JPH06122979A - Pretreatment of rein-coated steel tube - Google Patents

Pretreatment of rein-coated steel tube

Info

Publication number
JPH06122979A
JPH06122979A JP27162392A JP27162392A JPH06122979A JP H06122979 A JPH06122979 A JP H06122979A JP 27162392 A JP27162392 A JP 27162392A JP 27162392 A JP27162392 A JP 27162392A JP H06122979 A JPH06122979 A JP H06122979A
Authority
JP
Japan
Prior art keywords
steel pipe
resin
tube
water
coated steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP27162392A
Other languages
Japanese (ja)
Other versions
JP3244804B2 (en
Inventor
Tomio Wakamatsu
富夫 若松
Tatsufumi Kamigaki
達文 上垣
Isamu Yasuhara
勇 安原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP27162392A priority Critical patent/JP3244804B2/en
Publication of JPH06122979A publication Critical patent/JPH06122979A/en
Application granted granted Critical
Publication of JP3244804B2 publication Critical patent/JP3244804B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Chemical Treatment Of Metals (AREA)

Abstract

PURPOSE:To obtain a resin-coated steel tube excellent in secondary adhesion such as cathode peeling resistance by pretreating the tube. CONSTITUTION:When a raw steel tube 1 is coated with resin, the tube 1 is rotated in the circumferential direction and transferred in direction of an arrow F, the surface of the tube is blasted by the blasting equipment 2 and washed with water from a high-pressure water nozzle 3, then compressed air is injected from an air blow nozzle 5 to completely remove the contaminant such as dust generated in blasting, a chromating soln. is applied on the tube 1 surface by a chromate coating device 6, and a resin-coated steel tube excellent in secondary adhesion such as cathode peeling resistance is formed.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、樹脂被覆鋼管の前処理
方法に係り、特にポリエチレンなどのポリオレフィン被
覆鋼管および粉体エポキシ被覆鋼管の被覆に先立つ鋼管
の前処理方法に関するものであり、さらに詳しくはブラ
スト処理で発生した粉塵などのよごれを完全に除去し
て、品質特に耐陰極剥離性能などの2次密着性にすぐれ
た樹脂被覆鋼管を得る方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pretreatment method for a resin-coated steel pipe, and more particularly to a pretreatment method for a steel pipe prior to coating a polyolefin-coated steel pipe such as polyethylene and a powder epoxy coated steel pipe. Relates to a method for completely removing dust and the like generated by the blasting treatment to obtain a resin-coated steel pipe having excellent quality, particularly secondary adhesion such as cathode peeling resistance.

【0002】[0002]

【従来の技術】樹脂被覆、特にポリエチレンやポリプロ
ピレンなどを用いたポリオレフィン系被覆鋼管および粉
体エポキシ樹脂を用いた粉体エポキシ被覆鋼管は、天然
ガスや原油などの輸送用パイプラインに広く使用されて
いる。このようなパイプラインは、通常20年以上の耐久
性を要求されるため、樹脂被覆とともに電気防食が併用
される。
2. Description of the Related Art Resin coating, especially polyolefin-based coated steel pipe using polyethylene or polypropylene and powder epoxy coated steel pipe using powder epoxy resin are widely used in pipelines for transportation of natural gas and crude oil. There is. Since such a pipeline is usually required to have a durability of 20 years or more, the resin coating is used together with cathodic protection.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、上記の
ような樹脂被覆鋼管は、輸送,敷設時の損傷などにより
樹脂被覆層に鋼管素地にまで達する貫通孔が発生する場
合があり、上記電気防食を適用すると、貫通孔に流れる
電流によって環境中の水分が電気分解を起こして、発生
したアルカリなどによって接着が劣化していく現象、い
わゆる陰極剥離が発生するという問題がある。
However, in the resin-coated steel pipe as described above, a through hole reaching the steel pipe base material may be formed in the resin-coated layer due to damage during transportation or laying. When applied, there is a problem in that water in the environment is electrolyzed by the electric current flowing through the through-hole, and the adhesion is deteriorated by the generated alkali, so-called cathode peeling occurs.

【0004】このような耐陰極剥離性能などの2次密着
性を向上させる目的では、ブラスト処理後クロメート処
理を実施する方法が用いられている。ところがブラスト
処理を行うと、鋼管の外面にはブラスト粒から発生した
微細な粉塵などが付着する。粉塵などのよごれは密着性
を低下させるため、取り除くことが必要である。この粉
塵除去には従来、エアブローやナイロンブラシによるブ
ラッシングとか減圧吸引などの方法、あるいはこれらの
組合せによる方法が実施されているが、効果は小さく、
工業的設備ではブラスト処理によるショット粒の残存に
よりクロメート処理の特性を十分生かし切れていないの
が現状である。
For the purpose of improving the secondary adhesion such as the anti-cathode peeling performance, a method of performing chromate treatment after blast treatment is used. However, when the blast treatment is performed, fine dust generated from the blast particles adheres to the outer surface of the steel pipe. It is necessary to remove dust such as dust because it reduces the adhesion. To remove this dust, a method such as brushing with an air blow or a nylon brush, vacuum suction, or a combination thereof has been conventionally performed, but the effect is small,
At present, in industrial equipment, the characteristics of the chromate treatment cannot be fully utilized due to the shot particles remaining after the blast treatment.

【0005】また、ブラスト後の粉塵などのよごれを取
り除くためにリン酸系の化成処理液を用いる方法(たと
えば特開昭62−294183号公報など参照)が考えられる。
しかしこの方法では、確かに粉塵などのよごれは激減す
るが、化成処理液の回収設備や廃液処理設備などの設備
的な面でのデメリットが大きく実施が困難なのが現状で
ある。
Further, a method of using a phosphoric acid-based chemical conversion treatment liquid to remove dust such as dust after blasting (see, for example, JP-A-62-294183) is conceivable.
However, although this method certainly reduces dust and the like drastically, it is currently difficult to carry out because it has a large demerit in terms of facilities such as a chemical conversion treatment liquid recovery facility and a waste liquid treatment facility.

【0006】本発明は、上記したような従来技術の課題
を解決すべくしてなされたものであって、ブラスト処理
後の粉塵などのよごれを簡便にかつ完全に除去でき、ク
ロメート処理の性能を最大限に引き出し、耐陰極剥離性
能などの2次密着性にすぐれた樹脂被覆鋼管の形成を可
能にする前処理方法を提供することを目的とする。
The present invention has been made in order to solve the problems of the prior art as described above, and can easily and completely remove dust such as dust after blasting and maximize the performance of chromate treatment. It is an object of the present invention to provide a pretreatment method which allows the formation of a resin-coated steel pipe which is drawn out to the maximum extent and has excellent secondary adhesion such as cathode peeling resistance.

【0007】[0007]

【課題を解決するための手段】本発明は、素材鋼管に樹
脂被覆を施す際の前処理する方法であって、前記鋼管外
面をブラスト処理したあと、高圧水を吹き付けてよごれ
を除去し、さらに水分を除去してからクロメート処理を
施すことを特徴とする樹脂被覆鋼管の前処理方法であ
る。
The present invention is a method of pretreatment for applying a resin coating to a material steel pipe, which comprises blasting the outer surface of the steel pipe and then spraying high pressure water to remove dirt, and This is a pretreatment method for a resin-coated steel pipe, which comprises performing a chromate treatment after removing water.

【0008】[0008]

【作 用】本発明によれば、ブラスト処理後の粉塵など
のよごれ処理を高圧水の吹き付けによって実施するもの
であるから、エアブローなどの気体の吹き付けでは除去
困難なブラスト面のアンカーなどに食い込んだ粉塵をも
除去することができ、粉塵などのよごれの完全除去が可
能である。
[Operation] According to the present invention, since dust treatment such as dust after blasting is carried out by spraying high-pressure water, it bites into anchors or the like on the blast surface that are difficult to remove by spraying gas such as air blow. Dust can also be removed, and dust and other dirt can be completely removed.

【0009】ここで、本発明での高圧水の吹き付け圧力
は、水圧で5kgf/cm2 以上、より好ましくは10kgf/cm2
以上が望ましい。高圧水の圧力が5kgf/cm2 未満の場合
は、粉塵の除去が不十分で、その効果がほとんど得られ
ないのである。また、水量は1〜10l/m2が適当である。
水量が1l/m2以下では水が完全に鋼管表面を濡らすこと
ができないから十分な性能が得られず、10l/m2を超える
ものは実際上不要であるばかりか、設備コストや省スペ
ースの観点からも望ましくない。
Here, the high-pressure water spraying pressure in the present invention is 5 kgf / cm 2 or more, more preferably 10 kgf / cm 2 in terms of water pressure.
The above is desirable. When the pressure of the high-pressure water is less than 5 kgf / cm 2 , dust removal is insufficient and the effect is hardly obtained. Further, the water amount is suitably 1 to 10 l / m 2 .
If the amount of water is 1 l / m 2 or less, water cannot completely wet the surface of the steel pipe, so sufficient performance cannot be obtained, and if it exceeds 10 l / m 2 , not only is it practically unnecessary, but equipment cost and space saving It is not desirable from the viewpoint.

【0010】水洗後は、エアブローにより鋼管表面の水
を除去する必要がある。水洗の水は5分以内にエアブロ
ーにより除去する必要があり、エアブローまでの時間が
5分を超えるとブラスト面に発錆が生じ、むしろ性能が
低下する場合もある。また、エアブロー後は、10分以内
にクロメート処理などの化成処理を実施する必要があ
る。
After washing with water, it is necessary to remove water on the surface of the steel pipe by air blow. It is necessary to remove the water for washing by air blow within 5 minutes, and if the time until the air blow exceeds 5 minutes, rust may occur on the blast surface and the performance may be deteriorated. In addition, after air blowing, it is necessary to carry out chemical conversion treatment such as chromate treatment within 10 minutes.

【0011】クロメート処理液は、特に限定するもので
はないが、場合に応じてシリカ,リン酸,樹脂などのい
ずれか、あるいはその2つ以上のものを添加したものが
使用可能である。なお、クロメート処理液の付着量とし
ては、100 〜1000mgCr/m2 程度が好ましい。なお、通
常、水洗を行ったのみでは性能の向上は図れないといわ
れていた(たとえば前出の特開昭62−294183号公報など
参照)が、上記のようにクロメート処理を実施するこ
と、および水洗からエアブローまでの時間ならびにエア
ブローからクロメート塗布までの時間をコントロールす
ることにより、従来法に比して格段の2次密着性能を向
上させることができる。
The chromate treatment liquid is not particularly limited, but depending on the case, any one of silica, phosphoric acid, a resin, or a mixture of two or more thereof can be used. The amount of the chromate treatment liquid deposited is preferably about 100 to 1000 mgCr / m 2 . Incidentally, it has been generally said that the performance cannot be improved only by washing with water (see, for example, JP-A-62-294183 mentioned above), but it is necessary to carry out the chromate treatment as described above, and By controlling the time from water washing to air blow and the time from air blow to chromate coating, it is possible to significantly improve the secondary adhesion performance as compared with the conventional method.

【0012】[0012]

【実施例】以下に、本発明の実施例について図1を用い
て詳しく説明する。図1はTダイ法によるポリエチレン
被覆の場合の、本発明に係る前処理装置の実施例の構成
を示す概要図である。この図において、1は被処理材と
しての鋼管で、円周方向に回転しながら矢示F方向に移
送される。2はブラスト処理設備、3は水洗のための高
圧水ノズルであり、それぞれノズル孔が鋼管1の中心に
向けて配列される。4は水洗後の洗浄水を排水する排水
装置である。5は圧縮空気をを噴射するエアブローノズ
ルであり、そのノズル孔は鋼管1の中心に向けて配列さ
れる。なお、高圧水ノズル3とエアブローノズル5のそ
れぞれの幅Wは鋼管1が1回転する間に進む距離より大
きい値とする必要がある。6はクロメート処理液を鋼管
1の表面に塗布するクロメート塗布装置、7はエポキシ
プライマ塗布の前に鋼管1を予熱しポリエチレン被覆に
備える誘導加熱装置である。8は高圧水ノズル3の前後
に設けられる水飛散防止用しきり板である。
Embodiments of the present invention will be described in detail below with reference to FIG. FIG. 1 is a schematic diagram showing the configuration of an embodiment of a pretreatment apparatus according to the present invention in the case of polyethylene coating by the T-die method. In this figure, reference numeral 1 denotes a steel pipe as a material to be treated, which is transported in the direction of arrow F while rotating in the circumferential direction. 2 is a blast treatment facility, 3 is a high-pressure water nozzle for washing with water, and the nozzle holes are arranged toward the center of the steel pipe 1. Reference numeral 4 is a drainage device for draining the wash water after washing. Reference numeral 5 is an air blow nozzle for injecting compressed air, and its nozzle hole is arranged toward the center of the steel pipe 1. The width W of each of the high-pressure water nozzle 3 and the air blow nozzle 5 needs to be larger than the distance traveled during one rotation of the steel pipe 1. Reference numeral 6 is a chromate coating device that coats the surface of the steel pipe 1 with the chromate treatment liquid, and 7 is an induction heating device that preheats the steel pipe 1 and coats it with polyethylene before coating the epoxy primer. Reference numeral 8 is a water splash prevention partition plate provided before and after the high-pressure water nozzle 3.

【0013】なお、丸ダイ法などの小,中径管の場合
は、鋼管が円周方向に回転しないため、高圧水ノズル3
とエアブローノズル5ノズル孔の取付け位置は円周方向
に均等の間隔で配列する。その間隔は、鋼管全面を洗
浄,エアブローできる距離に設定すればよい。このよう
に構成された前処理装置を用いて、水洗後1分以内にエ
アブローした後5分以内にクロメート処理を実施して、
鋼管1の表面の前処理を行った後ポリエチレンを被覆し
た場合について、そのクロメート処理直前で調べた粉塵
付着率およびクロメート処理後の耐陰極剥離性能を図
2,図3にそれぞれ示した。ここで、高圧水は圧力;50
kgf/cm2 、水量;10 l/m2 とし、エアブローは圧力;10
kgf/cm2 とした。なお、比較のために、従来のエアブロ
ーのみによる場合を従来法1とし、ナイロンブラシによ
るワイピングによる場合を従来法2として、それぞれ併
せて示した。また、クロメート処理直前での粉塵付着率
は、鋼面にセロテープを張り付け、セロテープに付着し
た粉塵の付着面積率とし、耐陰極剥離試験はASTMG
8(印加電圧;−1.5 V(対基準電圧),試験温度;25
℃, 試験時間;60日間) に準じて行った。
In the case of small and medium diameter pipes such as the round die method, since the steel pipe does not rotate in the circumferential direction, the high pressure water nozzle 3
The air blow nozzle 5 and the nozzle holes are arranged at equal intervals in the circumferential direction. The interval may be set so that the entire surface of the steel pipe can be washed and blown with air. Using the pretreatment device configured as described above, the chromate treatment is performed within 5 minutes after air blowing within 1 minute after washing with water,
2 and 3 show the dust adhesion rate and the anti-cathode peeling performance after chromate treatment, which were examined immediately before the chromate treatment in the case where the surface of the steel pipe 1 was pretreated and coated with polyethylene. Where high pressure water is pressure; 50
kgf / cm 2 , water volume: 10 l / m 2 , air blow pressure: 10
It was set to kgf / cm 2 . For comparison, the case of using only the conventional air blow is shown as the conventional method 1, and the case of wiping with a nylon brush is shown as the conventional method 2. In addition, the dust adhesion rate immediately before chromate treatment is the adhesion area rate of the dust adhered to the cellophane tape when a cellophane tape is attached to the steel surface.
8 (applied voltage: -1.5 V (reference voltage), test temperature: 25
℃, test time; 60 days).

【0014】まず、図2において、本発明法の結果は従
来法1(エアブローのみ)および従来法2(ナイロンブ
ラシによるワイピングの場合)に比して粉塵除去が効果
的であることがわかる。また図3からは、本発明法の耐
陰極剥離特性は従来法1,2に比して飛躍的に向上して
いることがわかる。
First, in FIG. 2, the results of the method of the present invention show that dust removal is more effective than the conventional method 1 (only with air blowing) and the conventional method 2 (in the case of wiping with a nylon brush). Further, it can be seen from FIG. 3 that the cathode peeling resistance of the method of the present invention is dramatically improved as compared with the conventional methods 1 and 2.

【0015】[0015]

【発明の効果】以上説明したように本発明の前処理方法
によれば、水洗工程を付加してタイミングよく脱水する
ようにしたので、鋼管表面の粉塵を効果的に除去するこ
とができ、したがってクロメート処理の効果を十分に生
かすことができるから、耐陰極剥離性能などの2次密着
性をも大幅に向上し、高い防食性能を付与した被覆鋼管
が得られる。
As described above, according to the pretreatment method of the present invention, the washing process is added to dehydrate in a timely manner, so that the dust on the surface of the steel pipe can be effectively removed. Since the effect of the chromate treatment can be fully utilized, the secondary adhesion such as the anti-cathode peeling performance is also greatly improved, and the coated steel pipe having high anticorrosion performance can be obtained.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明に係る前処理装置の実施例の構成を示す
概要図である。
FIG. 1 is a schematic diagram showing a configuration of an embodiment of a pretreatment device according to the present invention.

【図2】クロメート処理直前で調べた粉塵付着率を示す
特性図である。
FIG. 2 is a characteristic diagram showing a dust adhesion rate examined immediately before chromate treatment.

【図3】クロメート処理後の耐陰極剥離性能を示す特性
図である。
FIG. 3 is a characteristic diagram showing cathode peel resistance after chromate treatment.

【符号の説明】[Explanation of symbols]

1 鋼管 2 ブラスト処理設備 3 高圧水ノズル 4 排水装置 5 エアブローノズル 6 クロメート塗布装置 7 誘導加熱装置 8 水飛散防止用しきり板 1 Steel Pipe 2 Blast Treatment Equipment 3 High Pressure Water Nozzle 4 Drainage Device 5 Air Blow Nozzle 6 Chromate Coating Device 7 Induction Heating Device 8 Water Scattering Prevention Plate

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 素材鋼管に樹脂被覆を施す際の前処理
する方法であって、前記鋼管外面をブラスト処理したあ
と、高圧水を吹き付けてよごれを除去し、さらに水分を
除去してからクロメート処理を施すことを特徴とする樹
脂被覆鋼管の前処理方法。
1. A method of pretreatment for applying a resin coating to a raw steel pipe, which comprises blasting the outer surface of the steel pipe, spraying high-pressure water to remove dirt, and further removing water, and then chromate treatment. A method for pretreating a resin-coated steel pipe, which comprises:
JP27162392A 1992-10-09 1992-10-09 Pretreatment method for resin-coated steel pipe Expired - Fee Related JP3244804B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP27162392A JP3244804B2 (en) 1992-10-09 1992-10-09 Pretreatment method for resin-coated steel pipe

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27162392A JP3244804B2 (en) 1992-10-09 1992-10-09 Pretreatment method for resin-coated steel pipe

Publications (2)

Publication Number Publication Date
JPH06122979A true JPH06122979A (en) 1994-05-06
JP3244804B2 JP3244804B2 (en) 2002-01-07

Family

ID=17502656

Family Applications (1)

Application Number Title Priority Date Filing Date
JP27162392A Expired - Fee Related JP3244804B2 (en) 1992-10-09 1992-10-09 Pretreatment method for resin-coated steel pipe

Country Status (1)

Country Link
JP (1) JP3244804B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017043090A (en) * 2015-08-24 2017-03-02 Jfeスチール株式会社 Polyethylene coated steel tube and manufacturing method therefor
JP2017043089A (en) * 2015-08-24 2017-03-02 Jfeスチール株式会社 Polyethylene coated steel tube and manufacturing method therefor
JP2018058350A (en) * 2016-09-28 2018-04-12 Jfeスチール株式会社 Polyethylene coated steel pipe and manufacturing method therefor
JP2018058349A (en) * 2016-09-28 2018-04-12 Jfeスチール株式会社 Polyethylene coated steel pipe and manufacturing method therefor
CN113848304A (en) * 2020-06-28 2021-12-28 中国石油天然气股份有限公司 Method for inspecting pipeline surface treatment quality

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017043090A (en) * 2015-08-24 2017-03-02 Jfeスチール株式会社 Polyethylene coated steel tube and manufacturing method therefor
JP2017043089A (en) * 2015-08-24 2017-03-02 Jfeスチール株式会社 Polyethylene coated steel tube and manufacturing method therefor
JP2018058350A (en) * 2016-09-28 2018-04-12 Jfeスチール株式会社 Polyethylene coated steel pipe and manufacturing method therefor
JP2018058349A (en) * 2016-09-28 2018-04-12 Jfeスチール株式会社 Polyethylene coated steel pipe and manufacturing method therefor
CN113848304A (en) * 2020-06-28 2021-12-28 中国石油天然气股份有限公司 Method for inspecting pipeline surface treatment quality
CN113848304B (en) * 2020-06-28 2024-04-30 中国石油天然气股份有限公司 Inspection method for pipeline surface treatment quality

Also Published As

Publication number Publication date
JP3244804B2 (en) 2002-01-07

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