JPH0551557A - Lubricating and heat-resistant coating composition - Google Patents
Lubricating and heat-resistant coating compositionInfo
- Publication number
- JPH0551557A JPH0551557A JP21545491A JP21545491A JPH0551557A JP H0551557 A JPH0551557 A JP H0551557A JP 21545491 A JP21545491 A JP 21545491A JP 21545491 A JP21545491 A JP 21545491A JP H0551557 A JPH0551557 A JP H0551557A
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- boron nitride
- heat
- silicone resin
- composition
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Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、調理器具、電熱器具、
自動車、オートバイ、自転車、油圧機器等に用いられ、
金属、木材、紙、陶器、硝子、セメント並びにプラスチ
ック類にコーティングする潤滑性、耐食性、耐摩耗性等
を向上させるための固体潤滑用コーティング組成物に関
するものである。BACKGROUND OF THE INVENTION The present invention relates to a cooking appliance, an electric heating appliance,
Used in automobiles, motorcycles, bicycles, hydraulic equipment, etc.,
The present invention relates to a solid lubricating coating composition for coating metal, wood, paper, pottery, glass, cement and plastics to improve lubricity, corrosion resistance, wear resistance and the like.
【０００２】[0002]
【従来の技術】従来より固体潤滑用コーティング組成物
は種々開発されている。例えば、シリコーン樹脂、ガラ
スフリット、セラミック顔料等の組み合わせ耐熱コーテ
ィング剤の耐熱温度は、７００℃と低いという問題点が
ある。また、フッソ樹脂、グラスファイト、二硫化モリ
ブデン等の組み合わせ潤滑剤は４００〜５００℃以上の
温度で潤滑特性が著しく低下するという欠点がある。他
方、窒化硼素は濡れ性が悪く、均一に分散できず、塗膜
の平滑性が極めて悪く充分に実用化されるに至っていな
い。2. Description of the Related Art Conventionally, various solid lubricating coating compositions have been developed. For example, there is a problem that the heat resistant temperature of a combination heat resistant coating agent such as silicone resin, glass frit, ceramic pigment, etc. is as low as 700 ° C. Further, a combination lubricant such as a fluororesin, a glassfight, or molybdenum disulfide has a drawback that the lubricating property is remarkably deteriorated at a temperature of 400 to 500 ° C or higher. On the other hand, boron nitride has poor wettability and cannot be uniformly dispersed, and the smoothness of the coating film is extremely poor and it has not yet been put to practical use.
【０００３】[0003]
【発明が解決しようとする課題】したがって、本発明
は、耐熱温度が７００℃以上で、５００℃以上の温度に
おいて良好な潤滑特性を持ち、濡れ性を改良した窒化硼
素を用い、色を自由に選択できる固体潤滑用コーティン
グ組成物を提供することを目的とする。Therefore, the present invention uses boron nitride having a heat resistant temperature of 700 ° C. or higher and good lubrication characteristics at a temperature of 500 ° C. or higher and improved wettability, and can freely change the color. It is an object to provide a solid lubricating coating composition that can be selected.
【０００４】[0004]
【課題を解決するための手段】すなわち、本発明は、シ
リコーン樹脂と、ガラスフリットと、セラミック顔料
と、窒化硼素の全重量に対して０．１〜５重量％の表面
処理剤によって表面処理された窒化硼素とを含有し、こ
れらが均一に分散されていることを特徴とする潤滑・耐
熱コーティング組成物を提供するものである。ここで、
前記組成物は、シリコーン樹脂を１０〜８０重量％、ガ
ラスフリットを２〜２０重量％、セラミック顔料を５〜
５０重量％、窒化硼素を１〜４０重量％含有するのが好
適である。That is, according to the present invention, a surface treatment is performed with a silicone resin, a glass frit, a ceramic pigment, and a surface treatment agent of 0.1 to 5% by weight based on the total weight of boron nitride. Another object of the present invention is to provide a lubricating / heat resistant coating composition containing boron nitride and being uniformly dispersed. here,
The composition comprises 10 to 80% by weight of silicone resin, 2 to 20% by weight of glass frit and 5 to 5% of ceramic pigment.
It is preferable to contain 50% by weight and 1 to 40% by weight of boron nitride.
【０００５】以下に本発明をさらに詳細に説明する。The present invention will be described in more detail below.
【０００６】本発明の固体潤滑用コーティング組成物
は、シリコーン樹脂と、ガラスフリットと、セラミック
顔料と、窒化硼素とを含有し、これらが均一に分散され
ているものである。The solid lubricating coating composition of the present invention contains a silicone resin, a glass frit, a ceramic pigment, and boron nitride, and these are uniformly dispersed.
【０００７】シリコーン樹脂は、他の成分のバインダー
として働き、基材への接着性及び耐熱性を与えるととも
に高温によりシリコーン樹脂が分解して生成するＳｉＯ
2 等の酸化物がガラスフリットと共に高融点のセラミッ
ク層を形成する。The silicone resin acts as a binder for other components, gives adhesiveness to a substrate and heat resistance, and is produced by decomposition of the silicone resin at high temperature.
Oxides such as 2 form a high melting point ceramic layer together with the glass frit.
【０００８】シリコーン樹脂の組成物中の含有量が１０
重量％より少ない場合は、温度上昇によりシリコーン樹
脂が分解して生成するＳｉＯ2 等の酸化物の量が少なく
なり、ガラスフリットと共に形成する高融点セラミック
物質層が少なくなる結果、耐熱性皮膜形成が不充分とな
る。また、塗膜の平滑性が低下する。また、８０重量％
より多い場合には、高温で生成したセラミック皮膜に亀
裂を生じ、基材との密着性が低下するので好ましくな
い。The content of the silicone resin in the composition is 10
If the amount is less than 10% by weight, the amount of oxides such as SiO 2 generated by decomposition of the silicone resin due to temperature increase is reduced, and the high melting point ceramic substance layer formed together with the glass frit is reduced, resulting in formation of a heat resistant film. Will be insufficient. In addition, the smoothness of the coating film decreases. Also, 80% by weight
If the amount is larger than the above range, the ceramic coating formed at a high temperature is cracked and the adhesion to the substrate is deteriorated, which is not preferable.
【０００９】シリコーン樹脂としてはメチル系シリコー
ン樹脂、メチルフェニル系シリコーン樹脂の単独もしく
は混合物、更にはエポキシ変性シリコーン樹脂、アクリ
ル変性シリコーン樹脂、あるいはシリコーン樹脂とメチ
ルメタクリレート、アクリロニトリル等の有機モノマー
との共重合体の１種または混合物を使用することができ
る。As the silicone resin, a methyl-based silicone resin, a methylphenyl-based silicone resin alone or a mixture thereof, further, an epoxy-modified silicone resin, an acrylic-modified silicone resin, or a copolymerization of the silicone resin and an organic monomer such as methylmethacrylate or acrylonitrile. One or a mixture of coalesces can be used.
【００１０】ガラスフリットは通常融点が３００〜６０
０℃のホウケイ酸ガラス、または、含鉛ガラスあるいは
りん酸系ガラス等が用いられる。高温における金属基材
との密着性を更に向上させるために、Ｃｏ、Ｎｉ、Ｐ、
Ｍｎ、Ｔｉ、Ｚｒ、Ｃｅ、Ｍｏ等の金属酸化物やその化
合物等を１種または２種以上添加混合したものを用いる
ことが望ましい。The glass frit usually has a melting point of 300 to 60.
Borosilicate glass at 0 ° C., lead-containing glass, phosphoric acid glass, or the like is used. In order to further improve the adhesion to the metal base material at high temperature, Co, Ni, P,
It is desirable to use a metal oxide such as Mn, Ti, Zr, Ce, Mo, or the like, or a mixture of one or more metal oxides thereof.
【００１１】組成物中のガラスフリットの含有量を２重
量％より少なくした場合には、塗膜中の樹脂成分の熱分
解後のセラミック皮膜形成が不充分となり、２０重量％
を超えるとコーティング時の塗膜の平滑性が低下、基材
への密着性が悪くなる傾向がある。When the content of the glass frit in the composition is less than 2% by weight, the formation of the ceramic film after the thermal decomposition of the resin component in the coating film becomes insufficient, resulting in 20% by weight.
If it exceeds, the smoothness of the coating film at the time of coating tends to deteriorate, and the adhesion to the substrate tends to deteriorate.
【００１２】セラミック顔料は少なくともガラスフリッ
トよりも融点が高い無機物で、融点６００℃、好ましく
は８００℃以上のもので、アルミナ、ジルコニア、チタ
ン酸バリウム、ジルコン、窒化珪素その他のセラミック
系耐熱着色顔料等が使用される。The ceramic pigment is an inorganic substance having a melting point higher than that of at least glass frit and has a melting point of 600 ° C. or higher, preferably 800 ° C. or higher. Alumina, zirconia, barium titanate, zircon, silicon nitride and other ceramic heat resistant coloring pigments. Is used.
【００１３】組成物中のセラミック顔料の含有量は５〜
５０重量％とする。顔料の含有量が５重量％未満では、
着色不足となり、５０重量％を超えると、密着性が悪く
なるためである。The content of the ceramic pigment in the composition is 5 to 5.
50% by weight. When the pigment content is less than 5% by weight,
This is because the coloring becomes insufficient, and when it exceeds 50% by weight, the adhesiveness deteriorates.
【００１４】本発明の組成物は窒化硼素を含むことが特
徴の一つである。窒化硼素には下記のような優れた特性
があり、本発明の目的である潤滑性、耐食性、低摩擦
性、耐衝撃性などを達成する。 （１）窒化硼素は、熱を伝えやすく耐熱衝撃性にすぐれ
ている。 （２）窒化硼素は、鱗片状をしており表面処理をした窒
化硼素は落葉的積層皮膜を形成し、塗料塗膜の防食性、
耐衝撃性、耐折り曲げ性等を大幅に改良する。 （３）窒化硼素は８００℃前後まで空気中で安定なため
高温下でも良好な潤滑性、低摩擦性離型性を付与する。 （４）窒化硼素は白色であり、固体潤滑塗料として、着
色顔料を添加することにより自由に色を選ぶことができ
る。 （５）窒化硼素は、中性物質（ｐＨ６．６〜７．０）で
あり塗料塗膜の耐防食性に影響しない。One of the characteristics of the composition of the present invention is that it contains boron nitride. Boron nitride has the following excellent properties and achieves the objects of the present invention such as lubricity, corrosion resistance, low friction property, impact resistance and the like. (1) Boron nitride easily transmits heat and has excellent thermal shock resistance. (2) Boron nitride has a scale-like shape and surface-treated boron nitride forms a deciduous laminated film, and the corrosion resistance of the paint film is
Greatly improves impact resistance and bending resistance. (3) Since boron nitride is stable in air up to around 800 ° C, it provides good lubricity and low friction releasability even at high temperatures. (4) Boron nitride is white, and its color can be freely selected as a solid lubricating coating by adding a coloring pigment. (5) Boron nitride is a neutral substance (pH 6.6 to 7.0) and does not affect the corrosion resistance of the paint film.
【００１５】組成物中の窒化硼素の含有量は１〜４０重
量％とする。窒化硼素を１重量％より少なくした場合に
は、潤滑性、低摩擦性、離型性、耐熱性、耐熱衝撃性が
低下し、４０重量％を超えると塗膜中バインダーが不足
して、基材との密着性を低下させるためである。The content of boron nitride in the composition is 1 to 40% by weight. When the content of boron nitride is less than 1% by weight, the lubricity, low friction property, releasability, heat resistance and thermal shock resistance are deteriorated. This is to reduce the adhesiveness with the material.
【００１６】窒化硼素は組成物中に均一に分散させるた
めにはカップリング剤のような表面処理剤で処理するの
がよい。窒化硼素の表面処理剤での処理は組成物中に混
合する前に予め処理してもよいし、組成物中で表面処理
剤とともに混合して処理してもよい。いずれの場合に
も、表面処理剤は窒化硼素の全重量に対して０．１〜
５．０重量％にするのがよく、０．１重量％未満である
と表面処理効果が十分発揮されず、５．０重量％を超え
ると耐熱性などの性能に悪影響を及ぼす恐れがあり、ま
た不経済である。Boron nitride is preferably treated with a surface treatment agent such as a coupling agent in order to uniformly disperse it in the composition. The treatment of the boron nitride with the surface treatment agent may be performed in advance before being mixed in the composition, or may be performed by mixing it with the surface treatment agent in the composition. In each case, the surface treatment agent is 0.1 to 0.1% based on the total weight of boron nitride.
It is preferable to be 5.0% by weight, and if it is less than 0.1% by weight, the surface treatment effect is not sufficiently exerted, and if it exceeds 5.0% by weight, performance such as heat resistance may be adversely affected. It is also uneconomical.
【００１７】本発明において表面処理剤は、チタネート
カップリング剤、シランカップリング剤およびノニオン
カップリング剤から選ばれた１種以上を用いる。In the present invention, as the surface treatment agent, one or more selected from titanate coupling agents, silane coupling agents and nonionic coupling agents are used.
【００１８】上記のカップリング剤について、代表的な
ものを以下に記す。Typical examples of the above coupling agent are shown below.
【００１９】チタネートカップリング剤には、イソプロ
ピルトリイソステアロイルチタネート、イソプロピルト
リドテシルベンゼン・スルホニルチタネート、テトラ
（２，２−ジアリルオキシメチル−１−ブチル）ビス
（ジートリデシル）ホスファイトチタネート等がある。Examples of titanate coupling agents include isopropyltriisostearoyl titanate, isopropyltridotecil benzene sulfonyl titanate, and tetra (2,2-diallyloxymethyl-1-butyl) bis (ditridecyl) phosphite titanate.
【００２０】シランカップリン剤には、ビニルトリクロ
ルシラン、ビニルトリエトキシシラン、ビニルトリス
（β−メトキシエトキシ）シラン等がある。Examples of the silane coupling agent include vinyltrichlorosilane, vinyltriethoxysilane, vinyltris (β-methoxyethoxy) silane and the like.
【００２１】ノニオンカップリング剤には、ポリオキシ
エチレン・ラウレート、ポリオキシエチレン・ステアレ
ート、ポリオキシエチレン・オレート等がある。Nonionic coupling agents include polyoxyethylene laurate, polyoxyethylene stearate, polyoxyethylene oleate and the like.
【００２２】本発明の組成物には、必要に応じて、他の
添加剤（例えば、分散剤、消泡剤など）、トルエン、キ
シレン、ブタノールなどの溶剤などを含有せしめてもよ
いのは勿論のことである。If desired, the composition of the present invention may contain other additives (for example, a dispersant, an antifoaming agent, etc.), a solvent such as toluene, xylene, butanol and the like. That is.
【００２３】そして、本発明のコーティング組成物を均
一に分散させる手段としては、ディスパー（高速撹拌
機）、アトライター、サンドミル、ボールミルなどの分
散機で行なうのがよい。As a means for uniformly dispersing the coating composition of the present invention, it is preferable to use a disperser such as a disper (high speed stirrer), an attritor, a sand mill or a ball mill.
【００２４】[0024]
【実施例】以下に本発明を実施例および比較例に基づい
て具体的に説明する。EXAMPLES The present invention will be specifically described below based on Examples and Comparative Examples.
【００２５】（実施例１）トルエン１０００重量部にイ
ソプロピルトリドテシルベンゼン・スルホニルチタネー
ト１重量部を溶解し、窒化硼素（粒径２〜１０μｍ）１
００重量部を加え、ディスパーで１０分撹拌した後吸引
濾過でトルエンを除去し、処理済み窒化硼素を得た。こ
の処理済み窒化硼素を用いて、下記の配合物をボールミ
ルで１０時間処理して充分分散した耐熱コーティング剤
を得た。 処理済み窒化硼素 １０重量部 シリコーン樹脂 ５０重量部（東芝シリコーン TSR-117) 耐熱顔料 ２０重量部 （大日精化工業 セラミックブラック） フリット １０重量部（日本琺瑯釉薬） 添加剤（分散剤） ５重量部 溶 剤（トルエン） ５重量部 ──────────────────── 計 １００重量部 (Example 1) 1 part by weight of isopropyl tridotecylbenzene sulfonyl titanate was dissolved in 1000 parts by weight of toluene, and boron nitride (particle size: 2 to 10 μm) 1
00 parts by weight was added, and the mixture was stirred with a disper for 10 minutes and then toluene was removed by suction filtration to obtain a treated boron nitride. Using the treated boron nitride, the following composition was treated with a ball mill for 10 hours to obtain a well-dispersed heat-resistant coating agent. Treated boron nitride 10 parts by weight Silicone resin 50 parts by weight (Toshiba Silicone TSR-117) Heat-resistant pigment 20 parts by weight (Dainichi Seika Kogyo Ceramic Black) Frit 10 parts by weight (Nippon Horo Glaze) Additive (dispersant) 5 parts by weight Solvent (toluene) 5 parts by weight ──────────────────── Total 100 parts by weight
【００２６】（比較例１）下記の配合物をボールミルで
１０時間処理して充分分散した耐熱コーティング剤を得
た。 シリコーン樹脂 ５０重量部（東芝シリコーン TSR-117) 耐熱顔料 ２０重量部 （大日精化工業 セラミックブラック） フリット １０重量部（日本琺瑯釉薬） 添加剤（分散剤） ５重量部 溶 剤（トルエン） １５重量部 ──────────────────── 計 １００重量部 (Comparative Example 1) The following formulation was treated with a ball mill for 10 hours to obtain a well-dispersed heat-resistant coating agent. Silicone resin 50 parts by weight (Toshiba Silicone TSR-117) Heat resistant pigment 20 parts by weight (Dainichi Seika Kogyo Ceramic Black) Frit 10 parts by weight (Nippon Enamel Glaze) Additive (dispersant) 5 parts by weight Solvent (toluene) 15 parts by weight Parts ──────────────────── Total 100 parts by weight
【００２７】（比較例２）下記の配合物をボールミルで
１０時間処理して充分分散した耐熱コーティング剤を得
た。 シリコーン樹脂 ５０重量部（東芝シリコーン TSR-117) 耐熱顔料 ２０重量部 （大日精化工業 セラミックブラック） 添加剤（分散剤） ５重量部 溶 剤（トルエン） ２５重量部 ──────────────────── 計 １００重量部 (Comparative Example 2) The following composition was treated with a ball mill for 10 hours to obtain a well-dispersed heat-resistant coating agent. Silicone resin 50 parts by weight (Toshiba Silicone TSR-117) Heat resistant pigment 20 parts by weight (Dainichi Seika Kogyo Ceramic Black) Additive (dispersant) 5 parts by weight Solvent (toluene) 25 parts by weight ───────── ──────────── Total 100 parts by weight
【００２８】上記にようにして得られた種々の潤滑耐熱
コーティング剤について鋼板上にコーティング剤を塗布
し、２００℃×２０分の焼付け条件で処理した上で下記
の試験方法で試験を行なった。その結果を表１に示す。The various lubricating and heat-resistant coating agents obtained as described above were coated on a steel sheet, treated under baking conditions of 200 ° C. for 20 minutes, and then tested by the following test method. The results are shown in Table 1.
【００２９】（平滑性）塗膜の平滑さを目視で観察し
た。(Smoothness) The smoothness of the coating film was visually observed.
【００３０】（耐熱性）１００℃から１００℃おきに９
００℃まで各２４時間加熱し、塗膜のふくれ、われ、剥
離等を観察した。(Heat resistance) From 100 ° C to 100 ° C every 9
It was heated to 00 ° C. for 24 hours each, and swelling, cracking, peeling and the like of the coating film were observed.
【００３１】（耐食性）３００℃で２時間加熱後、耐塩
水噴霧性をＪＩＳ Ｋ５４００ ９．１で１６８時間実
施した。(Corrosion resistance) After heating at 300 ° C. for 2 hours, salt spray resistance was carried out according to JIS K5400 9.1 for 168 hours.
【００３２】（耐摩耗性−低荷重および高荷重）ファレ
ックス試験機で実施した。(Abrasion resistance-low load and high load) It was carried out on a Falex tester.
【００３３】 [0033]
【００３４】[0034]
【発明の効果】本発明のコーティング組成物により得ら
れる塗膜は、平滑性、耐熱性、耐食性、耐摩耗化などに
優れ、種々の用途に最適である。The coating film obtained by the coating composition of the present invention is excellent in smoothness, heat resistance, corrosion resistance, abrasion resistance and the like, and is most suitable for various uses.
Claims (2)
ラミック顔料と、窒化硼素の全重量に対して０．１〜５
重量％の表面処理剤によって表面処理された窒化硼素と
を含有し、これらが均一に分散されていることを特徴と
する潤滑・耐熱コーティング組成物。1. A total of 0.1 to 5 relative to the total weight of silicone resin, glass frit, ceramic pigment, and boron nitride.
A lubricating / heat-resistant coating composition comprising boron nitride surface-treated with a surface treatment agent in an amount of% by weight, and these are uniformly dispersed.
０重量％、ガラスフリットを２〜２０重量％、セラミッ
ク顔料を５〜５０重量％、窒化硼素を１〜４０重量％含
有する請求項１に記載の潤滑・耐熱コーティング組成
物。2. The composition comprises 10 to 8 silicone resins.
The lubricating / heat resistant coating composition according to claim 1, which contains 0% by weight, 2 to 20% by weight of glass frit, 5 to 50% by weight of ceramic pigment, and 1 to 40% by weight of boron nitride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21545491A JPH0551557A (en) | 1991-08-27 | 1991-08-27 | Lubricating and heat-resistant coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21545491A JPH0551557A (en) | 1991-08-27 | 1991-08-27 | Lubricating and heat-resistant coating composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0551557A true JPH0551557A (en) | 1993-03-02 |
Family
ID=16672639
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21545491A Withdrawn JPH0551557A (en) | 1991-08-27 | 1991-08-27 | Lubricating and heat-resistant coating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0551557A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003003069A (en) * | 2001-06-21 | 2003-01-08 | Fujikura Ltd | Silicone resin composition and low-tension fire-resisting cable using the same |
| WO2004099327A1 (en) * | 2003-04-30 | 2004-11-18 | National Starch And Chemical Investment Holding Corporation | Waterbased high abrasion resistant coating |
| KR20060096528A (en) * | 2005-03-02 | 2006-09-13 | 이창호 | Heat resisting non stick coating composition |
| JP2007217493A (en) * | 2006-02-15 | 2007-08-30 | Denki Kagaku Kogyo Kk | Boron nitride slurry and mold-releasing agent |
| US7445797B2 (en) | 2005-03-14 | 2008-11-04 | Momentive Performance Materials Inc. | Enhanced boron nitride composition and polymer-based compositions made therewith |
| US7524560B2 (en) | 2005-08-19 | 2009-04-28 | Momentive Performance Materials Inc. | Enhanced boron nitride composition and compositions made therewith |
| US7527859B2 (en) | 2006-10-08 | 2009-05-05 | Momentive Performance Materials Inc. | Enhanced boron nitride composition and compositions made therewith |
| US7976941B2 (en) | 1999-08-31 | 2011-07-12 | Momentive Performance Materials Inc. | Boron nitride particles of spherical geometry and process for making thereof |
| JP2014091833A (en) * | 2012-10-31 | 2014-05-19 | Seb Sa | Ceramic coating with improved scratch resistance and heat conduction properties |
| US9550888B2 (en) | 1999-08-31 | 2017-01-24 | Momentive Performance Materials Inc. | Low viscosity filler composition of boron nitride particles of spherical geometry and process |
| JP2017066248A (en) * | 2015-09-29 | 2017-04-06 | 住鉱潤滑剤株式会社 | Coating material composition |
| FR3060600A1 (en) * | 2016-12-20 | 2018-06-22 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | ANTI-EROSION COATING OF A MECHANICAL PART AND PROCESSING METHOD |
| JP2020076045A (en) * | 2018-07-11 | 2020-05-21 | 三ツ星ベルト株式会社 | Ceramic color paste, ceramic color and glass with ceramic color and method for producing the same |
-
1991
- 1991-08-27 JP JP21545491A patent/JPH0551557A/en not_active Withdrawn
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7976941B2 (en) | 1999-08-31 | 2011-07-12 | Momentive Performance Materials Inc. | Boron nitride particles of spherical geometry and process for making thereof |
| US9550888B2 (en) | 1999-08-31 | 2017-01-24 | Momentive Performance Materials Inc. | Low viscosity filler composition of boron nitride particles of spherical geometry and process |
| US9079801B2 (en) | 1999-08-31 | 2015-07-14 | Momentive Performance Materials Inc. | Boron nitride particles of spherical geometry and process of making |
| JP2003003069A (en) * | 2001-06-21 | 2003-01-08 | Fujikura Ltd | Silicone resin composition and low-tension fire-resisting cable using the same |
| WO2004099327A1 (en) * | 2003-04-30 | 2004-11-18 | National Starch And Chemical Investment Holding Corporation | Waterbased high abrasion resistant coating |
| US7247673B2 (en) | 2003-04-30 | 2007-07-24 | National Starch And Chemical Investment Holding Corporation | Waterbased high abrasion resistant coating |
| KR20060096528A (en) * | 2005-03-02 | 2006-09-13 | 이창호 | Heat resisting non stick coating composition |
| US7445797B2 (en) | 2005-03-14 | 2008-11-04 | Momentive Performance Materials Inc. | Enhanced boron nitride composition and polymer-based compositions made therewith |
| US7524560B2 (en) | 2005-08-19 | 2009-04-28 | Momentive Performance Materials Inc. | Enhanced boron nitride composition and compositions made therewith |
| JP2007217493A (en) * | 2006-02-15 | 2007-08-30 | Denki Kagaku Kogyo Kk | Boron nitride slurry and mold-releasing agent |
| JP4575310B2 (en) * | 2006-02-15 | 2010-11-04 | 電気化学工業株式会社 | Boron nitride slurry and release agent |
| US7527859B2 (en) | 2006-10-08 | 2009-05-05 | Momentive Performance Materials Inc. | Enhanced boron nitride composition and compositions made therewith |
| JP2014091833A (en) * | 2012-10-31 | 2014-05-19 | Seb Sa | Ceramic coating with improved scratch resistance and heat conduction properties |
| US9725809B2 (en) | 2012-10-31 | 2017-08-08 | Seb S.A. | Ceramic coating with scratch resistance and thermal conduction properties |
| JP2017066248A (en) * | 2015-09-29 | 2017-04-06 | 住鉱潤滑剤株式会社 | Coating material composition |
| FR3060600A1 (en) * | 2016-12-20 | 2018-06-22 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | ANTI-EROSION COATING OF A MECHANICAL PART AND PROCESSING METHOD |
| JP2020076045A (en) * | 2018-07-11 | 2020-05-21 | 三ツ星ベルト株式会社 | Ceramic color paste, ceramic color and glass with ceramic color and method for producing the same |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A300 | Withdrawal of application because of no request for examination |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 19981112 |