205006B2 (en) 2013-03-15 2015-12-08 The Procter & Gamble Company Absorbent articles with nonwoven substrates having fibrils
US9504610B2 (en) 2013-03-15 2016-11-29 The Procter & Gamble Company Methods for forming absorbent articles with nonwoven substrates
US9974700B2 (en) 2013-03-15 2018-05-22 The Procter & Gamble Company Absorbent articles with nonwoven substrates having fibrils
US10016319B2 (en) 2013-03-15 2018-07-10 The Procter & Gamble Company Absorbent articles with nonwoven substrates having fibrils
US10993855B2 (en) 2013-03-15 2021-05-04 The Procter & Gamble Company Absorbent articles with nonwoven substrates having fibrils
US11110013B2 (en) 2014-09-10 2021-09-07 The Procter & Gamble Company Nonwoven webs with hydrophobic and hydrophilic layers
US11839531B2 (en) 2014-09-10 2023-12-12 The Procter And Gamble Company Nonwoven webs with hydrophobic and hydrophilic layers
US11129919B2 (en) 2016-03-09 2021-09-28 The Procter & Gamble Company Absorbent article with activatable material
US11090407B2 (en) 2017-03-09 2021-08-17 The Procter & Gamble Company Thermoplastic polymeric materials with heat activatable compositions

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