JPH06157108A - Carbon fiber reinforced lightweight mortar containing frp powder - Google Patents
Carbon fiber reinforced lightweight mortar containing frp powderInfo
- Publication number
- JPH06157108A JPH06157108A JP18023192A JP18023192A JPH06157108A JP H06157108 A JPH06157108 A JP H06157108A JP 18023192 A JP18023192 A JP 18023192A JP 18023192 A JP18023192 A JP 18023192A JP H06157108 A JPH06157108 A JP H06157108A
- Authority
- JP
- Japan
- Prior art keywords
- carbon fiber
- lightweight mortar
- frp
- fiber reinforced
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/0048—Fibrous materials
- C04B20/0052—Mixtures of fibres of different physical characteristics, e.g. different lengths
Abstract
Description
【0001】[0001]
【産業上の利用分野】この出願の発明は、建築物の外装
材料、あるいは建築物の外壁材の原材料などに利用され
る軽量モルタルに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The invention of this application relates to a lightweight mortar used as an exterior material of a building or a raw material of an outer wall material of a building.
【0002】[0002]
【従来の技術】従来、モルタルには用途に応じて、シラ
スバルーンやパーライトなどの軽量細骨材を用いたり、
モルタル中に多数の気泡を導入したりした軽量モルタ
ル、あるいはモルタル中に耐アルカリガラス繊維などを
混入した繊維補強モルタルなどが存在した。しかし、そ
れらのモルタルは、軽量化は実現しても機械的強度が低
かったり、強度は得られても軽量化が難しかったり、あ
るいは凍結融解に対して極めて弱体であったりなど、い
ずれも多くの欠点を有していた。一方、ガラス繊維など
の強化材で補強したFRP(繊維強化プラスチック)
は、成形素材として優れた性質を有しており、多くの分
野で利用されているが、その高強度と高耐久性のため不
要となったFRPの廃棄物の処理は破砕や分解に困難を
伴い、放置された場合には環境破壊を引き起こし、社会
問題となっている。これに対して、本出願の発明者の一
入は、鋭意研究の結果、FRP廃棄物を微粉砕すること
に成功し、最近は平均粒径数μm程度のFRP微粉末を
1時間当たり100kgも製造できる粉砕装置の開発に
成功した。(特願平3−126957号) また、その
FRP微粉末をセメント系材料の骨材として利用するこ
とを検討した結果、コンクリートやモルタルの細骨材と
して極めて有用なこともわかった。2. Description of the Related Art Conventionally, lightweight fine aggregate such as shirasu balloon or perlite is used for mortar, depending on the application.
There were lightweight mortars with many bubbles introduced into the mortar, and fiber reinforced mortars containing alkali-resistant glass fibers in the mortar. However, those mortars have many mechanical strengths such as low mechanical strength even if weight reduction is realized, difficult weight reduction even if strength is obtained, or extremely weak against freeze-thaw. It had drawbacks. On the other hand, FRP (fiber reinforced plastic) reinforced with a reinforcing material such as glass fiber
Has excellent properties as a molding material and is used in many fields, but its high strength and high durability make it difficult to crush and disassemble the waste of FRP that is no longer needed. Accordingly, if left unattended, it causes environmental damage, which is a social problem. On the other hand, the inventor of the present application succeeded in finely pulverizing FRP waste as a result of earnest research, and recently, 100 kg of FRP fine powder having an average particle diameter of several μm per hour was obtained. We have succeeded in developing a crusher that can be manufactured. (Japanese Patent Application No. 3-126957) Further, as a result of studying the use of the FRP fine powder as an aggregate of a cement-based material, it was found that it was extremely useful as a fine aggregate of concrete or mortar.
【0003】[0003]
【発明が解決しようとする課題】この出願の発明は、機
械的強度、乾燥によるひび割れ、及び耐凍結融解法に優
れた軽量モルタルを提供すると共に、そのモルタルの細
骨材としてFRP微粉末を利用し、産業廃棄物として多
量に発生するFRP廃材のリサイクルをも図ろうとする
ものである。DISCLOSURE OF THE INVENTION The invention of the present application provides a lightweight mortar excellent in mechanical strength, cracking due to drying, and freeze-thaw resistance, and uses FRP fine powder as a fine aggregate of the mortar. However, it also aims to recycle the FRP waste materials that are produced in large quantities as industrial waste.
【0004】[0004]
【課題を解決するための手段】この出願のFRP粉末を
混入した炭素繊維補強軽量モルタルは、FRP廃材の粉
末を細骨材の一部として混入した軽量モルタル中に、短
い炭素繊維をランダムに分散させたものである。[Means for Solving the Problems] The carbon fiber reinforced lightweight mortar containing the FRP powder of the present application has short carbon fibers randomly dispersed in the lightweight mortar containing the powder of FRP waste as a part of the fine aggregate. It was made.
【0005】[0005]
【作用】細骨材の一部として混入したFRP廃材の粉末
は、それ自体の粒径が小さいため、モルタル中の空隙を
減少させ、モルタルの乾燥時のひび割れの発生を抑制す
ると共に、凍結融解に対しても空隙の減少とFRP廃材
の粉末自体の撥水性とによってモルタル内部への水の侵
入を防止し、凍結現象を防ぎ、耐凍結融解性を向上させ
る。また、モルタル全体にわたってランダムに分散され
た短い炭素繊維は、モルタルの単位容積重量を変化させ
ることなく、炭素繊維自体の機械的性質により、モルタ
ル硬化後の曲げ強度及び圧縮強度を格段に向上させる。[Function] The powder of FRP waste material mixed as a part of the fine aggregate has a small particle size, so that it reduces the voids in the mortar, suppresses the occurrence of cracks when the mortar is dried, and freezes and thaws it. In contrast, the reduction of voids and the water repellency of the powder of the FRP waste material prevent the entry of water into the mortar, prevent the freezing phenomenon, and improve the freeze-thaw resistance. Also, the short carbon fibers randomly dispersed throughout the mortar significantly improve the bending strength and compressive strength after hardening of the mortar by the mechanical properties of the carbon fiber itself without changing the unit volume weight of the mortar.
【0006】[0006]
【実施例】この出願の発明の実施例について説明する。
軽量モルタルの性状改善を目的として、FRP廃材粉末
を細骨材の一部として混入した軽量モルタルの中に、比
較的少量の短い炭素繊維をランダムに分散させた炭素繊
維補強軽量モルタルを作成した。炭素繊維は長さ6mm
のピッチ系の汎用品、セメントは普通ポルトランドセメ
ント、軽量細骨材はシラスバルーン、FRP廃材粉末は
数μm程度の粒径のものを75%以上含むものをそれぞ
れ用いた。また、混和材料として高性能減水剤(マイテ
ィーFD)、メチルセルロースおよびシリカフュームを
用いた。軽量モルタルとしての諸特性を調べるために、
供試体を作って試験を行った。供試体(軽量モルタル)
は、水セメント比が0.9、細骨材(シラスバルーンと
FRP廃材粉末)セメント比が0.67、FRP廃材粉
末細骨材比が0.43で、高性能減水剤をセメント重量
の1.5%添加して作成した。その時、供試体Aの場合
は水の重量の0.5%のメチルセルロースを添加した。
また、供試体Bの場合には、セメント重量の20%をシ
リカフュームで置き換えて用いた。炭素繊維の容積混入
率(Vf)は、供試体A,Bとも1.5%とした。ま
た、特性の比較のために、供試体A,Bのそれぞれに炭
素繊維を全く含まない(Vf=0%)供試体も作製し
た。練り混ぜは、通常のモルタルミキサを用いて行なっ
た。供試体の寸法は、幅と高さが40mmで長さが16
0mmとし、JISR5201に準拠して作製し、これ
を水中で7日間養生を行った。作られた各供試体につい
て、フロー値,単位容積重量,曲げ強度及び圧縮強度を
求めた。それらの結果を表1に示す。EXAMPLES Examples of the invention of this application will be described.
For the purpose of improving the properties of the lightweight mortar, a carbon fiber reinforced lightweight mortar was prepared by randomly dispersing a relatively small amount of short carbon fibers in a lightweight mortar in which FRP waste powder was mixed as a part of fine aggregate. Carbon fiber is 6 mm long
A general-purpose pitch-based product, a cement was ordinary Portland cement, a lightweight fine aggregate was Shirasu balloon, and an FRP waste powder containing 75% or more of particles having a particle size of several μm. Further, a high performance water reducing agent (Mighty FD), methyl cellulose and silica fume were used as admixtures. In order to investigate various characteristics as a lightweight mortar,
A test piece was made and tested. Specimen (lightweight mortar)
Has a water-cement ratio of 0.9, a fine aggregate (shirasu balloon and FRP waste powder) cement ratio of 0.67, a FRP waste powder fine aggregate ratio of 0.43, and a high-performance water-reducing agent with a cement weight of 1 It was made by adding 0.5%. At that time, in the case of Specimen A, 0.5% by weight of water of methyl cellulose was added.
Further, in the case of Specimen B, 20% of the cement weight was replaced with silica fume. The volume mixing ratio (Vf) of carbon fiber was set to 1.5% for both test pieces A and B. Further, for the purpose of comparison of characteristics, a test sample was also prepared in which each of the test samples A and B did not contain any carbon fiber (Vf = 0%). The kneading was performed using a normal mortar mixer. The size of the test piece is 40 mm in width and height and 16 in length.
The thickness was set to 0 mm, and it was manufactured according to JIS R5201, and was cured in water for 7 days. The flow value, unit volume weight, bending strength, and compressive strength were obtained for each of the prepared specimens. The results are shown in Table 1.
【0007】[0007]
【表1】 [Table 1]
【0008】炭素繊維の分散性は、供試体A,Bともに
良好であった。また、単位容積重量は繊維を混入しても
繊維を混入しない場合とほぼ同じ値が得られた。ただ
し、複合材の流動性は、炭素繊維で補強しないものに比
べて当然ながら低下した。メチルセルロースを用いた供
試体Aの場合、炭素繊維で補強しないものに比べて、曲
げ強度は2倍,また圧縮強度でも1.8倍の値が得られ
た。また、シリカフュームを用いた供試体Bの場合で
も、炭素繊維で補強しないものに比べて、曲げ強度は
2.4倍,圧縮強度は1.2倍の値が得られた。これら
の荷重−たわみ曲線を図1に示す。図1において、1は
Vf=1.5%の炭素繊維補強の供試体A、2はVf=
1.5%の炭素繊維補強の供試体Bで、3は炭素繊維で
補強していないVf=0%の供試体A,Bのそれぞれの
荷重−たわみ曲線を示している。図示のように、最大荷
重時までのたわみ量は、炭素繊維で補強しないものに比
べ、いずれの供試体の場合も4倍程度が得られた。この
ように、比較的少ない繊維量でも、軽量を維持しなが
ら、強度や変形性能を向上させることができた。The dispersibility of the carbon fibers was good in both specimens A and B. Further, the unit volume weight was almost the same as when the fiber was not mixed even when the fiber was mixed. However, the fluidity of the composite material was naturally lower than that of the composite material not reinforced with carbon fiber. In the case of Specimen A using methyl cellulose, the bending strength was twice as high and the compressive strength was 1.8 times as high as that of the one not reinforced with carbon fiber. Also, in the case of the sample B using silica fume, the bending strength and the compressive strength were 2.4 times and 1.2 times, respectively, as compared with those not reinforced with carbon fiber. These load-deflection curves are shown in FIG. In FIG. 1, 1 is a carbon fiber reinforced sample A with Vf = 1.5%, and 2 is Vf =
Specimen B reinforced with carbon fiber of 1.5%, 3 shows load-deflection curves of specimens A and B with Vf = 0% not reinforced with carbon fiber. As shown in the figure, the amount of deflection up to the maximum load was about four times higher than that of one not reinforced with carbon fiber in any of the specimens. Thus, it was possible to improve the strength and the deformation performance while maintaining the light weight even with a relatively small amount of fibers.
【0009】[0009]
【発明の効果】この発明の炭素繊維補強軽量モルタル
は、軽量性,曲げ強度や圧縮強度などの機械的強度,乾
燥時の耐ひびわれ性及び耐凍結融解性の点で、従来の軽
量モルタルに比べて格段に優れた特性を示すと共に、廃
棄物となるFRP廃材を資源として再利用するという面
からも、極めて有用なものである。EFFECT OF THE INVENTION The carbon fiber reinforced lightweight mortar of the present invention is superior to conventional lightweight mortar in terms of lightness, mechanical strength such as bending strength and compression strength, crack resistance during drying and freeze-thaw resistance. It is extremely useful from the viewpoint of exhibiting remarkably excellent characteristics and reusing waste FRP waste material as a resource.
【図1】実施例における供試体の曲げ強度測定時の荷重
−たわみ曲線図である。FIG. 1 is a load-deflection curve diagram when measuring a bending strength of a test piece in an example.
1 炭素繊維で補強した供試体A(Vf=1.5%)の
荷重−たわみ曲線 2 炭素繊維で補強した供試体B(Vf=1.5%)の
荷重−たわみ曲線 3 炭素繊維で補強しない供試体A,B(Vf=0%)
の荷重−たわみ曲線1 Load-deflection curve of specimen A (Vf = 1.5%) reinforced with carbon fiber 2 Load-deflection curve of specimen B (Vf = 1.5%) reinforced with carbon fiber 3 Not reinforced with carbon fiber Specimens A and B (Vf = 0%)
Load-deflection curve
フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 C04B 14:38 A 2102−4G 14:16 2102−4G 24:22 B 2102−4G 24:38 D 2102−4G 22:06) A 2102−4G (72)発明者 浅田 俊彦 東京都狛江市東和泉一丁目34番19号Continuation of front page (51) Int.Cl. 5 Identification code Office reference number FI Technical display location C04B 14:38 A 2102-4G 14:16 2102-4G 24:22 B 2102-4G 24:38 D 2102-4G 22:06) A 2102-4G (72) Inventor Toshihiko Asada 1-34-19 Higashiizumi, Komae City, Tokyo
Claims (1)
して混入した軽量モルタル中に、短い炭素繊維をランダ
ムに分散させたことを特徴とするFRP粉末を混入した
炭素繊維補強軽量モルタル1. A carbon fiber reinforced lightweight mortar containing FRP powder, wherein short carbon fibers are randomly dispersed in a lightweight mortar containing powder of FRP waste as a part of fine aggregate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18023192A JPH06157108A (en) | 1992-05-29 | 1992-05-29 | Carbon fiber reinforced lightweight mortar containing frp powder |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18023192A JPH06157108A (en) | 1992-05-29 | 1992-05-29 | Carbon fiber reinforced lightweight mortar containing frp powder |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH06157108A true JPH06157108A (en) | 1994-06-03 |
Family
ID=16079674
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP18023192A Pending JPH06157108A (en) | 1992-05-29 | 1992-05-29 | Carbon fiber reinforced lightweight mortar containing frp powder |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH06157108A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107056098A (en) * | 2017-04-25 | 2017-08-18 | 济南大学 | A kind of standby alkali-activated carbonatite binder materials of discarded glass steel |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6433037A (en) * | 1987-04-13 | 1989-02-02 | Onoda Cement Co Ltd | Method for dispersing fiber for reinforcement |
JPH03275548A (en) * | 1990-03-14 | 1991-12-06 | Asaoka Kk | Cement-based composite material containing organic polymer made of waste fiber reinforced plastic powder as aggregate and hardened body thereof |
-
1992
- 1992-05-29 JP JP18023192A patent/JPH06157108A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6433037A (en) * | 1987-04-13 | 1989-02-02 | Onoda Cement Co Ltd | Method for dispersing fiber for reinforcement |
JPH03275548A (en) * | 1990-03-14 | 1991-12-06 | Asaoka Kk | Cement-based composite material containing organic polymer made of waste fiber reinforced plastic powder as aggregate and hardened body thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107056098A (en) * | 2017-04-25 | 2017-08-18 | 济南大学 | A kind of standby alkali-activated carbonatite binder materials of discarded glass steel |
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