JPH057903A - Manufacture of aluminum foil - Google Patents

Manufacture of aluminum foil

Info

Publication number
JPH057903A
JPH057903A JP3160375A JP16037591A JPH057903A JP H057903 A JPH057903 A JP H057903A JP 3160375 A JP3160375 A JP 3160375A JP 16037591 A JP16037591 A JP 16037591A JP H057903 A JPH057903 A JP H057903A
Authority
JP
Japan
Prior art keywords
aluminum foil
oil
foil
matting
rolled
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3160375A
Other languages
Japanese (ja)
Other versions
JPH07106365B2 (en
Inventor
Akio Fukuda
明夫 福田
Tatsuo Ono
龍夫 大野
Yoshinari Matsukiyo
義成 松清
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Showa Aluminum Can Corp
Original Assignee
Showa Aluminum Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Aluminum Corp filed Critical Showa Aluminum Corp
Priority to JP3160375A priority Critical patent/JPH07106365B2/en
Publication of JPH057903A publication Critical patent/JPH057903A/en
Publication of JPH07106365B2 publication Critical patent/JPH07106365B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/40Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling foils which present special problems, e.g. because of thinness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/38Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • B21B2003/001Aluminium or its alloys

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Metal Rolling (AREA)

Abstract

PURPOSE:To obtain a soft Al foil whose water wettability is satisfactory in a short time even in low temperature batch annealing by using mineral oil whose fractional distillation end point is specified as matting oil at the time of pair rolling. CONSTITUTION:In the inlet side of a finish rolling mill 3, two middle rolled Al foil coils 11, 12 are coiled out simultaneously, and by atomizing matting oil 4 to between those Al foil materials 1, 2, a pair rolled Al foil material is formed. Subsequently, by executing finish rolling, a pair rolled Al foil 5 is formed. In this case, as matting oil, mineral oil whose fractional distillation end point is 120-245 deg.C is used. In such a way, an Al foil whose water wettability is satisfactory can be manufactured, and also, annealing time can be shortened.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、アルミニウム箔の製
造法、とくに重合圧延によるアルミニウム箔の製造法に
関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing an aluminum foil, and more particularly to a method for producing an aluminum foil by polymerization rolling.

【0002】[0002]

【従来の技術】従来、一般にアルミニウムの薄箔を得る
には、2枚の中延圧延アルミニウム・コイルを、マッテ
ィングオイルを介して重ね合わせ、この2枚重ねアルミ
ニウム・コイルを仕上げ圧延し、圧延後の2枚合わせア
ルミニウム箔を相互に分離した後、焼鈍し、付着マッテ
ィングオイルを蒸発および酸化により除去していた。
2. Description of the Related Art Conventionally, in general, to obtain a thin foil of aluminum, two intermediate rolled aluminum coils are superposed through a matting oil, and the two superposed aluminum coils are finish-rolled and rolled. The two laminated aluminum foils of 1 were separated from each other and then annealed to remove the attached matting oil by evaporation and oxidation.

【0003】アルミニウム箔表面の水ぬれ性は、樹脂と
の接着性、印刷の工程に大きな影響を及ぼし、水ぬれ性
が悪い場合すなわち脱脂が悪い場合には、接着不良や印
刷剥がれの問題が生じる。
The wettability of the surface of the aluminum foil has a great influence on the adhesiveness with the resin and the printing process. If the wettability of the water is poor, that is, if the degreasing is poor, problems such as poor adhesion and peeling of the print may occur. .

【0004】そこで、水ぬれ性の改善のために、アルミ
ニウム箔の製造において、熱処理とりわけバッチ焼鈍に
おいて、焼鈍温度を高くして、脱脂を実施する方法
と、逆に、焼鈍温度を低くし、長時間で脱脂を実施す
る方法とが行なわれていた。
Therefore, in order to improve the water wettability, in the production of aluminum foil, in the heat treatment, particularly in the batch annealing, the annealing temperature is increased to perform degreasing. The method of performing degreasing in time was performed.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、従来
は、マッティングオイルとして、分留終点が265℃と
非常に高い鉱油を用いており、前者の焼鈍温度が40
0℃以下と、高い場合には、箔同志の密着(ステッキネ
ス)が発生し、アルミニウム箔の巻戻し時にしわが発生
するという問題があり、また後者の低温では、長時間
の焼鈍が必要となり、とくに広幅のアルミニウム箔とな
ると、要する時間は100時間以上となり、時間短縮の
必要性があるという問題があった。
However, conventionally, as the matting oil, a mineral oil having an extremely high fractional distillation end point of 265 ° C. is used, and the former annealing temperature is 40 ° C.
When it is as high as 0 ° C or lower, there is a problem that adhesion between the foils (stickiness) occurs and wrinkles occur when unwinding the aluminum foil, and at the low temperature of the latter, long-time annealing is required. Especially, when the width of the aluminum foil is wide, the time required is 100 hours or more, and there is a problem that the time needs to be shortened.

【0006】この発明の目的は、重合圧延によるアルミ
ニウム箔の製造法において、上記の従来技術の問題を解
決し、低温バッチ焼鈍によっても、短時間で、水ぬれ性
の良好な軟質アルミニウム箔を製造することができる、
アルミニウム箔の製造法を提供しようとするにある。
An object of the present invention is to solve the above-mentioned problems of the prior art in a method for producing an aluminum foil by polymerization rolling, and to produce a soft aluminum foil having good wettability in a short time even by low temperature batch annealing. can do,
There is an attempt to provide a method for manufacturing aluminum foil.

【0007】[0007]

【課題を解決するための手段】この発明は、上記の目的
を達成するために、2枚のアルミニウム箔材料を、マッ
ティングオイルを介して重ね合わせ、この2枚重ねアル
ミニウム箔材料を仕上げ圧延し、圧延後の2枚合わせア
ルミニウム箔を相互に分離した後、焼鈍するアルミニウ
ム箔の製造法において、上記マッティングオイルとし
て、分留終点が120〜245℃の鉱油を用いることを
特徴とする、アルミニウム箔の製造法を要旨としてい
る。
SUMMARY OF THE INVENTION In order to achieve the above-mentioned object, the present invention superimposes two aluminum foil materials through a matting oil, and finish-rolls the two aluminum foil materials. In the method for producing an aluminum foil in which two rolled aluminum foils after rolling are separated from each other and then annealed, a mineral oil having a fractionation end point of 120 to 245 ° C. is used as the matting oil. The main point is the foil manufacturing method.

【0008】図面を参照すると、重合圧延によるアルミ
ニウム箔の製造法としては、図1に示すように、仕上
げ圧延機(3) の入り側で2つの中延上がりアルミニウム
箔コイル(11)(12)を同時に巻き出し、それらのアルミニ
ウム箔材料(1)(2)間にマッティングオイル(4) を噴霧し
て、2枚重ね合わせアルミニウム箔材料を形成したの
ち、仕上げ圧延して2枚重ね合わせアルミニウム箔(5)
を形成する方法と、図2に示すように、2つの中延上
がりアルミニウム箔コイル(11)(12)から巻き出したアル
ミニウム箔材料(1)(2)を、ダブラーマシン(6) にて、両
アルミニウム箔材料(1)(2)間にマッティングオイル(4)
を滴下しながら2枚重ね合わせアルミニウム箔材料を形
成したのち、仕上げ圧延して2枚重ね合わせアルミニウ
ム箔(5) を形成する方法とがあるが、この発明は、これ
らいずれの方法にも適用されるものである。
Referring to the drawings, as a method of producing an aluminum foil by polymerization rolling, as shown in FIG. 1, two middle-rolled aluminum foil coils (11) and (12) are provided on the entry side of a finish rolling mill (3). Unwinding at the same time, spraying the matting oil (4) between the aluminum foil materials (1) and (2) to form a two-ply aluminum foil material, and then finishing rolling, two-ply aluminum foil. (Five)
As shown in FIG. 2, the aluminum foil material (1) and (2) unwound from the two middle-stretched aluminum foil coils (11) and (12) are placed in a doubler machine (6). Matting oil (4) between aluminum foil materials (1) (2)
There is a method of forming a two-ply aluminum foil material by dropping and then finishing rolling to form a two-ply aluminum foil (5). The present invention is applicable to any of these methods. It is something.

【0009】ここで、マッティングオイルの使用目的
は、アルミニウム箔の艶消し面の均一化と次工程のセパ
レータにて箔同志を分離しやすくすることにある。ま
た、焼鈍の目的は、加工硬化した箔に柔軟性を与えると
ともに、箔表面に付着しているマッティングオイルを除
去し、その後の工程、すなわちプラスチック・フィルム
との貼り合わせ、印刷、着色、あるいは型付けなどの加
工に適した表面を有する軟質箔を得ることにある。
Here, the purpose of using the matting oil is to make the matte surface of the aluminum foil uniform and to facilitate the separation of the foils by the separator in the next step. In addition, the purpose of annealing is to give flexibility to the work-hardened foil and to remove the matting oil adhering to the foil surface, and the subsequent steps, namely, laminating with plastic film, printing, coloring, or It is to obtain a soft foil having a surface suitable for processing such as patterning.

【0010】この発明は、分留終点(分留性状)の違っ
た鉱油を使用することにより、脱脂(バッチ焼鈍での水
ぬれ性)を改善するものであり、2枚の中延圧延アルミ
ニウム・コイル同志の間に介在させるマッティングオイ
ルとして、分留終点が120〜245℃の鉱油を用いる
ものである。
The present invention improves degreasing (water wettability in batch annealing) by using mineral oils having different fractionation end points (property of fractionation). As a matting oil to be interposed between the two, mineral oil having a fractionation end point of 120 to 245 ° C. is used.

【0011】マッティングオイルとして用いる鉱油の分
留終点が120℃未満であれば、焼鈍工程における付着
マッティングオイルの除去は簡単であるが、圧延工程に
おいて、マッティングオイルの性状、とくに粘度および
分留温度範囲が変化し、圧延性に悪影響を及ぼして、例
えば圧延速度がですぎたり、ヘリンボーンといわれる魚
の骨のようなしわができたり、オイルピットといわれる
オイル腐食による斑点、表面光沢不良などの表面欠陥が
現れ、アルミニウム箔の艶消し面の均一化が充分でな
く、表面状態の良好なアルミニウム箔が得られない。ま
た、鉱油の分留終点が245℃を越えると、焼鈍工程に
おいてマッティングオイルの除去が充分でなく、アルミ
ニウム箔表面の水ぬれ性が悪くなって、樹脂との接着
性、印刷の工程に悪い影響を及ぼすので、好ましくな
い。
If the fractional distillation end point of the mineral oil used as the matting oil is less than 120 ° C., it is easy to remove the adhering matting oil in the annealing process. Distillation temperature range changes, which adversely affects rolling performance, for example, the rolling speed is too high, wrinkles such as fish bone called herringbone, spots due to oil corrosion called oil pit, surface gloss defect etc. Defects appear, the matte surface of the aluminum foil is not sufficiently uniformized, and an aluminum foil having a good surface condition cannot be obtained. When the end point of the fractional distillation of mineral oil exceeds 245 ° C, the matting oil is not sufficiently removed in the annealing step, the wettability of the aluminum foil surface is deteriorated, and the adhesiveness with the resin and the printing step are poor. It has an adverse effect and is not preferable.

【0012】[0012]

【作用】上記のアルミニウム箔の製造法によれば、2枚
の中延圧延アルミニウム・コイル同志の間に介在させる
マッティングオイルとして、分留終点が120〜245
℃と低い鉱油を用いているから、重合圧延によるアルミ
ニウム箔の製造法において、低温バッチ焼鈍によって
も、短時間で、水ぬれ性の良好な軟質アルミニウム箔を
製造することができるものである。
According to the above-mentioned method for producing an aluminum foil, the fractional distillation end point is 120 to 245 as the matting oil to be interposed between the two sheets of the intermediate rolled aluminum coil.
Since a mineral oil having a low temperature of 0 ° C. is used, a soft aluminum foil having good water wettability can be produced in a short time even by low temperature batch annealing in the method for producing an aluminum foil by polymerization rolling.

【0013】[0013]

【実施例】つぎに、この発明の実施例を説明する。EXAMPLES Next, examples of the present invention will be described.

【0014】図1に示す方法により、重合圧延を行な
い、厚さ7μmアルミニウム箔を製造した。このとき、
分留終点(分留性状)の異なるつぎの3種類の鉱油をマ
ッティングオイルに使用した。
Polymerization rolling was performed by the method shown in FIG. 1 to produce an aluminum foil having a thickness of 7 μm. At this time,
The following three kinds of mineral oils having different fractionation end points (distillation properties) were used as matting oils.

【0015】分留終点175℃の(商品名クレンゾー
ル、日本石油株式会社製) 分留終点245℃の(新鉱油、モービル株式会社製) 従来の分留終点265℃の(鉱油、モービル株式会社
製) ついで、これらのアルミニウム箔を直径(φ)75mmの
鋼管に巻き付けて、幅1000mm、巻長さ18000m
のコイルを作成し、これらのコイルを300℃×30時
間(トータル時間60時間)の条件下でバッチ焼鈍し
た。
Fractional distillation end point 175 ° C. (trade name: Clensol, manufactured by Nippon Oil Co., Ltd.) Fractional end point 245 ° C. (new mineral oil, manufactured by Mobil Co.) Conventional fractionation end point 265 ° C. (mineral oil, manufactured by Mobil Co., Ltd. ) Then, these aluminum foils are wound around a steel pipe with a diameter (φ) of 75 mm, and the width is 1000 mm and the winding length is 18000 m.
No. 3 coil was prepared, and these coils were batch-annealed under the conditions of 300 ° C. × 30 hours (total time 60 hours).

【0016】焼鈍後のアルミニウム箔のコイルについ
て、水滴噴霧法によりぬれ率を求めた。ぬれ率の計算
は、つぎに方法により算出した。
The wettability of the annealed aluminum foil coil was determined by the water droplet spraying method. The wetting rate was calculated by the following method.

【0017】すなわち、図3に示すように、 A:焼鈍後のアルミニウム箔(5a)のコイルの全幅 B:水滴噴霧法においてアルミニウム箔(5a)のコイルが
ぬれない部分の幅、とすると、 得られた結果を図4のグラフに示した。
That is, as shown in FIG. 3, where A is the total width of the coil of the aluminum foil (5a) after annealing, and B is the width of the portion of the aluminum foil (5a) in which the coil is not wet in the water droplet spraying method, The obtained results are shown in the graph of FIG.

【0018】図4から明らかなように、低い分留終点
175℃の油をマッティングオイルとして使用すると、
ぬれ率は約87%であり、また、比較的低い分留終点
245℃の新鉱油をマッティングオイルを使用すると、
ぬれ率は約50%であった。
As is apparent from FIG. 4, when oil having a low fractional distillation end point of 175 ° C. is used as the matting oil,
The wettability is about 87%, and when matting oil is used as the new mineral oil having a relatively low fractionation end point of 245 ° C.,
The wetting rate was about 50%.

【0019】これに対し、従来の高い分留終点265
℃の鉱油をマッティングオイルとして使用すると、ぬれ
率は約32%であった。このことから、この発明の方法
によれば、水ぬれ性の良いアルミニウム箔を製造するこ
とができ、また、同じぬれ率のアルミニウム箔を得よう
とすると、焼鈍時間の短縮が可能であることが、明らか
である。
On the other hand, the conventional high fractional distillation end point 265
When mineral oil at 0 ° C was used as matting oil, the wettability was about 32%. From this, according to the method of the present invention, it is possible to produce an aluminum foil having good wettability with water, and to obtain an aluminum foil having the same wettability, it is possible to shorten the annealing time. ,it is obvious.

【0020】[0020]

【発明の効果】この発明は、上述のように、2枚のアル
ミニウム箔材料を、マッティングオイルを介して重ね合
わせ、この2枚重ねアルミニウム箔材料を仕上げ圧延
し、圧延後の2枚合わせアルミニウム箔を相互に分離し
た後、焼鈍するアルミニウム箔の製造法において、上記
マッティングオイルとして、分留終点が120〜245
℃の鉱油を用いるものであるから、重合圧延によるアル
ミニウム箔の製造法において、低温バッチ焼鈍によって
も、短時間で、水ぬれ性の良好な軟質アルミニウム箔を
製造することができるという効果を奏する。
As described above, according to the present invention, two aluminum foil materials are superposed on each other via a matting oil, the two superposed aluminum foil materials are finish-rolled, and the two post-rolled aluminum foil is rolled. In the method for producing an aluminum foil, which comprises annealing foils after separating them from each other, the fractionating distillation end point is 120 to 245 as the matting oil.
Since the mineral oil at 0 ° C. is used, it is possible to produce a soft aluminum foil having good water wettability in a short time even by low temperature batch annealing in the method for producing an aluminum foil by polymerization rolling.

【図面の簡単な説明】[Brief description of drawings]

【図1】この発明の方法を実施する装置の1例を示す概
略側面図である。
FIG. 1 is a schematic side view showing an example of an apparatus for carrying out the method of the present invention.

【図2】この発明の方法を実施する装置のいま1つの例
を示す概略側面図である。
FIG. 2 is a schematic side view showing another example of an apparatus for carrying out the method of the present invention.

【図3】焼鈍後のアルミニウム箔のコイルについて、水
滴噴霧法によりぬれ率を測定する状態を示す概略斜視図
である。
FIG. 3 is a schematic perspective view showing a state in which the wetting rate is measured by a water droplet spray method for an annealed aluminum foil coil.

【図4】圧延後の各コイルについて水滴噴霧法により算
出したぬれ率と、マッティングオイルの分留終点との関
係を示すグラフである。
FIG. 4 is a graph showing a relationship between a wetting rate calculated by a water droplet spraying method for each coil after rolling and a fractionation end point of matting oil.

【符号の説明】[Explanation of symbols]

1 中延圧延アルミニウム箔材料 2 中延圧延アルミニウム箔材料 3 圧延機 4 マッティングオイル 5 2枚重ね合わせアルミニウム箔 5a 焼鈍後のアルミニウム箔 6 ダブラーマシン 11 アルミニウム箔材料のコイル 12 アルミニウム箔材料のコイル 13 2枚重ねアルミニウム箔のコイル 1 Medium-rolled rolled aluminum foil material 2 Medium-rolled rolled aluminum foil material 3 Rolling machine 4 Matting oil 5 2 sheets Laminated aluminum foil 5a Aluminum foil after annealing 6 Doubler machine 11 Coil of aluminum foil material 12 Coil of aluminum foil material 13 2 sheets Laminated aluminum foil coil

Claims (1)

【特許請求の範囲】 【請求項1】 2枚のアルミニウム箔材料を、マッティ
ングオイルを介して重ね合わせ、この2枚重ねアルミニ
ウム箔材料を仕上げ圧延し、圧延後の2枚合わせアルミ
ニウム箔を相互に分離した後、焼鈍するアルミニウム箔
の製造法において、上記マッティングオイルとして、分
留終点が120〜245℃の鉱油を用いることを特徴と
する、アルミニウム箔の製造法。
Claims: 1. Two aluminum foil materials are superposed through a matting oil, the two superposed aluminum foil materials are finish-rolled, and the two post-rolled aluminum foils are mutually rolled. In the method for producing an aluminum foil, which is annealed after being separated into 1., a mineral oil having a fractionation end point of 120 to 245 ° C. is used as the matting oil, the method for producing an aluminum foil.
JP3160375A 1991-07-01 1991-07-01 Aluminum foil manufacturing method Expired - Fee Related JPH07106365B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3160375A JPH07106365B2 (en) 1991-07-01 1991-07-01 Aluminum foil manufacturing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3160375A JPH07106365B2 (en) 1991-07-01 1991-07-01 Aluminum foil manufacturing method

Publications (2)

Publication Number Publication Date
JPH057903A true JPH057903A (en) 1993-01-19
JPH07106365B2 JPH07106365B2 (en) 1995-11-15

Family

ID=15713612

Family Applications (1)

Application Number Title Priority Date Filing Date
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104442244A (en) * 2014-12-01 2015-03-25 衡阳合力工业车辆有限公司 Roadway and railway two-purpose tractor
CN106670233A (en) * 2016-12-20 2017-05-17 中南大学 Cryogenic rolling method for preparing nanometer lithium aluminum bi-metal composite foil
WO2019148679A1 (en) * 2018-01-30 2019-08-08 北京信达盛包装材料有限公司 Aluminum foil with double dark sides and preparation method therefor

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104442244A (en) * 2014-12-01 2015-03-25 衡阳合力工业车辆有限公司 Roadway and railway two-purpose tractor
CN106670233A (en) * 2016-12-20 2017-05-17 中南大学 Cryogenic rolling method for preparing nanometer lithium aluminum bi-metal composite foil
CN106670233B (en) * 2016-12-20 2018-06-29 中南大学 It is a kind of to prepare a nanometer deep cooling milling method for lithium Al bimetal composite foil
WO2019148679A1 (en) * 2018-01-30 2019-08-08 北京信达盛包装材料有限公司 Aluminum foil with double dark sides and preparation method therefor

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