JPH07236418A - Antioxidant smell correcting agent for docosahexaenoic acid and enicosapentaenoic acid - Google Patents

Antioxidant smell correcting agent for docosahexaenoic acid and enicosapentaenoic acid

Info

Publication number
JPH07236418A
JPH07236418A JP6053027A JP5302794A JPH07236418A JP H07236418 A JPH07236418 A JP H07236418A JP 6053027 A JP6053027 A JP 6053027A JP 5302794 A JP5302794 A JP 5302794A JP H07236418 A JPH07236418 A JP H07236418A
Authority
JP
Japan
Prior art keywords
acid
antioxidant
smell
docosahexaenoic acid
extracts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP6053027A
Other languages
Japanese (ja)
Inventor
Ikuo Katsumi
郁男 勝見
Taizo Kawabe
泰三 川辺
Yoshihiro Kawachi
義弘 河智
Sachiko Tanaka
幸子 田中
Ryozo Nakahara
良三 中原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanegafuchi Chemical Industry Co Ltd
Original Assignee
Kanegafuchi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanegafuchi Chemical Industry Co Ltd filed Critical Kanegafuchi Chemical Industry Co Ltd
Priority to JP6053027A priority Critical patent/JPH07236418A/en
Publication of JPH07236418A publication Critical patent/JPH07236418A/en
Withdrawn legal-status Critical Current

Links

Abstract

PURPOSE:To obtain the subject correcting agent containing at least two from among labiate, myrtaceous and lauraceous spices and their extracts, capable of deodorizing a fish-like smell by adding the agent to DHA, EPA or a fish oil containing DHA or EPA. CONSTITUTION:This agent contains at least two selected from the group consisting of labiate, myrtaceous and lauraceous spices (rosemary, clove, cinnamon, oregano, sage, etc.) and their extracts. The prepared smell correcting agent has anti-oxidizing properties and preventing effect on an oxidation smell.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、香辛料又はそれらの抽
出物を2種以上配合したドコサヘキサエン酸(DH
A)、エイコサペンタエン酸(EPA)、又はこれらを
含む魚油に対する抗酸化矯臭剤に関し、さらに詳しく
は、ドコサヘキサエン酸、エイコサペンタエン酸、又は
これらを含む魚油に添加することにより、抗酸化矯臭剤
に含まれる成分が相乗的に作用し、ドコサヘキサエン
酸、エイコサペンタエン酸、またはこれらを含む魚油の
酸化を防止し、酸化により生じる酸化臭、元来持ち合わ
せている魚臭等を矯臭(マスキング)する抗酸化矯臭剤
に関するものである。
TECHNICAL FIELD The present invention relates to docosahexaenoic acid (DH) containing two or more spices or their extracts.
A), eicosapentaenoic acid (EPA), or antioxidants for fish oils containing them, more specifically, docosahexaenoic acid, eicosapentaenoic acid, or by adding to fish oils containing them, it is included in the antioxidants. Antioxidative odors that act synergistically to prevent the oxidation of docosahexaenoic acid, eicosapentaenoic acid, or fish oil containing them, and to oxidize the odor caused by oxidation and the fish odor originally possessed. It is related to agents.

【0002】[0002]

【従来の技術】近年、健康志向が高まりドコサヘキサエ
ン酸、エイコサペンタエン酸も魚油由来の不飽和脂肪酸
として動脈硬化予防等種々の薬理作用が取り沙汰され注
目されているが、元来、不飽和脂肪酸は酸化され易く、
それによる品質劣化と共に酸化臭が問題となっている。
従来、この目的で使用されうる抗酸化剤としてトコフェ
ロール等が挙げられるが、その効果は充分とは云い難
い。また、ドコサヘキサエン酸、エイコサペンタエン酸
を多く含む魚油は元々持ち合わせている魚臭により、口
から摂取しにくい難点もある。この難点はカプセル化等
により軽減されつつあるが、摂取後に胃から臭いがたち
上ることもあり充分とは言えない。
2. Description of the Related Art Recently, docosahexaenoic acid and eicosapentaenoic acid, which have become increasingly health-conscious, have been attracting attention as various unsaturated fatty acids derived from fish oil for their various pharmacological effects such as arteriosclerosis prevention. Easy to be done,
Oxidative odor becomes a problem along with the deterioration of quality.
Conventionally, as an antioxidant that can be used for this purpose, tocopherol and the like can be mentioned, but the effect is not sufficient. In addition, fish oil containing a large amount of docosahexaenoic acid and eicosapentaenoic acid is difficult to take from the mouth due to the fish odor originally possessed. Although this difficulty is being alleviated by encapsulation and the like, it may not be said to be sufficient since the odor may rise from the stomach after ingestion.

【0003】[0003]

【発明が解決しようとする課題】本発明は上記の実情に
鑑み、ドコサヘキサエン酸、エイコサペンタエン酸、又
はこれらを含む魚油に添加することにより、抗酸化性、
酸化臭防止効果が驚異的に発揮され、魚臭が矯臭され
た、ドコサヘキサエン酸、エイコサペンタエン酸、又は
これらを含む魚油を得ることができる抗酸化矯臭剤を提
供するものである。
In view of the above-mentioned circumstances, the present invention provides antioxidants by adding docosahexaenoic acid, eicosapentaenoic acid, or fish oil containing these,
It is intended to provide an anti-oxidant flavoring agent capable of obtaining docosahexaenoic acid, eicosapentaenoic acid, or fish oil containing these, which has a surprisingly excellent effect of preventing oxidative odor and has a fishy odor.

【0004】[0004]

【課題を解決するための手段】本発明者らは、上記の課
題を解決するために鋭意研究の結果、特定の2種以上の
香辛料及び/又はその抽出物からなる配合物が上記目的
を達成し得ることを見出し、本発明を完成した。
Means for Solving the Problems As a result of intensive studies to solve the above-mentioned problems, the inventors of the present invention have achieved the above-mentioned object by using a combination of two or more specific spices and / or extracts thereof. The inventors have found that it can be done and have completed the present invention.

【0005】即ち、本発明の第1は、シソ科、フトモモ
科、クスノキ科の香辛料及びそれらの抽出物からなる群
より選択される少なくとも2種を配合してなることを特
徴とするドコサヘキサエン酸、エイコサペンタエン酸、
又はこれらを含む魚油用抗酸化矯臭剤を、本発明の第2
は、ローズマリー、クローブ、シナモン、オレガノ、セ
ージ及びそれらの抽出物からなる群より選択される少な
くとも2種を配合してなることを特徴とするドコサヘキ
サエン酸、エイコサペンタエン酸、又はこれらを含む魚
油用抗酸化矯臭剤を、本発明の第3は、クローブ、シナ
モン、オレガノ、セージ及びこれらの抽出物からなる群
より選択される少なくとも1種とローズマリーとを配合
してなることを特徴とするドコサヘキサエン酸、エイコ
サペンタエン酸、又はこれらを含む魚油用抗酸化矯臭剤
を、それぞれ内容とするものである。
That is, the first aspect of the present invention is that docosahexaenoic acid, characterized in that it contains at least two kinds selected from the group consisting of spices of Lamiaceae, Myrtaceae, Lauraceae and extracts thereof. Eicosapentaenoic acid,
Alternatively, an antioxidant for fish oil containing these may be used as the second aspect of the present invention.
Is docosahexaenoic acid, eicosapentaenoic acid, or a fish oil containing the same, which comprises at least two kinds selected from the group consisting of rosemary, cloves, cinnamon, oregano, sage, and extracts thereof. A third antioxidant of the present invention is docosahexaene, characterized in that at least one selected from the group consisting of clove, cinnamon, oregano, sage and extracts thereof is mixed with rosemary. Acids, eicosapentaenoic acid, or antioxidants for fish oils containing them, respectively.

【0006】本発明に用いられる香辛料又は抽出物とし
ては、シソ科、フトモモ科、クスノキ科の香辛料又はそ
れらの抽出物である。
The spices or extracts used in the present invention include spices of the Lamiaceae, Myrtaceae, Lauraceae or their extracts.

【0007】香辛料とは、広義に解釈して、地中海沿岸
を中心に産出する芳香を第一とするハーブ類と、熱帯及
び亜熱帯に産する香気と辛味の強いスパイス類との両者
を含むものである。これらの香辛料のもつ機能は、香気
と辛味の刺激による食用増進、成分の化学作用や香りに
よる魚や肉の不快臭に対する矯臭や芳香による匂い付
け、更には特有の色素による着色等が主なものである。
また、香辛料の中には防腐作用、生理薬理作用等を有す
るものもある。
[0007] Broadly speaking, spices include both herbs mainly having an aroma produced mainly in the Mediterranean coast and spices having a strong aroma and spice produced in tropical and subtropical regions. The main functions of these spices are to enhance food quality by stimulating aroma and spiciness, to smell the unpleasant odors of fish and meat due to the chemical action and aroma of the ingredients, to smell the aroma, and to color with a unique pigment. is there.
Further, some spices have antiseptic action, physiological pharmacological action and the like.

【0008】本発明に用いられる好ましい香辛料として
は、ローズマリー、クローブ、シナモン、オレガノ、セ
ージが挙げられ、これら又はこれらの抽出物を2種以上
併用することにより、これらの活性成分の相乗効果によ
り顕著な抗酸化矯臭効果を発現し、ドコサヘキサエン
酸、エイコサペンタエン酸、又はこれらを含む魚油の酸
化劣化を防止し酸化臭をおさえるとともに、元来保持し
ている魚臭等を矯臭し、ドコサヘキサエン酸、エイコサ
ペンタエン酸、又はこれらを含む魚油の鮮度保持力を増
大させ、酸化臭、魚臭が気にならない程度に改善するも
のである。
Preferred spices used in the present invention include rosemary, cloves, cinnamon, oregano and sage. By combining these or two or more kinds of these extracts, a synergistic effect of these active ingredients is obtained. Expressing a remarkable antioxidant and deodorizing effect, docosahexaenoic acid, eicosapentaenoic acid, or to prevent oxidative deterioration of fish oil containing these to suppress the oxidative odor, and to odorize the fish odor originally held, docosahexaenoic acid, Eicosapentaenoic acid, or fish oil containing them is increased in freshness-retaining power and is improved to such an extent that oxidative odor and fish odor are not noticeable.

【0009】上記香辛料及びその抽出物のうち、ローズ
マリーと、クローブ、シナモン、オレガノ、セージとの
組み合わせが特に良好な結果を与える。本発明の抗酸化
矯臭剤の添加量は、所望の抗酸化矯臭の程度により適宜
決定されるが、通常、ドコサヘキサエン酸、エイコサペ
ンタエン酸、又はこれらを含む魚油に対して10〜10
000ppm の範囲で良好な抗酸化矯臭効果が得られる。
Of the above spices and their extracts, the combination of rosemary with cloves, cinnamon, oregano and sage gives particularly good results. The addition amount of the antioxidant of the present invention is appropriately determined depending on the desired degree of antioxidant and odor, but is usually 10 to 10 relative to docosahexaenoic acid, eicosapentaenoic acid, or fish oil containing them.
A good antioxidant effect is obtained in the range of 000 ppm.

【0010】[0010]

【実施例】以下、本発明を実験例及び実施例に基づいて
更に詳細に説明するが、本発明はこれらにより何ら制限
を受けるものではない。
EXAMPLES The present invention will be described in more detail with reference to experimental examples and examples, but the present invention is not limited thereto.

【0011】実験例 ローズマリー(オレオレジン)、各種香辛料のエタノー
ル抽出物又は酸化防止剤15mgをエタノール0.5mlに
溶かし、そのうち50μlをシャーレ(直径6cm)に入
れ、これにドコサヘキサエン酸、及びエイコサペンタエ
ン酸を含む魚油(DHA26.6%、EPA6.4%含
有)1.5gを加えよく混合し、室温でエタノールを減
圧除去した。得られたものを室温で暗室保存し、毎日重
量を測定した。重量増加曲線から所定の方法によりτ値
を求めた。結果を表1に示す。
Experimental Example Rosemary (oleoresin), an ethanol extract of various spices or 15 mg of an antioxidant was dissolved in 0.5 ml of ethanol, 50 μl of which was placed in a petri dish (diameter 6 cm), and docosahexaenoic acid and eicosapentaene were added thereto. 1.5 g of fish oil containing acid (containing 26.6% of DHA and 6.4% of EPA) was added and mixed well, and ethanol was removed under reduced pressure at room temperature. The obtained product was stored at room temperature in the dark and weighed daily. The τ value was obtained from the weight increase curve by a predetermined method. The results are shown in Table 1.

【0012】尚、τ値とは、重量法による抗酸化テスト
の場合においては、図1に示すように、酸化が抑制され
ている間は緩やかな勾配で重量が増加し、抗酸化力が低
下すると急勾配で重量が上昇するが、この変曲点での日
数である。従って、τ値が大きい程抗酸化力が強いとい
える。
In the case of an antioxidant test by the gravimetric method, the τ value means that, as shown in FIG. 1, the weight increases with a gentle gradient while the oxidation is suppressed, and the antioxidant power decreases. Then, the weight increases steeply, but this is the number of days at this inflection point. Therefore, it can be said that the larger the τ value, the stronger the antioxidant power.

【0013】[0013]

【表1】 [Table 1]

【0014】表1の結果から、ローズマリー、セージ、
ガーリック等に強い抗酸化力がみられたが、酸化臭のみ
ならず魚臭を矯臭する本発明の目的には、ローズマリ
ー、セージ、クローブ、シナモン、オレガノが良好であ
る。
From the results in Table 1, rosemary, sage,
Garlic and the like showed a strong antioxidant power, but rosemary, sage, cloves, cinnamon, and oregano are preferable for the purpose of the present invention to smell not only the oxidative odor but also the fishy odor.

【0015】実施例 上記実験例と同様に、香辛料ローズマリー(オレオレジ
ン)又はこれと他の香辛料抽出物とを少量のエタノール
で溶かし、これにドコサヘキサエン酸、エイコサペンタ
エン酸を含む魚油を加え、これらについての臭に対する
官能試験を15人のパネラーで行い、下記の3段階で評
価した。結果を表2に示す。
Example In the same manner as in the above experimental example, spice rosemary (oleoresin) or another spice extract was dissolved in a small amount of ethanol, and fish oil containing docosahexaenoic acid and eicosapentaenoic acid was added to the solution. The sensory test for the odor was carried out by 15 panelists and evaluated according to the following 3 grades. The results are shown in Table 2.

【0016】 非常に良好なもの ◎(13人以上が良好と判断) 良好なもの ○(10人以上が良好と判断) やや良好なもの △(8人以上が良好と判断)Very good ◎ (13 or more people judged to be good) Good ○ (10 or more people judged to be good) Somewhat good △ (8 people or more judged to be good)

【0017】[0017]

【表2】 [Table 2]

【0018】表2の結果より、ローズマリーとセージ、
シナモン、クローブ、オレガノの組み合わせが良好な矯
臭効果を示すことがわかる。
From the results shown in Table 2, rosemary and sage,
It can be seen that the combination of cinnamon, cloves and oregano shows a good deodorizing effect.

【0019】[0019]

【発明の効果】以上のように、本発明の抗酸化矯臭剤
は、ドコサヘキサエン酸、エイコサペンタエン酸、又は
それらを含む魚油に添加することにより、ドコサヘキサ
エン酸、エイコサペンタエン酸、又はそれらを含む魚油
の抗酸化性を高め、酸化臭を防止するとともに、魚臭を
矯臭することができる。
As described above, the antioxidant of the present invention is added to docosahexaenoic acid, eicosapentaenoic acid, or fish oil containing them to obtain docosahexaenoic acid, eicosapentaenoic acid, or fish oil containing them. It is possible to enhance the antioxidant property, prevent the oxidative odor, and smell the fish odor.

【図面の簡単な説明】[Brief description of drawings]

【図1】τ値を説明するための図である。FIG. 1 is a diagram for explaining a τ value.

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 シソ科、フトモモ科、クスノキ科の香辛
料及びそれらの抽出物からなる群より選択される少なく
とも2種を配合してなることを特徴とするドコサヘキサ
エン酸、エイコサペンタエン酸、又はこれらを含む魚油
用抗酸化矯臭剤。
1. Docosahexaenoic acid, eicosapentaenoic acid, or a mixture thereof, comprising at least two kinds selected from the group consisting of spices of Lamiaceae, Myrtaceae, Lauraceae and extracts thereof. Antioxidant deodorant for fish oil containing.
【請求項2】 ローズマリー、クローブ、シナモン、オ
レガノ、セージ及びそれらの抽出物からなる群より選択
される少なくとも2種を配合してなることを特徴とする
ドコサヘキサエン酸、エイコサペンタエン酸、又はこれ
らを含む魚油用抗酸化矯臭剤。
2. Docosahexaenoic acid, eicosapentaenoic acid, or a mixture of at least two selected from the group consisting of rosemary, cloves, cinnamon, oregano, sage, and extracts thereof. Antioxidant deodorant for fish oil containing.
【請求項3】 クローブ、シナモン、オレガノ、セージ
及びこれらの抽出物からなる群より選択される少なくと
も1種とローズマリーとを配合してなることを特徴とす
るドコサヘキサエン酸、エイコサペンタエン酸、又はこ
れらを含む魚油用抗酸化矯臭剤。
3. Docosahexaenoic acid, eicosapentaenoic acid, or a mixture of at least one selected from the group consisting of clove, cinnamon, oregano, sage, and extracts thereof, and rosemary. Antioxidant deodorant for fish oil containing.
JP6053027A 1994-02-25 1994-02-25 Antioxidant smell correcting agent for docosahexaenoic acid and enicosapentaenoic acid Withdrawn JPH07236418A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6053027A JPH07236418A (en) 1994-02-25 1994-02-25 Antioxidant smell correcting agent for docosahexaenoic acid and enicosapentaenoic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6053027A JPH07236418A (en) 1994-02-25 1994-02-25 Antioxidant smell correcting agent for docosahexaenoic acid and enicosapentaenoic acid

Publications (1)

Publication Number Publication Date
JPH07236418A true JPH07236418A (en) 1995-09-12

Family

ID=12931416

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6053027A Withdrawn JPH07236418A (en) 1994-02-25 1994-02-25 Antioxidant smell correcting agent for docosahexaenoic acid and enicosapentaenoic acid

Country Status (1)

Country Link
JP (1) JPH07236418A (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002161042A (en) * 2000-11-27 2002-06-04 Soda Aromatic Co Ltd Antioxidant
JP2003113017A (en) * 2001-09-28 2003-04-18 Kentetsuku:Kk Deodorized fish oil-containing cosmetic
JP2008011715A (en) * 2006-07-03 2008-01-24 Sanki Shoji Kk Food compounded with processed seaweed, and method for producing the same
AU2003220417B2 (en) * 2002-03-28 2009-03-12 Alcon, Inc. Co-beadlet of DHA and rosemary and methods of use
JP2009284900A (en) * 2008-04-30 2009-12-10 Taisho Pharmaceutical Co Ltd Beverage
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JP2014237680A (en) * 2008-06-10 2014-12-18 ディーエスエム アイピー アセッツ ビー.ブイ. Plant extract and pufa combination
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US9572356B2 (en) 2012-03-30 2017-02-21 Kao Corporation Oil/fat composition
CN110974730A (en) * 2019-09-27 2020-04-10 中山大学新华学院 Antioxidant compound cinnamon essential oil and application
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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002161042A (en) * 2000-11-27 2002-06-04 Soda Aromatic Co Ltd Antioxidant
JP2003113017A (en) * 2001-09-28 2003-04-18 Kentetsuku:Kk Deodorized fish oil-containing cosmetic
AU2003220417B2 (en) * 2002-03-28 2009-03-12 Alcon, Inc. Co-beadlet of DHA and rosemary and methods of use
JP2008011715A (en) * 2006-07-03 2008-01-24 Sanki Shoji Kk Food compounded with processed seaweed, and method for producing the same
JP2009284900A (en) * 2008-04-30 2009-12-10 Taisho Pharmaceutical Co Ltd Beverage
JP2014237680A (en) * 2008-06-10 2014-12-18 ディーエスエム アイピー アセッツ ビー.ブイ. Plant extract and pufa combination
JP2014532773A (en) * 2011-11-01 2014-12-08 ディーエスエム アイピー アセッツ ビー.ブイ. Oils containing oxidatively stable polyunsaturated fatty acids
US9572356B2 (en) 2012-03-30 2017-02-21 Kao Corporation Oil/fat composition
JP2015002740A (en) * 2013-05-20 2015-01-08 花王株式会社 Fat composition
JP2015002735A (en) * 2013-05-20 2015-01-08 花王株式会社 Fat composition
CN105228460A (en) * 2013-05-20 2016-01-06 花王株式会社 Fat or oil composition
EP3000328A4 (en) * 2013-05-20 2016-12-07 Kao Corp Fat composition
WO2014189011A1 (en) * 2013-05-20 2014-11-27 花王株式会社 Fat composition
CN110974730A (en) * 2019-09-27 2020-04-10 中山大学新华学院 Antioxidant compound cinnamon essential oil and application
CN111772151A (en) * 2020-07-15 2020-10-16 福建省宁德市好顺水产养殖有限公司 Pickling material for weever and pickling method thereof
WO2022270560A1 (en) 2021-06-22 2022-12-29 不二製油グループ本社株式会社 Masking flavorant

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