JPH06133707A - Method for improving flavor of polyhydric unsaturated fatty acid-containing composition and food utilizing the same composition - Google Patents

Method for improving flavor of polyhydric unsaturated fatty acid-containing composition and food utilizing the same composition

Info

Publication number
JPH06133707A
JPH06133707A JP4327175A JP32717592A JPH06133707A JP H06133707 A JPH06133707 A JP H06133707A JP 4327175 A JP4327175 A JP 4327175A JP 32717592 A JP32717592 A JP 32717592A JP H06133707 A JPH06133707 A JP H06133707A
Authority
JP
Japan
Prior art keywords
oil
flavor
fat composition
acid
fatty acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP4327175A
Other languages
Japanese (ja)
Inventor
Susumu Abe
晋 阿部
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chugai Pharmaceutical Co Ltd
Original Assignee
Chugai Pharmaceutical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chugai Pharmaceutical Co Ltd filed Critical Chugai Pharmaceutical Co Ltd
Priority to JP4327175A priority Critical patent/JPH06133707A/en
Publication of JPH06133707A publication Critical patent/JPH06133707A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To efficiently remove oil odor and offensive odor from an oil and fat composition containing a polyhydric unsaturated fatty acid and improve flavor of the oil and fat composition excellent in palatability and useful for foods, etc., by adding peppermint-based flavor to the oil and fat composition. CONSTITUTION:Preferably 0.01-1.0% peppermint-based flavor is added to an oil and fat composition containing omega-3-based polyhydric unsaturated fatty acid selected from docosahexanoic acid, eicosapentanoic acid and alpha-linolenic acid and mixtures thereof to improve flavor of the oil and fat composition.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、ドコサヘキサエン酸、
エイコサペンタエン酸およびアルファリノレン酸等多価
不飽和脂肪酸を含有する油脂組成物において、特有の油
臭や不快臭をマスキングし香味を改善し、良好な嗜好性
を有する多価不飽和脂肪酸含有油脂組成物に関する。
The present invention relates to docosahexaenoic acid,
In an oil / fat composition containing a polyunsaturated fatty acid such as eicosapentaenoic acid and alpha-linolenic acid, a polyunsaturated fatty acid-containing oil / fat composition having a good palatability by masking a peculiar oily odor or an unpleasant odor and improving the flavor Regarding things.

【0002】[0002]

【従来の技術・発明が解決しようとする課題】リノール
酸等の不飽和脂肪酸摂取は、血中のコレステロール濃度
を低下させ、動脈硬化を予防し、さらには血栓を予防す
る物質として機能が認められている。近年までは主とし
てω−6系(n−6系)の不飽和脂肪酸に着目されてい
たが、最近は、種々の不飽和脂肪酸の中で、特にω−3
系(n−3系)の不飽和脂肪酸すなわちドコサヘキサエ
ン酸、エイコサペンタエン酸およびアルファリノレン酸
等が注目されてきている。これらのω−3系(n−3
系)の多価不飽和脂肪酸は、血中脂質(コレステロール
・中性脂肪)低下、血小板凝集抑制(抗血栓)、血圧降
下、抗腫瘍、抗糖尿病(血糖値低下)、抗炎症、抗アレ
ルギー、学習機能向上、網膜反射能向上作用等が報告さ
れ脚光を浴びている。これら多価不飽和脂肪酸は、天然
物からの抽出により製造されているため、不飽和脂肪酸
特有の油臭さを有し、特にドコサヘキサエン酸およびエ
イコサペンタエン酸は、魚油から製造されるので、原料
由来の魚臭等が感じられている。また、多価不飽和脂肪
酸は、保存によって、初期の自動酸化により発現する特
有の不快臭があり、さらに酸素や光等により容易に変質
するため、不快臭が発生し易い。このマスキング技術と
して従来の技術には、ライムフレーバーを含有させて不
快臭、嘔吐感を除去した「海産動物脂質濃縮物(特公昭
60−18382号公報)」がある。しかしながら、こ
の技術では、添加使用するライムフレーバーの量が1〜
10%と非常に多い。一般的に油脂類へ香料を添加する
場合、油脂とよく混ざり合うオイル系の香料が使用され
ることが多いが、オイル系の香料は高価格であり、1〜
10%配合して商品化することは、一部の高価な商品に
のみ限定され、広く様々な商品に使用することは、製造
コストの面で不利である。香料添加量についての公定書
記載例として、例えば医薬品製造指針には、内服液剤微
量表示の場合には通常0.01%以下、内服固形製剤に
おいても0.1%以下とされており、食品の場合にもこ
れに準じてできるだけ少量の添加が望まれている。ま
た、天然物抽出香料は成分の同定されていない十数種以
上の多成分系物質からなっていることが多く、合成香料
の場合には10〜30種の成分が調合されているため、
多量の香料を含む製品を食品として摂取することは、未
知物質の大量摂取につながり、安全性に問題がある。
BACKGROUND OF THE INVENTION Ingestion of unsaturated fatty acids such as linoleic acid has been recognized as a substance that lowers blood cholesterol level, prevents arteriosclerosis, and further prevents thrombus. ing. Until recently, the focus was mainly on the ω-6 (n-6) unsaturated fatty acids, but recently, among various unsaturated fatty acids, particularly ω-3.
Attention has been focused on the series (n-3 series) unsaturated fatty acids, that is, docosahexaenoic acid, eicosapentaenoic acid, and alpha-linolenic acid. These ω-3 systems (n-3
System) polyunsaturated fatty acids are low in blood lipids (cholesterol / triglyceride), platelet aggregation suppression (antithrombotic), hypotension, antitumor, antidiabetes (lowering blood glucose level), anti-inflammatory, anti-allergic, Improvements in learning function and retinal reflex ability have been reported and are in the spotlight. Since these polyunsaturated fatty acids are produced by extraction from natural products, they have an oily odor peculiar to unsaturated fatty acids. In particular, docosahexaenoic acid and eicosapentaenoic acid are produced from fish oil, so they are derived from raw materials. The smell of fish is felt. Further, the polyunsaturated fatty acid has a peculiar unpleasant odor that is expressed by initial autoxidation upon storage, and is easily denatured by oxygen, light, etc., so that the unpleasant odor is likely to occur. As a conventional technique for this masking technique, there is "Marine Animal Lipid Concentrate (Japanese Patent Publication No. 60-18382)" which contains a lime flavor to remove unpleasant odor and vomiting sensation. However, with this technique, the amount of lime flavor added and used is 1 to
Very high at 10%. Generally, when adding a fragrance to oils and fats, oil-based fragrances that are well mixed with oils and fats are often used, but oil-based fragrances are expensive and
Commercialization with 10% blending is limited to only some expensive products, and use in a wide variety of products is disadvantageous in terms of manufacturing cost. As an example of a compendial document regarding the amount of flavor added, for example, in the Pharmaceutical Manufacturing Guidelines, it is usually 0.01% or less in the case of a small amount indication for an internal liquid medicine, and 0.1% or less in a solid oral preparation. Even in this case, it is desired to add as little amount as possible in accordance with this. In addition, natural product-extracted fragrances are often composed of more than a dozen or more multi-component substances with no identified components, and in the case of synthetic fragrances, 10 to 30 types of components are prepared,
Ingesting a product containing a large amount of fragrance as a food leads to ingestion of a large amount of unknown substances, which poses a safety problem.

【0003】[0003]

【課題を解決するための手段】本発明者らは、上記課題
を解決すべく鋭意研究を重ねた結果、ペパーミント抽出
成分を含有するペパーミント系香料を、ドコサヘキサエ
ン酸、エイコサペンタエン酸およびアルファリノレン酸
等多価不飽和脂肪酸を含有する油脂組成物に微量添加す
ることにより、特有の油臭や不快な香味が著しく改善さ
れることをみいだした。本発明で使用するペパーミント
系香料は、ペパーミントから抽出された成分を含有する
ものであればよく、ペパーミントオイル、ペパーミント
フレーバー等の形でドコサヘキサエン酸、エイコサペン
タエン酸およびアルファリノレン酸等を含有する油脂組
成物に添加することができる。その添加量は、油脂組成
物に対して0.01%以上で有効であるが、1.0%以
上では香料の香りが強くなりすぎてしまう。好ましくは
0.05〜0.2%の範囲がよい。このようにペパーミ
ント系香料を多価不飽和脂肪酸を含有する油脂組成物に
添加使用することにより、ごく微量の添加によって香味
改善ができるので、ドコサヘキサエン酸、エイコサペン
タエン酸およびアルファリノレン酸等を含有する油脂組
成物を利用した健康食品や一般向け商品へも低コストで
使用でき、安全性の面からも有利である。さらに、ペパ
ーミント系香料を添加して香味が改善された多価不飽和
脂肪酸含有油脂組成物に他の香料を添加したり、ペパー
ミント系香料と他の香料をあらかじめ組み合わせること
により、他の香味を付加させることもできる。
Means for Solving the Problems As a result of intensive studies to solve the above problems, the present inventors have found that peppermint-based fragrances containing a peppermint extract component are used as docosahexaenoic acid, eicosapentaenoic acid, alpha linolenic acid, and the like. It was found that the peculiar oily odor and unpleasant flavor can be remarkably improved by adding a very small amount to an oil or fat composition containing a polyunsaturated fatty acid. Peppermint flavors used in the present invention may be those containing components extracted from peppermint, peppermint oil, oil composition containing docosahexaenoic acid, eicosapentaenoic acid and alpha linolenic acid in the form of peppermint flavor and the like. Can be added to the product. The addition amount is effective at 0.01% or more with respect to the oil and fat composition, but at 1.0% or more, the fragrance of the fragrance becomes too strong. The range of 0.05 to 0.2% is preferable. Thus, by adding and using a peppermint flavor to an oil and fat composition containing a polyunsaturated fatty acid, it is possible to improve the flavor by adding a very small amount, so that docosahexaenoic acid, eicosapentaenoic acid and alpha linolenic acid are contained. It can be used at low cost for health foods and general merchandise using the oil and fat composition, and is advantageous in terms of safety. Furthermore, by adding another flavor to the polyunsaturated fatty acid-containing oil or fat composition in which the flavor has been improved by adding a peppermint flavor, or adding another flavor by previously combining the peppermint flavor with another flavor. You can also let it.

【0004】本発明を利用して、ドコサヘキサエン酸、
エイコサペンタエン酸およびアルファリノレン酸等を含
有する油脂組成物をそのまま、あるいは必要に応じビタ
ミンA、ビタミンD、ビタミンE等の脂溶性ビタミン類
やレシチン等を添加して瓶詰めとしたり、ゼラチン等を
用いたソフトカプセルあるいはハードカプセルに充填
し、製品化することもできる。このほかに、サラダオイ
ル、ドレッシング、マヨネーズ、マーガリン等に添加し
て製品化することも可能である。
Utilizing the present invention, docosahexaenoic acid,
Oil and fat composition containing eicosapentaenoic acid and alpha linolenic acid etc. as it is, or if necessary, fat-soluble vitamins such as vitamin A, vitamin D, vitamin E, etc. and lecithin are added for bottling, gelatin etc. are used. It can also be put into a soft capsule or a hard capsule that has been used for commercialization. In addition to this, it is also possible to add it to salad oil, dressing, mayonnaise, margarine, etc. to commercialize it.

【0005】[0005]

【実施例】以下、実施例により本発明を詳述する。尚、
本発明はこれらによって何ら限定されるものではない。
EXAMPLES The present invention will be described in detail below with reference to examples. still,
The present invention is not limited to these.

【0006】[0006]

【実施例1】アルファリノレン酸を55%以上含有する
しそ油25gと、エイコサペンタエン酸を5%以上およ
びドコサヘキサエン酸を23%以上含む魚油25gを混
合した。これに、ペパーミントオイルを前記油脂混合物
に対して0.05%、0.1%および0.2%ずつ添加
混合し、香味を評価した。また、比較例として、ペパー
ミントオイルの代わりに他の香料を用いたものを同様に
製し、香味を評価した。結果を表1に示す。
Example 1 25 g of perilla oil containing 55% or more of alpha linolenic acid was mixed with 25 g of fish oil containing 5% or more of eicosapentaenoic acid and 23% or more of docosahexaenoic acid. Peppermint oil was added to and mixed with 0.05%, 0.1% and 0.2% of the oil / fat mixture, and the flavor was evaluated. In addition, as a comparative example, another flavor was used instead of peppermint oil, and the flavor was evaluated in the same manner. The results are shown in Table 1.

【0007】[0007]

【表1】 [Table 1]

【0008】表1から明らかなように、0.05%〜
0.2%の微量の香料添加量で香味改善効果が顕著にみ
られるのはペパーミント系香料のみで、他の香料成分を
添加したものの中にも、香味改善効果を示しているもの
があるが、その効果は弱く、かりに改善されたものでも
特有の油臭さは残っていた。
As is clear from Table 1, 0.05% to
It is only the peppermint type fragrance that a remarkable flavor improving effect can be seen with a small amount of the fragrance added of 0.2%, and among those added with other fragrance ingredients, there are some which show the flavor improving effect. However, the effect was weak, and even if it was improved, the characteristic oily odor remained.

【0009】[0009]

【実施例2】実施例1で用いたものと同じしそ油1.4
kgと魚油1.4kgを混合し、これにペパーミントオ
イルを前記油脂混合物に対して0.1%添加混合した後
ソフトゼラチンカプセルに充填し、香味を評価した。ま
た、比較例として、ペパーミントオイルを添加せずに同
様に製した製剤についても同様に香味を評価した。その
結果、ソフトゼラチンカプセルを口中で噛みつぶした場
合、ペパーミントオイル無添加のものは、特有な油臭が
口中に広がり不快であったが、ペパーミントオイルを添
加したものは、さわやかな軽い香味が口中に広がり不快
感は全くなかった。また、ソフトゼラチンカプセルをそ
のまま飲み込んだ場合、ペパーミントオイル無添加のも
は、服用後にげっぷ等によって油臭さや不快感を感じる
ことがあるが、ペパーミントオイルを添加したものは、
げっぷがでても不快な油臭さ等は全くなく、爽快なペパ
ーミントの軽い香りが口中に広がり、良好であった。
Example 2 Perilla oil 1.4 same as that used in Example 1
kg and fish oil 1.4 kg were mixed, and 0.1% of peppermint oil was added to the oil and fat mixture, and the mixture was filled in a soft gelatin capsule to evaluate the flavor. Further, as a comparative example, the flavor was similarly evaluated for a preparation prepared in the same manner without adding peppermint oil. As a result, when soft gelatin capsules were chewed in the mouth, the one without added peppermint oil had a peculiar oily odor and was uncomfortable, but the one with added peppermint oil had a refreshing light flavor in the mouth. There was no discomfort at all. Also, when swallowing soft gelatin capsules as they are, those without peppermint oil may feel oily or uncomfortable due to belching etc. after taking, but those with peppermint oil added,
There was no unpleasant oily odor even with belching, and a refreshing light scent of peppermint spread in the mouth, which was good.

【0010】[0010]

【発明の効果】以上説明したように、本発明の方法によ
れば、ω−3系多価不飽和脂肪酸を含有する油脂組成物
において、特有の油臭や不快臭を、効果的に、経済的に
改善することができる。本発明の、香味が改善されて安
全性も高いω−3系多価不飽和脂肪酸含有油脂組成物
は、食品等、様々な用途に適用できる優れたものであ
る。
As described above, according to the method of the present invention, in an oil / fat composition containing an ω-3 polyunsaturated fatty acid, a peculiar oily odor or unpleasant odor can be effectively and economically obtained. Can be improved. The ω-3 polyunsaturated fatty acid-containing oil / fat composition with improved flavor and high safety according to the present invention is excellent in various applications such as foods.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】ω−3系多価不飽和脂肪酸を含有する油脂
組成物において、ペパーミント系の香料を添加すること
により、特有の油臭および不快臭を改善する方法。
1. A method for improving peculiar oily odor and unpleasant odor by adding a peppermint fragrance to an oil and fat composition containing an ω-3 polyunsaturated fatty acid.
【請求項2】ω−3系多価不飽和脂肪酸がドコサヘキサ
エン酸、エイコサペンタエン酸、アルファリノレン酸お
よびその混合物から選ばれたものである、請求項1に記
載の方法。
2. The method according to claim 1, wherein the ω-3 polyunsaturated fatty acid is selected from docosahexaenoic acid, eicosapentaenoic acid, alpha-linolenic acid and mixtures thereof.
【請求項3】ペパーミント系香料の添加量が、油脂組成
物に対して0.01%〜1.0%である、請求項1また
は2に記載の方法。
3. The method according to claim 1, wherein the added amount of the peppermint flavor is 0.01% to 1.0% with respect to the oil or fat composition.
【請求項4】請求項1〜3のいずれかに記載の方法で不
快臭が改善された油脂組成物を含有する食品。
4. A food containing an oil and fat composition having an unpleasant odor improved by the method according to claim 1.
JP4327175A 1992-10-23 1992-10-23 Method for improving flavor of polyhydric unsaturated fatty acid-containing composition and food utilizing the same composition Pending JPH06133707A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4327175A JPH06133707A (en) 1992-10-23 1992-10-23 Method for improving flavor of polyhydric unsaturated fatty acid-containing composition and food utilizing the same composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4327175A JPH06133707A (en) 1992-10-23 1992-10-23 Method for improving flavor of polyhydric unsaturated fatty acid-containing composition and food utilizing the same composition

Publications (1)

Publication Number Publication Date
JPH06133707A true JPH06133707A (en) 1994-05-17

Family

ID=18196150

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4327175A Pending JPH06133707A (en) 1992-10-23 1992-10-23 Method for improving flavor of polyhydric unsaturated fatty acid-containing composition and food utilizing the same composition

Country Status (1)

Country Link
JP (1) JPH06133707A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004520355A (en) * 2001-01-17 2004-07-08 アール.ピー. シェーラー テクノロジーズ インコーポレイテッド Ingestible composition containing odorous oil

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004520355A (en) * 2001-01-17 2004-07-08 アール.ピー. シェーラー テクノロジーズ インコーポレイテッド Ingestible composition containing odorous oil
US9532585B2 (en) 2001-01-17 2017-01-03 R.P. Scherer Technologies, Llc Ingestible compositions containing an odoriferous oil

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