JPH0577218A - Production of double layer molded tile - Google Patents

Production of double layer molded tile

Info

Publication number
JPH0577218A
JPH0577218A JP24198391A JP24198391A JPH0577218A JP H0577218 A JPH0577218 A JP H0577218A JP 24198391 A JP24198391 A JP 24198391A JP 24198391 A JP24198391 A JP 24198391A JP H0577218 A JPH0577218 A JP H0577218A
Authority
JP
Japan
Prior art keywords
flakes
base material
raw material
laminated
tile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP24198391A
Other languages
Japanese (ja)
Inventor
Hidenori Kobayashi
秀紀 小林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toto Ltd
Original Assignee
Toto Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toto Ltd filed Critical Toto Ltd
Priority to JP24198391A priority Critical patent/JPH0577218A/en
Publication of JPH0577218A publication Critical patent/JPH0577218A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To obtain a tile having both of a three-dimensional appearance and a rich quality appearance by forming embossed patterns to a surface layer composed of flakes having various shapes or sizes by subjecting the flakes laminated to the surface of the raw material of a base material to pressure molding using an elastomer. CONSTITUTION:In the production of a double-layer molded title consisting of a base material and the surface layer laminated thereto, the inorg. raw material of the surface layer is prepared as a composition bondable to the raw material of the base material and granulated to obtain amorphous flakes 5. Next, these flakes 5 are laminated to the surface of the raw material 4 of the base material and all of them are subjected to the press molding by the pressing surface of the elastomer 1a provided to an upper mold 1 to unify the flackes 5 with the raw material 4. Thereafter, the molded one is baked to obtain a desired double-layer molded tile.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、基材の表面に表面層を
積層して加圧成形しその後焼成することによって製品を
得る二層成形タイルの製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a two-layer molded tile in which a surface layer is laminated on the surface of a substrate, pressure-molded and then fired to obtain a product.

【0002】[0002]

【従来の技術】二層成形タイルの一般的な製造方法は、
下層となる基材の上面にこの基材と同じかこれに近い組
成の素地を造粒したチップを上層の表面層としてチャー
ジし、プレス成形によって基材の中にチップを埋没させ
るようにして一体成形し、その後焼成するというもので
あった。プレス成形には、一般に金型装置が利用され、
チップを完全に基材の中に埋め込むようにして比較的平
らな表面を持たせた製品が多い。また、チップが完全に
基材中に埋没しない場合に備えて、研磨工程を施す製造
方法もある。
2. Description of the Related Art A general method for producing a two-layer molded tile is
The upper surface of the base material that is the lower layer is granulated with a base material having the same or similar composition as this base material, and the chips are charged as the upper surface layer, and the chips are embedded in the base material by press molding to be integrated. It was formed and then fired. A mold device is generally used for press molding,
Many products have relatively flat surfaces such that the chips are completely embedded in the substrate. There is also a manufacturing method in which a polishing step is performed in case the chip is not completely buried in the base material.

【0003】[0003]

【発明が解決しようとする課題】このような方法では、
チップの大きさの相違やその分布による様々な模様を持
つタイルの製品が得られる。ところが、チップは基材の
中に溶け込むような状態で一体化されて焼成されるの
で、出来上がった製品の表面は平面的なものに終わって
しまう。このため、質感に乏しいものとなり、深みや重
厚さに欠けるだけでなく、たとえば敢えて表面に凹凸を
持たせることによって光の反射具合を複雑にし、光沢や
外観の印象が特異な製品を得ることができなかった。
SUMMARY OF THE INVENTION In such a method,
Tile products with various patterns depending on the size of chips and their distribution can be obtained. However, since the chips are integrated and fired in such a state that they melt into the base material, the surface of the finished product ends up being flat. For this reason, the texture is poor, and not only is it lacking in depth and heavyness, but it is also possible to obtain a product with a unique impression of gloss and appearance by complicating the reflection of light by intentionally making the surface uneven. could not.

【0004】本発明において解決すべき課題は、焼成後
のタイルの表面に不定形の凹凸を残すようにし、質感に
富む新しい感覚のタイルの製造を可能とすることにあ
る。
[0004] The problem to be solved in the present invention is to leave irregular irregularities on the surface of the tile after firing so as to enable the production of a tile having a new feeling with a rich texture.

【0005】[0005]

【課題を解決するための手段】本発明は、基材とその上
に積層した表面層とからなる二層成形タイルの製造方法
であって、前記表面層の無機原料を前記基材の素地原料
と接合可能な組成とすると共に造粒によって不定形なフ
レークとし、これらのフレークを前記基材の素地原料の
表面に積層し、前記フレークと基材の素地原料とを弾性
体の加圧面によってプレス成形してフレークと素地原料
とを一体化し、更にこの後、焼成することを特徴とす
る。
The present invention is a method for producing a two-layer molded tile comprising a base material and a surface layer laminated on the base material, wherein the inorganic raw material of the surface layer is a base material of the base material. And flakes into indefinite flakes by granulation, and these flakes are laminated on the surface of the base material of the base material, and the flakes and the base material of the base material are pressed by a pressing surface of an elastic body. It is characterized in that the flakes and the raw material for raw material are integrated into one body and then fired.

【0006】[0006]

【作用】表面層の無機原料を予めフレークとしておくこ
とによって、このフレークを基材の素地原料の上に積層
すれば、多数のフレークが複雑に絡み合って積み重な
る。そして、弾性体の加圧面によってプレス成形する
と、加圧面はフレークの層の厚みの分布に沿って弾性変
形し、フレークを押し潰すことなく基材の素地原料に一
体化させる。したがって、プレス後にはフレークによる
凹凸模様が表面層に形成され、その後の焼成によって表
面に不定形の縞模様が凹凸面となって現れるものが製品
として得られる。
By preliminarily forming the flakes of the inorganic raw material of the surface layer and laminating the flakes on the base raw material of the base material, a large number of flakes are complicatedly entangled and stacked. Then, when press-molded by the pressing surface of the elastic body, the pressing surface elastically deforms along the distribution of the thickness of the flake layer, and the flakes are integrated with the base material of the base material without being crushed. Therefore, after pressing, an uneven pattern of flakes is formed on the surface layer, and an irregular striped pattern appears as an uneven surface on the surface by subsequent firing, so that a product is obtained.

【0007】[0007]

【実施例】成形しようとするタイルの基材の組成は、従
来のものとほぼ同様のものとし、長石:40重量部,粘
土:40重量部,陶石:20重量部、または長石:50
重量部,粘土:35重量部,陶石:15重量部とする。
EXAMPLE The composition of the base material of the tile to be formed is almost the same as the conventional one, and feldspar: 40 parts by weight, clay: 40 parts by weight, porcelain stone: 20 parts by weight, or feldspar: 50 parts by weight.
Parts by weight, clay: 35 parts by weight, porcelain stone: 15 parts by weight.

【0008】一方、表面層を形成するフレークは、カオ
リン,粘土:15〜40重量部,陶石:10〜50重量
部,長石25〜60重量部の組合せとする。たとえば、
カオリン,粘土:20重量部,陶石:20重量部,長
石:60重量部の無機原料とする。
On the other hand, the flakes forming the surface layer are a combination of kaolin, clay: 15-40 parts by weight, porcelain stone: 10-50 parts by weight, and feldspar 25-60 parts by weight. For example,
Kaolin, clay: 20 parts by weight, porcelain stone: 20 parts by weight, feldspar: 60 parts by weight as an inorganic raw material.

【0009】フレークの製造方法は次のとおりである。
まず、前記の組成の無機原料をボールミル等で粉砕して
粒径が50〜500ミクロン程度のスプレー粉とし、乾
燥させて含水率を7%程度にする。この後、スプレー粉
をアイリッヒミキサーで1〜10ミリ程度の大きさに造
粒し、水を添加して含水率を10〜15%に調整する。
なお、この造粒に際し、必要に応じて顔料を添加してフ
レークに着色するようにしてもよい。次いで、無機原料
の造粒物をローラで圧延し、0.5〜2ミリ程度の偏平
粒とする。
The method for producing flakes is as follows.
First, the inorganic raw material having the above composition is pulverized by a ball mill or the like into a spray powder having a particle size of about 50 to 500 microns, and dried to a water content of about 7%. Thereafter, the spray powder is granulated with an Erich mixer to a size of about 1 to 10 mm, and water is added to adjust the water content to 10 to 15%.
In addition, at the time of this granulation, a pigment may be added as necessary to color the flakes. Next, the granulated product of the inorganic raw material is rolled by a roller to obtain flat particles of about 0.5 to 2 mm.

【0010】このようにして製造されたフレークは、ほ
ぼ一様な厚さを持つ偏平状の小片となり、その平面形状
は造粒過程での造粒片の大きさに従って大小様々であ
り、形状もそれぞれに異なったものが得られる。
The flakes produced in this manner are flat small pieces having a substantially uniform thickness, and their planar shapes vary in size according to the size of the granulated pieces in the granulating process, and their shapes are also different. Different things are obtained for each.

【0011】図1は本発明の二層成形タイルの製造方法
における基材とフレークの表面層とのプレス工程を示す
概略図である。
FIG. 1 is a schematic view showing a step of pressing a base material and a surface layer of flakes in the method for producing a double-layer molded tile according to the present invention.

【0012】図において、上型1,下型2及び枠型3が
プレス装置として配置され、上型1の下面の加圧面には
弾性体としてラバー1aを全面に張り付けている。この
ラバー1aはJISゴム硬度が30〜85,好ましくは
35〜65であり、圧下方向の厚さは0.5〜2.5ミ
リ程度である。
In the figure, an upper die 1, a lower die 2 and a frame die 3 are arranged as a pressing device, and a rubber 1a as an elastic body is attached to the entire lower surface of the upper die 1 as a pressing surface. The rubber 1a has a JIS rubber hardness of 30 to 85, preferably 35 to 65, and a thickness in the rolling direction of about 0.5 to 2.5 mm.

【0013】このようなプレス装置に対し、下型2と枠
型3の中の成形空間の中に予め用意した基材の原料4を
充填し、この原料4の上面に先の製造方法によって製造
したフレーク5をチャージして積層する(図1の
(b))。
In such a pressing device, a raw material 4 for a base material prepared in advance is filled in the molding space in the lower mold 2 and the frame mold 3, and the upper surface of the raw material 4 is manufactured by the above manufacturing method. The formed flakes 5 are charged and laminated ((b) of FIG. 1).

【0014】ここで、基材の原料4とフレーク5との一
体化に必要な接着強度を確保するため、基材の原料4の
含水率を6〜7%とし、プレス時のフレーク5の含水率
は6〜14%,好ましくは8〜12%とすることを一つ
の条件とする。また、先に説明した基材の原料4の組成
に対して、同じ程度の耐火度や焼成収縮率等の焼成特性
を持つものとする。
Here, in order to secure the adhesive strength necessary for integrating the base material 4 and the flakes 5, the water content of the base material 4 is set to 6 to 7%, and the water content of the flakes 5 during pressing is increased. One condition is that the rate is 6 to 14%, preferably 8 to 12%. Further, it is assumed that the composition of the raw material 4 of the base material described above has the same firing characteristics such as fire resistance and firing shrinkage.

【0015】フレーク5を基材の原料4の上に積層した
後、上型1を下降させてフレーク5と原料4を加圧する
(図1の(c))。このときの上型1による圧下力は、
200〜400kgf/cm2 ,好ましくは250〜3
00kgf/cm2 程度とする。この加圧成形のとき、
上型1の下面のラバー1aがフレーク5を圧下するの
で、フレーク5の積層状態に応じてラバー1aが弾性変
形し、フレーク5を全て押し潰すことなくその積層分布
による表面の凹凸が残されたまま、フレーク5が基材の
原料4に一体化される。
After the flakes 5 are laminated on the raw material 4 of the base material, the upper mold 1 is lowered to pressurize the flakes 5 and the raw material 4 ((c) of FIG. 1). The pressing force by the upper mold 1 at this time is
200 to 400 kgf / cm 2 , preferably 250 to 3
It is set to about 00 kgf / cm 2 . At the time of this pressure molding,
Since the rubber 1a on the lower surface of the upper mold 1 presses down the flakes 5, the rubber 1a elastically deforms according to the laminated state of the flakes 5 and the surface unevenness due to the laminated distribution is left without crushing all the flakes 5. As it is, the flakes 5 are integrated with the raw material 4 of the base material.

【0016】次いで、この加圧成形によって得られた成
形体を焼成炉に装入し、焼成温度1280℃で70〜9
0分間焼成する。これにより、図2及び図3に示す基材
6と表面層7とによる二層成形タイルを最終製品として
得る。なお、焼成する前に透明釉を施釉してもよい。
Then, the molded body obtained by this pressure molding is charged into a firing furnace, and the firing temperature is 1280 ° C. to 70 to 9 ° C.
Bake for 0 minutes. As a result, a two-layer molded tile composed of the base material 6 and the surface layer 7 shown in FIGS. 2 and 3 is obtained as a final product. A transparent glaze may be applied before firing.

【0017】表面層7は、フレーク5を製造したときの
状態に比べてこれが押し付けられた状態に基材6の全面
に緻密に分布し、図4の概略図に示すように、フレーク
5が積層している部分やフレーク5の縁等が絡まりあっ
て複雑な凹凸形状を呈する。そして、この凹凸形状は、
表面層7の全体に亘って展開され、タイルの表面が多数
の小片を掻き集めてびっしりと詰め込んだような模様と
なって現れる。したがって、焼成後の製品の表面の凹凸
によって、質感に富み深みも増した従来にない特異な表
面を持つタイルが得られる。
The surface layer 7 is densely distributed over the entire surface of the base material 6 in the pressed state as compared with the state when the flakes 5 are manufactured, and the flakes 5 are laminated as shown in the schematic view of FIG. The indented portions and the edges of the flakes 5 are entangled with each other to form a complicated uneven shape. And this uneven shape is
Unfolded over the entire surface layer 7, the surface of the tile appears as a pattern in which a large number of small pieces are scraped together and packed tightly. Therefore, the unevenness of the surface of the product after firing can provide a tile having a unique surface with rich texture and increased depth.

【0018】ここで、加圧成形の際に、上型1の圧下力
やラバー1aの硬度を適正に変更すれば、フレーク5を
押し潰す力も様々に変化する。このため、表面に現出す
るフレーク5による凹凸の度合いも変更でき、たとえば
圧下力を小さくしたりラバー1aの硬度を下げると、凹
凸の起伏の激しいダイナミックな模様を成形することが
できる。
Here, when the pressing force of the upper die 1 and the hardness of the rubber 1a are appropriately changed during the pressure molding, the force for crushing the flakes 5 also changes variously. Therefore, the degree of the unevenness due to the flakes 5 appearing on the surface can be changed. For example, if the rolling force is reduced or the hardness of the rubber 1a is decreased, a dynamic pattern with the unevenness can be formed.

【0019】また、ラバー1aによる弾性負荷を利用し
てフレーク5と基材の原料4とを加圧するので、従来の
ような金型を使った場合に比べると、加圧成形時に発生
するラミネーションを抑えることができる。このことを
図5及び図6によって説明する。
Further, since the flakes 5 and the raw material 4 of the base material are pressed by utilizing the elastic load of the rubber 1a, the lamination generated at the time of pressure molding can be prevented as compared with the case of using a conventional mold. Can be suppressed. This will be described with reference to FIGS.

【0020】図5は、下層10(基材の原料4に相当)
の表面に造粒粉11(フレーク5に相当)を積層して金
型によるプレス成形を施す場合を説明するための概略図
である。
FIG. 5 shows the lower layer 10 (corresponding to the base material 4).
FIG. 3 is a schematic diagram for explaining a case where granulated powder 11 (corresponding to flakes 5) is laminated on the surface of and the press molding is performed by a mold.

【0021】同図(a)のように積層した造粒粉11が
互いに重なり合っていると、これを金型で加圧したとき
には、金型の下面が平坦で変形しないので、上に載って
いる造粒粉11が下の造粒粉11の隙間に入り込むよう
に圧下される。このため、隙間部分には空気が残ったま
まとなることが多く、同図の(b)のように網目状のハ
ッチングを施した表面層12に積層した造粒粉11が結
合されることになり、この表面層12の密度は他の部分
よりも高くなる。このように、加圧後に下層10と表面
層12との間に空気が残ったり、造粒粉11の充填度に
密や疎の部分があったりすると、焼成後の成形タイルの
変形やラミネーションを招く結果となりやすい。
When the laminated granulated powders 11 are stacked on each other as shown in FIG. 5A, the lower surface of the mold is flat and is not deformed when pressed by the mold, so that the granulated powders 11 are placed on top. The granulated powder 11 is pressed down so as to enter the gap between the granulated powder 11 below. For this reason, air is often left in the gap portion, and the granulated powder 11 laminated on the surface layer 12 having a mesh-like hatching as shown in FIG. The surface layer 12 has a higher density than the other parts. In this way, if air remains between the lower layer 10 and the surface layer 12 after pressing, or if there is a dense or sparse portion in the packing degree of the granulated powder 11, deformation or lamination of the molded tile after firing may occur. It is likely to result.

【0022】これに対し、図6は本発明の製造方法に用
いた上型1による加圧成形の場合を示すものである。
On the other hand, FIG. 6 shows the case of pressure molding by the upper mold 1 used in the manufacturing method of the present invention.

【0023】上型1のラバー1aは造粒粉11を加圧す
るときに、造粒粉11が重なり合っている部分について
は大きく収縮変形するので(同図の(a))、造粒粉1
1の充填度に従って加圧する。このため、同図の(b)
のように、成形された表面層12は平坦とはならない
が、その厚さ方向の密度に疎密を生じることがなく、ま
た造粒粉11の変形も緩やかに行われるのでこの間に空
気も逃げやすくなり、空気が残ってしまうこともない。
したがって、焼成後のラミネーションの発生や成形体の
変形もなく、脱型後も品質が安定した成形体を得ること
ができる。
When the rubber 1a of the upper die 1 pressurizes the granulated powder 11, the portion where the granulated powder 11 overlaps is greatly contracted and deformed ((a) in the figure).
Pressurize according to a filling degree of 1. Therefore, (b) in the figure
As described above, the formed surface layer 12 does not become flat, but the density in the thickness direction does not become uneven, and the granulated powder 11 is gently deformed, so that air can easily escape during this time. There is no air left.
Therefore, there is no occurrence of lamination after firing and deformation of the molded body, and it is possible to obtain a molded body with stable quality even after demolding.

【0024】このように、ラバー1aによる弾性的な圧
下を利用することで、フレーク5による凹凸模様の現出
だけでなく、焼成後の変形等も抑えられ、寸法精度の向
上も図られる。
As described above, by utilizing the elastic reduction by the rubber 1a, not only the appearance of the uneven pattern due to the flakes 5 but also the deformation after firing can be suppressed and the dimensional accuracy can be improved.

【0025】[0025]

【発明の効果】本発明では、基材の素地原料の表面に積
層したフレークを弾性体によって加圧成形するので、フ
レークを全て押し潰すことなくこれらを基材の表面に凹
凸状として残すことができる。このため、様々な形状や
大きさのフレークによって表面に複雑な凹凸模様を造り
出すことができ、立体感があって質感も豊かな従来には
ない全く新しい感覚のタイルを得ることができる。
In the present invention, the flakes laminated on the surface of the base material of the base material are pressure-molded by the elastic body, so that they can be left as irregularities on the surface of the base material without crushing all the flakes. it can. Therefore, it is possible to create a complicated uneven pattern on the surface by flakes of various shapes and sizes, and it is possible to obtain a tile with a completely new feeling that has a three-dimensional effect and is rich in texture.

【0026】また、プレス加工の際の圧下力や加圧面の
弾性体の硬度を変更することによって、フレークの凹凸
具合を自在に変えることができる。このため、フレーク
の組成や含水率等を厳しく設定しなくても十分に良好な
成形が行えるので加工の自由度も向上するほか、表面の
凹凸の立ち上がり等に緩急を付けることによって、様々
な製品仕様のものが簡単に製造できる。
Further, the degree of unevenness of the flakes can be freely changed by changing the pressing force during pressing and the hardness of the elastic body on the pressing surface. For this reason, it is possible to perform sufficiently good molding without strictly setting the composition and water content of the flakes, which improves the degree of freedom in processing and allows various products to be formed by gradually increasing or decreasing the unevenness of the surface. The one with the specifications can be easily manufactured.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の二層成形タイルの製造工程を示す概略
図である。
FIG. 1 is a schematic view showing a manufacturing process of a double-layer molded tile of the present invention.

【図2】得られた二層成形タイルの概略平面図である。FIG. 2 is a schematic plan view of the obtained two-layer molded tile.

【図3】図2の二層成形タイルの概略縦断面図である。3 is a schematic vertical cross-sectional view of the two-layer molded tile of FIG.

【図4】成形後のフレークによる表面凹凸の状態を示す
図である。
FIG. 4 is a diagram showing a state of surface irregularities due to flakes after molding.

【図5】従来の金型を利用したプレス加工の場合の造粒
粉の圧下変形を示す概略縦断面図である。
FIG. 5 is a schematic vertical cross-sectional view showing the rolling deformation of the granulated powder in the case of press processing using a conventional die.

【図6】ラバープレスによる造粒粉の圧下変形を示す概
略縦断面図である。
FIG. 6 is a schematic vertical cross-sectional view showing the deformation of the granulated powder under pressure by a rubber press.

【符号の説明】[Explanation of symbols]

1 上型 1a ラバー(弾性体) 2 下型 3 枠型 4 (基材の)原料 5 フレーク 6 基材 7 表面層 1 Upper Mold 1a Rubber (Elastic Body) 2 Lower Mold 3 Frame Mold 4 Raw Material (of Base Material) 5 Flakes 6 Base Material 7 Surface Layer

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 基材とその上に積層した表面層とからな
る二層成形タイルの製造方法であって、前記表面層の無
機原料を前記基材の素地原料と接合可能な組成とすると
共に造粒によって不定形なフレークとし、これらのフレ
ークを前記基材の素地原料の表面に積層し、前記フレー
クと基材の素地原料とを弾性体の加圧面によってプレス
成形してフレークと素地原料とを一体化し、更にこの
後、焼成することを特徴とする二層成形タイルの製造方
法。
1. A method for producing a two-layer molded tile comprising a base material and a surface layer laminated on the base material, wherein the inorganic raw material of the surface layer has a composition capable of being bonded to the base raw material of the base material. Amorphous flakes by granulation, these flakes are laminated on the surface of the base material of the base material, the flakes and the base material of the base material are press-molded by the pressing surface of the elastic body to form flakes and the base material. The method for producing a two-layer molded tile, comprising:
JP24198391A 1991-09-20 1991-09-20 Production of double layer molded tile Pending JPH0577218A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24198391A JPH0577218A (en) 1991-09-20 1991-09-20 Production of double layer molded tile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24198391A JPH0577218A (en) 1991-09-20 1991-09-20 Production of double layer molded tile

Publications (1)

Publication Number Publication Date
JPH0577218A true JPH0577218A (en) 1993-03-30

Family

ID=17082503

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24198391A Pending JPH0577218A (en) 1991-09-20 1991-09-20 Production of double layer molded tile

Country Status (1)

Country Link
JP (1) JPH0577218A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06312414A (en) * 1993-04-30 1994-11-08 Inax Corp Manufacture of tile with marble pattern
JP2001315110A (en) * 2000-05-12 2001-11-13 Shinko Yogyo Kk Method and apparatus for manufacturing tile
US6320530B1 (en) 1999-06-01 2001-11-20 Denso Corporation Recycling A/D converter

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06312414A (en) * 1993-04-30 1994-11-08 Inax Corp Manufacture of tile with marble pattern
US6320530B1 (en) 1999-06-01 2001-11-20 Denso Corporation Recycling A/D converter
JP2001315110A (en) * 2000-05-12 2001-11-13 Shinko Yogyo Kk Method and apparatus for manufacturing tile

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