JPH0570474B2 - - Google Patents

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Publication number
JPH0570474B2
JPH0570474B2 JP2187557A JP18755790A JPH0570474B2 JP H0570474 B2 JPH0570474 B2 JP H0570474B2 JP 2187557 A JP2187557 A JP 2187557A JP 18755790 A JP18755790 A JP 18755790A JP H0570474 B2 JPH0570474 B2 JP H0570474B2
Authority
JP
Japan
Prior art keywords
water
composite material
moisture
laminated sheet
breathability
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2187557A
Other languages
Japanese (ja)
Other versions
JPH0473065A (en
Inventor
Masayuki Makita
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP2187557A priority Critical patent/JPH0473065A/en
Publication of JPH0473065A publication Critical patent/JPH0473065A/en
Publication of JPH0570474B2 publication Critical patent/JPH0570474B2/ja
Granted legal-status Critical Current

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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

(産業上の利用分野) 本発明は多機能複合材料体に関する。 (従来の技術) 従来消臭・吸液用複合材料体として、本発明者
が開発した複合材料体がある。(特開昭63−
147468号)。 この複合材料体は、不織布、紙パルプ等の吸水
性を有する支持体に消臭液を含浸し、この支持体
を複数枚積層し、最下層の支持体中にはポリアク
リル酸ソーダ等の吸水剤を散在させると共に下面
には防水シートを貼着し、上層の支持体中には、
安定化二酸化塩素吸着体およびシリカゲル等の吸
湿・分散剤を散在させて成る。 この複合材料体によれば遺体等の悪臭の消臭・
野菜等の鮮度保持、殺菌、吸水性に優れるという
多機能を有する。 しかしながら、ガス吸収能力が不足するため、
野菜等の鮮度保持能力等の持続性にやや劣るとい
う問題点があつた。 (発明の目的) そこで発明者は上記問題点を解消すべく鋭意研
究を重ねて本発明に想到した。 すなわち本発明の目的とするところは、吸湿、
吸水、脱臭、防虫、防カビ性に優れ、特に脱臭、
野菜等の鮮度保持能力の持続性に優れる多機能複
合材料体を提供するにある。 (問題を解決するための手段) 上記目的による本発明に係る多機能複合材料で
は、ポリアクリル酸ソーダからなる吸水材を、通
気性、吸水性を有する不織布等の支持体と通気性
を有し非透水性の有孔通気性フイルムとの間に散
在させた第1の積層シート体の前記支持体側に、
含水珪酸マグネシウム鉱物からなり、細長いトン
ネル状の多数の空孔が断面マトリクス状に位置す
る無機多孔体粉末を、通気性、吸水性を有する不
織布等の2枚の支持体間に介在させた第2の積層
シート体を貼着したことを特徴としている。 ヒノキチオール、ヒノキオイル、ワサビ抽出成
分の少なくとも1種を含浸させると好適である。 (実施例) 以下では本発明の好適な実施例を添付図面に基
づいて詳細に説明する。 10は第1の積層シート体である。 この第1の積層シート体10は、不織布、割り
織布(スプリツトフアイバー)等からなる通気
性、吸水性を有する支持体12と、細孔が穿設さ
れて、通気性を有するが非透水性の、ポリオルフ
エン等からなる有孔通気性フイルム14との間に
ポリアクリル酸ソーダからなる吸水剤16を散在
させてなる。支持体12と有孔通気性フイルム1
4との接合はヒートシールによつている。 なお、支持体12は不織布等により2層に設け
て、その間に吸水剤を散在させてもよい。 ポリアクリル酸ソーダは食品添加物として使わ
れているものと同様に水に不溶の形にしておくの
がよい。 ポリアクリル酸ソーダの混入量は1m2当たり25
〜30g程度が好適である。 18は第2の積層シート体である。この第2の
積層シート体18は、通気性、吸水性を有する不
織布、あるいは目の粗い樹脂製の割り織布等から
なる2枚の支持体20,22間に細長いトンネル
状の多数の空孔が断面マトリクス状に位置する無
機多孔体粉末24を介在させてなる。この第2の
積層シート体18を形成するには、無機多孔体粉
末24中に少量の有機バインダーを混入させて、
支持体20,22で挾んで圧着せしめるとよい。 無機多孔体24は第2図に例示するような結晶
構造をなす含水珪酸マグネシウム鉱物からなり、
単繊維の断面はタルクを互い違いに積み重ねた構
造をなし(第3図)、繊維中に約5.6×11.0Åの口
径の長いトンネル状の空孔が多数マトリクス状に
幾つもあいた構造をしている。第2図に示す含水
珪酸マグネシウムの構造式は、(Mg8)[Si12
O30(OH)4(OH248H2Oで示される。外観的に
はアスベストに似ているが、アスベストはタルク
の板状結晶をロール状に巻いた構造をしており、
全く異なる構造のものである。このトンネル状空
孔を有することから、麦飯石などの約60倍ものガ
ス吸収性を有し、また臭気成分などを吸着する特
異な吸着能力を有する。また上記無機多孔体粉末
24はガス吸収性、吸水性を有し、これらを保持
あるいは放出する。この無機多孔体粉末24に加
えて、シリカゲル、麦飯石、活性炭などの無機粉
末を混入させてもよい。 無機多孔体粉末24の混入量は1m2当たり
150g程度がよい。 上記の第2の積層シート体18を前記第1の積
層シート体10の支持体12の上面に接着剤26
を用いて貼り合わせる。不織布同士を接着する接
着剤としてはゴム系の接着剤がよい。また接着剤
は全面に塗布するのでなく、水分、湿気が通過可
能にやはり網目状等部分的に塗布して接着するの
がよい。 また不織布同士の接着はあまり良好には行えな
いので、第4図に示すような、網目状の合成樹脂
製のシートの両面に接着剤を塗布した接着剤シー
トを介して不織布間を接着するようにすると良好
に両者を接着することができる。 上記のように構成した多機能複合材料体の使用
に際しては、軽く柔らかな不織布からなる外部化
粧カバー28中に収納して使用するとよい。 続いて機能について説明する。 外部からの湿気、水分や臭気性ガスなどは外部
化粧カバー28、支持体20,22に一部は吸収
され、大部分が透過して無機多孔体粉末24に至
り、捕集される。 前記したように無機多孔体粉末24は細長いト
ンネル状の多数の空孔が断面マトリクス状に位置
する構造をなして麦飯石の約60倍ものガス吸収性
を有することから、臭気性ガスは無機多孔体粉末
24に吸収され、その臭気性成分はトンネル状の
空孔内壁に吸着され、臭気性ガスは無臭となつて
放出される。また無機多孔体粉末24はエチレン
ガスの吸収性にも優れることから、野菜、果実等
の鮮度保持に効果がある。使用法としては野菜、
果実等を直接包むかあるいは収納用容器に入れて
用いればよい。また後記するように野菜、果実等
からでる水分の吸収性にも優れる。 無機多孔体粉末24に一旦吸収された湿気や水
分はやがて放出され、支持体22,12を透過し
て吸水剤16に吸収される。 ポリアクリル酸ソーダは2.4/m2程度の極め
て大きい吸収性を有する。シリカゲルの場合には
急速に吸収するが、吸湿飽和状態で吸湿能力を全
く失うと共に吸湿分の放散が少ない。したがつて
湿分の調整効果はあまり期待できない。一方ポリ
アクリル酸ソーダは上部より誘導された湿気、水
分をすばやくかつ多量に吸収しうると共に、ある
程度の放散性も有し、したがつて適度の調湿性も
有する。 表1に本複合材料体(実施例)とシリカゲルの
吸湿率を示す。
(Industrial Application Field) The present invention relates to a multifunctional composite material body. (Prior Art) As a conventional deodorizing/liquid absorbing composite material body, there is a composite material body developed by the present inventor. (Unexamined Japanese Patent Publication No. 1983-
No. 147468). This composite material body is made by impregnating a water-absorbing support such as nonwoven fabric or paper pulp with a deodorizing liquid, and then laminating multiple sheets of this support. In addition to scattering the agent, a waterproof sheet is attached to the lower surface, and the upper layer is in the support.
It consists of a stabilized chlorine dioxide adsorbent and a moisture absorbing/dispersing agent such as silica gel. This composite material body deodorizes bad odors from corpses, etc.
It has multiple functions such as maintaining the freshness of vegetables, sterilization, and excellent water absorption. However, due to insufficient gas absorption capacity,
There was a problem that the sustainability of the freshness-keeping ability of vegetables etc. was slightly inferior. (Object of the Invention) Therefore, the inventor conducted extensive research to solve the above problems and came up with the present invention. That is, the purpose of the present invention is to absorb moisture,
Excellent water absorption, deodorization, insect repellency, and mold resistance, especially deodorization,
An object of the present invention is to provide a multifunctional composite material body that has an excellent ability to maintain the freshness of vegetables and the like. (Means for Solving the Problems) In the multifunctional composite material according to the present invention for the above-mentioned purpose, a water-absorbing material made of sodium polyacrylate is combined with a support such as a non-woven fabric having breathability and water-absorbing properties. On the support side of the first laminated sheet body interspersed with a water-impermeable perforated breathable film,
An inorganic porous powder made of hydrated magnesium silicate mineral and having a large number of elongated tunnel-shaped pores arranged in a cross-sectional matrix is interposed between two supports such as non-woven fabrics having air permeability and water absorption properties. It is characterized by having a laminated sheet body attached to it. It is preferable to impregnate it with at least one of hinokitiol, hinoki oil, and wasabi extract. (Embodiments) Hereinafter, preferred embodiments of the present invention will be described in detail based on the accompanying drawings. 10 is a first laminated sheet body. This first laminated sheet body 10 has a support body 12 made of non-woven fabric, split fiber, etc., which has breathability and water absorption properties, and a support body 12 having air permeability and water absorption properties, and a support body 12 having air permeability and water absorption properties. A water-absorbing agent 16 made of sodium polyacrylate is interspersed between a perforated breathable film 14 made of polyolphene or the like. Support body 12 and perforated breathable film 1
4 is joined by heat sealing. In addition, the support body 12 may be provided in two layers of nonwoven fabric or the like, and the water absorbing agent may be interspersed between them. It is best to keep sodium polyacrylate in a form that is insoluble in water, similar to those used as food additives. The amount of sodium polyacrylate mixed is 25 per m2 .
~30g is suitable. 18 is a second laminated sheet body. This second laminated sheet body 18 has a large number of elongated tunnel-shaped holes between two supports 20 and 22 made of a nonwoven fabric having breathability and water absorption, or a coarse resin split fabric. is formed by interposing inorganic porous powder 24 arranged in a cross-sectional matrix shape. To form this second laminated sheet body 18, a small amount of organic binder is mixed into the inorganic porous powder 24,
It is preferable to sandwich and press the support bodies 20 and 22 together. The inorganic porous body 24 is made of a hydrous magnesium silicate mineral having a crystal structure as illustrated in FIG.
The cross-section of the single fiber has a structure in which talc is stacked alternately (Figure 3), and the fiber has a structure in which there are many tunnel-like holes with a diameter of about 5.6 x 11.0 Å in a matrix. . The structural formula of hydrated magnesium silicate shown in Figure 2 is (Mg 8 ) [Si 12 ]
It is represented by O 30 (OH) 4 (OH 2 ) 4 8H 2 O. Although it looks similar to asbestos, asbestos is made up of rolled talc crystals.
It has a completely different structure. Because it has these tunnel-like pores, it has gas absorbency that is about 60 times greater than maifan stone, and it also has a unique adsorption ability to adsorb odor components. Further, the inorganic porous powder 24 has gas absorbing properties and water absorbing properties, and retains or releases these. In addition to this inorganic porous powder 24, inorganic powder such as silica gel, maifan stone, activated carbon, etc. may be mixed. The amount of inorganic porous powder 24 mixed is per 1 m 2
About 150g is good. The second laminated sheet body 18 is attached to the upper surface of the support 12 of the first laminated sheet body 10 using an adhesive 26.
Paste together using As the adhesive for bonding the nonwoven fabrics together, a rubber adhesive is preferable. Furthermore, rather than applying the adhesive over the entire surface, it is preferable to apply the adhesive partially in a mesh shape or the like so that water and moisture can pass through. Also, since the adhesion between non-woven fabrics cannot be achieved very well, it is recommended that non-woven fabrics be bonded together using an adhesive sheet with adhesive applied to both sides of a mesh-like synthetic resin sheet, as shown in Figure 4. By doing so, the two can be bonded well. When using the multifunctional composite material body constructed as described above, it is preferable to store it in an external decorative cover 28 made of light and soft nonwoven fabric. Next, the functions will be explained. Moisture, moisture, odorous gas, etc. from the outside are partially absorbed by the external decorative cover 28 and the supports 20, 22, and most of them pass through and reach the inorganic porous powder 24, where they are collected. As mentioned above, the inorganic porous powder 24 has a structure in which a large number of pores in the form of long and narrow tunnels are arranged in a cross-sectional matrix, and has a gas absorbency approximately 60 times that of Maifan stone. The odorous gas is absorbed by the body powder 24, and its odorous components are adsorbed on the inner wall of the tunnel-like cavity, and the odorous gas is released as odorless. Furthermore, since the inorganic porous powder 24 has excellent ethylene gas absorption properties, it is effective in maintaining the freshness of vegetables, fruits, and the like. Usage: vegetables,
It can be used by directly wrapping fruits, etc., or by placing them in a storage container. Furthermore, as will be described later, it is also excellent in absorbing moisture from vegetables, fruits, etc. Moisture or moisture once absorbed by the inorganic porous powder 24 is eventually released, passes through the supports 22 and 12, and is absorbed by the water absorbing agent 16. Sodium polyacrylate has an extremely high absorbency of about 2.4/m 2 . In the case of silica gel, it absorbs rapidly, but when it is saturated with moisture, it loses its ability to absorb moisture completely and releases only a small amount of absorbed moisture. Therefore, it is not possible to expect much moisture adjustment effect. On the other hand, sodium polyacrylate can quickly and in large quantities absorb moisture and water introduced from the upper part, and also has a certain degree of dissipation ability, so it also has an appropriate humidity control ability. Table 1 shows the moisture absorption rates of this composite material (Example) and silica gel.

【表】 表1から明らかなように、シリカゲルの吸湿能
力は1週間以内で飽和状態となつてしまうが、本
実施例では吸湿率も大で、しかも3週間を経過し
ても吸湿能力を失わない。 このように吸水性に優れることから、結露防止
用の壁材等に有効に使用できる。例えば40℃、1
m2の空気が0℃になつたとき天井面1m2で約
117gの結露水となるが、本複合材料体は約20倍
の吸水能力をもち、その吸水、保水能力は1m2
たり約2400gある。シリガケルに換算すると5.7〜
6.4Kgに相当する。 またポリアクリル酸ソーダを水に不溶の形にす
ることによつてカビの発生を有効に防げる。 水溶性のポリアクリク酸ソーダの場合、デンプ
ンにアクリル酸ソーダをクラフト重合させている
ため、残存養分によりカビが発生すると考えられ
る。 有孔通気性フイルム14は水分は通さないか
ら、ポリアクリル酸ソーダで吸水した水分を外部
に洩らさない。一方通気性、通湿性は有するか
ら、前記の調湿性を損なわないと共に、保存物等
のムレ防止に寄与する。 上記の複合材料体にヒノキチオール、ヒノキオ
イル、あるいはワサビ抽出成分を含浸させるとよ
い。 これらは防虫および殺菌効果を有するので、よ
り多機能の複合材料体とすることができる。 本発明の複合材料体の用途は特に限定されない
が、食品コンテナ中に敷くなどして、吸湿、吸
水、脱臭、防虫用に使用するとか、結露防止の壁
材とか、タンス中に収納して吸湿、吸水、脱臭、
防虫用に用いるとか、野菜、果実の鮮度保持用等
に好適に用いることができる。 (発明の効果) 以上のように本発明によれば、含水珪酸マグネ
シウム鉱物からなり、細長い多数のトンネル状の
空孔が断面マトリクス状に位置する無機多孔体を
混入させたことにより、ガス吸収性に優れ、臭成
分を吸着するので脱臭性に優れ、またエチレンガ
ス等を吸収することから、野菜、果実等の鮮度保
持に効果があり、一方またポリアクリル酸ソーダ
を混入させたことにより、吸湿、吸水性に優れ、
また防カビ、防虫性も有する多機能の複合材料体
を提供できる。
[Table] As is clear from Table 1, the moisture absorption ability of silica gel reaches a saturated state within one week, but in this example, the moisture absorption rate was also high, and the moisture absorption ability was lost even after three weeks. do not have. Because of its excellent water absorbency, it can be effectively used for wall materials to prevent condensation. For example, 40℃, 1
When m2 of air reaches 0℃, 1m2 of ceiling surface has approx.
This results in 117g of condensed water, but this composite material body has about 20 times the water absorption capacity, and its water absorption and water retention capacity is about 2400g per 1 m2. 5.7~ when converted to siligakel
Equivalent to 6.4Kg. Furthermore, by making sodium polyacrylate insoluble in water, the growth of mold can be effectively prevented. In the case of water-soluble sodium polyacrylate, mold is thought to grow due to residual nutrients because the starch is subjected to craft polymerization of sodium acrylate. Since the perforated permeable film 14 does not allow moisture to pass through, the moisture absorbed by the sodium polyacrylate does not leak to the outside. On the other hand, since it has air permeability and moisture permeability, it does not impair the above-mentioned humidity control properties and also contributes to preventing stuffiness in stored items. It is preferable to impregnate the above composite material with hinokitiol, hinoki oil, or wasabi extract. Since these have insect repellent and bactericidal effects, they can be made into more multifunctional composite material bodies. The use of the composite material body of the present invention is not particularly limited, but it can be used for moisture absorption, water absorption, deodorization, and insect repellent by laying it in food containers, etc., it can be used as a wall material to prevent condensation, and it can be stored in a drawer to absorb moisture. , water absorption, deodorization,
It can be suitably used for insect repellent, for preserving the freshness of vegetables and fruits, etc. (Effects of the Invention) As described above, according to the present invention, by incorporating an inorganic porous material made of hydrated magnesium silicate mineral and having a large number of elongated tunnel-like pores arranged in a cross-sectional matrix, gas absorption properties are improved. It has excellent deodorizing properties because it adsorbs odor components, and it is effective in keeping vegetables, fruits, etc. fresh because it absorbs ethylene gas, etc. On the other hand, by mixing sodium polyacrylate, it has excellent deodorizing properties. , excellent water absorption,
Furthermore, it is possible to provide a multifunctional composite material body that also has antifungal and insect repellent properties.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は複合材料体の断面説明図、第2図、第
3図は無機多孔体の結晶構造の説明図、第4図は
接着剤シートの説明図である。 10……第1の積層シート体、12……支持
体、14……有孔通気性フイルム、16……吸水
剤、18……第2の積層シート体、20,22…
…支持体、24……無機多孔体粉末。
FIG. 1 is an explanatory cross-sectional view of the composite material body, FIGS. 2 and 3 are explanatory views of the crystal structure of the inorganic porous body, and FIG. 4 is an explanatory view of the adhesive sheet. DESCRIPTION OF SYMBOLS 10... First laminated sheet body, 12... Support body, 14... Perforated breathable film, 16... Water absorbing agent, 18... Second laminated sheet body, 20, 22...
... Support, 24 ... Inorganic porous powder.

Claims (1)

【特許請求の範囲】 1 ポリアクリル酸ソーダからなる吸水材を、通
気性、吸水性を有する不織布等の支持体と通気性
を有し非透水性の有孔通気性フイルムとの間に散
在させた第1の積層シート体の前記支持体側に、
含水珪酸マグネシウム鉱物からなり、細長いトン
ネル状の多数の空孔が断面マトリクス状に位置す
る無機多孔体粉末を、通気性、吸水性を有する不
織布等の2枚の支持体間に介在させた第2の積層
シート体を貼着したことを特徴とする多機能複合
材料体。 2 ヒノキチオール、ヒノキオイル、ワサビ抽出
成分の少なくとも1種を含浸させたことを特徴と
する請求項1記載の多機能複合材料体。
[Claims] 1. A water-absorbing material made of sodium polyacrylate is interspersed between a support such as a non-woven fabric that has breathability and water-absorption properties and a perforated perforated film that has breathability and is water-impermeable. On the support side of the first laminated sheet body,
A second inorganic porous powder made of hydrated magnesium silicate mineral and having a large number of elongated tunnel-like pores located in a cross-sectional matrix is interposed between two supports such as nonwoven fabrics having breathability and water absorption properties. A multifunctional composite material body characterized by having a laminated sheet body attached thereto. 2. The multifunctional composite material body according to claim 1, characterized in that it is impregnated with at least one of hinokitiol, cypress oil, and wasabi extract.
JP2187557A 1990-07-16 1990-07-16 Multifunctional composite material body Granted JPH0473065A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2187557A JPH0473065A (en) 1990-07-16 1990-07-16 Multifunctional composite material body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2187557A JPH0473065A (en) 1990-07-16 1990-07-16 Multifunctional composite material body

Publications (2)

Publication Number Publication Date
JPH0473065A JPH0473065A (en) 1992-03-09
JPH0570474B2 true JPH0570474B2 (en) 1993-10-05

Family

ID=16208164

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2187557A Granted JPH0473065A (en) 1990-07-16 1990-07-16 Multifunctional composite material body

Country Status (1)

Country Link
JP (1) JPH0473065A (en)

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CN109275707A (en) * 2018-09-08 2019-01-29 李仁帅 A kind of biomass-based degradable preserving fruit and vegetable utilizing moisturizing Gel Compositions film

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