JPH0548896B2 - - Google Patents
Info
- Publication number
- JPH0548896B2 JPH0548896B2 JP854484A JP854484A JPH0548896B2 JP H0548896 B2 JPH0548896 B2 JP H0548896B2 JP 854484 A JP854484 A JP 854484A JP 854484 A JP854484 A JP 854484A JP H0548896 B2 JPH0548896 B2 JP H0548896B2
- Authority
- JP
- Japan
- Prior art keywords
- silver halide
- silver
- halide photographic
- make
- add water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052709 silver Inorganic materials 0.000 claims description 9
- 239000004332 silver Substances 0.000 claims description 9
- -1 silver halide Chemical class 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 5
- IBWXIFXUDGADCV-UHFFFAOYSA-N 2h-benzotriazole;silver Chemical compound [Ag].C1=CC=C2NN=NC2=C1 IBWXIFXUDGADCV-UHFFFAOYSA-N 0.000 claims 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 239000000839 emulsion Substances 0.000 claims 1
- 229940100890 silver compound Drugs 0.000 claims 1
- 150000003379 silver compounds Chemical class 0.000 claims 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- GVEYRUKUJCHJSR-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.OCCN(CC)C1=CC=C(N)C(C)=C1 GVEYRUKUJCHJSR-UHFFFAOYSA-N 0.000 description 1
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- CTTCABBTXVGTAB-UHFFFAOYSA-L C(C)(=O)[O-].[Fe+2].C(CN)N.C(C)(=O)[O-] Chemical compound C(C)(=O)[O-].[Fe+2].C(CN)N.C(C)(=O)[O-] CTTCABBTXVGTAB-UHFFFAOYSA-L 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 235000011126 aluminium potassium sulphate Nutrition 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- KYQODXQIAJFKPH-UHFFFAOYSA-N diazanium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [NH4+].[NH4+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O KYQODXQIAJFKPH-UHFFFAOYSA-N 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229940001482 sodium sulfite Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- HERBOKBJKVUALN-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]acetate;hydrate Chemical compound O.[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O HERBOKBJKVUALN-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/34—Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
Description
Ｎ−メチル−ｐ−アミノフエノール硫酸塩 ３ｇ 無水亜硫酸ナトリウム 45ｇ ハロドロキノン 12ｇ 炭酸ナトリウム 66ｇ 臭化カリウム ２ｇ 水を加えて１とする 〔白黒定着液組成〕 チオ硫酸ナトリウム 160ｇ 無水亜硫酸ナトリウム 14ｇ 氷酢酸 12ml ホウ砂 12ｇ カリ明ばん ５ｇ 水を加えて１とする。 N-methyl-p-aminophenol sulfate 3g Anhydrous sodium sulfite 45g Halodroquinone 12g Sodium carbonate 66g Potassium bromide 2g Add water to make 1 [Black and white fixer composition] Sodium thiosulfate 160g Anhydrous sodium sulfite 14g Glacial acetic acid 12ml 12g borax Potash alum 5g Add water to make 1.
【表】【table】
10％チオ硫酸アンモニウム液 150ml 亜硫酸ナトリウム ５ｇ エチレンジアミン酢酸鉄（） ナトリウム 40ｇ エチレンジアミンテトラ酢酸 ４ｇ 水を加えて１とする。 10% ammonium thiosulfate solution 150ml Sodium sulfite 5g Ethylenediamine iron acetate () Sodium 40g Ethylenediaminetetraacetic acid 4g Add water to make 1.
４−アミノ−３−メチル−Ｎ−エチル−Ｎ（β
−ヒドロキシエチル）−アニリン硫酸塩 4.75ｇ
無水亜硫酸ナトリウム 4.25ｇ
ヒドロキシルアミン1/2硫酸塩 2.0ｇ
無水炭酸カリウム 37.5ｇ
臭化ナトリウム 1.3ｇ
ニトリロトリ酢酸−３ナトリウム塩（１水塩）
2.5ｇ
水酸化カリウム 1.0ｇ
水を加えて１とし、水酸化カリウムを
用いてPH10.0に調整する
〔漂白液組成〕
エチレンジアミンテトラ酢酸アンモニウム塩
100.0ｇ
エチレンジアミンテトラ酢酸２アンモニウム塩
10.0ｇ
臭化アンモニウム 150.0ｇ
氷酢酸 10.0ml
水を加えて１とし、アンモニア水を用いてPH
6.5に調整する。
〔定着液組成〕
ホルマリン（37％水溶液） 5.0ｇ
コニダツクス（小西六写真工業(株)製） 7.5ml
水を加えて１とする
4-amino-3-methyl-N-ethyl-N(β
-hydroxyethyl)-aniline sulfate 4.75g Anhydrous sodium sulfite 4.25g Hydroxylamine 1/2 sulfate 2.0g Anhydrous potassium carbonate 37.5g Sodium bromide 1.3g Nitrilotriacetic acid trisodium salt (monohydrate)
2.5g Potassium hydroxide 1.0g Add water to make 1 and adjust the pH to 10.0 using potassium hydroxide [Bleach solution composition] Ammonium salt of ethylenediaminetetraacetate
100.0g Ethylenediaminetetraacetic acid diammonium salt
10.0g Ammonium bromide 150.0g Glacial acetic acid 10.0ml Add water to make 1, and adjust the pH using ammonia water.
Adjust to 6.5. [Fixer composition] Formalin (37% aqueous solution) 5.0g Konidax (manufactured by Konishiroku Photo Industry Co., Ltd.) 7.5ml Add water to make 1.
【表】
発明の具体的効果
以上の実施例に示す如く、本発明の化合物を添
加したハロゲン化銀写真感光材料は、カブリをほ
とんど増加することなしに、大幅に感度が向上す
ることがわかる。[Table] Specific Effects of the Invention As shown in the examples above, it can be seen that the sensitivity of silver halide photographic materials to which the compound of the present invention is added is significantly improved with almost no increase in fog.
Claims (1)
ハロゲン化銀であるハロゲン化銀写真感光材料に
おいて、該ハロゲン化銀を含有する乳剤層中にベ
ンゾトリアゾール銀またはその誘導体を含有する
ことを特徴とするハロゲン化銀写真感光材料。 ２ 前記ベンゾトリアゾール銀またはその誘導体
の含有量が、ハロゲン化銀１モルに対して1.0×
10-4モル〜１モルである特許請求の範囲第１項記
載のハロゲン化銀写真感光材料。[Scope of Claims] 1. In a silver halide photographic light-sensitive material in which the silver compound that is developed to form a silver image is mainly silver halide, benzotriazole silver or a derivative thereof is present in the emulsion layer containing the silver halide. A silver halide photographic material characterized by containing. 2 The content of the silver benzotriazole or its derivative is 1.0× per mole of silver halide.
The silver halide photographic material according to claim 1, wherein the silver halide photographic material has a content of 10 -4 mol to 1 mol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP854484A JPS60153038A (en) | 1984-01-23 | 1984-01-23 | Photosensitive silver halide material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP854484A JPS60153038A (en) | 1984-01-23 | 1984-01-23 | Photosensitive silver halide material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60153038A JPS60153038A (en) | 1985-08-12 |
| JPH0548896B2 true JPH0548896B2 (en) | 1993-07-22 |
Family
ID=11696080
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP854484A Granted JPS60153038A (en) | 1984-01-23 | 1984-01-23 | Photosensitive silver halide material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60153038A (en) |
-
1984
- 1984-01-23 JP JP854484A patent/JPS60153038A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60153038A (en) | 1985-08-12 |
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