JPH0586999B2 - - Google Patents
Info
- Publication number
- JPH0586999B2 JPH0586999B2 JP61044030A JP4403086A JPH0586999B2 JP H0586999 B2 JPH0586999 B2 JP H0586999B2 JP 61044030 A JP61044030 A JP 61044030A JP 4403086 A JP4403086 A JP 4403086A JP H0586999 B2 JPH0586999 B2 JP H0586999B2
- Authority
- JP
- Japan
- Prior art keywords
- alcohol
- cleaning
- present
- hydrocarbon oil
- type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- 229930195733 hydrocarbon Natural products 0.000 claims description 10
- 150000002430 hydrocarbons Chemical class 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 9
- 239000012459 cleaning agent Substances 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 3
- 239000003208 petroleum Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 238000004140 cleaning Methods 0.000 description 11
- 239000003960 organic solvent Substances 0.000 description 10
- 239000003921 oil Substances 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 206010008428 Chemical poisoning Diseases 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 238000009423 ventilation Methods 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000003502 gasoline Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 235000015096 spirit Nutrition 0.000 description 2
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Paints Or Removers (AREA)
Description
〔産業上の利用分野〕
本発明は新聞輪転印刷機等の印刷機械の圧胴用
洗浄剤に関するものである。
〔従来の技術〕
従来使用されている圧胴洗浄剤は、塩素系溶剤
（例えば、１，１，１−トリクロルエタン）およ
びフツソ系溶剤（例えば、トリクロロ−トリフル
オロエタン）と炭化水素油（例えば、工業用ガソ
リン、ケロシン、ミネラルスピリツト）との混合
溶剤である。
〔発明が解決しようとする問題点〕
塩素系溶剤は、洗浄効果は大であるが、有機溶
剤中毒予防規則の第２種有機溶剤に該当するた
め、最高使用量が60ｇ／時間に制限され、これ以
上使用するときは局所排気装置を設置する必要が
ある。
フツソ系溶剤は、有機溶剤中毒予防規則に非該
当であるが、洗浄性が劣るため、使用量を多くす
る必要があり、コストアツプになる。
なお、上記の有機溶剤中毒予防規則は労働安全
衛生法によるもので、有害性の程度により第１種
から第３種に区分されている。すなわち、第１種
（クロロホルム他６種）＞第２種（アセトン他39
種）＞第３種（ガソリン他６種）の順である。そ
して、気積が150m3の場合、１時間当りの使用量
が、第１種で12.5ｇｒ、第２種で60ｇｒ、第３種
で225ｇｒを越えると、局所排気装置、全体換気
装置等の設備が義務づけられている。
本発明は、印刷中に圧胴表面に発生するインキ
汚れおよび紙粉汚れに対する洗浄効果が高く、作
業性が改善され、低コストの洗浄剤を提案するも
のである。
〔問題点を解決するための手段〕
本発明は、上記問題点を、炭化水素油（第３種
有機溶剤）にアルコール（第２種有機溶剤）を混
合させることにより、解決するものである。
すなわち本発明は、炭化水素油として炭素数８
〜12で沸点範囲100〜200℃の石油系溶剤を用い、
これに炭素数３〜６のアルコールを混合してなる
印刷機械洗浄剤に関する。
本発明において、上記アルコールの混合量は上
記炭化水素油に対し5vo％未満とすることを好
ましい実施態様とする。
本発明における炭化水素油としては、炭素数が
８〜12で、沸点範囲が100〜200℃の石油系溶剤、
例えばミネラルターペン、ミネラルスピリツト、
ソルベントナフサ、工業用ガソリン等が用いられ
る。
また、本発明におけるアルコールとしては、炭
素数が３〜６の、例えばｉ−プロピルアルコー
ル、ｎ−ブチルアルコール、ｎ−ヘキシルアルコ
ール、シクロヘキシルアルコール等が用いられ
る。
本発明において、アルコールの混合量を炭化水
素油に対し5vo％未満とするのを好ましい実施
態様とするのは、インキ溶解性の点では10vo
％程度が望ましいが、前述の有機溶剤中毒予防規
則によりアルコールが5vo％を越えて含むもの
は第２種有機溶剤となり、局所排気装置等の設備
義務基準が厳格となるばかりでなく、コストアツ
プをも招くことがあるからである。
〔作用〕〔発明の効果〕
本発明において、炭化水素油にアルコールを混
合させることで、洗浄効果を高めると共に、炭化
水素油単独の場合に比し、溶解範囲（すなわち洗
浄範囲）を広くでき、かつ強力な溶解（すなわち
洗浄）を達成しうる。
また、本発明において、アルコールの量を炭化
水素油に対し5vo％未満混合させる場合、この
混合溶剤は第２種有機溶剤に該当し、使用量が気
積150m3で225ｇｒ／１時間以内であれば、局所排
気装置の設備は不要となる。
〔実施例〕
本発明洗浄剤は、例えば新聞輪転印刷機械にお
いて、運転中に圧胴表面に付着するインキおよび
紙粉汚れを洗浄除去するために、自動洗浄装置の
スプレイノズルより圧胴表面に噴射されインキお
よび紙粉汚れを溶解、分散させて、印刷用紙でふ
きとり除去される。
尚、洗浄操作は間欠的（通常15〜20分）に行う
ことが通例であり、その間の印刷物は溶剤、汚れ
が付着しているため、損紙として処分される。
洗浄力テスト
ガラス板上に一定量の墨インキを塗布して、
50°の傾きをもたせ、上部より一定量の洗浄液を
一定時間流下洗浄し、洗浄前後のガラス板上のイ
ンキ量を測定比較した。
結果は表１に示す通りであつた。
[Industrial Application Field] The present invention relates to a cleaning agent for impression cylinders of printing machines such as newspaper rotary presses. [Prior Art] Conventionally used impression cylinder cleaners include chlorinated solvents (e.g. 1,1,1-trichloroethane) and fluorinated solvents (e.g. trichloro-trifluoroethane) and hydrocarbon oils (e.g. , industrial gasoline, kerosene, mineral spirits). [Problems to be solved by the invention] Although chlorinated solvents have a great cleaning effect, they fall under the class 2 organic solvents of the Organic Solvent Poisoning Prevention Regulations, so the maximum usage amount is limited to 60g/hour. When using more than this, it is necessary to install a local exhaust system. Fluorine-based solvents do not fall under the Organic Solvent Poisoning Prevention Ordinance, but their cleaning properties are poor, so it is necessary to use a large amount, which increases costs. The above-mentioned organic solvent poisoning prevention regulations are based on the Industrial Safety and Health Act, and are classified into Types 1 to 3 depending on the degree of toxicity. In other words, type 1 (chloroform and 6 other types) > type 2 (acetone and 39 other types)
Type) > Type 3 (gasoline and 6 other types). If the air volume is 150m3 , and the usage amount per hour exceeds 12.5gr for Type 1, 60gr for Type 2, and 225gr for Type 3, equipment such as local exhaust ventilation system, general ventilation system, etc. is required. The present invention proposes a cleaning agent that is highly effective in cleaning ink stains and paper dust stains generated on the impression cylinder surface during printing, improves workability, and is low cost. [Means for Solving the Problems] The present invention solves the above problems by mixing alcohol (second type organic solvent) with hydrocarbon oil (third type organic solvent). That is, in the present invention, the hydrocarbon oil has 8 carbon atoms.
Using a petroleum solvent with a boiling point range of 100-200℃ at ~12℃,
This invention relates to a printing machine cleaning agent prepared by mixing this with an alcohol having 3 to 6 carbon atoms. In the present invention, it is a preferred embodiment that the mixing amount of the alcohol is less than 5 vol% with respect to the hydrocarbon oil. The hydrocarbon oil in the present invention includes petroleum solvents having 8 to 12 carbon atoms and a boiling point range of 100 to 200°C;
For example, mineral turpentine, mineral spirits,
Solvent naphtha, industrial gasoline, etc. are used. Further, as the alcohol in the present invention, those having 3 to 6 carbon atoms, such as i-propyl alcohol, n-butyl alcohol, n-hexyl alcohol, and cyclohexyl alcohol, are used. In the present invention, it is preferable that the amount of alcohol mixed with the hydrocarbon oil be less than 5 vol%, in terms of ink solubility.
%, but according to the organic solvent poisoning prevention regulations mentioned above, those containing more than 5 vol% of alcohol are class 2 organic solvents, which not only imposes strict standards for equipment such as local exhaust ventilation, but also increases costs. This is because you may be invited. [Function] [Effects of the Invention] In the present invention, by mixing alcohol with hydrocarbon oil, the cleaning effect can be enhanced and the dissolution range (i.e., cleaning range) can be widened compared to the case of using only hydrocarbon oil. and strong dissolution (ie, washing) can be achieved. In addition, in the present invention, when the amount of alcohol is mixed with hydrocarbon oil at less than 5 vol%, this mixed solvent falls under the class 2 organic solvent, and even if the amount used is within 225 gr/hour in a volume of 150 m3 . For example, local exhaust ventilation equipment is not required. [Example] The cleaning agent of the present invention is sprayed onto the impression cylinder surface from a spray nozzle of an automatic cleaning device in order to wash and remove ink and paper dust stains that adhere to the impression cylinder surface during operation, for example in a newspaper rotary printing machine. The ink and paper dust stains are dissolved and dispersed, and then wiped off with printing paper. Note that the cleaning operation is usually performed intermittently (usually for 15 to 20 minutes), and the printed matter during that time is disposed of as waste paper because it has solvent and dirt attached to it. Cleaning power test: Apply a certain amount of black ink on a glass plate,
The glass plate was tilted at 50°, and a certain amount of cleaning liquid was flowed down from the top for a certain period of time, and the amount of ink on the glass plate before and after cleaning was measured and compared. The results were as shown in Table 1.
【表】
上表および第１〜４図から明らかなように、本
発明洗浄剤は、従来の第２種有機溶剤に該当する
洗浄剤と同等以上の洗浄効果を得ることができ
る。[Table] As is clear from the above table and FIGS. 1 to 4, the cleaning agent of the present invention can obtain a cleaning effect equal to or higher than that of the conventional cleaning agent corresponding to the second type organic solvent.
第１〜４図は、本発明の洗浄力テストにより得
られた結果を示す図である。
1 to 4 are diagrams showing the results obtained from the detergency test of the present invention.
Claims (1)
100〜200℃の石油系溶剤を用い、これに炭素数３
〜６のアルコールを混合してなる印刷機械洗浄
剤。1 Hydrocarbon oil with 8 to 12 carbon atoms and boiling point range
Using a petroleum solvent at 100 to 200℃, and adding carbon number 3 to this
A printing machine cleaning agent made by mixing ~6 alcohols.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4403086A JPS62202000A (en) | 1986-03-03 | 1986-03-03 | Detergent for printing press |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4403086A JPS62202000A (en) | 1986-03-03 | 1986-03-03 | Detergent for printing press |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62202000A JPS62202000A (en) | 1987-09-05 |
| JPH0586999B2 true JPH0586999B2 (en) | 1993-12-15 |
Family
ID=12680241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4403086A Granted JPS62202000A (en) | 1986-03-03 | 1986-03-03 | Detergent for printing press |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62202000A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0326798A (en) * | 1989-06-23 | 1991-02-05 | Takashi Nakamura | Cleaning agent for plastic |
| JP2700922B2 (en) * | 1989-07-05 | 1998-01-21 | 株式会社スリーボンド | Cleaning agent for brake equipment |
| CA2097017C (en) * | 1992-09-24 | 2004-03-16 | William M. Rinehart | Non-chlorinated cleaner-drier |
-
1986
- 1986-03-03 JP JP4403086A patent/JPS62202000A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62202000A (en) | 1987-09-05 |
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