JPH0585429B2 - - Google Patents

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Publication number
JPH0585429B2
JPH0585429B2 JP2214996A JP21499690A JPH0585429B2 JP H0585429 B2 JPH0585429 B2 JP H0585429B2 JP 2214996 A JP2214996 A JP 2214996A JP 21499690 A JP21499690 A JP 21499690A JP H0585429 B2 JPH0585429 B2 JP H0585429B2
Authority
JP
Japan
Prior art keywords
paper
vaporizable
packaging material
drug
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2214996A
Other languages
Japanese (ja)
Other versions
JPH03133759A (en
Inventor
Hachiro Saito
Motohide Okamoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Nippon Petrochemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Petrochemicals Co Ltd filed Critical Nippon Petrochemicals Co Ltd
Priority to JP21499690A priority Critical patent/JPH03133759A/en
Publication of JPH03133759A publication Critical patent/JPH03133759A/en
Publication of JPH0585429B2 publication Critical patent/JPH0585429B2/ja
Granted legal-status Critical Current

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  • Packages (AREA)
  • Packaging Of Annular Or Rod-Shaped Articles, Wearing Apparel, Cassettes, Or The Like (AREA)
  • Wrappers (AREA)

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、紙の上に防錆剤、防かび剤、賦香
剤などの粉粒状の気化性薬剤を散布または配列し
た後、気化性薬剤に対してバリヤー性の合成樹脂
の押出コーテイングによつて該薬剤を埋設、固定
することを特徴とする、合成樹脂、気化性薬剤お
よび紙を一体化した優れた薬効を有する包装材を
製造する方法に関する。
[Detailed Description of the Invention] [Field of Industrial Application] This invention is a method of spraying or arranging a powdery vaporizable agent such as a rust preventive agent, a fungicide, or a flavoring agent on paper. To manufacture a packaging material having excellent medicinal efficacy, which integrates a synthetic resin, a vaporizable drug, and paper, and which is characterized by embedding and fixing the drug by extrusion coating of a synthetic resin having barrier properties against the drug. Regarding the method.

〔従来の技術〕[Conventional technology]

従来、防錆剤、防かび剤、賦香剤などの粉粒状
の気化性薬剤の使用によつて防錆効果、防かび効
果、賦香効果などの付与された包装材は数多く知
られている。例えば、 (1) 紙やフイルムに上記粉粒状の気化性薬剤類の
溶液を含浸または塗布したもの (2) 上記粉粒状の気化性薬剤類を熱可塑性合成樹
脂に配合混練し、フイルムとしたもの (3) ラミネート紙と合成樹脂フイルムとの間に上
記粉粒状の気化性薬剤層を介在させて圧着一体
化して積層シートとしたもの などがある。
Many packaging materials have been known that have anti-corrosion, anti-mold, and fragrance effects through the use of powdery, volatile chemicals such as anti-corrosion agents, anti-fungal agents, and fragrance agents. . For example, (1) paper or film impregnated with or coated with a solution of the above-mentioned powdery vaporizable drugs; (2) film made by mixing and kneading the above-mentioned powdery vaporizable drugs with a thermoplastic synthetic resin. (3) There is a laminated sheet made by interposing the powdery vaporizable drug layer between laminated paper and a synthetic resin film and press-bonding them together.

しかしながら、(1)においては、一般に粉粒状気
化性薬剤の溶液を含浸または塗布した紙は表裏両
面からの薬剤の気化逸散が急速に起きるので、使
用に際してはこの紙の上からクラフト紙やポリエ
チレンフイルムでさらに包装する必要が生じ、包
装費がかさむばかりでなく、作業能率も低下す
る。また、フイルム成形後に粉粒状の気化性薬剤
の溶液を塗布または含浸する方法は工程が複雑に
なるほか、溶媒除去のための付属設備が必要にな
り経済的に不利である。(2)のフイルムにおいて
は、両面に気化性薬剤がしみ出して薬剤のロスが
多くなり、包装材として必要なフイルム内面の薬
効が半減するなどの欠点がある。(3)の積層シート
は、上記(1)および(2)と比較してはるかに効率のよ
い包装材であるが、あらかじめラミネートした加
工紙を圧着して積層シートとするので高価になる
ばかりでなく、紙の通気性がラミネート層で妨げ
られるために気化性薬剤の気化性が悪くなる。
However, in (1), paper impregnated with or coated with a solution of a powdery vaporizable drug generally vaporizes quickly from both the front and back sides, so when using the paper, kraft paper or polyethylene It becomes necessary to wrap the product in additional film, which not only increases packaging costs but also reduces work efficiency. In addition, the method of applying or impregnating a solution of a powdery vaporizable chemical after film forming requires complicated steps and requires additional equipment for removing the solvent, which is economically disadvantageous. The film (2) has drawbacks such as the vaporizable drug seeping out on both sides, resulting in a large amount of drug loss, and the drug efficacy on the inner surface of the film, which is necessary as a packaging material, being halved. The laminated sheet (3) is a much more efficient packaging material than the above (1) and (2), but it is expensive because it is made by pressing pre-laminated processed paper. However, since the air permeability of the paper is impeded by the laminate layer, the vaporization of vaporizable chemicals becomes poor.

(4) 実開昭53−32877号公報には、熱可塑性樹脂
発泡シートと樹脂フイルムとの間に、気化性防
錆剤の粉末が介在して密着積層されたことより
なる金属防錆用積層シートが開示されている。
この考案は、熱可塑性樹脂発泡シートと樹脂フ
イルムの2層間に気化性防錆剤を介在させ、こ
れらの熱可塑性樹脂発泡シートと樹脂フイルム
とを熱融着するか、あるいは接着剤によつて密
着積層するものであつて、本質的に熱融着を行
うための2次加工を必要とするか、あるいは2
層のシートおよびフイルムを接着させるための
接着材層を必要とするものである。
(4) Japanese Utility Model Application Publication No. 53-32877 discloses a laminated metal rust-preventing layer consisting of a thermoplastic resin foam sheet and a resin film that are closely laminated with powder of a volatile rust preventive agent interposed between them. sheet is disclosed.
This idea involves interposing a volatile rust preventive agent between the two layers of a thermoplastic resin foam sheet and a resin film, and then bonding the thermoplastic resin foam sheet and the resin film by heat-sealing or using an adhesive. It is laminated and essentially requires secondary processing to perform heat fusion, or
It requires an adhesive layer to adhere the sheets and films of the layers.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

この発明の目的は上記の問題点を解決した薬効
の優れた包装材の製造方法を提供することであ
る。
An object of the present invention is to provide a method for producing a packaging material with excellent medicinal efficacy that solves the above-mentioned problems.

〔課題を解決するための手段〕[Means to solve the problem]

この発明は紙の上に粉粒状の気化性薬剤を所望
シール部を残して散布または配列した後、気化性
薬剤に対してバリヤー性の合成樹脂の押出しコー
テイングによつて該薬剤を埋設、固定し、合成樹
脂、気化性薬剤および紙を一体化したことを特徴
とする包装材の製造方法である。
This invention involves scattering or arranging a powdery vaporizable drug on paper leaving a desired seal area, and then embedding and fixing the drug by extrusion coating with a synthetic resin that has barrier properties against the vaporizable drug. , a method for producing a packaging material characterized by integrating a synthetic resin, a vaporizable drug, and paper.

〔実施例〕〔Example〕

この発明で使用される紙は、天然繊維を原料と
したクラフト紙のような洋紙、和紙などの一般的
なものであるが、合成繊維を原料とする不織布で
もよい。
The paper used in this invention is general paper such as Western paper such as kraft paper made from natural fibers, Japanese paper, etc., but it may also be a nonwoven fabric made from synthetic fibers.

この発明に使用される気化性薬剤としては、パ
ラジクロールベンゾール、ナフタリンなどの防虫
剤や防かび剤、防錆剤、賦香剤などやこれらの溶
液をシリカゲル粉粒体などに担持させたものなど
が挙げられる。なかでも、α−ブロム・シンナミ
ツク・アルデヒド(BCA)のような気化性防か
び剤、ジシクロヘキシル・アンモニウム・ナイト
ライト(DICHAN)のような気化性防錆剤、賦
香剤などの気化性薬剤が特に好ましい。
Volatile agents used in this invention include insect repellents such as paradichlorobenzole and naphthalene, fungicides, rust preventives, flavoring agents, and solutions of these agents supported on silica gel particles. can be mentioned. Among them, volatile fungicides such as α-bromo cinnamic aldehyde (BCA), volatile rust inhibitors such as dicyclohexyl ammonium nitrite (DICHAN), and volatile agents such as fragrances are particularly important. preferable.

この発明に使用される合成樹脂にはポリエチレ
ン、ポリプロピレン、ポリブテン−1、エチレン
−酢酸ビニル共重合体、エチレン−アルキルアク
リレート共重合体、イオノマー樹脂などのポリオ
レフイン系樹脂、ポリアミド系樹脂、ポリスチレ
ン系樹脂、ポリ塩化ビニル系樹脂、ポリビニルア
ルコール系樹脂、ポリエステル系樹脂などの熱可
塑性樹脂であれば特に限定はないが、使用する気
化性薬剤の種類に応じて、それに対するバリヤー
性の観点から適当な樹脂を選ぶ必要がある。
Synthetic resins used in this invention include polyolefin resins such as polyethylene, polypropylene, polybutene-1, ethylene-vinyl acetate copolymers, ethylene-alkyl acrylate copolymers, ionomer resins, polyamide resins, polystyrene resins, There is no particular limitation as long as it is a thermoplastic resin such as polyvinyl chloride resin, polyvinyl alcohol resin, polyester resin, etc., but depending on the type of vaporizing agent to be used, an appropriate resin may be selected from the viewpoint of barrier properties against it. You need to choose.

例えば防かび剤のα−ブロム・シンナミツク・
アルデヒド(BCA)においてはナイロン、防錆
剤のジシクロヘキシル・アンモニウム・ナイトラ
イト(DICHAN)においてはポリエチレンとい
うように、気化性薬剤の種類によつて適宜選択さ
れる。
For example, the fungicide α-brome, cinnamon,
The material is appropriately selected depending on the type of vaporizing agent, such as nylon for aldehyde (BCA) and polyethylene for dicyclohexyl ammonium nitrite (DICHAN), a rust inhibitor.

以下、添付の図面に基づいてこの発明を説明す
る。
The present invention will be explained below based on the accompanying drawings.

第1図はこの発明の包装材の製造方法の工程図
の一例を示すものである。紙1を所望の速度で送
行させてベルトコンベヤ4上に導入し、ホツパー
より気化性薬剤2の所要量を紙1上に投下する。
気化性薬剤2は例えばホツパーに所要間隔の多数
の出口を並列に設けることにより、紙1上に帯状
に散布され、さらにホツパーからの投下を断続す
ることによりコンベヤの進行方向にも間隔をとり
ながら散布される。また幅広に散布された気化性
薬剤を櫛歯5で帯状に配列することもできる。こ
のような気化性薬剤の散布または配列により所望
のシール部9を帯状または格子状に形成させる。
次いで押出機から排出される溶融樹脂3をガイド
ロール6に導入してラミネートし、ピンチロール
7で圧着しながら気化性薬剤2を埋設、固定する
と同時に、紙1と溶融樹脂3とをシール部9で接
着し、合成樹脂、気化性薬剤および紙が一体化さ
れた包装材8を得る。
FIG. 1 shows an example of a process diagram of the method for producing a packaging material of the present invention. Paper 1 is fed at a desired speed and introduced onto a belt conveyor 4, and a required amount of vaporizable chemical 2 is dropped onto the paper 1 from a hopper.
For example, by providing a hopper with a large number of outlets spaced apart in parallel, the vaporizable chemical 2 is dispersed onto the paper 1 in a strip shape, and by intermittent dropping from the hopper, the vaporizable chemical 2 is dispersed at intervals in the direction in which the conveyor travels. be scattered. Further, the vaporizable chemicals spread widely can also be arranged in a band shape using the comb teeth 5. By dispersing or arranging the vaporizable chemicals in this manner, the desired seal portion 9 is formed in a band-like or lattice-like form.
Next, the molten resin 3 discharged from the extruder is introduced into the guide roll 6 and laminated, and the vaporizable agent 2 is buried and fixed while being pressed with the pinch roll 7. At the same time, the paper 1 and the molten resin 3 are bonded to the sealing part 9. A packaging material 8 in which a synthetic resin, a vaporizable drug, and paper are integrated is obtained.

このような方法で得られる包装材は、紙の上に
所望シール部を残して粉粒状の気化性薬剤を散布
または配列した後、気化性薬剤に対してバリヤー
性の合成樹脂の押出コーテイングによつて、直接
気化性薬剤を埋設、固定し、紙、気化性薬剤およ
び合成樹脂を一体化した包装材で、接着剤を必要
とせず本質的には紙と合成樹脂層の2層からなる
もので、連続的に製造ができ、非常に簡素化され
た構成となつているものである。
The packaging material obtained by this method is made by sprinkling or arranging powdery vaporizable drugs on paper, leaving a desired seal area, and then applying an extrusion coating with a synthetic resin that has barrier properties against vaporizable drugs. It is a packaging material that directly embeds and fixes vaporizable drugs, and integrates paper, vaporizable drugs, and synthetic resin.It does not require adhesive and is essentially made of two layers: paper and synthetic resin. , which can be manufactured continuously and has a very simple structure.

実施例 1 坪量78g/m2のクラフト紙上に、25mm毎に幅5
mmのシール部を縦、横に格子状に設けて、シール
部以外の部分にジシクロヘキシル・アンモニウ
ム・ナイトライト(DICHAN)粉末を1m2当り
0.5g散布したのち、低密度ポリエチレン(1dPE)
を300℃で膜状に押出し、25μ厚のラミネートを
し、包装材を得た。
Example 1 On kraft paper with a basis weight of 78 g/m 2 , a width of 5
mm seals are provided in a grid pattern vertically and horizontally, and dicyclohexyl ammonium nitrite (DICHAN) powder is applied to the areas other than the seals per 1 m2 .
After spraying 0.5g, low density polyethylene (1dPE)
was extruded into a film at 300°C and laminated to a thickness of 25μ to obtain a packaging material.

散布されたDICHANの粉末は1dPE層中に埋設
して固定されていると同時に、シール部において
クラフト紙と1dPE層とが接着しているため、包
装材は完全に一体化していた。
The sprinkled DICHAN powder was embedded and fixed in the 1dPE layer, and at the same time, the kraft paper and the 1dPE layer were bonded to each other at the sealing part, so the packaging material was completely integrated.

得られた包装材でクラフト紙側を内側にて鉄板
を包装し、室内に1年間放置した後、開封したと
ころ、鉄板表面に錆は認められず、また包装材中
のDICHAN粉末は若干残存していた。
The iron plate was wrapped in the obtained packaging material with the kraft paper side inside, and when the package was opened after being left indoors for one year, no rust was observed on the surface of the iron plate, and some DICHAN powder remained in the packaging material. was.

同時に行つたクラフト紙側を外側にして包装し
た試験では錆の発生は著しく、またDICHAN粉
末は殆ど残つていなかつた。
In a test conducted at the same time in which the product was packaged with the kraft paper side outside, there was significant rust and almost no DICHAN powder remained.

実施例 2 実施例1におけるDICHANの代りにα−ブロ
ム・シンナミツク・アルデヒド(BCA)粉末を
1m2当り0.3g散布し、1dPEの代りに66ナイロン
樹脂(PA)を350℃で押出し20μ厚のラミネート
をした以外は実施例1と同様にして、包装材を得
た。
Example 2 Instead of DICHAN in Example 1, α-brome cinnamic aldehyde (BCA) powder was sprinkled at 0.3g per 1 m2, and instead of 1dPE, 66 nylon resin (PA) was extruded at 350°C to form a 20μ thick laminate. A packaging material was obtained in the same manner as in Example 1 except that.

散布されたBCAの粉末はPA層中に埋設して固
定されていると同時に、シール部においてクラフ
ト紙とPA層とが接着しているため、包装材は完
全に一体化していた。
The dispersed BCA powder was embedded and fixed in the PA layer, and at the same time, the kraft paper and PA layer were bonded to each other at the sealing part, so the packaging material was completely integrated.

得られた包装材でクラフト紙を内側にして食パ
ンを包装し、室内に1週間放置した後、開封した
ところ、かびの発生は皆無であり、また包装材中
のBCA粉末が若干残存していた。
Bread was wrapped in the resulting packaging material with kraft paper on the inside, and when the package was opened after being left indoors for a week, there was no mold growth, and some BCA powder in the packaging material remained. .

同時に行つたクラフト紙を外側にして包装した
試験ではかびの発生は著しく、またBCA粉末は
殆ど残つていなかつた。
In a test conducted at the same time in which the product was packaged with kraft paper on the outside, there was significant mold growth, and almost no BCA powder remained.

〔発明の効果〕〔Effect of the invention〕

以上詳細に説明したように、この発明の方法
は、従来の製造プロセスよりも簡素で経剤的な、
連続的な包装材の製造方法である。
As explained in detail above, the method of the present invention is simpler and more convenient than conventional manufacturing processes.
This is a continuous packaging material manufacturing method.

この発明の方法で得られる包装材は、合成樹脂
フイルムより格段に気化性薬剤の透過性のよい、
通気性の紙を使用し、紙と薬剤とを直接接触させ
て、気化性薬剤に対してバリヤー性の合成樹脂で
紙に固定化した構成となつているので、この紙を
通して、気化性薬剤効果が著しく、かつその効果
は速効性を有している。さらに気化性薬剤の粉粒
体が樹脂で埋設、固定化されると同時にシール部
を通して樹脂と紙とが強固に接着されるので気化
性薬剤が摩擦振動などの外力によつて剥離脱落す
ることもない。
The packaging material obtained by the method of this invention has much better permeability to vaporizable drugs than synthetic resin film.
Using breathable paper, the paper and drug are brought into direct contact, and the drug is fixed to the paper using a synthetic resin that has barrier properties against vaporizable drugs. is remarkable, and its effect is fast-acting. Furthermore, as the powder and granules of the vaporizable drug are embedded and fixed in the resin, the resin and paper are firmly bonded through the sealing part, so the vaporizable drug is not likely to peel off or fall off due to external forces such as frictional vibrations. do not have.

この包装材は、気化性薬剤の透過性を有する紙
層を内側にして、被包装物を包装する。これによ
つて、外層のバリヤー性合成樹脂で気化性薬剤の
蒸気の逸散が防止でき、効率のよい薬剤効果を発
揮することができる。
This packaging material wraps an object with a paper layer that is permeable to vaporizable drugs on the inside. As a result, the barrier synthetic resin of the outer layer can prevent the vapor of the volatile drug from escaping, and an efficient drug effect can be achieved.

【図面の簡単な説明】[Brief explanation of drawings]

第1図はこの発明の包装材の製造方法の工程図
の一例を、第2図はこの発明の方法で得られる包
装材の拡大断面図の一例を示す。 1……紙、2……気化性薬剤、3……樹脂、4
……ベルトコンベヤ、5……櫛歯、6……ガイド
ロール、7……ピンチロール、8……包装材、9
……シール部。
FIG. 1 shows an example of a process diagram of the method for manufacturing a packaging material of the present invention, and FIG. 2 shows an example of an enlarged sectional view of the packaging material obtained by the method of the present invention. 1... Paper, 2... Volatile chemical, 3... Resin, 4
... Belt conveyor, 5 ... Comb teeth, 6 ... Guide roll, 7 ... Pinch roll, 8 ... Packaging material, 9
...Seal part.

Claims (1)

【特許請求の範囲】[Claims] 1 紙の上に粉粒状の気化性薬剤を所望シール部
を残して散布または配列した後、気化性薬剤に対
してバリヤー性の合成樹脂の押出コーテイングに
よつて該薬剤を埋設、固定し、合成樹脂、気化性
薬剤および紙を一体化したことを特徴とする包装
材の製造方法。
1. After scattering or arranging powdery vaporizable drugs on paper leaving the desired seal area, the drugs are embedded and fixed by extrusion coating with a synthetic resin that has barrier properties against the vaporizable drugs, and then synthesized. A method for producing a packaging material characterized by integrating a resin, a vaporizable drug, and paper.
JP21499690A 1990-08-16 1990-08-16 Manufacture of packaging material Granted JPH03133759A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21499690A JPH03133759A (en) 1990-08-16 1990-08-16 Manufacture of packaging material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21499690A JPH03133759A (en) 1990-08-16 1990-08-16 Manufacture of packaging material

Publications (2)

Publication Number Publication Date
JPH03133759A JPH03133759A (en) 1991-06-06
JPH0585429B2 true JPH0585429B2 (en) 1993-12-07

Family

ID=16664975

Family Applications (1)

Application Number Title Priority Date Filing Date
JP21499690A Granted JPH03133759A (en) 1990-08-16 1990-08-16 Manufacture of packaging material

Country Status (1)

Country Link
JP (1) JPH03133759A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9221751D0 (en) * 1992-10-16 1992-12-02 Unilever Plc Packaging materials

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5332877B2 (en) * 1972-12-31 1978-09-11

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5332877U (en) * 1976-08-26 1978-03-22

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5332877B2 (en) * 1972-12-31 1978-09-11

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Publication number Publication date
JPH03133759A (en) 1991-06-06

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